CN109384593A - Special fertilizer for soaked kiwi fruits and preparation method thereof - Google Patents
Special fertilizer for soaked kiwi fruits and preparation method thereof Download PDFInfo
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- CN109384593A CN109384593A CN201811424531.8A CN201811424531A CN109384593A CN 109384593 A CN109384593 A CN 109384593A CN 201811424531 A CN201811424531 A CN 201811424531A CN 109384593 A CN109384593 A CN 109384593A
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- chelated
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- kiwi berry
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- 235000009436 Actinidia deliciosa Nutrition 0.000 title claims abstract description 81
- 239000003337 fertilizer Substances 0.000 title claims abstract description 79
- 238000002360 preparation method Methods 0.000 title claims abstract description 21
- 244000298697 Actinidia deliciosa Species 0.000 title abstract description 65
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 32
- YIXJRHPUWRPCBB-UHFFFAOYSA-N magnesium nitrate Chemical compound [Mg+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O YIXJRHPUWRPCBB-UHFFFAOYSA-N 0.000 claims abstract description 25
- 239000011575 calcium Substances 0.000 claims abstract description 21
- 239000010949 copper Substances 0.000 claims abstract description 19
- 239000004202 carbamide Substances 0.000 claims abstract description 17
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims abstract description 16
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims abstract description 14
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229910052791 calcium Inorganic materials 0.000 claims abstract description 14
- 229910052802 copper Inorganic materials 0.000 claims abstract description 14
- 229910052742 iron Inorganic materials 0.000 claims abstract description 14
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000004327 boric acid Substances 0.000 claims abstract description 13
- 229940038879 chelated zinc Drugs 0.000 claims abstract description 13
- 239000001397 quillaja saponaria molina bark Substances 0.000 claims abstract description 13
- 229930182490 saponin Natural products 0.000 claims abstract description 13
- 150000007949 saponins Chemical class 0.000 claims abstract description 13
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 claims abstract description 12
- 229930195725 Mannitol Natural products 0.000 claims abstract description 12
- 239000000594 mannitol Substances 0.000 claims abstract description 12
- 235000010355 mannitol Nutrition 0.000 claims abstract description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 11
- APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 claims abstract description 10
- 239000011609 ammonium molybdate Substances 0.000 claims abstract description 10
- 235000018660 ammonium molybdate Nutrition 0.000 claims abstract description 10
- 229940010552 ammonium molybdate Drugs 0.000 claims abstract description 10
- ZPWVASYFFYYZEW-UHFFFAOYSA-L dipotassium hydrogen phosphate Chemical compound [K+].[K+].OP([O-])([O-])=O ZPWVASYFFYYZEW-UHFFFAOYSA-L 0.000 claims abstract description 10
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims abstract description 10
- 238000002156 mixing Methods 0.000 claims abstract description 4
- 235000009434 Actinidia chinensis Nutrition 0.000 claims description 75
- 235000021028 berry Nutrition 0.000 claims description 74
- 235000013399 edible fruits Nutrition 0.000 claims description 67
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 42
- 238000002386 leaching Methods 0.000 claims description 30
- 229910052757 nitrogen Inorganic materials 0.000 claims description 27
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 21
- 229940072033 potash Drugs 0.000 claims description 21
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims description 21
- 235000015320 potassium carbonate Nutrition 0.000 claims description 21
- 239000013522 chelant Substances 0.000 claims description 10
- 239000011572 manganese Substances 0.000 claims description 9
- 244000131522 Citrus pyriformis Species 0.000 claims description 8
- 229910052700 potassium Inorganic materials 0.000 claims description 8
- 239000011701 zinc Substances 0.000 claims description 8
- 235000005979 Citrus limon Nutrition 0.000 claims description 7
- 239000002253 acid Substances 0.000 claims description 7
- 230000004044 response Effects 0.000 claims description 6
- 230000002459 sustained effect Effects 0.000 claims description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 claims description 5
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 5
- 229910052748 manganese Inorganic materials 0.000 claims description 5
- -1 phosphoric acid hydrogen Chemical class 0.000 claims description 5
- 241000219068 Actinidia Species 0.000 claims description 4
- 238000006243 chemical reaction Methods 0.000 claims description 4
- 230000035484 reaction time Effects 0.000 claims description 4
- OAVRWNUUOUXDFH-UHFFFAOYSA-H 2-hydroxypropane-1,2,3-tricarboxylate;manganese(2+) Chemical group [Mn+2].[Mn+2].[Mn+2].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O.[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O OAVRWNUUOUXDFH-UHFFFAOYSA-H 0.000 claims description 3
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 3
- BDXBEDXBWNPQNP-UHFFFAOYSA-L copper;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate;hydron Chemical compound [Cu+2].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O BDXBEDXBWNPQNP-UHFFFAOYSA-L 0.000 claims description 3
- FWBOFUGDKHMVPI-UHFFFAOYSA-K dicopper;2-oxidopropane-1,2,3-tricarboxylate Chemical group [Cu+2].[Cu+2].[O-]C(=O)CC([O-])(C([O-])=O)CC([O-])=O FWBOFUGDKHMVPI-UHFFFAOYSA-K 0.000 claims description 3
- 239000001257 hydrogen Substances 0.000 claims description 3
- 229910052739 hydrogen Inorganic materials 0.000 claims description 3
- 239000011564 manganese citrate Substances 0.000 claims description 3
- 235000014872 manganese citrate Nutrition 0.000 claims description 3
- 229940097206 manganese citrate Drugs 0.000 claims description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-N phosphoric acid Substances OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 3
- WFIZEGIEIOHZCP-UHFFFAOYSA-M potassium formate Chemical compound [K+].[O-]C=O WFIZEGIEIOHZCP-UHFFFAOYSA-M 0.000 claims description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 2
- 229910052725 zinc Inorganic materials 0.000 claims description 2
- 244000298715 Actinidia chinensis Species 0.000 claims 16
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 2
- 235000009508 confectionery Nutrition 0.000 claims 2
- 241000040710 Chela Species 0.000 claims 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 abstract description 21
- 230000000694 effects Effects 0.000 abstract description 13
- 238000001914 filtration Methods 0.000 abstract description 6
- 231100000674 Phytotoxicity Toxicity 0.000 abstract description 5
- 244000269722 Thea sinensis Species 0.000 abstract description 2
- 238000010521 absorption reaction Methods 0.000 abstract description 2
- 239000005979 Forchlorfenuron Substances 0.000 abstract 1
- DHKHZGZAXCWQTA-UHFFFAOYSA-N [N].[K] Chemical compound [N].[K] DHKHZGZAXCWQTA-UHFFFAOYSA-N 0.000 abstract 1
- 230000009920 chelation Effects 0.000 abstract 1
- 229910000396 dipotassium phosphate Inorganic materials 0.000 abstract 1
- 235000019797 dipotassium phosphate Nutrition 0.000 abstract 1
- GPXLRLUVLMHHIK-UHFFFAOYSA-N forchlorfenuron Chemical compound C1=NC(Cl)=CC(NC(=O)NC=2C=CC=CC=2)=C1 GPXLRLUVLMHHIK-UHFFFAOYSA-N 0.000 abstract 1
- LWIHDJKSTIGBAC-UHFFFAOYSA-K potassium phosphate Substances [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 abstract 1
- 239000007788 liquid Substances 0.000 description 9
- 239000003795 chemical substances by application Substances 0.000 description 8
- 235000015165 citric acid Nutrition 0.000 description 8
- 230000008961 swelling Effects 0.000 description 8
- 238000000034 method Methods 0.000 description 6
- 235000015097 nutrients Nutrition 0.000 description 6
- 239000007787 solid Substances 0.000 description 4
- 238000010998 test method Methods 0.000 description 4
- 244000144730 Amygdalus persica Species 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 3
- 235000006040 Prunus persica var persica Nutrition 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 239000002366 mineral element Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 2
- 241000282553 Macaca Species 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000004069 differentiation Effects 0.000 description 2
- WHYUWYVXDNNLTR-UHFFFAOYSA-J dizinc;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Zn+2].[Zn+2].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O WHYUWYVXDNNLTR-UHFFFAOYSA-J 0.000 description 2
- 239000000796 flavoring agent Substances 0.000 description 2
- 235000019634 flavors Nutrition 0.000 description 2
- 230000004345 fruit ripening Effects 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 230000035800 maturation Effects 0.000 description 2
- VLAPMBHFAWRUQP-UHFFFAOYSA-L molybdic acid Chemical compound O[Mo](O)(=O)=O VLAPMBHFAWRUQP-UHFFFAOYSA-L 0.000 description 2
- 235000016709 nutrition Nutrition 0.000 description 2
- 230000029553 photosynthesis Effects 0.000 description 2
- 238000010672 photosynthesis Methods 0.000 description 2
- 239000005648 plant growth regulator Substances 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- WGIWBXUNRXCYRA-UHFFFAOYSA-H trizinc;2-hydroxypropane-1,2,3-tricarboxylate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O.[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O WGIWBXUNRXCYRA-UHFFFAOYSA-H 0.000 description 2
- 239000011746 zinc citrate Substances 0.000 description 2
- 235000006076 zinc citrate Nutrition 0.000 description 2
- 229940068475 zinc citrate Drugs 0.000 description 2
- LUBJCRLGQSPQNN-UHFFFAOYSA-N 1-Phenylurea Chemical class NC(=O)NC1=CC=CC=C1 LUBJCRLGQSPQNN-UHFFFAOYSA-N 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- 241000282693 Cercopithecidae Species 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 239000004471 Glycine Substances 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 1
- QPSDTTKZPURNIB-UHFFFAOYSA-N NC(=O)N.N1C=CC=C1.[Cl] Chemical compound NC(=O)N.N1C=CC=C1.[Cl] QPSDTTKZPURNIB-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 description 1
- 229910000387 ammonium dihydrogen phosphate Inorganic materials 0.000 description 1
- 229930002877 anthocyanin Natural products 0.000 description 1
- 235000010208 anthocyanin Nutrition 0.000 description 1
- 239000004410 anthocyanin Substances 0.000 description 1
- 150000004636 anthocyanins Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000035558 fertility Effects 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 235000001727 glucose Nutrition 0.000 description 1
- 230000012010 growth Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 229910001425 magnesium ion Inorganic materials 0.000 description 1
- SWHAQEYMVUEVNF-UHFFFAOYSA-N magnesium potassium Chemical compound [Mg].[K] SWHAQEYMVUEVNF-UHFFFAOYSA-N 0.000 description 1
- 238000007726 management method Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 235000019837 monoammonium phosphate Nutrition 0.000 description 1
- 229910000402 monopotassium phosphate Inorganic materials 0.000 description 1
- 235000019796 monopotassium phosphate Nutrition 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 230000035764 nutrition Effects 0.000 description 1
- 230000000050 nutritive effect Effects 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- PJNZPQUBCPKICU-UHFFFAOYSA-N phosphoric acid;potassium Chemical compound [K].OP(O)(O)=O PJNZPQUBCPKICU-UHFFFAOYSA-N 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 230000002786 root growth Effects 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000001502 supplementing effect Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- 210000002700 urine Anatomy 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B7/00—Fertilisers based essentially on alkali or ammonium orthophosphates
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Fertilizers (AREA)
Abstract
The invention relates to a fertilizer special for soaked kiwi fruits and a preparation method thereof, and belongs to the field of fertilizers for kiwi fruits. The preparation method of the special fertilizer after the kiwi fruit is soaked comprises the following steps: a. chelating magnesium nitrate, citric acid and water to obtain a first solution; b. mixing urea, chelated calcium, chelated iron, chelated manganese, chelated zinc, chelated copper, ammonium molybdate, boric acid and nitrogen-potassium fertilizer with the first solution, and reacting at 60-70 ℃ for 20-90 minutes to obtain a second solution; c. adding dipotassium phosphate and mannitol into the second solution, and carrying out chelation for 30-60 minutes at constant temperature of 60-70 ℃ to obtain a third solution; d. and (3) reducing the temperature of the third solution to 40-50 ℃, adding the tea saponin into the third solution, mixing and filtering to obtain the fertilizer special for the soaked kiwi fruits. The special fertilizer has high absorption and utilization rate and obvious effect of improving the phytotoxicity of the forchlorfenuron.
Description
Technical field
The present invention relates to special fertilizers after Kiwi berry leaching fruit and preparation method thereof, belong to Kiwi berry fertilizer field.
Background technique
At the beginning of since the 1990s, external source plant growth regulator i.e. swelling agent are as a kind of important
Yield-increasing technology, the application of large area in Kiwi berry plantation.Chloropyuril abbreviation CPPU (the chloro- 4- pyridyl group benzene-N- phenyl of N-2-
Urea), it is a kind of exogenous plant growth regulator filtered out from phenylurea derivatives.Chloropyuril i.e. swelling agent are as a kind of
Important volume increase, the application of large area in Kiwi berry plantation.Chloropyuril function and effect on Kiwi berry show as promoting cell
The effects of division, differentiation and expansion, have and promote bud differentiation, flower and fruit protecting, improve percentage of fertile fruit and promote Fruit.But
Be, there are unilateral pursuit Kiwi berry yield and to increase dosage, leaching fruit uneven and be used for a long time, make Kiwi berry
There is a series of problem in quality, occurs hollow, flavor and nutritional ingredient reduction, fruit inside fruit such as after fruit maturation
Deformity is expanded, the hardness of fruit declines, is shortened intolerant to transport and storage period.
It is badly in need of a kind of new-type fertilizer birth that " chloropyuril poison can be solved " based on above counter productive.And it marks on the market
The special fertilizer for Chinese goosebeery of note is the nutrient for supplementing Kiwi growth and needing, and fails to have reduction and reduces chloropyuril in Mi
The effect of the counter productive of monkey peach.
A kind of Kiwi berry liquid is disclosed application No. is 2014107797221 Chinese patent and expands Resource, this is specially
Benefit is to study the early stage of the present inventor.The Kiwi berry liquid expands the component of Resource are as follows: its active constituent is by sulphur
Sour potassium magnesium and the chelate of glycine, the chelate of potassium dihydrogen phosphate and mannitol, ammonium dihydrogen phosphate and glucose chelate,
Urea, EDTA-Zn, EDTA-Ca, EDTA-Cu, organic acid, boric acid and water soluble nonionic surfactant composition.But the battalion
Mixture is supported as the effect of Kiwi berry swelling agent and is not so good as chloropyuril, in order to keep Kiwi berry bigger, chloropyuril is still used as mainstream
Swelling agent.But after using chloropyuril, bring side effect is also more, which also can not be substantially reduced and reduce chlorine
Pyrrole urea is in the counter productive of Kiwi berry.
After therefore, it is necessary to a kind of Kiwi berrys using chloropyuril leaching fruit, the special fertilizer of chloropyuril side effect is prevented.
Summary of the invention
The invention solves first technical problem be to provide special fertilizer after a kind of Kiwi berry leaching fruit, which can be with
Chloropyuril is substantially reduced and reduced in the effect of the counter productive of Kiwi berry.
Kiwi berry soaks the preparation method of special fertilizer after fruit, is prepared according to the following steps:
A, 1~2 parts by weight magnesium nitrate, 1~3 parts by weight of lemon acid and 20~25 parts by weight water are chelated at 65~75 DEG C
30~120 minutes, obtain the first solution；
B, 3~4 parts by weight of urea, 1~2 parts by weight chelating calcium, 1~2 parts by weight chelated iron, 1~2 parts by weight are chelated
Manganese, 0~1 parts by weight chelated zinc, 0~1 parts by weight chelated copper, 0~1 parts by weight ammonium molybdate, 0~1 part by weight of boric acid, 20~25 weights
Amount part nitrogen potash fertilizer mixed with the first solution, and 60~70 DEG C sustained response 20~90 minutes, obtain the second solution；
C, 32~38 parts by weight of phosphoric acid hydrogen dipotassiums, 2~4 parts by weight mannitol are added in the second solution, and constant temperature is extremely
60~70 DEG C chelate 30~60 minutes, obtain third solution；
D, the temperature of third solution is down to 40~50 DEG C, 1~3 parts by weight Tea Saponin is added in third solution, mixed
It closes, filtering, obtains special fertilizer after Kiwi berry leaching fruit.
Preferably, magnesium nitrate, citric acid, urea, chelating calcium, chelated iron, Chelated Manganese, chelated zinc, chelated copper, ammonium molybdate,
Boric acid, nitrogen potash fertilizer, dipotassium hydrogen phosphate, mannitol, Tea Saponin weight ratio be 1~2:2~3:3~4:1~2:1~2:1~2:
0.5~1:0.5~1:0.5~1:0.5~1:20~25:32~38:2~4:1~3.
It is furthermore preferred that magnesium nitrate, citric acid, urea, chelating calcium, chelated iron, Chelated Manganese, chelated zinc, chelated copper, molybdic acid
Ammonium, boric acid, nitrogen potash fertilizer, dipotassium hydrogen phosphate, mannitol, Tea Saponin weight ratio be 2:2:4:1:2:1:0.5:0.5:0.5:0.5:
25:38:2:3。
Wherein: chelating calcium of the present invention is EDTA-Ca；Chelated iron is ironic citrate or EDTA-Fe；Chelated Manganese is lemon
Sour manganese or EDTA-Mn；Chelated zinc is zinc citrate or EDTA-Zn；Chelated copper is copper citrate or EDTA-Cu.
Preferred: the mass ratio of N and K is 1:2~4 in nitrogen potash fertilizer.
Preferred: nitrogen potash fertilizer is made of urea and potassium formate.
Preferred: in step a, chelates temperature is 75 DEG C, and the chelating time is 30min；In step b, reaction temperature is 70 DEG C,
Reaction time is 20min；In step c, chelates temperature is 60 DEG C, and the chelating time is 30min.
The invention solves second technical problem be to provide special fertilizer after a kind of Kiwi berry leaching fruit.The Kiwi berry leaching
Special fertilizer after fruit is prepared by the preparation method of special fertilizer after above-mentioned Kiwi berry leaching fruit.
The present invention also provides application of the special fertilizer in Kiwi berry plantation after Kiwi berry leaching fruit.Application method are as follows: in macaque
After peach is using chloropyuril leaching fruit, special fertilizer is sprayed on the blade face of actinidia tree or fruit after Kiwi berry is soaked fruit.
Beneficial effects of the present invention:
1, special fertilizer nutrient is abundant after Kiwi berry leaching fruit of the present invention, and nutritive element content is high.Each element is rationally matched
Than dark green, the promotion photosynthesis that can promote Kiwi berry root growth, promote plant leaf, the tree of Kiwi berry entirety is improved
Gesture.
2, the rational proportion of special fertilizer each element of the invention can promote it is mutual be absorbed and utilized, absorption rate
Height improves chloropyuril phytotoxicity significant effect by mineral element, shows as the hardness for increasing Kiwi berry, extends the shelf of Kiwi berry
Phase reduces hollow fruit rate, promotes quality and mouthfeel of Kiwi berry etc..
3, preparation method mode of the invention is simple, and low energy consumption, and the chelating time is short.
Specific embodiment
The invention solves first technical problem be to provide special fertilizer after a kind of Kiwi berry leaching fruit, which can be with
Chloropyuril is substantially reduced and reduced in the effect of the counter productive of Kiwi berry.
Kiwi berry soaks the preparation method of special fertilizer after fruit, is prepared according to the following steps:
A, 1~2 parts by weight magnesium nitrate, 1~3 parts by weight of lemon acid and 20~25 parts by weight water are chelated at 65~75 DEG C
30~120 minutes, obtain the first solution；
B, 3~4 parts by weight of urea, 1~2 parts by weight chelating calcium, 1~2 parts by weight chelated iron, 1~2 parts by weight are chelated
Manganese, 0~1 parts by weight chelated zinc, 0~1 parts by weight chelated copper, 0~1 parts by weight ammonium molybdate, 0~1 part by weight of boric acid, 20~25 weights
Amount part nitrogen potash fertilizer mixed with the first solution, and 60~70 DEG C sustained response 20~90 minutes, obtain the second solution；
C, 32~38 parts by weight of phosphoric acid hydrogen dipotassiums, 2~4 parts by weight mannitol are added in the second solution, and constant temperature is extremely
60~70 DEG C chelate 30~60 minutes, obtain third solution；
D, the temperature of third solution is down to 40~50 DEG C, 1~3 parts by weight Tea Saponin is added in third solution, mixed
It closes, filtering, obtains special fertilizer after Kiwi berry leaching fruit.
The present invention needs that above-mentioned steps is used to prepare: a step chelating is moderate-element, if all chelated together
Phosphate anion and magnesium ion are also easy to produce precipitating, influence the stability of solution.The advantages of substep chelates is the acid of each step system
Basicity is different, is conducive to each nutrient and thoroughly chelates.
Chelates temperature of the invention is relatively low, reduces costs.Within the scope of the temperature and time that the present invention limits, system
Standby special fertilizer solution is stablized.
The present invention improves chloropyuril phytotoxicity effect by mineral element.
The mineral elements such as calcium, boron, potassium apply adjustable Premeabilisation of cells gesture so as to cause the water swelling of cell, mention
The hardness of high kiwifruit fruit is to extend shelf life and the storage period of Kiwi berry.
Potassium, iron, magnesium, zinc etc. can activate sugar transhipment enzyme to increase crop photosynthesis, increase sugar product in fruit
It is tired, promote anthocyanin synthesis in fruit, promotes fruit color, aromatic substance accumulation, improve the quality and flavor of fruit.
The present invention can effectively improve the effective of each nutrient by each nutrient scientific matching and perfect combination
Property and compatibility, fertilizer efficiency be obviously improved, scientific prescription guarantees the nutrient demand of Kiwi berry expanding stage, realizes organic mesh expanded
Mark.If the proportion of ingredient is not within the scope of the invention, it is poor to improve chloropyuril phytotoxicity effect.
In order to further increase the performance that Kiwi berry of the present invention soaks special fertilizer after fruit, it is preferred that magnesium nitrate, citric acid, urine
Element, chelating calcium, chelated iron, Chelated Manganese, chelated zinc, chelated copper, ammonium molybdate, boric acid, nitrogen potash fertilizer, dipotassium hydrogen phosphate, mannitol, tea
The weight ratio of saponin be 1~2:2~3:3~4:1~2:1~2:1~2:0.5~1:0.5~1:0.5~1:0.5~1:20~
25:32~38:2~4:1~3.
It is furthermore preferred that magnesium nitrate, citric acid, urea, chelating calcium, chelated iron, Chelated Manganese, chelated zinc, chelated copper, molybdic acid
Ammonium, boric acid, nitrogen potash fertilizer, dipotassium hydrogen phosphate, mannitol, Tea Saponin weight ratio be 2:2:4:1:2:1:0.5:0.5:0.5:0.5:
25:38:2:3.Under the proportion, special fertilizer improvement chloropyuril phytotoxicity effect is best after Kiwi berry soaks fruit.
Wherein: chelating calcium of the present invention is EDTA-Ca；Chelated iron is ironic citrate or EDTA-Fe；Chelated Manganese is lemon
Sour manganese or EDTA-Mn；Chelated zinc is zinc citrate or EDTA-Zn；Chelated copper is copper citrate or EDTA-Cu.
Preferred: the mass ratio of N and K is 1:2~4 in nitrogen potash fertilizer.
Preferred: nitrogen potash fertilizer is made of urea and potassium formate.
Preferred: in step a, chelates temperature is 75 DEG C, and the chelating time is 30min；In step b, reaction temperature is 70 DEG C,
Reaction time is 20min；In step c, chelates temperature is 60 DEG C, and the chelating time is 30min.In the reaction temperature and reaction time
Special fertilizer after lower Kiwi berry leaching fruit obtained, it is solution-stabilized.
The invention solves second technical problem be to provide special fertilizer after a kind of Kiwi berry leaching fruit.The Kiwi berry leaching
Special fertilizer after fruit is prepared by the preparation method of special fertilizer after above-mentioned Kiwi berry leaching fruit.
The present invention also provides application of the special fertilizer in Kiwi berry plantation after Kiwi berry leaching fruit.Application method are as follows: in macaque
After peach is using chloropyuril leaching fruit, special fertilizer is sprayed on the blade face and fruit of actinidia tree after Kiwi berry is soaked fruit.This product is dilute
800-1500 times is released, first time administration time is consistent with chloropyuril administration time, interval is applied second, second for 10-15 days
The third time of application in 10-15 days is spaced after application.
A specific embodiment of the invention is further described below with reference to embodiment, is not therefore limited the present invention
System is among the embodiment described range.In following embodiment, the number of taken article refers both to parts by weight.
1 Kiwi berry of embodiment soaks the preparation of special fertilizer after fruit
A, 1 part of moderate-element magnesium nitrate, 3 parts of citric acids and 20 parts of water are chelated 30 minutes at 65 DEG C, it is molten obtains first
Liquid；
B, by 3 parts of urea, 2 parts of EDTA-Ca, 1 part of ironic citrate, 2 parts of manganese citrate, 1 part of EDTA-Zn, EDTA-Cu 1
Part, 1 part of ammonium molybdate, 1 part of boric acid, 20 parts of nitrogen potash fertilizer mixed with the first solution, and 60 DEG C sustained response 20 minutes, obtain second
Solution；Wherein, in nitrogen potash fertilizer, the mass ratio of N and K are 1:2；
C, 32 parts of dipotassium hydrogen phosphate, 4 parts of mannitol are added in the second solution, and constant temperature to 70 DEG C chelate 30 minutes,
Obtain third solution；
D, the temperature of third solution is down to 50 DEG C, 2 parts of Tea Saponin dissolved is added in third solution, stirring 2
Minute, it stands, filtering, obtains green translucent liquid, i.e. special fertilizer S1 after Kiwi berry leaching fruit.
2 Kiwi berry of embodiment soaks the preparation of special fertilizer after fruit
A, 2 parts of moderate-element magnesium nitrates, 2 parts of citric acids and 20 parts of water are chelated 30 minutes at 75 DEG C, it is molten obtains first
Liquid；
B, by 4 parts of urea, 1 part of EDTA-Ca, 2 parts of EDTA-Fe, 1 part of EDTA-Mn, 0.5 part of EDTA-Zn, citric acid
0.5 part of copper, 0.5 part of ammonium molybdate, 0.5 part of boric acid, 25 parts of nitrogen potash fertilizer mix with the first solution, and divide in 70 DEG C of sustained responses 20
Clock obtains the second solution；Wherein, in nitrogen potash fertilizer, the mass ratio of N and K are 1:3.5；
C, 38 parts of dipotassium hydrogen phosphate, 2 parts of mannitol are added in the second solution, and constant temperature to 60 DEG C chelate 30 minutes,
Obtain third solution；
D, the temperature of third solution is down to 50 DEG C, 3 parts of Tea Saponin dissolved is added in third solution, stirring 2
Minute, it stands, filtering, obtains green translucent liquid, i.e. special fertilizer S2 after Kiwi berry leaching fruit.
3 Kiwi berry of embodiment soaks the preparation of special fertilizer after fruit
A, 1 part of moderate-element magnesium nitrate, 3 parts of citric acids and 25 parts of water are chelated 30 minutes at 70 DEG C, it is molten obtains first
Liquid；
B, by 3 parts of urea, 1 part of EDTA-Ca, 1 part of ironic citrate, 1 part of manganese citrate, 20 parts of nitrogen potash fertilizer and the first solution
Mixing, and 65 DEG C sustained response 20 minutes, obtain the second solution；Wherein, in nitrogen potash fertilizer, the mass ratio of N and K are 1:2；
C, 36 parts of dipotassium hydrogen phosphate, 3 parts of mannitol are added in the second solution, and constant temperature to 65 DEG C chelate 30 minutes,
Obtain third solution；
D, the temperature of third solution is down to 50 DEG C, 2 parts of Tea Saponin dissolved is added in third solution, stirring 2
Minute, it stands, filtering, obtains green translucent liquid, i.e. special fertilizer S3 after Kiwi berry leaching fruit.
Comparative example 1
Using in the patent application No. is 2014107797221Embodiment 1A kind of Kiwi berry liquid is made and expands nutrition conjunction
Agent D1.
Application examples
1, test material
For studying object: Kiwi berry；
For trying fertilizer: S1, S2, S3, D1.
2, test method
Test setting 5 groups of processing methods, be respectively as follows: handled with S1, S2, S3, D1 fertilizer, clear water is handled.Every group
55 plants of actinidia trees are selected, Kiwi berry type is identical, and each group, which plants slot, has isolation to prevent from influencing each other, and soil fertility is consistent,
Other pest managements are consistent.The swelling agent of each group application uses chloropyuril, and the usage amount of swelling agent uses time and use
Concentration is all the same.
This product is the water base fertilizer of foliage spray type, and the specific application method of each group is as shown in table 1.
Table 1
2.1 investigation methods, content: the fruit hollow rate of Kiwi berry, soluble solids, VC content, storage period are adjusted
It looks into.
The test method of fruit hollow rate are as follows: cut observation fruit boring situation after Kiwi berry is mature, count hollow
Rate.
The test method of soluble solids are as follows: refractometer method.
The test method of VC content are as follows: 2,6-indophenols titrations.
2.2 control time
On the day before transverse and longitudinal stem control time first time is chloropyuril use, second of control time is after maturation is picked.Fruit
Occupied space heart rate, soluble solids, VC content, these index control times of storage period are after maturation is picked.
3. test results and analysis
Note: in table Lo indicate swelling agent chloropyuril use preceding 200 fruits average value, L1 be by A1, A2, A3, D1,
After CK processing, the average value of 200 fruits when fruit maturation.K is averagely to expand rate.Expand rate (K) calculation formula are as follows: K=
(L-L0)/L0。
Analysis: product made from Examples 1 to 3, comparative example 1 is used in the plantation of Kiwi berry, finds Examples 1 to 3
Product can preferably improve the harm of chloropyuril bring, compared to the product of comparative example 1, soluble solids, VC content, storage
Deposit that the phase is all higher, and hollow rate is smaller.And product produced by the present invention further increases the rate of expanding of Kiwi berry also.
Claims (10)
1. the preparation method that Kiwi berry soaks special fertilizer after fruit, which is characterized in that be prepared according to the following steps:
A, by 1~2 parts by weight magnesium nitrate, 1~3 parts by weight of lemon acid and 20~25 parts by weight water 65~75 DEG C chelate 30~
120 minutes, obtain the first solution；
B, by 3~4 parts by weight of urea, 1~2 parts by weight chelating calcium, 1~2 parts by weight chelated iron, 1~2 parts by weight Chelated Manganese, 0~
1 parts by weight chelated zinc, 0~1 parts by weight chelated copper, 0~1 parts by weight ammonium molybdate, 0~1 part by weight of boric acid, 20~25 parts by weight nitrogen
Potash fertilizer is mixed with the first solution, and 60~70 DEG C sustained response 20~90 minutes, obtain the second solution；
C, 32~38 parts by weight of phosphoric acid hydrogen dipotassiums, 2~4 parts by weight mannitol are added in the second solution, and constant temperature to 60~
70 DEG C chelate 30~60 minutes, obtain third solution；
D, the temperature of third solution is down to 40~50 DEG C, 1~3 parts by weight Tea Saponin is added in third solution, mixing, mistake
Filter obtains special fertilizer after Kiwi berry leaching fruit.
2. the preparation method of special fertilizer after Kiwi berry leaching fruit according to claim 1, which is characterized in that magnesium nitrate, lemon
Acid, urea, chelating calcium, chelated iron, Chelated Manganese, chelated zinc, chelated copper, ammonium molybdate, boric acid, nitrogen potash fertilizer, dipotassium hydrogen phosphate, sweet dew
Alcohol, Tea Saponin weight ratio be 1~2:2~3:3~4:1~2:1~2:1~2:0.5~1:0.5~1:0.5~1:0.5~1:
20~25:32~38:2~4:1~3.
3. the preparation method of special fertilizer after Kiwi berry leaching fruit according to claim 2, which is characterized in that magnesium nitrate, lemon
Acid, urea, chelating calcium, chelated iron, Chelated Manganese, chelated zinc, chelated copper, ammonium molybdate, boric acid, nitrogen potash fertilizer, dipotassium hydrogen phosphate, sweet dew
Alcohol, Tea Saponin weight ratio be 2:2:4:1:2:1:0.5:0.5:0.5:0.5:25:38:2:3.
4. described in any item Kiwi berrys soak the preparation method of special fertilizer after fruits according to claim 1~3, it is characterised in that: chela
Conjunction calcium is EDTA-Ca；Chelated iron is ironic citrate or EDTA-Fe；Chelated Manganese is manganese citrate or EDTA-Mn；Chelated zinc is lemon
Lemon acid zinc or EDTA-Zn；Chelated copper is copper citrate or EDTA-Cu.
5. described in any item Kiwi berrys soak the preparation method of special fertilizer after fruits according to claim 1~3, it is characterised in that: nitrogen
The mass ratio of N and K is 1:2~4 in potash fertilizer.
6. described in any item Kiwi berrys soak the preparation method of special fertilizer after fruits according to claim 1~3, it is characterised in that: nitrogen
Potash fertilizer is made of urea and potassium formate.
7. described in any item Kiwi berrys soak the preparation method of special fertilizer after fruits according to claim 1~6, it is characterised in that: step
In rapid a, chelates temperature is 75 DEG C, and the chelating time is 30min；In step b, reaction temperature is 70 DEG C, reaction time 20min；
In step c, chelates temperature is 60 DEG C, and the chelating time is 30min.
8. Kiwi berry soaks special fertilizer after fruit, which is characterized in that by special after the described in any item Kiwi berry leaching fruits of claim 1~7
It is prepared with the preparation method of fertilizer.
9. application of the special fertilizer in Kiwi berry plantation after Kiwi berry leaching fruit according to any one of claims 8.
10. application of the special fertilizer in Kiwi berry plantation after Kiwi berry leaching fruit according to claim 9, which is characterized in that
After Kiwi berry is using chloropyuril leaching fruit, special fertilizer is sprayed on the blade face of actinidia tree and fruit after Kiwi berry is soaked fruit.
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| FR3108531A1 (en) * | 2020-03-30 | 2021-10-01 | Total Marketing Services | Homogeneous copper-based fluid for depollution of heat engines |
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Application publication date: 20190226 |