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CN109253322A - A kind of high-temperature oxidation resistant welded still pipe - Google Patents

A kind of high-temperature oxidation resistant welded still pipe Download PDF

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Publication number
CN109253322A
CN109253322A CN201811054207.1A CN201811054207A CN109253322A CN 109253322 A CN109253322 A CN 109253322A CN 201811054207 A CN201811054207 A CN 201811054207A CN 109253322 A CN109253322 A CN 109253322A
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CN
China
Prior art keywords
parts
ingredient
weight shared
outer layer
tin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811054207.1A
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Chinese (zh)
Inventor
章坤元
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhangjiagang Square Pipe Industry Manufacturing Co Ltd
Original Assignee
Zhangjiagang Square Pipe Industry Manufacturing Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zhangjiagang Square Pipe Industry Manufacturing Co Ltd filed Critical Zhangjiagang Square Pipe Industry Manufacturing Co Ltd
Priority to CN201811054207.1A priority Critical patent/CN109253322A/en
Publication of CN109253322A publication Critical patent/CN109253322A/en
Pending legal-status Critical Current

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16LPIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L9/00Rigid pipes
    • F16L9/14Compound tubes, i.e. made of materials not wholly covered by any one of the preceding groups
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B1/00Layered products having a non-planar shape
    • B32B1/08Tubular products
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/18Layered products comprising a layer of metal comprising iron or steel
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/04Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B9/041Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material of metal
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/14Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silica
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C49/00Alloys containing metallic or non-metallic fibres or filaments
    • C22C49/02Alloys containing metallic or non-metallic fibres or filaments characterised by the matrix material
    • C22C49/08Iron group metals
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C49/00Alloys containing metallic or non-metallic fibres or filaments
    • C22C49/14Alloys containing metallic or non-metallic fibres or filaments characterised by the fibres or filaments
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/714Inert, i.e. inert to chemical degradation, corrosion
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2597/00Tubular articles, e.g. hoses, pipes
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3262Manganese oxides, manganates, rhenium oxides or oxide-forming salts thereof, e.g. MnO
    • C04B2235/3267MnO2
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/40Metallic constituents or additives not added as binding phase
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/42Non metallic elements added as constituents or additives, e.g. sulfur, phosphor, selenium or tellurium
    • C04B2235/422Carbon

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • General Engineering & Computer Science (AREA)
  • Metallurgy (AREA)
  • Manufacturing & Machinery (AREA)
  • Structural Engineering (AREA)
  • Rigid Pipes And Flexible Pipes (AREA)
  • Ceramic Products (AREA)

Abstract

The invention discloses a kind of high-temperature oxidation resistant welded still pipes, it include: outer layer and internal layer, the outer layer is by glass fibre, silicon nitride, titanium dioxide and iron composition, the internal layer is by manganese dioxide, quartz sand, carbon and tin composition, parts by weight shared by each ingredient in the outer layer: 2-8 parts of glass fibre, 9-18 parts of silicon nitride, 12-18 parts and iron 20-30 parts of titanium dioxide, parts by weight shared by each ingredient in the internal layer: 4-12 parts of manganese dioxide, 20-30 parts of quartz sand, 1.1-1.8 parts and tin 0.8-1.6 parts of carbon, the outer layer is arranged in inner layer outer surface, and it is connected by way of seamless welding.By the above-mentioned means, high-temperature oxidation resistant welded still pipe provided by the invention, has good inoxidizability.

Description

A kind of high-temperature oxidation resistant welded still pipe
Technical field
The present invention relates to technical field of metal material, more particularly to a kind of high-temperature oxidation resistant welded still pipe.
Background technique
With the continuous progress of science, the place for using welded still pipe is more and more extensive, and welded still pipe is in daily life In served it is sizable, but now tube materials many on the market, antioxygenic property is poor, at high cost, is unable to satisfy people Demand.
Summary of the invention
The invention mainly solves the technical problem of providing a kind of high-temperature oxidation resistant welded still pipes, have good anti-oxidant Property.
In order to solve the above technical problems, one technical scheme adopted by the invention is that: a kind of high-temperature oxidation resistant welding is provided Steel pipe, comprising: outer layer and internal layer, the outer layer are made of glass fibre, silicon nitride, titanium dioxide and iron, and the internal layer is by two Manganese oxide, quartz sand, carbon and tin form, parts by weight shared by each ingredient in the outer layer: 2-8 parts of glass fibre, silicon nitride 9- 18 parts, 12-18 parts of titanium dioxide and 20-30 parts of iron, parts by weight shared by each ingredient in the internal layer: 4-12 parts of manganese dioxide, 20-30 parts of quartz sand, 1.1-1.8 parts of carbon and 0.8-1.6 parts of tin, the outer layer is arranged in inner layer outer surface, and passes through no seam weld The mode connect connects.
In a preferred embodiment of the present invention, parts by weight shared by each ingredient in the outer layer: 2 parts of glass fibre, nitrogen 9 parts of SiClx, 12 parts of titanium dioxide and 20 parts of iron, parts by weight shared by each ingredient in the internal layer: 4 parts of manganese dioxide, quartz sand 20 parts, 1.1 parts of carbon and 0.8 part of tin.
In a preferred embodiment of the present invention, parts by weight shared by each ingredient in the outer layer: 3 parts of glass fibre, nitrogen 11 parts of SiClx, 13 parts of titanium dioxide and 21 parts of iron, parts by weight shared by each ingredient in the internal layer: 5 parts of manganese dioxide, quartz sand 21 parts, 1.2 parts of carbon and 0.9 part of tin.
In a preferred embodiment of the present invention, parts by weight shared by each ingredient in the outer layer: 5 parts of glass fibre, nitrogen 13 parts of SiClx, 14 parts of titanium dioxide and 22 parts of iron, parts by weight shared by each ingredient in the internal layer: 6 parts of manganese dioxide, quartz sand 23 parts, 1.4 parts of carbon and 1.1 parts of tin.
In a preferred embodiment of the present invention, parts by weight shared by each ingredient in the outer layer: 6 parts of glass fibre, nitrogen 14 parts of SiClx, 15 parts of titanium dioxide and 24 parts of iron, parts by weight shared by each ingredient in the internal layer: 7 parts of manganese dioxide, quartz sand 25 parts, 1.5 parts of carbon and 1.2 parts of tin.
In a preferred embodiment of the present invention, parts by weight shared by each ingredient in the outer layer: 7 parts of glass fibre, nitrogen 16 parts of SiClx, 16 parts of titanium dioxide and 26 parts of iron, parts by weight shared by each ingredient in the internal layer: 8 parts of manganese dioxide, quartz sand 26 parts, 1.6 parts of carbon and 1.5 parts of tin.
The beneficial effects of the present invention are: a kind of high-temperature oxidation resistant welded still pipe that the present invention points out, has good antioxygen The property changed.
Specific embodiment
The technical scheme in the embodiments of the invention will be clearly and completely described below, it is clear that described implementation Example is only a part of the embodiments of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field is common Technical staff's all other embodiment obtained without making creative work belongs to the model that the present invention protects It encloses.
Embodiment 1: parts by weight shared by each ingredient in the outer layer: 2 parts of glass fibre, 9 parts of silicon nitride, titanium dioxide 12 Part and 20 parts of iron, parts by weight shared by each ingredient in the internal layer: 4 parts of manganese dioxide, 20 parts of quartz sand, 1.1 parts of carbon and tin 0.8 Part.
Embodiment 2: parts by weight shared by each ingredient in the outer layer: 3 parts of glass fibre, 11 parts of silicon nitride, titanium dioxide 13 parts and 21 parts of iron, parts by weight shared by each ingredient in the internal layer: 5 parts of manganese dioxide, 21 parts of quartz sand, 1.2 parts of carbon and tin 0.9 part.
Embodiment 3: parts by weight shared by each ingredient in the outer layer: 5 parts of glass fibre, 13 parts of silicon nitride, titanium dioxide 14 parts and 22 parts of iron, parts by weight shared by each ingredient in the internal layer: 6 parts of manganese dioxide, 23 parts of quartz sand, 1.4 parts of carbon and tin 1.1 part.
Embodiment 4: parts by weight shared by each ingredient in the outer layer: 6 parts of glass fibre, 14 parts of silicon nitride, titanium dioxide 15 parts and 24 parts of iron, parts by weight shared by each ingredient in the internal layer: 7 parts of manganese dioxide, 25 parts of quartz sand, 1.5 parts of carbon and tin 1.2 part.
Embodiment 5: parts by weight shared by each ingredient in the outer layer: 7 parts of glass fibre, 16 parts of silicon nitride, titanium dioxide 16 parts and 26 parts of iron, parts by weight shared by each ingredient in the internal layer: 8 parts of manganese dioxide, 26 parts of quartz sand, 1.6 parts of carbon and tin 1.5 part.
Test case:
Sample is exposed in the laboratory atmosphere of high temperature, weighing is taken out in sample hot environment after 1000 hours, can be calculated The degree that scale is formed out.Corresponding oxidation is obtained by the weight change (milli gram/cm) after measurement high-temperature process Test result.The average weight variation that each sample measures is as shown in table 1.
Table 1: high temperature antioxidant
Weight change (mg/cm2)
Test temperature 800℃ 1000℃
Embodiment 1 0.119 0.319
Embodiment 2 0.126 0.325
Embodiment 3 0.115 0.338
Embodiment 4 0.127 0.330
Embodiment 5 0.122 0.331
Existing product 0.371 0.886
In conclusion a kind of high-temperature oxidation resistant welded still pipe that the present invention points out, has good inoxidizability.
The above description is only an embodiment of the present invention, is not intended to limit the scope of the invention, all to utilize this hair Equivalent structure or equivalent flow shift made by bright description is applied directly or indirectly in other relevant technology necks Domain is included within the scope of the present invention.

Claims (6)

1. a kind of high-temperature oxidation resistant welded still pipe characterized by comprising outer layer and internal layer, the outer layer is by glass fibre, nitrogen SiClx, titanium dioxide and iron composition, the internal layer are made of manganese dioxide, quartz sand, carbon and tin, each ingredient institute in the outer layer Account for parts by weight: 2-8 parts of glass fibre, 9-18 parts of silicon nitride, 12-18 parts of titanium dioxide and 20-30 parts of iron, it is each in the internal layer Parts by weight shared by ingredient: 4-12 parts of manganese dioxide, 20-30 parts of quartz sand, 1.1-1.8 parts of carbon and 0.8-1.6 parts of tin, it is described outer Layer setting is connected in inner layer outer surface, and by way of seamless welding.
2. high-temperature oxidation resistant welded still pipe according to claim 1, which is characterized in that weight shared by each ingredient in the outer layer Number: 2 parts of glass fibre, 9 parts of silicon nitride, 12 parts of titanium dioxide and 20 parts of iron is measured, parts by weight shared by each ingredient in the internal layer Number: 4 parts of manganese dioxide, 20 parts of quartz sand, 1.1 parts of carbon and 0.8 part of tin.
3. high-temperature oxidation resistant welded still pipe according to claim 1, which is characterized in that weight shared by each ingredient in the outer layer Number: 3 parts of glass fibre, 11 parts of silicon nitride, 13 parts of titanium dioxide and 21 parts of iron is measured, parts by weight shared by each ingredient in the internal layer Number: 5 parts of manganese dioxide, 21 parts of quartz sand, 1.2 parts of carbon and 0.9 part of tin.
4. high-temperature oxidation resistant welded still pipe according to claim 1, which is characterized in that weight shared by each ingredient in the outer layer Number: 5 parts of glass fibre, 13 parts of silicon nitride, 14 parts of titanium dioxide and 22 parts of iron is measured, parts by weight shared by each ingredient in the internal layer Number: 6 parts of manganese dioxide, 23 parts of quartz sand, 1.4 parts of carbon and 1.1 parts of tin.
5. high-temperature oxidation resistant welded still pipe according to claim 1, which is characterized in that weight shared by each ingredient in the outer layer Number: 6 parts of glass fibre, 14 parts of silicon nitride, 15 parts of titanium dioxide and 24 parts of iron is measured, parts by weight shared by each ingredient in the internal layer Number: 7 parts of manganese dioxide, 25 parts of quartz sand, 1.5 parts of carbon and 1.2 parts of tin.
6. high-temperature oxidation resistant welded still pipe according to claim 1, which is characterized in that weight shared by each ingredient in the outer layer Number: 7 parts of glass fibre, 16 parts of silicon nitride, 16 parts of titanium dioxide and 26 parts of iron is measured, parts by weight shared by each ingredient in the internal layer Number: 8 parts of manganese dioxide, 26 parts of quartz sand, 1.6 parts of carbon and 1.5 parts of tin.
CN201811054207.1A 2018-09-11 2018-09-11 A kind of high-temperature oxidation resistant welded still pipe Pending CN109253322A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811054207.1A CN109253322A (en) 2018-09-11 2018-09-11 A kind of high-temperature oxidation resistant welded still pipe

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201811054207.1A CN109253322A (en) 2018-09-11 2018-09-11 A kind of high-temperature oxidation resistant welded still pipe

Publications (1)

Publication Number Publication Date
CN109253322A true CN109253322A (en) 2019-01-22

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1405355A (en) * 2001-08-04 2003-03-26 山东科技大学机械电子工程学院 Method for depositing paint-coat of metal surface, especially for gradient paint-coat
CN107032815A (en) * 2017-03-31 2017-08-11 长乐巧通工业设计有限公司 High ceramic material of a kind of compression strength and preparation method thereof
CN107824819A (en) * 2017-12-19 2018-03-23 苏州中骏木工机械配件有限公司 A kind of high intensity wear-resistant cutting tool

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1405355A (en) * 2001-08-04 2003-03-26 山东科技大学机械电子工程学院 Method for depositing paint-coat of metal surface, especially for gradient paint-coat
CN107032815A (en) * 2017-03-31 2017-08-11 长乐巧通工业设计有限公司 High ceramic material of a kind of compression strength and preparation method thereof
CN107824819A (en) * 2017-12-19 2018-03-23 苏州中骏木工机械配件有限公司 A kind of high intensity wear-resistant cutting tool

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Application publication date: 20190122