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CN109401804A - A kind of methane purification system with peak regulating function - Google Patents

A kind of methane purification system with peak regulating function Download PDF

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Publication number
CN109401804A
CN109401804A CN201811498673.9A CN201811498673A CN109401804A CN 109401804 A CN109401804 A CN 109401804A CN 201811498673 A CN201811498673 A CN 201811498673A CN 109401804 A CN109401804 A CN 109401804A
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CN
China
Prior art keywords
biogas
compressor
natural gas
gas
surge tank
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811498673.9A
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Chinese (zh)
Inventor
东广友
康相江
王宏杰
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Inner Mongolia Hongda Bio-Environmental Technology Co Ltd
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Inner Mongolia Hongda Bio-Environmental Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Inner Mongolia Hongda Bio-Environmental Technology Co Ltd filed Critical Inner Mongolia Hongda Bio-Environmental Technology Co Ltd
Priority to CN201811498673.9A priority Critical patent/CN109401804A/en
Publication of CN109401804A publication Critical patent/CN109401804A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L3/00Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
    • C10L3/06Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
    • C10L3/10Working-up natural gas or synthetic natural gas
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L3/00Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
    • C10L3/06Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
    • C10L3/10Working-up natural gas or synthetic natural gas
    • C10L3/101Removal of contaminants
    • C10L3/102Removal of contaminants of acid contaminants
    • C10L3/103Sulfur containing contaminants
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L3/00Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
    • C10L3/06Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
    • C10L3/10Working-up natural gas or synthetic natural gas
    • C10L3/101Removal of contaminants
    • C10L3/102Removal of contaminants of acid contaminants
    • C10L3/104Carbon dioxide
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L3/00Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
    • C10L3/06Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
    • C10L3/10Working-up natural gas or synthetic natural gas
    • C10L3/101Removal of contaminants
    • C10L3/106Removal of contaminants of water

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Gas Separation By Absorption (AREA)

Abstract

The present invention provides a kind of methane purification systems with peak regulating function, it includes passing through the sequentially connected biogas gas holder of pipeline, separator, desulfurizing tower, stripping gas recycling can, biogas compressor system, biogas surge tank, circulation, dehydration device and natural gas compressing refueling system;The biogas compressor system includes surge tank after surge tank, biogas compressor, compressor before compressor;The circulation includes multistage Analytic Tower, process water water pump, cold water circulation pump, cooling component, and the multistage Analytic Tower includes absorption tower, level-one Analytic Tower, second level Analytic Tower;The natural gas compressing refueling system includes natural gas surge tank, natural gas compressor, aerating column, tail gas recycle tank.Technical solution of the present invention efficiently solves methane purification system in the prior art and is designed according to declared working condition, and operating flexibility is small, can not solve the problems such as processing of biogas is accumulated in stopping process.

Description

A kind of methane purification system with peak regulating function
Technical field
The present invention relates to methane purification technical fields, in particular to a kind of methane purification system with peak regulating function System.
Background technique
Because biogas contains great amount of carbon dioxide and water and hydrogen sulfide, value itself is not high.Traditional biogas utilization mode is big Mostly burning boiler, power generation etc., added value is lower, and economic benefit is unobvious.By in biogas invalid component carbon dioxide and water and The removal process of hydrogen sulfide is known as methane purification technology, and main component is methane after biogas is purified, and alternative gasoline, diesel is made For natural gas used for automobile use, social benefit with good economic efficiency and environmental benefit.
The oil-gas ratio that National Development and Reform Committee is drafted 07 year is 0.75:1, i.e., various regions will be sold benchmark price according to No. 90 gasoline Price relations not less than 0.75:1 improve natural gas used for automobile selling price.(it is natural about adjustment to be detailed in National Development and Reform Commission The notice of gas price lattice relevant issues, which is generated, changes electricity [2007] 301)
The performance of one side's natural gas is equivalent to one liter of gasoline, but price difference 40%, and after automobile repacking CNG, fuel cost drops significantly It is low.Most domestic has the area of natural gas supply, and taxi has been changed to CNG vehicle, and part private car has also been reequiped.
With the development of the social economy, the demand to electric power is increasing, power supply contradiction is further prominent.It will be to electric power The demand most vigorous time is known as " peak " time, remaining is then " low ebb " time.The generally existing peak-trough electricity of domestic industry electricity consumption Valence, the division of peak interval of time are as follows: spike period: 18:00-22:00;Peak period: 8:00-12:00;The level values period: 12: 00-18:00,22:00-24:00;Low-valley interval: 0:00-8:00.Generally, the electricity price difference of big industry 1-10Kv day part Are as follows: the spike period be 0.813 yuan/(kilowatt hour), peak period be 0.722 yuan/(kilowatt hour), the flat section period be 0.492 yuan/ (kilowatt hour), low-valley interval be 0.329 yuan/(kilowatt hour).It can be seen from the above, the electricity charge in rush hour are expensive, the electricity of low ebb time Take cheap.
The main technique of this field has hydramine to wash, pressure-variable adsorption, UF membrane, pressurization washing etc..Phase is produced with traditional industry Than methane purification system is unique.The front end of methane purification is to produce bionethanation system, and rear end is natural gas sales system.It produces Bionethanation system is the continual and steady process for producing gas, and marketing system is restricted by market, has uncertainty.Thus methane purification system Whether whether system can unobstructed depending on rear end natural gas sales system with continuous operation, only in the case where market is unobstructed, is System can just continuously open;When natural gas sales section goes wrong, system must be shut down, and the production bionethanation system of front end Still it will cause waste and environmental pollution if this portion gas cannot be handled in time in production gas.
Traditional methane purification technology is designed according to declared working condition, and operating flexibility is small.It can not solve to shut down The processing problem of biogas is accumulated in journey.
Summary of the invention
The present invention is intended to provide a kind of methane purification system with peak regulating function, to solve methane purification in the prior art The processing problem of biogas is accumulated in the short stopping process of system.
The technical scheme adopted by the invention is that be achieved: a kind of methane purification system with peak regulating function, it Including passing through the sequentially connected biogas gas holder of pipeline, separator, desulfurizing tower, stripping gas recycling can, biogas compressor system, natural pond Gas surge tank, circulation, dehydration device and natural gas compressing refueling system;The biogas compressor system includes compression Surge tank after surge tank, biogas compressor, compressor before machine;The circulation includes multistage Analytic Tower, process water water Pump, cold water circulation pump, cooling component;The multistage Analytic Tower includes absorption tower, level-one Analytic Tower, second level Analytic Tower;It is described Natural gas compressing refueling system include natural gas surge tank, natural gas compressor, aerating column, tail gas recycle tank.
Preferably, the tail gas recycle tank is arranged between natural gas surge tank and natural gas compressor, natural gas buffering Tank includes the first air inlet, the second air inlet, gas outlet, and the first air inlet of natural gas surge tank is connected with dehydration device gas outlet It connects, natural gas buffer tank outlet is connected with natural gas compressor air inlet, tail gas recycle canister incoming gas mouth and natural gas compressing Machine cylinder is connected, and tail gas recycle tank gas outlet is connected with the second air inlet of natural gas surge tank, natural gas compressor outlet Mouth is connected with aerating column air inlet.
Preferably, the desulfurizing tower is two dry-type desulfurizing towers, the using and the reserved;The biogas compressor system is two Set, the using and the reserved;The dehydration device is two sets, an operation, a regeneration;The natural gas compressor is two sets, The using and the reserved;The process water water pump is two, the using and the reserved;The cold water circulation pump is two, the using and the reserved.
Preferably, the biogas volume of gas cabinet V takes V1 and V2 and maximum value, V1=Vb × 6, V2=Vc × Vb × 6 6-, In, Vb is that specified biogas output, Vc are system maximum biogas treatment amount per hour per hour.
The course of work of the invention is as follows:
Process flow of the invention is divided into process of gas path and water-flow chart two parts.
The process of gas path: raw material biogas enters biogas gas holder, removes free water and impurity into separator, then Hydrogen sulfide is removed into desulfurizing tower, the biogas after desulfurization enters natural pond after the buffering of surge tank before stripping gas recycling can, compressor Air compressor is compressed to 0.8MPa, into compressor after surge tank, biogas surge tank buffered after enter absorption tower removal two Water dew point is taken off to -65 DEG C subsequently into dehydration device and enters natural gas surge tank by carbonoxide, is compressed into natural gas compressor Enter aerating column to 25MPa and gives tank car aerating;Natural gas when natural gas compressor is shut down in compresser cylinder enters tail gas Enter natural gas surge tank after recycling can recycling.
The water-flow chart: after absorption tower completes to absorb, cleaning solution goes to level-one desorber from absorbing tower bottom;Through Enter second level desorber after crossing the cleaning solution decompression of level-one desorption;It is divided into two parts by the process water that second level desorbs, a part From process water pump is flow to, this some processes moisture is known as the process water that flows automatically;Another part is sent into after going to cold water circulation pump Cooling component is cooling, referred to as refrigerating process water;Refrigerating process water transmission of heat by contact in second level desorber packing layer, by cleaning solution Temperature is reduced to 0~20 DEG C;The gravity flow process water of outflow second level desorber squeezes into absorption tower through technique water pump, completes entire water system The circulation of system.
Level-one desorption column overhead stripping gas is recycled to stripping gas recycling can to improve the methane recovery of system.
Technical effect and advantage of the invention:
The present invention can meet continuous operation and the interval two kinds of operating conditions of operation in 6 hours: the biogas treatment amount of interval operation in 6 hours simultaneously It is twice of continuous operation biogas treatment amount.
When system continuous operation, biogas compressor opens one, and natural gas compressor opens one, and process water water pump is opened Qi Yitai, cold water circulation pump open one, other are according to gas circuit, water circuit system circular flow.
When running when system interval 6 is small, biogas compressor two are opened simultaneously, and natural gas compressor two are opened simultaneously It opens, two, process water water water pump is opened simultaneously, and cold water circulation pump is opened simultaneously, other are according to gas circuit, water circuit system circular flow. System is opened 6 hours, is stopped 6 hours, and shutting down the biogas within 6 hours can store into biogas gas holder, 6 as a child system boots, even Continuous work 6 hours, the enrichment biogas shut down before can all be digested.
It designs in this way, system time has 6 hours time kept in reserve, can cope with emergency situations, and can ensure front end The processing of biogas.And the operation in 6 hours of system interval can efficiently use valley electricity price, improve the aerating time, advantage is more significant. 0 point to 6 points daily (electricity price low-valley interval), the whole standby host operations of 12 points to 18 points (electricity price flat section period) unlatchings, remaining period (electricity price spike and peak period) shuts down, and can reduce the aerating time 50%, power cost saving 30% or so.0 point to 6 points and 12 points to 18 Point is also the sale low-valley interval of gas station, and the present invention can make full use of this period to give tank car aerating, improve tank car Turnover rate.
Compared with traditional handicraft, invention increases biogas gas holder one, reduce middle pressure natural gas storage tank and high pressure day Right gas cylinders group reduces sequential control cabinet, and gross investment, which maintains an equal level, even slightly to be reduced.
Compared with traditional handicraft, power-equipment of the invention: biogas compressor, natural gas compressor, water pump etc. do not increase Add, still uses the using and the reserved form.
When natural market by restrict shut down when, system-down, the biogas storage within shutdown 6 hours is to biogas gas holder In, it is switched on after 6 hours, all dynamic opening of device continuous work 6 hours, can all digest the enrichment biogas shut down before.This Sample design, system time have 6 hours time kept in reserve, can cope with emergency situations, and can ensure the processing of front end biogas.
In the case that natural gas market is unobstructed, the present invention can efficiently use valley electricity price, improve aerating time, advantage It is more significant.0 point to 6 points daily (electricity price low-valley interval), the whole standby host operations of 12 points to 18 points (electricity price flat section period) unlatchings, Remaining period (electricity price spike and peak period) shuts down, and can reduce the aerating time 50%, power cost saving 30% or so.0 point to 6 points and 12 points to 18 points be also gas station sale low-valley interval, the present invention can make full use of this period to give tank car aerating, mention The turnover rate of high tank car.
Detailed description of the invention:
Fig. 1 is a kind of structural schematic diagram of methane purification system with peak regulating function of the invention.
In figure: 1- biogas gas holder, 2- separator, 3- desulfurizing tower, 4- stripping gas recycling can, surge tank before 5- compressor, 6- biogas compressor, surge tank after 7- compressor, 8- biogas surge tank, the absorption tower 9-, 10- dehydration device, 11- natural gas are slow Rush tank, 12- natural gas compressor, 13- aerating column, 14- tail gas recycle tank, 15- level-one desorber, 16- second level desorber, 17- Process water water pump, 18- cold water circulation pump, 19- cooling component.
Specific embodiment
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete Site preparation description.
As shown in Figure 1, a kind of methane purification system with peak regulating function, it includes passing through the sequentially connected biogas of pipeline Gas holder 1, separator 2, desulfurizing tower 3, stripping gas recycling can 4, biogas compressor system, biogas surge tank 8, circulation, Dehydration device 10 and natural gas compressing refueling system;The biogas compressor system includes surge tank 5, biogas pressure before compressor Surge tank 7 after contracting machine 6, compressor;The circulation includes multistage Analytic Tower, process water water pump 17, cold water circulation pump 19, cooling component 19;The multistage Analytic Tower includes absorption tower 9, level-one Analytic Tower 15, second level Analytic Tower 16;The day Right air pressure contracting refueling system includes natural gas surge tank 11, natural gas compressor 12, aerating column 13, tail gas recycle tank 14.
The tail gas recycle tank 14 is arranged between natural gas surge tank 11 and the natural gas compressor 12, natural gas Surge tank 11 includes the first air inlet, the second air inlet, gas outlet, 11 first air inlet of natural gas surge tank and dehydration device 10 Gas outlet is connected, and 11 gas outlet of natural gas surge tank is connected with 12 air inlet of natural gas compressor, tail gas recycle tank 14 into Port is connected with 12 cylinder of natural gas compressor, 14 gas outlet of tail gas recycle tank and 11 second air inlet phase of natural gas surge tank Connection, 12 gas outlet of natural gas compressor is connected with 13 air inlet of aerating column.
The desulfurizing tower 3 is two dry-type desulfurizing towers 3, the using and the reserved;The biogas compressor system be two sets, one It is standby with one;The dehydration device 10 is two sets, an operation, a regeneration;The natural gas compressor 12 be two sets, one It is standby with one;The process water water pump 17 is two, the using and the reserved;The cold water circulation pump 18 is two, the using and the reserved;
The 1 volume V of biogas gas holder takes V1 and V2 and maximum value, V1=Vb × 6, V2=Vc × Vb × 6 6-, wherein Vb is every Hour specified biogas output, Vc are system maximum biogas treatment amount per hour.The present embodiment uses 3750m3Biogas gas holder, can Stocking system shuts down the biogas stored required for 6 hours, can meet 15000Nm simultaneously3/ d continuous operation and 30000Nm3Between/d It has a rest 6 hours and runs two kinds of operating conditions.
A kind of methane purification system course of work with peak regulating function is as follows:
This example is divided into gas circuit and water route two parts.Gas circuit enters biogas gas holder 1 by raw material biogas, removes into separator 2 Free water and impurity remove hydrogen sulfide subsequently into desulfurizing tower 3, and the biogas after desulfurization before stripping gas recycling can 4, compressor through delaying Rush after the buffering of tank 5 and enter biogas compressor 6 and be compressed to 0.8MPa, into compressor after surge tank 7, biogas surge tank 8 carry out Enter absorption tower 9 after buffering and remove removing carbon dioxide, water dew point is taken off to -65 DEG C into natural gas subsequently into dehydration device 10 and is delayed Tank 11 is rushed, 25MPa is compressed into natural gas compressor 12 and enters aerating column 13 to tank car aerating.When natural gas compressor 12 stops Natural gas when machine in compresser cylinder enters after tail gas recycle tank 14 recycles and enters natural gas surge tank 11.
This example uses circulation, and after absorption tower 9 completes to absorb, cleaning solution goes to level-one from 9 tower bottom of absorption tower Desorber 15 enters second level desorber 16 after the cleaning solution decompression by level-one desorption, is divided by the process water that second level desorbs Two parts, for a part from process water pump 17 is flow to, this some processes moisture is known as the process water that flows automatically;Another part is cold through going to It is cooling that cooling component 19 is sent into after water-circulating pump 18, referred to as refrigerating process water.Refrigerating process water is in 16 filler of second level desorber Transmission of heat by contact in layer, is reduced to 0~20 DEG C for cleaning solution temperature.It is squeezed into from the water of outflow second level desorber 16 through technique water pump 17 The circulation of entire water system is completed on absorption tower 9.15 tower top stripping gas of level-one desorber is recycled to stripping gas recycling can 4 to improve The methane recovery of system.
The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention, for the skill of this field For art personnel, the invention may be variously modified and varied.All within the spirits and principles of the present invention, made any to repair Change, equivalent replacement, improvement etc., should all be included in the protection scope of the present invention.

Claims (4)

1. a kind of methane purification system with peak regulating function, it includes being separated by the sequentially connected biogas gas holder of pipeline, water Device, desulfurizing tower, stripping gas recycling can, biogas compressor system, biogas surge tank, circulation, dehydration device and natural gas Compress refueling system;The biogas compressor system includes being buffered before compressor after surge tank, biogas compressor, compressor Tank;The circulation includes multistage Analytic Tower, process water water pump, cold water circulation pump, cooling component;The multistage solution Analysing tower includes absorption tower, level-one Analytic Tower, second level Analytic Tower;The natural gas compressing refueling system includes natural gas buffering Tank, natural gas compressor, aerating column, tail gas recycle tank.
2. a kind of methane purification system with peak regulating function according to claim 1, it is characterised in that: the tail gas returns Closed cans is arranged between natural gas surge tank and natural gas compressor, and natural gas surge tank includes the first air inlet, the second air inlet Mouth, gas outlet, the first air inlet of natural gas surge tank are connected with dehydration device gas outlet, natural gas buffer tank outlet and day Right air compressor air inlet is connected, and tail gas recycle canister incoming gas mouth is connected with natural gas compressor cylinder, and tail gas recycle tank goes out Port is connected with the second air inlet of natural gas surge tank, and natural gas compressor outlet is connected with aerating column air inlet.
3. a kind of methane purification system with peak regulating function according to claim 1, it is characterised in that: the desulfurization Tower is two dry-type desulfurizing towers, the using and the reserved;The biogas compressor system is two sets, the using and the reserved;The dehydration dress Two sets are set to, an operation, one regenerates;The natural gas compressor is two sets, the using and the reserved;The process water water pump It is two, the using and the reserved;The cold water circulation pump is two, the using and the reserved.
4. a kind of methane purification system with peak regulating function according to claim 1, it is characterised in that: the biogas gas Cabinet volume V takes V1 and V2 and maximum value, V1=Vb × 6, V2=Vc × Vb × 6 6-, wherein Vb is that specified biogas produces per hour Amount, Vc are system maximum biogas treatment amount per hour.
CN201811498673.9A 2018-12-08 2018-12-08 A kind of methane purification system with peak regulating function Pending CN109401804A (en)

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Cited By (2)

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CN110762946A (en) * 2019-11-14 2020-02-07 山东和利时石化科技开发有限公司 Skid-mounted natural gas treatment device
CN112662527A (en) * 2020-12-28 2021-04-16 山西能投生物质能开发利用股份有限公司 Straw livestock and poultry manure co-production biogas and organic fertilizer system

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CN209276468U (en) * 2018-12-08 2019-08-20 内蒙古弘达生物环保科技有限责任公司 A kind of methane purification system with peak regulating function

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* Cited by examiner, † Cited by third party
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CN110762946A (en) * 2019-11-14 2020-02-07 山东和利时石化科技开发有限公司 Skid-mounted natural gas treatment device
CN110762946B (en) * 2019-11-14 2025-01-07 山东和利时石化科技开发有限公司 A skid-mounted natural gas processing device
CN112662527A (en) * 2020-12-28 2021-04-16 山西能投生物质能开发利用股份有限公司 Straw livestock and poultry manure co-production biogas and organic fertilizer system

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