Specific embodiment
Present invention is generally directed to traditional high-frequency triode structures, and problem complex, that manufacture difficulty is high provides a kind of solution
Certainly scheme.
It is clear in order to be more clear the purpose of the present invention, technical solution and advantageous effects, below in conjunction with this hair
Attached drawing in bright embodiment, technical scheme in the embodiment of the invention is clearly and completely described, it is clear that described
Embodiment is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field
Those of ordinary skill's every other embodiment obtained without making creative work, belongs to protection of the present invention
Range.
In the description of the present invention, it should be noted that term " center ", "upper", "lower", "left", "right", "vertical",
The orientation or positional relationship of the instructions such as "horizontal", "inner", "outside" is to be based on the orientation or positional relationship shown in the drawings, or be somebody's turn to do
Invention product using when the orientation or positional relationship usually put, be merely for convenience of description of the present invention and simplification of the description, without
It is that the device of indication or suggestion meaning or element must have a particular orientation, be constructed and operated in a specific orientation, therefore not
It can be interpreted as limitation of the present invention.In addition, term " first ", " second ", " third " etc. are only used for distinguishing description, and cannot manage
Solution is indication or suggestion relative importance.
Referring to Fig. 2, a kind of high-frequency triode comprising:
The substrate 10 of first conduction type;
Positioned at the epitaxial layer 20 of the first conduction type of the upper surface of the substrate 10, is formed in the epitaxial layer 20
The outer base areas 21 of two conduction types and connect the outer base area 21 the second conduction type base area 22, the in the outer base area 21
The doping concentration of the impurity of two conduction types is higher than the doping concentration of the impurity of the second conduction type in the base area 22;The base
The emitter region 23 of the first conduction type is also formed in area 22;
Polysilicon island 30 positioned at the upper surface of the epitaxial layer 20, the polysilicon island 30 include and the outer base area 21
First base polysilicon 31 of the impurity of connection and the second conduction type of doping;
Positioned at the epitaxial layer 20 upper surface and thickness be greater than or equal to the polysilicon island 30 height dielectric layer
40, the contact hole 41 of the dielectric layer 40 is formed through in the dielectric layer 40, the contact hole 41 includes the corresponding hair
The emitter contact hole 411 in area 23 is penetrated, the hair of the impurity filled with the first conduction type of doping in the emitter contact hole 411
Emitter polysilicon 421, the upper surface of the emitter-polysilicon 421 are covered with the second metal silicide layer 431;
Base stage 51 and emitter 52 positioned at the upper surface of the dielectric layer 40, the base stage 51 and the polysilicon island 30
Connection, the emitter 52 are connect with the emitter-polysilicon 421;
Collector 53 positioned at the lower surface of the substrate 10.
In high-frequency triode of the present invention, the emitter-polysilicon 421 can reduce the surface recombination of emitter region 23
Speed increases current gain, can also form an ultra shallow emitter junction, promotes triode frequency;Under the outer base area 21 and emitter junction
The base area 22 of side connects, and reduces base resistance;It is compared to traditional high-frequency triode, high-frequency triode of the present invention
Collector 53 directly from the back side of the substrate 10 draw, eliminate buried layer and phosphorus bridge technique, save process costs and core
Piece area;Field oxide is eliminated in high-frequency triode of the present invention, and connects the first base stage polycrystalline of the outer base area 21
Silicon 31 it is smaller, the integrated level of the high-frequency triode is higher, and the current capacity of device is stronger under unit area.
Referring to Fig. 3, a kind of production method of high-frequency triode comprising following steps:
S01: the substrate 10 of the first conduction type is provided, and in one conduction type of upper surface growth regulation of the substrate 10
Epitaxial layer 20;
S02: in the one polysilicon layer 30a of upper surface growth regulation of the epitaxial layer 20;
S03: the impurity of the second conduction type is injected to the first polysilicon layer 30a and in first polysilicon layer
Polysilicon doped regions 30c is formed in 30a;
S04: carrying out partial penetration etching to the first polysilicon layer 30a and forms the upper table positioned at the epitaxial layer 20
The polysilicon island 30 in face;
S05: high-temperature heat treatment makes the impurity of the second conduction type in the polysilicon doped regions 30c described first
The first base of the impurity of the second conduction type of doping is spread and converted the first polysilicon layer 30a in polysilicon layer 30a
Pole polysilicon 31, while the impurity diffusion of second conduction type into the epitaxial layer 20 and is formed positioned at the epitaxial layer
The outer base area 21 of the second conduction type in 20;
S06: to the impurity of 20 the second conduction type of part doping of the epitaxial layer, formed be located in the epitaxial layer 20 and
The base area 22 of the second conduction type of the outer base area 21 is connected, the doping of the impurity of second conduction type is dense in the base area 22
Doping concentration of the degree lower than the impurity of the second conduction type in the outer base area 21;
S07: it is greater than or equal to Jie of the height of the polysilicon island 30 in the upper surface growth thickness of the epitaxial layer 20
Matter layer 40;
S08: it etches the dielectric layer 40 and forms the emitter contact hole 411 for running through the dielectric layer 40, the transmitting
The corresponding base area 22 of pole contact hole 411;
S09: the polysilicon of first conductive type impurity of filling doping high concentration in the emitter contact hole 411,
And form the emitter-polysilicon 421 being located in the emitter contact hole;
S10: the first metal layer 43 is grown in the upper surface of the dielectric layer;
S11: the second metal silicide layer is formed in the upper surface of the emitter-polysilicon 421 using rapid thermal treatment
431, and the emitter region 23 for the first conduction type being formed simultaneously in the base area 21;
S12: the upper surface of the dielectric layer 40 formed the base stage 51 that is connect with the polysilicon island 30 and with the hair
The emitter 52 that emitter polysilicon 421 connects;
S13: collector 53 is grown in the lower surface of the substrate 10.
In the production method of high-frequency triode of the present invention, using polysilicon technology and highly doped polycrystalline
Silicon forms the technology of outer base area, guarantees that the high-frequency triode can reach high frequency;The emitter contact hole 411 is logical
Cross directly individually etching formed, replace conventional double isolation side walls etching technics, reduce device technology difficulty and technique at
This.
With reference to the accompanying drawings, described high-frequency triode and preparation method thereof is elaborated.
Special to illustrate herein for convenience of subsequent description: first conduction type can be N-type, then, described second leads
Electric type is p-type, conversely, first conduction type may be p-type, correspondingly, second conduction type is N-type.?
In next embodiment, retouched so that first conduction type is N-type and second conduction type is p-type as an example
It states, but is defined not to this.
Referring to Fig. 4, executing step S01: providing substrate 10.Carrier of the substrate 10 as the high-frequency triode,
Primarily serve the effect of support.In the present embodiment, the substrate 10 is silicon substrate, and silicon is that most common, cheap and performance is stablized
Semiconductor material, can effectively reduce cost and promote yield.In other embodiments, the material of the substrate 10 may be used also
Think silicon carbide, germanium or germanium silicon etc..
In detail, the substrate 10 is the first conduction type.In the present embodiment, first conduction type is N-type, because
This described substrate 10 is N-type semiconductor.In other embodiments, first conduction type may be p-type, therefore, described
Substrate 10 is P-type semiconductor.The N-type substrate 10 can adulterate the elements such as phosphorus, arsenic, antimony by silicon and be formed, and not limit herein
It is fixed.
In more detail, the substrate 10 is highly doped semiconductor.In the present embodiment, the N-type substrate 10 is doping
The N+ substrate 10 of the N-type impurity of high concentration.Highly doped effect is the resistance for reducing the substrate 10, because the substrate 10
As electrode leads to client, reducing its resistance can be improved the response speed and current capacity of the high-frequency triode for lower surface, into
And the power of the high-frequency triode is promoted, increase its application range.Preferably, the resistivity of the N+ substrate 10 is less than 0.1
Ω·CM。
Further, in the surface grown epitaxial layer 20 of the substrate 10.Specifically institute is grown in the upper surface of the substrate 10
Epitaxial layer 20 is stated, the epitaxial layer 20 is silicon epitaxy layer.
In detail, the epitaxial layer 20 is the first conduction type.In the present embodiment, first conduction type is N-type,
Therefore epitaxial layer 20 is N-type semiconductor.In other embodiments, first conduction type may be p-type, therefore, described
Epitaxial layer 20 is P-type semiconductor.The N-type epitaxy layer 20 can adulterate the elements such as phosphorus, arsenic, antimony by silicon and be formed, herein not
It limits.
In more detail, the epitaxial layer 20 is the semiconductor being lightly doped.In the present embodiment, the N-type epitaxy layer 20 is
Adulterate the N- epitaxial layer 20 of the N-type impurity of low concentration.The purpose being lightly doped is to guarantee that the epitaxial layer 20 has biggish resistance
Value is so that it can bear biggish voltage, to promote the breakdown voltage of the high-frequency triode.Preferably, the extension
The resistivity of layer 20 is 0.5~10 Ω CM.Further, it is also possible to be promoted by the thickness for increasing the epitaxial layer 20 described outer
Prolong the ability that layer 20 bears voltage.Preferably, the epitaxial layer 20 with a thickness of 0.8~5 μm.
Specifically, the epitaxial layer 20 is grown in 10 upper surface of substrate using epitaxy method.The epitaxy method packet
Depositing operation is included, the depositing operation can be in electron beam evaporation, chemical vapor deposition, atomic layer deposition, sputtering
It is a kind of.Preferably, the epitaxial layer 20 is formed on the substrate 10 using chemical vapor deposition in the present embodiment.At other
In specific embodiment, the extension can also be formed on 10 surface of substrate by ion implanting and/or the method for diffusion
Layer 20.
Referring to Fig. 5, executing step S02: in the one polysilicon layer 30a of upper surface growth regulation of the epitaxial layer 20.It is described
First polysilicon layer 30a is made of undoped polysilicon.The thickness of the first polysilicon layer 30a is preferably 200~
500nm。
It specifically, can be using CVD method (Chemical Vapor Deposition, CVD) described outer
The upper surface for prolonging layer 20 deposits the first polysilicon layer 30a.
Further, in the one metal silicide layer 30b of upper surface growth regulation of the first polysilicon layer 30a.Described first
Metal silicide layer 30b is made of metal silicide, and the metal silicide can be silicide, such as titanium silicide, zirconium silicide, silicon
Change at least one of tantalum, tungsten silicide etc..In the present embodiment, the metal silicide is tungsten silicide.First metallic silicon
The thickness of compound layer 30b is preferably 50~200nm.In the present embodiment, after the first metal silicide layer 30b is for connecting
The first base polysilicon 31 and the second base polysilicon 422 formed during continuous, to form good Ohmic contact, substantially
Degree reduces base resistance.
It specifically, can be using CVD method in the upper surface of the first polysilicon layer 30a deposition described the
One metal silicide layer 30b.
Referring to Fig. 6, executing step S03: second that doping high concentration is formed in the first polysilicon layer 30a is conductive
The polysilicon doped regions 30c of type dopant.In the present embodiment, second conduction type is p-type, then second conductive-type
Type impurity is p type impurity comprising the substance of the elements such as boracic, indium or gallium.Preferably, the p type impurity is boron or fluorination
Boron.
Specifically, the polysilicon doped regions 30c, and described polysilicon doped regions 30c are formed by the way of injection
In the surface layer of the first polysilicon layer 30a.The first metal silicide layer 30b's and the first polysilicon layer 30a
Second conductive type impurity is injected on surface.In injection process, the depth of injection is greater than first metal silicide layer
The thickness of 30b, to guarantee that second conductive type impurity can penetrate the first metal silicide layer 30b, meanwhile, injection
Depth is less than the sum of the first metal silicide layer 30b and the first polysilicon layer 30a thickness again, avoids described second from leading
Electric type dopant penetrates the first polysilicon layer 30a, to form the polysilicon doping in the first polysilicon layer 30a
Area 30c.In detail, in injection process, being preferably injected dosage is 1E15~1E16CM-2, Implantation Energy is 30~180kev.
Referring to Fig. 7, executing step S04: partial penetration etches the first metal silicide layer 30b and described more than first
Crystal silicon layer 30a, and form the polysilicon island 30 for being located at the upper surface of the epitaxial layer 20.It is appreciated that the polysilicon island 30
It is made of the first metal silicide layer 30b and the first polysilicon layer 30a that are not etched away, in the first polysilicon layer 30a
Including the polysilicon doped regions 30c.In general, multiple three poles of the high frequency can be made on same wafer in the production process
Pipe, therefore, will form multiple polysilicon islands 30 in the upper surface of the epitaxial layer 20.In detail, the single polysilicon
Island 30 is preferably dimensioned to be 0.5~1.5um, and the spacing between multiple polysilicon islands 30 is preferably 0.5~1.0um.
Specifically, the polysilicon island 30 is formed to include the following steps: first the first metal silicide layer 30b's
Upper surface is laid with a layer photoresist layer (not shown), later using the mask plate with 30 figure of polysilicon island as exposure mask
The photoresist layer is exposed, then is developed, is formed and 30 figure one of polysilicon island on the photoresist layer
The window (not shown) of cause;Further, using the photoresist layer as exposure mask, from the photoresist layer by the way of etching
Window carries out substep to the first metal silicide layer 30b and the first polysilicon layer 30a and penetrates etching: the first step, carves
Lose the first metal silicide layer 30b;Second step etches the first polysilicon layer 30a.In detail, the side of the etching
Method includes dry etching and wet etching.In the present embodiment, it is preferred to use the method for dry etching.The quarter of the dry etching
Losing agent is plasma, using plasma and the substance reaction that is etched, forms volatile materials, or directly bombard the object that is etched
Matter is allowed to be corroded, and can be realized anisotropic etching, consequently facilitating ensure the shape and size of the polysilicon island 30
Precision, while in etching process, by accurately controlling etch amount, it is ensured that described in the corresponding region of the window
One polysilicon layer 30a is etched completely, avoids the epitaxial layer 20 to be carved as far as possible while locally exposure epitaxial layer 20
Erosion.In addition, dry etching easily realizes that automation, treatment process are not introduced into pollution, cleannes height.Produce the polysilicon island 30
Afterwards, the photoresist layer is first removed using cleaning solution.
Referring to Fig. 8, executing step S05: forming the outer base area 21 being located in the epitaxial layer 20.In detail, described outer
Base area 21 is the second conduction type.In the present embodiment, second conduction type is p-type, therefore the outer base area 21 is p-type
Semiconductor.In more detail, the outer base area 21 is highly doped semiconductor.It can be protected by the outer base area 21 for being arranged highly doped
Demonstrate,prove the frequency that the high-frequency triode can reach high.
Specifically, it forms the outer base area 21 and includes the following steps: that high-temperature heat treatment activates institute in the polysilicon island 30
The impurity for stating the second conduction type in the 30c of polysilicon doped regions makes the impurity part of second conduction type to described more
Regional diffusion other than doped polycrystal silicon area 30c, i.e., the impurity diffusion of described second conduction type to the first polysilicon layer 30a
And it further diffuses in the epitaxial layer 20.In high-temperature heat treatment process, the impurity of the second conduction type described first exists
Diffusion in the first polysilicon layer 30a, and the first polysilicon layer 30a is fully converted to the second conduction type of doping
First base polysilicon 31 of impurity, i.e., after high-temperature heat treatment, the polysilicon island 30 is by 31 He of the first base polysilicon
The first metal silicide layer 30b is constituted.With the propulsion of high-temperature heat treatment, the impurity of second conduction type is further
It diffuses into the epitaxial layer 20.Due to the second conduction type adulterated in the polysilicon doped regions 30c impurity it is dense
Degree is high, and during high-temperature heat treatment, the impurity of second conduction type is largely diffused in the epitaxial layer 20, and makes
Obtaining the local transoid of the epitaxial layer 20 becomes the outer base area 21.It is appreciated that the outer base area 21 and first base stage are more
Crystal silicon 31 connect, and the cross section of the outer base area 21 be greater than first base polysilicon 31 cross section, i.e., described first
View field of the base polysilicon 31 on the direction of the upper surface perpendicular to the substrate 10 is comprised in the outer base area 21
View field on the direction of the upper surface perpendicular to the substrate 10.
More specifically, the high-temperature heat treatment carries out in boiler tube.The temperature of the boiler tube is 800~950 DEG C, the height
The time of warm processing is 20~60min, and the junction depth of the outer base area 21 formed in the range is 0.1~0.5um.It is logical
Often, the junction depth of outer base area 21 is advisable be no more than the spacing of the polysilicon island 30 40%.
Referring to Fig. 9, executing step S06: forming the base area 22 being located in the epitaxial layer 20.In detail, the base area
22 be the second conduction type.In the present embodiment, second conduction type is p-type, therefore the outer base area 21 is that p-type is partly led
Body.In more detail, the base area 22 is connect with the outer base area 21, and the impurity of second conduction type is mixed in the base area 22
Doping concentration of the miscellaneous concentration lower than the impurity of the second conduction type in the outer base area 21.In the present embodiment, it described second leads
Electric type is p-type, then second conductive type impurity is p type impurity comprising the substance of the elements such as boracic, indium or gallium.It is excellent
Selection of land, the p type impurity are boron fluoride.
Specifically, forming the base area 22 includes the following steps: the upper surface from the epitaxial layer 20 to the epitaxial layer
20 carry out the impurity of the second conduction type of part doping.It is appreciated that 20 upper surface of epitaxial layer is formed with the polysilicon
Island 30 can pass through epitaxial layer locally exposed between the polysilicon island 30 when carrying out local adulterate to the epitaxial layer 20
20 surface is doped.The mode of the doping can be the mode of diffusion, be also possible to the mode of injection, in the present embodiment
In preferably using injection by the way of.The mode of the injection has purity is high, and good evenness can accurately control implantation dosage and depth
Degree, temperature is lower, is not susceptible to thermal defect, and it is more can to carry out selective area injection etc. as exposure mask using photoresist or metal
Weight advantage.
In more detail, in injection process, being preferably injected dosage is 1E13-5E13CM-2, Implantation Energy 10-50Kev,
Junction depth is injected within 0.1um.
Referring to Fig. 10, executing step S07: somatomedin layer 40.In the present embodiment, the thickness of the dielectric layer 40 is big
In the height of the polysilicon island 30, and the dielectric layer 40 be covered on the epitaxial layer 20 upper surface and the polysilicon island
30 upper surface.In other embodiments, the thickness of the dielectric layer may be set to be the height equal to the polysilicon island 30
Degree, the dielectric layer 40 are covered on the upper surface of the epitaxial layer 20.The effect of the dielectric layer 40 is to the epitaxial layer
20 and the polysilicon island 30 carry out insulation blocking.In detail, the dielectric layer 40 is the phosphorosilicate glass (BPSG) of boracic.At it
In his embodiment, the dielectric layer 90 can be the phosphorosilicate glass (PSG) of not boracic, be also possible to undoped silica glass
(USG), it can also be depositing silica at low pressure (LPTEOS).
Specifically, the dielectric layer 40 is formed to include the following steps: first using chemical vapour deposition technique in the extension
The upper surface of layer 20 and the upper surface of the polysilicon island 30 grow the dielectric layer 40, the dielectric layer 40 deposited
With a thickness of 500~1500nm;Further, planarization process carried out to the upper surface of the dielectric layer 40, after planarization process, position
It is at least 300nm in the thickness of the dielectric layer 40 of the upper surface of the polysilicon island 30.In detail, it is thrown using chemical machinery
The mode of light (Chemical Mechanical Polishing, CMP) carries out at planarization the upper surface of the dielectric layer 40
Reason.Chemical Mechanical Polishing Technique organically combines the mechanical abrasive action of abrasive grain with the chemical action of oxidant, can be real
The existing not damaged surface processing of ultraprecise, meets characteristic size in 0.35 μm of global planarizartion requirement below.It is specific real at other
It applies in mode, planarization process can also be carried out to the upper surface of the dielectric layer 40 by the way of dry etching.
Figure 11 is please referred to, step S08 is executed: through the etching dielectric layer 40, and forming contact hole 41, the contact hole
41 include emitter contact hole 411 and base stage contact hole 412.Wherein, the corresponding base area 22 of the emitter contact hole 411;
The corresponding polysilicon island 30 of the base stage contact hole 412.The emitter contact hole 411 be sized to it is smaller, with
Guarantee the frequency parameter of the high-frequency triode, the size of the preferably described emitter contact hole 411 is 0.15~0.4 μm.It is preferred that
The size of the base stage contact hole 412 is the half of the size of the polysilicon island 30.
Specifically, the emitter contact hole 411 is formed to include the following steps: first in the upper surface of the dielectric layer 40
It is laid with a layer photoresist layer (not shown), later using the mask plate with 411 figure of emitter contact hole as exposure mask
The photoresist layer is exposed, then is developed, is formed and 411 figure of emitter contact hole on the photoresist layer
The consistent window (not shown) of shape, view field of the window on the direction of the upper surface perpendicular to the substrate 10 is wrapped
It is contained in view field of the base area 22 on the direction of the upper surface perpendicular to the substrate 10;Further, with the photoetching
Glue-line penetrates etching to the dielectric layer 40 from the window of the photoresist layer by the way of etching as exposure mask, and etches
Shi Jinliang is performed etching along the direction on the surface perpendicular to the substrate 10.In detail, the etching is that dry anisotropic is carved
Erosion, etching gas is fluorine base gas, and the fluorine base gas is CF4, SF6, CHF3In any one.
Specifically, the base stage contact hole 412 is formed to include the following steps: to spread in the upper surface of the dielectric layer 40 first
If a layer photoresist layer (not shown), use has the mask plate of 412 figure of base stage contact hole as exposure mask to institute later
It states photoresist layer to be exposed, then develops, formed on the photoresist layer consistent with 412 figure of base stage contact hole
Window (not shown), view field of the window on the direction of the upper surface perpendicular to the substrate 10 be comprised in institute
State view field of the polysilicon island 30 on the direction of the upper surface perpendicular to the substrate 10;Further, with the photoresist
Layer is used as exposure mask, when penetrating etching to the dielectric layer 40 from the window of the photoresist layer by the way of etching, and etching
Direction as far as possible along the surface perpendicular to the substrate 10 performs etching.In detail, the etching is that dry anisotropic etches,
Etching gas is fluorine base gas, and the fluorine base gas is CF4, SF6, CHF3In any one.
It should be noted that form the emitter contact hole 411 synchronous can carry out with the base stage contact hole 412,
It can also carry out, be not limited thereto step by step.In addition, guaranteeing the choosing between etch media material and silicon materials as far as possible in etching
Ratio is selected, is hardly etched so that completing the base area 22 after the etching of the contact hole 41.
Please refer to Figure 12 and Figure 13, execute step S09: in the contact hole 41 and the upper surface of the dielectric layer 40 is raw
Long second polysilicon layer 42, wherein the contact hole 41 is fully filled with by the polysilicon being grown in the contact hole 41.It is described
Second polysilicon layer 42 is made of the polysilicon of the first conductive type impurity of doping high concentration.In the present embodiment, described
One conduction type is N-type, and first conductive type impurity is N-type impurity comprising the substance of the elements such as phosphorous, arsenic or antimony.
It is preferred that the N-type impurity is phosphorus or arsenic.In detail, the first conductive type impurity described in second polysilicon layer 42 is mixed
Miscellaneous concentration is 1E20~1E21CM-3.In more detail, the thickness of second polysilicon layer 42 is preferably 500~1000nm.
Specifically, it can use CVD method in the contact hole 41 and the upper surface of the dielectric layer 40 is heavy
Product second polysilicon layer 42.
Further, second polysilicon layer 42 is etched back, removal is located at the upper surface of the dielectric layer 40
Polysilicon simultaneously retains the polysilicon in the contact hole 41, to form the emitter being located in the emitter contact hole 411
Polysilicon 421 and the second base polysilicon 422 in the base stage contact hole 412.It is appreciated that the emitter polycrystalline
Silicon 421 and second base polysilicon 422 as second polysilicon layer 42, are led by the first of doping high concentration
The polysilicon of electric type dopant forms, and the emitter-polysilicon 421 connects the base area 22, second base polysilicon
422 connection the first metal silicide layer 30b.
Specifically, in the present embodiment, second polysilicon layer 42 is returned by the way of chemically mechanical polishing
Etching, chemically mechanical polishing can not only make the surface of second polysilicon layer 42 more flat, moreover it is possible to eliminate more than described second
The surface stress of crystal silicon layer 42.It in some other embodiments, can also be by the way of dry etching to more than described second
Crystal silicon layer 42 is etched back.It in other embodiments, can also be by way of wet etching to second polycrystalline
Silicon layer 42 is etched back.
Please refer to Figure 14, execute step S10: growth the first metal layer 43, the first metal layer 43, which is covered on, to be given an account of
The upper surface of the upper surface of matter layer 40 and the emitter-polysilicon 421 and second base polysilicon 422.In detail, institute
State the first metal layer 43 with a thickness of 20~100nm.In more detail, the first metal layer 43 can by Titanium, zirconium, tantalum,
At least one of tungsten etc. composition.In the present embodiment, the first metal layer 43 is made of Titanium.
Specifically, upper surface and the emitter-polysilicon of the CVD method in the dielectric layer 40 can be used
421 and the upper surface of second base polysilicon 422 deposit the first metal layer 43.
Figure 15 is please referred to, step S11 is executed: forming the second metal silicide layer 431 and third metal silicide layer 432,
Second metal silicide layer 431 is located at the upper surface of the emitter-polysilicon 421, the third metal silicide layer
432 are located at the upper surface of second base polysilicon 422.Second metal silicide layer 431 and the third metallic silicon
Compound layer 432 is made of metal silicide, and the metal silicide can be silicide, such as titanium silicide, zirconium silicide, silication
At least one of tantalum, tungsten silicide etc..In addition, second metal silicide layer 431 and the third metal silicide layer 432
It can be and be made of same metal silicide, be also possible to metal silicide composition not of the same race.In order to facilitate manufacture, in this implementation
In example, preferably described second metal silicide layer 431 and the third metal silicide layer 432 be can be by same metal silication
Object composition.In addition, the metal silicide of composition second metal silicide layer 431 and the third metal silicide layer 432
Can be identical with the metal silicide for forming the first metal silicide layer 30b, can not also be identical, it is not limited thereto.
In the present embodiment, the metal silicide of second metal silicide layer 431 and the third metal silicide layer 432 is formed
It is not identical as the metal silicide of composition the first metal silicide layer 30b.In the present embodiment, second metal is formed
The metal silicide of silicide layer 431 and the third metal silicide layer 432 is transformed by the first metal layer 43,
Therefore, the metal silicide is titanium silicide.
Meanwhile emitter region 23 is also formed, the emitter region 23 is located in the base area 22.In detail, the emitter region 23
For the first conduction type.In the present embodiment, first conduction type is N-type, therefore the emitter region 23 is that N-type is partly led
Body.
Specifically, it is formed simultaneously using the method for rapid thermal treatment (Rapid Thermal Processing, RTP) described
Second metal silicide layer 431, the third metal silicide layer 432 and the emitter region 23.The rapid thermal treatment includes
Three one-step rapid thermal anneals (Rapid Thermal Annealing, RTA).In detail, forming the outer base area 21 includes following step
It is rapid: to be first step quick thermal annealing process first, the temperature of the first step quick thermal annealing process is 640~740 DEG C, the time
For 10~30s.During first step quick thermal annealing process, silicon can with metal reaction and form metal silicide, i.e. institute
It states emitter-polysilicon 421 and is located at the first metal layer 43 of the upper surface of the emitter-polysilicon 421 on contact interface
It reacts, and forms the second metal silicide layer 431 for being located at 421 upper surface of emitter-polysilicon;Second base
Pole polysilicon 422 and the first metal layer 43 for the upper surface for being located at second base polysilicon 422 occur on contact interface
Reaction, and form the third metal silicide layer 432 for being located at the upper surface of second base polysilicon 422.It is appreciated that institute
State the first metal layer 43 be located at the dielectric layer 40 upper surface partially due to do not contact elemental silicon, therefore will not be converted to
Metal silicide, and the first metal layer 43 is located at the emitter-polysilicon 421 and second base polysilicon 422
Upper surface and metal silicide will not be converted to far from the part of contact interface.For unreacted in the first metal layer 43
Metal can be removed in the follow-up process by wet etching.In the present embodiment, because the first metal layer 43 by
Titanium composition, therefore second metal silicide layer 431 and the third metal silicide layer 432 that are formed are by titanium silicide
Composition.It is the slightly higher titanium silicide of C49 phase resistance rate that titanium silicide is formed by during first step quick thermal annealing process.It connects
Get off and carry out second step quick thermal annealing process, the temperature of the second step quick thermal annealing process is 750~850 DEG C.?
During the processing of two one-step rapid thermal anneals, it is lower that the slightly higher titanium silicide of the C49 phase resistance rate is converted into C49 phase resistance rate
Titanium silicide.Then third step quick thermal annealing process is carried out, the temperature of the third step quick thermal annealing process is 850~1100
DEG C, the time is 20~120s.During third step quick thermal annealing process, in the emitter-polysilicon 421 first
Conductive type impurity is by activated at and diffuses in the base area 22 connecting with the emitter-polysilicon 421.Although the base
Area 22 is the second conduction type, but since the doping concentration of the first conductive type impurity in the emitter-polysilicon 421 is high,
First conductive type impurity largely diffuses into the base area 22, and the local transoid in the base area 22 is made to become first
The emitter region 23 of conduction type.Since the emitter region 23 is impurity in the emitter-polysilicon 421 to external diffusion and shape
At, can avoid ion implanting and caused by residual impairment, while extremely shallow emitter junction can be made.The usual emitter junction
Depth be less than the base area 22 junction depth.
Figure 16 and Figure 17 are please referred to, step S12 is executed: being removed in wet etching unreacted in the first metal layer 43
After metal, the upper surface of the dielectric layer 40 and second metal silicide layer 431 and the third metal silicide layer 432
Upper surface grow second metal layer 50.The second metal layer 50 is preferably made of the preferable metal of electric conductivity.It needs herein
Illustrate, form the metal of the second metal layer 50 with form the first metal layer 43 metal can it is identical can also be with
It is not identical, it is not limited thereto.
Specifically, upper surface and second metal silication of the CVD method in the dielectric layer 40 can be used
The upper surface of nitride layer 431 and the third metal silicide layer 432 deposits the second metal layer 50.
Further, it etches the second metal layer 50 and forms base stage 51 and emitter 52, the base stage 51 connects described
Third metal silicide layer 432, the emitter 52 connect second metal silicide layer 431.
Specifically, it forms the base stage 51 and the emitter 52 includes the following steps: in the second metal layer 50
Upper surface covers a layer photoresist layer (not shown), is exposed to the photoresist layer, (figure is not for the first occlusion part of formation that develops
Show) and the second occlusion part (not shown), wherein first occlusion part is directed at the third metal silicide layer 432, described the
Two occlusion parts are directed at second metal silicide layer 431;The second metal layer 50 is performed etching, second gold medal is removed
Belong to the part not covered by first occlusion part and second occlusion part in layer 50, leaves corresponding first occlusion part
With the part of second occlusion part and be respectively formed base stage 51 and emitter 52.In detail, the method for the etching includes dry
Method etching and wet etching.In the present embodiment, it is preferred to use the method for wet etching.The wet etching is carved by chemistry
Erosion liquid and the substance that is etched, which occur to chemically react the substance that will be etched, to be stripped down, with preferable isotropic etching, because
This is convenient for the quick silicon nitride layer for removing the window's position.In addition, wet etching also have it is easy to operate, low for equipment requirements, easy
In realize produce in enormous quantities the characteristics of.After producing the base stage 51 and the emitter 52, first removed using cleaning solution described in
Photoresist layer.
In some other embodiment, in the case where the first metal layer 43 compares thick, described can also be retained
One metal layer 43, and the base stage 51 and the emitter 52 are formed by etching the first metal layer 43.Other one
The first metal layer 43 can also be retained in a little embodiments, and grow described second in the upper surface of the first metal layer 43
Metal layer 50, and the base stage 51 and the hair are formed by etching the first metal layer 43 and the second metal layer 50
Emitter-base bandgap grading 52, is not limited thereto.
Figure 18 is please referred to, step S13 is executed: in the substrate 10 in the following, the i.e. described substrate 10 is relatively described to prolong layer 20
One side surface deposits one layer of metal layer and constitutes collector 53.Preferably, the metal layer for constituting the collector 53 is TiNiAg
Complex metal layer.
In detail, the substrate 10 is first thinned before forming the collector 53.The substrate 10 is thinned, can not only have
There is lower collector resistance, while there can also be better heating conduction.In general, be thinned after the substrate 10 with a thickness of
80~200 μm.
The foregoing is merely one embodiment of the present of invention, are not intended to limit the invention, all in essence of the invention
Within mind and principle, any modification, equivalent substitution, improvement and etc. done be should be included within the scope of the present invention.