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CN109392562B - A special bag for mango with strong light transmittance - Google Patents

A special bag for mango with strong light transmittance Download PDF

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CN109392562B
CN109392562B CN201811580239.5A CN201811580239A CN109392562B CN 109392562 B CN109392562 B CN 109392562B CN 201811580239 A CN201811580239 A CN 201811580239A CN 109392562 B CN109392562 B CN 109392562B
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mango
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CN109392562A (en
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谢宗宜
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Guangxi Woston Technology Co ltd
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Taizhou Zhongzhi Yingjian Machinery Automation Co ltd
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01GHORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
    • A01G13/00Protection of plants
    • A01G13/20Protective coverings for plants
    • A01G13/27Protective coverings for plants protecting specific parts of plants, e.g. roots, trunks or fruits

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Abstract

本发明公开了一种透光性强的芒果专用套袋,所述芒果专用套袋袋身由纸张制成,所述纸张由袋内至袋外依次设有药物涂布层、甲壳素纤维层、竹浆纤维层、纳米二氧化钛涂层,所述芒果专用套袋袋底为内外两层结构,内层为聚丙烯纤维层,外层为纳米二氧化钛涂层;所述芒果专用套袋袋口边缘固定有针线;所述药物涂布层由柔软剂、助留剂、丙胺酸、聚乙烯醇、防雾性树脂、邻苯二甲酸二辛酯、脂肪酸甘油酯、正丁醇、抗菌剂、防霉剂、杀虫剂、对甲苯磺酸、去离子水组成;本发明的芒果套袋具有透光性强、经久耐用、实用性强、病虫防害效果好,套袋后芒果色泽艳丽等效果。

Figure 201811580239

The invention discloses a special bag for mangoes with strong light transmittance. The body of the special bag for mango is made of paper, and the paper is sequentially provided with a drug coating layer and a chitin fiber layer from the inside of the bag to the outside of the bag. , bamboo pulp fiber layer, nano-titanium dioxide coating, the bottom of the mango special bagging bag is an inner and outer two-layer structure, the inner layer is a polypropylene fiber layer, and the outer layer is a nano-titanium dioxide coating; the mango special bagging bag mouth edge Needle and thread are fixed; the drug coating layer is composed of softener, retention aid, alanine, polyvinyl alcohol, anti-fog resin, dioctyl phthalate, fatty acid glyceride, n-butanol, antibacterial agent, anti-fog It is composed of mold agent, insecticide, p-toluenesulfonic acid and deionized water; the mango bagging of the present invention has the advantages of strong light transmittance, durability, strong practicability, good pest and disease prevention effect, and the mango after bagging has bright color and luster, etc. Effect.

Figure 201811580239

Description

一种透光性强的芒果专用套袋A special bag for mango with strong light transmittance

技术领域technical field

本发明涉及果树种植技术领域,具体涉及一种透光性强的芒果专用套袋。The invention relates to the technical field of fruit tree planting, in particular to a special bagging for mangoes with strong light transmittance.

背景技术Background technique

我区属于亚热带季风气候,雨、热资源丰富,雨热同季,由于雨、热资源丰富,也带来了很多的病虫害,给芒果生产带来较大的危害,每年因病虫为害所造成的损失占水果总产量的30%以上,如稍为不注意病虫的防治,有的甚至造成失收。虽用药物防治可保住部分产量,但用药量和次数太多,又增加了农药的残留量。目前解决这个矛盾的最好办法就是进行套袋培育。Our region belongs to the subtropical monsoon climate, with abundant rain and heat resources. Rain and heat are in the same season. Due to the abundant rain and heat resources, it also brings a lot of pests and diseases, which brings great harm to mango production. The loss accounts for more than 30% of the total fruit output. If the control of diseases and insects is not paid attention to, some even cause the loss of harvest. Although the use of drug control can keep part of the output, but the amount and frequency of drug use are too many, which increases the amount of pesticide residues. The best way to solve this contradiction at present is to carry out bagging cultivation.

芒果套袋具有如下优点:可防止病菌的感染、传播、以及昆虫等侵害果实;防止空气有害物质及酸雨污染果实;防止强光照紫外线灼伤果实表皮;减少果实与其它物质相互摩擦损伤果面;减少农药喷药次数,避免农药与果实接触,降低农药残留量;为生育期的果实营造优良环境、改善着色、增加果皮蜡质,提高果面的光洁度及光泽。Mango bagging has the following advantages: it can prevent the infection, spread of bacteria, and insects from invading the fruit; prevent air pollution and acid rain from contaminating the fruit; prevent strong sunlight and ultraviolet rays from burning the fruit skin; reduce the friction between the fruit and other substances to damage the fruit surface; reduce The number of times of pesticide spraying can avoid the contact between pesticides and fruits and reduce pesticide residues; create a good environment for fruits in the growing period, improve the coloring, increase the wax quality of the peel, and improve the smoothness and luster of the fruit surface.

目前,芒果套袋的材料主要有白色无纺布果袋、透气塑膜袋、尼龙网袋、纸袋等。使用最多的是纸袋。而红象牙、爱文、红苹芒等品种在生长过程中需要一定的光照以满足色泽的要求。现有技术中,一般采用在收货前10天左右进行摘除套袋,工作量大。At present, mango bagging materials mainly include white non-woven fruit bags, breathable plastic film bags, nylon mesh bags, paper bags, etc. The most used are paper bags. And red ivory, Aiwen, red apple awn and other varieties need a certain amount of light in the growth process to meet the color requirements. In the prior art, it is generally adopted to remove the bag about 10 days before receiving the goods, and the workload is large.

发明内容SUMMARY OF THE INVENTION

本发明克服了现有技术中,套袋透光性差,不能满足芒果光照需求的技术问题,提供一种透光性强的芒果专用套袋。The invention overcomes the technical problems in the prior art that the bagging has poor light transmittance and cannot meet the lighting requirements of mangoes, and provides a special bagging for mangoes with strong light transmittance.

为解决上述问题,本发明采取如下技术方案:In order to solve the above problems, the present invention adopts the following technical solutions:

一种透光性强的芒果专用套袋,包括袋身和袋底,所述芒果专用套袋袋身由纸张制成,所述纸张由袋内至袋外依次设有药物涂布层、甲壳素纤维层、竹浆纤维层、纳米二氧化钛涂层,所述芒果专用套袋袋底为内外两层结构,内层为聚丙烯纤维层,外层为纳米二氧化钛涂层;所述芒果专用套袋袋口边缘固定有针线;所述药物涂布层由以下重量组份的材料组成:柔软剂0.1~0.2份、助留剂0.2~0.3份、丙胺酸1~2份、聚乙烯醇5~10份、防雾性树脂5~10份、邻苯二甲酸二辛酯8~10份、脂肪酸甘油酯3~6份、正丁醇1~5份、抗菌剂4~9份、防霉剂4~8份、杀虫剂3~6份、对甲苯磺酸1~3份、去离子水10~20份;A special cover bag for mangoes with strong light transmittance, comprising a bag body and a bag bottom. A plain fiber layer, a bamboo pulp fiber layer, and a nano-titanium dioxide coating. The bottom of the mango special bagging bag has an inner and outer two-layer structure, the inner layer is a polypropylene fiber layer, and the outer layer is a nano-titanium dioxide coating; the mango special bagging bag Needle and thread are fixed on the edge of the bag mouth; the drug coating layer is composed of the following materials by weight: 0.1-0.2 parts of softener, 0.2-0.3 parts of retention aid, 1-2 parts of alanine, 5-10 parts of polyvinyl alcohol parts, 5-10 parts of anti-fog resin, 8-10 parts of dioctyl phthalate, 3-6 parts of fatty acid glycerides, 1-5 parts of n-butanol, 4-9 parts of antibacterial agent, 4 parts of antifungal agent ~8 parts, 3-6 parts pesticides, 1-3 parts p-toluenesulfonic acid, 10-20 parts deionized water;

所述药物涂布层的厚度为0.01~0.1mm;所述甲壳素纤维层的厚度为0.01~0.05mm。The thickness of the drug coating layer is 0.01-0.1 mm; the thickness of the chitin fiber layer is 0.01-0.05 mm.

其中,所述袋身、袋底的纳米二氧化钛涂层厚度一致,均为0.01~0.1mm。Wherein, the thickness of the nano-titanium dioxide coating on the bag body and the bag bottom is the same, and both are 0.01-0.1 mm.

其中,所述的纳米二氧化钛涂层由质量份的如下原料制成:吐温20~30份、正丁醇1~5份、乙酰丙酮50~80份、钛酸四丁酯10~20份、丙三醇14~17份、无水乙醇20~30份、氧化钼0.1~0.3份。Wherein, the nano titanium dioxide coating is made of the following raw materials in parts by mass: 20-30 parts of Tween, 1-5 parts of n-butanol, 50-80 parts of acetylacetone, 10-20 parts of tetrabutyl titanate, 14-17 parts of glycerol, 20-30 parts of anhydrous ethanol, and 0.1-0.3 parts of molybdenum oxide.

其中,所述纳米二氧化钛涂层由如下方法制备得到:按质量称取吐温-60、正丁醇、乙酰丙酮、钛酸四丁酯、丙三醇、无水乙醇;将钛酸四丁酯溶于无水乙醇,再依次加入乙酰丙酮后搅拌2h,再添加丙三醇、正丁醇和吐温-60继续搅拌10~20min得到TiO2溶胶,将TiO2溶胶平铺于竹浆纤维层或聚丙烯纤维层的一侧面上,在红外线下照射12~15min,再将竹浆纤维层置于马福炉中在350~400摄氏度下保温1h后浸质于4mol/L的氧化钼溶液中5~7d,取出在红外线下照射12~15min,再将竹浆纤维层置于马福炉中在350~400摄氏度下保温1h即得所述纳米二氧化钛涂层。Wherein, the nano titanium dioxide coating is prepared by the following method: weighing Tween-60, n-butanol, acetylacetone, tetrabutyl titanate, glycerol, and absolute ethanol by mass; Dissolve in absolute ethanol, add acetylacetone in turn and stir for 2 hours, then add glycerol, n-butanol and Tween-60 and continue stirring for 10-20min to obtain TiO 2 sol, and spread the TiO 2 sol on the bamboo pulp fiber layer or One side of the polypropylene fiber layer is irradiated with infrared rays for 12 to 15 minutes, and then the bamboo pulp fiber layer is placed in a muffle furnace for 1 hour at 350 to 400 degrees Celsius, and then soaked in a 4mol/L molybdenum oxide solution for 5 to 7 days. , take out and irradiate under infrared rays for 12-15 minutes, and then place the bamboo pulp fiber layer in a muffle furnace at 350-400 degrees Celsius for 1 hour to obtain the nano-titanium dioxide coating.

其中,所述聚丙烯纤维层的厚度为0.1~0.3mm。Wherein, the thickness of the polypropylene fiber layer is 0.1-0.3 mm.

其中,所述抗菌剂为壳聚糖,防霉剂为吡啶硫酮锌,所述杀虫剂为噻虫啉、氟虫双酰胺、除虫脲、多杀菌素、阿维菌素、苦参碱、白僵菌的一种或几种。Wherein, the antibacterial agent is chitosan, the antifungal agent is zinc pyrithione, and the insecticide is thiacloprid, flubendiamide, diflubenzuron, spinosyn, abamectin, Sophora flavescens One or more of Alkali and Beauveria bassiana.

其中,所述柔软剂为硬脂酸三乙醇胺酯季铵盐,助留剂为瓜耳胶。Wherein, the softener is triethanolamine stearate quaternary ammonium salt, and the retention aid is guar gum.

本发明与现有技术相比较具有以下有益效果:Compared with the prior art, the present invention has the following beneficial effects:

(1)本发明纸袋中纸张由袋内至袋外依次设有药物涂布层、甲壳素纤维层、竹浆纤维层、纳米二氧化钛涂层。药物涂布层、甲壳素纤维层、竹浆纤维层、纳米二氧化钛涂层制成的袋子牢固性强,耐用性高,甲壳素纤维层、竹浆纤维层为透光性层涂料,有利于光照透过套袋,有利于芒果色泽的生成,适用于红象牙、爱文、红苹芒等品种等品种套袋。本发明的芒果套袋具有透光性强、经久耐用、实用性强、病虫防害效果好,套袋后芒果色泽艳丽等效果。(1) The paper in the paper bag of the present invention is sequentially provided with a drug coating layer, a chitin fiber layer, a bamboo pulp fiber layer, and a nano-titanium dioxide coating layer from the inside to the outside of the bag. The bag made of drug coating layer, chitin fiber layer, bamboo pulp fiber layer and nano-titanium dioxide coating has strong firmness and high durability. Through bagging, it is conducive to the formation of mango color and luster, and is suitable for bagging of varieties such as red ivory, Aiwen, and red apple mango. The mango bagging of the invention has the advantages of strong light transmittance, durability, practicability, good pest and disease prevention effect, and the mangoes after bagging have the effects of bright color and luster.

(2)本发明芒果套袋袋内层为药物涂布层,具有防菌抑菌、杀虫作用,套袋前可不用喷洒农药即可具有防虫防害作用。本发明芒果套袋袋外层为纳米二氧化钛涂层,在太阳光的作用下,纳米二氧化钛涂层具有杀菌抑菌作用,病害防治效果好。(2) The inner layer of the mango bagging bag of the present invention is a drug coating layer, which has antibacterial, bacteriostatic, and insecticidal effects, and can have the effect of preventing insects and pests without spraying pesticides before bagging. The outer layer of the mango bagging bag of the present invention is a nano-titanium dioxide coating, and under the action of sunlight, the nano-titanium dioxide coating has bactericidal and bacteriostatic effects, and has a good disease control effect.

(3)本发明纳米二氧化钛涂层以无水乙醇为溶剂,以吐温、正丁醇、乙酰丙酮、钛酸四丁酯、丙三醇、无水乙醇为原料,并添加MoO3制备成纳米二氧化钛涂层的吸收光的波长范围变广,透光性强、牢固性强、稳定性高、光催化强等优点。(3) the nano titanium dioxide coating of the present invention takes absolute ethanol as solvent, takes Tween, n - butanol, acetylacetone, tetrabutyl titanate, glycerol, absolute ethanol as raw materials, and adds MoO to prepare nanometer Titanium dioxide coating has the advantages of widening the wavelength range of light absorption, strong light transmission, strong firmness, high stability, and strong photocatalysis.

附图说明Description of drawings

图1为本发明芒果专用套袋的整体结构示意图;Fig. 1 is the overall structure schematic diagram of the special bagging for mango of the present invention;

图2为本发明芒果专用套袋的切面图;Fig. 2 is the sectional view of the special bagging for mango of the present invention;

图中,1-芒果专用套袋、2-针线、3-药物涂布层、4-甲壳素纤维层、5-竹浆纤维层、6-袋身纳米二氧化钛涂层、7-聚丙烯纤维层、8-袋底纳米二氧化钛涂层。In the picture, 1- mango special bag, 2- needle thread, 3- drug coating layer, 4- chitin fiber layer, 5- bamboo pulp fiber layer, 6- bag body nano-titanium dioxide coating, 7- polypropylene fiber layer , 8 - nano-titanium dioxide coating at the bottom of the bag.

具体实施方式Detailed ways

下面结合实施例。附图和试验对本发明作进一步说明。Embodiments are combined below. The drawings and experiments further illustrate the invention.

实施例1Example 1

如图1、图2所示,一种透光性强的芒果专用套袋1,包括袋身和袋底,所述芒果专用套袋1袋身由纸张制成,所述纸张由袋内至袋外依次设有药物涂布层3、甲壳素纤维层4、竹浆纤维层5、纳米二氧化钛涂层6,所述芒果专用套袋袋底为内外两层结构,内层为聚丙烯纤维层7,外层为纳米二氧化钛涂层5;所述芒果专用套袋1袋口边缘固定有针线2。所述的针线2用于将套袋1较好的套在芒果上并防止套袋1掉落。As shown in Figures 1 and 2, a special cover bag 1 for mangoes with strong light transmittance includes a bag body and a bag bottom. The outside of the bag is sequentially provided with a drug coating layer 3, a chitin fiber layer 4, a bamboo pulp fiber layer 5, and a nano-titanium dioxide coating 6. The bottom of the mango special bagging bag has an inner and outer two-layer structure, and the inner layer is a polypropylene fiber layer. 7. The outer layer is a nano-titanium dioxide coating 5; a needle thread 2 is fixed on the edge of the bag mouth of the mango special bag 1. Said needle thread 2 is used to better cover the bag 1 on the mango and prevent the bag 1 from falling.

所述药物涂布层3由以下重量组份的材料组成:柔软剂0.2份、助留剂0.2份、丙胺酸2份、聚乙烯醇5份、防雾性树脂10份、邻苯二甲酸二辛酯8份、脂肪酸甘油酯6份、正丁醇1份、抗菌剂9份、防霉剂4份、杀虫剂6份、对甲苯磺酸1份、去离子水20份;所述药物涂布层3的厚度为0.01mm;所述抗菌剂为壳聚糖,防霉剂为吡啶硫酮锌,所述杀虫剂为噻虫啉、氟虫双酰胺、除虫脲、多杀菌素、阿维菌素、苦参碱、白僵菌,所述柔软剂为硬脂酸三乙醇胺酯季铵盐,助留剂为瓜耳胶。The drug coating layer 3 is composed of the following materials by weight: 0.2 part of softener, 0.2 part of retention aid, 2 parts of alanine, 5 parts of polyvinyl alcohol, 10 parts of anti-fogging resin, phthalic acid two parts 8 parts of octyl ester, 6 parts of fatty acid glycerides, 1 part of n-butanol, 9 parts of antibacterial agent, 4 parts of antifungal agent, 6 parts of insecticide, 1 part of p-toluenesulfonic acid, 20 parts of deionized water; the medicine The thickness of the coating layer 3 is 0.01mm; the antibacterial agent is chitosan, the antifungal agent is zinc pyrithione, and the insecticide is thiacloprid, flufenoxamide, diflubenzuron, spinosad , Abamectin, matrine, Beauveria bassiana, the softener is triethanolamine stearate quaternary ammonium salt, and the retention aid is guar gum.

所述甲壳素纤维层4的厚度为0.05mm。The thickness of the chitin fiber layer 4 is 0.05 mm.

所述聚丙烯纤维层7的厚度为0.1mm。The thickness of the polypropylene fiber layer 7 is 0.1 mm.

所述袋身纳米二氧化钛涂层6与所述袋底纳米二氧化钛涂层8厚度的厚度一致,均为0.1mm,所述袋身纳米二氧化钛涂层6与所述袋底纳米二氧化钛涂层8均由质量份的如下原料制成:吐温20份、正丁醇5份、乙酰丙酮50份、钛酸四丁酯20份、丙三醇14份、无水乙醇30份、氧化钼0.1份。所述纳米二氧化钛涂层6由如下方法制备得到:按质量称取吐温-60、正丁醇、乙酰丙酮、钛酸四丁酯、丙三醇、无水乙醇;将钛酸四丁酯溶于无水乙醇,再依次加入乙酰丙酮后搅拌2h,再添加丙三醇、正丁醇和吐温-60继续搅拌20min得到TiO2溶胶,将TiO2溶胶平铺于竹浆纤维层或聚丙烯纤维层的一侧面上,在红外线下照射12min,再将竹浆纤维层置于马福炉中在400摄氏度下保温1h后浸质于4mol/L的氧化钼溶液中5d,取出在红外线下照射15min,再将竹浆纤维层置于马福炉中在350摄氏度下保温1h即得所述纳米二氧化钛涂层。The thickness of the bag body nano-titanium dioxide coating 6 and the bag bottom nano-titanium dioxide coating 8 are the same thickness, both are 0.1mm, the bag body nano-titanium dioxide coating 6 and the bag bottom nano-titanium dioxide coating 8 are both composed of The following raw materials were prepared in parts by mass: 20 parts of Tween, 5 parts of n-butanol, 50 parts of acetylacetone, 20 parts of tetrabutyl titanate, 14 parts of glycerol, 30 parts of absolute ethanol, and 0.1 part of molybdenum oxide. The nano titanium dioxide coating 6 is prepared by the following method: weighing Tween-60, n-butanol, acetylacetone, tetrabutyl titanate, glycerol, and absolute ethanol by mass; dissolving tetrabutyl titanate In anhydrous ethanol, add acetylacetone in turn and stir for 2h, then add glycerol, n-butanol and Tween-60 and continue stirring for 20min to obtain a TiO 2 sol, and spread the TiO 2 sol on the bamboo pulp fiber layer or polypropylene fiber One side of the layer was irradiated under infrared rays for 12 minutes, and then the bamboo pulp fiber layer was placed in a muffle furnace for 1 hour at 400 degrees Celsius, soaked in a 4 mol/L molybdenum oxide solution for 5 days, taken out and irradiated under infrared rays for 15 minutes, and then The bamboo pulp fiber layer was placed in a muffle furnace and kept at 350 degrees Celsius for 1 hour to obtain the nano-titanium dioxide coating.

实施例2Example 2

如图1、图2所示,一种透光性强的芒果专用套袋1,包括袋身和袋底,所述芒果专用套袋1袋身由纸张制成,所述纸张由袋内至袋外依次设有药物涂布层3、甲壳素纤维层4、竹浆纤维层5、纳米二氧化钛涂层6,所述芒果专用套袋袋底为内外两层结构,内层为聚丙烯纤维层7,外层为纳米二氧化钛涂层5;所述芒果专用套袋1袋口边缘固定有针线。2。所述的针线2用于将套袋1较好的套在芒果上并防止套袋1掉落。As shown in Figures 1 and 2, a special cover bag 1 for mangoes with strong light transmittance includes a bag body and a bag bottom. The outside of the bag is sequentially provided with a drug coating layer 3, a chitin fiber layer 4, a bamboo pulp fiber layer 5, and a nano-titanium dioxide coating 6. The bottom of the mango special bagging bag has an inner and outer two-layer structure, and the inner layer is a polypropylene fiber layer. 7. The outer layer is a nano-titanium dioxide coating 5; the edge of the bag mouth of the mango special bag 1 is fixed with needle and thread. 2. Said needle thread 2 is used to better cover the bag 1 on the mango and prevent the bag 1 from falling.

所述药物涂布层3由以下重量组份的材料组成:柔软剂0.1份、助留剂0.3份、丙胺酸1份、聚乙烯醇10份、防雾性树脂5份、邻苯二甲酸二辛酯10份、脂肪酸甘油酯3份、正丁醇5份、抗菌剂4份、防霉剂8份、杀虫剂3份、对甲苯磺酸3份、去离子水10份;所述药物涂布层3的厚度为0.1mm;所述抗菌剂为壳聚糖,防霉剂为吡啶硫酮锌,所述杀虫剂为噻虫啉,所述柔软剂为硬脂酸三乙醇胺酯季铵盐,助留剂为瓜耳胶,The drug coating layer 3 is composed of the following materials by weight: 0.1 part of softener, 0.3 part of retention aid, 1 part of alanine, 10 parts of polyvinyl alcohol, 5 parts of anti-fogging resin, phthalic acid two parts 10 parts of octyl ester, 3 parts of fatty acid glycerides, 5 parts of n-butanol, 4 parts of antibacterial agent, 8 parts of antifungal agent, 3 parts of insecticide, 3 parts of p-toluenesulfonic acid, 10 parts of deionized water; the medicine The thickness of the coating layer 3 is 0.1 mm; the antibacterial agent is chitosan, the antifungal agent is zinc pyrithione, the insecticide is thiacloprid, and the softener is triethanolamine stearate quaternary Ammonium salt, retention aid is guar gum,

所述甲壳素纤维层4的厚度为0.01mm。The thickness of the chitin fiber layer 4 is 0.01 mm.

所述聚丙烯纤维层7的厚度为0.3mm。The thickness of the polypropylene fiber layer 7 is 0.3 mm.

所述袋身纳米二氧化钛涂层6与所述袋底纳米二氧化钛涂层8厚度的厚度一致,均为0.01mm,所述袋身纳米二氧化钛涂层6与所述袋底纳米二氧化钛涂层8均由质量份的如下原料制成:吐温30份、正丁醇1份、乙酰丙酮80份、钛酸四丁酯10份、丙三醇17份、无水乙醇20份、氧化钼0.3份。所述纳米二氧化钛涂层6由如下方法制备得到:按质量称取吐温-60、正丁醇、乙酰丙酮、钛酸四丁酯、丙三醇、无水乙醇;将钛酸四丁酯溶于无水乙醇,再依次加入乙酰丙酮后搅拌2h,再添加丙三醇、正丁醇和吐温-60继续搅拌10~20min得到TiO2溶胶,将TiO2溶胶平铺于竹浆纤维层或聚丙烯纤维层的一侧面上,在红外线下照射12min,再将竹浆纤维层置于马福炉中在400摄氏度下保温1h后浸质于4mol/L的氧化钼溶液中5d,取出在红外线下照射15min,再将竹浆纤维层置于马福炉中在350摄氏度下保温1h即得所述纳米二氧化钛涂层。The thickness of the bag body nano-titanium dioxide coating 6 and the bag bottom nano-titanium dioxide coating 8 are the same thickness, both of which are 0.01 mm, and the bag body nano-titanium dioxide coating 6 and the bag bottom nano-titanium dioxide coating 8 are both made of the same thickness. The following raw materials were prepared in parts by mass: 30 parts of Tween, 1 part of n-butanol, 80 parts of acetylacetone, 10 parts of tetrabutyl titanate, 17 parts of glycerol, 20 parts of absolute ethanol, and 0.3 parts of molybdenum oxide. The nano titanium dioxide coating 6 is prepared by the following method: weighing Tween-60, n-butanol, acetylacetone, tetrabutyl titanate, glycerol, and absolute ethanol by mass; dissolving tetrabutyl titanate In anhydrous ethanol, add acetylacetone in turn and stir for 2h, then add glycerol, n-butanol and Tween-60 and continue stirring for 10-20min to obtain a TiO 2 sol, and spread the TiO 2 sol on the bamboo pulp fiber layer or polymer. One side of the propylene fiber layer was irradiated under infrared light for 12 minutes, and then the bamboo pulp fiber layer was placed in a muffle furnace for 1 hour at 400 degrees Celsius, soaked in a 4 mol/L molybdenum oxide solution for 5 days, taken out and irradiated under infrared light for 15 minutes , and then placing the bamboo pulp fiber layer in a muffle furnace at 350 degrees Celsius for 1 hour to obtain the nano-titanium dioxide coating.

实施例3Example 3

如图1、图2所示,一种透光性强的芒果专用套袋1,包括袋身和袋底,所述芒果专用套袋1袋身由纸张制成,所述纸张由袋内至袋外依次设有药物涂布层3、甲壳素纤维层4、竹浆纤维层5、纳米二氧化钛涂层6,所述芒果专用套袋袋底为内外两层结构,内层为聚丙烯纤维层7,外层为纳米二氧化钛涂层5;所述芒果专用套袋1袋口边缘固定有针线。2。所述的针线2用于将套袋1较好的套在芒果上并防止套袋1掉落。As shown in Figures 1 and 2, a special cover bag 1 for mangoes with strong light transmittance includes a bag body and a bag bottom. The outside of the bag is sequentially provided with a drug coating layer 3, a chitin fiber layer 4, a bamboo pulp fiber layer 5, and a nano-titanium dioxide coating 6. The bottom of the mango special bagging bag has an inner and outer two-layer structure, and the inner layer is a polypropylene fiber layer. 7. The outer layer is a nano-titanium dioxide coating 5; the edge of the bag mouth of the mango special bag 1 is fixed with needle and thread. 2. Said needle thread 2 is used to better cover the bag 1 on the mango and prevent the bag 1 from falling.

所述药物涂布层3由以下重量组份的材料组成:柔软剂0.15份、助留剂0.25份、丙胺酸2份、聚乙烯醇8份、防雾性树脂7份、邻苯二甲酸二辛酯9份、脂肪酸甘油酯5份、正丁醇3份、抗菌剂8份、防霉剂7份、杀虫剂5份、对甲苯磺酸2份、去离子水15份;所述药物涂布层3的厚度为0.05mm;所述抗菌剂为壳聚糖,防霉剂为吡啶硫酮锌,所述杀虫剂为噻虫啉、氟虫双酰胺、除虫脲、多杀菌素,所述柔软剂为硬脂酸三乙醇胺酯季铵盐,助留剂为瓜耳胶。The drug coating layer 3 is composed of the following materials by weight: 0.15 parts of softener, 0.25 parts of retention aid, 2 parts of alanine, 8 parts of polyvinyl alcohol, 7 parts of anti-fogging resin, phthalic acid two parts 9 parts of octyl ester, 5 parts of fatty acid glyceride, 3 parts of n-butanol, 8 parts of antibacterial agent, 7 parts of antifungal agent, 5 parts of insecticide, 2 parts of p-toluenesulfonic acid, 15 parts of deionized water; the medicine The thickness of the coating layer 3 is 0.05mm; the antibacterial agent is chitosan, the antifungal agent is zinc pyrithione, and the insecticide is thiacloprid, flufenoxamide, diflubenzuron, spinosad , the softener is triethanolamine stearate quaternary ammonium salt, and the retention aid is guar gum.

所述甲壳素纤维层4的厚度为0.04mm。The thickness of the chitin fiber layer 4 is 0.04 mm.

所述聚丙烯纤维层7的厚度为0.2mm。The thickness of the polypropylene fiber layer 7 is 0.2 mm.

所述袋身纳米二氧化钛涂层6与所述袋底纳米二氧化钛涂层8厚度的厚度一致,均为0.05mm,所述袋身纳米二氧化钛涂层6与所述袋底纳米二氧化钛涂层8均由质量份的如下原料制成:吐温25份、正丁醇3份、乙酰丙酮70份、钛酸四丁酯15份、丙三醇15份、无水乙醇25份、氧化钼0.2份。所述纳米二氧化钛涂层6由如下方法制备得到:按质量称取吐温-60、正丁醇、乙酰丙酮、钛酸四丁酯、丙三醇、无水乙醇;将钛酸四丁酯溶于无水乙醇,再依次加入乙酰丙酮后搅拌2h,再添加丙三醇、正丁醇和吐温-60继续搅拌15min得到TiO2溶胶,将TiO2溶胶平铺于竹浆纤维层或聚丙烯纤维层的一侧面上,在红外线下照射14min,再将竹浆纤维层置于马福炉中在380摄氏度下保温1h后浸质于4mol/L的氧化钼溶液中6d,取出在红外线下照射14min,再将竹浆纤维层置于马福炉中在390摄氏度下保温1h即得所述纳米二氧化钛涂层。The thickness of the bag body nano-titanium dioxide coating 6 and the thickness of the bag bottom nano-titanium dioxide coating 8 are the same, both of which are 0.05 mm, and the bag body nano-titanium dioxide coating 6 and the bag bottom nano-titanium dioxide coating 8 are both made of the same thickness. The following raw materials were prepared in parts by mass: 25 parts of Tween, 3 parts of n-butanol, 70 parts of acetylacetone, 15 parts of tetrabutyl titanate, 15 parts of glycerol, 25 parts of absolute ethanol, and 0.2 parts of molybdenum oxide. The nano titanium dioxide coating 6 is prepared by the following method: weighing Tween-60, n-butanol, acetylacetone, tetrabutyl titanate, glycerol, and absolute ethanol by mass; dissolving tetrabutyl titanate In absolute ethanol, add acetylacetone in turn and stir for 2h, then add glycerol, n-butanol and Tween-60 and continue stirring for 15min to obtain a TiO 2 sol, and spread the TiO 2 sol on the bamboo pulp fiber layer or polypropylene fiber One side of the layer was irradiated under infrared light for 14 minutes, and then the bamboo pulp fiber layer was placed in a muffle furnace for 1 hour at 380 degrees Celsius, soaked in 4 mol/L molybdenum oxide solution for 6 days, taken out and irradiated under infrared light for 14 minutes, and then The bamboo pulp fiber layer is placed in a muffle furnace and kept at 390 degrees Celsius for 1 hour to obtain the nano-titanium dioxide coating.

为了说明本发明的技术效果,设置如下对照组:In order to illustrate the technical effect of the present invention, the following control groups are set:

对照组1control group 1

对照组1的芒果套袋为普通纸袋。The mango bags of control group 1 were ordinary paper bags.

对照组2control group 2

对照组2的芒果专用套袋结构上于实施例3相同,区别仅在于:对照组2的药物涂布层由以下重量组份的材料组成:柔软剂0.15份、助留剂0.25份、丙胺酸2份、聚乙烯醇8份、邻苯二甲酸二辛酯9份、正丁醇3份、抗菌剂8份、防霉剂7份、杀虫剂5份、去离子水15份。The mango special bagging structure of the control group 2 is the same as that of the embodiment 3, and the difference is only that: the drug coating layer of the control group 2 is composed of the following materials by weight: 0.15 part of softener, 0.25 part of retention aid, alanine 2 parts, 8 parts of polyvinyl alcohol, 9 parts of dioctyl phthalate, 3 parts of n-butanol, 8 parts of antibacterial agent, 7 parts of antifungal agent, 5 parts of insecticide, and 15 parts of deionized water.

对照组3control group 3

对照组3的芒果专用套袋结构上于实施例1相同,区别仅在于:对照组3的柔软剂0.2份、助留剂0.2份、防雾性树脂10份、脂肪酸甘油酯6份、正丁醇1份、抗菌剂9份、防霉剂4份、杀虫剂6份、对甲苯磺酸1份、去离子水20份;所述药物涂布层3的厚度为0.01mm;所述抗菌剂为壳聚糖,防霉剂为吡啶硫酮锌,所述杀虫剂为噻虫啉、氟虫双酰胺、除虫脲、多杀菌素、阿维菌素、苦参碱、白僵菌,所述柔软剂为硬脂酸三乙醇胺酯季铵盐,助留剂为瓜耳胶。The mango special bagging structure of the control group 3 is the same as that of the embodiment 1, and the difference is only that: the control group 3 contains 0.2 parts of softener, 0.2 parts of retention aid, 10 parts of anti-fog resin, 6 parts of fatty acid glycerides, 1 part of alcohol, 9 parts of antibacterial agent, 4 parts of antifungal agent, 6 parts of insecticide, 1 part of p-toluenesulfonic acid, and 20 parts of deionized water; the thickness of the drug coating layer 3 is 0.01mm; The agent is chitosan, the antifungal agent is zinc pyrithione, and the insecticide is thiacloprid, flubendiamide, diflubenzuron, spinosad, abamectin, matrine, Beauveria bassiana , the softener is triethanolamine stearate quaternary ammonium salt, and the retention aid is guar gum.

对照组4control group 4

对照组4的芒果专用套袋结构上于实施例1相同,区别仅在于:对照组4的袋身纳米二氧化钛涂层与袋底纳米二氧化钛涂层均由质量份的如下原料制成:吐温20份、正丁醇5份、乙酰丙酮50份、钛酸四丁酯20份、丙三醇14份、无水乙醇30份。纳米二氧化钛涂层的制备方法为:按质量称取吐温-60、正丁醇、乙酰丙酮、钛酸四丁酯、丙三醇、无水乙醇;将钛酸四丁酯溶于无水乙醇,再依次加入乙酰丙酮后搅拌2h,再添加丙三醇、正丁醇和吐温-60继续搅拌20min得到TiO2溶胶,将TiO2溶胶平铺于竹浆纤维层或聚丙烯纤维层的一侧面上,在红外线下照射12min,再将竹浆纤维层置于马福炉中在400摄氏度下保温1h后即得所述纳米二氧化钛涂层。The mango-specific bagging structure of the control group 4 is the same as that of the embodiment 1, and the difference is only that: the nano-titanium dioxide coating of the bag body and the nano-titanium dioxide coating of the bag bottom of the control group 4 are both made of the following raw materials in parts by mass: Tween 20 parts, 5 parts of n-butanol, 50 parts of acetylacetone, 20 parts of tetrabutyl titanate, 14 parts of glycerol, and 30 parts of anhydrous ethanol. The preparation method of the nano titanium dioxide coating is as follows: weighing Tween-60, n-butanol, acetylacetone, tetrabutyl titanate, glycerol, and absolute ethanol by mass; dissolving the tetrabutyl titanate in the absolute ethanol Then add acetylacetone and stir for 2h, then add glycerol, n-butanol and Tween-60 and continue to stir for 20min to obtain TiO 2 sol, and spread the TiO 2 sol on one side of the bamboo pulp fiber layer or polypropylene fiber layer The nano-titanium dioxide coating was obtained by irradiating the bamboo pulp fiber layer for 12 minutes under infrared rays, placing the bamboo pulp fiber layer in a muffle furnace and keeping the temperature at 400 degrees Celsius for 1 hour.

对照组5control group 5

对照组5的芒果专用套袋结构上于实施例1相同,区别仅在于:对照组5的袋身纳米二氧化钛涂层与袋底纳米二氧化钛涂层均由质量份的如下原料制成:乙酰丙酮50份、钛酸四丁酯20份、丙三醇14份、无水乙醇30份、氧化钼0.1份。所述纳米二氧化钛涂层由如下方法制备得到:按质量称取乙酰丙酮、钛酸四丁酯、丙三醇、无水乙醇;将钛酸四丁酯溶于无水乙醇,再依次加入乙酰丙酮后搅拌2h,再添加丙三醇继续搅拌20min得到TiO2溶胶,将TiO2溶胶平铺于竹浆纤维层或聚丙烯纤维层的一侧面上,在红外线下照射12min,再将竹浆纤维层置于马福炉中在400摄氏度下保温1h后浸质于4mol/L的氧化钼溶液中5d,取出在红外线下照射15min,再将竹浆纤维层置于马福炉中在350摄氏度下保温1h即得所述纳米二氧化钛涂层。The mango special bagging structure of the control group 5 is the same as that of the embodiment 1, and the difference is only that: the nano-titanium dioxide coating of the bag body and the nano-titanium dioxide coating of the bag bottom of the control group 5 are both made of the following raw materials in parts by mass: acetylacetone 50 parts, 20 parts of tetrabutyl titanate, 14 parts of glycerol, 30 parts of anhydrous ethanol, and 0.1 part of molybdenum oxide. The nano titanium dioxide coating is prepared by the following method: weighing acetylacetone, tetrabutyl titanate, glycerol, and absolute ethanol by mass; dissolving tetrabutyl titanate in absolute ethanol, and then adding acetylacetone in turn After stirring for 2 hours, add glycerol and continue stirring for 20 minutes to obtain TiO 2 sol, spread the TiO 2 sol on one side of the bamboo pulp fiber layer or polypropylene fiber layer, irradiate it under infrared rays for 12 minutes, and then put the bamboo pulp fiber layer Placed in a muffle furnace, kept at 400 degrees Celsius for 1 hour, soaked in 4 mol/L molybdenum oxide solution for 5 days, taken out and irradiated with infrared rays for 15 minutes, and then placed the bamboo pulp fiber layer in a muffle furnace and kept it at 350 degrees Celsius for 1 hour. The nano-TiO2 coating.

使用效果:Effect:

1、实施例1~实施例3与对照组1~对照组5的芒果专用套袋应用于芒果套袋,实施例1~实施例3、对照组2~对照组5的芒果专用套袋可循环连续使用三年都完好无损,经久耐用。对照组1的芒果套袋仅可使用1年。1. The special mango baggings of Examples 1 to 3 and Control Group 1 to Control Group 5 were applied to mango bagging, and the special mango bagging of Examples 1 to 3 and Control Group 2 to Control Group 5 could be recycled It has been in good condition for three years of continuous use and is durable. Mango bagging in control group 1 was only available for 1 year.

2、将实施例1~实施例3以及对照组1~对照组5的芒果专用套袋给红象牙芒果套袋至采摘,芒果长斑率、腐烂率、病虫残害率、色泽如下表1。2. The red ivory mangoes were bagged for the special bagging of the mangoes of Examples 1 to 3 and the control group 1 to the control group 5 until they were picked.

表1Table 1

Figure BDA0001917594950000071
Figure BDA0001917594950000071

由表1可知,本发明的芒果专用套袋实施例1~实施例3相比于对照组1的普通套袋的芒果长斑率、腐烂率、病虫残害率低,说明本发明的芒果专用套袋具有较好的病虫防害效果,本发明的套袋的透光性比普通纸袋透光性好,不用提前去除套袋,芒果也具有色泽分明,颜色艳丽的色泽。实施例1~实施例3相比于对照组2的药物涂布层不含有防雾性树脂、脂肪酸甘油酯、对甲苯磺酸,对照组3的药物涂布层不含有丙胺酸、聚乙烯醇、邻苯二甲酸二辛酯,本发明的药物涂布层性能更稳定,透气性好、药物包埋性好、能稳固的粘合于甲壳素纤维层,防虫害防霉效果更好。实施例1~实施例3相比于对照组4的芒果专用套袋的纳米二氧化钛涂层不含有氧化钼,对照组5芒果专用套袋的的纳米二氧化钛涂层不含有吐温60和正丁醇,对照组4、对照组5套袋后,芒果色泽以及病虫妨害、长斑情况都比本发明差。本发明纳米二氧化钛涂层添加氧化钼后提高了纳米二氧化钛涂层的透光性、牢固性、稳定性、光催化性能,透光性的改善可使芒果色泽更好,光催化性好,抑菌杀菌效果好。本发明纳米二氧化钛涂层添加吐温60以及正丁醇后,纳米二氧化钛涂层稳定性高,透明度增强,有利于光照,芒果的色泽好。From Table 1, it can be seen that the mango special bagging Examples 1 to 3 of the present invention have lower spot rate, rot rate, and disease and insect damage rate than the ordinary bagging of control group 1. The bagging has better pest control effect, and the light transmission of the bag of the present invention is better than that of the ordinary paper bag, and the bagging does not need to be removed in advance, and the mango also has a clear and bright color. Compared with Example 1 to Example 3, the drug coating layer of control group 2 does not contain anti-fogging resin, fatty acid glyceride, p-toluenesulfonic acid, and the drug coating layer of control group 3 does not contain alanine, polyvinyl alcohol , dioctyl phthalate, the drug coating layer of the present invention has more stable performance, good air permeability, good drug embedding, can be firmly bonded to the chitin fiber layer, and has better pest and mildew prevention effects. Compared with Examples 1 to 3, the nano-titanium dioxide coating of the mango special bagging in control group 4 does not contain molybdenum oxide, and the nano-titanium dioxide coating of the mango special bagging in control group 5 does not contain Tween 60 and n-butanol, After the control group 4 and the control group 5 were bagged, the mango color, disease and insect damage, and long spot conditions were all worse than those of the present invention. After adding molybdenum oxide to the nano titanium dioxide coating of the invention, the light transmittance, firmness, stability and photocatalytic performance of the nano titanium dioxide coating are improved. Good sterilization effect. After adding Tween 60 and n-butanol to the nano-titanium dioxide coating of the invention, the nano-titanium dioxide coating has high stability, enhanced transparency, is beneficial to light, and has good mango color.

上述说明是针对本发明较佳可行实施例的详细说明,但实施例并非用以限定本发明的专利申请范围,凡本发明所提示的技术精神下所完成的同等变化或修饰变更,均应属于本发明所涵盖专利范围。The above description is a detailed description of the preferred feasible embodiments of the present invention, but the embodiments are not intended to limit the scope of the patent application of the present invention. All equivalent changes or modifications completed under the technical spirit suggested by the present invention shall belong to This invention covers the scope of the patent.

Claims (7)

1. The mango special cover bag with strong light transmission is characterized by comprising a bag body and a bag bottom, wherein the bag body is made of paper, a medicine coating layer, a chitin fiber layer, a bamboo pulp fiber layer and a nano titanium dioxide coating layer are sequentially arranged from the inside to the outside of the bag on the paper, the bag bottom of the mango special cover bag is of an inner-layer structure and an outer-layer structure, the inner layer is a polypropylene fiber layer, and the outer layer is a nano titanium dioxide coating layer; the edge of the opening of the special mango bagging is fixed with a needle thread; the medicine coating layer is composed of the following materials in parts by weight: 0.1-0.2 part of a softening agent, 0.2-0.3 part of a retention aid, 1-2 parts of alanine, 5-10 parts of polyvinyl alcohol, 5-10 parts of an antifogging resin, 8-10 parts of dioctyl phthalate, 3-6 parts of fatty glyceride, 1-5 parts of n-butyl alcohol, 4-9 parts of an antibacterial agent, 4-8 parts of a mildew preventive, 3-6 parts of an insecticide, 1-3 parts of p-toluenesulfonic acid and 10-20 parts of deionized water;
the thickness of the medicine coating layer is 0.01-0.1 mm; the thickness of the chitin fiber layer is 0.01-0.05 mm.
2. The special mango bagging bag with strong light transmission according to claim 1, characterized in that: the thicknesses of the nanometer titanium dioxide coatings at the bag body and the bag bottom are consistent and are 0.01-0.1 mm.
3. The special mango bagging bag with strong light transmission according to claim 1 or 2, characterized in that: the nano titanium dioxide coating is prepared from the following raw materials in parts by mass: tween-6020-30 parts, n-butanol 1-5 parts, acetylacetone 50-80 parts, tetrabutyl titanate 10-20 parts, glycerol 14-17 parts, absolute ethyl alcohol 20-30 parts, and molybdenum oxide 0.1-0.3 part.
4. The special mango bagging bag with strong light transmission according to claim 3, characterized in that: the nano titanium dioxide coating is prepared by the following method: weighing Tween-60, n-butanol, acetylacetone, tetrabutyl titanate, glycerol and absolute ethyl alcohol according to the mass; dissolving tetrabutyl titanate in absolute ethyl alcohol, sequentially adding acetylacetone, stirring for 2 hours, adding glycerol, n-butanol and tween-60, and continuously stirring for 10-20 min to obtain TiO2Sol of TiO2Spreading the sol on one side surface of the bamboo pulp fiber layer or the polypropylene fiber layer, irradiating for 12-15 min under infrared rays, placing the bamboo pulp fiber layer or the polypropylene fiber layer in a muffle furnace, preserving heat for 1h at 350-400 ℃, soaking in 4mol/L molybdenum oxide solution for 5-7 d, taking out, irradiating for 12-15 min under infrared rays, placing the bamboo pulp fiber layer or the polypropylene fiber layer in the muffle furnace, preserving heat for 1h at 350-400 ℃, and obtaining the nano titanium dioxideAnd (4) coating.
5. The special mango bagging bag with strong light transmission according to claim 1, characterized in that: the thickness of the polypropylene fiber layer is 0.1-0.3 mm.
6. The special mango bagging bag with strong light transmission according to claim 1, characterized in that: the antibacterial agent is chitosan, the mildew preventive is zinc pyrithione, and the pesticide is one or more of thiacloprid, flubendiamide, diflubenzuron, spinosad, abamectin, matrine and beauveria bassiana.
7. The special mango bagging bag with strong light transmission according to claim 1, characterized in that: the softening agent is triethanolamine stearate quaternary ammonium salt, and the retention aid is guar gum.
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FR2729535B1 (en) * 1995-01-19 1997-04-11 Vanier Henri Marie COVER FOR CULTIVATION, PARTICULARLY BANANAS
JP4749943B2 (en) * 2006-06-13 2011-08-17 東罐興業株式会社 White asparagus cultivation film and cultivation house using it
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CN104231683A (en) * 2014-08-25 2014-12-24 北京市建筑工程研究院有限责任公司 Titanium dioxide-silicon dioxide composite photocatalytic coating and preparation method thereof
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