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CN109437589A - A kind of production technology of glass - Google Patents

A kind of production technology of glass Download PDF

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Publication number
CN109437589A
CN109437589A CN201811338972.6A CN201811338972A CN109437589A CN 109437589 A CN109437589 A CN 109437589A CN 201811338972 A CN201811338972 A CN 201811338972A CN 109437589 A CN109437589 A CN 109437589A
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CN
China
Prior art keywords
glass
parts
production technology
agent
finishing coat
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811338972.6A
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Chinese (zh)
Inventor
陈开华
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ZHEJIANG ZHONGGANG GLASS CO Ltd
Original Assignee
ZHEJIANG ZHONGGANG GLASS CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ZHEJIANG ZHONGGANG GLASS CO Ltd filed Critical ZHEJIANG ZHONGGANG GLASS CO Ltd
Priority to CN201811338972.6A priority Critical patent/CN109437589A/en
Publication of CN109437589A publication Critical patent/CN109437589A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B27/00Tempering or quenching glass products
    • C03B27/012Tempering or quenching glass products by heat treatment, e.g. for crystallisation; Heat treatment of glass products before tempering by cooling
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00Coatings on glass
    • C03C2217/70Properties of coatings
    • C03C2217/78Coatings specially designed to be durable, e.g. scratch-resistant
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2218/00Methods for coating glass
    • C03C2218/10Deposition methods
    • C03C2218/11Deposition methods from solutions or suspensions
    • C03C2218/112Deposition methods from solutions or suspensions by spraying
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2218/00Methods for coating glass
    • C03C2218/30Aspects of methods for coating glass not covered above
    • C03C2218/32After-treatment

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Paints Or Removers (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

The present invention improves a kind of production technology of glass, is related to glass production manufacturing field.The present invention is a kind of production technology of glass, comprising the following steps: (1) glass tempering;Glass blocks is kept the temperature into 220-260s at 720-730 DEG C, glass is cooled to 30-35 DEG C in 75-95s and obtains tempered glass;(2) UV silane coupling agent is sprayed on the surface of tempered glass;(3) UV silane coupling agent surface sprays UV coating, and carries out UV solidification;(4) successively spray-applied primer, decorative layer, finishing coat, the drying temperature of the priming paint are 50-70 DEG C again, drying time: 10-20min.The glass that production technology of the invention is produced, is detected the heavy metal not being harmful to the human body, and surface reaches the test of grade-safe.With preferably resisting anti-UV, anti-oxidation function.The stereoscopic effect showed is true to nature, product easy cleaning, do not account for greasy dirt, be nontoxic, antibiotic property it is strong.

Description

A kind of production technology of glass
Technical field
The present invention relates to glass production manufacturing fields, and in particular to a kind of production technology of glass.
Background technique
Glass is a kind of relatively common inorganic material, because of its light transmission, it is reflexive good the features such as be widely used in building With house articles field.
Glass is amorphous inorganic non-metallic material, and usually with a variety of inorganic minerals, (such as quartz sand, borax, boric acid, weight are brilliant Stone, barium carbonate, lime stone, feldspar, soda ash etc.) it is primary raw material, it additionally incorporates made of a small amount of auxiliary material.It it is main at It is divided into silica and other oxides.The chemical composition of simple glass is Na2SiO3、CaSiO3、SiO2Or Na2O·CaO· 6SiO2Deng main component is silicate double salt, is a kind of non-crystalline solids of random structure.It is widely used in building, uses To belong to mixture every wind light transmission.The another coloured glass for having the oxide for being mixed into certain metals or salt and showing color Glass, and the tempered glass as made from the method for physics or chemistry etc..Sometimes some transparent plastics (such as polymethyls Sour methyl esters) it is also referred to as organic glass.
Glassware is to use glass for daily necessity made of main Raw material processing, the general designation of industrial goods.Glass is A kind of relatively transparent solid matter forms contiguous network structure in melting, and cooling procedure medium viscosity is gradually increased and hardens And non crystallized silicates nonmetallic materials.In order to improve the production efficiency, the specification of certain processing glass kinds tends to be large-scale Change, such as coated glass, sandwich boards for construction glass.Certain processing glass will grind original sheet glass before carrying out technique processing The processing such as grinding and polishing light, cutting, edging, drilling, washing drying, such as toughened glass, laminated glass.Also some processing glass, Washed drying just carries out technique processing, is then polished directly, is cut according to the requirement used, edging, drilling, washing Become final products Deng processing.Glass has good grease resistance, longer in daily life to use.It gives birth in the prior art The antibiotic property of the life glass of production is poor, and uvioresistant, oxidation resistance are poor, at present on the market glassware can be irregular, Some can add some harmful substances for intensity, the gloss etc. that improve glassware, influence the health of human body of user.
Summary of the invention
In view of this, the present invention provides a kind of production technology of glass, it is able to produce out good anti-bacterial effect, it is anti-oxidant, rotten The glassware of erosion, while there is very high safety.
The present invention is a kind of production technology of glass, comprising the following steps:
(1) glass tempering;Glass blocks is kept the temperature into 220-260s at 720-730 DEG C, glass is cooled to 30-35 in 75-95s DEG C obtain tempered glass;
(2) UV silane coupling agent is sprayed on the surface of tempered glass;
(3) UV silane coupling agent surface sprays UV coating, and carries out UV solidification;
(4) successively spray-applied primer, decorative layer, finishing coat, the drying temperature of the priming paint are 50-70 DEG C again, drying time: 10- 20min。
The physical toughened method generallyd use at present is that glass is heated to softening point is attached (650 DEG C or so), and at this moment glass is still It is able to maintain original shape, but particle has certain transfer ability in glass, structural adjustment is carried out, so as to answer existing for inside Power is eliminated quickly, and quenching then is blowed in glass tempering furnace tempered glass, and after equalized temperature, glass surface produces pressure Stress, internal layer produce tensile stress, i.e. glass produces a kind of internal stress of uniform and regular distribution, improve glass conduct The tensile strength of fragile material, to make that glass is counter-bending and impact strength is improved.Simultaneously as inside glass is uniform The presence of stress, when glass part is ruptured by the impact that can be born more than its intensity, in the effect of internal stress Lower self-destruction is little particle, improves its safety.Therefore, tempered glass is also referred to as prestressed glass or safety glass.This hair The tempering temperature of bright middle glass is 720-730 DEG C, and soaking time 220-260s can be good at benefit in this temperature range The internal stress generated with glass, the mechanical performance of reinforcing glass improve the toughness and mechanical strength of glass.
The effect of UV silane coupling agent: keeping UV ink adhesive force more preferable, and coating can be closely combined together with ink.UV light There are the significant drawbacks in terms of adhesive force on glass, metal, ceramics, acrylic and clinker printable fabric for cured printing ink.UV Photocuring gloss oil lacks the penetration to ground, and glass article surface tension is low, it is difficult to soak, UV curing varnish can not penetrate into glass Two secure adhesion of glass surface layer, the profit of UV light-cured resin is big during cured.Therefore spray UV curing varnish when Time can spray one layer of UV silane coupling agent, and Hua Jinsi UV aqueous basecoat agent can be used for example.The printing of ink can be used 3D and beat Print old can first go out better effect, and three-dimensional sense is strong.
Priming paint includes following components by weight: 1-1.5 parts of cellulose, 45-55 parts of titanium dioxide, defoaming agent 0.5-.8 Part, 12-18 parts of coalescing agent, 20-28 parts of talcum powder, 0.8-1.4 parts of fungicide, 2-3 parts of ethylene glycol, 90-110 parts of coarse whiting, cream 180-220 parts of liquid, 2.5-4-3.4 parts of dispersing agent.
Priming paint is the first layer of paint system, for improving the adhesive force of finishing coat, the richness for increasing finishing coat, providing alkali resistant Property, anti-corrosion function etc. is provided, while can guarantee the uniform pickup of finishing coat, paint system is made to play optimum efficiency.Surface paint quality Priming paint can not be had to well, this saying is not right, because finishing coat is different from the function of priming paint, finishing coat more lays particular emphasis on final dress Decorations and apparent effect, and priming paint then lays particular emphasis on and improves adhesive force, anti-corrosion function, alkali resistance etc..The air pump pressure of spray-applied primer: 4.5-6KG。
The decorative layer is layer of sand.Air pump pressure of the layer of sand in spraying is 5-6KG, three dedicated sandblasting pipette tips, bore At 8mm or so (sealing state), then sand drying is carried out, temperature: 50-70 degree, the time: 20-30 minutes, glass surface of finally polishing Sand (front, 4 sides) and dust suction processing.
Finishing coat includes following components by weight: 65-75 parts of lotion, 0.3-0.5 parts of hand feeling agent, defoaming agent 0.15-0.2 Part, 8-10 parts of dipropylene, anti-scratch dose 7-10 parts, 0.2-0.3 parts of dispersing agent, 4-6 parts of wax emulsion, 3-5 parts of flatting silica.
The air pump pressure of spray paint: 4.5-6KG, there are three pipette tips (sealing state), the drying temperature of the finishing coat is 60-80 DEG C, drying time 15-20min.
The glass that production technology of the invention is produced, through detecting the heavy metal not being harmful to the human body, surface reaches The test of grade-safe.With preferably resisting anti-UV, anti-oxidation function.The stereoscopic effect showed is true to nature, and product is easy clear It is clean, do not account for greasy dirt, be nontoxic, antibiotic property it is strong.
Specific embodiment
The present invention will be described in detail With reference to embodiment.
Embodiment one
(1) glass tempering;Glass blocks is kept the temperature into 220s at 720 DEG C, glass is cooled to 30 DEG C in 75s and obtains tempering glass Glass;
(2) UV silane coupling agent is sprayed on the surface of tempered glass;
(3) UV silane coupling agent surface sprays UV coating, and carries out UV solidification;
(4) successively spray-applied primer, decorative layer, finishing coat, the drying temperature of the priming paint are 50 DEG C again, drying time: 10min.
Priming paint includes following components by weight: 1 part of cellulose, 45 parts of titanium dioxide, 0.5 part of defoaming agent, coalescing agent 12 parts, 20 parts of talcum powder, 0.8 part of fungicide, 2 parts of ethylene glycol, 90 parts of coarse whiting, 180 parts of lotion, 2.5 parts of dispersing agent.
The air pump pressure of spray-applied primer: 4.5KG.
The decorative layer is layer of sand.Spray the air pump pressure of sand: 5KG, three dedicated sandblasting pipette tips, bore is in 8mm or so (sealing state), then carry out sand drying, temperature: 50 degree, the time: 20 minutes, the sand of glass surface of finally polishing (front, 4 A side) and dust suction processing.
Finishing coat includes following components by weight: 65 parts of lotion, 0.3 part of hand feeling agent, 0.15 part of defoaming agent, dipropylene glycol 8 parts of butyl ether, anti-scratch dose 7 parts, 0.2 part of dispersing agent, 4 parts of wax emulsion, 3 parts of flatting silica.
The air pump pressure of spray paint: 4.5KG, there are three pipette tips (sealing state), the drying temperature of the finishing coat is 60 DEG C, drying time 15min.
Embodiment two
(1) glass tempering;Glass blocks is kept the temperature into 260s at 730 DEG C, glass is cooled to 35 DEG C in 95s and obtains tempering glass Glass;
(2) UV silane coupling agent is sprayed on the surface of tempered glass;
(3) UV silane coupling agent surface sprays UV coating, and carries out UV solidification;
(4) successively spray-applied primer, decorative layer, finishing coat, the drying temperature of the priming paint are 70 DEG C again, drying time: 20min.
Priming paint includes following components by weight: 1.5 parts of cellulose, 55 parts of titanium dioxide, 0.8 part of defoaming agent, film forming help 18 parts of agent, 28 parts of talcum powder, 1.4 parts of fungicide, 3 parts of ethylene glycol, 110 parts of coarse whiting, 220 parts of lotion, 3.4 parts of dispersing agent.
The air pump pressure of spray-applied primer: 6KG.
The decorative layer is layer of sand.Air pump pressure of the layer of sand in spraying is 6KG.The air pump pressure of spraying sand: 6KG, three The dedicated sandblasting pipette tips of branch, bore is at 8mm or so (sealing state), then carries out sand drying, temperature: 70 degree, the time: and 30 minutes, most The sand (front, 4 sides) of polishing glass surface and dust suction processing afterwards.
Finishing coat includes following components by weight: 75 parts of lotion, 0.5 part of hand feeling agent, 0.2 part of defoaming agent, dipropylene glycol 10 parts of butyl ether, anti-scratch dose 10 parts, 0.3 part of dispersing agent, 6 parts of wax emulsion, 5 parts of flatting silica.
The air pump pressure of spray paint: 6KG, there are three pipette tips (sealing state), the drying temperature of the finishing coat is 80 DEG C, drying time 20min.
Embodiment three
(1) glass tempering;Glass blocks is kept the temperature into 240s at 725 DEG C, glass is cooled to 32 DEG C in 80s and obtains tempering glass Glass;
(2) UV silane coupling agent is sprayed on the surface of tempered glass;
(3) UV silane coupling agent surface sprays UV coating, and carries out UV solidification;
(4) successively spray-applied primer, decorative layer, finishing coat, the drying temperature of the priming paint are 60 DEG C again, drying time: 15min.
Priming paint includes following components by weight: 1.2 parts of cellulose, 46 parts of titanium dioxide, 0.7 part of defoaming agent, film forming help 15 parts of agent, 25 parts of talcum powder, 1.2 parts of fungicide, 2.5 parts of ethylene glycol, 100 parts of coarse whiting, 200 parts of lotion, 3 parts of dispersing agent.
The air pump pressure of spray-applied primer: 5KG.
The decorative layer is layer of sand.Air pump pressure of the layer of sand in spraying is 5.5KG.Spray the air pump pressure of sand: 4.5KG, three dedicated sandblasting pipette tips, bore is at 8mm or so (sealing state), then carries out sand drying, temperature: 60 degree, the time: 25 Minute, the sand (front, 4 sides) for glass surface of finally polishing and dust suction processing.
Finishing coat includes following components by weight: 70 parts of lotion, 0.4 part of hand feeling agent, 0.17 part of defoaming agent, dipropylene glycol 9 parts of butyl ether, anti-scratch dose 8 parts, 0.25 part of dispersing agent, 5 parts of wax emulsion, 4 parts of flatting silica.
The air pump pressure of spray paint: 5KG, there are three pipette tips (sealing state), the drying temperature of the finishing coat is 70 DEG C, Drying time is 18min.
Example IV
(1) glass tempering;Glass blocks is kept the temperature into 250s at 730 DEG C, glass is cooled to 30-35 DEG C in 90s and obtains tempering Glass;
(2) UV silane coupling agent is sprayed on the surface of tempered glass;
(3) UV silane coupling agent surface sprays UV coating, and carries out UV solidification;
(4) successively spray-applied primer, decorative layer, finishing coat, the drying temperature of the priming paint are 60 DEG C again, drying time: 14min.
Priming paint includes following components by weight: 1.2 parts of cellulose, 46 parts of titanium dioxide, 0.7 part of defoaming agent, film forming help 15 parts of agent, 25 parts of talcum powder, 1.2 parts of fungicide, 2.5 parts of ethylene glycol, 100 parts of coarse whiting, 200 parts of lotion, 3 parts of dispersing agent.
The air pump pressure of spray-applied primer: 5KG.
The decorative layer is layer of sand.Air pump pressure of the layer of sand in spraying is 5.5KG.Spray the air pump pressure of sand: 4.5KG, three dedicated sandblasting pipette tips, bore is at 8mm or so (sealing state), then carries out sand drying, temperature: 60 degree, the time: 25 Minute, the sand (front, 4 sides) for glass surface of finally polishing and dust suction processing.
Finishing coat includes following components by weight: 70 parts of lotion, 0.4 part of hand feeling agent, 0.17 part of defoaming agent, dipropylene glycol 9 parts of butyl ether, anti-scratch dose 8 parts, 0.25 part of dispersing agent, 5 parts of wax emulsion, 4 parts of flatting silica.
The air pump pressure of spray paint: 5KG, there are three pipette tips (sealing state), the drying temperature of the finishing coat is 72 DEG C, Drying time is 18min.
Therein group is divided into the common component of commercially available priming paint, finishing coat technical field.
The standard for meeting Germany outlet through detecting embodiment one to the product that example IV produces, is not harmful to the human body Heavy metal, surface reach the test of grade-safe.And appearance looks elegant.
The glass that production technology of the invention is produced, through detecting the heavy metal not being harmful to the human body, surface reaches The test of grade-safe.With preferable anti-UV, anti-oxidation function.The stereoscopic effect showed is true to nature, product easy cleaning, Do not account for that greasy dirt, nontoxic, antibiotic property is strong.It is glass on one side that surface treatment, which is seen, can print various patterns (marble, wood grain. Ceramic tile effect etc.);It is spray stone on one side, feel is natural.The Standard General furniture surface paint that surface India can achieve 6H only has 3H.Beautiful and production cost is low.
The present invention is not limited to above-mentioned specific embodiment, and the invention may be variously modified and varied.All foundations Technical spirit of the invention should be included in the present invention to embodiment of above any modification, equivalent replacement, improvement and so on Protection scope.

Claims (8)

1. a kind of production technology of glass, which comprises the following steps:
Glass tempering;Glass blocks is kept the temperature into 220-260s at 720-730 DEG C, glass is cooled to 30-35 DEG C in 75-95s Obtain tempered glass;
UV silane coupling agent is sprayed on the surface of tempered glass;
UV silane coupling agent surface sprays UV coating, and carries out UV solidification;
Successively spray-applied primer, decorative layer, finishing coat, the drying temperature of the priming paint are 50-70 DEG C again, drying time: 10-20min.
2. a kind of production technology of glass according to claim 1, which is characterized in that the priming paint includes by weight Following components: 1-1.5 parts of cellulose, 45-55 parts of titanium dioxide, 0.5-0.8 parts of defoaming agent, 12-18 parts of coalescing agent, talcum powder 20-28 parts, 0.8-1.4 parts of fungicide, 2-3 parts of ethylene glycol, 90-110 parts of coarse whiting.
3. a kind of production technology of glass according to claim 2, which is characterized in that the priming paint further includes by weight Lotion 180-220 parts, 2.5-3.4 parts of dispersing agent of meter.
4. a kind of production technology of glass according to claim 1, which is characterized in that the priming paint, finishing coat are in spraying Air pump pressure is 4.5-6KG.
5. a kind of production technology of glass according to claim 4, which is characterized in that the decorative layer is layer of sand.
6. a kind of production technology of glass according to claim 5, which is characterized in that air pump of the layer of sand in spraying Pressure is 5-6KG.
7. a kind of production technology of glass according to claim 1, which is characterized in that the finishing coat includes by weight Following components: 65-75 parts of lotion, 0.3-0.5 parts of hand feeling agent, 0.15-0.2 parts of defoaming agent, 8-10 parts of dipropylene, anti-zoned 7-10 parts of trace agent, 0.2-0.3 parts of dispersing agent, 4-6 parts of wax emulsion, 3-5 parts of flatting silica.
8. a kind of production technology of glass according to claim 7, which is characterized in that the drying temperature of the finishing coat is 60-80 DEG C, drying time 15-20min.
CN201811338972.6A 2018-11-12 2018-11-12 A kind of production technology of glass Pending CN109437589A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811338972.6A CN109437589A (en) 2018-11-12 2018-11-12 A kind of production technology of glass

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201811338972.6A CN109437589A (en) 2018-11-12 2018-11-12 A kind of production technology of glass

Publications (1)

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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103073976A (en) * 2013-01-23 2013-05-01 浙江佑谦特种材料有限公司 Crack lacquer for glass surface
CN103694884A (en) * 2013-12-16 2014-04-02 丹阳市雷兰斯汽车零部件有限公司 Glass product for automobile skylight and coating ultraviolet (UV) curing technology
CN103866939A (en) * 2014-03-14 2014-06-18 珠海东诚光固化材料有限公司 Novel safety glass decorative sheet and preparation method thereof
CN104559698A (en) * 2014-12-11 2015-04-29 惠州市长润发涂料有限公司 Yellowing-resistant UV (ultraviolet) transparent primer for electrostatic spraying
CN105667015A (en) * 2016-03-23 2016-06-15 东莞市森泰玻璃制品有限公司 Stone pattern glass plate and its production process
CN106186722A (en) * 2015-04-29 2016-12-07 邓黎华 There is the technology for making glass of decoration function
WO2018153874A1 (en) * 2017-02-24 2018-08-30 Profol Kunststoffe Gmbh Antistatic decorative laminate

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103073976A (en) * 2013-01-23 2013-05-01 浙江佑谦特种材料有限公司 Crack lacquer for glass surface
CN103694884A (en) * 2013-12-16 2014-04-02 丹阳市雷兰斯汽车零部件有限公司 Glass product for automobile skylight and coating ultraviolet (UV) curing technology
CN103866939A (en) * 2014-03-14 2014-06-18 珠海东诚光固化材料有限公司 Novel safety glass decorative sheet and preparation method thereof
CN104559698A (en) * 2014-12-11 2015-04-29 惠州市长润发涂料有限公司 Yellowing-resistant UV (ultraviolet) transparent primer for electrostatic spraying
CN106186722A (en) * 2015-04-29 2016-12-07 邓黎华 There is the technology for making glass of decoration function
CN105667015A (en) * 2016-03-23 2016-06-15 东莞市森泰玻璃制品有限公司 Stone pattern glass plate and its production process
WO2018153874A1 (en) * 2017-02-24 2018-08-30 Profol Kunststoffe Gmbh Antistatic decorative laminate

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