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CN109454939A - 一种人造革及用在人造革的pvc面层原料 - Google Patents

一种人造革及用在人造革的pvc面层原料 Download PDF

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Publication number
CN109454939A
CN109454939A CN201811139073.3A CN201811139073A CN109454939A CN 109454939 A CN109454939 A CN 109454939A CN 201811139073 A CN201811139073 A CN 201811139073A CN 109454939 A CN109454939 A CN 109454939A
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artificial leather
layer
pvc
scuff
fixture block
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曹忠德
姜志军
方忠华
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ZHEJIANG HUAXIANG LEATHER Co Ltd
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ZHEJIANG HUAXIANG LEATHER Co Ltd
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/12—Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
    • B32B3/26—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/04—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/04—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B9/045—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0059—Organic ingredients with special effects, e.g. oil- or water-repellent, antimicrobial, flame-resistant, magnetic, bactericidal, odour-influencing agents; perfumes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N3/06—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with polyvinylchloride or its copolymerisation products
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10—Inorganic fibres
    • B32B2262/106—Carbon fibres, e.g. graphite fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/554—Wear resistance
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/71—Resistive to light or to UV
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/714—Inert, i.e. inert to chemical degradation, corrosion
    • B32B2307/7145—Rot proof, resistant to bacteria, mildew, mould, fungi
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/724—Permeability to gases, adsorption

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  • Textile Engineering (AREA)
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  • Chemical Kinetics & Catalysis (AREA)
  • Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)

Abstract

本发明提供一种人造革，包括人造革本体，在人造革本体上设有若干通透孔，所述的人造革本体包括从外到内依次设有的基布层、粘合层、PVC面层、防磨层和防臭夹层，所述的防磨层与PVC面层之间设有抗菌夹层，还讲述了一种用在人造革的PVC面层原料，由下列重量份的原料组成：PVC树脂粉80‑90%，稳定剂1‑3%，紫外线吸收剂1‑3%，AC发泡剂3‑10%，增塑剂6‑12%。本发明的有益效果是：通过在人造革内设置的防磨层，提高其抗磨性；设置的PVC面层原料内设有的紫外线吸收剂，提高抗紫外线性能；设置的抗菌夹层，提高抗菌性能；在人造革本体上设有的若干通透孔，透气性好，更加方便。

Description

一种人造革及用在人造革的PVC面层原料
技术领域
本发明属于人造革技术领域，尤其是涉及一种人造革及用在人造革的PVC面层原料。
背景技术
人造革是一种外观、手感似皮革并可代替其使用的塑料制品。通常以织物为底基，涂覆合成树脂及各种塑料添加制成，然后加热使之塑化，并经滚压压平或压花，即得产品。近似于天然皮革，具有柔软、耐磨等特点。根据覆盖物的种类不同，按照用途有鞋用人造革、箱包用人造革等。
人造革在服装、运动鞋、沙发、箱包等领域应用中，对紫外线起到无法起到防护作用，抗紫外线性能差；随着人们使用人造革，其抗菌性能差，防臭等性能差，使得降低对其使用寿命；尤其是在服装装领域中，其易出现磨损等现象，影响其外观使用。
发明内容
本发明的目的是提供一种结构简单、提高其抗磨性、抗紫外线性能强、抗菌性能强和透气性好的人造革及用在人造革的PVC面层原料，尤其适合用在服装、运动鞋、沙发、箱包等领域应用。
本发明的技术方案是：一种人造革，包括人造革本体，在人造革本体上设有若干通透孔，所述的人造革本体包括从外到内依次设有的基布层、粘合层、PVC面层、防磨层和防臭夹层，所述的基布层为起毛布、针织布、无纺布，所述的粘合层包括上层和下层，所述的上层的上表面、下层的下表面分别通过粘贴方式设在基布层、PVC面层上，所述的上层下表面、下层的上表面上对应设有下卡块、上卡块，所述的上卡块卡在下卡块内，且在上卡块与下卡块之间的间隙设有胶水，所述的防磨层与PVC面层之间设有抗菌夹层，在防磨层的最内侧设有防臭夹层，所述防臭夹层包括外层和内层，活性炭纤维粘合在外层和内层之间，其防臭夹层具有吸附臭味的功能，其面层具有排除臭味的功能。
优选地，所述的通透孔为正方形、圆形、菱形或者各种星型图案。
优选地，所述的防磨层为在人造革本体内表面设有多个小凸起。
优选地，所述的抗菌夹层为银离子层，起到对人造革服装的抗菌作用。
优选地，所述的防臭夹层为活性炭纤维。
一种用在人造革的PVC面层原料，由下列重量份的原料组成：
所述的稳定剂为KZn稳定剂，所述的紫外线吸收剂为AD12T紫外线吸收剂。
优选地，所述的增速剂为己二酸二辛脂和邻苯二甲酸二辛脂，可以与PVC树脂粉有很好的相容性，进而起到降低粘度的作用。
优选地，所述的PVC面层原料还包括抗氧化剂，所述的抗氧化剂站占原料的重量份为1-3％。
优选地，所述的抗氧化剂为AD12S抗氧化剂。
优选地，所述增塑剂剂采用DOP、DINP和DOA中的一种或几种混合物。
优选地，所述的PVC面层原料，最优重量份的原料组成为
本发明具有的优点和积极效果是：由于采用上述技术方案，通过在人造革内设置的防磨层，提高其抗磨性；设置的PVC面层原料内设有的紫外线吸收剂，提高抗紫外线性能；设置的抗菌夹层，提高抗菌性能；在人造革本体上设有的若干通透孔，透气性好，更加方便。
附图说明
图1是本发明的结构示意图。
图中：
1、基布层 2、粘合层 3、PVC面层
4、防磨层 5、防臭夹层 6、下卡块
7、上卡块 8、抗菌夹层
具体实施方式
如图1所示，本发明的技术方案为提供一种人造革，包括人造革本体，在人造革本体上设有若干通透孔，所述的人造革本体包括从外到内依次设有的基布层1、粘合层2、PVC面层3、防磨层4和防臭夹层5，所述的基布层1为起毛布、针织布、无纺布，所述的粘合层2包括上层和下层，所述的上层的上表面、下层的下表面分别通过粘贴方式设在基布层1、PVC面层3上，所述的上层下表面、下层的上表面上对应设有下卡块6、上卡块7，所述的上卡块卡在下卡块内，且在上卡块与下卡块之间的间隙设有胶水，起到对其减震的作用，所述的防磨层4与PVC面层3之间设有抗菌夹层8，在防磨层4的最内侧设有防臭夹层5，所述防臭夹层5包括外层和内层，活性炭纤维粘合在外层和内层之间，其防臭夹层具有吸附臭味的功能，其面层具有排除臭味的功能。
本实施例中，所述的通透孔为正方形、圆形、菱形或者各种星型图案。
本实施例中，所述的防磨层4为在人造革本体内表面设有多个小凸起。
本实施例中，所述的抗菌夹层8为银离子层，起到对人造革服装的抗菌作用。
本实施例中，所述的防臭夹层5为活性炭纤维。
实施例1
一种用在人造革的PVC面层原料，由下列重量份的原料组成：
本实施例中，所述的增速剂为己二酸二辛脂和邻苯二甲酸二辛脂，可以与PVC树脂粉有很好的的相容性，进而起到降低粘度的作用。
本实施例中，所述增塑剂剂采用DOP、DINP和DOA中的一种或几种混合物。
实施例2
一种用在人造革的PVC面层原料，由下列重量份的原料组成：
本实施例中，所述的增速剂为己二酸二辛脂和邻苯二甲酸二辛脂，可以与PVC树脂粉有很好的的相容性，进而起到降低粘度的作用。
本实施例中，所述增塑剂剂采用DOP、DINP和DOA中的一种或几种混合物。
实施例3
一种用在人造革的PVC面层原料，由下列重量份的原料组成：
本实施例中，所述的增速剂为己二酸二辛脂和邻苯二甲酸二辛脂，可以与PVC树脂粉有很好的相容性，进而起到降低粘度的作用。
本实施例中，所述增塑剂剂采用DOP、DINP和DOA中的一种或几种混合物。
性能测试结果
将实施例1-3的抗紫外线的人造革分别裁成40CM*40CM的用锡箔片将皮革表面一半遮住放在离紫外线灯泡50CM的灯泡下，温度60℃测试1个月，并用耐黄变测试仪进行检测；同时将实施例1-3的人造革在相同环境下进行抗菌测试，结果如下：
检测对象 抗紫外线性能 抗菌性能
实施例1 颜色不变 抗菌好
实施例2 颜色不变 抗菌好
实施例3 颜色不变 抗菌好
常规聚氨酯人造革 颜色开始变色 表面滋生细菌
综上所述，本发明提供的人造革具有抗紫外线性能好和抗菌性能高特点。
以上对本发明的一个实施例进行了详细说明，但所述内容仅为本发明的较佳实施例，不能被认为用于限定本发明的实施范围。凡依本发明申请范围所作的均等变化与改进等，均应仍归属于本发明的专利涵盖范围之内。

Claims (9)

1.一种人造革，其特征在于：包括人造革本体，在人造革本体上设有若干通透孔，所述的人造革本体包括从外到内依次设有的基布层、粘合层、PVC面层、防磨层和防臭夹层，所述的基布层为起毛布、针织布、无纺布，所述的粘合层包括上层和下层，所述的上层的上表面、下层的下表面分别通过粘贴方式设在基布层、PVC面层上，所述的上层下表面、下层的上表面上对应设有下卡块、上卡块，所述的上卡块卡在下卡块内，且在上卡块与下卡块之间的间隙设有胶水，所述的防磨层与PVC面层之间设有抗菌夹层，在防磨层的最内侧设有防臭夹层，所述防臭夹层包括外层和内层，活性炭纤维粘合在外层和内层之间。
2.根据权利要求1所述的一种人造革，其特征在于：所述的防磨层为在人造革本体内表面设有多个小凸起。
3.根据权利要求1所述的一种人造革，其特征在于：所述的抗菌夹层为银离子层。
4.根据权利要求1所述的一种人造革，其特征在于：所述的防臭夹层为活性炭纤维。
5.一种用在权利要求1所述的人造革的PVC面层原料，由下列重量份的原料组成：
PVC树脂粉 80-90%，
稳定剂 1-3%，
紫外线吸收剂 1-3%，
AC发泡剂 3-10%，
增塑剂 6-12%，
所述的稳定剂为KZn稳定剂，所述的紫外线吸收剂为AD12T紫外线吸收剂。
6.根据权利要求5所述的一种用在人造革的PVC面层原料，其特征在于：最优重量份的原料组成为
PVC树脂粉 85%，
稳定剂 2%，
紫外线吸收剂 2%，
AC发泡剂 6.5%，
增塑剂 9%。
7.根据权利要求5所述的一种用在人造革的PVC面层原料，其特征在于：所述的增速剂为己二酸二辛脂和邻苯二甲酸二辛脂。
8.根据权利要求5所述的一种用在人造革的PVC面层原料，其特征在于：所述的PVC面层原料还包括抗氧化剂，所述的抗氧化剂站占原料的重量份为1-3%，所述的抗氧化剂为AD12S抗氧化剂。
9.根据权利要求5所述的一种用在人造革的PVC面层原料，其特征在于：所述增塑剂剂采用 DOP、DINP和DOA中的一种或几种混合物。
CN201811139073.3A 2018-09-28 2018-09-28 一种人造革及用在人造革的pvc面层原料 Pending CN109454939A (zh)

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