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CN109234613A - The production method of hot-rolled coil and hot-rolled coil - Google Patents

The production method of hot-rolled coil and hot-rolled coil Download PDF

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Publication number
CN109234613A
CN109234613A CN201810970683.1A CN201810970683A CN109234613A CN 109234613 A CN109234613 A CN 109234613A CN 201810970683 A CN201810970683 A CN 201810970683A CN 109234613 A CN109234613 A CN 109234613A
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CN
China
Prior art keywords
hot
rolled coil
rolling
temperature
roughing mill
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810970683.1A
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Chinese (zh)
Inventor
武利平
宿成
刘妍
王皓
曹妍
李钊
孙婷婷
刘朋成
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Baotou Iron and Steel Group Co Ltd
Original Assignee
Baotou Iron and Steel Group Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Baotou Iron and Steel Group Co Ltd filed Critical Baotou Iron and Steel Group Co Ltd
Priority to CN201810970683.1A priority Critical patent/CN109234613A/en
Publication of CN109234613A publication Critical patent/CN109234613A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0205Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips of ferrous alloys
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0221Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
    • C21D8/0226Hot rolling
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C33/00Making ferrous alloys
    • C22C33/04Making ferrous alloys by melting
    • C22C33/06Making ferrous alloys by melting using master alloys
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/002Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/06Ferrous alloys, e.g. steel alloys containing aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/12Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Metal Rolling (AREA)
  • Heat Treatment Of Steel (AREA)

Abstract

The present invention provides the production methods of a kind of hot-rolled coil and hot-rolled coil, wherein hot-rolled coil, by percentage to the quality, chemical component are as follows: C 0.16~0.20%, Si 0.10~0.50%, Mn 1.20~1.50%, P≤0.030%, S≤0.030%, Nb 0.007~0.070%, Als 0.020~0.050, Ca 0.0010~0.0030%, N≤0.009, surplus are Fe and the other relict elements of raw material.According to the technical solution of the present invention, by using the think gauge hot-rolled coil preparation process and method of C-Mn-Nb low-alloy low cost, using addition trace alloying element, utilize 2250mm hot rolling producing line advantage, utilize cooling controlling and rolling controlling process, the matching that intensity and plasticity are further realized by refined crystalline strengthening mechanism, promotes the comprehensive mechanical performance of material, has a good application prospect.Hot-rolled coil prepared by the present invention can satisfy thickness in the properties of the hot-rolled coil of 18mm~25mm, can not only guarantee that hot-rolled coil self-strength and plasticity match, but also ensure the excellent performance of product after pipe is made in material.

Description

The production method of hot-rolled coil and hot-rolled coil
Technical field
The present invention relates to metallurgical technology fields, in particular to a kind of hot-rolled coil and a kind of production of hot-rolled coil Method.
Background technique
Currently, the petroleum casing pipe exploitation of think gauge is in the starting stage, most of the country iron and steel enterprise not can guarantee production Product have some strength and elongation, and not can guarantee hot-rolled coil and the performance standard for reaching product after pipe is made.Therefore, in order to Meet the properties after hot-rolled coil and tubulation simultaneously, needs to design the preparation method of a set of think gauge hot-rolled coil.
Summary of the invention
The present invention is directed to solve at least one of the technical problems existing in the prior art or related technologies.
For this purpose, it is an object of the present invention to provide a kind of hot-rolled coils.
It is another object of the present invention to provide a kind of production methods of hot-rolled coil.
In view of this, the technical solution of first aspect present invention provides a kind of hot-rolled coil, by percentage to the quality, Chemical component are as follows: C 0.16~0.20%, Si 0.10~0.50%, Mn 1.20~1.50%, P≤0.030%, S≤ 0.030%, Nb 0.007~0.070%, Als 0.020~0.050, Ca 0.0010~0.0030%, N≤0.009, surplus For Fe and the other relict elements of raw material.
The technical solution of second aspect of the present invention proposes a kind of production method of hot-rolled coil, for producing first aspect Technical solution hot-rolled coil, comprising: refining procedure: LF furnace carry out slag making, deoxidation, desulfurization and removal of inclusions it is excessively program-controlled System is added the alloys such as manganese iron, ferrosilicon, ferro-niobium according to molten steel composition and finely tunes molten steel composition to target zone, feeds calcium line and carry out calcium Processing, Calcium treatment, which finishes, guarantees that the soft blow time is greater than 8min;Continuous casting working procedure: the steel grade liquidus temperature is 1513 DEG C, the first packet 25~40 DEG C of the Metal in Tundish degree of superheat, 15~30 DEG C of other heat of molten steel degrees of superheat;Casting machine uses permanent pulling rate, control range: 1.0~1.5m/min;Hot-rolled process: slab heating temperature is controlled at 1180~1220 DEG C;Time inside furnace control 180~ 300min;Soaking temperature is controlled at 1190~1230 DEG C;Roughing uses 3+3 mode or 1+5 mode;The control of finish rolling start rolling temperature At 950~1050 DEG C;Finishing temperature control is at 830~880 DEG C;Coiling temperature is at 550~610 DEG C.
Further, the hot-rolled process specifically includes: slab heating temperature control is at 1180 ± 20 DEG C, time inside furnace control System is in >=180min;High pressure water dephosphorization;Press machine fixed width;The rolling of E1R1 roughing mill and the rolling of E2R2 roughing mill, roughing mode are adopted 1 passage is rolled with 1# roughing mill, 2# roughing mill rolls 5 passages;Or 1# roughing mill rolls 3 passages, 2# roughing mill rolls 3 passages; Roughing mill finishing temperature≤1100 DEG C;Flying shear;High pressure water dephosphorization;The rolling of 2250mm finishing mill, finish rolling start rolling temperature are controlled 950 ~1050 DEG C;Finishing temperature control is at 830~880 DEG C;Section cooling is encrypted, the control of steel band cooling velocity is uniform at 15~25 DEG C It is cooling.
One or more technical solution provided by the invention, has at least the following technical effects or advantages:
It is micro- using being added by using the think gauge hot-rolled coil preparation process and method of C-Mn-Nb low-alloy low cost Alloying element is measured, is further realized by refined crystalline strengthening mechanism using 2250mm hot rolling producing line advantage using cooling controlling and rolling controlling process The matching of intensity and plasticity promotes the comprehensive mechanical performance of material, has a good application prospect.Hot rolled coil prepared by the present invention Plate can satisfy thickness in the properties of the hot-rolled coil of 18mm~25mm, can not only guarantee hot-rolled coil self-strength and Plasticity matches, and ensures the excellent performance of product after pipe is made in material.
Additional aspect and advantage of the invention will be set forth in part in the description, and will partially become from the following description Obviously, or practice through the invention is recognized.
Specific embodiment
In order to be more clearly understood that aforementioned aspect of the present invention, feature and advantage, With reference to embodiment The present invention is further described in detail.It should be noted that in the absence of conflict, embodiments herein and reality The feature applied in example can be combined with each other.
In the following description, numerous specific details are set forth in order to facilitate a full understanding of the present invention, still, the present invention may be used also To be implemented using other than the one described here other modes, therefore, protection scope of the present invention is not by described below Specific embodiment limitation.
Embodiment 1:
The hot-rolled coil of embodiment according to the present invention, by percentage to the quality, chemical component are as follows: C0.16~ 0.20%, Si 0.10~0.50%, Mn 1.20~1.50%, P≤0.030%, S≤0.030%, Nb0.007~ 0.070%, Als 0.020~0.050, Ca 0.0010~0.0030%, N≤0.009, surplus are Fe and the other residuals of raw material Element.
In the element of addition, Mn is mainly present in product tissue in a manner of solid solution, improves intensity by solution strengthening;Nb Play refined crystalline strengthening, not only improved the intensity of material but also guarantees the plasticity index of material.
Embodiment 2:
The production method of the hot-rolled coil of embodiment according to the present invention, comprising: refining procedure: LF furnace carries out slag making, takes off Oxygen, desulfurization and removal of inclusions process control are added the alloys such as manganese iron, ferrosilicon, ferro-niobium according to molten steel composition and finely tune molten steel composition To target zone, feeds calcium line and carry out Calcium treatment, Calcium treatment, which finishes, guarantees that the soft blow time is greater than 8min;Continuous casting working procedure: the steel grade Liquidus temperature is 1513 DEG C, first 25~40 DEG C of the packet Metal in Tundish degree of superheat, 15~30 DEG C of other heat of molten steel degrees of superheat; Casting machine is using permanent pulling rate, control range: 1.0~1.5m/min;Hot-rolled process: slab heating temperature is controlled 1180~1220 ℃;Time inside furnace is controlled in 180~300min;Soaking temperature is controlled at 1190~1230 DEG C;Roughing uses 3+3 mode or 1+ 5 modes;Finish rolling start rolling temperature is controlled at 950~1050 DEG C;Finishing temperature control is at 830~880 DEG C;Coiling temperature 550~ 610℃。
Further, the hot-rolled process specifically includes: slab heating temperature control is at 1180 ± 20 DEG C, time inside furnace control System is in >=180min;High pressure water dephosphorization;Press machine fixed width;The rolling of E1R1 roughing mill and the rolling of E2R2 roughing mill, roughing mode are adopted 1 passage is rolled with 1# roughing mill, 2# roughing mill rolls 5 passages;Or 1# roughing mill rolls 3 passages, 2# roughing mill rolls 3 passages; Roughing mill finishing temperature≤1100 DEG C;Flying shear;High pressure water dephosphorization;The rolling of 2250mm finishing mill, finish rolling start rolling temperature are controlled 950 ~1050 DEG C;Finishing temperature control is at 830~880 DEG C;Section cooling is encrypted, the control of steel band cooling velocity is uniform at 15~25 DEG C It is cooling.
It is micro- using being added by using the think gauge hot-rolled coil preparation process and method of C-Mn-Nb low-alloy low cost Alloying element is measured, is further realized by refined crystalline strengthening mechanism using 2250mm hot rolling producing line advantage using cooling controlling and rolling controlling process The matching of intensity and plasticity promotes the comprehensive mechanical performance of material, has a good application prospect.Hot rolled coil prepared by the present invention Plate can satisfy thickness in the properties of the hot-rolled coil of 18mm~25mm, can not only guarantee hot-rolled coil self-strength and Plasticity matches, and ensures the excellent performance of product after pipe is made in material.
Specific embodiment
1. the smelting of material
1.1 converters: tapping temperature >=1620 DEG C guarantee that ingredient and temperature are coordinated to tap;If new tapping hole tapping temperature exists Take the circumstances into consideration to improve 10~15 DEG C on the basis of temperature upper limit.The steel grade carries out alloying using alloys such as manganese iron, ferrosilicon, and final deoxidizing is adopted With ferro-aluminum deoxidation.
1.2 refinings: LF furnace carries out slag making, deoxidation, desulfurization and removal of inclusions process control, and manganese is added according to molten steel composition The alloys such as iron, ferrosilicon, ferro-niobium finely tune molten steel composition to target zone, feed calcium line and carry out Calcium treatment, it is soft that Calcium treatment finishes guarantee The time is blown greater than 8min.
1.3 continuous castings: the steel grade liquidus temperature is 1513 DEG C, and first 25~40 DEG C of the packet Metal in Tundish degree of superheat is other 15~30 DEG C of the heat of molten steel degree of superheat.
2. cooling controlling and rolling controlling process
Using stepped heating stove heating slab, concrete technology is shown in Table 1, and roughing uses 3+3 mode or 1+5 mode, essence It rolls using F1~F7.
1 slab heating technique parameter of table
Slab thickness mm Heating temperature DEG C Time inside furnace min Soaking temperature DEG C Soaking time min Tapping temperature DEG C
230 1180~1220 180~300 1190~1230 40~60 1210±20
2 rolling technological parameter of table
The analysis of 3 embodiments
3.1 according to the above smelting requirements, and the chemical component for smelting think gauge product is shown in Table 3.
3 think gauge casing chemical component of table
Element C Si Mn P S Nb Als Ca N
Target 0.17 0.15 1.30 0.010 0.005 0.010 0.030 0.0020 0.004
3.2 according to mentioned component design and hot rolling technology, produces tensile property and impact that product thickness is 24.5mm Performance is shown in Table 4, and test method is referring to GB/T 228 and 229 standard of GB/T.
The tensile property and impact property of 4 product of table
The metallographic structure of 3.3 products is ferrite+bainite, and specific tissue topography is as shown in Figure 1.
In conclusion hot-rolled coil intensity with higher and toughness that the present invention designs and develops, are widely used in petroleum The oil well casing field of industry and natural gas industry, all standard are all satisfied API Spec 5CT 9th standard requirements.
In the description of this specification, the description of term " one embodiment ", " some embodiments ", " specific embodiment " etc. Mean that particular features, structures, materials, or characteristics described in conjunction with this embodiment or example are contained at least one reality of the invention It applies in example or example.In the present specification, schematic expression of the above terms are not necessarily referring to identical embodiment or reality Example.Moreover, description particular features, structures, materials, or characteristics can in any one or more of the embodiments or examples with Suitable mode combines.
The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention, for the skill of this field For art personnel, the invention may be variously modified and varied.All within the spirits and principles of the present invention, made any to repair Change, equivalent replacement, improvement etc., should all be included in the protection scope of the present invention.

Claims (3)

1. a kind of hot-rolled coil, which is characterized in that by percentage to the quality, chemical component are as follows: C 0.16~0.20%, Si 0.10~0.50%, Mn 1.20~1.50%, P≤0.030%, S≤0.030%, Nb 0.007~0.070%, Als 0.020~0.050, Ca 0.0010~0.0030%, N≤0.009, surplus are Fe and the other relict elements of raw material.
2. a kind of production method of hot-rolled coil, for producing hot-rolled coil as described in claim 1, which is characterized in that Include:
Refining procedure: LF furnace carry out slag making, deoxidation, desulfurization and removal of inclusions process control, according to molten steel composition be added manganese iron, The alloys such as ferrosilicon, ferro-niobium finely tune molten steel composition to target zone, feed calcium line and carry out Calcium treatment, when Calcium treatment finishes guarantee soft blow Between be greater than 8min;
Continuous casting working procedure: the steel grade liquidus temperature is 1513 DEG C, first 25~40 DEG C of the packet Metal in Tundish degree of superheat, other heats 15~30 DEG C of molten steel overheat;Casting machine is using permanent pulling rate, control range: 1.0~1.5m/min;
Hot-rolled process: slab heating temperature is controlled at 1180~1220 DEG C;Time inside furnace is controlled in 180~300min;Soaking temperature Degree control is at 1190~1230 DEG C;Roughing uses 3+3 mode or 1+5 mode;Finish rolling start rolling temperature is controlled 950~1050 ℃;Finishing temperature control is at 830~880 DEG C;Coiling temperature is at 550~610 DEG C.
3. the production method of hot-rolled coil according to claim 2, which is characterized in that the hot-rolled process specifically includes:
At 1180 ± 20 DEG C, time inside furnace is controlled in >=180min for slab heating temperature control;
High pressure water dephosphorization;
Press machine fixed width;
The rolling of E1R1 roughing mill and the rolling of E2R2 roughing mill, roughing mode roll 1 passage, the rolling of 2# roughing mill using 1# roughing mill 5 passages;Or 1# roughing mill rolls 3 passages, 2# roughing mill rolls 3 passages;Roughing mill finishing temperature≤1100 DEG C;
Flying shear;
High pressure water dephosphorization;
The rolling of 2250mm finishing mill, finish rolling start rolling temperature are controlled at 950~1050 DEG C;Finishing temperature control is at 830~880 DEG C;
Section cooling is encrypted, the control of steel band cooling velocity is uniformly cooling at 15~25 DEG C.
CN201810970683.1A 2018-08-24 2018-08-24 The production method of hot-rolled coil and hot-rolled coil Pending CN109234613A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810970683.1A CN109234613A (en) 2018-08-24 2018-08-24 The production method of hot-rolled coil and hot-rolled coil

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810970683.1A CN109234613A (en) 2018-08-24 2018-08-24 The production method of hot-rolled coil and hot-rolled coil

Publications (1)

Publication Number Publication Date
CN109234613A true CN109234613A (en) 2019-01-18

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110205546A (en) * 2019-06-12 2019-09-06 包头钢铁(集团)有限责任公司 A kind of yield strength is greater than the petroleum casing pipe and preparation method thereof of 450MPa
CN110303066A (en) * 2019-07-31 2019-10-08 攀钢集团攀枝花钢铁研究院有限公司 Steel for oil casing with high transverse impact energy and manufacturing method thereof
CN110343958A (en) * 2019-07-25 2019-10-18 包头钢铁(集团)有限责任公司 A kind of tensile strength 500MPa grades of automobile axle housing roll bendings and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008255397A (en) * 2007-04-03 2008-10-23 Nisshin Steel Co Ltd Method for producing electric resistance welded tube for hollow stabilizer
CN102400040A (en) * 2010-09-07 2012-04-04 鞍钢股份有限公司 A low-carbon bainitic steel hot-rolled coil for low temperature and its production method
CN102719743A (en) * 2012-06-27 2012-10-10 山西太钢不锈钢股份有限公司 Hot-rolled coil plate for oil casing and manufacturing method thereof
KR20160036813A (en) * 2014-09-26 2016-04-05 현대제철 주식회사 Carbon steel and method of manufacturing the carbon steel
CN106917043A (en) * 2017-02-17 2017-07-04 舞阳钢铁有限责任公司 A kind of resisting sulfide stress corrosion cracking sheet metal and its production method

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008255397A (en) * 2007-04-03 2008-10-23 Nisshin Steel Co Ltd Method for producing electric resistance welded tube for hollow stabilizer
CN102400040A (en) * 2010-09-07 2012-04-04 鞍钢股份有限公司 A low-carbon bainitic steel hot-rolled coil for low temperature and its production method
CN102719743A (en) * 2012-06-27 2012-10-10 山西太钢不锈钢股份有限公司 Hot-rolled coil plate for oil casing and manufacturing method thereof
KR20160036813A (en) * 2014-09-26 2016-04-05 현대제철 주식회사 Carbon steel and method of manufacturing the carbon steel
CN106917043A (en) * 2017-02-17 2017-07-04 舞阳钢铁有限责任公司 A kind of resisting sulfide stress corrosion cracking sheet metal and its production method

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110205546A (en) * 2019-06-12 2019-09-06 包头钢铁(集团)有限责任公司 A kind of yield strength is greater than the petroleum casing pipe and preparation method thereof of 450MPa
CN110343958A (en) * 2019-07-25 2019-10-18 包头钢铁(集团)有限责任公司 A kind of tensile strength 500MPa grades of automobile axle housing roll bendings and preparation method thereof
CN110303066A (en) * 2019-07-31 2019-10-08 攀钢集团攀枝花钢铁研究院有限公司 Steel for oil casing with high transverse impact energy and manufacturing method thereof
CN110303066B (en) * 2019-07-31 2021-01-26 攀钢集团攀枝花钢铁研究院有限公司 Steel for petroleum casing pipe with high transverse impact energy and manufacturing method thereof

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Application publication date: 20190118