CN109267129A - A kind of spinning pipe internal surface low temperature fast deposition process - Google Patents
A kind of spinning pipe internal surface low temperature fast deposition process Download PDFInfo
- Publication number
- CN109267129A CN109267129A CN201811348614.3A CN201811348614A CN109267129A CN 109267129 A CN109267129 A CN 109267129A CN 201811348614 A CN201811348614 A CN 201811348614A CN 109267129 A CN109267129 A CN 109267129A
- Authority
- CN
- China
- Prior art keywords
- bent
- spinneret
- unbent
- tube
- low temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000009987 spinning Methods 0.000 title claims abstract description 18
- 238000005137 deposition process Methods 0.000 title abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 18
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000007864 aqueous solution Substances 0.000 claims abstract description 10
- 239000000956 alloy Substances 0.000 claims abstract description 9
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 9
- 230000008021 deposition Effects 0.000 claims abstract description 6
- 230000004913 activation Effects 0.000 claims abstract description 4
- 238000005406 washing Methods 0.000 claims abstract description 3
- 238000000034 method Methods 0.000 claims description 12
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 10
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 6
- 239000012670 alkaline solution Substances 0.000 claims description 6
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 6
- 239000000243 solution Substances 0.000 claims description 4
- 238000005868 electrolysis reaction Methods 0.000 claims description 3
- 239000008399 tap water Substances 0.000 claims description 3
- 235000020679 tap water Nutrition 0.000 claims description 3
- 238000004080 punching Methods 0.000 claims description 2
- 239000011734 sodium Substances 0.000 claims 2
- 238000004140 cleaning Methods 0.000 claims 1
- 238000005238 degreasing Methods 0.000 claims 1
- 238000005554 pickling Methods 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 abstract description 9
- 229910052742 iron Inorganic materials 0.000 abstract description 7
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract description 3
- 229910052739 hydrogen Inorganic materials 0.000 abstract description 3
- 239000001257 hydrogen Substances 0.000 abstract description 3
- 238000005728 strengthening Methods 0.000 abstract 1
- 229910000831 Steel Inorganic materials 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 7
- 239000010959 steel Substances 0.000 description 7
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 6
- 239000004810 polytetrafluoroethylene Substances 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 238000005452 bending Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- -1 polytetrafluoroethylene Polymers 0.000 description 3
- 238000005096 rolling process Methods 0.000 description 3
- 230000008859 change Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- 229910000406 trisodium phosphate Inorganic materials 0.000 description 2
- HNNQYHFROJDYHQ-UHFFFAOYSA-N 3-(4-ethylcyclohexyl)propanoic acid 3-(3-ethylcyclopentyl)propanoic acid Chemical compound CCC1CCC(CCC(O)=O)C1.CCC1CCC(CCC(O)=O)CC1 HNNQYHFROJDYHQ-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000005253 cladding Methods 0.000 description 1
- 230000009514 concussion Effects 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical compound FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D7/00—Electroplating characterised by the article coated
- C25D7/04—Tubes; Rings; Hollow bodies
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/34—Pretreatment of metallic surfaces to be electroplated
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D9/00—Electrolytic coating other than with metals
- C25D9/04—Electrolytic coating other than with metals with inorganic materials
- C25D9/08—Electrolytic coating other than with metals with inorganic materials by cathodic processes
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Metal Extraction Processes (AREA)
Abstract
The invention discloses a kind of spinning pipe internal surface low temperature fast deposition process, include the following steps: Step 1: being punched to the concave side to be bent for not being bent spinneret；Step 2: carrying out washing oil processing to the spinneret that is not bent；Step 3: carrying out acid-wash activation to the spinneret that is not bent；Step 4: spinning tube cavity, water circulating pump and the autolyzed alloy cluster compound aqueous solution of high-purity iron family element of not being bent is formed closed cycle；Step 5: the spinneret that is not bent is electrolysed, and open the water circulating pump.The present invention by sprawled in spinning tube outer surface inner surface hydrogen and thus caused by the autolyzed alloy cluster compound of low temperature iron group hydrogenate fast deposition；Using the autolyzed alloy coated layer of iron family element, spinning pipe internal surface high temperature Strengthening and Toughening is realized, achieve the purpose that improve its service life.
Description
Technical field
The present invention relates to Machine Manufacturing Technologies, and in particular to a kind of spinning pipe internal surface low temperature fast deposition process.
Background technique
Wire rod is one of important species of steel products, is widely used in building and Products Industry.At present in world wide
Wire rod annual output accounts for 10% or so of world's steel total output.The main steel country that produces generallys use Total continuity high speed without torsion wire rod essence
Milling train group and controlled cooling technique, the main technique equipment means as wire production.High-speed rod-rolling mill is machine-building skill
The condensation products of art, metallurgical technology and chemical control technique development.
Wire rod is also the second largest steel production kind in China, and annual output accounts for world's production one third or more.Wire rod
Product variety and specification limit are constantly expanding, and wire product quality has tremendous raising, and China has become maximum
Wire production state and exported country.
Wire production develops towards continuous, two Main ways of high speed.High-speed wire mill is one from steel billet to finished product
Continuous production process, Laying head spinneret is to control key equipment from straight line to wire rod that change from of wire rod.Rolled piece after finish rolling
Temperature is approximately kept at 850 DEG C, and speed may be up to 120m/s, and into after spinneret, wire rod causes by pinch roller and Laying head
The comprehensive functions such as motive force, relative inertness power, frictional force, normal pressure under, moved forwards by spinneret, changing linear motion is spiral shell
Rotation movement forms the ballast coil that diameter is about 1080mm and spues from spinneret, and uniform shakedown falls in stelmo line entrance
On roller-way.
With the raising of mill speed, the spinning effect of Laying head is not able to satisfy the requirement of high-speed rolling, problem increasingly
More and more, when especially speed is increased to 85m/s or more, spinning pipe abrasion is violent: since wire rod is violent in spinneret
Relative motion, inner wall is easy to wear or even worn out, and piling of steel accident occurs.The heel and toe wear of spinneret cause service life it is too short and
Spinning exception has been a great problem in wire production.
Summary of the invention
In view of the deficiencies of the prior art, spitting for obdurability under spinneret high temperature can be provided the object of the present invention is to provide a kind of
Fiber tube inner surface low temperature fast deposition process.
To achieve the above object, The technical solution adopted by the invention is as follows:
A kind of spinning pipe internal surface low temperature fast deposition process, includes the following steps:
Step 1: being punched to the concave side to be bent for not being bent spinneret；
Step 2: carrying out washing oil processing to the spinneret that is not bent；
Step 3: carrying out acid-wash activation to the spinneret that is not bent；
Step 4: spinning tube cavity, water circulating pump and the autolyzed alloy bunch of high-purity iron family element of not being bent is closed
Object aqueous solution forms closed cycle；
Step 5: the spinneret that is not bent is electrolysed, and open the water circulating pump.
Further, the step 2 includes carrying out oil removing to the spinneret that is not bent by alkaline solution, then pass through
Tap water cleans the spinneret that is not bent.
Further, the alkaline solution presses NaOH, Na2CO3And Na3PO4Concentration be respectively 50g/L, 30g/L with
And the mode of 30g/L configures.
Further, step 1 specifically include to it is described be not bent spinneret along axial 3/5 part of centre, after bending
The concave side position of spinneret radially, stays the hole of a 2~6mm of diameter every 3~10cm.
Further, step 5 specifically include by it is described be not bent spinneret be placed on mass percent be 5%~30%
The cathode of aqueous sodium carbonate be electrolysed；
After 5-10 minutes to be energised, the water circulating pump is opened；The water circulating pump and electricity are closed after continuing 2 hours
Source.
Further, step 3 specifically includes: being that 1~10% sulfuric acid solution spits described be not bent by mass percent
Fiber tube acid-wash activation.
The present invention by sprawled in spinning tube outer surface inner surface hydrogen and thus caused by low temperature iron group autolyzed conjunction
Golden cluster compound hydrogenates fast deposition；Using the autolyzed alloy coated layer of iron family element, realize that spinning pipe internal surface high temperature is tough
Change, achievees the purpose that improve its service life.
Specific embodiment
The present invention is described in further detail With reference to embodiment.
The invention proposes a kind of low temperature fast deposition process of table in spinneret, to the not curved of not yet progress bending process
Bent spinneret is pre-processed, to improve its high temperature obdurability.The present invention carries out as follows:
S101, it will not be bent spinneret along axial 3/5 part of centre, the concave side portion of spinneret radially after bending
Position, stays the hole of a 2~6mm of diameter every 3~10cm；
It is compound to obtain using paraffin Seal treatment, then by fine needle or the processing of thin stick through-hole when drilled hole is excessive
The aperture that diameter requires；
The purpose of punching is to prevent not being bent spinning tube cavity in subsequent step and the different aqueous solutions of outer surface are obvious
Leakage mixing, but hydrogen sprawling from spinning tube outer surface inner surface when electrolysis processing is not influenced；
S102, it will not be bent spinneret and be connected to water circulating pump, by alkaline solution oil removing, wherein alkaline solution is pressed
NaOH、Na2CO3And Na3PO4Concentration be respectively that the mode of 50g/L, 30g/L and 30g/L configures；Pass through tap water again
The spinneret that is not bent is cleaned；
S103, the spinneret that is not bent is followed for 1~10% sulfuric acid solution with water circulating pump and mass percent
Naphthenic acid is washed to be activated；
S104, the autolyzed alloy cluster compound of high-purity iron family element and water are matched with molar percentage 0.2~1.5:1 ratio
It is set to aqueous solution, putting the autolyzed alloy cluster compound aqueous solution of high-purity iron family element into length is the poly- of 1m*0.5m*0.5m
In tetrafluoroethene slot；Spinneret it is not bent water circulating pump, the autolyzed alloy cluster compound aqueous solution of high-purity iron family element and again
Inner cavity form closed cycle；Paying attention to, which there is no, need to open water circulating pump；
Specifically, it is not bent spinneret both ends and installs PVC material flange, aperture size size is interior with selected spinneret
Diameter is the same.Two end flanges of spinneret all connect corresponding plastic tube, and are fastened with suitable lead screw.Two plastic tube other ends
All fasten with the connection of small-sized cycle water pump interface, and small-sized circulating water pump submerges to be placed in configured cluster compound molten
In the polytetrafluoroethylene (PTFE) slot of liquid, to realize that the closed cycle of cluster compound aqueous solution, guarantee are not bent the certain freedom of spinneret
Degree；
S105 is while retaining the closed cycle of S104, the sodium carbonate that will not be bent spinneret and be placed on 5%~30%
It is electrolysed in aqueous solution, the 1/4 of spinneret specific length and the polytetrafluoroethylene (PTFE) slot of height 0.5m is taken using long 1m, width
For electrolytic cell, and it is not bent spinneret and is placed in cathode end side, anode then uses length 1m, wall thickness 5mm and internal diameter for 10mm
Q235 steel pipe.
Wherein, not being bent spinneret can move freely along the width direction of polytetrafluoroethylene (PTFE) slot electrolytic cell, so as in it
Surface needs the intermediate portions strengthened to be among aqueous sodium carbonate cladding；
In S105, preferably to be not bent spinneret carry out concussion rotation improve reaction effect.
Voltage 0-240V regulated power supply, voltage 120-220V are used when electrolysis, current density is set as 20~200A/
cm2, operation temperature room temperature, energization closes circulating pump and regulated power supply after opening water circulating pump, then 2 hours after 5-10 minutes, heavy
Product finishes.
Those skilled in the art various changes and modifications can be made to the invention without departing from spirit of the invention and
Range.In this way, if these modifications and changes of the present invention belongs within the scope of the claims in the present invention and its equivalent technology,
Then the present invention is also intended to include these modifications and variations.
Claims (6)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811348614.3A CN109267129A (en) | 2018-11-13 | 2018-11-13 | A kind of spinning pipe internal surface low temperature fast deposition process |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811348614.3A CN109267129A (en) | 2018-11-13 | 2018-11-13 | A kind of spinning pipe internal surface low temperature fast deposition process |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109267129A true CN109267129A (en) | 2019-01-25 |
Family
ID=65192751
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811348614.3A Pending CN109267129A (en) | 2018-11-13 | 2018-11-13 | A kind of spinning pipe internal surface low temperature fast deposition process |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109267129A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS54121239A (en) * | 1978-03-14 | 1979-09-20 | Toshiba Corp | Plating internal surface of elongated metal pipe |
| CN1136333A (en) * | 1993-11-16 | 1996-11-20 | 安大略水疗处 | Metal tube having a section with an internal electroplated structural layer |
| CN1465753A (en) * | 2002-06-25 | 2004-01-07 | 首钢总公司 | Crystallizer inner surface electroplating method |
| CN201793784U (en) * | 2010-09-29 | 2011-04-13 | 成都四威高科技产业园有限公司 | High-speed silvering device for bent waveguide cavity |
-
2018
- 2018-11-13 CN CN201811348614.3A patent/CN109267129A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS54121239A (en) * | 1978-03-14 | 1979-09-20 | Toshiba Corp | Plating internal surface of elongated metal pipe |
| CN1136333A (en) * | 1993-11-16 | 1996-11-20 | 安大略水疗处 | Metal tube having a section with an internal electroplated structural layer |
| CN1465753A (en) * | 2002-06-25 | 2004-01-07 | 首钢总公司 | Crystallizer inner surface electroplating method |
| CN201793784U (en) * | 2010-09-29 | 2011-04-13 | 成都四威高科技产业园有限公司 | High-speed silvering device for bent waveguide cavity |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190125 |
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| RJ01 | Rejection of invention patent application after publication |