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CN109401666A - A kind of plywood glue environmentally friendly filler and its preparation process - Google Patents

A kind of plywood glue environmentally friendly filler and its preparation process Download PDF

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Publication number
CN109401666A
CN109401666A CN201811021808.2A CN201811021808A CN109401666A CN 109401666 A CN109401666 A CN 109401666A CN 201811021808 A CN201811021808 A CN 201811021808A CN 109401666 A CN109401666 A CN 109401666A
Authority
CN
China
Prior art keywords
parts
inorganic mineral
mineral powder
environmentally friendly
filler
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811021808.2A
Other languages
Chinese (zh)
Inventor
曾召刚
喻浩然
龙臻彦
吴婷
程琪林
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Xiangtan Sepiolite Technology Co Ltd
Original Assignee
Xiangtan Sepiolite Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Xiangtan Sepiolite Technology Co Ltd filed Critical Xiangtan Sepiolite Technology Co Ltd
Priority to CN201811021808.2A priority Critical patent/CN109401666A/en
Publication of CN109401666A publication Critical patent/CN109401666A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/04Non-macromolecular additives inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/06Non-macromolecular additives organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/08Macromolecular additives

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

The invention discloses a kind of environmentally friendly fillers of plywood glue, are made of the material of following mass fraction: 60-85 parts of inorganic mineral powder, 5-15 parts of organic filler, 1-5 parts of modifying agent, 2-10 parts of thickener, and 3-15 parts of adhesive, 0.5-5 parts of curing agent;Inorganic mineral powder is one or more of sepiolite, diatomite, zeolite, attapulgite;Organic filler is one of starch, flour, albumen powder;Modifying agent is one or more of resorcinol, melamine, thiocarbamide, azodicarbonamide, sodium alkyl sulfonate;Thickener is one of sodium alginate, sodium carboxymethylcellulose, Sodium Polyacrylate;Adhesive is one of Lauxite, phenolic resin, polyvinyl alcohol, waterglass;Curing agent is one or more of ammonium chloride, zinc chloride, ammonium sulfate.The formula of the invention is reasonable, and the flour of addition is less, and inorganic mineral powder is more, and formaldehyde adsorption and inhibition mould, Anti-moth-eating effect are more preferable, and manufacturing cost is lower, and the timber intensity manufactured is higher, and comprehensive performance is more excellent.

Description

A kind of plywood glue environmentally friendly filler and its preparation process
Technical field
The present invention relates to a kind of plywood glue filler and its preparation processes.
Background technique
Currently, glued board have become indoor furniture, floor, decoration it is main with material, 75% or more glued board is adopted in the market Adhesive is formaldehyde system synthetic resin, mainly Lauxite and its modified product.Although by the effort of many years, China Adhesive of artificial board production level has large increase, but urea-formaldehyde resin adhesive remains more serious Form aldehyde release Problem is the main source of formaldehyde pollution in room air pollution.
Indoors during plywood production, need that flour filler is added in urea-formaldehyde resin adhesive, to increase glue consistency And degree of adhesion.But traditional filler material flour acts on single and flour in glued board and belongs to agricultural product, and a large amount of use necessarily is made At the waste of grain.Flour price is higher simultaneously, increases the cost of manufacturing enterprise.
Although existing have on the market using inorganic mineral powders such as bentonite, kaolin, attapulgite, sepiolites as glued Plate glue substitutes flour with filler, but bentonite, kaolin have no formaldehyde and acts on, and the biggish dilatancy of bentonite easily leads to glue Delamination of plywood, although and attapulgite and sepiolite can adsorb the free formaldehyde in urea-formaldehyde resin adhesive, the excessive bumps of addition Stick soil and sepiolite substitution flour have that glued board is hardened, and Chinese patent " CN 1506427A " discloses a kind of " wood industry Special-purpose multifunctional filler and its preparing process ", it is still necessary to which a large amount of cooperation addition organic fillers just can guarantee timber intensity, limit The purpose for reducing cost is also not achieved in the adsorption effect of formaldehyde.
Summary of the invention
To overcome above-mentioned deficiency, the object of the present invention is to provide a kind of environmentally friendly fillers of plywood glue, compared to existing Other glue fillers, manufacturing cost is low, can effective formaldehyde adsorption, also to all kinds of moulds and damage by worms and have good inhibiting effect, make Standby glued board toughness, tack, intensity are higher, are not easy to come unglued, blister and hardened, have excellent mechanical property, effectively make It is long with the service life.
The environmentally friendly filler of plywood glue of the invention, is made: inorganic mineral powder 60-85 of the material of following mass fraction Part, 5-15 parts of organic filler, 1-5 parts of modifying agent, 2-10 parts of thickener, 3-15 parts of adhesive, 0.5-5 parts of curing agent;
The inorganic mineral powder is one or more of sepiolite, diatomite, zeolite, attapulgite;
The organic filler is starch, chooses one kind in flour, albumen powder;
The modifying agent is one or more of resorcinol, melamine, thiocarbamide, azodicarbonamide, sodium alkyl sulfonate;
The thickener is sodium alginate, chooses one kind in sodium carboxymethylcellulose, Sodium Polyacrylate;
The adhesive is Lauxite, chooses one kind in phenolic resin, polyvinyl alcohol, waterglass;
The curing agent is one or more of ammonium chloride, zinc chloride, ammonium sulfate.
Preferably, the environmentally friendly filler of the plywood glue, is made: inorganic mineral powder of the material of following mass fraction 70-80 parts, 8-12 parts of organic filler, 1.5-4 parts of modifying agent, 3-7 parts of thickener, 5-10 parts of adhesive, 1-3 parts of curing agent.
The present invention also provides the plywood glue preparation processes of environmentally friendly filler, include the following steps: that (1) is inorganic Miberal powder is through mechanical lapping at about 200 mesh;(2) levigate inorganic mineral powder and other raw materials are sufficiently mixed uniformly in proportion.
Compared with prior art, the present invention have it is following the utility model has the advantages that
(1) present invention by by inorganic mineral powder, organic filler, modifying agent, thickener, binder and curing agent according to a certain percentage It is compound to be configured to the environmentally friendly filler of plywood glue, it is applied to that there is excellent dispersibility, intersolubility in glued board adhesive And suspension, free formaldehyde not only can be effectively adsorbed, also to all kinds of moulds and damages by worms and has good inhibiting effect, meet people couple The demand of household green building material;
(2) plywood glue can substitute flour with environmentally friendly filler completely, and price is cheap more than flour, and manufacturing cost is low, technique Concise, industrialized production easy to operate and realize, high production efficiency, and it is gentle during plywood production will not to generate dust Taste has no stimulation to eye, mucous membrane and respiratory tract, and working condition is good compared with flour and without explosion danger;
(3) present invention prepares cementability, permeability, water imbibition by addition modifying agent, thickener, binder, curing agent etc. With the environmentally friendly filler of the strong plywood glue of water resistance, it can effectively avoid plate and come unglued, blister and hardened phenomenon, not only increase Inorganic mineral powder can additional amount, effectively increase the adsorption effect of formaldehyde, also reduce the addition of the organic fillers such as flour, reduce Cost, while cooperateing with film-forming to form composite network between modifying agent and curing agent, improves bonding strength, toughness and just Viscosity, curing time is short, and Acceptable life is long, and the plate prepared is made to have excellent mechanical property;
Plywood glue of the invention is reasonable with environmental protection filling agent prescription, substitutes flour compared to existing addition inorganic mineral powder in the market Plywood glue filler, the flour of addition is less, and inorganic mineral powder is more, formaldehyde adsorption and inhibit mould, Anti-moth-eating effect more Good, manufacturing cost is lower, and the timber intensity manufactured is higher, and comprehensive performance is more excellent.
Specific embodiment
Below in conjunction with the embodiment of the present invention, technical scheme in the embodiment of the invention is clearly and completely described, Obviously, described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based in the present invention Embodiment, every other embodiment obtained by those of ordinary skill in the art without making creative efforts, all Belong to the scope of protection of the invention.
A kind of embodiment 1, the environmentally friendly filler of plywood glue, is made of: diatomite 35 by weight following raw material Part, 40 parts of sepiolite, 12 parts of flour, 2 parts of melamine, 3 parts of sodium alginate, 10 parts of polyvinyl alcohol, 1 part of ammonium chloride.
Embodiment 2,40 parts of sepiolite, 30 parts of diatomite, 5 parts of zeolite, 10 parts of starch, 3 parts of thiocarbamide, sodium carboxymethylcellulose 7 parts, 8 parts of waterglass, 1.5 parts of zinc chloride.
Embodiment 3,70 parts of sepiolite, 8 parts of albumen powder, 2 parts of sodium alkyl sulfonate, 1.5 parts of resorcinol, Sodium Polyacrylate 5 Part, 5 parts of Lauxite, 1.2 parts of ammonium sulfate.
The preparation process of the environmentally friendly filler of the plywood glue of the invention, includes the following steps: that (1) inorganic mineral powder passes through Mechanical lapping is at about 200 mesh;(2) levigate inorganic mineral powder and other raw materials are sufficiently mixed uniformly in proportion.
To those skilled in the art, the details that the present invention is not limited to the above embodiments, without departing substantially from of the invention In the case where spirit or essential attributes, it can also make several improvements and modify, these improvement and modification also should be regarded as the present invention Protection scope.

Claims (3)

1. a kind of environmentally friendly filler of plywood glue, which is characterized in that be made of the material of following mass fraction: inorganic mineral powder 60-85 parts, 5-15 parts of organic filler, 1-5 parts of modifying agent, 2-10 parts of thickener, 3-15 parts of adhesive, 0.5-5 parts of curing agent;
The inorganic mineral powder is one or more of sepiolite, diatomite, zeolite, attapulgite;
The organic filler is starch, chooses one kind in flour, albumen powder;
The modifying agent is one or more of resorcinol, melamine, thiocarbamide, azodicarbonamide, sodium alkyl sulfonate;
The thickener is sodium alginate, chooses one kind in sodium carboxymethylcellulose, Sodium Polyacrylate;
The adhesive is Lauxite, chooses one kind in phenolic resin, polyvinyl alcohol, waterglass;
The curing agent is one or more of ammonium chloride, zinc chloride, ammonium sulfate.
2. a kind of environmentally friendly filler of plywood glue according to claim 1, which is characterized in that by following mass fraction Material is made: 70-80 parts of inorganic mineral powder, 8-12 parts of organic filler, 1.5-4 parts of modifying agent, 3-7 parts of thickener, adhesive 5- 10 parts, 1-3 parts of curing agent.
3. a kind of preparation process of the environmentally friendly filler of plywood glue described in claim 1 or 2, which is characterized in that including such as Lower step: (1) inorganic mineral powder is through mechanical lapping at about 200 mesh;(2) levigate inorganic mineral powder and other raw materials is abundant in proportion It is uniformly mixed.
CN201811021808.2A 2018-09-03 2018-09-03 A kind of plywood glue environmentally friendly filler and its preparation process Pending CN109401666A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811021808.2A CN109401666A (en) 2018-09-03 2018-09-03 A kind of plywood glue environmentally friendly filler and its preparation process

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201811021808.2A CN109401666A (en) 2018-09-03 2018-09-03 A kind of plywood glue environmentally friendly filler and its preparation process

Publications (1)

Publication Number Publication Date
CN109401666A true CN109401666A (en) 2019-03-01

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CN201811021808.2A Pending CN109401666A (en) 2018-09-03 2018-09-03 A kind of plywood glue environmentally friendly filler and its preparation process

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111500216A (en) * 2020-05-22 2020-08-07 东莞市东创纸品制造有限公司 Adhesive for corrugated board and preparation method thereof
CN115260987A (en) * 2022-08-18 2022-11-01 谭志刚 Adhesive, preparation method of adhesive, composite flour and plywood

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1478842A (en) * 2002-08-28 2004-03-03 上海鹰翔实业有限公司 Special multifunction filler for wood production and its blending process
CN1506427A (en) * 2002-12-12 2004-06-23 上海鹰翔实业有限公司 Multifunctional carpentery stuffing and its compounding process
JP5466491B2 (en) * 2009-11-20 2014-04-09 Dic株式会社 Wood board manufacturing method

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1478842A (en) * 2002-08-28 2004-03-03 上海鹰翔实业有限公司 Special multifunction filler for wood production and its blending process
CN1506427A (en) * 2002-12-12 2004-06-23 上海鹰翔实业有限公司 Multifunctional carpentery stuffing and its compounding process
JP5466491B2 (en) * 2009-11-20 2014-04-09 Dic株式会社 Wood board manufacturing method

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111500216A (en) * 2020-05-22 2020-08-07 东莞市东创纸品制造有限公司 Adhesive for corrugated board and preparation method thereof
CN115260987A (en) * 2022-08-18 2022-11-01 谭志刚 Adhesive, preparation method of adhesive, composite flour and plywood

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Application publication date: 20190301