CN109439429A - A kind of supercritical extraction method of walnut oil - Google Patents
A kind of supercritical extraction method of walnut oil Download PDFInfo
- Publication number
- CN109439429A CN109439429A CN201811549793.7A CN201811549793A CN109439429A CN 109439429 A CN109439429 A CN 109439429A CN 201811549793 A CN201811549793 A CN 201811549793A CN 109439429 A CN109439429 A CN 109439429A
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- CN
- China
- Prior art keywords
- walnut
- extraction
- walnut oil
- supercritical
- carbon dioxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 235000019498 Walnut oil Nutrition 0.000 title claims abstract description 35
- 239000008170 walnut oil Substances 0.000 title claims abstract description 35
- 238000000034 method Methods 0.000 title claims abstract description 27
- 238000000194 supercritical-fluid extraction Methods 0.000 title claims abstract description 11
- 238000000605 extraction Methods 0.000 claims abstract description 33
- 241000758789 Juglans Species 0.000 claims abstract description 28
- 235000009496 Juglans regia Nutrition 0.000 claims abstract description 28
- 235000020234 walnut Nutrition 0.000 claims abstract description 28
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims abstract description 26
- 229910002092 carbon dioxide Inorganic materials 0.000 claims abstract description 14
- 238000001035 drying Methods 0.000 claims abstract description 14
- 239000012530 fluid Substances 0.000 claims abstract description 12
- 239000001569 carbon dioxide Substances 0.000 claims abstract description 11
- 239000000843 powder Substances 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 239000000463 material Substances 0.000 claims description 3
- 239000005445 natural material Substances 0.000 claims description 3
- 238000000926 separation method Methods 0.000 claims description 3
- 239000002904 solvent Substances 0.000 abstract description 6
- 238000003912 environmental pollution Methods 0.000 abstract description 5
- 238000005265 energy consumption Methods 0.000 abstract description 2
- 239000003921 oil Substances 0.000 description 4
- 235000019198 oils Nutrition 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 241000790917 Dioxys <bee> Species 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- GCNLQHANGFOQKY-UHFFFAOYSA-N [C+4].[O-2].[O-2].[Ti+4] Chemical compound [C+4].[O-2].[O-2].[Ti+4] GCNLQHANGFOQKY-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229930014626 natural product Natural products 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 238000013441 quality evaluation Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B1/00—Production of fats or fatty oils from raw materials
- C11B1/02—Pretreatment
- C11B1/04—Pretreatment of vegetable raw material
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B1/00—Production of fats or fatty oils from raw materials
- C11B1/10—Production of fats or fatty oils from raw materials by extracting
- C11B1/104—Production of fats or fatty oils from raw materials by extracting using super critical gases or vapours
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Medicines Containing Plant Substances (AREA)
Abstract
The invention discloses a kind of supercritical extraction method of walnut oil, this method is that walnut oil is extracted from walnut kernel using supercritical carbon dioxide fluid, i.e., first that walnut is dry；Again by the crushing of the walnut after drying；Then being extracted from smashed walnut kernel using supercritical carbon dioxide fluid can be prepared by walnut oil finished product；The present invention is to use CO2 as extractant in the supercritical state, and solvent consumption is few, and obtains the high income of product, to reduce the extraction cost of walnut oil.CO 2 fluid is green non-pollution solvent, and the walnut oil of extraction has the features such as high-quality, purity is high, color is good, free from extraneous odour, no solvent residue, non-environmental-pollution, and extraction cycle is short.Present invention process is simple, and low energy consumption.
Description
Technical field
The present invention relates to a kind of supercritical extraction methods of walnut oil, belong to technical field of natural product extraction.
Background technique
The extracting method of walnut oil mainly has at present: supercritical CO2Extraction；Extraction mentions oil process；Water substitution；Water phase
Enzyme process；Squeezing method etc..Current walnut oil extracting method main problem includes: that walnut oil quality is low, environmental pollution is big, is extracted into
The disadvantages of this is higher.
Summary of the invention
The purpose of the present invention is to provide a kind of supercritical extraction method of walnut oil, to improve walnut oil yield and oil
Quality reduces environmental pollution, extraction cost is reduced, thus overcome the deficiencies in the prior art.
The technical scheme of the present invention is realized as follows:
A kind of supercritical extraction method of walnut oil of the invention, method includes the following steps:
1) drying of walnut；
2) crushing of the walnut after drying；
3) walnut oil is extracted from smashed walnut kernel using supercritical carbon dioxide fluid.
In preceding method, walnut powder after drying is put into the material barrel of extraction kettle by when extraction, by titanium dioxide
Carbon gas injects extraction kettle, keeps the temperature and pressure in extraction kettle in the supercriticality and natural material of carbon dioxide gas
Contact, is dissolved in the walnut oil component in walnut powder among supercritical fluid, and from the outlet of separating still, collection contains walnut oil
Fluid.
In preceding method, the supercriticality temperature is 35 DEG C~45 DEG C, and extracting pressure is 35MPa~45MPa；Dioxy
Changing carbon gas by the flow of extraction kettle is 150~250kg/h, and extraction time is 1.2h~2.5h, separation temperature when extraction
It is 30 DEG C~45 DEG C, separating pressure 14MPa.
In preceding method, the drying is that the walnut that will be cleaned is put into baking oven, is dried at a temperature of 50~60 DEG C to walnut
To water content in 10~15% ranges, then puts it into pulverizer and be ground into the walnut powder that partial size is greater than 60 mesh.
By adopting the above-described technical solution, compared with prior art, the present invention the present invention is to make in the supercritical state
Use CO2 as extractant, solvent consumption greatly reduces, and obtains the high income of product, to significantly reduce walnut oil
Extraction cost.CO 2 fluid used in the present invention is green non-pollution solvent, and the walnut oil of extraction has high-quality, purity
The features such as height, color is good, free from extraneous odour, no solvent residue, non-environmental-pollution, and extraction cycle is short.Therefore, the present invention not only has
Can effectively improve walnut oil yield and oil quality the advantages of, but also have can effectively reduce environmental pollution, production technology letter
List, low energy consumption, small investment, the advantages that extraction cost can be effectively reduced.
Specific embodiment
Below with reference to embodiment, the present invention is further illustrated:
The embodiment of the present invention: when using a kind of supercritical extraction method of walnut oil of the invention, existing skill can be directlyed adopt
Drying equipment, disintegrating apparatus and extraction kettle in art are produced, and the method for the present invention includes the following steps:
1) drying of walnut；
2) crushing of the walnut after drying；
3) being extracted from smashed walnut kernel using supercritical carbon dioxide fluid can be prepared by walnut oil finished product；It will when extraction
Walnut powder after drying is put into the material barrel of extraction kettle, and carbon dioxide gas is injected extraction kettle, is kept in extraction kettle
Temperature and pressure is contacted in the supercriticality of carbon dioxide gas with natural material, dissolves the walnut oil component in walnut powder
Among supercritical fluid, the fluid containing walnut oil is collected from the outlet of separating still；The temperature of its supercriticality is preferably controlled
System is at 35 DEG C~45 DEG C, and for extracting pressure general control in the range of 35MPa~45MPa, extracting pressure is preferably 40MPa；Dioxy
Changing the flow that carbon gas passes through extraction kettle is 150~250kg/h, and extraction time controls the range in 1.2h~2.5h, general feelings
Extraction time is 1.5h under condition, and separation temperature when extraction is 30 DEG C~45 DEG C, separating pressure 14MPa；Its drying is will to clean
Walnut be put into baking oven, water content is dried within the scope of 10-15% to walnut at a temperature of 50~60 DEG C, is then put it into
Pulverizer is ground into the walnut powder that partial size is greater than 60 mesh.
Referring to the measuring method of fat and fat oil in first annex IX N of Pharmacopoeia of the People's Republic of China version in 2010
And IX P degree of rancidity measuring method carries out quality evaluation, present invention walnut oil institute produced to present invention walnut oil produced
Acid value, peroxide value and iodine number for containing etc. not only conform with Pharmacopoeia of the People's Republic of China set quota, and use this hair
Bright walnut oil quality produced is significantly better than the quality using existing traditional technology walnut oil produced.
Claims (4)
1. a kind of supercritical extraction method of walnut oil, it is characterised in that: method includes the following steps:
1) drying of walnut；
2) crushing of the walnut after drying；
3) walnut oil is extracted from smashed walnut kernel using supercritical carbon dioxide fluid.
2. the supercritical extraction method of walnut oil according to claim 1, it is characterised in that: will after drying when extraction
Walnut powder is put into the material barrel of extraction kettle, and carbon dioxide gas is injected extraction kettle, keeps the temperature and pressure in extraction kettle
It is contacted in the supercriticality of carbon dioxide gas with natural material, the walnut oil component in walnut powder is made to be dissolved in shooting flow
Among body, the fluid containing walnut oil is collected from the outlet of separating still.
3. the supercritical extraction method of walnut oil according to claim 2, it is characterised in that: the temperature of the supercriticality
Degree is 35 DEG C~45 DEG C, and extracting pressure is 35MPa~45MPa；Carbon dioxide gas by the flow of extraction kettle be 150~
250kg/h, extraction time are 1.2h~2.5h, and separation temperature is 30 DEG C~45 DEG C, separating pressure 14MPa.
4. the supercritical extraction method of walnut oil according to claim 2, it is characterised in that: the drying will be cleaned
Walnut is put into baking oven, is dried to water content within the scope of 10-15% to walnut at a temperature of 50~60 DEG C, then puts it into powder
Broken machine is ground into the walnut powder that partial size is greater than 60 mesh.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811549793.7A CN109439429A (en) | 2018-12-18 | 2018-12-18 | A kind of supercritical extraction method of walnut oil |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811549793.7A CN109439429A (en) | 2018-12-18 | 2018-12-18 | A kind of supercritical extraction method of walnut oil |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109439429A true CN109439429A (en) | 2019-03-08 |
Family
ID=65559142
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811549793.7A Withdrawn CN109439429A (en) | 2018-12-18 | 2018-12-18 | A kind of supercritical extraction method of walnut oil |
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| Country | Link |
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| CN (1) | CN109439429A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110923059A (en) * | 2019-12-27 | 2020-03-27 | 贵州航天乌江机电设备有限责任公司 | Supercritical carbon dioxide extraction method of walnut oil |
| CN111534371A (en) * | 2020-05-12 | 2020-08-14 | 广元海诺食品有限公司 | Using supercritical CO2Production process of extracted walnut oil |
| CN113999725A (en) * | 2021-11-30 | 2022-02-01 | 唐川 | Supercritical carbon dioxide extraction method of walnut oil |
| CN114085707A (en) * | 2021-11-30 | 2022-02-25 | 唐川 | Supercritical carbon dioxide extraction system of walnut oil |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1285165A (en) * | 1999-08-20 | 2001-02-28 | 山西大学 | Deep-processing method for semen juglandis and its products of health care walnut oil and defatted walnut powder |
| CN101926392A (en) * | 2010-09-07 | 2010-12-29 | 杭州临安东升绿色食品有限公司 | Method for extracting pecan oil by using supercritical carbon dioxide fluid |
| CN104140882A (en) * | 2013-05-06 | 2014-11-12 | 四川印山红农业科技有限公司 | Walnut oil extraction process by supercritical carbon dioxide |
| CN104789348A (en) * | 2015-04-06 | 2015-07-22 | 查孝柱 | Supercritical extraction technology for East China wild walnut oil |
| CN105038947A (en) * | 2015-06-24 | 2015-11-11 | 洛阳国花坊牡丹生物科技有限公司 | Supercritical extraction method of walnut oil |
| CN107164073A (en) * | 2016-07-11 | 2017-09-15 | 杭州珍鑫源食品有限公司 | The method of extracting pecan oil by using supercritical carbon dioxide fluid |
| CN108753445A (en) * | 2018-05-31 | 2018-11-06 | 陕西海源生态农业有限公司 | A kind of technique of supercritical carbon dioxide extraction walnut oil |
-
2018
- 2018-12-18 CN CN201811549793.7A patent/CN109439429A/en not_active Withdrawn
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1285165A (en) * | 1999-08-20 | 2001-02-28 | 山西大学 | Deep-processing method for semen juglandis and its products of health care walnut oil and defatted walnut powder |
| CN101926392A (en) * | 2010-09-07 | 2010-12-29 | 杭州临安东升绿色食品有限公司 | Method for extracting pecan oil by using supercritical carbon dioxide fluid |
| CN104140882A (en) * | 2013-05-06 | 2014-11-12 | 四川印山红农业科技有限公司 | Walnut oil extraction process by supercritical carbon dioxide |
| CN104789348A (en) * | 2015-04-06 | 2015-07-22 | 查孝柱 | Supercritical extraction technology for East China wild walnut oil |
| CN105038947A (en) * | 2015-06-24 | 2015-11-11 | 洛阳国花坊牡丹生物科技有限公司 | Supercritical extraction method of walnut oil |
| CN107164073A (en) * | 2016-07-11 | 2017-09-15 | 杭州珍鑫源食品有限公司 | The method of extracting pecan oil by using supercritical carbon dioxide fluid |
| CN108753445A (en) * | 2018-05-31 | 2018-11-06 | 陕西海源生态农业有限公司 | A kind of technique of supercritical carbon dioxide extraction walnut oil |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110923059A (en) * | 2019-12-27 | 2020-03-27 | 贵州航天乌江机电设备有限责任公司 | Supercritical carbon dioxide extraction method of walnut oil |
| CN111534371A (en) * | 2020-05-12 | 2020-08-14 | 广元海诺食品有限公司 | Using supercritical CO2Production process of extracted walnut oil |
| CN113999725A (en) * | 2021-11-30 | 2022-02-01 | 唐川 | Supercritical carbon dioxide extraction method of walnut oil |
| CN114085707A (en) * | 2021-11-30 | 2022-02-25 | 唐川 | Supercritical carbon dioxide extraction system of walnut oil |
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Application publication date: 20190308 |