CN109250945A - A kind of polycarboxylic acid water reducing agent - Google Patents
A kind of polycarboxylic acid water reducing agent Download PDFInfo
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- CN109250945A CN109250945A CN201810390090.8A CN201810390090A CN109250945A CN 109250945 A CN109250945 A CN 109250945A CN 201810390090 A CN201810390090 A CN 201810390090A CN 109250945 A CN109250945 A CN 109250945A
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- China
- Prior art keywords
- parts
- reducing agent
- water reducing
- polycarboxylic acid
- acid water
- Prior art date
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- 239000003638 chemical reducing agent Substances 0.000 title claims abstract description 80
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 68
- 239000002253 acid Substances 0.000 title claims abstract description 59
- 239000003755 preservative agent Substances 0.000 claims abstract description 23
- 230000002335 preservative effect Effects 0.000 claims abstract description 23
- 239000003999 initiator Substances 0.000 claims abstract description 22
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims abstract description 18
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 18
- 238000004132 cross linking Methods 0.000 claims abstract description 18
- 239000000178 monomer Substances 0.000 claims abstract description 18
- AEQDJSLRWYMAQI-UHFFFAOYSA-N 2,3,9,10-tetramethoxy-6,8,13,13a-tetrahydro-5H-isoquinolino[2,1-b]isoquinoline Chemical compound C1CN2CC(C(=C(OC)C=C3)OC)=C3CC2C2=C1C=C(OC)C(OC)=C2 AEQDJSLRWYMAQI-UHFFFAOYSA-N 0.000 claims abstract description 17
- DKIDEFUBRARXTE-UHFFFAOYSA-N 3-mercaptopropanoic acid Chemical compound OC(=O)CCS DKIDEFUBRARXTE-UHFFFAOYSA-N 0.000 claims abstract description 17
- JPAOMENBKRZQDR-UHFFFAOYSA-N CC=CC.[Na] Chemical compound CC=CC.[Na] JPAOMENBKRZQDR-UHFFFAOYSA-N 0.000 claims abstract description 17
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 claims abstract description 17
- 150000007942 carboxylates Chemical class 0.000 claims abstract description 17
- 229940051841 polyoxyethylene ether Drugs 0.000 claims abstract description 17
- 229920000056 polyoxyethylene ether Polymers 0.000 claims abstract description 17
- 239000000176 sodium gluconate Substances 0.000 claims abstract description 17
- 229940005574 sodium gluconate Drugs 0.000 claims abstract description 17
- 235000012207 sodium gluconate Nutrition 0.000 claims abstract description 17
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims abstract description 17
- KWSLGOVYXMQPPX-UHFFFAOYSA-N 5-[3-(trifluoromethyl)phenyl]-2h-tetrazole Chemical compound FC(F)(F)C1=CC=CC(C2=NNN=N2)=C1 KWSLGOVYXMQPPX-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229910001379 sodium hypophosphite Inorganic materials 0.000 claims abstract description 16
- HXKKHQJGJAFBHI-UHFFFAOYSA-N 1-aminopropan-2-ol Chemical compound CC(O)CN HXKKHQJGJAFBHI-UHFFFAOYSA-N 0.000 claims abstract description 15
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000013067 intermediate product Substances 0.000 claims description 20
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 18
- 230000009471 action Effects 0.000 claims description 9
- 229920000881 Modified starch Polymers 0.000 claims description 6
- 239000004368 Modified starch Substances 0.000 claims description 6
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 6
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 6
- 239000011976 maleic acid Substances 0.000 claims description 6
- 235000019426 modified starch Nutrition 0.000 claims description 6
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 5
- 150000002170 ethers Chemical class 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 5
- 239000011734 sodium Substances 0.000 claims description 5
- 229910052708 sodium Inorganic materials 0.000 claims description 5
- VYGBQXDNOUHIBZ-UHFFFAOYSA-L sodium formaldehyde sulphoxylate Chemical class [Na+].[Na+].O=C.[O-]S[O-] VYGBQXDNOUHIBZ-UHFFFAOYSA-L 0.000 claims description 5
- 150000008065 acid anhydrides Chemical class 0.000 claims 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical group [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims 1
- 239000011574 phosphorus Substances 0.000 claims 1
- 229910052698 phosphorus Inorganic materials 0.000 claims 1
- 238000010276 construction Methods 0.000 abstract description 4
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- 238000004904 shortening Methods 0.000 abstract description 3
- 230000006872 improvement Effects 0.000 description 8
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 238000013268 sustained release Methods 0.000 description 3
- 239000012730 sustained-release form Substances 0.000 description 3
- RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- ZZVUWRFHKOJYTH-UHFFFAOYSA-N diphenhydramine Chemical compound C=1C=CC=CC=1C(OCCN(C)C)C1=CC=CC=C1 ZZVUWRFHKOJYTH-UHFFFAOYSA-N 0.000 description 2
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 2
- -1 polyoxy Polymers 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- JHUFGBSGINLPOW-UHFFFAOYSA-N 3-chloro-4-(trifluoromethoxy)benzoyl cyanide Chemical compound FC(F)(F)OC1=CC=C(C(=O)C#N)C=C1Cl JHUFGBSGINLPOW-UHFFFAOYSA-N 0.000 description 1
- RGHNJXZEOKUKBD-UHFFFAOYSA-N D-gluconic acid Natural products OCC(O)C(O)C(O)C(O)C(O)=O RGHNJXZEOKUKBD-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 238000009435 building construction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000004035 construction material Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- HRKQOINLCJTGBK-UHFFFAOYSA-N dihydroxidosulfur Chemical compound OSO HRKQOINLCJTGBK-UHFFFAOYSA-N 0.000 description 1
- MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000000174 gluconic acid Substances 0.000 description 1
- 235000012208 gluconic acid Nutrition 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- ACVYVLVWPXVTIT-UHFFFAOYSA-N phosphinic acid Chemical compound O[PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-N 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
- C04B24/16—Sulfur-containing compounds
- C04B24/161—Macromolecular compounds comprising sulfonate or sulfate groups
- C04B24/163—Macromolecular compounds comprising sulfonate or sulfate groups obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C04B24/165—Macromolecular compounds comprising sulfonate or sulfate groups obtained by reactions only involving carbon-to-carbon unsaturated bonds containing polyether side chains
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B40/00—Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
- C04B40/0028—Aspects relating to the mixing step of the mortar preparation
- C04B40/0039—Premixtures of ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/06—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polyethers, polyoxymethylenes or polyacetals
- C08F283/065—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polyethers, polyoxymethylenes or polyacetals on to unsaturated polyethers, polyoxymethylenes or polyacetals
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/30—Water reducers, plasticisers, air-entrainers, flow improvers
- C04B2103/302—Water reducers
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Polymerisation Methods In General (AREA)
Abstract
The present invention provides a kind of polycarboxylic acid water reducing agent, it includes following component by weight percentage: unsaturated polyoxyethylene ether 14-21 parts, 2.8-3.5 parts of slow release high-efficiency water-reducing agent, 3.8-12.5 parts of lauryl sodium sulfate, 5.5-8.5 parts of acrylic acid, 5-10 parts of cross-linking monomer, 11-26 parts of diethanol monoisopropanolamine, 8-20 parts of sodium gluconate, 1.6-3.0 parts of maleic anhydride, 8-16 parts of mercaptopropionic acid, 1-2 parts of N- dimethyl cyclohexyl amine, 3.5-7.5 parts of carboxylate, 7-9 parts of methylpropene sodium sulfonate, 8-13 parts of sodium hypophosphite, 3-5 parts of initiator, 6-12 parts of preservative.The water-reducing agent that the production method of high-performance water reducing agent of the invention provides can reduce the water being added in concrete construction, be conducive to the setting time for shortening concrete, and improve the intensity of concrete.
Description
Technical field
The present invention relates to a kind of concrete additive technical field more particularly to a kind of polycarboxylic acid water reducing agents.
Background technique
Concrete is the construction material that the realm of building construction often needs to use.In the actual construction process, in order to enable
Each component is sufficiently mixed in concrete, is needed for concrete to be stirred with a certain amount of water and is mixed.Due to concrete middle reaches
The water of amorph is less, therefore usually requires the more water of addition and mixed.It is coagulated however, excessive water is added and increases concrete
Solid time.Therefore, in view of the above-mentioned problems, it is necessary to propose further solution.
Summary of the invention
The purpose of the present invention is to provide a kind of polycarboxylic acid water reducing agents, to overcome the deficiencies in the prior art.
For achieving the above object, the present invention provides a kind of polycarboxylic acid water reducing agent, by weight percentage includes such as
Lower component: unsaturated polyoxyethylene ether 14-21 parts, 2.8-3.5 parts of slow release high-efficiency water-reducing agent, lauryl sodium sulfate 3.8-
12.5 parts, 5.5-8.5 parts of acrylic acid, 5-10 parts of cross-linking monomer, 11-26 parts of diethanol monoisopropanolamine, sodium gluconate 8-20
Part, 1.6-3.0 parts of maleic anhydride, 8-16 parts of mercaptopropionic acid, 1-2 parts of N- dimethyl cyclohexyl amine, 3.5-7.5 parts of carboxylate,
7-9 parts of methylpropene sodium sulfonate, 8-13 parts of sodium hypophosphite, 3-5 parts of initiator, 6-12 parts of preservative.
As the improvement of polycarboxylic acid water reducing agent of the invention, the polycarboxylic acid water reducing agent includes such as by weight percentage
Lower component: 15 parts of unsaturated polyoxyethylene ether, 2.8 parts of slow release high-efficiency water-reducing agent, 4.8 parts of lauryl sodium sulfate, acrylic acid
6.5 parts, 7.5 parts of cross-linking monomer, 17.5 parts of diethanol monoisopropanolamine, 16.5 parts of sodium gluconate, maleic anhydride 2.8
Part, 8.9 parts of mercaptopropionic acid, 1.5 parts of N- dimethyl cyclohexyl amine, 5.5 parts of carboxylate, 8.5 parts of methylpropene sodium sulfonate, sodium hypophosphite
10.5 parts, 4.5 parts of initiator, 8.5 parts of preservative.
As the improvement of polycarboxylic acid water reducing agent of the invention, the polycarboxylic acid water reducing agent includes such as by weight percentage
Lower component: 20 parts of unsaturated polyoxyethylene ether, 3.5 parts of slow release high-efficiency water-reducing agent, 12.5 parts of lauryl sodium sulfate, acrylic acid
8.5 parts, 10 parts of cross-linking monomer, diethanol monoisopropanolamine 11-26,8 parts of sodium gluconate, 2.6 parts of maleic anhydride, sulfydryl
8 parts of propionic acid, 6 parts of carboxylate, 7.5 parts of methylpropene sodium sulfonate, 11.5 parts of sodium hypophosphite, causes 1.5 parts of N- dimethyl cyclohexyl amine
5 parts of agent, 6 parts of preservative.
As the improvement of polycarboxylic acid water reducing agent of the invention, the polycarboxylic acid water reducing agent includes such as by weight percentage
Lower component: 18 parts of unsaturated polyoxyethylene ether, 3.3 parts of slow release high-efficiency water-reducing agent, 16.5 parts of lauryl sodium sulfate, acrylic acid
7.2 parts, 8.5 parts of cross-linking monomer, 17.5 parts of diethanol monoisopropanolamine, 17.5 parts of sodium gluconate, maleic anhydride 2.8
Part, 8.9 parts of mercaptopropionic acid, 1.5 parts of N- dimethyl cyclohexyl amine, 5.5 parts of carboxylate, 8.5 parts of methylpropene sodium sulfonate, sodium hypophosphite
10.5 parts, 4.4 parts of initiator, 11.5 parts of preservative.
As the improvement of polycarboxylic acid water reducing agent of the invention, the polycarboxylic acid water reducing agent also wraps by weight percentage
It includes: 1.5-2.0 parts of sodium formaldehyde sulphoxylates, 2-3.5 parts of modified starch ethers.
As the improvement of polycarboxylic acid water reducing agent of the invention, the polycarboxylic acid water reducing agent also wraps by weight percentage
It includes: 1.8 parts of sodium formaldehyde sulphoxylates, 2.5 parts of modified starch ethers.
As the improvement of polycarboxylic acid water reducing agent of the invention, the polycarboxylic acid water reducing agent also wraps by weight percentage
It includes: 6-19 parts of ethylene glycol, 4-9 parts of maleic acid.
As the improvement of polycarboxylic acid water reducing agent of the invention, the polycarboxylic acid water reducing agent also wraps by weight percentage
It includes: 7 parts of ethylene glycol, 8 parts of maleic acid.
As the improvement of polycarboxylic acid water reducing agent of the invention, the production method of the polycarboxylic acid water reducing agent includes as follows
Step:
S1, unsaturated 14-21 parts of polyoxyethylene ether, 2.8-3.5 parts of slow release high-efficiency water-reducing agent, dodecyl sulphate are provided
3.8-12.5 parts of sodium, 5.5-8.5 parts of acrylic acid, 5-10 parts of cross-linking monomer, 11-26 parts of diethanol monoisopropanolamine, gluconic acid
8-20 parts of sodium, above-mentioned component is mixed under the action of initiator and preservative, obtains the first intermediate product；
S2,1-2 parts of N- dimethyl cyclohexyl amine, 3.5-7.5 parts of carboxylate, 7-9 parts of methylpropene sodium sulfonate, hypophosphorous acid are provided
8-13 parts of sodium, 1.6-3.0 parts of maleic anhydride, 8-16 parts of mercaptopropionic acid, by above-mentioned component initiator and preservative work
With lower mixing, the second intermediate product is obtained, the second intermediate product is mixed with the first intermediate product, obtains polycarboxylic acids of the invention
Type water-reducing agent.
Compared with prior art, the beneficial effects of the present invention are: the production method of high-performance water reducing agent of the invention provides
Water-reducing agent can reduce the water being added in concrete construction, be conducive to the setting time for shortening concrete, and improve
The intensity of concrete.
Specific embodiment
Below with reference to specific embodiment, the present invention is described in detail, but it should be stated that, these embodiment party
Formula is not limitation of the present invention, those of ordinary skill in the art according to these embodiments made by function, method or knot
Equivalent transformation or substitution on structure, all belong to the scope of protection of the present invention within.
The present invention provides a kind of polycarboxylic acid water reducing agent, by weight percentage includes following component: unsaturated polyoxy second
14-21 parts of alkene ether, 2.8-3.5 parts of slow release high-efficiency water-reducing agent, 3.8-12.5 parts of lauryl sodium sulfate, acrylic acid 5.5-8.5
Part, 5-10 parts of cross-linking monomer, 11-26 parts of diethanol monoisopropanolamine, 8-20 parts of sodium gluconate, maleic anhydride 1.6-
3.0 parts, 8-16 parts of mercaptopropionic acid, 1-2 parts of N- dimethyl cyclohexyl amine, 3.5-7.5 parts of carboxylate, 7-9 parts of methylpropene sodium sulfonate,
8-13 parts of sodium hypophosphite, 3-5 parts of initiator, 6-12 parts of preservative.
In addition, the polycarboxylic acid water reducing agent is by weight percentage further include: 1.5-2.0 parts of sodium formaldehyde sulphoxylates,
2-3.5 part modified starch ether.Preferably, the polycarboxylic acid water reducing agent includes: that 1.8 parts of formaldehyde close sulphoxylic acid by weight percentage
Hydrogen sodium, 2.5 parts of modified starch ethers.The polycarboxylic acid water reducing agent is by weight percentage further include: 6-19 parts of ethylene glycol, maleic acid
4-9 parts.Preferably, the polycarboxylic acid water reducing agent includes: 7 parts of ethylene glycol, 8 parts of maleic acid by weight percentage.
Polycarboxylic acid water reducing agent of the invention is illustrated combined with specific embodiments below.
Embodiment 1
The polycarboxylic acid water reducing agent includes following component by weight percentage: 15 parts of unsaturated polyoxyethylene ether, sustained release
2.8 parts of type high efficiency water reducing agent, 4.8 parts of lauryl sodium sulfate, 6.5 parts of acrylic acid, 7.5 parts of cross-linking monomer, diethanol list isopropyl
17.5 parts of hydramine, 16.5 parts of sodium gluconate, 2.8 parts of maleic anhydride, 8.9 parts of mercaptopropionic acid, N- dimethyl cyclohexyl amine 1.5
Part, 5.5 parts of carboxylate, 8.5 parts of methylpropene sodium sulfonate, 10.5 parts of sodium hypophosphite, 4.5 parts of initiator, 8.5 parts of preservative.
Above-mentioned polycarboxylic acid water reducing agent is prepared as follows:
S1, unsaturated 15 parts of polyoxyethylene ether, 2.8 parts of slow release high-efficiency water-reducing agent, lauryl sodium sulfate 4.8 are provided
Part, 6.5 parts of acrylic acid, 7.5 parts of cross-linking monomer, 17.5 parts of diethanol monoisopropanolamine, 16.5 parts of sodium gluconate, by above-mentioned group
Part mixes under the action of initiator and preservative, obtains the first intermediate product；
S2,2.8 parts of maleic anhydride, 8.9 parts of mercaptopropionic acid, 1.5 parts of N- dimethyl cyclohexyl amine, carboxylate 5.5 are provided
Part, 8.5 parts of methylpropene sodium sulfonate, 10.5 parts of sodium hypophosphite, above-mentioned component is mixed under the action of initiator and preservative,
The second intermediate product is obtained, the second intermediate product is mixed with the first intermediate product, obtains polycarboxylic acid water reducing agent of the invention.
Embodiment 2
The polycarboxylic acid water reducing agent includes following component by weight percentage: 20 parts of unsaturated polyoxyethylene ether, sustained release
3.5 parts of type high efficiency water reducing agent, 12.5 parts of lauryl sodium sulfate, 8.5 parts of acrylic acid, 10 parts of cross-linking monomer, diethanol list isopropyl
Hydramine 11-26,8 parts of sodium gluconate, 2.6 parts of maleic anhydride, 8 parts of mercaptopropionic acid, 1.5 parts of N- dimethyl cyclohexyl amine, carboxylic
6 parts of acid esters, 7.5 parts of methylpropene sodium sulfonate, 11.5 parts of sodium hypophosphite, 5 parts of initiator, 6 parts of preservative.
Above-mentioned polycarboxylic acid water reducing agent is prepared as follows:
S1, unsaturated 20 parts of polyoxyethylene ether, 3.5 parts of slow release high-efficiency water-reducing agent, lauryl sodium sulfate 12.5 are provided
Part, 8.5 parts of acrylic acid, 10 parts of cross-linking monomer, diethanol monoisopropanolamine 11-26,8 parts of sodium gluconate, above-mentioned component is existed
It is mixed under the action of initiator and preservative, obtains the first intermediate product；
S2,2.6 parts of maleic anhydride, 8 parts of mercaptopropionic acid, 1.5 parts of N- dimethyl cyclohexyl amine, 6 parts of carboxylate, first are provided
7.5 parts of base sodium allylsulfonate, 11.5 parts of sodium hypophosphite mix above-mentioned component under the action of initiator and preservative, obtain
Second intermediate product is mixed with the first intermediate product, obtains polycarboxylic acid water reducing agent of the invention by the second intermediate product.
Embodiment 3
The polycarboxylic acid water reducing agent includes following component by weight percentage: 18 parts of unsaturated polyoxyethylene ether, sustained release
3.3 parts of type high efficiency water reducing agent, 16.5 parts of lauryl sodium sulfate, 7.2 parts of acrylic acid, 8.5 parts of cross-linking monomer, diethanol list isopropyl
17.5 parts of hydramine, 17.5 parts of sodium gluconate, 2.8 parts of maleic anhydride, 8.9 parts of mercaptopropionic acid, N- dimethyl cyclohexyl amine 1.5
Part, 5.5 parts of carboxylate, 8.5 parts of methylpropene sodium sulfonate, 10.5 parts of sodium hypophosphite, 4.4 parts of initiator, 11.5 parts of preservative.
Above-mentioned polycarboxylic acid water reducing agent is prepared as follows:
S1, unsaturated 18 parts of polyoxyethylene ether, 3.3 parts of slow release high-efficiency water-reducing agent, lauryl sodium sulfate 16.5 are provided
Part, 7.2 parts of acrylic acid, 8.5 parts of cross-linking monomer, 17.5 parts of diethanol monoisopropanolamine, 17.5 parts of sodium gluconate, by above-mentioned group
Part mixes under the action of initiator and preservative, obtains the first intermediate product；
S2,2.8 parts of maleic anhydride, 8.9 parts of mercaptopropionic acid, 1.5 parts of N- dimethyl cyclohexyl amine, carboxylate 5.5 are provided
Part, 8.5 parts of methylpropene sodium sulfonate, 10.5 parts of sodium hypophosphite, above-mentioned component is mixed under the action of initiator and preservative,
The second intermediate product is obtained, the second intermediate product is mixed with the first intermediate product, obtains polycarboxylic acid water reducing agent of the invention.
In conclusion the water-reducing agent that the production method of high-performance water reducing agent of the invention provides can reduce concrete construction
The water being added in the process is conducive to the setting time for shortening concrete, and improves the intensity of concrete.
It is obvious to a person skilled in the art that invention is not limited to the details of the above exemplary embodiments, Er Qie
In the case where without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter
From the point of view of which point, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is by appended power
Benefit requires rather than above description limits, it is intended that all by what is fallen within the meaning and scope of the equivalent elements of the claims
Variation is included within the present invention.
In addition, it should be understood that although this specification is described in terms of embodiments, but not each embodiment is only wrapped
Containing an independent technical solution, this description of the specification is merely for the sake of clarity, and those skilled in the art should
It considers the specification as a whole, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art
The other embodiments being understood that.
Claims (9)
1. a kind of polycarboxylic acid water reducing agent, which is characterized in that the polycarboxylic acid water reducing agent includes such as the following group by weight percentage
Point:
Unsaturated polyoxyethylene ether 14-21 parts,
2.8-3.5 parts of slow release high-efficiency water-reducing agent,
3.8-12.5 parts of lauryl sodium sulfate,
5.5-8.5 parts of acrylic acid,
5-10 parts of cross-linking monomer,
11-26 parts of diethanol monoisopropanolamine,
8-20 parts of sodium gluconate,
1.6-3.0 parts of maleic anhydride,
8-16 parts of mercaptopropionic acid,
1-2 parts of N- dimethyl cyclohexyl amine,
3.5-7.5 parts of carboxylate,
7-9 parts of methylpropene sodium sulfonate,
8-13 parts of sodium hypophosphite,
3-5 parts of initiator,
6-12 parts of preservative.
2. polycarboxylic acid water reducing agent according to claim 1, which is characterized in that the polycarboxylic acid water reducing agent by weight hundred
Divide than including following component: 15 parts of unsaturated polyoxyethylene ether, 2.8 parts of slow release high-efficiency water-reducing agent, lauryl sodium sulfate 4.8
Part, 6.5 parts of acrylic acid, 7.5 parts of cross-linking monomer, 17.5 parts of diethanol monoisopropanolamine, 16.5 parts of sodium gluconate, maleic two
2.8 parts of acid anhydrides, 8.9 parts of mercaptopropionic acid, 1.5 parts of N- dimethyl cyclohexyl amine, 5.5 parts of carboxylate, 8.5 parts of methylpropene sodium sulfonate,
10.5 parts of sodium hypophosphite, 4.5 parts of initiator, 8.5 parts of preservative.
3. polycarboxylic acid water reducing agent according to claim 1, which is characterized in that the polycarboxylic acid water reducing agent by weight hundred
Divide than including following component: 20 parts of unsaturated polyoxyethylene ether, 3.5 parts of slow release high-efficiency water-reducing agent, lauryl sodium sulfate
12.5 parts, 8.5 parts of acrylic acid, 10 parts of cross-linking monomer, diethanol monoisopropanolamine 11-26,8 parts of sodium gluconate, maleic two
2.6 parts of acid anhydrides, 8 parts of mercaptopropionic acid, 1.5 parts of N- dimethyl cyclohexyl amine, 6 parts of carboxylate, 7.5 parts of methylpropene sodium sulfonate, secondary phosphorus
11.5 parts of sour sodium, 5 parts of initiator, 6 parts of preservative.
4. polycarboxylic acid water reducing agent according to claim 1, which is characterized in that the polycarboxylic acid water reducing agent by weight hundred
Divide than including following component: 18 parts of unsaturated polyoxyethylene ether, 3.3 parts of slow release high-efficiency water-reducing agent, lauryl sodium sulfate
16.5 parts, 7.2 parts of acrylic acid, 8.5 parts of cross-linking monomer, 17.5 parts of diethanol monoisopropanolamine, 17.5 parts of sodium gluconate, suitable fourth
2.8 parts of enedioic acid acid anhydride, 8.9 parts of mercaptopropionic acid, 1.5 parts of N- dimethyl cyclohexyl amine, 5.5 parts of carboxylate, methylpropene sodium sulfonate 8.5
Part, 10.5 parts of sodium hypophosphite, 4.4 parts of initiator, 11.5 parts of preservative.
5. polycarboxylic acid water reducing agent according to claim 1, which is characterized in that the polycarboxylic acid water reducing agent by weight hundred
Divide ratio further include: 1.5-2.0 parts of sodium formaldehyde sulphoxylates, 2-3.5 parts of modified starch ethers.
6. polycarboxylic acid water reducing agent according to claim 5, which is characterized in that the polycarboxylic acid water reducing agent by weight hundred
Divide ratio further include: 1.8 parts of sodium formaldehyde sulphoxylates, 2.5 parts of modified starch ethers.
7. polycarboxylic acid water reducing agent according to claim 1, which is characterized in that the polycarboxylic acid water reducing agent by weight hundred
Divide ratio further include: 6-19 parts of ethylene glycol, 4-9 parts of maleic acid.
8. polycarboxylic acid water reducing agent according to claim 7, which is characterized in that the polycarboxylic acid water reducing agent by weight hundred
Divide ratio further include: 7 parts of ethylene glycol, 8 parts of maleic acid.
9. polycarboxylic acid water reducing agent according to claim 1, which is characterized in that the producer of the polycarboxylic acid water reducing agent
Method includes the following steps:
S1, unsaturated 14-21 parts of polyoxyethylene ether, 2.8-3.5 parts of slow release high-efficiency water-reducing agent, lauryl sodium sulfate are provided
3.8-12.5 parts, 5.5-8.5 parts of acrylic acid, 5-10 parts of cross-linking monomer, 11-26 parts of diethanol monoisopropanolamine, sodium gluconate
8-20 parts, above-mentioned component is mixed under the action of initiator and preservative, obtains the first intermediate product；
S2,1-2 parts of N- dimethyl cyclohexyl amine, 3.5-7.5 parts of carboxylate, 7-9 parts of methylpropene sodium sulfonate, sodium hypophosphite 8- are provided
13 parts, 1.6-3.0 parts of maleic anhydride, 8-16 parts of mercaptopropionic acid, by above-mentioned component under the action of initiator and preservative
Mixing obtains the second intermediate product, the second intermediate product is mixed with the first intermediate product, polyocarboxy acid type of the invention is obtained and subtracts
Aqua.
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