A kind of flue gas temperature adjustment gametic fertility integral system
Technical field
The present invention relates to a kind of flue gas temperature adjustment gametic fertility integral systems, belong to the denitrating flue gas neck of sintering or coke oven
Domain.
Background technique
In recent years, the Air Pollution Control of non-electrical industry has become the emphasis emission reduction object after power industry.From
Regulation in " coking chemistry emission of industrial pollutants standard " (GB16171-2012) of execution from January, 2015: general area is burnt
Furnace chimney smoke particulate matter, SO2, NOx emission concentration need to be lower than 30mg/m3、50mg/m3、500mg/m3;Key area need to be lower than
15mg/m3、30mg/m3、150mg/m3。
In May, 2018 publication about soliciting " iron and steel enterprise's minimum discharge retrofit work scheme (exposure draft) " opinion
Letter proposes and steel industry minimum discharge transformation requirement plan is pushed to be strict controlled in the NOx emission concentration in sintering flue gas
50mg/m3Within, huge environmental protection pressure is brought to iron and steel enterprise.2018, " the steel and iron industry atmosphere pollution of each place publication
Minimum discharge standard ", " coking chemistry industrial air pollution minimum discharge standard ", " it is dirty to execute atmosphere about some importance city
Dye object especially discharges the bulletin of limitation ", the files such as " steel and iron industry atmosphere pollution minimum discharge standard (exposure draft) " make
The pollutant minimum discharge transformation for obtaining steel industry is extremely urgent.This means that China will enter extensive control non-electrical industry
The important stage of NOx emission.
In the past few decades, power industry has accumulated a large amount of advanced and mature experiences, especially SCR in denitrating flue gas field
(selective catalytic reduction) denitration technology, can economical and efficient removing nitrogen oxides.However, sintering, coke oven flue gas feature are not
It is same as power industry.Sintering flue gas converges rear smoke temperature and is generally below 200 DEG C, and coke oven flue gas temperature range is 180~230 DEG C, and
It is not achieved 320~450 DEG C of temperature window of SCR denitration technology catalytic denitration, brings huge challenge to steel industry denitrating flue gas.It adopts
With external high temperature flue gas to sintering, coke oven flue gas heats, be currently used Conventional solutions.However, external ammonia
It is mixed that the quick blending of (or ammonium hydroxide), high-temperature flue gas and sintering (or coke oven) low-temperature flue gas is related to big section, short-range component
Conjunction problem, the uniformity of flue-gas temperature distribution and ammonia density distribution significantly affects denitration efficiency after mixing, is that whole system is thrown
Transport the key of success or not.Previous research, it is most to be all provided separately hot wind blending system and spray ammonia system.Hot wind blending is adopted
With the technology of single port or more mouthfuls of jet mixings, mixed effect is poor, reaches SCR inlet even across the optimization of structure, after mixing and cuts
The maximum temperature deviation in face is also up to 40 DEG C, and also adversely affects to being uniformly distributed for velocity field, has seriously affected system
Denitration efficiency.In addition, spray ammonia system uses ammonia-spraying grid, system includes air mixer, liquefied ammonia station, dilution air etc., system
Complexity, O&M cost are higher.
Summary of the invention
The present invention is intended to provide a kind of flue gas temperature adjustment gametic fertility integral system, using ammonia water spray gun, in hot blast manifold
The interior evaporation for realizing ammonium hydroxide, is mixed into hot wind, and hot wind is followed to enter hot wind mixing device together, is designed using isobaric design concept
It is uniform to guarantee that hot wind initially sprays point in big section flue for hot wind matching air box and hot wind mixing device, are subsequent hot wind, ammonia
Diffusion blending of the gas in flue gas provides guarantee, and completes being sufficiently mixed for each flue gas composition by high-efficiency low-resistance static mixer
And coke oven or sintering machine low exit temperature flue gas are evenly heated.
The invention is realized by the following technical scheme:
A kind of flue gas temperature adjustment gametic fertility integral system, including hot-blast stove and boiler flue and setting are in boiler flue
Interior SCR device, the boiler flue include sequentially connected low temperature flue section, high-temperature flue section and low-temperature outlet flue, institute
High-temperature flue section is stated to be arranged in Π type;The hot-blast stove by hot air duct be connected to the boiler flue low temperature flue section and
Between high-temperature flue section;The hot air duct is provided with ammonia water spray gun, and the hot air duct is located at the hot wind of boiler flue and goes out
Mouth is provided with constant pressure mixing device.
In above-mentioned technical proposal, the hot air duct is provided with sequentially connected isobaric matching air box and the distribution of several hot winds
Pipe, several described hot wind distribution pipes are evenly distributed, and connect with the isobaric matching air box;The constant pressure mixing device is arranged in institute
State hot wind distribution pipe outlet end;The ammonia water spray gun is arranged in a one-to-one correspondence several with the hot wind distribution pipe.
In above-mentioned technical proposal, the hot wind distribution pipe is linear type, L shape or " inverted L " shape, the equipressure matching air box
The vertical section entrance side of the hot wind distribution pipe is set, and the horizontal segment of the hot wind distribution pipe is arranged in the constant pressure mixing device
Outlet side.
In above-mentioned technical proposal, hot blast flow direction is from front to back along the isobaric matching air box for several described hot wind distribution pipes
It equidistantly distributes;The equipressure matching air box cross-sectional flow area is successively decreased step by step along hot blast flow direction, so that hot blast flow direction is quiet
Pressure head distribution is impartial.
In above-mentioned technical proposal, the spacing of two neighboring hot wind distribution pipe is 1~3m.
In above-mentioned technical proposal, the ammonia water spray gun is inclined in the hot wind distribution pipe, center axis thereof direction
It is 0~150 ° with flue gas flow direction angle.
In above-mentioned technical proposal, the system also includes static mixer, the static mixer is arranged in the high temperature
Flue section is located at constant pressure mixing device downstream.
In above-mentioned technical proposal, the static mixer includes support rod and the symmetrically arranged turbulence blades of guiding;It is described
Support rod is tubulose or plate;The turbulence blades are round, ellipse or polygon.
In above-mentioned technical proposal, the system also includes flue gas heat-exchange unit, the flue gas heat-exchange unit selects rotary heat exchange
Device, while the high-temperature flue gas heat that in low temperature flue section and high-temperature flue section, high-temperature flue Duan Zhongcong SCR device is come out is set
The low-temperature flue gas of low temperature flue section is passed to after recycling.
In above-mentioned technical proposal, the constant pressure mixing device includes isobaric aid distributing pipe and is arranged on the isobaric aid distributing pipe
Hot air spout;The equipressure aid distributing pipe and the hot wind distribution pipe have been arranged in a one-to-one correspondence several;Each isobaric air distribution
Pipe cross-sectional flow area is successively decreased step by step along hot blast flow direction, so that the hydrostatic head of hot blast flow direction is distributed equalization;The equipressure air distribution
Pipe is arranged to 8~10m/s of design current velocity in pipe;The hot air spout is arranged to 20~30m/s of hot wind design current velocity.
In above-mentioned technical proposal, the hot air spout is provided with several, several hot air spouts are along isobaric aid distributing pipe
Trapezoidal short transverse is evenly arranged, and former and later two adjacent hot air spouts are at a distance of 0.5~1.5m.
As a kind of prioritization scheme, several are arranged in the hot air spout, and every two hot air spout is one group, composition heat
Two hot air spout air-out directions of wind snout group, each group of hot air spout group are opposite, towards perpendicular with trapezoidal height two
A direction;The hot air spout group is evenly arranged along the trapezoidal short transverse of isobaric aid distributing pipe, and the adjacent hot wind spray in two groups of front and back
Mouth group is at a distance of 0.5~1.5m.
In above-mentioned technical proposal, the Π shape horizontal segment two sides of the high-temperature flue section are provided with deflector.
The present invention has the following advantages and beneficial effects: 1) mixing spray ammonia and combined with hot wind blending, cancellation involves great expense
Ammonia-spraying grid and spray ammonia dilution air, simplify system structure, significantly reduce project cost;2) it is set using isobaric air distribution principle
Hot wind distribution bellows and hot wind-flue gas-ammonia mixing device are counted, and by flue optimization design, ensure that from structure design
Smoke temperature, ammonia are uniformly distributed, and reduce hot wind, flue gas, ammonia blending system resistance.
Detailed description of the invention
Fig. 1 is the flue gas temperature adjustment gametic fertility integral system signal of one of embodiment according to the present invention
Figure.
Fig. 2 is the flue gas temperature adjustment gametic fertility integral system schematic diagram of another embodiment according to the present invention.
Fig. 3 is the flue gas temperature adjustment gametic fertility integral system schematic diagram of another embodiment according to the present invention.
Fig. 4 be the isobaric bellows of flue gas temperature adjustment gametic fertility integral system according to the present invention, hot wind distribution pipe and
Constant pressure mixing device connection schematic diagram.
Fig. 5 is the schematic side view of Fig. 4.
Fig. 6 is the constant pressure mixing device structural schematic diagram of flue gas temperature adjustment gametic fertility integral system according to the present invention.
Fig. 7 is the static mixer structure schematic diagram of flue gas temperature adjustment gametic fertility integral system according to the present invention.
In figure: 1-hot-blast stove;2-isobaric matching air boxs;3-hot wind distribution pipes;4-constant pressure mixing devices;41-isobaric air distributions
Pipe;42-hot air spouts;5-low temperature flue sections;6-flue gas heat-exchange units;7-high-temperature flue sections;8-static mixers;81―
Support rod;82-turbulence blades;9-deflectors;10-SCR devices;11-low-temperature outlet flues;12-ammonia water spray guns.
Specific embodiment
A specific embodiment of the invention and the course of work are further described with reference to the accompanying drawing.
The positional terms such as the upper, lower, left, right, front and rear in present specification be positional relationship based on the figure and
It establishes.Attached drawing is different, then corresponding positional relationship is also possible to change therewith, therefore cannot be interpreted as with this to protection model
The restriction enclosed.
As shown in Figure 1 to Figure 3, a kind of flue gas temperature adjustment gametic fertility integral system, including hot-blast stove 1, boiler flue with
And the SCR device 10 in boiler flue is set.Boiler flue includes sequentially connected low temperature flue section 5,7 and of high-temperature flue section
Low-temperature outlet flue 11.High-temperature flue section 7 is arranged in Π shape, and the descending branch of Π shape high-temperature flue section is arranged in SCR device 10.
Hot-blast stove 1 is connected between the low temperature flue section 5 of boiler flue and high-temperature flue section 7 by hot air duct, to be
System provides hot wind, that is, high-temperature flue gas.Hot air duct is provided with ammonia water spray gun 12, provides reducing agent NH for denitrating system3, and heat
The hot-blast outlet that air piping is located at boiler flue is provided with constant pressure mixing device 4, to guarantee hot wind, ammonia, flue gas in big section
Short distance in flue uniformly blends rapidly.
As the technical solution advanced optimized, hot air duct is provided with sequentially connected isobaric matching air box 2 and several
Hot wind distribution pipe 3.Several hot wind distribution pipes 3 are evenly distributed, and connect with isobaric matching air box 2.Isobaric matching air box 2 is trapezoidal
Setting.Constant pressure mixing device 4 is arranged in 3 outlet end of hot wind distribution pipe.
Hot wind distribution pipe 3 is equidistant straight up from isobaric matching air box 2, downwards or it is horizontal draw, respectively such as Fig. 1, Fig. 3 and
Shown in Fig. 2, the spacing of adjacent hot wind distribution pipe 3 is 1~3m.When hot wind distribution pipe 3 is upwardly or downwardly to draw, hot wind point
Piping 3 is L shape or inverted L-shaped, and the vertical section entrance side of hot wind distribution pipe 3 is arranged in isobaric matching air box 2, and constant pressure mixing device 4 is arranged
In the horizontal segment outlet side of hot wind distribution pipe 3.
Ammonia water spray gun 12 is arranged in a one-to-one correspondence several with hot wind distribution pipe 3.Ammonia water spray gun 12 is inclined at hot wind point
In piping 3, center axis thereof direction and flue gas flow direction angle are 0~150 °.Also that is, the spray centerline direction of ammonium hydroxide and flue gas
Flowing to angle is 0~150 °, and the atomization radius of ammonia water spray gun will cover the pipeline section of entire hot wind distribution pipe, to guarantee ammonia
The uniform premix of water.
Hot-blast stove 1 and isobaric matching air box 2 are arranged in side air admission, and several hot wind distribution pipes 3 are along isobaric matching air box 2
Interior hot blast flow direction equidistantly distributes, for the equal allocation of the amount of air for realizing each hot wind distribution pipe 3, using each hot wind distribution pipe 3 as one
Grade, isobaric 2 cross-sectional flow area of matching air box are successively decreased step by step along hot blast flow direction, so that the hydrostatic head distribution of hot blast flow direction is equal
Deng.
One of embodiment as shown in Figure 4, hot wind distribution pipe 3 are arranged in inverted L-shaped, and isobaric matching air box 2 is trapezoidal,
Several hot wind distribution pipes 3 are successively equidistantly connected on isobaric matching air box 2 along trapezoidal tapered direction.Hot wind distribution pipe 3 goes out
Mouth end is connected with constant pressure mixing device 4.
As shown in Figure 5 and Figure 6, constant pressure mixing device 4 includes the heat that equipressure aid distributing pipe 41 and is arranged on isobaric aid distributing pipe 41
Wind snout 42.Isobaric aid distributing pipe 41 is arranged in a one-to-one correspondence with hot wind distribution pipe 3.The isobaric trapezoidal tapered setting of aid distributing pipe 41,
Cross-sectional area most big end and the outlet of hot wind distribution pipe 3 connect.Hot air spout 42 is provided with several, several 42 edges of hot air spout
The isobaric trapezoidal short transverse of aid distributing pipe 41 be evenly arranged, and former and later two adjacent hot air spouts 42 are at a distance of 0.5~1.5m.As
A kind of prioritization scheme, hot air spout 42 two are one group of composition hot air spout group, and two hot winds of each hot air spout group spray
42 air-out directions of mouth are opposite, towards the both direction perpendicular with trapezoidal height.Hot air spout group is along isobaric 41 ladder of aid distributing pipe
Shape short transverse is evenly arranged, and the adjacent hot air spout group in two groups of front and back is at a distance of 0.5~1.5m.
Correspondingly, isobaric aid distributing pipe 41 cross-sectional flow face corresponding with several hot air spouts or hot air spout group arrangement
Product is successively decreased step by step along hot blast flow direction, so that the hydrostatic head of hot blast flow direction is distributed equalization.Preferably, isobaric aid distributing pipe 41 is arranged to
8~10m/s of design current velocity, hot air spout 42 are arranged to 20~30m/s of hot wind design current velocity in managing.
System further includes static mixer 8, and the setting of static mixer 8 is located under constant pressure mixing device 4 in high-temperature flue section 7
Trip.7 cross section of high-temperature flue section from constant pressure mixing device 4 to static mixer 8 is tapered.As shown in fig. 7, static mixer 8 wraps
It includes support rod 81 and is oriented to symmetrically arranged turbulence blades 82.Support rod 81 is tubulose or plate;Turbulence blades 82 are round, ellipse
Round or polygon.Several groups are arranged in turbulence blades 82, and it is opposite that two adjacent groups stream blade guiding.
The Π shape horizontal segment two sides of high-temperature flue section 7 are additionally provided with deflector 9.
The hot wind (high-temperature flue gas) that hot-blast stove 1 generates is evenly distributed to hot wind distribution pipe 3 by isobaric matching air box 2.Ammonium hydroxide
Hot wind distribution pipe 3 is sprayed into from ammonia water spray gun 12, by hot wind (high-temperature flue gas) heating evaporation and is carry into isobaric aid distributing pipe 41,
High-temperature flue section 7 is sprayed into from hot air spout 42.Flue gas to be processed enters high-temperature flue section 7 from low temperature flue section 5, in constant pressure mixing
Device 4 is mixed with the hot wind containing ammonia (high-temperature flue gas) sprayed into from hot air spout 42, is entered after tapered high-temperature flue gas section 7 static mixed
Clutch, being further uniformly mixed with hot wind containing ammonia becomes hot fume containing ammonia.The hot fume containing ammonia being then sufficiently mixed is in deflector 9
Water conservancy diversion under, into denitration in SCR device 10 after pass through 11 discharge system of low-temperature outlet flue.
As a kind of prioritization scheme, system is additionally provided with flue gas heat-exchange unit 6, and flue gas heat-exchange unit 6 selects rotary type heat exchanger,
Setting simultaneously is in low temperature flue section 5 and high-temperature flue section 7, the high-temperature flue gas heat that will be come out in high-temperature flue section 7 from SCR device 10
The low-temperature flue gas that low temperature flue section 5 is passed to after amount recycling realizes the first order heating of low-temperature flue gas.And from constant pressure mixing device 4
The high-temperature flue gas of entrance is directly blended with the flue gas after the heating of 6 first order of heat exchanger, realizes the second level liter of low-temperature flue gas
Temperature, to guarantee that flue-gas temperature reaches 300 DEG C of SCR denitration reaction temperature window or more.
From the low-temperature flue gas of 11 discharge system of low-temperature outlet flue, the cold source that can be used as hot-blast stove 1 is heated.
The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention, for the skill of this field
For art personnel, the invention may be variously modified and varied.All within the spirits and principles of the present invention, made any to repair
Change, equivalent replacement, improvement etc., should all be included in the protection scope of the present invention.