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CN109205992A - Biological sludge heating and pyrohydrolysis system and technique - Google Patents

Biological sludge heating and pyrohydrolysis system and technique Download PDF

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Publication number
CN109205992A
CN109205992A CN201811268027.3A CN201811268027A CN109205992A CN 109205992 A CN109205992 A CN 109205992A CN 201811268027 A CN201811268027 A CN 201811268027A CN 109205992 A CN109205992 A CN 109205992A
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steam
biological sludge
thermal hydrolysis
pyrohydrolysis
heating
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CN109205992B (en
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赵李铁
昌盛
周武林
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Hunan Hongsheng Science And Technology Development Co Ltd
Changsha University of Science and Technology
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Hunan Hongsheng Science And Technology Development Co Ltd
Changsha University of Science and Technology
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/18Treatment of sludge; Devices therefor by thermal conditioning
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor

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  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Treatment Of Sludge (AREA)

Abstract

本发明公开了一种生物污泥加热与热水解系统及工艺,该系统包括依次用管道首尾连通的物料预热器、物料输送泵、一级蒸汽喷射器、物料储存器、进料泵、热水解反应器、出料泵、蒸汽闪蒸器和泄压阀,以及用于对热水解反应器中生物污泥进行加热的二级蒸汽喷射器。该工艺采用上述系统进行加热和热水解。本发明生物污泥加热与热水解系统具有传热效果好、物料受热均匀性好、蒸汽消耗量小、加热时间短、连续操作稳定性好等优点,能够广泛用于降解生物污泥,有着很好的应用价值和应用前景。本发明生物污泥加热与热水解系统工艺具有工艺简单、操作方便、处理成本低、处理效率高、处理效果好等优点,有利于提高生物污泥的利用率以及扩大厌氧消化的应用范围。

The invention discloses a biological sludge heating and thermal hydrolysis system and process. The system comprises a material preheater, a material conveying pump, a first-stage steam ejector, a material storage, a feeding pump, Thermal hydrolysis reactor, discharge pump, steam flasher and pressure relief valve, and secondary steam ejector for heating biological sludge in the thermal hydrolysis reactor. The process uses the system described above for heating and thermal hydrolysis. The biological sludge heating and thermal hydrolysis system of the invention has the advantages of good heat transfer effect, good heating uniformity of materials, small steam consumption, short heating time, good continuous operation stability, etc., and can be widely used for degrading biological sludge. Very good application value and application prospects. The biological sludge heating and thermal hydrolysis system process of the invention has the advantages of simple process, convenient operation, low processing cost, high processing efficiency, good processing effect, etc., and is beneficial to improve the utilization rate of biological sludge and expand the application range of anaerobic digestion .

Description

Biological sludge heating and pyrohydrolysis system and technique
Technical field
The invention belongs to biological sludge recycling treatment field, it is related to a kind of biological sludge heating and pyrohydrolysis system and work Skill.
Background technique
With the continuous development of society and economy the yield of the biological sludges such as biogas residue, activated sludge is increasing.Currently, The pretreated research hotspot of biological sludge include high-temperature-hot-water solution, biological acidification hydrolysis, high temperature and pressure oxidation, ultrasonication, High temperature homogeneous, ozone chemistry processing etc., wherein the characteristics of high-temperature-hot-water solution technology is that biological sludge is warmed to 150-180 DEG C, To achieve the purpose that destroy flocculation structure, destroy cell wall tissue and degradation part macromolecular substances.Due to high-temperature-hot-water solution energy Solid particle and macromolecular substances difficult to degrade be in enough bio-sludge degradings to increase the content of organic acid and dissolved organic matter, In this, as the preposition preprocessing process of anaerobic digestion, is conducive to the gas production for increasing anaerobic digestion and reduces the production for consuming biogas residue Output, thus high-temperature-hot-water solution technology is used for the preposition pretreatment of anaerobic digestion.
Existing sludge hot hydrolysis system mainly includes intermittent pyrohydrolysis system (such as CAMBI (health is green) product), continuous vertical Formula baffle plate pyrohydrolysis system (such as Veolia Exelys product) and hot oil tubular heating system (such as Ovivo water LysoTherm product), wherein the most extensive as the intermittent pyrohydrolysis systematic difference of representative using CAMBI.With CAMBI product For, intermittent pyrohydrolysis system includes preheating pulp tank, hot water solution reaction kettle and pressure release flash tank, and main flow includes will Dry solid content is pumped into preheating pulp tank for the dewatered sludge of 16-18% and is preheated to 90-100 DEG C, and it is anti-to be then pumped into pyrohydrolysis It answers kettle to be heated to 165 DEG C, and reacts at this temperature 20-30 minutes, sludge is sent into the cooling of pressure release flash tank after the reaction was completed To 100 DEG C, temperature needed for continuing cool to anaerobic digestion later.But intermittent pyrohydrolysis system and technique there are still with Lower shortcoming: it is passed through steam preheating in the preheating pulp tank of big volume, since dewatered sludge dry solid is at concentrations up to 16- 18%, being heated evenly property of sludge is poor in heating process, and heat transfer efficiency is low, so as to cause heating the time required to long, steam consumption Amount is big;The pyrohydrolysis process of CAMBI product needs to realize continuous operation using multiple hot water solution reaction kettles, exist program-controlled The problems such as system is complicated, equipment input cost is high.Using Veolia Exelys product as the vertical continuous baffle plate pyrohydrolysis system of representative System mainly by installing baffle plate in Vertical Heat hydrolysis reactor, and promotes effect by steam and realizes sludge in pyrohydrolysis Reactor internal circulation flow, to reach the required reaction time (about 20min), due to the mobility of high solids content sludge and mixed Conjunction property is all poor, causes the technology when handling high solids content sludge, heat transfer efficiency is low, heating uniformity is poor, steam consumption Amount is high, continuous operation stability is poor.If reducing sewage sludge solid concentration, mud handling capacity and processing energy consumption can be obviously increased, is led Cause processing cost higher.Hot oil tubular heating system (such as Ovivo water LysoTherm product) is using oily heat pipe-type heating Device heats sludge, as the viscosity of high solids content sludge is big and poor fluidity and leads to lower heat transfer efficiency, thus Increase the manufacture and operating cost of equipment.It can be seen that equipment employed in existing high-temperature-hot-water solution technology is in processing Gao Gu Generally existing following problems when body content sludge: heat-transfer effect is poor, material uneven heating is even, steam consumption is big, heating time is long, It is poor to operate continuously stability, and thus leads to equipment input cost height, processing cost height, poor processing effect.In addition, The biological sludges such as activated sludge are pre-processed using existing high-temperature-hot-water solution equipment and technique in actual application, then High-temperature-hot-water solution treated product is subjected to anaerobic digestion, whole gas production can not be significantly improved, this is primarily due to existing There are pyrohydrolysis equipment and technique to be difficult to the hardly degraded organic substance in the biological sludges such as hydrolysing activity sludge, and these are difficult to degrade organic Object is difficult to effectively degrade in existing anaerobic digestion process, so as to cause the reduction of anaerobic digestion rate, imitates the degradation of anaerobic digestion Fruit and whole gas production are bad.The presence of the above problem limits the application effect and application range of anaerobic digestion techniques, very Be unfavorable for biological sludge be effectively treated and recycling recycle, the due value of biological sludge can not be played.Therefore, such as What, which is effectively improved the above problem, obtains that a kind of heat-transfer effect is good, being heated evenly property of material is good, steam consumption is small, heating time Short, the continuous operation good pyrohydrolysis device of stability and the pyrohydrolysis method that matches for improve the utilization rate of biological sludge with And the application range of expansion anaerobic digestion is of great significance.
Summary of the invention
The technical problem to be solved by the present invention is to overcome the deficiencies in the prior art, provide a kind of heat-transfer effect is good, material by Biological sludge heating and the pyrohydrolysis system that thermal uniformity is good, steam consumption is small, heating time is short, continuous operation stability is good And technique.
In order to solve the above technical problems, the present invention uses following technical scheme.
A kind of heating of biological sludge and pyrohydrolysis system, the biological sludge heating and pyrohydrolysis system include successively with managing The material preheater of road head and the tail connection, material-handling pump, level-one steam jet ejector, material storage storage, feed pump, pyrohydrolysis reaction Device, discharging pump, steam flash vessel and relief valve;The biological sludge heating further includes for anti-to pyrohydrolysis with pyrohydrolysis system Answer the second steam injector that biological sludge is heated in device.
Above-mentioned biological sludge heating and pyrohydrolysis system, further improved, the second steam injector includes outer Set steam pipeline and the external steam injection pipe of at least one, one end of the external steam injection pipe and external steam pipeline Connection, the other end are connected to pyrohydrolysis reactor;The pyrohydrolysis reactor is in horizontally disposed cylindrical structure, the pyrohydrolysis Spiral deflector, oblique deflector, vertical deflector or partition board are equipped in reactor.
Above-mentioned biological sludge heating and pyrohydrolysis system, further improved, the second steam injector includes interior Steam pipeline is set, one end of the built-in steam pipeline is installed in the side of pyrohydrolysis reactor, and the other end extend into heat The inside of hydrolysis reactor;The built-in steam pipeline is equipped with steam jetting hole.
Above-mentioned biological sludge heating and pyrohydrolysis system, further improved, the built-in steam pipeline rotary type It is installed in the side of pyrohydrolysis reactor;The built-in steam pipeline and pyrohydrolysis reactor are externally connected to for rotating The power mechanism of built-in steam pipeline;The power mechanism includes motor and driving wheel group, and the motor passes through driving wheel group Drive built-in steam pipeline rotation.
Above-mentioned biological sludge heating and pyrohydrolysis system, it is further improved, it is connected on the built-in steam pipeline There is at least one steam diffuser;The side wall of the steam diffuser is equipped with steam diffusion hole.
Above-mentioned biological sludge heating and pyrohydrolysis system, further improved, the built-in steam pipeline is equipped with Helical feed plate.
Above-mentioned biological sludge heating and pyrohydrolysis system, further improved, the built-in fixed dress of steam pipeline Set on the side of pyrohydrolysis reactor;The pyrohydrolysis reactor is in horizontally disposed cylindrical structure, the pyrohydrolysis reactor Interior to be equipped at least one piece of partition board, the partition board is located at the top of built-in steam pipeline.
Above-mentioned biological sludge heating and pyrohydrolysis system, further improved, the built-in fixed dress of steam pipeline Set on the side of pyrohydrolysis reactor, at least one steam diffuser, the steam are communicated on the built-in steam pipeline The side wall of diffuser is equipped with steam diffusion hole.
Above-mentioned biological sludge heating and pyrohydrolysis system, further improved, the built-in fixed dress of steam pipeline Set on the side of pyrohydrolysis reactor, the built-in steam pipeline is equipped with helical feed plate.
As a general technical idea, described the present invention also provides a kind of heating of biological sludge and pyrohydrolysis technique Biological sludge heating carries out heating and pyrohydrolysis, packet with pyrohydrolysis system using above-mentioned biological sludge heating with pyrohydrolysis technique Include following steps:
S1, the biological sludge in material preheater is preheated;
S2, the biological sludge after preheating in step S1 is continuously conveyed to level-one steam jet ejector using material-handling pump In, level-one heating is carried out to biological sludge using high steam, gained biological sludge is stored in material storage storage;
S3, biological sludge in material storage storage is continuously conveyed into pyrohydrolysis reactor using feed pump, is utilized simultaneously High steam is continuously conveyed into pyrohydrolysis reactor and carries out second level heating to biological sludge by second steam injector, and heat occurs Hydrolysis;
S4, the feed liquid in step S3 after pyrohydrolysis is continuously conveyed into steam flash vessel using discharging pump, is led to simultaneously It crosses control relief valve to flash the feed liquid in steam flash vessel, obtains low-pressure steam and pyrohydrolysis concentrate, gained low pressure Steam is back in step S1 for preheating to the biological sludge in material preheater, is discharged into outside gained pyrohydrolysis concentrate Row subsequent processing completes the processing to biological sludge.
Above-mentioned biological sludge heating and pyrohydrolysis technique, it is further improved, in the step S1, the biological sludge For biogas residue and/or activated sludge.
Above-mentioned biological sludge heating and pyrohydrolysis technique, further improved, in the step S4, the pyrohydrolysis is dense The subsequent processing of contracting liquid uses any one following mode;
Mode one: being cooled to 35 DEG C~55 DEG C for pyrohydrolysis concentrate, and progress level-one is sent into level-one anaerobic digester to detest Oxygen digestion;
Mode two: being cooled to 35 DEG C~55 DEG C for pyrohydrolysis concentrate, and progress second level is sent into secondary anaerobic digester to detest Oxygen digestion;
Mode three: pyrohydrolysis concentrate is separated by solid-liquid separation, and obtained solid is used as organic fertilizer after being dehydrated, being dried, Gained liquid is sent as the raw material for producing biogas to level-one anaerobic digester or secondary anaerobic digester.
Compared with the prior art, the advantages of the present invention are as follows:
(1) the present invention provides a kind of heating of biological sludge and pyrohydrolysis system, including successively with pipeline head and the tail connection Material preheater, material-handling pump, level-one steam jet ejector, material storage storage, feed pump, pyrohydrolysis reactor, discharging pump, steaming Vapour flash vessel and relief valve, and the second steam injector for being heated to biological sludge in pyrohydrolysis reactor.This In invention, biological sludge heating is equipped with level-one steam jet ejector with pyrohydrolysis system, is steamed high pressure using level-one steam jet ejector Vapour is sufficiently mixed with biological sludge, carries out level-one heating to biological sludge using the heat of high steam, being capable of augmentation of heat transfer effect Fruit enables biological sludge to be heated rapidly to 100 DEG C or so, can reduce steam consumption, advantageously reduces processing cost, and will High steam and biological sludge are mixed, and mixed effect can be strengthened, i.e. level-one steam jet ejector can be obviously improved biology Mixing efficiency and heat transfer efficiency between sludge and steam reduce heating time and steam consumption.Biological sludge heating and heat Hydrolysis system is equipped with material storage storage, for storing the biological sludge after the heating of level-one steam jet ejector, and the material storing Device occupied area is smaller.On this basis, biological sludge heating is additionally provided with pyrohydrolysis system for pyrohydrolysis reactor Middle biological sludge carries out the second steam injector of second level heating, specially utilizes second steam injector to pyrohydrolysis reactor In be continuously conveyed high steam to biological sludge carry out second level heating, not only can use high steam heat reinforce to biology The heating effect of sludge makes the heat-transfer effect of biological sludge more preferably, so that biological sludge be enable to be rapidly achieved needed for pyrohydrolysis Temperature makes the biological sludge abundant pyrohydrolysis, and the high pressure steaming sprayed into using high speed within a short period of time in pyrohydrolysis reactor Vapour also can enhanced biological sludge mixed effect, reduction is stirred required energy, is conducive to enhance heated equal of biological sludge Even property, to enhance pyrohydrolysis effect, while the high steam that high speed sprays into can also promote biological sludge in pyrohydrolysis reactor Flowing, and the especially refractory organic compounds of the organic substance in biological sludge are efficiently finally hydrolyzed into organic acid and molten The small-molecule substance that solution property organic matter etc. can be efficiently used by microorganism, reaching improves pyrohydrolysis effect, reduces processing cost The purpose of.In addition, biological sludge heating is equipped with feed pump and discharging pump with pyrohydrolysis system, by feed pump and discharging pump It is controlled, can effectively control the input quantity and output quantity of biological sludge in pyrohydrolysis reactor, be conducive to improve continuous add Heat, the stability of pyrohydrolysis and flash distillation, and be conducive to improve treatment effeciency.Biological sludge heating of the present invention has with pyrohydrolysis system Have the advantages that heat-transfer effect is good, being heated evenly property of material is good, steam consumption is small, heating time is short, continuous operation stability is good, It can be widely applied for bio-sludge degrading (such as biogas residue, activated sludge), and can be realized effective degradation to biological sludge, have Application value and application prospect well.
(2) the present invention also provides a kind of heating of biological sludge and pyrohydrolysis technique, dirty using the biology of aforementioned present invention Mud heating carries out heating and pyrohydrolysis with pyrohydrolysis system, and intermittent operation and continous way operation can be realized, have technique It is simple and convenient to operate, the advantages that processing cost is low, treatment effeciency is high, high treating effect, is conducive to the utilization for improving biological sludge Rate and the application range for expanding anaerobic digestion.
Detailed description of the invention
In order to make the object, technical scheme and advantages of the embodiment of the invention clearer, below in conjunction with the embodiment of the present invention In attached drawing, the technical scheme in the embodiment of the invention is clearly and completely described.
Fig. 1 is the structural schematic diagram of biological sludge heating and pyrohydrolysis system in the embodiment of the present invention 1.
Fig. 2 is the structural schematic diagram of biological sludge heating and pyrohydrolysis system in the embodiment of the present invention 2.
Fig. 3 is the structural schematic diagram of pyrohydrolysis reactor in the embodiment of the present invention 2.
Fig. 4 is the structural schematic diagram of biological sludge heating and pyrohydrolysis system in the embodiment of the present invention 3.
Fig. 5 is the structural schematic diagram of pyrohydrolysis reactor in the embodiment of the present invention 3.
Fig. 6 is the structural schematic diagram of biological sludge heating and pyrohydrolysis system in the embodiment of the present invention 4.
Fig. 7 is the structural schematic diagram of biological sludge heating and pyrohydrolysis system in the embodiment of the present invention 5.
Fig. 8 is the structural schematic diagram of biological sludge heating and pyrohydrolysis system in the embodiment of the present invention 6.
Fig. 9 is the structural schematic diagram of biological sludge heating and pyrohydrolysis system in the embodiment of the present invention 7.
Figure 10 is the structural schematic diagram of biological sludge heating and pyrohydrolysis system in the embodiment of the present invention 8.
Figure 11 is the structural schematic diagram of biological sludge heating and pyrohydrolysis system in the embodiment of the present invention 9.
Marginal data:
1, material preheater;2, material-handling pump;3, level-one steam jet ejector;4, material storage storage;5, feed pump;6, hot Hydrolysis reactor;61, spiral deflector;62, oblique deflector;63, vertical deflector;64, partition board;65, material inlet; 66, material outlet;7, second steam injector;71, external steam pipeline;72, external steam injection pipe;73, built-in steam Delivery pipe;74, steam jetting hole;75, power mechanism;751, motor;752, driving wheel group;753, bearing;76, steam is spread Pipe;77, steam diffusion hole;78, helical feed plate;8, discharging pump;9, steam flash vessel;10, relief valve;A, high steam;b, Biological sludge, c, pyrohydrolysis concentrate.
Specific embodiment
Below in conjunction with Figure of description and specific preferred embodiment, the invention will be further described, but not therefore and It limits the scope of the invention.
Embodiment 1
A kind of heating of biological sludge and pyrohydrolysis system, as shown in Figure 1, including that material successively with pipeline head and the tail connection is pre- Hot device 1, material-handling pump 2, level-one steam jet ejector 3, material storage storage 4, feed pump 5, pyrohydrolysis reactor 6, discharging pump 8, Steam flash vessel 9 and relief valve 10, and further include the second level steaming for being heated to biological sludge in pyrohydrolysis reactor 6 Vapour injector 7.
In the present embodiment, second steam injector 7 includes external steam pipeline 71 and the external steam injection of at least one Pipe 72, one end of external steam injection pipe 72 are connected to external steam pipeline 71, and the other end is connected to pyrohydrolysis reactor 6.
In the present embodiment, pyrohydrolysis reactor 6 is in horizontally disposed cylindrical structure, and biological sludge passes through feed pump 5 from heat The material inlet 65 of hydrolysis reactor 6 enters in pyrohydrolysis reactor 6, passes through after the completion of pyrohydrolysis from the discharging of material outlet 66 Discharging pump 8 is delivered in steam flash vessel 9.
In the present embodiment, by control feed pump 5 and discharging pump 8, so that it is dirty effectively to control biology in pyrohydrolysis reactor 6 The input quantity and output quantity of mud, while biological sludge can be driven to exist by the high steam sprayed in external steam injection pipe 72 Transfer in pyrohydrolysis reactor 6.
In the present embodiment, a is high steam, and b is biological sludge, and c is pyrohydrolysis concentrate.
In the present embodiment, biological sludge is preheated in material preheater 1, and will be preheated by material-handling pump 2 Biological sludge afterwards is continuously conveyed into level-one steam jet ejector 3.In 3 mesohigh steam of level-one steam jet ejector and biological sludge It is sufficiently mixed, and level-one heating is carried out to biological sludge using the heat of high steam in mixed process, after gained heating Biological sludge is stored in material storage storage 4.The biological sludge in material storage storage 4 is continuously conveyed to heat using feed pump 5 In hydrolysis reactor 6, while high steam is continuously sprayed into pyrohydrolysis reactor 6 by second steam injector 7, utilizes height It presses the heat of steam to carry out second level heating to biological sludge, so that biological sludge is faster reached pyrohydrolysis required temperature, and high speed is sprayed The high steam entered also can be such that the biological sludge in pyrohydrolysis reactor 6 is vigorously stirred, so that biological sludge be enable to exist Pyrohydrolysis required temperature is sufficiently mixed and is rapidly achieved in short period, and final biological sludge is completed in pyrohydrolysis reactor 6 Pyrohydrolysis.The residence time of pressure and biological sludge in pyrohydrolysis reactor 6 is controlled by discharging pump 8.After the completion of pyrohydrolysis, The feed liquid after pyrohydrolysis is continuously conveyed into steam flash vessel 9 by discharging pump 8, and steam is dodged by control relief valve 10 Feed liquid in steaming pot 9 is flashed, and the gas-liquid in feed liquid is efficiently separated, wherein flash distillation gained low-pressure steam passes through relief valve 10 It is continuously conveyed into material preheater 1 for being preheated to biological sludge, gained pyrohydrolysis concentrate is from 9 bottom of steam flash vessel Portion's discharge, is handled by corresponding subsequent treatment process, to realize the continuous processing to biological sludge.
In the present embodiment, biological sludge heating is equipped with level-one steam jet ejector 3 with pyrohydrolysis system, using level-one steam High steam and biological sludge are sufficiently mixed by injector 3, carry out level-one heating to biological sludge using the heat of high steam, Can augmentation of heat transfer effect, so that biological sludge is heated rapidly to 100 DEG C or so, steam consumption can be reduced, be conducive to drop Reduction process cost, and high steam and biological sludge are mixed, mixed effect, i.e. level-one steam jet ejector 3 can be strengthened The mixing efficiency and heat transfer efficiency that can be obviously improved between biological sludge and steam reduce heating time and steam consumption.It should Biological sludge heating is equipped with material storage storage 4 with pyrohydrolysis system, for storing the biology after the heating of level-one steam jet ejector 3 Sludge, and 4 occupied area of material storage storage is smaller.On this basis, biological sludge heating is additionally provided with pyrohydrolysis system Second steam injector 7 for being heated to biological sludge in pyrohydrolysis reactor 6 is specially sprayed using second steam High steam is continuously conveyed into pyrohydrolysis reactor 6 and carries out second level heating to biological sludge for device 7, wherein second steam injector 7 include external steam pipeline 71 and the external steam injection pipe 72 of at least one, passes through external steam pipeline 71 and at least one High steam high speed is injected in pyrohydrolysis reactor 6 by the external steam injection pipe 72 of root, not only can use high steam Heat reinforces making the heating effect of biological sludge the heat-transfer effect of biological sludge more preferably, to keep biological sludge quick Reach pyrohydrolysis required temperature, promotes the biological sludge abundant pyrohydrolysis, and utilization within a short period of time in pyrohydrolysis reactor 6 High speed spray into high steam also can enhanced biological sludge mixed effect, reduction be stirred required energy, be conducive to enhance The heated uniformity of biological sludge, to enhance pyrohydrolysis effect, while the high steam that high speed sprays into can also promote biological dirt Mud pyrohydrolysis reactor 6 flowing, and it is finally that the especially refractory organic compounds of the organic substance in biological sludge are efficient Ground is hydrolyzed into the small-molecule substance that organic acid and dissolved organic matter etc. can be efficiently used by microorganism, reaches improvement pyrohydrolysis Effect reduces the purpose of processing cost.In addition, biological sludge heating is equipped with feed pump 5 and discharging pump 8 with pyrohydrolysis system, By controlling feed pump 5 and discharging pump 8, can effectively control in pyrohydrolysis reactor 6 input quantity of biological sludge and Output quantity is conducive to the stability for improving laser heating, pyrohydrolysis and flash distillation, and is conducive to improve treatment effeciency.The present invention is raw The heating of object sludge is with pyrohydrolysis system with heat-transfer effect is good, being heated evenly property of material is good, steam consumption is small, heating time It is short, continuous operation stability it is good the advantages that, can be widely applied for bio-sludge degrading (such as biogas residue, activated sludge), and can It realizes effective degradation to biological sludge, there is good application value and application prospect.
Embodiment 2
A kind of heating of biological sludge and pyrohydrolysis system, as shown in Figures 2 and 3, including successively with the object of pipeline head and the tail connection Expect preheater 1, material-handling pump 2, level-one steam jet ejector 3, material storage storage 4, feed pump 5, pyrohydrolysis reactor 6, discharging Pump 8, steam flash vessel 9 and relief valve 10, and further include for being heated to biological sludge in pyrohydrolysis reactor 6 two Grade steam jet ejector 7.
In the present embodiment, second steam injector 7 includes external steam pipeline 71 and the external steam injection of at least one Pipe 72, one end of external steam injection pipe 72 are connected to external steam pipeline 71, and the other end is connected to pyrohydrolysis reactor 6.
In the present embodiment, pyrohydrolysis reactor 6 is in horizontally disposed cylindrical structure, is equipped with spiral in pyrohydrolysis reactor 6 Deflector 61.In the present embodiment, into the biological sludge in pyrohydrolysis reactor 6 by the guide function of spiral deflector 61, Being heated evenly property of material is improved, and improves transmission effect of the biological sludge in pyrohydrolysis reactor 6, so as to improve life The treatment effeciency of object sludge.
In the present embodiment, biological sludge enters pyrohydrolysis from the material inlet 65 of pyrohydrolysis reactor 6 by feed pump 5 In reactor 6, it is delivered in steam flash vessel 9 after the completion of pyrohydrolysis from the discharging of material outlet 66 by discharging pump 8.
In the present embodiment, by control feed pump 5 and discharging pump 8, so that it is dirty effectively to control biology in pyrohydrolysis reactor 6 The input quantity and output quantity of mud, while biological sludge can be driven to exist by the high steam sprayed in external steam injection pipe 72 Transfer in pyrohydrolysis reactor 6.
In the present embodiment, a is high steam, and b is biological sludge, and c is pyrohydrolysis concentrate.
Embodiment 3
A kind of heating of biological sludge and pyrohydrolysis system, as shown in Figures 4 and 5, including successively with the object of pipeline head and the tail connection Expect preheater 1, material-handling pump 2, level-one steam jet ejector 3, material storage storage 4, feed pump 5, pyrohydrolysis reactor 6, discharging Pump 8, steam flash vessel 9 and relief valve 10, and further include for being heated to biological sludge in pyrohydrolysis reactor 6 two Grade steam jet ejector 7.
In the present embodiment, second steam injector 7 includes external steam pipeline 71 and the external steam injection of at least one Pipe 72, one end of external steam injection pipe 72 are connected to external steam pipeline 71, and the other end is connected to pyrohydrolysis reactor 6.
In the present embodiment, pyrohydrolysis reactor 6 is in horizontally disposed cylindrical structure, is equipped in pyrohydrolysis reactor 6 oblique Deflector 62.In the present embodiment, into the biological sludge in pyrohydrolysis reactor 6 by the guide function of oblique deflector 62, It can be improved heat transfer efficiency of the biological sludge in pyrohydrolysis reactor 6, being heated evenly property of biological sludge improved, to improve life The pyrohydrolysis efficiency of object sludge.
In the present embodiment, biological sludge enters pyrohydrolysis from the material inlet 65 of pyrohydrolysis reactor 6 by feed pump 5 In reactor 6, it is delivered in steam flash vessel 9 after the completion of pyrohydrolysis from the discharging of material outlet 66 by discharging pump 8.
In the present embodiment, by control feed pump 5 and discharging pump 8, so that it is dirty effectively to control biology in pyrohydrolysis reactor 6 The input quantity and output quantity of mud, while biological sludge can be driven to exist by the high steam sprayed in external steam injection pipe 72 Transfer in pyrohydrolysis reactor 6.
In the present embodiment, a is high steam, and b is biological sludge, and c is pyrohydrolysis concentrate.
Embodiment 4
A kind of heating of biological sludge and pyrohydrolysis system, as shown in fig. 6, including that material successively with pipeline head and the tail connection is pre- Hot device 1, material-handling pump 2, level-one steam jet ejector 3, material storage storage 4, feed pump 5, pyrohydrolysis reactor 6, discharging pump 8, Steam flash vessel 9 and relief valve 10, and further include the second level steaming for being heated to biological sludge in pyrohydrolysis reactor 6 Vapour injector 7.
In the present embodiment, second steam injector 7 includes external steam pipeline 71 and the external steam injection of at least one Pipe 72, one end of external steam injection pipe 72 are connected to external steam pipeline 71, and the other end is connected to pyrohydrolysis reactor 6.
In the present embodiment, pyrohydrolysis reactor 6 is in horizontally disposed cylindrical structure, is equipped in pyrohydrolysis reactor 6 vertical Deflector 63.In the present embodiment, into the biological sludge in pyrohydrolysis reactor 6 by the guiding function of oblique vertical deflector 63 Can, it can be improved heat transfer efficiency of the biological sludge in pyrohydrolysis reactor 6, being heated evenly property of biological sludge improved, to mention The pyrohydrolysis efficiency of high biological sludge.
In the present embodiment, pyrohydrolysis reactor 6 is in horizontally disposed cylindrical structure.Biological sludge is entered by feed pump 5 Into pyrohydrolysis reactor 6, passes through discharging pump 8 after the completion of pyrohydrolysis and be delivered in steam flash vessel 9.
In the present embodiment, by control feed pump 5 and discharging pump 8, so that it is dirty effectively to control biology in pyrohydrolysis reactor 6 The input quantity and output quantity of mud, while biological sludge can be driven to exist by the high steam sprayed in external steam injection pipe 72 Transfer in pyrohydrolysis reactor 6.
In the present embodiment, a is high steam, and b is biological sludge, and c is pyrohydrolysis concentrate.
Embodiment 5
A kind of heating of biological sludge and pyrohydrolysis system, as shown in fig. 7, comprises the material successively with pipeline head and the tail connection is pre- Hot device 1, material-handling pump 2, level-one steam jet ejector 3, material storage storage 4, feed pump 5, pyrohydrolysis reactor 6, discharging pump 8, Steam flash vessel 9 and relief valve 10, and further include the second level steaming for being heated to biological sludge in pyrohydrolysis reactor 6 Vapour injector 7.
In the present embodiment, second steam injector 7 includes built-in steam pipeline 73, one end of built-in steam pipeline 73 It is installed in the side of pyrohydrolysis reactor 6, the other end extend into the inside of pyrohydrolysis reactor 6, on built-in steam pipeline 73 Equipped with steam jetting hole 74.
In the present embodiment, built-in steam pipeline 73 is fixed at the side of pyrohydrolysis reactor 6.Pyrohydrolysis reactor 6 be in horizontally disposed cylindrical structure, partition board 64 is equipped in pyrohydrolysis reactor 6, it is defeated that partition board 64 is located at built-in steam The top of pipe 73 is sent, and the lower section between two pieces of partition boards 64 is equipped with steam jetting hole 74.It is more by being arranged in the present embodiment Pyrohydrolysis reactor 6 is divided into several smaller spaces by a partition board 64, simultaneously because under between two pieces of partition boards 64 Side is equipped with steam jetting hole 74, it is thus possible to further increase the being heated evenly property of feed liquid and heat transfer speed in pyrohydrolysis reactor 6 Rate, so that feed liquid be made more rapidly and effectively to complete pyrohydrolysis reaction.
In the present embodiment, biological sludge is entered in pyrohydrolysis reactor 6 by feed pump 5, is passed through after the completion of pyrohydrolysis Discharging pump 8 is delivered in steam flash vessel 9.
In the present embodiment, by control feed pump 5 and discharging pump 8, so that it is dirty effectively to control biology in pyrohydrolysis reactor 6 The input quantity and output quantity of mud, while biological sludge can be driven in hot water by the high steam sprayed in steam jetting hole 74 Solve the transfer in reactor 6.
In the present embodiment, a is high steam, and b is biological sludge, and c is pyrohydrolysis concentrate.
Embodiment 6
A kind of heating of biological sludge and pyrohydrolysis system, as shown in figure 8, including that material successively with pipeline head and the tail connection is pre- Hot device 1, material-handling pump 2, level-one steam jet ejector 3, material storage storage 4, feed pump 5, pyrohydrolysis reactor 6, discharging pump 8, Steam flash vessel 9 and relief valve 10, and further include the second level steaming for being heated to biological sludge in pyrohydrolysis reactor 6 Vapour injector 7.
In the present embodiment, second steam injector 7 includes built-in steam pipeline 73, one end of built-in steam pipeline 73 It is installed in the side of pyrohydrolysis reactor 6, the other end extend into the inside of pyrohydrolysis reactor 6, on built-in steam pipeline 73 Equipped with steam jetting hole 74.
In the present embodiment, built-in steam pipeline 73 is fixed at the side of pyrohydrolysis reactor 6.Built-in steam conveying At least one steam diffuser 76 is communicated on pipe 73, the side wall of steam diffuser 76 is equipped with steam diffusion hole 77.This implementation In example, built-in steam pipeline 73 is connected to 76 oblique 45 ° of steam diffuser, since pyrohydrolysis reactor 6 is in horizontally disposed Cylindrical structure, steam diffuser 76 is distributed in biological sludge, is sprayed at this time by steam diffusion hole 77 into biological sludge High steam is uniformly heated biological sludge to further enhance the heat-transfer effect of biological sludge, is uniformly distributed simultaneously Steam diffusion hole 77 can be improved the mass transfer effect of biological sludge, so that the hardly degraded organic substance in biological sludge be made more to increase It is hydrolyzed into the small-molecule substance that can be utilized by microorganism to effect.
In the present embodiment, pyrohydrolysis reactor 6 is in horizontally disposed cylindrical structure.Biological sludge is entered by feed pump 5 Into pyrohydrolysis reactor 6, passes through discharging pump 8 after the completion of pyrohydrolysis and be delivered in steam flash vessel 9.
In the present embodiment, by control feed pump 5 and discharging pump 8, so that it is dirty effectively to control biology in pyrohydrolysis reactor 6 The input quantity and output quantity of mud, while can be driven by the high steam sprayed in steam jetting hole 74 and steam diffusion hole 77 Transfer of the biological sludge in pyrohydrolysis reactor 6.
In the present embodiment, a is high steam, and b is biological sludge, and c is pyrohydrolysis concentrate.
Embodiment 7
A kind of heating of biological sludge and pyrohydrolysis system, as shown in figure 9, including that material successively with pipeline head and the tail connection is pre- Hot device 1, material-handling pump 2, level-one steam jet ejector 3, material storage storage 4, feed pump 5, pyrohydrolysis reactor 6, discharging pump 8, Steam flash vessel 9 and relief valve 10, and further include the second level steaming for being heated to biological sludge in pyrohydrolysis reactor 6 Vapour injector 7.
In the present embodiment, second steam injector 7 includes built-in steam pipeline 73, one end of built-in steam pipeline 73 It is installed in the side of pyrohydrolysis reactor 6, the other end extend into the inside of pyrohydrolysis reactor 6, on built-in steam pipeline 73 Equipped with steam jetting hole 74.
In the present embodiment, built-in steam pipeline 73 is fixed at the side of pyrohydrolysis reactor 6, built-in steam conveying Pipe 73 is equipped with helical feed plate 78.In the present embodiment, by being equipped with helical feed plate 78, benefit on built-in steam pipeline 73 With the guiding role of helical feed plate 78, the being heated evenly property and heat transfer of feed liquid in pyrohydrolysis reactor 6 can be further improved Rate, so that feed liquid be made more rapidly and effectively to complete pyrohydrolysis reaction.
In the present embodiment, pyrohydrolysis reactor 6 is in horizontally disposed cylindrical structure.Biological sludge is entered by feed pump 5 Into pyrohydrolysis reactor 6, passes through discharging pump 8 after the completion of pyrohydrolysis and be delivered in steam flash vessel 9.
In the present embodiment, by control feed pump 5 and discharging pump 8, to effectively control what pyrohydrolysis reactor 6 was imported and exported Pressure difference drives helical feed plate 78 to rotate by pressure difference, and then biological sludge is pushed to turn in pyrohydrolysis reactor 6 It moves, while can also drive biological sludge in pyrohydrolysis reactor 6 by the high steam sprayed in steam jetting hole 74 Transfer.
In the present embodiment, a is high steam, and b is biological sludge, and c is pyrohydrolysis concentrate.
Embodiment 8
A kind of heating of biological sludge and pyrohydrolysis system, as shown in Figure 10, including successively with the material of pipeline head and the tail connection Preheater 1, material-handling pump 2, level-one steam jet ejector 3, material storage storage 4, feed pump 5, pyrohydrolysis reactor 6, discharging pump 8, steam flash vessel 9 and relief valve 10, and further include the second level for being heated to biological sludge in pyrohydrolysis reactor 6 Steam jet ejector 7.
In the present embodiment, second steam injector 7 includes built-in steam pipeline 73, one end of built-in steam pipeline 73 It is installed in the side of pyrohydrolysis reactor 6, the other end extend into the inside of pyrohydrolysis reactor 6, on built-in steam pipeline 73 Equipped with steam jetting hole 74.
In the present embodiment, built-in 73 rotary type of steam pipeline is installed in the side of pyrohydrolysis reactor 6, and built-in steam is defeated Send pipe 73 in the power mechanism 75 of pyrohydrolysis reactor 6 being externally connected to for rotating built-in steam pipeline 73, wherein moving Force mechanisms 75 include that motor 751, driving wheel group 752 and the bearing 753 set on 6 end of pyrohydrolysis reactor, motor 751 pass through biography Driving wheel group 752 is connected to built-in steam pipeline 73, drives built-in steam conveying in the support lower driving wheel group 752 of bearing 753 Pipe 73 rotates.In the present embodiment, built-in steam pipeline 73 can be in 6 inner rotation of pyrohydrolysis reactor, during rotation High steam is constantly sprayed into using the steam jetting hole 74 being arranged on built-in steam pipeline 73, biological sludge is stirred It mixes, the heat-transfer effect of biological sludge can not only be improved, can also improve the mass transfer effect of biological sludge, to enable biological sludge It is enough more quickly to reach pyrohydrolysis temperature, and further promote pyrohydrolysis efficiency and pyrohydrolysis effect.
In the present embodiment, built-in steam pipeline 73 is communicated at least one steam diffuser 76, steam diffuser 76 Side wall is equipped with steam diffusion hole 77, and the angle between built-in steam pipeline 73 and steam diffuser 76 is 45 °, i.e., will be built-in Steam pipeline 73 is connected to 76 oblique 45 ° of steam diffuser.In the present embodiment, since pyrohydrolysis reactor 6 is in horizontally disposed Cylindrical structure, steam diffuser 76 is distributed in biological sludge, is sprayed at this time by steam diffusion hole 77 into biological sludge High steam is uniformly heated biological sludge to further enhance the heat-transfer effect of biological sludge, is uniformly distributed simultaneously Steam diffusion hole 77 can be improved the mass transfer effect of biological sludge, so that the hardly degraded organic substance in biological sludge be made more to increase It is hydrolyzed into the small-molecule substance that can be utilized by microorganism to effect.Particularly, in the present embodiment, built-in steam pipeline 73 can be 6 inner rotation of pyrohydrolysis reactor is right using the steam diffuser 76 being arranged on built-in steam pipeline 73 during rotation Biological sludge is stirred, and the steam jetting hole 74 and steaming by being arranged on built-in steam pipeline 73 during rotation The steam diffusion hole 77 being arranged on vapour diffuser 76 constantly sprays into high steam, can not only improve the heat transfer effect of biological sludge Fruit, can also improve the mass transfer effect of biological sludge, to enable biological sludge more quickly to reach pyrohydrolysis temperature, in turn More efficiently the especially refractory organic compounds pyrohydrolysis of the organic substance in biological sludge is had at organic acid and dissolubility The small-molecule substance that machine object etc. can be efficiently used by microorganism.
In the present embodiment, pyrohydrolysis reactor 6 is in horizontally disposed cylindrical structure.Biological sludge is entered by feed pump 5 Into pyrohydrolysis reactor 6, passes through discharging pump 8 after the completion of pyrohydrolysis and be delivered in steam flash vessel 9.
In the present embodiment, by control feed pump 5 and discharging pump 8, so that it is dirty effectively to control biology in pyrohydrolysis reactor 6 The input quantity and output quantity of mud can also be given birth to by the high steam driving sprayed in steam jetting hole 74 and steam diffusion hole 77 Transfer of the object sludge in pyrohydrolysis reactor 6 can also be existed by the rotate driving biological sludge of built-in steam pipeline 73 Transfer in pyrohydrolysis reactor 6.
In the present embodiment, a is steam, and b is biological sludge, and c is pyrohydrolysis concentrate.
In the present embodiment, biological sludge is preheated in material preheater 1, and will be preheated by material-handling pump 2 Biological sludge afterwards is continuously conveyed into level-one steam jet ejector 3.In 3 mesohigh steam of level-one steam jet ejector and biological sludge It is sufficiently mixed, and level-one heating is carried out to biological sludge using the heat of high steam in mixed process, after gained heating Biological sludge is stored in material storage storage 4.The biological sludge in material storage storage 4 is continuously conveyed to heat using feed pump 5 In hydrolysis reactor 6, while high steam is continuously sprayed into pyrohydrolysis reactor 6 by second steam injector 7, utilizes height It presses the heat of steam to carry out second level heating to biological sludge, so that biological sludge is faster reached pyrohydrolysis required temperature, and high speed is sprayed The high steam entered also can be such that the biological sludge in pyrohydrolysis reactor 6 is vigorously stirred, while built-in steam pipeline 73 Rotation can also enhance the heating effect and mass transfer effect of biological sludge, thus enable biological sludge within a short period of time sufficiently Pyrohydrolysis required temperature is mixed and is rapidly achieved, final biological sludge completes pyrohydrolysis in pyrohydrolysis reactor 6.Pyrohydrolysis is anti- The residence time of pressure and biological sludge in device 6 is answered to be controlled by discharging pump 8.It, will be hot by discharging pump 8 after the completion of pyrohydrolysis Feed liquid after hydrolysis is continuously conveyed into steam flash vessel 9, and by control relief valve 10 to the feed liquid in steam flash vessel 9 into Row flash distillation, efficiently separates the gas-liquid in feed liquid, wherein flash distillation gained low-pressure steam is continuously conveyed by relief valve 10 to material For preheating to biological sludge in preheater 1, gained pyrohydrolysis concentrate is discharged from 9 bottom of steam flash vessel, passes through phase The subsequent treatment process answered is handled, to realize the continuous processing to biological sludge.
In the present embodiment, biological sludge heating is equipped with level-one steam jet ejector 3 with pyrohydrolysis system, using level-one steam High steam and biological sludge are sufficiently mixed by injector 3, carry out level-one heating to biological sludge using the heat of high steam, Can augmentation of heat transfer effect, so that biological sludge is heated rapidly to 100 DEG C or so, steam consumption can be reduced, be conducive to drop Reduction process cost, and high steam and biological sludge are mixed, mixed effect, i.e. level-one steam jet ejector 3 can be strengthened The mixing efficiency and heat transfer efficiency that can be obviously improved between biological sludge and steam reduce heating time and steam consumption.It should Biological sludge heating is equipped with material storage storage 4 with pyrohydrolysis system, for storing the biology after the heating of level-one steam jet ejector 3 Sludge, and 4 occupied area of material storage storage is smaller.On this basis, biological sludge heating is additionally provided with pyrohydrolysis system For carrying out the second steam injector 7 of second level heating to biological sludge in pyrohydrolysis reactor 6, second steam is specially utilized High steam is continuously conveyed into pyrohydrolysis reactor 6 and carries out second level heating to biological sludge for injector 7, and wherein second steam sprays Emitter 7 includes built-in steam pipeline 73 and the steam jetting hole 74 being located on built-in steam pipeline 73, passes through built-in steam High steam high speed is injected in pyrohydrolysis reactor 6 by delivery pipe 73 and steam jetting hole 74, not only can use high pressure steaming The heat of vapour reinforces the heating effect to biological sludge, makes the heat-transfer effect of biological sludge more preferably, to enable biological sludge It is rapidly achieved pyrohydrolysis required temperature, makes the biological sludge abundant pyrohydrolysis, and benefit within a short period of time in pyrohydrolysis reactor 6 With high speed spray into high steam also can enhanced biological sludge mixed effect, reduction be stirred required energy, be conducive to increase The heated uniformity of strong biological sludge, to enhance pyrohydrolysis effect, while the high steam and built-in steam that high speed sprays into The rotation of delivery pipe 73 also can promote biological sludge in the flowing of pyrohydrolysis reactor 6, and finally will be organic in biological sludge Substance especially refractory organic compounds are efficiently hydrolyzed into organic acid and dissolved organic matter etc. can be effectively sharp by microorganism Small-molecule substance, reaching improves pyrohydrolysis effect, reduces the purpose of processing cost.In addition, biological sludge heating and heat Hydrolysis system, which is equipped with feed pump 5 and discharging pump 8, can effectively control hot water by controlling feed pump 5 and discharging pump 8 The input quantity and output quantity for solving biological sludge in reactor 6 are conducive to the stability for improving laser heating, pyrohydrolysis and flash distillation, And be conducive to improve treatment effeciency.With heat-transfer effect, good, material is heated with pyrohydrolysis system for biological sludge heating of the present invention The advantages that even property is good, steam consumption is small, heating time is short, continuous operation stability is good can be widely applied for degradation biological dirt Mud (such as biogas residue, activated sludge), and can be realized effective degradation to biological sludge, there are good application value and application Prospect.
Embodiment 9
A kind of heating of biological sludge and pyrohydrolysis system, as shown in figure 11, including successively with the material of pipeline head and the tail connection Preheater 1, material-handling pump 2, level-one steam jet ejector 3, material storage storage 4, feed pump 5, pyrohydrolysis reactor 6, discharging pump 8, steam flash vessel 9 and relief valve 10, and further include the second level for being heated to biological sludge in pyrohydrolysis reactor 6 Steam jet ejector 7.
In the present embodiment, second steam injector 7 includes built-in steam pipeline 73, one end of built-in steam pipeline 73 It is installed in the side of pyrohydrolysis reactor 6, the other end extend into the inside of pyrohydrolysis reactor 6, on built-in steam pipeline 73 Equipped with steam jetting hole 74.
In the present embodiment, built-in 73 rotary type of steam pipeline is installed in the side of pyrohydrolysis reactor 6, and built-in steam is defeated Send pipe 73 in the power mechanism 75 of pyrohydrolysis reactor 6 being externally connected to for rotating built-in steam pipeline 73, wherein moving Force mechanisms 75 include that motor 751, driving wheel group 752 and the bearing 753 set on 6 end of pyrohydrolysis reactor, motor 751 pass through biography Driving wheel group 752 is connected to built-in steam pipeline 73, drives built-in steam conveying in the support lower driving wheel group 752 of bearing 753 Pipe 73 rotates.In the present embodiment, built-in steam pipeline 73 can be in 6 inner rotation of pyrohydrolysis reactor, during rotation Steam is constantly sprayed into using the steam jetting hole 74 being arranged on built-in steam pipeline 73, biological sludge is stirred, no It only can be improved the heat-transfer effect of biological sludge, can also improve the mass transfer effect of biological sludge, to enable biological sludge more Add and quickly reach pyrohydrolysis temperature, and further promotes pyrohydrolysis efficiency and pyrohydrolysis effect.
In the present embodiment, by being equipped with helical feed plate 78 on built-in steam pipeline 73, helical feed plate 78 is utilized Guiding role, can be further improved the being heated evenly property and rate of heat transfer of feed liquid in pyrohydrolysis reactor 6, to make feed liquid More rapidly and effectively complete pyrohydrolysis reaction.At the same time, in the present embodiment, built-in steam pipeline 73 can be in pyrohydrolysis 6 inner rotation of reactor has 78 pairs of biologies of helical feed plate using what is be arranged on built-in steam pipeline 73 during rotation Sludge is stirred, and is constantly sprayed by the steam jetting hole 74 being arranged on built-in steam pipeline 73 during rotation High steam can not only improve the heat-transfer effect of biological sludge, can also improve the mass transfer effect of biological sludge, to make biology Sludge can more quickly reach pyrohydrolysis temperature, and then more efficiently that the organic substance in biological sludge is especially difficult The small-molecule substance that degradation of organic substances matter pyrohydrolysis can be efficiently used at organic acid and dissolved organic matter etc. by microorganism.
In the present embodiment, pyrohydrolysis reactor 6 is in horizontally disposed cylindrical structure.Biological sludge is entered by feed pump 5 Into pyrohydrolysis reactor 6, passes through discharging pump 8 after the completion of pyrohydrolysis and be delivered in steam flash vessel 9.
In the present embodiment, by control feed pump 5 and discharging pump 8, to effectively control what pyrohydrolysis reactor 6 was imported and exported Pressure difference drives transfer of the biological sludge in pyrohydrolysis reactor 6 by pressure difference, can also pass through 74 He of steam jetting hole Transfer of the high steam driving biological sludge sprayed in steam diffusion hole 77 in pyrohydrolysis reactor 6, can also be by interior Set transfer of the rotate driving biological sludge of steam pipeline 73 in pyrohydrolysis reactor 6.
In the present embodiment, a is high steam, and b is biological sludge, and c is pyrohydrolysis concentrate.
Embodiment 10
A kind of heating of biological sludge and pyrohydrolysis technique, using the biological sludge heating and pyrohydrolysis system in embodiment 9 Heating and pyrohydrolysis are carried out to biological sludge, specially operated using continous way, comprising the following steps:
S1, to the biological sludge (biological sludge be activated sludge, in municipal sewage plant) in material preheater 1 It is preheated.
S2, the biological sludge after preheating in step S1 is delivered in level-one steam jet ejector 3 using material-handling pump 2, High steam is sufficiently mixed with biological sludge in level-one steam jet ejector 3, and biological sludge is carried out using high steam Level-one heating, gained biological sludge are stored in material storage storage 4.
S3, the biological sludge in material storage storage 4 is continuously conveyed into pyrohydrolysis reactor 6 using feed pump 5, simultaneously High steam is continuously conveyed into pyrohydrolysis reactor 6 using second steam injector 7, second level heating is carried out to biological sludge, It is rapidly achieved biological sludge temperature pyrohydrolysis temperature (180 DEG C), it is anti-that pyrohydrolysis occurs in pyrohydrolysis reactor 6 for biological sludge It answers.In the step, effective control to pyrohydrolysis process pressure, temperature and residence time is realized by control discharging pump 8.
S4, the feed liquid in step S3 after pyrohydrolysis is continuously conveyed into steam flash vessel 9 using discharging pump 8, simultaneously The feed liquid in steam flash vessel 9 is flashed by controlling relief valve 10, obtains low-pressure steam and pyrohydrolysis concentrate, gained Low-pressure steam is back in step S1 for preheating to the biological sludge in material preheater 1, gained pyrohydrolysis concentrate Outlet carries out subsequent processing, completes the continuous processing to biological sludge.
In the present embodiment, biological sludge add twice using level-one steam jet ejector 3 and second steam injector 7 Heat makes the biological sludge in pyrohydrolysis reactor 6 quickly and effectively complete pyrohydrolysis, while passing through control feed pump 5, discharging Pump 8 and relief valve 10 can make the feed liquid in steam flash vessel 9 quickly and effectively complete to flash, and keep the gas-liquid in feed liquid effective Separation, to realize the continuous processing to biological sludge.
In the present embodiment, flash distillation gained pyrohydrolysis concentrate can be carried out subsequent by following any following methods in step S4 Processing.
Mode one: being cooled to 35 DEG C~55 DEG C for pyrohydrolysis concentrate, and progress level-one is sent into level-one anaerobic digester to detest Oxygen digestion.
Mode two: being cooled to 35 DEG C~55 DEG C for pyrohydrolysis concentrate, and progress second level is sent into secondary anaerobic digester to detest Oxygen digestion.
Mode three: pyrohydrolysis concentrate is separated by solid-liquid separation, and obtained solid is used as organic fertilizer after being dehydrated, being dried, Gained liquid is sent as the raw material for producing biogas to level-one anaerobic digester or secondary anaerobic digester.
In summary, biological sludge heating of the present invention is steamed with pyrohydrolysis system equipped with level-one steam jet ejector 3 and second level Vapour injector 7, wherein level-one steam jet ejector 3 with biological sludge by mixing using high steam and can add rapidly biological sludge Heat realizes the primary heating (level-one heating) of biological sludge to 100 DEG C or so.On this basis, second steam injector 7 utilizes High steam continues to enable biological sludge to be sufficiently mixed within a short period of time simultaneously to biological sludge reheating (second level heating) It is rapidly achieved pyrohydrolysis required temperature, and by changing the connection side between second steam injector 7 and pyrohydrolysis reactor 6 Formula optimizes the incorporation way of high steam, can effectively control the residence time of biological sludge in pyrohydrolysis reactor 6, protects Card pyrohydrolysis reaction is completed in a relatively short time.Biological sludge heating i.e. of the present invention is sprayed with level-one steam in pyrohydrolysis system The collective effect of device 3 and second steam injector 7 can be obviously improved mixing and heat transfer between biological sludge and high steam Efficiency, while the usage amount of heating required time and high steam can be also substantially reduced, convert biological sludge quickly and effectively For the small-molecule substance that can be used effectively, reaching improves pyrohydrolysis effect, reduces the purpose of processing cost.Meanwhile the present invention In also optimize the structure of pyrohydrolysis reactor 6, be arranged by the position of optimization steam injection pipe and nozzle or in reactor The modes such as partition board 64 reinforce spraying into high steam to the agitation effects of biological sludge, with augmentation of heat transfer efficiency, further Improve heating uniformity and pyrohydrolysis effect.In addition, biological sludge of the present invention heating be equipped in pyrohydrolysis system feed pump 5 and Discharging pump 8 can effectively control the input quantity of biological sludge in pyrohydrolysis reactor 6 by control feed pump 5 and discharging pump 8 And output quantity, be conducive to the stability for improving laser heating, pyrohydrolysis and flash distillation.It can be seen that biological sludge heating of the present invention With pyrohydrolysis system with heat-transfer effect is good, being heated evenly property of material is good, steam consumption is small, heating time is short, continuous operation The advantages that stability is good can be widely applied for degradable organic pollutant (such as biogas residue, activated sludge), and can be realized to organic Effective degradation of pollutant especially persistent organic pollutants has good application value and application prospect, meanwhile, this hair The heating of bright biological sludge and pyrohydrolysis system be able to solve heat-transfer effect existing in the prior art is poor, material uneven heating is even, The problems such as steam consumption is big, heating time is long, continuous operation stability is poor.Biological sludge heating of the present invention and pyrohydrolysis technique, Heating is carried out with pyrohydrolysis system using the heating of above-mentioned biological sludge and pyrohydrolysis is able to achieve intermittent operation and continous way is grasped Make, has many advantages, such as that simple process, easy to operate, processing cost is low, treatment effeciency is high, pyrohydrolysis effect is good, be conducive to improve The utilization rate of biological sludge and the application range for expanding anaerobic digestion.
The above described is only a preferred embodiment of the present invention, being not intended to limit the present invention in any form.Though So the present invention is disclosed as above with preferred embodiment, and however, it is not intended to limit the invention.It is any to be familiar with those skilled in the art Member, in the case where not departing from Spirit Essence of the invention and technical solution, all using in the methods and techniques of the disclosure above Appearance makes many possible changes and modifications or equivalent example modified to equivalent change to technical solution of the present invention.Therefore, Anything that does not depart from the technical scheme of the invention are made to the above embodiment any simple according to the technical essence of the invention Modification, equivalent replacement, equivalence changes and modification, all of which are still within the scope of protection of the technical scheme of the invention.

Claims (10)

1.一种生物污泥加热与热水解系统,其特征在于,所述生物污泥加热与热水解系统包括依次用管道首尾连通的物料预热器(1)、物料输送泵(2)、一级蒸汽喷射器(3)、物料储存器(4)、进料泵(5)、热水解反应器(6)、出料泵(8)、蒸汽闪蒸器(9)和泄压阀(10);所述生物污泥加热与热水解系统还包括用于对热水解反应器(6)中生物污泥进行加热的二级蒸汽喷射器(7)。1. A biological sludge heating and thermal hydrolysis system is characterized in that, the biological sludge heating and thermal hydrolysis system comprises a material preheater (1) and a material delivery pump (2) which are communicated with pipes in turn. , primary steam ejector (3), material storage (4), feed pump (5), thermal hydrolysis reactor (6), discharge pump (8), steam flasher (9) and pressure relief valve (10); the biological sludge heating and thermal hydrolysis system further comprises a secondary steam injector (7) for heating the biological sludge in the thermal hydrolysis reactor (6). 2.根据权利要求1所述的生物污泥加热与热水解系统,其特征在于,所述二级蒸汽喷射器(7)包括外置蒸汽输送管(71)及至少一根外置蒸汽喷射管(72),所述外置蒸汽喷射管(72)的一端与外置蒸汽输送管(71)连通,另一端与热水解反应器(6)连通;所述热水解反应器(6)呈水平设置的圆筒结构,所述热水解反应器(6)内设有螺旋导流板(61)、斜向导流板(62)、垂向导流板(63)或分隔隔板(64)。2 . The biological sludge heating and thermal hydrolysis system according to claim 1 , wherein the secondary steam injector ( 7 ) comprises an external steam conveying pipe ( 71 ) and at least one external steam injector. 3 . Pipe (72), one end of the external steam injection pipe (72) is communicated with the external steam conveying pipe (71), and the other end is communicated with the thermal hydrolysis reactor (6); the thermal hydrolysis reactor (6) ) is a horizontally arranged cylindrical structure, and the thermal hydrolysis reactor (6) is provided with a spiral deflector (61), an oblique deflector (62), a vertical deflector (63) or a dividing baffle ( 64). 3.根据权利要求1所述的生物污泥加热与热水解系统,其特征在于,所述二级蒸汽喷射器(7)包括内置蒸汽输送管(73),所述内置蒸汽输送管(73)的一端装设于热水解反应器(6)的侧端,另一端伸入到热水解反应器(6)的内部;所述内置蒸汽输送管(73)上设有蒸汽喷射孔(74)。3. The biological sludge heating and thermal hydrolysis system according to claim 1, wherein the secondary steam ejector (7) comprises a built-in steam conveying pipe (73), and the built-in steam conveying pipe (73) ) is installed at the side end of the thermal hydrolysis reactor (6), and the other end extends into the interior of the thermal hydrolysis reactor (6); the built-in steam delivery pipe (73) is provided with a steam injection hole ( 74). 4.根据权利要求3项所述的生物污泥加热与热水解系统,其特征在于,所述内置蒸汽输送管(73)转动式装设于热水解反应器(6)的侧端;所述内置蒸汽输送管(73)与热水解反应器(6)的外部连接有用于转动内置蒸汽输送管(73)的动力机构(75);所述动力机构(75)包括电机(751)及传动轮组(752),所述电机(751)通过传动轮组(752)带动内置蒸汽输送管(73)转动。4. The biological sludge heating and thermal hydrolysis system according to claim 3, wherein the built-in steam conveying pipe (73) is rotatably installed at the side end of the thermal hydrolysis reactor (6); A power mechanism (75) for rotating the built-in steam transport pipe (73) is connected with the outside of the thermal hydrolysis reactor (6); the power mechanism (75) includes a motor (751) and a transmission wheel group (752), the motor (751) drives the built-in steam conveying pipe (73) to rotate through the transmission wheel group (752). 5.根据权利要求4所述的生物污泥加热与热水解系统,其特征在于,所述内置蒸汽输送管(73)上连通有至少一根蒸汽扩散管(76);所述蒸汽扩散管(76)的侧壁上设有蒸汽扩散孔(77)。5. The biological sludge heating and thermal hydrolysis system according to claim 4, wherein at least one steam diffusion pipe (76) is communicated with the built-in steam conveying pipe (73); the steam diffusion pipe The side wall of (76) is provided with steam diffusion holes (77). 6.根据权利要求4所述的生物污泥加热与热水解系统,其特征在于,所述内置蒸汽输送管(73)上设有螺旋输送板(78)。6 . The biological sludge heating and thermal hydrolysis system according to claim 4 , wherein a screw conveying plate ( 78 ) is provided on the built-in steam conveying pipe ( 73 ). 7 . 7.根据权利要求3所述的生物污泥加热与热水解系统,其特征在于,所述内置蒸汽输送管(73)固定装设于热水解反应器(6)的侧端;所述热水解反应器(6)呈水平设置的圆筒结构,所述热水解反应器(6)内设有至少一块分隔隔板(64),所述分隔隔板(64)设在内置蒸汽输送管(73)的上方。7. The biological sludge heating and thermal hydrolysis system according to claim 3, wherein the built-in steam conveying pipe (73) is fixedly installed on the side end of the thermal hydrolysis reactor (6); the The thermal hydrolysis reactor (6) has a horizontally arranged cylindrical structure, and at least one partition plate (64) is provided in the thermal hydrolysis reactor (6), and the partition partition plate (64) is arranged in the built-in steam. Above the delivery tube (73). 8.根据权利要求3所述的生物污泥加热与热水解系统,其特征在于,所述内置蒸汽输送(73)管固定装设于热水解反应器(6)的侧端,所述内置蒸汽输送管(73)上连通有至少一根蒸汽扩散管(76),所述蒸汽扩散管(76)的侧壁上设有蒸汽扩散孔(77);8. The biological sludge heating and thermal hydrolysis system according to claim 3, wherein the built-in steam conveying (73) pipe is fixedly installed at the side end of the thermal hydrolysis reactor (6), and the At least one steam diffusion pipe (76) is communicated with the built-in steam conveying pipe (73), and a steam diffusion hole (77) is provided on the side wall of the steam diffusion pipe (76); 或,所述内置蒸汽输送管(73)固定装设于热水解反应器(6)的侧端,所述内置蒸汽输送管(73)上设有螺旋输送板(78)。Or, the built-in steam conveying pipe (73) is fixedly installed on the side end of the thermal hydrolysis reactor (6), and the built-in steam conveying pipe (73) is provided with a screw conveying plate (78). 9.一种生物污泥加热与热水解工艺,其特征在于,所述生物污泥加热与热水解工艺采用权利要求1~8中任一项所述的生物污泥加热与热水解系统进行加热和热水解,包括以下步骤:9 . A biological sludge heating and thermal hydrolysis process, wherein the biological sludge heating and thermal hydrolysis process adopts the biological sludge heating and thermal hydrolysis described in any one of claims 1 to 8 The system performs heating and thermal hydrolysis, including the following steps: S1、对物料预热器(1)中的生物污泥进行预热;S1, preheating the biological sludge in the material preheater (1); S2、利用物料输送泵(2)将步骤S1中预热后的生物污泥连续输送至一级蒸汽喷射器(3)中,利用高压蒸汽对生物污泥进行一级加热,所得生物污泥存储在物料储存器(4)中;S2. Use the material conveying pump (2) to continuously transport the preheated biological sludge in step S1 to the primary steam ejector (3), use high-pressure steam to perform primary heating on the biological sludge, and store the obtained biological sludge in the material storage (4); S3、利用进料泵(5)将物料储存器(4)中的生物污泥连续输送至热水解反应器(6)中,同时利用二级蒸汽喷射器(7)将高压蒸汽连续输送至热水解反应器(6)中对生物污泥进行二级加热,发生热水解反应;S3. The biological sludge in the material storage (4) is continuously transported to the thermal hydrolysis reactor (6) by the feed pump (5), and the high-pressure steam is continuously transported to the thermal hydrolysis reactor (6) by the secondary steam ejector (7). The biological sludge is heated in two stages in the thermal hydrolysis reactor (6), and a thermal hydrolysis reaction occurs; S4、利用出料泵(8)将步骤S3中经热水解后的料液连续输送至蒸汽闪蒸器(9)中,同时通过控制泄压阀(10)对蒸汽闪蒸器(9)中的料液进行闪蒸,得到低压蒸汽和热水解浓缩液,所得低压蒸汽返回至步骤S1中用于对物料预热器(1)中的生物污泥进行预热,所得热水解浓缩液外排进行后续处理,完成对生物污泥的处理。S4, using the discharge pump (8) to continuously transport the feed liquid after thermal hydrolysis in step S3 to the steam flasher (9), and simultaneously control the pressure relief valve (10) to the steam flasher (9). The feed liquid is flashed to obtain low-pressure steam and a thermally hydrolyzed concentrated solution, and the obtained low-pressure steam is returned to step S1 for preheating the biological sludge in the material preheater (1), and the obtained thermally hydrolyzed concentrated solution is outside the Follow-up treatment is carried out to complete the treatment of biological sludge. 10.根据权利要求9所述的生物污泥加热与热水解工艺,其特征在于,所述步骤S1中,所述生物污泥为沼渣和/或活性污泥;10. The biological sludge heating and thermal hydrolysis process according to claim 9, wherein in the step S1, the biological sludge is biogas residue and/or activated sludge; 所述步骤S4中,所述热水解浓缩液的后续处理采用以下任意一种方式;In the step S4, the follow-up treatment of the thermal hydrolysis concentrate adopts any one of the following methods; 方式一:将热水解浓缩液冷却至35℃~55℃,送至一级厌氧消化池中进行一级厌氧消化;Method 1: Cool the hot hydrolysis concentrate to 35℃~55℃, and send it to the first-level anaerobic digestion tank for first-level anaerobic digestion; 方式二:将热水解浓缩液冷却至35℃~55℃,送至二级厌氧消化池中进行二级厌氧消化;Method 2: Cool the hot hydrolysis concentrate to 35°C to 55°C and send it to the secondary anaerobic digestion tank for secondary anaerobic digestion; 方式三:将热水解浓缩液进行固液分离,所得固体经脱水、干燥后作为有机肥料,所得液体作为产沼气的原料送至一级厌氧消化池或二级厌氧消化池。Method 3: The thermally hydrolyzed concentrated liquid is separated into solid and liquid, the obtained solid is dehydrated and dried as organic fertilizer, and the obtained liquid is sent to the first-level anaerobic digester or the second-level anaerobic digester as the raw material for biogas production.
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