CN109265020A - A kind of novel glass fiber size - Google Patents
A kind of novel glass fiber size Download PDFInfo
- Publication number
- CN109265020A CN109265020A CN201811316384.2A CN201811316384A CN109265020A CN 109265020 A CN109265020 A CN 109265020A CN 201811316384 A CN201811316384 A CN 201811316384A CN 109265020 A CN109265020 A CN 109265020A
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- parts
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Classifications
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/465—Coatings containing composite materials
- C03C25/47—Coatings containing composite materials containing particles, fibres or flakes, e.g. in a continuous phase
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/24—Coatings containing organic materials
- C03C25/255—Oils, waxes, fats or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/24—Coatings containing organic materials
- C03C25/26—Macromolecular compounds or prepolymers
- C03C25/32—Macromolecular compounds or prepolymers obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
- C03C25/321—Starch; Starch derivatives
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/24—Coatings containing organic materials
- C03C25/40—Organo-silicon compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Composite Materials (AREA)
- Surface Treatment Of Glass Fibres Or Filaments (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses a kind of novel glass fiber sizes, it is made of by weight the following raw material: 30-40 parts of polypropylene wax emulsion, 15-20 parts of modified starch, 8-13 parts of polyvinyl acetate, 2-6 parts of silane coupling agent, 1-4 parts of neopelex, 1-3 parts of fluorocarbon surfactant, 5-8 parts of Purple Perilla Seed Oil, 3-6 parts of modified nano zinc oxide, 2-5 parts of graphene, 1-2 parts of lubricant, 0.5-1 parts of pH adjusting agent, 2-4 parts of nano-titanium dioxide, 0.5-1 parts of defoaming agent, 70-85 parts of water, the present invention has carried out reasonable proportion to the component of size, the film forming greasy property of size entirety has wherein been effectively ensured with modified starch component, glass fiber yarn mechanical property after infiltration has very big promotion, the Purple Perilla Seed Oil and silane of addition are even Connection agent ingredient improves lubrication, plasticising and the antibacterial effect of size.
Description
Technical field
The present invention relates to glass surface paint-on technique field, specifically a kind of novel glass fiber size.
Background technique
The advantages such as electronic-grade glass fiber cloth has grammes per square metre uniform, and dielectric constant is low become most widely used at present and cover copper
Plate enhancing base materials, according to IPC association announce data from the point of view of, glass fabric base copper-clad plate account for the 50% of whole market share with
On.
Electronic-grade glass fiber cloth is to be process by electron level spun yarn by processes such as weaving post-processings, and post-processing is
Except glass fabric sealer and coat can be with the production technology of the chemical component in conjunction with matrix resin, after post treatment work
Artistic skill assigns the various aft-loaded airfoil performances of electronic-grade glass fiber cloth.
The final products of electronic-grade glass fiber cloth are printed circuit board, for producing various electronic equipments.With electronics
The rapid development of industry, product develop towards light, thin, small direction, therefore original part integrated level to printed circuit board and heat-resisting
The requirement of property is more and more stringent.And most of electronics cloths of market are common process agent processing at present, it is difficult to meet high-end customer
Requirement.
Summary of the invention
It is mentioned above in the background art to solve the purpose of the present invention is to provide a kind of novel glass fiber size
Problem.
To achieve the above object, the invention provides the following technical scheme:
A kind of novel glass fiber size is made of by weight the following raw material:
30-40 parts of polypropylene wax emulsion, 15-20 parts of modified starch, 8-13 parts of polyvinyl acetate, silane coupling agent 2-6
Part, 1-4 parts of neopelex, 1-3 parts of fluorocarbon surfactant, 5-8 parts of Purple Perilla Seed Oil, modified nano zinc oxide 3-6
Part, 2-5 parts of graphene, 1-2 parts of lubricant, 0.5-1 parts of pH adjusting agent, 2-4 parts of nano-titanium dioxide, 0.5-1 parts of defoaming agent, water
70-85 parts.
A kind of novel glass fiber size is made of by weight the following raw material:
30 parts of polypropylene wax emulsion, 15 parts of modified starch, 8 parts of polyvinyl acetate, 2 parts of silane coupling agent, dodecyl
1 part of benzene sulfonic acid sodium salt, 1 part of fluorocarbon surfactant, 5 parts of Purple Perilla Seed Oil, 3 parts of modified nano zinc oxide, 2 parts of graphene, lubricant 1
Part, 0.5 part of pH adjusting agent, 2 parts of nano-titanium dioxide, 0.5 part of defoaming agent, 70 parts of water.
A kind of novel glass fiber size is made of by weight the following raw material:
40 parts of polypropylene wax emulsion, 20 parts of modified starch, 13 parts of polyvinyl acetate, 6 parts of silane coupling agent, dodecyl
4 parts of benzene sulfonic acid sodium salt, 3 parts of fluorocarbon surfactant, 8 parts of Purple Perilla Seed Oil, 6 parts of modified nano zinc oxide, 5 parts of graphene, lubricant 2
Part, 1 part of pH adjusting agent, 4 parts of nano-titanium dioxide, 1 part of defoaming agent, 85 parts of water.
A kind of novel glass fiber size is made of by weight the following raw material:
35 parts of polypropylene wax emulsion, 18 parts of modified starch, 11 parts of polyvinyl acetate, 4 parts of silane coupling agent, dodecyl
2.5 parts of benzene sulfonic acid sodium salt, 2 parts of fluorocarbon surfactant, 6.5 parts of Purple Perilla Seed Oil, 5 parts of modified nano zinc oxide, 3.5 parts of graphene,
1.5 parts of lubricant, 0.8 part of pH adjusting agent, 3 parts of nano-titanium dioxide, 0.8 part of defoaming agent, 78 parts of water.
The polypropylene wax emulsion number-average molecular weight is 30000~80000.
The modified starch is epoxy resin modification potato starch, reaction condition are as follows: potato starch 25g, epoxy resin contain
Amount be 10wt%, NaOH content 2g, 93 DEG C of reaction temperature, reaction time 6h.
The modified nano zinc oxide the preparation method is as follows: by nano zine oxide be impregnated in amino-modified silicone oil just oneself
It in alkane solvents, is evaporated after mixing evenly, is placed in dry 30-40min in the baking oven that temperature is 120 DEG C, deposition ammonia is made
The nano zine oxide of base modified silicon oil；It places it in Muffle furnace again, carries out high-temperature roasting, amino-modified silicone oil is made to be converted to two
Silica obtains the modified nano zinc oxide that surface is deposited with silica.
The pH adjusting agent is citric acid.
Compared with prior art, the beneficial effects of the present invention are:
The present invention has carried out reasonable proportion to the component of size, wherein infiltration has been effectively ensured with modified starch component
The film forming greasy property of agent entirety, the glass fiber yarn mechanical property after infiltration have very big promotion, and breaking strength values reach
0.45N·tex-1.The Purple Perilla Seed Oil and silane coupling agent ingredient of addition improve lubrication, plasticising and the antibacterial effect of size,
It is added to nano-titanium dioxide ingredient again, short grained titanium dioxide content can not only promote the consistency of size film forming and right
Glass fibre wraps effect, while improving its processing quality, reduces rejection rate；
The present invention improves the dispersibility and stabilization of nano zine oxide nanometer by effective modification to nano zine oxide
Property, the surface polarity of its nano material is greatly reduced, dispersibility and affinity of the nanoparticle in size are improved, is expanded
The applicability of big nano zine oxide；
Size of the invention can effectively improve the impregnation performance of glass fibre, and resin impregnated rate mentions in the unit time
It is high.And the mechanical strength and heat resistance of plate also can be all effectively improved.
Specific embodiment
Embodiment 1
A kind of novel glass fiber size is made of by weight the following raw material:
30 parts of polypropylene wax emulsion, 15 parts of modified starch, 8 parts of polyvinyl acetate, 2 parts of silane coupling agent, dodecyl
1 part of benzene sulfonic acid sodium salt, 1 part of fluorocarbon surfactant, 5 parts of Purple Perilla Seed Oil, 3 parts of modified nano zinc oxide, 2 parts of graphene, lubricant 1
Part, 0.5 part of pH adjusting agent, 2 parts of nano-titanium dioxide, 0.5 part of defoaming agent, 70 parts of water.
The polypropylene wax emulsion number-average molecular weight is 30000~80000.
The modified starch is epoxy resin modification potato starch, reaction condition are as follows: potato starch 25g, epoxy resin contain
Amount be 10wt%, NaOH content 2g, 93 DEG C of reaction temperature, reaction time 6h.
The modified nano zinc oxide the preparation method is as follows: by nano zine oxide be impregnated in amino-modified silicone oil just oneself
It in alkane solvents, is evaporated after mixing evenly, is placed in dry 30-40min in the baking oven that temperature is 120 DEG C, deposition ammonia is made
The nano zine oxide of base modified silicon oil；It places it in Muffle furnace again, carries out high-temperature roasting, amino-modified silicone oil is made to be converted to two
Silica obtains the modified nano zinc oxide that surface is deposited with silica.
The pH adjusting agent is citric acid.
Embodiment 2
A kind of novel glass fiber size is made of by weight the following raw material:
40 parts of polypropylene wax emulsion, 20 parts of modified starch, 13 parts of polyvinyl acetate, 6 parts of silane coupling agent, dodecyl
4 parts of benzene sulfonic acid sodium salt, 3 parts of fluorocarbon surfactant, 8 parts of Purple Perilla Seed Oil, 6 parts of modified nano zinc oxide, 5 parts of graphene, lubricant 2
Part, 1 part of pH adjusting agent, 4 parts of nano-titanium dioxide, 1 part of defoaming agent, 85 parts of water.
The polypropylene wax emulsion number-average molecular weight is 30000~80000.
The modified starch is epoxy resin modification potato starch, reaction condition are as follows: potato starch 25g, epoxy resin contain
Amount be 10wt%, NaOH content 2g, 93 DEG C of reaction temperature, reaction time 6h.
The modified nano zinc oxide the preparation method is as follows: by nano zine oxide be impregnated in amino-modified silicone oil just oneself
It in alkane solvents, is evaporated after mixing evenly, is placed in dry 30-40min in the baking oven that temperature is 120 DEG C, deposition ammonia is made
The nano zine oxide of base modified silicon oil；It places it in Muffle furnace again, carries out high-temperature roasting, amino-modified silicone oil is made to be converted to two
Silica obtains the modified nano zinc oxide that surface is deposited with silica.
The pH adjusting agent is citric acid.
Embodiment 3
A kind of novel glass fiber size is made of by weight the following raw material:
35 parts of polypropylene wax emulsion, 18 parts of modified starch, 11 parts of polyvinyl acetate, 4 parts of silane coupling agent, dodecyl
2.5 parts of benzene sulfonic acid sodium salt, 2 parts of fluorocarbon surfactant, 6.5 parts of Purple Perilla Seed Oil, 5 parts of modified nano zinc oxide, 3.5 parts of graphene,
1.5 parts of lubricant, 0.8 part of pH adjusting agent, 3 parts of nano-titanium dioxide, 0.8 part of defoaming agent, 78 parts of water.
The polypropylene wax emulsion number-average molecular weight is 30000~80000.
The modified starch is epoxy resin modification potato starch, reaction condition are as follows: potato starch 25g, epoxy resin contain
Amount be 10wt%, NaOH content 2g, 93 DEG C of reaction temperature, reaction time 6h.
The modified nano zinc oxide the preparation method is as follows: by nano zine oxide be impregnated in amino-modified silicone oil just oneself
It in alkane solvents, is evaporated after mixing evenly, is placed in dry 30-40min in the baking oven that temperature is 120 DEG C, deposition ammonia is made
The nano zine oxide of base modified silicon oil；It places it in Muffle furnace again, carries out high-temperature roasting, amino-modified silicone oil is made to be converted to two
Silica obtains the modified nano zinc oxide that surface is deposited with silica.
The pH adjusting agent is citric acid.
Claims (8)
1. a kind of novel glass fiber size, which is characterized in that be made of by weight the following raw material:
30-40 parts of polypropylene wax emulsion, 15-20 parts of modified starch, 8-13 parts of polyvinyl acetate, 2-6 parts of silane coupling agent, ten
1-4 parts of dialkyl benzene sulfonic acids sodium, 1-3 parts of fluorocarbon surfactant, 5-8 parts of Purple Perilla Seed Oil, 3-6 parts of modified nano zinc oxide, stone
Black alkene 2-5 parts, 1-2 parts of lubricant, 0.5-1 parts of pH adjusting agent, 2-4 parts of nano-titanium dioxide, 0.5-1 parts of defoaming agent, water 70-85
Part.
2. novel glass fiber size according to claim 1, which is characterized in that by the following raw material group by weight
At:
30 parts of polypropylene wax emulsion, 15 parts of modified starch, 8 parts of polyvinyl acetate, 2 parts of silane coupling agent, detergent alkylate sulphur
1 part of sour sodium, 1 part of fluorocarbon surfactant, 5 parts of Purple Perilla Seed Oil, 3 parts of modified nano zinc oxide, 2 parts of graphene, 1 part of lubricant,
0.5 part of pH adjusting agent, 2 parts of nano-titanium dioxide, 0.5 part of defoaming agent, 70 parts of water.
3. novel glass fiber size according to claim 1, which is characterized in that by the following raw material group by weight
At:
40 parts of polypropylene wax emulsion, 20 parts of modified starch, 13 parts of polyvinyl acetate, 6 parts of silane coupling agent, detergent alkylate sulphur
4 parts of sour sodium, 3 parts of fluorocarbon surfactant, 8 parts of Purple Perilla Seed Oil, 6 parts of modified nano zinc oxide, 5 parts of graphene, 2 parts of lubricant,
1 part of pH adjusting agent, 4 parts of nano-titanium dioxide, 1 part of defoaming agent, 85 parts of water.
4. novel glass fiber size according to claim 1, which is characterized in that by the following raw material group by weight
At:
35 parts of polypropylene wax emulsion, 18 parts of modified starch, 11 parts of polyvinyl acetate, 4 parts of silane coupling agent, detergent alkylate sulphur
2.5 parts of sour sodium, 2 parts of fluorocarbon surfactant, 6.5 parts of Purple Perilla Seed Oil, 5 parts of modified nano zinc oxide, 3.5 parts of graphene, lubrication
1.5 parts of agent, 0.8 part of pH adjusting agent, 3 parts of nano-titanium dioxide, 0.8 part of defoaming agent, 78 parts of water.
5. novel glass fiber size according to claim 1, which is characterized in that the polypropylene wax emulsion number is divided equally
Son amount is 30000~80000.
6. novel glass fiber size according to claim 1, which is characterized in that the modified starch is epoxy resin
Modified potato starch, reaction condition are as follows: potato starch 25g, epoxy resin content 10wt%, NaOH content 2g, reaction temperature
93 DEG C of degree, reaction time 6h.
7. novel glass fiber size according to claim 1, which is characterized in that the system of the modified nano zinc oxide
Preparation Method is as follows: nano zine oxide is impregnated in the n-hexane solvent of amino-modified silicone oil, is evaporated after mixing evenly, and
It is placed in dry 30-40min in the baking oven that temperature is 120 DEG C, the nano zine oxide of deposition amino-modified silicone oil is made；It is set again
In Muffle furnace, high-temperature roasting is carried out, so that amino-modified silicone oil is converted to silica, obtains surface and be deposited with silica
Modified nano zinc oxide.
8. novel glass fiber size according to claim 1, which is characterized in that the pH adjusting agent is citric acid.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811316384.2A CN109265020A (en) | 2018-11-07 | 2018-11-07 | A kind of novel glass fiber size |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811316384.2A CN109265020A (en) | 2018-11-07 | 2018-11-07 | A kind of novel glass fiber size |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109265020A true CN109265020A (en) | 2019-01-25 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811316384.2A Pending CN109265020A (en) | 2018-11-07 | 2018-11-07 | A kind of novel glass fiber size |
Country Status (1)
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN117774482A (en) * | 2023-12-15 | 2024-03-29 | 江苏耀鸿电子有限公司 | High-speed low-loss hydrocarbon copper-clad plate and preparation method thereof |
| CN117844400A (en) * | 2024-01-10 | 2024-04-09 | 东莞市益和纸制品有限公司 | Environment-friendly sealing adhesive for corrugated paper and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104894839A (en) * | 2015-06-01 | 2015-09-09 | 北京中铁润海科技有限公司 | Fiber sizing agent having catalytic function and process for preparing fiber structure by adopting same |
| CN105036178A (en) * | 2015-07-20 | 2015-11-11 | 苏州宇希新材料科技有限公司 | Preparation method of modified nano zinc oxide |
| CN108409163A (en) * | 2017-02-09 | 2018-08-17 | 巨石集团有限公司 | A kind of glass fiber infiltration agent and its preparation method and application |
-
2018
- 2018-11-07 CN CN201811316384.2A patent/CN109265020A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104894839A (en) * | 2015-06-01 | 2015-09-09 | 北京中铁润海科技有限公司 | Fiber sizing agent having catalytic function and process for preparing fiber structure by adopting same |
| CN105036178A (en) * | 2015-07-20 | 2015-11-11 | 苏州宇希新材料科技有限公司 | Preparation method of modified nano zinc oxide |
| CN108409163A (en) * | 2017-02-09 | 2018-08-17 | 巨石集团有限公司 | A kind of glass fiber infiltration agent and its preparation method and application |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN117774482A (en) * | 2023-12-15 | 2024-03-29 | 江苏耀鸿电子有限公司 | High-speed low-loss hydrocarbon copper-clad plate and preparation method thereof |
| CN117774482B (en) * | 2023-12-15 | 2024-05-17 | 江苏耀鸿电子有限公司 | High-speed low-loss hydrocarbon copper-clad plate and preparation method thereof |
| CN117844400A (en) * | 2024-01-10 | 2024-04-09 | 东莞市益和纸制品有限公司 | Environment-friendly sealing adhesive for corrugated paper and preparation method thereof |
| CN117844400B (en) * | 2024-01-10 | 2024-09-24 | 东莞市益和纸制品有限公司 | Environment-friendly sealing adhesive for corrugated paper and preparation method thereof |
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Application publication date: 20190125 |