CN109401050A - A kind of chemical industry packaging bag - Google Patents
A kind of chemical industry packaging bag Download PDFInfo
- Publication number
- CN109401050A CN109401050A CN201811207966.7A CN201811207966A CN109401050A CN 109401050 A CN109401050 A CN 109401050A CN 201811207966 A CN201811207966 A CN 201811207966A CN 109401050 A CN109401050 A CN 109401050A
- Authority
- CN
- China
- Prior art keywords
- parts
- chemical industry
- silicon dioxide
- packaging bag
- dioxide compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000004806 packaging method and process Methods 0.000 title claims abstract description 26
- 239000000126 substance Substances 0.000 title claims abstract description 22
- -1 polypropylene Polymers 0.000 claims abstract description 51
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims abstract description 36
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 27
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 claims abstract description 24
- JMXKSZRRTHPKDL-UHFFFAOYSA-N titanium ethoxide Chemical compound [Ti+4].CC[O-].CC[O-].CC[O-].CC[O-] JMXKSZRRTHPKDL-UHFFFAOYSA-N 0.000 claims abstract description 24
- 238000003756 stirring Methods 0.000 claims abstract description 20
- FPGGTKZVZWFYPV-UHFFFAOYSA-M tetrabutylammonium fluoride Chemical compound [F-].CCCC[N+](CCCC)(CCCC)CCCC FPGGTKZVZWFYPV-UHFFFAOYSA-M 0.000 claims abstract description 18
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 16
- 239000003431 cross linking reagent Substances 0.000 claims abstract description 15
- 238000005406 washing Methods 0.000 claims abstract description 15
- IDGUHHHQCWSQLU-UHFFFAOYSA-N ethanol;hydrate Chemical compound O.CCO IDGUHHHQCWSQLU-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 14
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 13
- 239000002202 Polyethylene glycol Substances 0.000 claims abstract description 13
- 229920001223 polyethylene glycol Polymers 0.000 claims abstract description 13
- LRWZZZWJMFNZIK-UHFFFAOYSA-N 2-chloro-3-methyloxirane Chemical compound CC1OC1Cl LRWZZZWJMFNZIK-UHFFFAOYSA-N 0.000 claims abstract description 12
- 238000000034 method Methods 0.000 claims abstract description 12
- 239000004743 Polypropylene Substances 0.000 claims abstract description 11
- 229920001155 polypropylene Polymers 0.000 claims abstract description 11
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 10
- 238000012856 packing Methods 0.000 claims abstract description 10
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 10
- 238000005728 strengthening Methods 0.000 claims abstract description 10
- 229920001610 polycaprolactone Polymers 0.000 claims abstract description 9
- 239000004632 polycaprolactone Substances 0.000 claims abstract description 9
- 229920000915 polyvinyl chloride Polymers 0.000 claims abstract description 9
- 239000004800 polyvinyl chloride Substances 0.000 claims abstract description 9
- 230000001376 precipitating effect Effects 0.000 claims abstract description 9
- 239000002994 raw material Substances 0.000 claims abstract description 9
- 239000003822 epoxy resin Substances 0.000 claims abstract description 8
- 235000013873 oxidized polyethylene wax Nutrition 0.000 claims abstract description 8
- 239000004209 oxidized polyethylene wax Substances 0.000 claims abstract description 8
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 8
- 229920001225 polyester resin Polymers 0.000 claims abstract description 8
- 239000004645 polyester resin Substances 0.000 claims abstract description 8
- 239000004927 clay Substances 0.000 claims description 10
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 10
- 229910001928 zirconium oxide Inorganic materials 0.000 claims description 10
- 229910052582 BN Inorganic materials 0.000 claims description 9
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 claims description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 9
- 239000000440 bentonite Substances 0.000 claims description 9
- 229910000278 bentonite Inorganic materials 0.000 claims description 9
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 9
- 229910052570 clay Inorganic materials 0.000 claims description 9
- 229910021389 graphene Inorganic materials 0.000 claims description 9
- 238000002156 mixing Methods 0.000 claims description 9
- XQUPVDVFXZDTLT-UHFFFAOYSA-N 1-[4-[[4-(2,5-dioxopyrrol-1-yl)phenyl]methyl]phenyl]pyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1C(C=C1)=CC=C1CC1=CC=C(N2C(C=CC2=O)=O)C=C1 XQUPVDVFXZDTLT-UHFFFAOYSA-N 0.000 claims description 8
- 229920003192 poly(bis maleimide) Polymers 0.000 claims description 8
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 claims description 8
- 238000002360 preparation method Methods 0.000 claims description 5
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 2
- 230000008859 change Effects 0.000 claims description 2
- YNJSNEKCXVFDKW-UHFFFAOYSA-N 3-(5-amino-1h-indol-3-yl)-2-azaniumylpropanoate Chemical compound C1=C(N)C=C2C(CC(N)C(O)=O)=CNC2=C1 YNJSNEKCXVFDKW-UHFFFAOYSA-N 0.000 claims 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims 1
- 239000004593 Epoxy Substances 0.000 claims 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims 1
- 229910052796 boron Inorganic materials 0.000 claims 1
- 229910052731 fluorine Inorganic materials 0.000 claims 1
- 239000011737 fluorine Substances 0.000 claims 1
- 229910002804 graphite Inorganic materials 0.000 claims 1
- 239000010439 graphite Substances 0.000 claims 1
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 claims 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 abstract description 7
- 229910000077 silane Inorganic materials 0.000 abstract description 7
- 229920005989 resin Polymers 0.000 abstract description 6
- 239000011347 resin Substances 0.000 abstract description 6
- 150000001875 compounds Chemical class 0.000 abstract description 3
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical class CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 abstract description 2
- 238000001914 filtration Methods 0.000 abstract 1
- 235000012239 silicon dioxide Nutrition 0.000 abstract 1
- DDFHBQSCUXNBSA-UHFFFAOYSA-N 5-(5-carboxythiophen-2-yl)thiophene-2-carboxylic acid Chemical compound S1C(C(=O)O)=CC=C1C1=CC=C(C(O)=O)S1 DDFHBQSCUXNBSA-UHFFFAOYSA-N 0.000 description 3
- 230000001788 irregular Effects 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000002985 plastic film Substances 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 229910003978 SiClx Inorganic materials 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 229920006238 degradable plastic Polymers 0.000 description 1
- 229960002380 dibutyl phthalate Drugs 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2244—Oxides; Hydroxides of metals of zirconium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
- C08K2003/382—Boron-containing compounds and nitrogen
- C08K2003/385—Binary compounds of nitrogen with boron
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of chemical industry packaging bags, its raw material includes: 60-70 parts of polypropylene, 15-25 parts of polycaprolactone, 20-30 parts of polyvinyl chloride by weight, 50-70 parts of packing strengthening agent, 20-26 parts of fluorinated silicon dioxide compound, 1-2 parts of silane resin acceptor kh-550,2-4 parts of oxidized polyethylene wax, 1.5-2.5 parts of crosslinking agent, 2-4 parts of epoxy resin, 1-2 parts of polyester resin, 0.8-1.6 parts of double Lauryl Alcohol esters.Fluorinated silicon dioxide compound is prepared using following technique: tetraethyl titanate, nano silica, polyvinyl alcohol is uniform, polyethylene glycol acrylate, epoxychloropropane, cyclohexanone is added to be uniformly mixed, it is subsequently added into tetrabutyl ammonium fluoride, potassium hydroxide stirring, ethanol water stirring is added in washing, precipitating, it stands, filtering, washing, is dried to obtain fluorinated silicon dioxide compound.Chemical industry packaging bag proposed by the present invention, tensile strength and elongation at break are outstanding, good toughness.
Description
Technical field
The present invention relates to packaging bag technical field more particularly to a kind of chemical industry packaging bags.
Background technique
In order to mitigate pollution of the plastic film to environment, people have developed some degradable plastic films in succession.It is existing
Plastic packaging bag good, Yi Huishou with fastness, to the good barrier property of water, oil, gas body, far super paper and plastics compound bag.Plastic bag at present
There is rupture of the part by stress caused by irregular in pack.
Summary of the invention
Technical problems based on background technology, the invention proposes a kind of chemical industry packaging bag, tensile strength and fracture
Elongation is outstanding, there is no part by stress it is irregular caused by rupture the phenomenon that, good toughness.
A kind of chemical industry packaging bag proposed by the present invention, raw material include: 60-70 parts of polypropylene by weight, polycaprolactone
It is 15-25 parts, 20-30 parts of polyvinyl chloride, 50-70 parts of packing strengthening agent, 20-26 parts of fluorinated silicon dioxide compound, silane coupled
1-2 parts of agent KH-550,2-4 parts of oxidized polyethylene wax, 1.5-2.5 parts of crosslinking agent, 2-4 parts of epoxy resin, 1-2 parts of polyester resin,
0.8-1.6 parts of double Lauryl Alcohol esters.
Preferably, fluorinated silicon dioxide compound is prepared using following technique: by tetraethyl titanate, nano silica, being gathered
Vinyl alcohol is uniformly mixed, and is added polyethylene glycol acrylate, epoxychloropropane, cyclohexanone and is uniformly mixed, is subsequently added into four fourths
Base ammonium fluoride, potassium hydroxide stirring, are washed, precipitating, and ethanol water stirring is added, stands, filters, and washing is dried to obtain and contains
Fluorodioxy SiClx compound.
Preferably, in the preparation process of fluorinated silicon dioxide compound, ethanol water concentration is 55-65wt%.
Preferably, in the preparation process of fluorinated silicon dioxide compound, tetraethyl titanate, nano silica, polyvinyl alcohol,
Polyethylene glycol acrylate, epoxychloropropane, cyclohexanone, tetrabutyl ammonium fluoride, potassium hydroxide, ethanol water weight ratio be
0.4-0.8:10-20:18-24:1-1.6:8-16:80-120:0.04-0.1:0.4-0.8:1 40-220.
Preferably, fluorinated silicon dioxide compound is prepared using following technique: by tetraethyl titanate, nano silica, being gathered
Vinyl alcohol is uniformly mixed, and is added polyethylene glycol acrylate, epoxychloropropane, cyclohexanone and is uniformly mixed, is subsequently added into four fourths
Base ammonium fluoride, potassium hydroxide stir 30-50min, and whipping temp is 75-85 DEG C, is washed, precipitating, and addition concentration is 55-65wt%
Ethanol water stirs 10-20min, and whipping temp is 70-76 DEG C, mixing speed 1400-1800r/min, stands 15-25
It, filters, and washing is dried to obtain fluorinated silicon dioxide compound.
Preferably, packing strengthening agent includes: gangue, graphene, hard (china) clay, zirconium oxide, boron nitride, calcium base swelling
Soil.
Preferably, gangue, graphene, hard (china) clay, zirconium oxide, boron nitride, calcium-base bentonite weight ratio be 20-
30:10-20:10-20:4-8:6-14:8-12.
Preferably, crosslinking agent includes: peroxidized t-butyl perbenzoate, N, N '-penylene bismaleimide.
Preferably, peroxidized t-butyl perbenzoate, N, the weight ratio of N '-penylene bismaleimide are 1-2:1-2.
Tensile strength and elongation at break of the invention is outstanding, and the rupture there is no part by stress caused by irregular shows
As good toughness.In fluorinated silicon dioxide compound of the invention, Butyl Phthalate Uniform Doped nano silica can avoid two
Surface high can generate agglomeration to titanium oxide as time went on, and cooperation polyethylene glycol acrylate, epoxychloropropane are in four fourths
Under the action of base ammonium fluoride, at surface construction low-surface-energy interface, it can be achieved that having with polypropylene, polycaprolactone, polyvinyl chloride
Effect combines, effectively enhancing tensile strength of the present invention, improves elongation at break；Fluorinated silicon dioxide compound is in silane coupling agent
It is high with gangue, graphene, hard (china) clay, zirconium oxide, boron nitride, calcium-base bentonite combination degree under the cooperation of KH-550, it can
Bridge formation effect is formed in system, good with the compatibility of organic matter in raw material, mixing uniformity is fabulous, and binding force is strong, makes this
Invention mechanical property is extremely excellent.
Specific embodiment
In the following, technical solution of the present invention is described in detail by specific embodiment.
Embodiment 1
A kind of chemical industry packaging bag, raw material include: polypropylene 60kg, polycaprolactone 25kg, polyvinyl chloride 20kg, and filling is mended
Strong agent 70kg, fluorinated silicon dioxide compound 20kg, silane resin acceptor kh-550 2kg, oxidized polyethylene wax 2kg, crosslinking agent
2.5kg, epoxy resin 2kg, polyester resin 2kg, double Lauryl Alcohol ester 0.8kg.
Packing strengthening agent is by weight by gangue, graphene, hard (china) clay, zirconium oxide, boron nitride, calcium-base bentonite
30:10:20:4:14:8 composition.Crosslinking agent is by peroxidized t-butyl perbenzoate, N, and N '-penylene bismaleimide is by weight
Than being formed for 2:1.
Fluorinated silicon dioxide compound using following technique prepare: by 0.8kg tetraethyl titanate, 10kg nano silica,
24kg polyvinyl alcohol is uniform, adds 1kg polyethylene glycol acrylate, 16kg epoxychloropropane, the mixing of 80kg cyclohexanone
Uniformly, it is subsequently added into 0.1kg tetrabutyl ammonium fluoride, 0.4kg potassium hydroxide stirring 50min, whipping temp is 75 DEG C, washs, sinks
It forms sediment, it is that 55wt% ethanol water stirs 20min that 220kg concentration, which is added, and whipping temp is 70 DEG C, mixing speed 1800r/
Min stands 15 days, filters, and washing is dried to obtain fluorinated silicon dioxide compound.
Embodiment 2
A kind of chemical industry packaging bag, raw material include: polypropylene 70kg, polycaprolactone 15kg, polyvinyl chloride 30kg, and filling is mended
Strong agent 50kg, fluorinated silicon dioxide compound 26kg, silane resin acceptor kh-550 1kg, oxidized polyethylene wax 4kg, crosslinking agent
1.5kg, epoxy resin 4kg, polyester resin 1kg, double Lauryl Alcohol ester 1.6kg.
Packing strengthening agent is by weight by gangue, graphene, hard (china) clay, zirconium oxide, boron nitride, calcium-base bentonite
20:20:10:8:6:12 composition.Crosslinking agent is by peroxidized t-butyl perbenzoate, N, and N '-penylene bismaleimide is by weight
Than being formed for 1:2.
Fluorinated silicon dioxide compound using following technique prepare: by 0.4kg tetraethyl titanate, 20kg nano silica,
18kg polyvinyl alcohol is uniform, and it is mixed to add 1.6kg polyethylene glycol acrylate, 8kg epoxychloropropane, 120kg cyclohexanone
It closing uniformly, is subsequently added into 0.04kg tetrabutyl ammonium fluoride, 0.8kg potassium hydroxide stirring 30min, whipping temp is 85 DEG C, washing,
Precipitating, it is that 65wt% ethanol water stirs 10min that 140kg concentration, which is added, and whipping temp is 76 DEG C, mixing speed 1400r/
Min stands 25 days, filters, and washing is dried to obtain fluorinated silicon dioxide compound.
Embodiment 3
A kind of chemical industry packaging bag, raw material include: polypropylene 64kg, polycaprolactone 22kg, polyvinyl chloride 22kg, and filling is mended
Strong agent 65kg, fluorinated silicon dioxide compound 22kg, silane resin acceptor kh-550 1.7kg, oxidized polyethylene wax 2.5kg, crosslinking
Agent 2.2kg, epoxy resin 2.5kg, polyester resin 1.7kg, double Lauryl Alcohol ester 1kg.
Packing strengthening agent is by weight by gangue, graphene, hard (china) clay, zirconium oxide, boron nitride, calcium-base bentonite
28:13:18:5:12:9 composition.Crosslinking agent is by peroxidized t-butyl perbenzoate, N, and N '-penylene bismaleimide is by weight
Than being formed for 1.7:1.4.
Fluorinated silicon dioxide compound using following technique prepare: by 0.7kg tetraethyl titanate, 13kg nano silica,
22kg polyvinyl alcohol is uniform, and it is mixed to add 1.2kg polyethylene glycol acrylate, 14kg epoxychloropropane, 90kg cyclohexanone
It closing uniformly, is subsequently added into 0.08kg tetrabutyl ammonium fluoride, 0.5kg potassium hydroxide stirring 45min, whipping temp is 78 DEG C, washing,
Precipitating, it is that 58wt% ethanol water stirs 17min that 200kg concentration, which is added, and whipping temp is 72 DEG C, mixing speed 1700r/
Min stands 18 days, filters, and washing is dried to obtain fluorinated silicon dioxide compound.
Embodiment 4
A kind of chemical industry packaging bag, raw material include: polypropylene 66kg, polycaprolactone 18kg, polyvinyl chloride 28kg, and filling is mended
Strong agent 55kg, fluorinated silicon dioxide compound 24kg, silane resin acceptor kh-550 1.3kg, oxidized polyethylene wax 3.5kg, crosslinking
Agent 1.8kg, epoxy resin 3.5kg, polyester resin 1.3kg, double Lauryl Alcohol ester 1.4kg.
Packing strengthening agent is by weight by gangue, graphene, hard (china) clay, zirconium oxide, boron nitride, calcium-base bentonite
22:17:12:7:8:11 composition.Crosslinking agent is by peroxidized t-butyl perbenzoate, N, and N '-penylene bismaleimide is by weight
Than being formed for 1.3:1.8.
Fluorinated silicon dioxide compound using following technique prepare: by 0.5kg tetraethyl titanate, 17kg nano silica,
20kg polyvinyl alcohol is uniform, and it is mixed to add 1.4kg polyethylene glycol acrylate, 10kg epoxychloropropane, 110kg cyclohexanone
It closing uniformly, is subsequently added into 0.06kg tetrabutyl ammonium fluoride, 0.7kg potassium hydroxide stirring 35min, whipping temp is 82 DEG C, washing,
Precipitating, it is that 62wt% ethanol water stirs 13min that 160kg concentration, which is added, and whipping temp is 74 DEG C, mixing speed 1500r/
Min stands 22 days, filters, and washing is dried to obtain fluorinated silicon dioxide compound.
Embodiment 5
A kind of chemical industry packaging bag, raw material include: polypropylene 65kg, polycaprolactone 20kg, polyvinyl chloride 25kg, and filling is mended
Strong agent 60kg, fluorinated silicon dioxide compound 23kg, silane resin acceptor kh-550 1.5kg, oxidized polyethylene wax 3kg, crosslinking agent
2kg, epoxy resin 3kg, polyester resin 1.5kg, double Lauryl Alcohol ester 1.2kg.
Packing strengthening agent is by weight by gangue, graphene, hard (china) clay, zirconium oxide, boron nitride, calcium-base bentonite
25:15:15:6:10:10 composition.Crosslinking agent is by peroxidized t-butyl perbenzoate, N, and N '-penylene bismaleimide is by weight
Than being formed for 1.5:1.6.
Fluorinated silicon dioxide compound using following technique prepare: by 0.6kg tetraethyl titanate, 15kg nano silica,
21kg polyvinyl alcohol is uniform, and it is mixed to add 1.3kg polyethylene glycol acrylate, 12kg epoxychloropropane, 100kg cyclohexanone
It closing uniformly, is subsequently added into 0.07kg tetrabutyl ammonium fluoride, 0.6kg potassium hydroxide stirring 40min, whipping temp is 80 DEG C, washing,
Precipitating, it is that 60wt% ethanol water stirs 15min that 180kg concentration, which is added, and whipping temp is 73 DEG C, mixing speed 1600r/
Min stands 20 days, filters, and washing is dried to obtain fluorinated silicon dioxide compound.
5 gained chemical industry packaging bag of embodiment and plain polypropylene packaging bag are subjected to performance comparison, result is as follows:
| Embodiment 5 | Plain polypropylene packaging bag | |
| Longitudinal tensile strength, Mpa | 46.86 | 37.26 |
| Transverse tensile strength, Mpa | 33.3 | 30.3 |
| Longitudinal elongation at break rate, % | 589 | 462 |
| Transverse breakage elongation, % | 403 | 375 |
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto,
Anyone skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its
Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.
Claims (9)
1. a kind of chemical industry packaging bag, which is characterized in that its raw material includes: 60-70 parts of polypropylene by weight, polycaprolactone 15-
25 parts, 20-30 parts of polyvinyl chloride, 50-70 parts of packing strengthening agent, 20-26 parts of fluorinated silicon dioxide compound, silane coupling agent
It is 1-2 parts of KH-550,2-4 parts of oxidized polyethylene wax, 1.5-2.5 parts of crosslinking agent, 2-4 parts of epoxy resin, 1-2 parts of polyester resin, double
0.8-1.6 parts of Lauryl Alcohol ester.
2. chemical industry packaging bag according to claim 1, which is characterized in that fluorinated silicon dioxide compound uses following technique system
It is standby: tetraethyl titanate, nano silica, polyvinyl alcohol is uniform, add polyethylene glycol acrylate, epoxy chloropropionate
Alkane, cyclohexanone are uniformly mixed, and are subsequently added into tetrabutyl ammonium fluoride, potassium hydroxide stirring, are washed, ethanol water is added in precipitating
Stirring is stood, and is filtered, and washing is dried to obtain fluorinated silicon dioxide compound.
3. chemical industry packaging bag according to claim 2, which is characterized in that in the preparation process of fluorinated silicon dioxide compound,
Ethanol water concentration is 55-65wt%.
4. the chemical industry packaging bag according to Claims 2 or 3, which is characterized in that the preparation process of fluorinated silicon dioxide compound
In, tetraethyl titanate, nano silica, polyvinyl alcohol, polyethylene glycol acrylate, epoxychloropropane, cyclohexanone, tetrabutyl fluorine
Change ammonium, potassium hydroxide, ethanol water weight ratio be 0.4-0.8:10-20:18-24:1-1.6:8-16:80-120:0.04-
0.1:0.4-0.8:140-220.
5. stating chemical industry packaging bag according to any one of claim 2-4, which is characterized in that fluorinated silicon dioxide compound is using as follows
Technique preparation: tetraethyl titanate, nano silica, polyvinyl alcohol is uniform, add polyethylene glycol acrylate, epoxy
Chloropropane, cyclohexanone are uniformly mixed, and are subsequently added into tetrabutyl ammonium fluoride, potassium hydroxide stirring 30-50min, whipping temp 75-
It 85 DEG C, washs, precipitating, it is that 55-65wt% ethanol water stirs 10-20min that concentration, which is added, and whipping temp is 70-76 DEG C, is stirred
Mixing speed is 1400-1800r/min, stands 15-25 days, is filtered, and washing is dried to obtain fluorinated silicon dioxide compound.
6. any one of -5 stating chemical industry packaging bag according to claim 1, which is characterized in that packing strengthening agent includes: gangue, graphite
Alkene, hard (china) clay, zirconium oxide, boron nitride, calcium-base bentonite.
7. stating chemical industry packaging bag according to claim 6, which is characterized in that gangue, graphene, hard (china) clay, zirconium oxide, nitridation
Boron, calcium-base bentonite weight ratio be 20-30:10-20:10-20:4-8:6-14:8-12.
8. any one of -7 stating chemical industry packaging bag according to claim 1, which is characterized in that crosslinking agent includes: perbenzoic acid uncle
Butyl ester, N, N '-penylene bismaleimide.
9. stating chemical industry packaging bag according to claim 8, which is characterized in that peroxidized t-butyl perbenzoate, N, N '-penylene span
Carrying out imido weight ratio is 1-2:1-2.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811207966.7A CN109401050A (en) | 2018-10-17 | 2018-10-17 | A kind of chemical industry packaging bag |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811207966.7A CN109401050A (en) | 2018-10-17 | 2018-10-17 | A kind of chemical industry packaging bag |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109401050A true CN109401050A (en) | 2019-03-01 |
Family
ID=65468374
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811207966.7A Withdrawn CN109401050A (en) | 2018-10-17 | 2018-10-17 | A kind of chemical industry packaging bag |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109401050A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0474376A2 (en) * | 1990-08-13 | 1992-03-11 | W.R. Grace & Co.-Conn. | Films of blends of polypropylene and ethylene copolymer |
| CN102964544A (en) * | 2012-11-02 | 2013-03-13 | 中科院广州化学有限公司 | Water-dispersible crosslinking type fluoropolymer and application of fluoropolymer in preparation of super-amphiphobic surfaces |
| CN106188971A (en) * | 2016-08-11 | 2016-12-07 | 安徽松泰包装材料有限公司 | A kind of plastic sheeting and preparation method thereof |
-
2018
- 2018-10-17 CN CN201811207966.7A patent/CN109401050A/en not_active Withdrawn
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0474376A2 (en) * | 1990-08-13 | 1992-03-11 | W.R. Grace & Co.-Conn. | Films of blends of polypropylene and ethylene copolymer |
| CN102964544A (en) * | 2012-11-02 | 2013-03-13 | 中科院广州化学有限公司 | Water-dispersible crosslinking type fluoropolymer and application of fluoropolymer in preparation of super-amphiphobic surfaces |
| CN106188971A (en) * | 2016-08-11 | 2016-12-07 | 安徽松泰包装材料有限公司 | A kind of plastic sheeting and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103613975B (en) | One utilizes magnesium slag CO absorption 2the preparation method of exterior coating | |
| CN101074355B (en) | Cement-based penetrant crystalline waterproof material and production thereof | |
| CN106242398B (en) | A kind of high-strength and high ductility Waterproof mortar material and preparation method thereof can be used for 3D building printings | |
| CN109437657A (en) | A kind of Diamond Search cement group water-proofing material polymerized emulsion and preparation method thereof | |
| JPH06511228A (en) | Workable cement composition | |
| CN102731779B (en) | Synthetic method of hybrid non-isocyanate polyurethane | |
| CN114956768B (en) | Anti-dispersion grouting material for grouting and water plugging of water-rich stratum, and preparation method and construction method thereof | |
| CN106477955A (en) | Organic polymer material and the portland cement containing this material and preparation method thereof | |
| CN1680502A (en) | A kind of expandable graphite nano fireproof coating and its preparation method and application | |
| CN106674810A (en) | Polyvinyl chloride cable material with excellent mechanical properties | |
| CN109401050A (en) | A kind of chemical industry packaging bag | |
| KR100882840B1 (en) | Manufacturing method of waterproof paint composition and waterproof paint composition produced thereby | |
| CN106566042A (en) | Corrosion-resistant carbon fiber resin-based composite material used for pump | |
| CN103073967B (en) | Preparation method of polyacrylate leather finishing agent | |
| CN106986575A (en) | A kind of high-effective concrete performance-enhancing additive and preparation method thereof | |
| CN112680006B (en) | Water-based nano waterproof slurry and preparation method thereof | |
| CN109320846A (en) | A kind of fresh-keeping plastic packaging bag of food | |
| CN114686192A (en) | High-temperature-resistant high-elasticity epoxy resin well cementing fluid and preparation method thereof | |
| CN104086699B (en) | A kind of non-commixed type high stability polyacrylic ester water swelling rubber and its preparation method | |
| CN1640977A (en) | Polymeric adhesive for exposed wall thermal-insulation | |
| CN110157116A (en) | A kind of unleaded drainage pipe of novel hard polyvinyl chloride and preparation method thereof | |
| CN113637429A (en) | Glue, preparation method thereof and adhesive tape | |
| CN112961458A (en) | Tung oil based epoxy flexibilizer and preparation method thereof | |
| CN104496541B (en) | The preparation method of a kind of waterproof paint for cement | |
| CN105038245A (en) | Preparation technology of environmental friendly silicone rubber |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20190301 |