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CN109269310B - A sinter waste heat recovery device and method based on a vertical cold kiln - Google Patents

A sinter waste heat recovery device and method based on a vertical cold kiln Download PDF

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Publication number
CN109269310B
CN109269310B CN201811011819.2A CN201811011819A CN109269310B CN 109269310 B CN109269310 B CN 109269310B CN 201811011819 A CN201811011819 A CN 201811011819A CN 109269310 B CN109269310 B CN 109269310B
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section
flue
flue gas
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sinter
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CN109269310A (en
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王海风
张春霞
刘和平
林万舟
严定鎏
周和敏
齐渊洪
王�锋
高建军
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Gangyan Sheng Hua Polytron Technologies Inc
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D17/00Arrangements for using waste heat; Arrangements for using, or disposing of, waste gases
    • F27D17/10Arrangements for using waste heat
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D17/00Arrangements for using waste heat; Arrangements for using, or disposing of, waste gases
    • F27D17/20Arrangements for treatment or cleaning of waste gases
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27MINDEXING SCHEME RELATING TO ASPECTS OF THE CHARGES OR FURNACES, KILNS, OVENS OR RETORTS
    • F27M2003/00Type of treatment of the charge
    • F27M2003/04Sintering

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  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Waste-Gas Treatment And Other Accessory Devices For Furnaces (AREA)

Abstract

本发明公开了一种基于竖冷窑的烧结矿余热回收装置及方法,属于烧结矿余热回收技术领域,解决了现有技术中烧结矿显热回收利用率低的问题。装置包括烧结机、风箱、烟道和竖冷窑;沿烧结机运行方向,烟道分为A段烟道、B段烟道和C段烟道;沿竖冷窑从上至下方向,竖冷窑分为高温段和低温段;A段烟道的出烟口与脱硫单元、低温段、SCR脱硝单元和烟囱连接,B段烟道中的烟气循环至A段烟道对应的烧结机部分。方法为B段烟气循环至A段烟道对应的烧结机部分;A段烟气依次进行脱硫、与低温段烧结矿换热和脱硝;将C段烟气与高温段烧结矿换热,利用余热回收单元进行余热回收。上述装置和方法可用于烧结矿余热回收。

The invention discloses a sinter waste heat recovery device and method based on a vertical cooling kiln, belongs to the technical field of sinter waste heat recovery, and solves the problem of low utilization rate of sinter sensible heat recovery in the prior art. The device includes a sintering machine, an air box, a flue and a vertical cooling kiln; along the running direction of the sintering machine, the flue is divided into a section A flue, a B section flue and a C section flue; along the vertical cooling kiln from top to bottom, the vertical The cold kiln is divided into a high-temperature section and a low-temperature section; the flue outlet of section A is connected to the desulfurization unit, low-temperature section, SCR denitrification unit and chimney, and the flue gas in section B is circulated to the corresponding sintering machine part of the flue of section A . The method is that the flue gas from section B is circulated to the sintering machine corresponding to the flue of section A; the flue gas from section A is desulfurized, heat-exchanged with the sintered ore in the low-temperature section and denitrated sequentially; the flue gas from section C is exchanged with the sintered ore in the high-temperature section, and used The waste heat recovery unit performs waste heat recovery. The above device and method can be used for waste heat recovery of sintering ore.

Description

一种基于竖冷窑的烧结矿余热回收装置及方法A sinter waste heat recovery device and method based on a vertical cold kiln

技术领域technical field

本发明涉及一种烧结矿余热回收技术,尤其涉及一种基于竖冷窑的烧结矿余热回收装置及方法。The invention relates to a sinter waste heat recovery technology, in particular to a sinter waste heat recovery device and method based on a vertical cooling kiln.

背景技术Background technique

我国钢铁生产以高炉-转炉长流程为主,转炉钢比例达到90%以上。我国高炉炉料结构中烧结矿比例达到70%~75%,2014年我国烧结矿产量达到9.01亿吨。2013年,国家颁布执行《粗钢生产主要工序单位产品能耗消耗限额》(GB21256-2013),规定烧结工序单位产品能耗限定值为≤55kgce/t,准入值为≤50kgce/t,先进值为≤45kgce/t,余热回收量先进值为≥10kgce/t。能耗标准的提升将增加企业运营压力,促使不满足要求的企业退出市场,企业压力巨大。my country's iron and steel production is dominated by the blast furnace-converter long process, and the proportion of converter steel reaches more than 90%. The proportion of sinter in my country's blast furnace charge structure reaches 70% to 75%. In 2014, my country's sinter output reached 901 million tons. In 2013, the state promulgated and implemented the "Crude Steel Production Main Process Unit Product Energy Consumption Limit" (GB21256-2013), which stipulates that the sintering process unit product energy consumption limit value is ≤55kgce/t, and the access value is ≤50kgce/t, advanced The value is ≤45kgce/t, and the advanced value of waste heat recovery is ≥10kgce/t. The improvement of energy consumption standards will increase the operating pressure of enterprises, prompting enterprises that do not meet the requirements to withdraw from the market, and the pressure on enterprises is huge.

目前利用烧结矿余热主要是在带冷机或环冷机上通过鼓风对烧结矿进行冷却,底部鼓入的冷风在穿过炽热的烧结矿层时与烧结矿进行热交换,产生大量的高温废气。废气可用于预热点火助燃空气、产生蒸汽或发电。但是,此种余热回收方法烧结矿显热利用率低。At present, the use of sinter waste heat is mainly to cool the sinter by blowing air on the belt cooler or ring cooler. The cold air blown from the bottom exchanges heat with the sinter when it passes through the hot sinter layer, generating a large amount of high-temperature waste gas. Exhaust gases can be used to preheat combustion air for ignition, generate steam, or generate electricity. However, this waste heat recovery method has a low utilization rate of sensible heat of sinter.

发明内容Contents of the invention

鉴于上述的分析,本发明旨在提供一种基于竖冷窑的烧结矿余热回收装置及方法,解决了现有技术中烧结矿显热回收利用率低的问题。In view of the above analysis, the present invention aims to provide a sinter waste heat recovery device and method based on a vertical cooling kiln, which solves the problem of low recycling rate of sinter sensible heat in the prior art.

本发明的目的主要是通过以下技术方案实现的:The purpose of the present invention is mainly achieved through the following technical solutions:

一方面,本发明提供了一种基于竖冷窑的烧结矿余热回收装置,包括依次连接的烧结机、风箱、烟道和竖冷窑;沿烧结机运行方向,烟道分为A段烟道、B段烟道和C段烟道;沿竖冷窑从上至下方向,竖冷窑分为高温段和低温段;A段烟道的出烟口依次与脱硫单元、低温段、SCR脱硝单元和烟囱连接,B段烟道中的烟气循环至A段烟道对应的烧结机部分,C段烟道的出烟口依次与高温段、C段余热利用单元和烟囱连接;B段烟道的烟气SO2浓度>C段烟道的烟气SO2浓度>A段烟道的烟气SO2浓度;A段烟道的烟气NOX浓度>B段烟道的烟气NOX浓度>C段烟道的烟气NOX浓度。On the one hand, the present invention provides a sinter waste heat recovery device based on a vertical cooling kiln, which includes a sintering machine, an air box, a flue and a vertical cooling kiln connected in sequence; along the running direction of the sintering machine, the flue is divided into a section A flue , B-section flue and C-section flue; along the vertical cooling kiln from top to bottom, the vertical cooling kiln is divided into a high-temperature section and a low-temperature section; the smoke outlet of the A-section flue is connected with the desulfurization unit, low-temperature section, and SCR denitrification The unit is connected to the chimney, the flue gas in the section B flue is circulated to the corresponding sintering machine part of the A section flue, and the smoke outlet of the C section flue is connected with the high temperature section, the C section waste heat utilization unit and the chimney in turn; the B section flue flue gas SO 2 concentration in section C > flue gas SO 2 concentration in section C > flue gas SO 2 concentration in section A; flue gas NO X concentration in section A > flue gas NO x concentration in section B > The flue gas NO X concentration of the C-section flue.

在一种可能的设计中,A段烟道、B段烟道与C段烟道对应的风箱个数的比为14~16:5~9:4~6。In a possible design, the ratio of the number of bellows corresponding to the section A flue, the section B flue, and the section C flue is 14-16:5-9:4-6.

在一种可能的设计中,低温段的出烟口处,烧结矿的温度为400℃~450℃。In a possible design, the temperature of the sintered ore at the smoke outlet of the low temperature section is 400°C-450°C.

在一种可能的设计中,高温段的进烟口设置于高温段的下部,出烟口设置于高温段的上部;低温段的进烟口设置于低温段的下部,出烟口设置于低温段的上部。In a possible design, the smoke inlet of the high temperature section is set at the lower part of the high temperature section, and the smoke outlet is set at the upper part of the high temperature section; the smoke inlet of the low temperature section is set at the lower part of the low temperature section, and the smoke outlet is set at the lower part of the low temperature section. the upper part of the segment.

在一种可能的设计中,A段烟道与脱硫单元的连接管路上以及C段烟道与高温段的连接管路上均设有引风机。In a possible design, an induced draft fan is installed on the connecting pipeline between the flue in section A and the desulfurization unit, and on the connecting pipeline between the flue in section C and the high temperature section.

在一种可能的设计中,引风机的进风口前设有引风机除尘器。In a possible design, an induced fan dust collector is arranged in front of the air inlet of the induced fan.

在一种可能的设计中,高温段与C段余热利用单元的连接管路上以及低温段与SCR脱硝单元的连接管路上设置竖冷窑除尘器。In a possible design, a vertical cooling kiln dust collector is installed on the connecting pipeline between the high temperature section and the C-section waste heat utilization unit, and on the connecting pipeline between the low temperature section and the SCR denitrification unit.

在一种可能的设计中,SCR脱硝单元与烟囱的连接管道上设有A段余热利用单元。In a possible design, the connecting pipe between the SCR denitrification unit and the chimney is provided with a section A waste heat utilization unit.

在一种可能的设计中,装置还包括破碎筛,烧结机中的烧结矿通过破碎筛落入高温段中。In a possible design, the device also includes a crushing screen through which the sintered ore in the sintering machine falls into the high temperature section.

另一方面,本发明还提供了一种基于竖冷窑的烧结矿余热回收方法,采用上述基于竖冷窑的烧结矿余热装置,方法包括如下步骤:On the other hand, the present invention also provides a sinter waste heat recovery method based on a vertical cooling kiln, using the above-mentioned sinter waste heat device based on a vertical cooling kiln, the method includes the following steps:

将烧结原料送入烧结机进行烧结,生产烧结成品矿的同时产生烟气;B段烟气循环至A段烟道对应的烧结机部分;A段烟气经过脱硫单元脱硫,脱硫后的烟气与竖冷窑的低温段烧结矿进行换热,使得混合后的烟气温度升至SCR脱硝的合适温度,进行脱硝;将C段烟气与竖冷窑的高温段烧结矿进行换热,得到高温烟气,利用余热回收单元进行余热回收。The sintering raw materials are sent to the sintering machine for sintering, and flue gas is generated while producing sintered finished ore; the flue gas in section B is circulated to the part of the sintering machine corresponding to the flue of section A; the flue gas in section A is desulfurized by the desulfurization unit, and the flue gas after desulfurization Heat exchange with the sintered ore in the low-temperature section of the vertical cooling kiln, so that the temperature of the mixed flue gas rises to an appropriate temperature for SCR denitrification, and denitrification is performed; the flue gas in section C is exchanged with the sintered ore in the high-temperature section of the vertical cooling kiln to obtain The high-temperature flue gas is recovered by using the waste heat recovery unit.

与现有技术相比,本发明有益效果如下:Compared with the prior art, the beneficial effects of the present invention are as follows:

a)本发明提供的基于竖冷窑的烧结矿余热回收装置,烟道分为A段烟道、B段烟道和C段烟道,竖冷窑分为高温段和低温段,有效地对换热后的烟气进行余热回收率可提高50%以上,余热回收总量大大提高,最大限度地回收烟气和烧结矿显热(几乎全部的回收)。对于烟气品质,高温的C段烟气与高温段换热,得到高温烟气,混合后的A段烟气与低温段换热,得到中温烟气,提高了携带烧结矿显热的烟气品质,服了传统冷却机生产蒸汽品质较低且流量不稳定的弊端,为后续生产蒸汽品质从提高吨烧结矿发电量打下良好的基础。同时,对于烧结矿的品质,热烧结矿在高温段具有保温作用,进行温度均匀化和残存挥发份析出过程,因而经过高温段,烧结矿成熟度得到进一步的提高,生矿基本消除,烧结矿在高温段向下流动过程中,烧结矿受机械力作用,脆弱部分及生矿部分得以筛除,成品率得到提高,克服了传统冷却机漏风,只回收温度较高的烧结余热资源等弊端,改变了冷却机仅限于烧结矿冷却而不能高效回收显热的局面。a) In the sinter waste heat recovery device based on the vertical cooling kiln provided by the present invention, the flue is divided into a section flue, a B section flue and a C section flue, and the vertical cooling kiln is divided into a high temperature section and a low temperature section, effectively The waste heat recovery rate of the flue gas after heat exchange can be increased by more than 50%, the total amount of waste heat recovery is greatly improved, and the flue gas and sinter sensible heat can be recovered to the maximum extent (almost all recovery). Regarding flue gas quality, the flue gas in the high-temperature section C exchanges heat with the high-temperature section to obtain high-temperature flue gas, and the mixed flue gas in section A exchanges heat with the low-temperature section to obtain medium-temperature flue gas, which improves the flue gas carrying sensible heat of sinter Quality, overcoming the disadvantages of low steam quality and unstable flow produced by traditional coolers, and laying a good foundation for subsequent production of steam quality from improving power generation per ton of sinter. At the same time, regarding the quality of sinter, hot sinter has the function of heat preservation in the high-temperature section, and the process of temperature homogenization and residual volatile precipitation is carried out. Therefore, after passing through the high-temperature section, the maturity of sinter is further improved, raw ore is basically eliminated, and sinter During the downward flow of the high temperature section, the sinter is subjected to mechanical force, the fragile part and the raw ore part can be screened out, and the yield of the finished product is improved. It has changed the situation that the cooler is only limited to sinter cooling and cannot recover sensible heat efficiently.

b)本发明提供的基于竖冷窑的烧结矿余热回收装置,能够充分回收烧结矿和烧结烟气余热,同时减少SOx和NOx排放,降低粉尘的排放量,保护环境。由于冷却气体在密闭罐体内对烧结矿进行冷却,同时罐体采用定位接矿,粉尘易得到控制。通过循环工作,资源的反复利用率提高,同时工作效率也得以提高,从而进一步提高热能利用率。具有流程短,适用性强,投资、运行成本低等优点,可以作为已有烧结脱硫工艺的企业配套建设,也可选择成熟的烧结烟气脱硫工艺一起新建,具有很大的应用价值。b) The sinter waste heat recovery device based on the vertical cooling kiln provided by the present invention can fully recover sinter and sinter flue gas waste heat, reduce SO x and NO x emissions, reduce dust emissions, and protect the environment. Since the cooling gas cools the sintered ore in the closed tank, and the tank is positioned to connect to the ore, the dust is easily controlled. Through cyclic work, the repeated utilization rate of resources is improved, and the work efficiency is also improved, thereby further improving the utilization rate of heat energy. It has the advantages of short process, strong applicability, low investment and operating costs, etc. It can be used as a supporting construction for enterprises with existing sintering desulfurization processes, or it can be newly built together with mature sintering flue gas desulfurization processes, which has great application value.

c)本发明提供的基于竖冷窑的烧结矿余热回收装置,对于C段烟气,高温低NOX低SO2,C段烟气通入高温段,由于高温段顶端烧结矿的温度在700℃左右,因此,换热后的C段烟气的温度能够达到680℃左右,明显高于现有技术,进一步通过余热回收单元能够有效地回收C段烟气和高温段烧结矿的余热。对于A段烟气和B段烟气,将B段烟气循环至A段烟道对应的烧结机部分,使得B段烟气和A段烟道中烟气混合,使得SO2混合、富集,得到混合后的A段烟气,混合后的A段烟气温度在100℃左右,此温度适合于脱硫,因此,可以直接进行烟气脱硫处理;经过脱硫处理的A段烟气,与低温段换热,温度可以升至350℃左右,此温度适合于SCR脱硝,因此,可以直接进行烟气脱硝处理。本发明的余热回收装置,通过将烟道和竖冷窑分段,不仅有效地回收了高温的C段烟气和高温段烧结矿的显热,还能够使得混合后的A段烟气直接达到脱硫和SCR脱硝的合适温度,不需要额外的燃烧机。c) The sinter waste heat recovery device based on the vertical cooling kiln provided by the present invention, for the flue gas of the C section, high temperature, low NOx and low SO 2 , the flue gas of the C section is passed into the high temperature section, because the temperature of the sinter at the top of the high temperature section is 700 Therefore, the temperature of the flue gas in the C section after heat exchange can reach about 680°C, which is significantly higher than that of the existing technology, and the waste heat of the flue gas in the C section and the sintering ore in the high temperature section can be effectively recovered through the waste heat recovery unit. For the flue gas of section A and flue gas of section B, the flue gas of section B is circulated to the part of the sintering machine corresponding to the flue of section A, so that the flue gas of section B is mixed with the flue gas in the flue of section A, so that SO 2 is mixed and enriched, The mixed flue gas in section A is obtained. The temperature of the mixed flue gas in section A is about 100°C, which is suitable for desulfurization. Therefore, flue gas desulfurization can be performed directly; Heat exchange, the temperature can rise to about 350°C, which is suitable for SCR denitrification, therefore, the flue gas denitrification treatment can be carried out directly. The waste heat recovery device of the present invention, by segmenting the flue and the vertical cooling kiln, not only effectively recovers the high-temperature C-section flue gas and the sensible heat of the high-temperature section sinter, but also enables the mixed A-section flue gas to directly reach Suitable temperature for desulfurization and SCR denitrification, no additional burner required.

本发明的其他特征和优点将在随后的说明书中阐述,并且,部分从说明书中变得显而易见,或者通过实施本发明而了解。本发明的目的和其他优点可通过在所写的说明书和权利要求书中所特别指出的结构来实现和获得。Additional features and advantages of the invention will be set forth in the description which follows, and in part will be obvious from the description, or may be learned by practice of the invention. The objectives and other advantages of the invention may be realized and attained by the structure particularly pointed out in the written description and claims hereof.

附图说明Description of drawings

附图仅用于示出具体实施例的目的,而并不认为是对本发明的限制,在整个附图中,相同的参考符号表示相同的部件。The drawings are for the purpose of illustrating specific embodiments only and are not to be considered as limitations of the invention, and like reference numerals refer to like parts throughout the drawings.

图1为本发明的烧结矿余热回收装置的结构示意图;Fig. 1 is the structural representation of the sinter waste heat recovery device of the present invention;

图2为本发明的烧结矿余热回收装置竖冷窑中气固换热的示意图;Fig. 2 is a schematic diagram of gas-solid heat exchange in the vertical cooling kiln of the sinter waste heat recovery device of the present invention;

图3为各段烟气的SO2浓度、NOx浓度和温度的曲线图。Fig. 3 is a graph of SO2 concentration, NOx concentration and temperature of flue gas in each section.

附图标记:Reference signs:

1-烧结机;2-风箱;3-A段烟道;4-B段烟道;5-C段烟道;6-高温除尘器;7-引风机;8-高温段;9-第一重力除尘器;10-C段余热利用单元;11-烟囱;12-循环烟气罩;13-破碎筛;14-静电除尘器;15-第二重力除尘器;16-脱硫单元;17-低温段;18-A段余热利用单元;19-SCR脱硝单元。1-Sintering machine; 2-Blower box; 3-A section flue; 4-B section flue; 5-C section flue; 6-High temperature dust collector; 7-Induced fan; 8-High temperature section; Gravity dust collector; 10-C section waste heat utilization unit; 11-chimney; 12-circulating flue gas hood; 13-crushing screen; 14-electrostatic precipitator; section; 18-A section waste heat utilization unit; 19-SCR denitrification unit.

具体实施方式Detailed ways

下面结合附图来具体描述本发明的优选实施例,其中,附图构成本申请一部分,并与本发明的实施例一起用于阐释本发明的原理。Preferred embodiments of the present invention will be specifically described below in conjunction with the accompanying drawings, wherein the accompanying drawings constitute a part of the application and are used together with the embodiments of the present invention to explain the principles of the present invention.

一方面,本发明提供了一种基于竖冷窑的烧结矿余热回收装置,参见图1至图3,包括依次连接的烧结机1、风箱2、烟道和竖冷窑;沿烧结机1运行方向,烟道分为A段烟道3、B段烟道4和C段烟道5;沿竖冷窑从上至下方向,竖冷窑分为高温段8和低温段17;A段烟道3的出烟口依次与脱硫单元16、低温段17、SCR脱硝单元19和烟囱11连接,B段烟道4的出烟口通过循环烟气罩12与A段烟道3对应的烧结机1部分的进烟口连接,B段烟道4中的烟气循环至A段烟道3对应的烧结机部分,C段烟道5的出烟口依次与高温段8、C段余热利用单元10(例如,余热发电装置等)和烟囱11连接;B段烟道4的烟气SO2浓度>C段烟道5的烟气SO2浓度>A段烟道3的烟气SO2浓度;A段烟道3的烟气NOX浓度>B段烟道4的烟气NOX浓度>C段烟道5的烟气NOX浓度,也就是说,A段烟道3的烟气为低温高NOX低SO2,B段烟道4的烟气为中温中NOX高SO2,C段烟道5的烟气为高温低NOX低SO2On the one hand, the present invention provides a sinter waste heat recovery device based on a vertical cooling kiln, see Fig. 1 to Fig. 3, including a sintering machine 1, an air box 2, a flue and a vertical cooling kiln connected in sequence; running along the sintering machine 1 direction, the flue is divided into A-section flue 3, B-section flue 4 and C-section flue 5; along the direction from top to bottom of the vertical cooling kiln, the vertical cooling kiln is divided into high-temperature section 8 and low-temperature section 17; The smoke outlet of channel 3 is connected with desulfurization unit 16, low temperature section 17, SCR denitrification unit 19 and chimney 11 in sequence, and the smoke outlet of section B flue 4 is connected to the sintering machine corresponding to section A flue 3 through circulating flue gas hood 12 The smoke inlet of section 1 is connected, the flue gas in section B flue 4 is circulated to the sintering machine part corresponding to section A flue 3, and the smoke outlet of section C flue 5 is connected with high temperature section 8 and C section waste heat utilization unit in turn 10 (for example, waste heat power generation device, etc.) is connected with the chimney 11; the flue gas SO concentration of the B section flue 4 > the flue gas SO concentration of the C section flue 5 > the flue gas SO concentration of the A section flue 3 ; The flue gas NO X concentration of flue gas 3 in section A > the flue gas NO x concentration of flue gas 4 in section B > the flue gas NO x concentration of flue gas 5 in section C, that is to say, the flue gas in flue 3 of section A is low temperature High NO X and low SO 2 , the flue gas of section B flue 4 is medium temperature, medium NO x and high SO 2 , and the flue gas of C section flue 5 is high temperature, low NO X and low SO 2 .

可以理解的是,沿烧结机1运行方向,烧结矿的温度逐渐升高,因此,烟气的温度也逐渐升高,C段烟道5的烟气温度>B段烟道4的烟气温度>A段烟道3的烟气温度。It can be understood that along the running direction of the sintering machine 1, the temperature of the sintered ore gradually increases, so the temperature of the flue gas also gradually increases, and the flue gas temperature of the flue 5 in the C section is greater than the flue gas temperature of the flue 4 in the B section > Flue gas temperature of section A flue 3.

实施时,将B段烟气循环至A段烟道3对应的烧结机1部分,使得B段烟气与A段烟道3对应的烧结机部分料层反应,使得SO2混合、富集,A段烟气经过脱硫单元16去除SO2,然后,将A段烟气与竖冷窑的低温段17烧结矿进行换热,使得A段烟气温度升至SCR脱硝的合适温度,进行脱硝;将C段烟气与竖冷窑的高温段8烧结矿进行换热,得到高温烟气,利用余热回收单元进行余热回收。During implementation, the flue gas from section B is circulated to the part of the sintering machine corresponding to the flue 3 of the section A, so that the flue gas from the section B reacts with the part of the material layer of the sintering machine corresponding to the flue 3 of the section A, so that SO 2 is mixed and enriched, The flue gas in section A passes through the desulfurization unit 16 to remove SO 2 , and then exchanges heat between the flue gas in section A and the sintered ore in the low-temperature section 17 of the vertical cooling kiln, so that the temperature of the flue gas in section A rises to a suitable temperature for SCR denitrification, and denitrification is performed; The flue gas in section C is exchanged with the sintered ore in the high-temperature section 8 of the vertical cooling kiln to obtain high-temperature flue gas, and the waste heat recovery unit is used for waste heat recovery.

需要说明的是,烧结矿竖冷窑冷却技术是一种全新的烧结矿冷却和余热回收工艺技术,该工艺的流程为:将热破碎后的烧结矿从顶部装入竖冷窑内,并与从竖冷窑下部鼓入的冷却空气进行逆向热交换;冷却风在冷却烧结矿的同时,自身温度逐渐升高,在达到竖冷窑上部料面后,温度可达到380℃~450℃左右,变为高温热风。It should be noted that the sinter vertical cooling kiln cooling technology is a brand-new sinter cooling and waste heat recovery process technology. The cooling air blasted from the lower part of the vertical cooling kiln performs reverse heat exchange; while the cooling air cools the sinter, its own temperature gradually rises. After reaching the upper material surface of the vertical cooling kiln, the temperature can reach about 380 ° C ~ 450 ° C. into high temperature hot air.

与现有技术相比,本发明提供的基于竖冷窑的烧结矿余热回收装置,烟道分为A段烟道3、B段烟道4和C段烟道5,竖冷窑分为高温段8和低温段17,有效地对换热后的烟气进行余热回收率可提高50%以上,余热回收总量大大提高,最大限度地回收烟气和烧结矿显热(几乎全部的回收)。对于烟气品质,高温的C段烟气与高温段8换热,得到高温烟气,混合后的A段烟气与低温段17换热,得到中温烟气,提高了携带烧结矿显热的烟气品质,服了传统冷却机生产蒸汽品质较低且流量不稳定的弊端,为后续生产蒸汽品质从提高吨烧结矿发电量打下良好的基础。同时,对于烧结矿的品质,热烧结矿在高温段8具有保温作用,进行温度均匀化和残存挥发份析出过程,因而经过高温段8,烧结矿成熟度得到进一步的提高,生矿基本消除,烧结矿在高温段8向下流动过程中,烧结矿受机械力作用,脆弱部分及生矿部分得以筛除,成品率得到提高,克服了传统冷却机漏风,只回收温度较高的烧结余热资源等弊端,改变了冷却机仅限于烧结矿冷却而不能高效回收显热的局面。Compared with the prior art, in the sinter waste heat recovery device based on the vertical cooling kiln provided by the present invention, the flue is divided into the A-section flue 3, the B-section flue 4 and the C-section flue 5, and the vertical cooling kiln is divided into high-temperature Section 8 and low-temperature section 17 can effectively recover the waste heat of the flue gas after heat exchange by more than 50%, the total amount of waste heat recovery is greatly improved, and the maximum recovery of flue gas and sinter sensible heat (almost all recovery) . Regarding the flue gas quality, the flue gas in the high-temperature section C exchanges heat with the high-temperature section 8 to obtain high-temperature flue gas, and the mixed flue gas in section A exchanges heat with the low-temperature section 17 to obtain medium-temperature flue gas, which improves the capacity of carrying sensible heat of sinter The quality of flue gas overcomes the disadvantages of low steam quality and unstable flow produced by traditional coolers, and lays a good foundation for the subsequent production of steam quality to improve the power generation per ton of sinter. At the same time, regarding the quality of the sinter, the hot sinter has the function of heat preservation in the high temperature section 8, and the process of temperature homogenization and residual volatile precipitation is carried out. Therefore, after passing through the high temperature section 8, the maturity of the sinter is further improved, and the raw ore is basically eliminated. During the downward flow of the sinter in the high temperature section 8, the sinter is subjected to mechanical force, the fragile part and the raw ore part can be screened out, the yield of the finished product is improved, the air leakage of the traditional cooler is overcome, and only the sintering waste heat resource with a higher temperature is recovered Such disadvantages have changed the situation that the cooler is limited to sinter cooling and cannot recover sensible heat efficiently.

此外,上述余热回收装置能够充分回收烧结矿和烧结烟气余热,同时减少SOx和NOx排放,降低粉尘的排放量,保护环境。由于冷却气体在密闭罐体内对烧结矿进行冷却,同时罐体采用定位接矿,粉尘易得到控制。通过循环工作,资源的反复利用率提高,同时工作效率也得以提高,从而进一步提高热能利用率。具有流程短,适用性强,投资、运行成本低等优点,可以作为已有烧结脱硫工艺的企业配套建设,也可选择成熟的烧结烟气脱硫工艺一起新建,具有很大的应用价值。In addition, the above waste heat recovery device can fully recover the waste heat of sintering ore and sintering flue gas, reduce SO x and NO x emissions, reduce dust emissions, and protect the environment. Since the cooling gas cools the sintered ore in the closed tank, and the tank is positioned to connect to the ore, the dust is easily controlled. Through cyclic work, the repeated utilization rate of resources is improved, and the work efficiency is also improved, thereby further improving the utilization rate of heat energy. It has the advantages of short process, strong applicability, low investment and operating costs, etc. It can be used as a supporting construction for enterprises with existing sintering desulfurization processes, or it can be newly built together with mature sintering flue gas desulfurization processes, which has great application value.

具体来说,如果不将烟道和竖冷窑分段,烟气直接与竖冷窑整体换热,其得到的烟气温度仅能够达到380℃~450℃左右,而对于C段烟气,高温低NOX低SO2,C段烟气通入高温段8,由于高温段8顶端烧结矿的温度在700℃左右,因此,换热后的C段烟气的温度能够达到680℃左右,明显高于现有技术,进一步通过余热回收单元能够有效地回收C段烟气和高温段8烧结矿的余热。对于A段烟气和B段烟气,将B段烟气循环至A段烟道3对应的烧结机1部分,使得B段烟气和A段烟道3中烟气混合,使得SO2混合、富集,得到混合后的A段烟气,混合后的A段烟气温度在100℃左右,此温度适合于脱硫,因此,可以直接进行烟气脱硫处理;经过脱硫处理的A段烟气,与低温段17换热,温度可以升至350℃左右,此温度适合于SCR脱硝,因此,可以直接进行烟气脱硝处理。本发明的余热回收装置,通过将烟道和竖冷窑分段,不仅有效地回收了高温的C段烟气和高温段8烧结矿的显热,还能够使得混合后的A段烟气直接达到脱硫和SCR脱硝的合适温度,不需要额外的燃烧机。Specifically, if the flue and the vertical cooling kiln are not divided into sections, the flue gas directly exchanges heat with the vertical cooling kiln as a whole, and the temperature of the flue gas obtained can only reach about 380 ° C ~ 450 ° C, while for the flue gas in the C section, High temperature, low NO X and low SO 2 , the flue gas in section C is passed into high temperature section 8, and since the temperature of the sinter at the top of high temperature section 8 is about 700°C, the temperature of the flue gas in section C after heat exchange can reach about 680°C, It is obviously higher than that of the prior art, and the flue gas in section C and the waste heat of sinter in high-temperature section 8 can be effectively recovered through the waste heat recovery unit. For the flue gas in section A and flue gas in section B, the flue gas in section B is circulated to the part of sintering machine 1 corresponding to flue 3 in section A, so that the flue gas in section B is mixed with the flue gas in flue 3 in section A, so that SO 2 is mixed , enrichment, and get mixed A-section flue gas. The mixed A-section flue gas temperature is about 100°C, which is suitable for desulfurization. Therefore, flue gas desulfurization treatment can be directly carried out; A-section flue gas after desulfurization treatment , exchanging heat with the low-temperature section 17, the temperature can rise to about 350°C, which is suitable for SCR denitrification, therefore, the flue gas denitrification treatment can be directly carried out. The waste heat recovery device of the present invention, by segmenting the flue and the vertical cooling kiln, not only effectively recovers the high-temperature C-section flue gas and the sensible heat of the high-temperature section 8 sinter, but also enables the mixed A-section flue gas to directly To achieve the appropriate temperature for desulfurization and SCR denitrification, no additional burner is required.

对于烟道的分段方式,具体来说,A段烟道3、B段烟道4与C段烟道5对应的风箱个数的比为14~16:5~9:4~6。示例性地,现有的烧结机风箱2的总个数通常在27个左右(1~27号风箱),也就是说,A段烟道3对应的风箱个数可以为15个,B段烟道4对应的风箱个数可以为6个,C段烟道5对应的风箱个数可以为6个,也就是说,A段烟道3对应的风箱为1~15号,B段烟道4对应的风箱为16~21号,C段烟道5对应的风箱为22~27号。For the sectioning of the flue, specifically, the ratio of the number of bellows corresponding to the flue 3 in section A, the flue 4 in section B, and the flue 5 in section C is 14-16:5-9:4-6. Exemplarily, the total number of wind boxes 2 of the existing sintering machine is usually about 27 (wind boxes No. The number of bellows corresponding to channel 4 can be 6, and the number of bellows corresponding to section C flue 5 can be 6, that is to say, the number of bellows corresponding to section A flue 3 is No. The corresponding bellows are No. 16-21, and the bellows corresponding to section C flue 5 are No. 22-27.

为了使烟气能够与烧结矿充分换热,高温段8的进烟口设置于高温段8的下部,出烟口设置于高温段8的上部;同样地,低温段17的进烟口设置于低温段17的下部,出烟口设置于低温段17的上部。In order to enable the flue gas to fully exchange heat with the sinter, the smoke inlet of the high temperature section 8 is set at the lower part of the high temperature section 8, and the smoke outlet is set at the upper part of the high temperature section 8; similarly, the smoke inlet of the low temperature section 17 is set at The lower part of the low temperature section 17, the smoke outlet is arranged on the upper part of the low temperature section 17.

为了使脱硫后的A段烟气与低温段17换热后,温度能够达到适合SCR脱硝的温度(350℃左右),低温段17的出烟口处,烧结矿的温度应该控制在400℃~450℃的范围内,这样,当脱硫后的A段烟气与低温段17的烧结矿进行换热后,可以使得A段烟气的温度直接达到适合SCR脱硝的温度,而无需额外设置燃烧机或降温单元,从而节约能源,简化上述余热回收装置的结构。In order to make the desulfurized A-stage flue gas exchange heat with the low-temperature section 17, the temperature can reach the temperature suitable for SCR denitrification (about 350°C), the temperature of the sintered ore at the smoke outlet of the low-temperature section 17 should be controlled at 400°C~ In this way, when the desulfurized A-stage flue gas exchanges heat with the sintered ore in the low-temperature section 17, the temperature of the A-stage flue gas can directly reach the temperature suitable for SCR denitrification without additional burners or a cooling unit, thereby saving energy and simplifying the structure of the above-mentioned waste heat recovery device.

可以理解的是,为了使烧结机1产生的烟气进入风箱2以及所涉及的管路,A段烟道3与脱硫单元16的连接管路上以及C段烟道5与高温段8的连接管路上均设有引风机7。通过引风机7,可以将烧结机1产生的烟气引入风箱2,并进一步引入各段风箱2对应的烟道,从而实现烟气的流动和处理。It can be understood that in order to allow the flue gas generated by the sintering machine 1 to enter the wind box 2 and related pipelines, the connecting pipeline between the flue 3 in section A and the desulfurization unit 16 and the connecting pipe between the flue 5 in section C and the high temperature section 8 Induced draft fans 7 are all provided on the road. Through the induced draft fan 7, the flue gas generated by the sintering machine 1 can be introduced into the wind box 2, and further introduced into the flue corresponding to each section of the wind box 2, so as to realize the flow and treatment of the flue gas.

为了避免A段烟气和C段烟气中的粉尘堵引风机7,在引风机7的进风口前可以设置引风机除尘器(例如,高温除尘器6或静电除尘器14)。In order to avoid the dust in the A-section flue gas and the C-section flue gas from blocking the induced draft fan 7, an induced draft fan dust collector (for example, a high-temperature dust collector 6 or an electrostatic precipitator 14) can be set before the air inlet of the induced fan 7.

考虑到烟气经过竖冷窑后,竖冷窑中的烧结矿在余热的作用下,仍然会产生粉尘,进入到烟气中,为了避免此部分粉尘污染后续的设备和大气,可以在高温段8与C段余热利用单元10的连接管路上以及低温段17与SCR脱硝单元19的连接管路上设置竖冷窑除尘器(例如,第一重力除尘器9和第二重力除尘器15),通过竖冷窑除尘器去除经过竖冷窑后的烟气中粉尘。Considering that after the flue gas passes through the vertical cooling kiln, the sinter in the vertical cooling kiln will still produce dust under the action of waste heat and enter the flue gas. In order to prevent this part of dust from polluting subsequent equipment and the atmosphere, it can 8 and C-section waste heat utilization unit 10 and on the connecting pipeline between low temperature section 17 and SCR denitrification unit 19, a vertical cold kiln dust collector (for example, the first gravity dust collector 9 and the second gravity dust collector 15) is arranged, through The vertical cooling kiln dust collector removes the dust in the flue gas after passing through the vertical cooling kiln.

为了进一步提高上述装置的余热回收利用率,在SCR脱硝单元19与烟囱11的连接管道上可以设置A段余热利用单元18。这是因为,A段烟气经过脱硝后,温度仍然能够保持在350℃左右,通过A段余热利用单元18回收经过脱硝后的A段烟气显热,提高上述装置的余热回收利用率。In order to further improve the utilization rate of waste heat recovery of the above-mentioned device, a section A waste heat utilization unit 18 may be installed on the connecting pipe between the SCR denitrification unit 19 and the chimney 11 . This is because, after denitrification, the temperature of the flue gas in section A can still be maintained at about 350°C, and the sensible heat of flue gas in section A after denitration can be recovered by the waste heat utilization unit 18 in section A, so as to improve the waste heat recovery utilization rate of the above-mentioned device.

可以理解的是,为了使烧结矿能够落入高温段8中,上述装置还包括破碎筛13,烧结机1中的烧结矿通过破碎筛13落入高温段8中。It can be understood that, in order to allow the sintered ore to fall into the high temperature section 8 , the above device also includes a crushing screen 13 through which the sintered ore in the sintering machine 1 falls into the high temperature section 8 .

另一方面,本发明还提供了一种基于竖冷窑的烧结矿余热回收方法,采用上述基于竖冷窑的烧结矿余热装置,包括如下步骤:On the other hand, the present invention also provides a sinter waste heat recovery method based on a vertical cooling kiln, using the above-mentioned sinter waste heat device based on a vertical cooling kiln, including the following steps:

将烧结原料(例如,铁矿石、燃料、熔剂、返矿和返回料等)送入烧结机进行烧结,生产烧结成品矿的同时产生烟气;B段烟气循环至A段烟道对应的烧结机部分;A段烟气经过脱硫单元脱硫,脱硫后的烟气与竖冷窑的低温段烧结矿进行换热,使得混合后的烟气温度升至SCR脱硝的合适温度,进行脱硝;将C段烟气与竖冷窑的高温段烧结矿进行换热,得到高温烟气,利用余热回收单元进行余热回收。The raw materials for sintering (such as iron ore, fuel, flux, returned ore, and returned materials, etc.) are sent to the sintering machine for sintering, and flue gas is produced while producing sintered finished ore; the flue gas in section B is circulated to the flue corresponding to section A Sintering machine part: the flue gas in section A is desulfurized by the desulfurization unit, and the desulfurized flue gas exchanges heat with the sinter in the low-temperature section of the vertical cooling kiln, so that the temperature of the mixed flue gas rises to the appropriate temperature for SCR denitrification, and denitrification is performed; The flue gas in section C exchanges heat with the sinter in the high-temperature section of the vertical cooling kiln to obtain high-temperature flue gas, which is recovered by using the waste heat recovery unit.

与现有技术相比,本发明提供的基于竖冷窑的烧结矿余热回收方法的有益效果与上述基于竖冷窑的烧结矿余热回收装置的有益效果基本相同,在此不一一赘述。Compared with the prior art, the beneficial effects of the vertical kiln-based sinter waste heat recovery method provided by the present invention are basically the same as those of the above-mentioned vertical kiln-based sinter waste heat recovery device, and will not be repeated here.

实施例一Embodiment one

以某钢210m2烧结机为例,共27个风箱,其烟气浓度见表1。Taking a 210m 2 sintering machine of a certain steel as an example, there are 27 bellows in total, and the flue gas concentration is shown in Table 1.

将1-15号烧结风箱烟气混合为A段烟道,16-21号烧结风箱烟气混合为B段烟道,22-27号烧结风箱烟气混合为C段烟道5,A段烟道烟气量21万Nm3/h,温度77℃,SO2浓度506mg/Nm3,NOx浓度245mg/Nm3;B段烟道烟气量13万Nm3/h,温度178℃,SO2浓度2018mg/Nm3,NOx浓度103mg/Nm3;C段烟道烟气量17万Nm3/h,温度318℃,SO2浓度1447mg/Nm3,NOx浓度15mg/Nm3Mix the flue gas from No. 1-15 sintering bellows into section A flue, mix the flue gas from No. 16-21 sintering bellows into B-section flue, mix the flue gas from No. 22-27 sintering bellows into C-section flue The flue gas volume of section B is 210,000 Nm 3 /h, the temperature is 77°C, the concentration of SO 2 is 506 mg/Nm 3 , and the concentration of NO x is 245 mg/Nm 3 ; the flue gas volume of section B is 130,000 Nm 3 /h, the temperature is 178°C, 2 Concentration 2018mg/Nm 3 , NOx concentration 103mg/Nm 3 ; C-section flue gas volume 170,000 Nm 3 /h, temperature 318°C, SO 2 concentration 1447mg/Nm 3 , NOx concentration 15mg/Nm 3 .

将C段烟气通入高温段,与热烧结矿换热,烧结矿温度700℃,换热后得到高温烟气温度约680℃,利用余热锅炉回收高温烟气余热;将B段循环至烧结机前段,充分利用烧结烟气温度,同时将SO2富集;将A段经除尘、脱硫后,通入低温段,烧结矿温度400℃,换热后得到中温烟气温度约350℃,利用余热锅炉回收烟气余热。Pass the flue gas from section C into the high-temperature section and exchange heat with the hot sinter. The temperature of the sinter is 700°C. The front section of the machine makes full use of the temperature of the sintering flue gas and enriches SO2 at the same time ; after the dust removal and desulfurization of section A, it is passed into the low-temperature section, the temperature of the sintering ore is 400°C, and the temperature of the medium-temperature flue gas is about 350°C after heat exchange. The waste heat boiler recovers the waste heat of the flue gas.

将烧结烟气余热回收分为高品质(680℃)和低品质(300℃),可利用范围更广。The waste heat recovery of sintering flue gas is divided into high-quality (680°C) and low-quality (300°C), which can be used in a wider range.

表1烟气浓度表Table 1 Smoke concentration table

以上所述,仅为本发明较佳的具体实施方式,但本发明的保护范围并不局限于此,任何熟悉本技术领域的技术人员在本发明揭露的技术范围内,可轻易想到的变化或替换,都应涵盖在本发明的保护范围之内。The above is only a preferred embodiment of the present invention, but the scope of protection of the present invention is not limited thereto. Any person skilled in the art within the technical scope disclosed in the present invention can easily think of changes or Replacement should be covered within the protection scope of the present invention.

Claims (10)

1. a kind of based on the sinter waste-heat recovery device for erecting cold kiln, which is characterized in that including sequentially connected sintering machine, wind Case, flue and erect cold kiln;Along sintering machine traffic direction, the flue is divided into A sections of flues, B sections of flues and C sections of flues;It is cold along erecting Kiln direction from top to bottom, it is described to erect cold kiln and be divided into high temperature section and low-temperature zone;
The outlet flue of the A sections of flue is successively connect with desulfurization unit, low-temperature zone, SCR denitration unit and chimney, the B sections of cigarette Flue gas recirculation in road to the corresponding sintering machine partial of A sections of flues, the outlet flue of the C sections of flue successively with high temperature section, more than C sections Heat utilization unit is connected with chimney;
The flue gas SO of the B sections of flue2The flue gas SO of C sections of flues of concentration >2The flue gas SO of A sections of flues of concentration >2Concentration;A sections of cigarettes The flue gas NO in roadXThe flue gas NO of B sections of flues of concentration >XThe flue gas NO of C sections of flues of concentration >XConcentration.
2. according to claim 1 based on the sinter waste-heat recovery device for erecting cold kiln, which is characterized in that the A sections of cigarette Road, B section flue and the ratio of the corresponding bellows number of C sections of flues are 14~16:5~9:4~6.
3. according to claim 1 based on the sinter waste-heat recovery device for erecting cold kiln, which is characterized in that the low-temperature zone Outlet flue at, the temperature of sinter is 400 DEG C~450 DEG C.
4. according to claim 1 based on the sinter waste-heat recovery device for erecting cold kiln, which is characterized in that the high temperature section Smoke inlet be set to the lower part of high temperature section, outlet flue is set to the top of high temperature section;The smoke inlet of the low-temperature zone is set to The lower part of low-temperature zone, outlet flue are set to the top of low-temperature zone.
5. according to claim 1 based on the sinter waste-heat recovery device for erecting cold kiln, which is characterized in that the A sections of cigarette Air-introduced machine is equipped on the connecting line of road and desulfurization unit and on C sections of flue and the connecting line of high temperature section.
6. according to claim 5 based on the sinter waste-heat recovery device for erecting cold kiln, which is characterized in that the air-introduced machine Air inlet before be equipped with air-introduced machine deduster.
7. according to claim 1 based on the sinter waste-heat recovery device for erecting cold kiln, which is characterized in that the high temperature section With on the connecting line of C sections of UTILIZATION OF VESIDUAL HEAT IN units and low-temperature zone with setting on the connecting line of SCR denitration unit is erected cold kiln and removed Dirt device.
8. according to claim 1 based on the sinter waste-heat recovery device for erecting cold kiln, which is characterized in that the SCR is de- The connecting pipe of nitre unit and chimney is equipped with A sections of UTILIZATION OF VESIDUAL HEAT IN units.
9. according to any one of claims 1 to 8 based on the sinter waste-heat recovery device for erecting cold kiln, which is characterized in that It further include broken sieve, the sinter in the sintering machine is fallen into high temperature section by broken sieve.
10. a kind of based on the sinter exhaust heat recovering method for erecting cold kiln, which is characterized in that using such as any one of claim 1 to 9 It is described based on the sinter waste heat apparatus for erecting cold kiln, described method includes following steps:
Raw materials for sintering feeding sintering machine is sintered, generates flue gas while producing sintering finished ores;B sections of flue gas recirculations are to A The corresponding sintering machine partial of section flue;A sections of flue gases pass through desulfurization unit desulfurization, and the flue gas after desulfurization is burnt with the low-temperature zone for erecting cold kiln Knot mine exchanges heat, so that mixed flue-gas temperature rises to the suitable temperature of SCR denitration, carries out denitration;By C sections of flue gases and erect The high temperature section sinter of cold kiln exchanges heat, and obtains high-temperature flue gas, carries out waste heat recycling using waste heat recovery unit.
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