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CN109453876B - Condensation-reboiling closed circulation method for tail gas generated by ultrafine grinding of superheated steam - Google Patents

Condensation-reboiling closed circulation method for tail gas generated by ultrafine grinding of superheated steam Download PDF

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CN109453876B
CN109453876B CN201811255172.8A CN201811255172A CN109453876B CN 109453876 B CN109453876 B CN 109453876B CN 201811255172 A CN201811255172 A CN 201811255172A CN 109453876 B CN109453876 B CN 109453876B
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steam
liquid
reboiling
tail gas
superheated steam
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CN109453876A (en
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朱家骅
葛敬
李季
谢安帝
陈倬
宫源
夏素兰
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Sichuan University
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B02CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
    • B02CCRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
    • B02C19/00Other disintegrating devices or methods
    • B02C19/06Jet mills
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D46/00Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
    • B01D46/02Particle separators, e.g. dust precipitators, having hollow filters made of flexible material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D46/00Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
    • B01D46/42Auxiliary equipment or operation thereof
    • B01D46/4227Manipulating filters or filter elements, e.g. handles or extracting tools
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D50/00Combinations of methods or devices for separating particles from gases or vapours
    • B01D50/20Combinations of devices covered by groups B01D45/00 and B01D46/00
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B02CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
    • B02CCRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
    • B02C23/00Auxiliary methods or auxiliary devices or accessories specially adapted for crushing or disintegrating not provided for in preceding groups or not specially adapted to apparatus covered by a single preceding group

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Abstract

一种过热蒸汽流超音速超细粉碎尾气冷凝‑再沸封闭循环方法,适用于以1.2~2.5MPa、280~420℃的过热蒸汽介质粉碎水不溶性颗粒后产生95~125kPa、110~150℃粉碎尾气的场合。尾气通过水喷射冷凝器升压冷凝、冷凝循环液两段绝热再沸,再生为105~200kPa的洁净饱和蒸汽,通过蒸汽加压机升温升压提供超音速气流超细粉碎所需的机械能,从而免用锅炉、节约生产蒸汽的一次能源,并且循环再生过程同时完成尾气净化。以2000 kg/h过热蒸汽超细粉碎装置为例,本发明方法以405kW动力替代200 kg/h标煤燃烧,并且克服了现有过热蒸汽超音速气流粉碎技术废热排放和冷却水消耗的问题,为低碳、环保技术进步提供经济、适用的解决方案。

Figure 201811255172

A supersonic superfine pulverization tail gas condensation-reboiling closed cycle method with superheated steam flow, which is suitable for pulverizing water-insoluble particles with a superheated steam medium of 1.2-2.5MPa and 280-420°C to produce 95-125kPa and 110-150°C pulverization. In the case of exhaust gas. The exhaust gas is boosted and condensed by the water jet condenser, and the condensed circulating liquid is reboiled adiabatically in two stages, and is regenerated into clean saturated steam of 105~200kPa. The temperature and pressure of the steam pressurizer provide the mechanical energy required for supersonic airflow ultrafine grinding, thereby It eliminates the use of boilers, saves primary energy for steam production, and completes exhaust gas purification during the cyclic regeneration process. Taking a 2000 kg/h super-fine pulverizing device for superheated steam as an example, the method of the present invention uses 405kW power to replace 200 kg/h standard coal combustion, and overcomes the problems of waste heat discharge and cooling water consumption of the existing supersonic supersonic jet pulverization technology of superheated steam, Provide economical and applicable solutions for low-carbon and environmentally friendly technological progress.

Figure 201811255172

Description

Condensation-reboiling closed circulation method for tail gas generated by ultrafine grinding of superheated steam
Technical Field
The invention relates to the technical field of industrial waste gas treatment, waste heat recovery and low-level energy utilization, in particular to an energy-saving and emission-reducing method for closed cyclic utilization of chemical tail gas. .
Background
The superheated steam flow crushing is a processing technology of superfine powder materials. Compared with air, superheated steam as a crushing medium has high cleanliness and low viscosity, and can eliminate static electricity generated by particle friction in the crushing process so as to reduce the secondary cohesion phenomenon of particles, thereby becoming a preferred technology for processing high-end inorganic ultrafine powder products. One of the defects of the prior art is high energy consumption, because 1.2-2.5 MPa (absolute pressure, the same below) of superheated steam generated by a boiler at 280-420 ℃ is used as a crushing medium, the enthalpy of the superheated steam is converted into fluid kinetic energy through a supersonic nozzle, the proportion of the kinetic energy actually used in the crushing process is less than 25%, and more than 75% of the enthalpy of the superheated steam is remained in crushed tail gas at 95-125 kPa (absolute pressure, the same below) and 110-150 ℃. In the existing waste heat recovery technology, the tail gas is used for heating combustion-supporting air at 65-120 ℃ (Liushajun and the like, the application of airflow pulverization in titanium dioxide production, Guangzhou chemical industry, 2015, 43 (23): 215-216) or hot water at 65 ℃ (Chengsheng, titanium dioxide airflow pulverization production process optimization and energy-saving technology application, Shandong chemical industry, 2017, 46: 72-73), the grade of the recovered waste heat is too low, and the effect of reducing the primary energy consumption in the steam generation process is not great. The invention is a more effective waste heat utilization method, which maintains the enthalpy grade of the tail gas and replaces the primary energy consumed in the boiler steam generation process on the premise of ensuring the process condition of superheated steam supersonic speed grinding, thereby recycling the enthalpy of the tail gas accounting for 75 percent of the ratio and greatly reducing the energy consumption in the superheated steam supersonic speed grinding process.
According to the closed cycle method for condensing and reboiling the tail gas by ultrafine grinding of superheated steam, firstly, the tail gas is pressurized and condensed under the action of a water injection pump, and then the condensate is subjected to adiabatic reboiling under the pressure of 105-200 kPa, so that the tail gas is purified and regenerated into clean saturated steam. And then reduced to a superheated steam state required for the ultra-fine pulverization process by mechanical pressurization. By adopting the method, the purification and regeneration of the superheated steam flow ultrafine grinding tail gas are completed through pressurization condensation-adiabatic reboiling, and the cyclic utilization is realized, so that the steam generation energy consumption accounting for 75 percent of the traditional superheated steam flow ultrafine grinding method is saved, a steam boiler is replaced, and the method has the four benefits of remarkable energy conservation, emission reduction, consumption reduction and income increase.
Disclosure of Invention
The invention discloses a closed cycle method for condensing and reboiling tail gas generated by ultrafine grinding of superheated steam flow. The method is suitable for occasions where the superheated steam medium with the pressure of 1.2-2.5 MPa and the temperature of 280-420 ℃ is used for crushing water-insoluble particles to generate crushed tail gas with the pressure of 95-125 kPa and the temperature of 110-150 ℃. For example, in the process of crushing the superfine titanium dioxide by adopting a flat supersonic jet mill, superheated steam with the pressure of 1.8-2.0 MPa and the temperature of 280-320 ℃ is used as a crushing medium, and the main component of the generated tail gas is still the superheated steam, the pressure of which is 95-125 kPa, and the temperature of which is 110-140 ℃. The method for improving the tail gas waste heat recovery technology comprises the following steps: firstly, pressurizing and condensing the tail gas, and then, carrying out adiabatic reboiling on the condensate to generate clean saturated steam with the pressure of 105-200 kPa; and then the mixture is heated and pressurized by a steam pressurizing machine to form superheated steam which meets the requirements of supersonic airflow superfine grinding process and is 1.2-2.5 MPa and 280-420 ℃. The invention has the main idea that a pressurizing condensation-adiabatic reboiling tail gas purification and steam regeneration process and system are constructed according to the fluid statics, the gas-liquid two-phase fluid dynamics, the heat and mass transfer principle, the steam temperature-pressure-enthalpy correlation characteristic and the phase change law, the closed circulation of superheated steam supersonic speed crushing media is realized by utilizing mechanical pressurization, the primary energy consumption in the steam generation process is avoided, a boiler is not used, and economic and applicable low-carbon environmental protection technical progress is provided for superheated steam supersonic speed airflow crushing.
As shown in the attached figure, a vibration metering screw conveyor 1 adds the particle raw materials to be crushed into a superheated steam flow crusher 2, the superheated steam with the pressure of 1.2-2.5 MPa and the temperature of 280-420 ℃ sent by a steam compressor 3 carries out ultrafine crushing under the supersonic speed condition, the steam flow is cooled, decelerated and kept in an overheated state to carry ultrafine powder products into a bag filter 4 for separation, the ultrafine powder products are collected from a lower outlet, and crushing tail gas is output from an upper outlet of the bag filter 4, kept in the overheated state, kept at the pressure of 95-125 kPa and the temperature of 110-150 ℃. The tail gas is sucked into a water jet condenser 5, is wrapped by 100-120 ℃ circulating liquid jet flow conveyed by a reboiling liquid circulating pump 6, flows down along a vertical downcomer 10 and directly reaches 1m below the liquid level of the lower section of a heat insulation reboiler 7, is subjected to rotational flow when the temperature is raised to 110-125 ℃ to be boiled and vaporized, and generates heat insulation reboiling saturated steam of 120-200 kPa, and is sucked into a front steam inlet of a steam pressurizer 3; circulating liquid cooled to 2-5 ℃ due to vaporization passes through a liquid lifting pipe embedded below the liquid level, rises through a partition plate, enters an upper space of a heat insulation reboiler 7, is continuously boiled and vaporized, is further cooled to 2-5 ℃, 70% of generated 105-175 kPa heat insulation reboiled saturated steam is sucked into a middle steam inlet of a steam compressor 3, the rest 30% of generated 105-175 kPa heat insulation reboiled saturated steam continuously rises and flows into a pipe of a pipe shell type falling film degasser 8 directly communicated with a top cover of the heat insulation reboiler 7, is condensed and conveyed to a post-process, the condensed heat in the pipe is transferred to the outside of the pipe, and the saturated steam generated by the falling film evaporation outside the pipe is sucked into a rear steam inlet of the steam compressor 3 and has a temperature of 80. According to the mass and heat balance rule of the adiabatic reboiling process, the amount of the water vapor sucked by the water injection condenser 5 is equal to the total amount of the vapor generated by the adiabatic reboiler 7, and the ratio of the vapor generation amount of the lower section to the vapor generation amount of the upper section is equal to the ratio of the temperature reduction amplitude of the circulating liquid passing through the lower section to the upper section; saturated steam entering the steam pressurizer 3 from the front-mounted steam inlet, the middle-mounted steam inlet and the rear-mounted steam inlet is mixed, pressurized and heated to 1.2-2.5 MPa, the temperature of the saturated steam is 280-420 ℃, the saturated steam is conveyed to the superheated steam flow pulverizer 2 to complete a pulverizing task, tail gas is sucked into the water jet condenser 5, circulating liquid is subjected to adiabatic reboiling on the lower section and the upper section, the temperature of the circulating liquid is recovered to 100-120 ℃, the circulating liquid is conveyed to the water jet condenser 5 by the circulating pump 6 to suck and pulverize the tail gas, and the steps are repeated in this way and circulated in a closed manner, so that the continuous and stable superheated steam supersonic flow superfine pulverization is realized, and only mechanical energy required by superfine.
The reboiled circulating liquid at 100-120 ℃ is heated by the crushed tail gas at 110-150 ℃ through the water injection condenser 5 to increase the temperature by deltatMass flow rate delivered by the steam press 3m(kg/h) and the mass flow of the reboiler circulation pump 6W(kg/h) varies by a factor oft>(mr)/(WC) The relational expression (c) wherein physical property datar(kJ/kg) is the latent heat of condensation of water vapor,C(kJ/kg. ℃ C.) is the specific heat capacity of water.
Synchronously with the steps, the tail gas dedusting and purifying are completed, so that the dust at the outlet of the bag filter 4 is not more than 30mg/m3) The tail gas is condensed and absorbed by reboiling circulating liquid through a water injection condenser 5 and is conveyed to a heat insulation reboiler 7, the powder particles are enriched due to vaporization of water, the mass percentage concentration of the powder particles is not more than 0.05 percent, the displacement liquid discharge amount at the bottom of the heat insulation reboiler 7 is determined according to the index, the discharged liquid is subjected to solid-liquid separation, the recovered clean clear liquid is supplemented with pure water to be not less than the displacement liquid discharge amount, and the clean clear liquid is added with pure waterThe temperature is adjusted to 80-95 ℃, and the liquid is added into an outer tube falling film space of the falling film degasser 8 from the upper part to be vaporized as a replenishing liquid and returns to the tail gas for closed circulation.
The vertical downcomer 10 extends from the water injection condenser 5 to the lower section below the liquid level through the top cover and the middle partition plate of the heat insulation reboiler 7, and the total height is 15-16 m; the liquid level position of the lower section is 1.5-2.0 m lower than that of the middle partition plate; the lower pipe mouth of the vertical riser pipe 9 penetrating through the middle partition plate and embedded below the liquid level of the lower section is 2.5-3.0 m lower than the partition plate, and the upper pipe mouth is 0.2-0.5 m higher than the partition plate; the adiabatic reboiling circulating liquid rises from the lower section of the adiabatic reboiler 7 to the upper section through the liquid lifting pipe 9, the formed liquid level is 0.3-0.6 m higher than that of the partition plate, the circulating liquid enters an inlet of the reboiling liquid circulating pump 6 from the lower part of the partition plate through a connecting pipeline, and the inlet is 11-12 m lower than the partition plate.
Drawings
FIG. 1 is a schematic diagram of a closed cycle method of condensing and reboiling tail gas generated by ultrafine grinding of superheated steam, provided by the invention, wherein: 1-vibrating a metering screw conveyor; 2-a superheated steam flow pulverizer; 3-a steam press; 4-bag filter; 5-water injection condenser; 6-reboiling liquid circulating pump; 7-an adiabatic reboiler; 8-a falling film degasser; 9-a riser tube; 10-a downcomer.
The figures are further illustrated with reference to examples.
Detailed Description
The following examples are given to illustrate specific embodiments of the present invention.
Example (b): the superheated steam supersonic speed grinding closed cycle process of the annual production of 3 ten thousand tons of the superfine titanium dioxide. Superheated steam parameters: the mass flow is 2000kg/h, the temperature is 380 ℃, and the pressure is 1.5 MPa. Crushing tail gas parameters: volumetric flow 3300 Nm3At 140 ℃ under 120kPa, a dust content of 28 mg/Nm/h3. The local atmospheric pressure value is 98 kPa.
As shown in the figure, a vibration metering screw conveyor 1 is used for adding the particle raw materials to be crushed into a superheated steam flow crusher 2, after the supersonic speed super-fine crushing of the superheated steam at 380 ℃ at 1.5MPa and 2000kg/h sent by a steam pressurizer 3, the super-fine crushing enters a bag filter 4 for steam-powder separation and collection of products, and the pressure of the exhausted tail gas is120kPa, 140 ℃, the steam is sucked into a water jet condenser 5, and is wrapped by a circulating liquid jet flow at 101 ℃ conveyed by a reboiling liquid circulating pump 6 to directly reach a position 1m below the liquid level of the lower section of an adiabatic reboiler 7 along a vertical downcomer to form a rotational flow, the temperature reaches 113 ℃, and 1000 kg/h of adiabatic reboiling saturated steam which is generated by boiling vaporization and 140-150 kPa is sucked into a front steam inlet of a steam pressurizer 3; circulating liquid cooled to 5 ℃ due to vaporization passes through a partition plate through a liquid lifting pipe buried below the liquid level and rises to enter the upper section of a heat insulation reboiler 7 to be continuously boiled and vaporized for further cooling to 5-7 ℃ to generate heat insulation reboiled saturated steam of 107-115 kPa (kilopascal pressure) 1000-1200 kg/h, 700-840 kg/h of the heat insulation reboiled saturated steam is directly sucked into a middle steam inlet of a steam pressurizer 3, the rest of the heat insulation reboiled saturated steam is continuously ascended to flow into a shell-and-tube falling film degasser 8 which is directly communicated with a top cover of the heat insulation reboiler 7 to be condensed and non-condensable gas is discharged to a post-process, the condensed heat in the tube is transferred to the falling film evaporation outside the tube to generate saturated steam of 90 ℃ 160-300 kg/h, and the. The total amount of saturated steam entering the steam pressurizer 3 from the front-mounted steam inlet, the middle-mounted steam inlet and the rear-mounted steam inlet is 2000kg/h, and the saturated steam is mixed by the pressurizer, pressurized, heated to 1.5MPa and at 380 ℃ and is conveyed to the superheated steam flow pulverizer 2 as a pulverizing medium, so that the continuous stable closed-cycle superheated steam supersonic flow ultrafine grinding is realized in cycles. The power of the steam pressurizing machine of 2000kg/h in the embodiment is 380 kW; the power of the reboiling liquid circulating pump is 25kW, and the circulating flow is 110 m3H, the lift is 45 m; the reboiled circulating liquid at 101 ℃ is heated by the crushed tail gas at 140 ℃ and 120kPa through a water injection condenser to raise the temperature deltatEqual to 10-12 ℃.
The mass percentage concentration of the water-insoluble powder particles in the adiabatic reboiler 7 does not exceed 0.05%, and the displacement of the bottom discharge liquid of the adiabatic reboiler 7 is determined to be 0.3 m according to the index3H, 0.25 m of clean clear liquid obtained by solid-liquid separation and recovery3H, supplementing to 0.3 m with pure water3And/h, adding the mixture into the upper part of the falling film degasser 8 for returning and circulating.
The beneficial effects of the embodiment on the supersonic speed grinding process of the superfine titanium dioxide consuming 2000kg/h of superheated steam are as follows: 1) the waste heat of 140 ℃ crushed tail gas is recycled to generate reboiling steam, and the primary energy consumed by replacing 2000kg/h of boiler steam is about 200 kg/h of standard coal; 2) the production process of the superheated steam supersonic speed crushed superfine titanium dioxide powder is free from the dependence on a steam boiler, and the clean production technology is favorably implemented; 3) the power consumption of the embodiment is 405kW, and the energy cost is saved by more than 25% compared with the energy cost of using 2000kg/h boiler steam.
The invention is not limited to the above-described embodiments, the technical solutions of which have been described in the summary of the invention.

Claims (3)

1. A condensation-reboiling closed circulation method for tail gas generated by ultrafine grinding of superheated steam flow is characterized in that a steam pressurizer conveys 1.2-2.5 MPa superheated steam at 280-420 ℃ under the supersonic speed condition, the superfine grinding is carried out, the main component of the tail gas is still superheated steam after separation through a bag filter, the superheated steam is sucked into a water jet condenser under the superheated state of 95-125 kPa and 110-150 ℃, 100-120 ℃ circulating liquid jet conveyed by a reboiling liquid circulating pump wraps up the steam and directly reaches 1m below the liquid level of the lower section of an adiabatic reboiler along a vertical downcomer, the steam is swirled and boiled and vaporized when the temperature is increased to 110-125 ℃, and adiabatic reboiling saturated steam with 120-200 kPa is sucked into a preposed steam inlet of the steam pressurizer; circulating liquid cooled to 2-5 ℃ due to vaporization passes through a liquid lifting pipe embedded below the liquid level of the lower section of the heat insulation reboiler, and then passes through a partition plate to rise into the upper section space of the heat insulation reboiler to be continuously boiled and vaporized for further cooling to 2-5 ℃, so that 70% of generated 105-175 kPa heat insulation reboiled saturated steam is sucked into a steam inlet arranged in a steam pressurizing machine, the rest 30% of generated heat insulation reboiled saturated steam continuously rises and flows into a pipe of a pipe shell type falling film degasser directly communicated with a top cover of the heat insulation reboiler to be condensed and non-condensable gas is conveyed to a post-process for treatment, and the heat of condensation in the pipe enables the falling film evaporation outside the pipe to generate saturated steam with the temperature of;
the steam quantity absorbed by the water injection condenser is equal to the total steam quantity generated by the adiabatic reboiler, and the ratio of the steam production quantity of the lower section to the steam production quantity of the upper section is equal to the ratio of the temperature reduction amplitude of the circulating liquid passing through the lower section to the upper section; after the saturated steam entering the steam pressurizing machine from the front-arranged steam inlet, the middle-arranged steam inlet and the rear-arranged steam inlet is mixed, pressurized and heated to 1.2-2.5 MPa and is conveyed to the superheated steam flow pulverizer at 280-420 ℃ to complete the pulverizing and separating task, tail gas with the pressure of 95-125 kPa and the temperature of 110-150 ℃ is sucked into the water jet condenser and is wrapped and carried by 100-120 ℃ circulating liquid jet flow conveyed by the reboiling liquid circulating pump to reach the lower section of the adiabatic reboiler along the vertical downcomer, after the lower section and the upper section are subjected to adiabatic reboiling vaporization, the temperature of the circulating liquid is reduced and recovered to 100-120 ℃, and the circulating liquid is conveyed to the water jet condenser by the reboiling liquid circulating pump, and the steps are repeated and closed for circulation, so that continuous and stable supersonic-speed ultrafine pulverization of the superheated steam is realized, and only mechanical energy required by ultrafine pulverization;
according to the correlation characteristics of water vapor temperature-pressure-enthalpy and the phase change rule, the heating temperature rise range delta of the crushed tail gas of the reboiled circulating liquid through the water injection condensertMass flow rate delivered with steam pressurizermAnd mass flow rate of the reboiled liquid circulating pumpWA relationship of variation, corresponding to Δt>(mr)/(WC) Physical property data in the formularIs the latent heat of condensation of water vapor,CIs the specific heat capacity of water.
2. The superheated steam flow superfine crushed tail gas condensation-reboiling closed cycle method as claimed in claim 1, characterized in that tail gas dust at the outlet of the bag filter is condensed and absorbed by reboiling cycle liquid through a water injection condenser and is conveyed to an adiabatic reboiler, so that the powder particles are enriched and the mass percentage concentration of the powder particles is not more than 0.05%;
and (3) displacing and draining the liquid at the bottom of the heat insulation reboiler, performing solid-liquid separation on the discharged liquid, supplementing the recovered clean clear liquid with pure water to a temperature not lower than the displacement liquid drainage amount, adjusting the temperature to 80-95 ℃, adding the liquid as a supplemented liquid into an external falling film space of the falling film degasser for vaporization, and pumping the generated saturated steam at 80-95 ℃ into a post-positioned steam inlet of a steam pressurizer to return to a tail gas closed circulation system.
3. The superheated steam flow ultrafine grinding tail gas condensation-reboiling closed cycle method according to claim 1, characterized in that the total height of a vertical downcomer connected with a water injection condenser is 15-16 m, the vertical downcomer penetrates through a top cover of a heat insulation reboiler and a middle partition plate and extends to a position 1m below the liquid level of a lower section, and the position of the liquid level of the lower section is 1.5-2.0 m lower than that of the middle partition plate;
the heat insulation reboiling circulation liquid rises from the lower section of the heat insulation reboiler 7 to the upper section through the liquid lifting pipe 9, and the formed liquid level is 0.3-0.6 m higher than that of the partition plate;
circulating liquid on the partition plate enters an inlet of the reboiling liquid circulating pump through a connecting pipeline from the lower part of the partition plate, and the position of the inlet is 11-12 m lower than that of the partition plate.
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