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CN109233026A - A kind of heat resistance conveyor belt rubber cover of anti-material sticks and preparation method thereof - Google Patents

A kind of heat resistance conveyor belt rubber cover of anti-material sticks and preparation method thereof Download PDF

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Publication number
CN109233026A
CN109233026A CN201810882191.7A CN201810882191A CN109233026A CN 109233026 A CN109233026 A CN 109233026A CN 201810882191 A CN201810882191 A CN 201810882191A CN 109233026 A CN109233026 A CN 109233026A
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China
Prior art keywords
parts
weight
agent
conveyor belt
heat resistance
Prior art date
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Pending
Application number
CN201810882191.7A
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Chinese (zh)
Inventor
刘伟影
闰明涛
于颖韬
袁斌
周肃苗
苏阿倩
申嘉祥
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Beijing Tianjin Hebei Sheng Hua (bo Ye) New Material Research Institute Co Ltd
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Beijing Tianjin Hebei Sheng Hua (bo Ye) New Material Research Institute Co Ltd
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Priority to CN201810882191.7A priority Critical patent/CN109233026A/en
Publication of CN109233026A publication Critical patent/CN109233026A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08L9/06Copolymers with styrene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2217Oxides; Hydroxides of metals of magnesium
    • C08K2003/222Magnesia, i.e. magnesium oxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/017Additives being an antistatic agent
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/04Antistatic

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Belt Conveyors (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The present invention relates to a kind of heat resistance conveyor belt rubber covers of anti-material sticks, belong to conveyer belt technical field.The rubber cover is made of the component of following parts by weight: butadiene-styrene rubber is 100 parts, high-temperature resistant rubber is 40~60 parts, reinforcing agent is 20~30 parts, heat-resistant agent is 30~60 parts, vulcanizing activator is 11~23 parts, vulcanization accelerator is 3~5.5 parts, 0.5~1.5 part of anti-aging agent, coumarone are 4.5~5.5 parts, antistatic agent is 5~10 parts, Stiffening agent is 3~6 parts.Anti- material sticks heat resistance conveyor belt rubber cover product has good antistatic property in the present invention, can significantly reduce viscous ash quantity of conveyer belt during conveying powder material, solves production and environmental issue for enterprise.Test result shows that compared with unmodified conveyer belt, such rubber cover can reduce cement adhesive capacity 60% or more.

Description

A kind of heat resistance conveyor belt rubber cover of anti-material sticks and preparation method thereof
Technical field
The present invention relates to for metallurgy, cement industry conveying powder material conveyer belt technical field, more particularly to A kind of heat resistance conveyor belt rubber cover of anti-material sticks and preparation method thereof.
Background technique
Conveyer is most economical effective method in industrial bulk material conveying, and conveyer belt is its most important composition portion Part.Rubber conveyer belt is the important rubber product of the second major class for being only second to tire, is mainly used in coal, metallurgy, building materials, coke The state key industry of the support national economy and social development such as charcoal, power generation.
Under normal circumstances, material can be brought into the form of the bulk of different shape and size, particle and powder etc. by conveying Row transmits, in existing metallurgical, cement industry granular material transmission process, since material and the generation of conveyer belt friction subsurface are quiet Electricity causes conveyer belt to there is adhered materials phenomenon in use.
Current the most frequently used solution attachment approach is installation sweeper, but is easy to appear sweeper scraper plate and scratches band body situation; If arranging hand sweeping, higher cost, and the material flown upward is harmful to the human body.Fundamentally to solve the problems, such as material sticks, it can To consider from the performance of conveyer belt coating rubber.
Summary of the invention
The object of the present invention is to provide heat resistance conveyor belt rubber covers of a kind of anti-material sticks and preparation method thereof, to solve The above-mentioned problems of the prior art makes anti-material sticks heat resistance conveyor belt rubber cover product have good antistatic property, Viscous ash quantity of conveyer belt during conveying powder material is significantly reduced, solves production and environmental issue for enterprise.
To achieve the above object, the present invention provides following schemes:
The present invention provides a kind of heat resistance conveyor belt rubber cover of anti-material sticks, is made of the component of following parts by weight: fourth Benzene rubber is 100 parts, high-temperature resistant rubber is 40~60 parts, reinforcing agent is 20~30 parts, heat-resistant agent is 30~60 parts, sulfurate activity Agent is 11~23 parts, vulcanization accelerator is 3~5.5 parts, 0.5~1.5 part of anti-aging agent, coumarone are 4.5~5.5 parts, antistatic Agent is 5~10 parts, Stiffening agent is 3~6 parts.
Further, the reinforcing agent is white carbon black.
Further, the heat-resistant agent is magnesinm methacrylate and magnesia mixture (MDMA).
Further, the vulcanizing activator is nano zine oxide and stearic acid, and the nano zine oxide and stearic acid are pressed Weight ratio is 10~20:1~3.
Further, the vulcanization accelerator is DM, CZ, DTDM and TMTD, and described DM, CZ, DTDM and TMTD are by weight Ratio is 0.5~1:1~1.5:0.5~1.5:1~1.5.
Further, the anti-aging agent is 6- dodecyl -2,2,4- trimethyl -1,2- dihyaroquinoline (anti-aging agent DD)。
Further, the antistatic agent is conductive black, and the resistivity of the conductive black is 1.0~3.0 Ω m.
Further, the Stiffening agent is nano silica.
The present invention also provides the preparation methods of the heat resistance conveyor belt rubber cover of above-mentioned anti-material sticks, comprising the following steps:
(1) high-temperature resistant rubber of the butadiene-styrene rubber of 100 parts by weight and 40~60 parts by weight is put into mixer and carries out mixing 2 Then the oxidation of the heat-resistant agent of 30~60 parts by weight, the coumarone, 10~20 parts by weight of 4.5~5.5 parts by weight is added in~5min The stearic acid of zinc, 1~3 parts by weight, the antioxidant D D of 0.5~1.5 parts by weight, the white carbon black of 20~30 parts by weight, 5~10 weight Part antistatic agent, 3~6 parts by weight Stiffening agent, be kneaded 5~10 minutes, melting temperature control at 120~130 DEG C, obtain one Section rubber compound;
B, one section of rubber compound is cooled to room temperature;
C, the vulcanization of one section of rubber compound, the vulcanization accelerator TMTD of 1~1.5 parts by weight, 0.5~1.5 parts by weight is promoted Agent DTDM, the accelerator DM of 0.5~1 parts by weight, 1~1.5 parts by weight accelerator CZ, be put into mixer and mixed Refining 5~10 minutes, melting temperature are controlled at 90~100 DEG C, obtain two-stage mixing glue;
D, two-stage mixing glue is vulcanized with vulcanizing press, curing temperature control is at 145~150 DEG C, vulcanization time At 20~25 minutes, sulfide stress was controlled in 10~15MPa for control, obtained anti-material sticks heat resistance conveyor belt rubber cover.
The invention discloses following technical effects: anti-material sticks heat resistance conveyor belt rubber cover product has good in the present invention Good antistatic property, can significantly reduce viscous ash quantity of conveyer belt during conveying powder material, solve production for enterprise And environmental issue.Test result shows that compared with unmodified conveyer belt, such rubber cover can reduce cement adhesive capacity and exist 60% or more.
Specific embodiment
Below in conjunction with the embodiment of the present invention, technical scheme in the embodiment of the invention is clearly and completely described, Obviously, described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based in the present invention Embodiment, every other embodiment obtained by those of ordinary skill in the art without making creative efforts, all Belong to the scope of protection of the invention.
In order to make the foregoing objectives, features and advantages of the present invention clearer and more comprehensible, With reference to embodiment The present invention is described in further detail.
Embodiment 1
A kind of heat resistance conveyor belt rubber cover, is made of the component of following parts by weight: butadiene-styrene rubber is 100 parts, high temperature resistant rubber Glue is 40 parts, white carbon black is 20 parts, heat-resistant agent is 30 parts, zinc oxide is 10 parts, stearic acid is 1 part, DM is 0.5 part, CZ 1 Part, DTDM are 0.5 part, coumarone is 4.5 parts, TMTD is 1 part, antistatic agent is 5 parts, Stiffening agent is 3 parts.
The preparation method of the heat resistance conveyor belt rubber cover, comprising the following steps:
(1) butadiene-styrene rubber and high-temperature resistant rubber are put into mixer and carry out mixing 2min, heat-resistant agent, ancient horse is then added Grand, zinc oxide, stearic acid, antioxidant D D, white carbon black, antistatic agent, Stiffening agent are kneaded 5 minutes, and melting temperature is controlled 120 DEG C, obtain one section of rubber compound;
B, one section of rubber compound is cooled to room temperature;
C, by one section of rubber compound, vulcanization accelerator TMTD, accelerator D TDM, accelerator DM, vulcanization accelerator CZ is put into mixer and be kneaded 5 minutes, and melting temperature is controlled at 90 DEG C, obtains two-stage mixing glue;
D, two-stage mixing glue is vulcanized with vulcanizing press, at 145 DEG C, vulcanization time control exists for curing temperature control 20 minutes, sulfide stress was controlled in 10MPa, obtained heat resistance conveyor belt rubber cover.
Embodiment 2
A kind of heat resistance conveyor belt rubber cover of anti-material sticks, is made of: butadiene-styrene rubber 100 component of following parts by weight Part, high-temperature resistant rubber are 50 parts, white carbon black is 25 parts, heat-resistant agent is 45 parts, zinc oxide is 15 parts, stearic acid is 2 parts, DM is 0.75 part, CZ be 1.3 parts, DTDM is 1 part, coumarone is 5 parts, TMTD is 1.3 parts, antistatic agent is 8 parts, Stiffening agent 4.5 Part.
The preparation method of the heat resistance conveyor belt rubber cover of the anti-material sticks, comprising the following steps:
(1) butadiene-styrene rubber and high-temperature resistant rubber are put into mixer and carry out mixing 2min, heat-resistant agent, ancient horse is then added Grand, zinc oxide, stearic acid, antioxidant D D, white carbon black, antistatic agent, Stiffening agent are kneaded 8 minutes, and melting temperature is controlled 125 DEG C, obtain one section of rubber compound;
B, one section of rubber compound is cooled to room temperature;
C, by one section of rubber compound, vulcanization accelerator TMTD, accelerator D TDM, accelerator DM, vulcanization accelerator CZ is put into mixer and be kneaded 7.5 minutes, and melting temperature is controlled at 95 DEG C, obtains two-stage mixing glue;
D, two-stage mixing glue is vulcanized with vulcanizing press, at 147 DEG C, vulcanization time control exists for curing temperature control 22.5 minutes, sulfide stress was controlled in 12.5MPa, obtained heat resistance conveyor belt rubber cover.
Embodiment 3
A kind of heat resistance conveyor belt rubber cover of anti-material sticks, is made of: butadiene-styrene rubber 100 component of following parts by weight Part, high-temperature resistant rubber are 60 parts, white carbon black is 30 parts, heat-resistant agent is 60 parts, zinc oxide is 20 parts, stearic acid is 3 parts, DM 1 Part, CZ are 1.5 parts, DTDM is 1.5 parts, coumarone is 5.5 parts, TMTD is 1.5 parts, antistatic agent is 10 parts, Stiffening agent 6 Part.
The preparation method of the heat resistance conveyor belt rubber cover of the anti-material sticks, comprising the following steps:
(1) butadiene-styrene rubber and high-temperature resistant rubber are put into mixer and carry out mixing 2min, heat-resistant agent, ancient horse is then added Grand, zinc oxide, stearic acid, antioxidant D D, white carbon black, antistatic agent, Stiffening agent are kneaded 10 minutes, and melting temperature is controlled 130 DEG C, obtain one section of rubber compound;
B, one section of rubber compound is cooled to room temperature;
C, by one section of rubber compound, vulcanization accelerator TMTD, accelerator D TDM, accelerator DM, vulcanization accelerator CZ is put into mixer and be kneaded 10 minutes, and melting temperature is controlled at 100 DEG C, obtains two-stage mixing glue;
D, two-stage mixing glue is vulcanized with vulcanizing press, at 150 DEG C, vulcanization time control exists for curing temperature control 25 minutes, sulfide stress was controlled in 15MPa, obtained heat resistance conveyor belt rubber cover.
Conveyer belt coating rubber made from above-described embodiment 1-3 is tested for the property:
The physical property and adherency cement amount of anti-material sticks heat resistance conveyor belt rubber cover, as shown in table 1,
Table 1
Mechanical property and adherency cement amount are as shown in table 2 after anti-material sticks heat resistance conveyor belt rubber cover aging,
Table 2
The all data index in table 3, these indexs and national standard can be calculated from the data of Tables 1 and 2 The performance indicator of T3 grades of conveyer belts is compared in " GB/T 20021-2005 canvas core heat resistance conveyor belt ", up to or over National standard, therefore, the heat resistance conveyor belt rubber cover of anti-material sticks prepared by the invention patent can either meet national mark Alignment request, and there is excellent anti-material sticks effect, it plays a role to reduce production line dust, reinforcing environmental protection.
The heat-resisting rubber cover ageing-resistant performance of the anti-material sticks of table 3 and cement adhesive capacity
Embodiment described above is only that preferred embodiment of the invention is described, and is not carried out to the scope of the present invention It limits, without departing from the spirit of the design of the present invention, those of ordinary skill in the art make technical solution of the present invention Various changes and improvements, should all fall into claims of the present invention determine protection scope in.

Claims (9)

1. a kind of heat resistance conveyor belt rubber cover of anti-material sticks, it is characterised in that: be made of the component of following parts by weight: butylbenzene Rubber is 100 parts, high-temperature resistant rubber is 40~60 parts, reinforcing agent is 20~30 parts, heat-resistant agent is 30~60 parts, vulcanizing activator For 11~23 parts, vulcanization accelerator be 3~5.5 parts, 0.5~1.5 part of anti-aging agent, coumarone are 4.5~5.5 parts, antistatic agent It is 3~6 parts for 5~10 parts, Stiffening agent.
2. a kind of heat resistance conveyor belt rubber cover of anti-material sticks according to claim 1, it is characterised in that: the reinforcement Agent is white carbon black.
3. a kind of heat resistance conveyor belt rubber cover of anti-material sticks according to claim 1, it is characterised in that: described heat-resisting Agent is magnesinm methacrylate and magnesia mixture.
4. a kind of heat resistance conveyor belt rubber cover of anti-material sticks according to claim 1, it is characterised in that: the vulcanization Activating agent is nano zine oxide and stearic acid, and the nano zine oxide and stearic acid ratio by weight are 10~20:1~3.
5. a kind of heat resistance conveyor belt rubber cover of anti-material sticks according to claim 1, it is characterised in that: the vulcanization Promotor be DM, CZ, DTDM and TMTD, described DM, CZ, DTDM and TMTD ratio by weight be 0.5~1:1~1.5:0.5~ 1.5:1~1.5.
6. a kind of heat resistance conveyor belt rubber cover of anti-material sticks according to claim 1, it is characterised in that: described anti-old Agent is 6- dodecyl -2,2,4- trimethyl -1,2- dihyaroquinoline.
7. a kind of heat resistance conveyor belt rubber cover of anti-material sticks according to claim 1, it is characterised in that: it is described resist it is quiet Electric agent is conductive black, and the resistivity of the conductive black is 1.0~3.0 Ω m.
8. a kind of heat resistance conveyor belt rubber cover of anti-material sticks according to claim 1, it is characterised in that: described to increase just Agent is nano silica.
9. the preparation method of the heat resistance conveyor belt rubber cover of any one anti-material sticks according to claim 1~8, feature It is, comprising the following steps:
(1) by the high-temperature resistant rubber of the butadiene-styrene rubber of 100 parts by weight and 40~60 parts by weight be put into mixer carry out mixing 2~ Then the oxidation of the heat-resistant agent of 30~60 parts by weight, the coumarone, 10~20 parts by weight of 4.5~5.5 parts by weight is added in 5min The stearic acid of zinc, 1~3 parts by weight, the antioxidant D D of 0.5~1.5 parts by weight, the white carbon black of 20~30 parts by weight, 5~10 weight Part antistatic agent, 3~6 parts by weight Stiffening agent, be kneaded 5~10 minutes, melting temperature control at 120~130 DEG C, obtain one Section rubber compound;
B, one section of rubber compound is cooled to room temperature;
C, by one section of rubber compound, the vulcanization accelerator TMTD of 1~1.5 parts by weight, 0.5~1.5 parts by weight vulcanization accelerator DTDM, the accelerator DM of 0.5~1 parts by weight, 1~1.5 parts by weight accelerator CZ, be put into mixer and be kneaded 5~10 minutes, melting temperature was controlled at 90~100 DEG C, obtained two-stage mixing glue;
D, two-stage mixing glue is vulcanized with vulcanizing press, at 145~150 DEG C, vulcanization time is controlled for curing temperature control At 20~25 minutes, sulfide stress was controlled in 10~15MPa, obtained anti-material sticks heat resistance conveyor belt rubber cover.
CN201810882191.7A 2018-08-06 2018-08-06 A kind of heat resistance conveyor belt rubber cover of anti-material sticks and preparation method thereof Pending CN109233026A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810882191.7A CN109233026A (en) 2018-08-06 2018-08-06 A kind of heat resistance conveyor belt rubber cover of anti-material sticks and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810882191.7A CN109233026A (en) 2018-08-06 2018-08-06 A kind of heat resistance conveyor belt rubber cover of anti-material sticks and preparation method thereof

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CN109233026A true CN109233026A (en) 2019-01-18

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20050096433A1 (en) * 2003-10-31 2005-05-05 Mitsuboshi Belting Ltd. Power transmission belt
CN101250305A (en) * 2008-04-07 2008-08-27 北京化工大学 A rubber composite material for a high heat-resistant conveyor belt cover
CN105199173A (en) * 2015-10-21 2015-12-30 无锡宝通科技股份有限公司 Common heat-resisting conveyer belt cover rubber and preparation method thereof
CN106243429A (en) * 2016-08-29 2016-12-21 樊之雄 A kind of flame-retardant and anti-static conveyer belt cover layer elastomeric material and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20050096433A1 (en) * 2003-10-31 2005-05-05 Mitsuboshi Belting Ltd. Power transmission belt
CN101250305A (en) * 2008-04-07 2008-08-27 北京化工大学 A rubber composite material for a high heat-resistant conveyor belt cover
CN105199173A (en) * 2015-10-21 2015-12-30 无锡宝通科技股份有限公司 Common heat-resisting conveyer belt cover rubber and preparation method thereof
CN106243429A (en) * 2016-08-29 2016-12-21 樊之雄 A kind of flame-retardant and anti-static conveyer belt cover layer elastomeric material and preparation method thereof

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