CN109199888A - A kind of novel U.S. face and the water of makeup removing function and preparation method thereof - Google Patents
A kind of novel U.S. face and the water of makeup removing function and preparation method thereof Download PDFInfo
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- CN109199888A CN109199888A CN201811358066.2A CN201811358066A CN109199888A CN 109199888 A CN109199888 A CN 109199888A CN 201811358066 A CN201811358066 A CN 201811358066A CN 109199888 A CN109199888 A CN 109199888A
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 169
- 238000002360 preparation method Methods 0.000 title claims abstract description 28
- 229910052500 inorganic mineral Inorganic materials 0.000 claims abstract description 100
- 239000011707 mineral Substances 0.000 claims abstract description 100
- 230000035622 drinking Effects 0.000 claims abstract description 26
- 239000000203 mixture Substances 0.000 claims abstract description 23
- 239000000843 powder Substances 0.000 claims description 123
- 239000004575 stone Substances 0.000 claims description 79
- 238000000498 ball milling Methods 0.000 claims description 57
- 239000000919 ceramic Substances 0.000 claims description 52
- 238000010792 warming Methods 0.000 claims description 46
- 238000000034 method Methods 0.000 claims description 39
- 238000005245 sintering Methods 0.000 claims description 39
- 239000002002 slurry Substances 0.000 claims description 39
- 235000012054 meals Nutrition 0.000 claims description 37
- 238000002156 mixing Methods 0.000 claims description 33
- 238000005406 washing Methods 0.000 claims description 31
- 238000003756 stirring Methods 0.000 claims description 30
- 239000000243 solution Substances 0.000 claims description 29
- 239000000853 adhesive Substances 0.000 claims description 25
- 230000001070 adhesive effect Effects 0.000 claims description 25
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 23
- 230000004048 modification Effects 0.000 claims description 23
- 238000012986 modification Methods 0.000 claims description 23
- 238000004321 preservation Methods 0.000 claims description 23
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 22
- 229910044991 metal oxide Inorganic materials 0.000 claims description 21
- 150000004706 metal oxides Chemical class 0.000 claims description 21
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 20
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 19
- 239000004744 fabric Substances 0.000 claims description 19
- 239000011812 mixed powder Substances 0.000 claims description 19
- 239000011268 mixed slurry Substances 0.000 claims description 19
- 238000000227 grinding Methods 0.000 claims description 18
- 238000001914 filtration Methods 0.000 claims description 17
- 239000008187 granular material Substances 0.000 claims description 14
- 150000001413 amino acids Chemical class 0.000 claims description 13
- 238000005119 centrifugation Methods 0.000 claims description 13
- 235000019441 ethanol Nutrition 0.000 claims description 13
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 claims description 12
- GHVNFZFCNZKVNT-UHFFFAOYSA-N Decanoic acid Natural products CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 claims description 12
- 241000237536 Mytilus edulis Species 0.000 claims description 12
- 235000020638 mussel Nutrition 0.000 claims description 12
- 239000007864 aqueous solution Substances 0.000 claims description 11
- 239000011230 binding agent Substances 0.000 claims description 11
- 229910000420 cerium oxide Inorganic materials 0.000 claims description 11
- 238000001035 drying Methods 0.000 claims description 11
- 239000012065 filter cake Substances 0.000 claims description 11
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 claims description 11
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 11
- 229910052613 tourmaline Inorganic materials 0.000 claims description 11
- 229940070527 tourmaline Drugs 0.000 claims description 11
- 239000011032 tourmaline Substances 0.000 claims description 11
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 claims description 10
- 229910021536 Zeolite Inorganic materials 0.000 claims description 10
- 229910052656 albite Inorganic materials 0.000 claims description 10
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 10
- 230000001376 precipitating effect Effects 0.000 claims description 10
- 239000013049 sediment Substances 0.000 claims description 10
- 239000000661 sodium alginate Substances 0.000 claims description 10
- 235000010413 sodium alginate Nutrition 0.000 claims description 10
- 229940005550 sodium alginate Drugs 0.000 claims description 10
- 239000010457 zeolite Substances 0.000 claims description 10
- 239000011787 zinc oxide Substances 0.000 claims description 9
- 239000003795 chemical substances by application Substances 0.000 claims description 8
- 239000003607 modifier Substances 0.000 claims description 7
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 7
- 229910001928 zirconium oxide Inorganic materials 0.000 claims description 7
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 6
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 5
- 239000007788 liquid Substances 0.000 claims description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 2
- 241000237509 Patinopecten sp. Species 0.000 claims description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 2
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims description 2
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 2
- 235000019422 polyvinyl alcohol Nutrition 0.000 claims description 2
- 229910052573 porcelain Inorganic materials 0.000 claims description 2
- 235000020637 scallop Nutrition 0.000 claims description 2
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 claims description 2
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 claims description 2
- 241000209140 Triticum Species 0.000 claims 2
- 235000021307 Triticum Nutrition 0.000 claims 2
- 235000013312 flour Nutrition 0.000 claims 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims 1
- 239000006210 lotion Substances 0.000 claims 1
- 229910052751 metal Inorganic materials 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- 229910017604 nitric acid Inorganic materials 0.000 claims 1
- 150000002927 oxygen compounds Chemical class 0.000 claims 1
- 235000015170 shellfish Nutrition 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 15
- 239000000126 substance Substances 0.000 abstract description 11
- 150000002632 lipids Chemical class 0.000 abstract description 7
- 239000002994 raw material Substances 0.000 abstract description 6
- 239000002253 acid Substances 0.000 abstract description 5
- 241000894006 Bacteria Species 0.000 abstract description 4
- 241000700605 Viruses Species 0.000 abstract description 4
- 230000006378 damage Effects 0.000 abstract description 4
- 230000008021 deposition Effects 0.000 abstract description 4
- 239000000693 micelle Substances 0.000 abstract description 4
- 235000016709 nutrition Nutrition 0.000 abstract description 4
- 230000035764 nutrition Effects 0.000 abstract description 4
- 230000035515 penetration Effects 0.000 abstract description 4
- 208000027418 Wounds and injury Diseases 0.000 abstract description 3
- 208000014674 injury Diseases 0.000 abstract description 3
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 16
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 14
- 239000002537 cosmetic Substances 0.000 description 10
- 239000000463 material Substances 0.000 description 8
- 229910001961 silver nitrate Inorganic materials 0.000 description 8
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 8
- 238000012360 testing method Methods 0.000 description 8
- 206010013786 Dry skin Diseases 0.000 description 7
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 7
- 239000011148 porous material Substances 0.000 description 7
- 239000000047 product Substances 0.000 description 7
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 6
- 125000004430 oxygen atom Chemical group O* 0.000 description 6
- 239000002245 particle Substances 0.000 description 6
- 238000012545 processing Methods 0.000 description 6
- 229910052739 hydrogen Inorganic materials 0.000 description 5
- 239000001257 hydrogen Substances 0.000 description 5
- 239000007921 spray Substances 0.000 description 5
- 206010000496 acne Diseases 0.000 description 4
- 230000009514 concussion Effects 0.000 description 4
- KSAVQLQVUXSOCR-UHFFFAOYSA-M sodium lauroyl sarcosinate Chemical compound [Na+].CCCCCCCCCCCC(=O)N(C)CC([O-])=O KSAVQLQVUXSOCR-UHFFFAOYSA-M 0.000 description 4
- 208000002874 Acne Vulgaris Diseases 0.000 description 3
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical class OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical class CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 230000004913 activation Effects 0.000 description 3
- 235000013399 edible fruits Nutrition 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 150000003384 small molecules Chemical class 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 244000147568 Laurus nobilis Species 0.000 description 2
- 235000017858 Laurus nobilis Nutrition 0.000 description 2
- 238000005481 NMR spectroscopy Methods 0.000 description 2
- 239000004113 Sepiolite Substances 0.000 description 2
- 235000005212 Terminalia tomentosa Nutrition 0.000 description 2
- 238000005411 Van der Waals force Methods 0.000 description 2
- 125000004429 atom Chemical group 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000003796 beauty Effects 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 230000001815 facial effect Effects 0.000 description 2
- 239000004519 grease Substances 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 229910052622 kaolinite Inorganic materials 0.000 description 2
- 230000003020 moisturizing effect Effects 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 235000019355 sepiolite Nutrition 0.000 description 2
- 229910052624 sepiolite Inorganic materials 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- -1 which can't detect Substances 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical class OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 description 1
- 244000144927 Aloe barbadensis Species 0.000 description 1
- 235000002961 Aloe barbadensis Nutrition 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 206010020751 Hypersensitivity Diseases 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 241000700647 Variola virus Species 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 125000002252 acyl group Chemical group 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 230000007815 allergy Effects 0.000 description 1
- 235000011399 aloe vera Nutrition 0.000 description 1
- JYIBXUUINYLWLR-UHFFFAOYSA-N aluminum;calcium;potassium;silicon;sodium;trihydrate Chemical compound O.O.O.[Na].[Al].[Si].[K].[Ca] JYIBXUUINYLWLR-UHFFFAOYSA-N 0.000 description 1
- 235000019445 benzyl alcohol Nutrition 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 229910001603 clinoptilolite Inorganic materials 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000003845 household chemical Substances 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000003834 intracellular effect Effects 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 235000013372 meat Nutrition 0.000 description 1
- 230000004060 metabolic process Effects 0.000 description 1
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical class COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 229910052755 nonmetal Inorganic materials 0.000 description 1
- 238000001225 nuclear magnetic resonance method Methods 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 229960005323 phenoxyethanol Drugs 0.000 description 1
- 230000035790 physiological processes and functions Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 230000010287 polarization Effects 0.000 description 1
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000011164 primary particle Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 208000017520 skin disease Diseases 0.000 description 1
- 230000036559 skin health Effects 0.000 description 1
- 230000005808 skin problem Effects 0.000 description 1
- MSXHSNHNTORCAW-WTFUTCKNSA-M sodium;(2s,3s,4s,5s,6r)-3,4,5,6-tetrahydroxyoxane-2-carboxylate Chemical compound [Na+].O[C@@H]1O[C@H](C([O-])=O)[C@@H](O)[C@H](O)[C@@H]1O MSXHSNHNTORCAW-WTFUTCKNSA-M 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000013268 sustained release Methods 0.000 description 1
- 239000012730 sustained-release form Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/26—Aluminium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0241—Containing particulates characterized by their shape and/or structure
- A61K8/025—Explicitly spheroidal or spherical shape
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/27—Zinc; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/98—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution of animal origin
- A61K8/987—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution of animal origin of species other than mammals or birds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/14—Preparations for removing make-up
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Zoology (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
Abstract
The invention discloses a kind of novel U.S. face and the water of makeup removing function and preparation method thereof, the water preparation method of the novel U.S. face and makeup removing function is the following steps are included: (1) takes drinking pure water；(2) mineral ball activates.The present invention novel U.S. face and the water of makeup removing function and preparation method thereof, water is activated by mineral ball, obtained water is small-micelle water, penetration and dissolving power are stronger, skin can be penetrated deep into, nutrition needed by human and moisture etc. are transported into the cell, it can be preferably deposition bacterium in the cell, virus, the harmful substances such as the oiliness such as color make-up molecule and lipid carry out dissolving to excrete achieving the purpose that U.S. face, and it is rich in mineral composition, so that the pH of water becomes alkalescent from faintly acid, the oiliness such as color make-up molecule and lipid can be effectively removed, makeup removing effect is good, and this sends out U.S. face novel and the raw material of the water of makeup removing function is drinking pure water, any chemicals is not added, secondary injury will not be caused to skin.
Description
Technical field
The present invention relates to household chemicals technical fields, and in particular to a kind of water and its system of novel U.S. face and makeup removing function
Preparation Method.
Background technique
Makeup can make one to become beautiful, the feeling finding everything fresh and new to people.In life, schoolgirl's makeup is required course.This is exhibition
Show oneself beautiful and glamour good mode.Makeup remover is the cosmetic product for removing ornaments and formal dress.More and more women can be in face now
Upper to smear various cosmetics, makeup is the indispensable work that almost modern female is daily, but cosmetics itself have one to skin
Fixed injury, clear water used for cosmetic are difficult to clean out, and the cosmetics remained on the face can block pore, and it is normal to influence skin
Metabolism, so that the normal physiological function of skin is hindered and is generated various skin diseases, can also accelerate the aging of skin,
So every night must all lay down dressing on the face, if makeup removing is not thorough, cosmetics are remained on the face, meeting blocked pore, then
It is easy to produce serious consequence.
In face of dazzling cosmetics, makeup remover is just particularly important.Makeup remover on the market is broadly divided into two classes,
One kind is makeup remover, and one kind is makeup remover.The ingredient of makeup remover is mainly vegetable oil, mineral oil and artificial synthesized ester and surface
Activating agent.Makeup remover mainly dissolves color make-up or the dirt of face oil as solvent using the characteristic to mix similar between grease
Dirt, makeup removing effect are efficiently thorough.But it is thick and heavy greasy that it uses skin sense, once cleaning not in time instead can blocked pore, draw
Play the skin problems such as acne, acne.Makeup removing water constituent does for the chemical solvent (benzyl alcohol) of surfactant and dissolvable grease
For primary raw material, use is mostly artificial synthesized chemicals such as alcohol, fragrance, pigment etc., be used for a long time stimulation to skin and
It destroys very big.If do not unloaded completely, pore will be blocked for a long time by going down, and cause a series of skin such as coarse pore, blackhead, small pox
Problem.So the people to make up now is more and more, the people of abuse is also more, and the people for the makeup being ignorant of is also more, the result is that the age is gently
It is acne with regard to whole face, causes facial skin impaired, a lot of people are perplexed by beauty.
Summary of the invention
Aiming at the above shortcomings existing in the prior art, technical problem to be solved by the invention is to provide a kind of novel beauty
The water of face and the water of makeup removing function and preparation method thereof, obtained novel U.S. face and makeup removing function is small-micelle water.Due to water
Molecule has polarity (hydrone is polar molecule), and hydrone is in horn shape, hydrogen atom be located at end and oxygen atom then on vertex,
Since the electronegativity of oxygen is higher than hydrogen, so having one side charge of oxygen atom in molecule can bear partially, point with such a charge difference
Son is referred to as dipole.Charge difference makes hydrone attract each other (region of polarization electricity can be attracted by the region of inclined negative electricity), together
When so that them is attracted each other with other polar molecules, lead to that hydrone is easy to pollute, easily links.Terahertz ball is capable of providing one kind
Energy, concussion interrupt co-acting force-Van der Waals force between molecule.Low frequency energy concussion hydrone makes the molecular weight of water exist
500 dalton, high-frequency energy make the molecular weight of water in 700 dalton, become small molecule water.Small molecule water penetration and molten
Xie Li is stronger, can penetrate deep into skin, and nutrition needed by human and moisture etc. are transported into the cell, can be preferably deposition
The harmful substances such as the oiliness such as bacterium, virus, color make-up in the cell molecule and lipid carry out dissolving to excrete reaching U.S. face
Purpose, and it is rich in mineral composition, so that the pH of water becomes alkalescent from faintly acid, the oiliness such as color make-up point can be effectively removed
Son and lipid, makeup removing effect are good.
Object of the present invention is to what is be achieved through the following technical solutions:
A kind of preparation method of the water of novel U.S. face and makeup removing function, comprising the following steps:
(1) drinking pure water is taken；
(2) mineral ball activates: by drinking pure water and mineral ball 100:(5-30 in mass ratio) mixing, it impregnates 2-4 hours,
It filters to get the water of the novel U.S. face and makeup removing function is arrived.
The mineral ball is Terahertz ceramic mineral ball and/or MPH+ ceramic mineral ball.
Preferably, the mineral ball is Terahertz ceramic mineral ball and MPH+ ceramic mineral ball (1-5) in mass ratio: (1-
5) mixture.
The MPH+ ceramic mineral ball is prepared using following methods, and wherein part is parts by weight:
(1) 0.2-2 parts of adhesive are added in 10-20 parts of water, at 75-85 DEG C with 100-300 revs/min of stirring 10-20
Minute, obtain binder solution, by 20-40 part of albite, pretreatment conch meal 15-25 parts, modification medical stone powder 10-20 parts,
10-20 parts of zeolite powder, 8-12 parts of tourmaline powder, 8-12 parts of zinc oxide mixing, with 500-1000 revs/min stirring 40-60 minutes, obtain
Be added in mixed powder to mixed powder, then by binder solution, with 500-1000 revs/min stirring 1-3 hours, obtain mixture
Slurry, then mixed slurry is processed by the spheric granules that diameter is 3-6mm by bowling machine；
(2) spheric granules is 2-4 hours dry at 40-50 DEG C, sintering furnace is placed into, 300- is warming up to 8-12 DEG C/min
400 DEG C, and heat preservation sintering 20-30 minutes, then 650-750 DEG C, and heat preservation sintering 20-30 minutes are warming up to 15-25 DEG C/min,
1000-1100 DEG C, and heat preservation sintering 1-3 hours are warming up to 15-25 DEG C/min again, cool to room temperature with the furnace to get MPH+ pottery
Porcelain mineral ball.
Described adhesive is one of sodium alginate, polyvinyl alcohol, sodium carboxymethylcellulose or a variety of mixtures.
The pretreatment conch meal is prepared using following methods, and wherein part is parts by weight:
(1) shell is cleaned, cleans, drains surface moisture, crush the shell coarse powder for 0.1-1mm；
(2) by 20-30 parts of aqueous sodium carbonate mixing of 5-10 parts of shell coarse powder and 3-8wt%, with 100-300 revs/min
Stirring 40-60 minute, standing 5-10 hours, then with 500-1000 revs/min stirring 20-40 minutes, using 100-300 mesh filter cloth mistake
Filter, filter cake is with water washing 1-3 times of 20-30 parts, and 2-5 hours dry at 100-120 DEG C, the shell for obtaining removal cuticula is thick
Powder；
(3) the shell coarse powder for the removal cuticula that step (2) obtains is packed into ball grinder and carries out ball milling, 5-10 parts of second are added
Alcohol after rotational speed of ball-mill is 400-600 revs/min, ball milling 16-28 hours, obtains ball milling slurries as ball-milling medium；
(4) ball milling slurries are warming up to 60-80 DEG C, 60-80 DEG C with 100-300 revs/min stirring 1-3 hours, changed
Property slurries, will modified slurries in 80-100 DEG C of drying, grinding obtains pretreatment conch meal.
Preferably, the pretreatment conch meal is prepared using following methods, and wherein part is parts by weight:
(1) shell is cleaned, cleans, drains surface moisture, crush the shell coarse powder for 0.1-1mm；
(2) by 20-30 parts of aqueous sodium carbonate mixing of 5-10 parts of shell coarse powder and 3-8wt%, with 100-300 revs/min
Stirring 40-60 minute, standing 5-10 hours, then with 500-1000 revs/min stirring 20-40 minutes, using 100-300 mesh filter cloth mistake
Filter, filter cake is with water washing 1-3 times of 20-30 parts, and 2-5 hours dry at 100-120 DEG C, the shell for obtaining removal cuticula is thick
Powder；
(3) the shell coarse powder for the removal cuticula for obtaining step (2) and 0.01-0.05 part lanthanium titanates loading ball grinders into
Row ball milling is added 5-10 parts of ethyl alcohol as ball-milling medium, after rotational speed of ball-mill is 400-600 revs/min, ball milling 15-25 hours, is added
1-5 parts of 8-12wt% modifier aqueous solutions continue ball milling 1-3 hours, obtain ball milling slurries；
(4) ball milling slurries are warming up to 60-80 DEG C, 60-80 DEG C with 100-300 revs/min stirring 1-3 hours, changed
Property slurries, will modified slurries with 4000-6000 revs/min centrifugation 20-30 minutes, what is obtained is deposited in 80-100 DEG C of drying, grind,
Obtain pretreatment conch meal.
The shell is one of mussel shell, scallop shell, oyster shell, cycle of sixty years shell or a variety of mixtures.
The modifying agent is N- sodium lauroyl sarcosine and/or pungent capric acid acyl oat amino acid nano.
Preferably, the modifying agent is the mixture of N- sodium lauroyl sarcosine and pungent capric acid acyl oat amino acid nano, institute
The mass ratio for stating N- sodium lauroyl sarcosine and pungent capric acid acyl oat amino acid nano is 1:(1-5).
The modified medical stone powder is prepared using following methods, and wherein part is parts by weight:
(1) it by 5-10 parts and 80-120 parts of 3-5wt% hydrochloric acid mixing of medical stone powder, is stirred at 40-50 DEG C with 60-100 revs/min
Mix 20-40 minutes, with 4000-6000 revs/min centrifugation 20-30 minutes, obtained precipitating is washed with water to the nitre with 0.1mol/L
Sour silver solution, which can't detect, Cl in washing lotion-In the presence of what is obtained is precipitated as pretreatment medical stone powder；
(2) medical stone powder will be pre-processed and is warming up to 200-300 DEG C with 8-12 DEG C/min, it is small in 200-300 DEG C of heat preservation 3-4
When, then with furnace cooled to room temperature, grind to get heat modification medical stone；
(3) 4-8 parts and 40-60 parts water of heat modification medical stone are mixed, 0.05-0.2 parts of calgons is added, in 60-
80 DEG C with 60-100 revs/min stirring 10-20 minutes, 0.01 part of metal oxide is added, is stirred at 60-80 DEG C with 60-100 revs/min
Mix 5-10 minutes, then 20-30 DEG C with 60-100 revs/min stirring 20-30 minutes, stand 40-60 minutes, with 5000 revs/min from
The heart 20-30 minutes, lower sediment with 40-60 parts water washing 1-3 times, then it is 4-8 hours dry at 80-100 DEG C, obtain the modification
Medical stone powder.
The metal oxide is one of cerium oxide, zirconium oxide, titanium oxide.
Preferably, the metal oxide is cerium oxide.
A kind of water of novel U.S. face and makeup removing function, is prepared using the above method.
Hydrone is to be linked together by two hydrogen atoms and an oxygen atom by atom chemical combination key.Hydrone is in angle
Shape, hydrogen atom is located at end and oxygen atom then on vertex in the middle.Since the electronegativity of oxygen is higher than hydrogen, so there is oxygen atom in molecule
One side charge can bear partially.Charge difference makes hydrone attract each other, so hydrone has polarity.In addition, a hydrone
In hydrogen atom also have a connection power between the oxygen atom in its neighbouring hydrone, be called hydrogen bond, it is not atom chemical combination
Key, but the molecular link between hydrone.Hydrogen bond is longer, and bond energy is smaller, is easy to be broken by destruction.Due to the effect of hydrogen bond,
It is associated between hydrone, forms big micel and be present in nature.
Terahertz ceramic mineral ball is made of that have natural release terahertz using the ore Compound Machining with natural energy
Hereby wave energy.THz wave (THz) is otherwise known as " life light ", is one kind of " light " energy, refers to wavelength at 3 μm to 1000
Between μm, frequency 0.1-10THz, the electromagnetic wave between microwave and infrared ray.Belong to one kind of far infrared.Terahertz
Ceramic mineral ball issues THz wave, is capable of providing a kind of energy, and concussion interrupts co-acting force-Van der Waals force between molecule.
Low frequency energy concussion hydrone makes the molecular weight of water in 500 dalton, and high-frequency energy makes the molecular weight of water in 700 dongles
, become small molecule water.The penetration and dissolving power of the water of subset are stronger, can penetrate deep into skin, must human body
The nutrition and moisture etc. needed be transported to it is intracellular, can the oiliness molecule such as bacterium, virus, color make-up preferably deposition in the cell
It carries out dissolving to excrete with harmful substances such as lipids achieving the purpose that U.S. face.
MPH+ ceramic mineral ball is roasted using mineral materials such as natural seashells using newest " micropore sustained release " technology and Duo Wen
Technique production is process, and containing there are many beneficial minerals of human body, water can be hydrolyzed reaction so that the pH of water by
Faintly acid (pH value 6-6.8) becomes the alkaline environment of alkalescent (pH value 7.5-9.5).Due to the main component of the cosmetics such as color make-up
For esters and chemical combination such as glycerol, propylene glycol, methyl hydroxybenzoate, Phenoxyethanol, acrylic acid (ester) class, aloe barbadensis Miller leaf extracts
Object is bound up this group of (- COO-) in alkaline water with the organic matter of carboxyl (- COOH) by the sum of hydroxyl (- OH)
Hydrolysis generates carboxylic acid sodium salt and alcohol, soluble easily in water, easily wipes.
By the two comprehensive function, the fruit of U.S. face and makeup removing effect well can be reached.
The Terahertz ceramic mineral ball prepared in the present invention has the effect of significantly discharging far infrared, can make water
Sufficiently activation, becomes small-micelle water.And natural waste conch meal is used, MPH+ ceramics are prepared after conch meal is pre-processed
Mineral ball, conch meal release carbon dioxide makes ceramics form pore structure during the sintering process, and then realizes MPH+ ceramic mineral ball
Slow release effect.Ball milling and modification are carried out to conch meal, form it into molecule and are uniformly mixed with other raw materials, is conducive to
Uniform and small pore structure is formed, promotes MPH+ ceramic mineral ball to the activation effect of water, and then promotes novel U.S. face and unloads
The solvability and penetrating power of the water of adornment function make the water of novel U.S. face and makeup removing function have good U.S. face and makeup removing effect
Fruit.
Terahertz ceramic mineral ball and MPH+ ceramic mineral ball of the invention can be placed in conventional push type cosmetic bottle,
The built-in full water of bottle, by pressing, water is after Terahertz ceramic mineral ball and MPH+ ceramic mineral ball sufficiently activate with spraying shape
Formula sprays.
Specifically, can be by mineral ball as in filter element shell 1, face shell cover board 2 is secured using ultrasonic bonding.?
The end face of shell 1 and housing cover 2 is respectively arranged with the water through-hole excessively of diameter equal distribution, will fill the shell of mineral Ceramic Balls
1 is placed among spray bottle 3, and drinking pure water is poured into spray bottle 3, impregnates 2-4 hours to get the novel U.S. face and makeup removing is arrived
The water of function.User can carry out U.S. face, makeup removing using various ways can be sprayed directly on to needs due to being pure water activation
The position of the makeup removings such as moisturizing, whitening can also be sprayed on facial mask, be used for moisturizing.Or it is sprayed on makeup removing cotton and removes ornaments and formal dress.
The present invention novel U.S. face and the water of makeup removing function and preparation method thereof, are activated water by mineral ball, what is obtained is new
The water of type U.S. face and makeup removing function is small-micelle water, and penetration and dissolving power are stronger, skin can be penetrated deep into, human body
Required nutrition and moisture etc. are transported into the cell, can be preferably oiliness point such as deposition bacterium, virus, color make-ups in the cell
The harmful substances such as son and lipid carry out dissolving to excrete achieving the purpose that U.S. face, and are rich in mineral composition, so that water
PH becomes alkalescent from faintly acid, can effectively remove the oiliness such as color make-up molecule and lipid, makeup removing effect is good, and the present invention is new
The raw material of the water of type U.S. face and makeup removing function is drinking pure water, does not add any chemicals, will not cause to skin secondary
Injury.
Specific embodiment
In the present invention, if not refering in particular to, all devices and raw material is commercially available or the industry is common are following
Method in embodiment is unless otherwise instructed conventional method in that art.
Terahertz ceramic mineral ball can use commercially available Terahertz ceramic mineral ball, can also make by oneself, in embodiment too
Hertz ceramic mineral ball is prepared using following methods, and wherein part is parts by weight: by 35 parts of tourmaline, 25 parts of medical stone,
20 parts of sepiolite, 15 parts of kaolinite, 3 parts of titanium oxide, 2 parts of zirconium oxide, each raw material is mixed by weight, is stirred with 800 revs/min
30 minutes, mixed powder is obtained, adds 15 parts of water, is stirred 2 hours with 800 revs/min, obtains mixed slurry, then pass through bowling machine
Mixed slurry is processed into the spheric granules that diameter is 4mm, spheric granules is 3 hours dry at 45 DEG C, sintering furnace is placed into, with
20 DEG C/min is warming up to 1050 DEG C, and heat preservation sintering 2 hours, cools to room temperature with the furnace to get Terahertz Ceramics Ceramic mineral ball.
Sepiolite is bought from Lingshou County Heng Zhan mineral products processing factory, 800 mesh.
Kaolinite is bought from Ren County Hua Kang nonmetal mineral product processing factory, 800 mesh.
Albite is bought from Lingshou County Jin Yuan mineral products processing factory, 800 mesh.
Mussel after removing meat and impurity, is cleaned using commercially available mussel, obtains mussel shell.
Medical stone powder, purchase is from Lingshou County along damp mineral products processing factory, 800 mesh.
Zeolite powder buys the clinoptilolite powder from Lingshou County along damp mineral products processing factory production, 800 mesh.
Tourmaline powder, purchase is from Lingshou County along damp mineral products processing factory, 800 mesh.
Zinc oxide, No. CAS: 1314-13-2, the nano zine oxide produced from Jiangsu nature new material Co., Ltd is bought,
Model: TZP-50, primary particle size 30nm.
Sodium alginate, No. CAS: 9005-38-3, it buys from Hebei Yan Ke Biotechnology Co., Ltd.
Lanthanium titanate buys the lanthanium titanate crystal produced from Wuxi Kaitianxing Photoelectric Material Co., Ltd..
Sodium lauroyl sarcosine, No. CAS: 137-16-6, it buys from this biochemical technology Co., Ltd of Tianjin Skien, is used
Water is diluted to the sodium lauroyl sarcosine aqueous solution of 10wt%, spare.
Pungent capric acid acyl oat amino acid nano, using application No. is the pungent last of the ten Heavenly stems obtained in embodiment 3 in 201410784026.X
The pungent capric acid acyl oat amino acid nano aqueous solution for 10wt% is diluted with water in sour acyl oat amino acid nano aqueous solution, spare.
Cerium oxide, No. CAS: 1306-38-3, it buys from Shanghai Yun Fu nanosecond science and technology Co., Ltd, granularity: 50 nanometers.
Zirconium oxide, No. CAS: 1314-23-4, it buys from Shanghai Yun Fu nanosecond science and technology Co., Ltd, granularity: 50 nanometers.
Titanium oxide, No. CAS: 1317-80-2, it buys from Shanghai Yun Fu nanosecond science and technology Co., Ltd, granularity: 50 nanometers.
Ball mill, using the bedroom planetary ball mill for the model PBM-40 that crystallization work Machinery Co., Ltd. in Changsha produces
Machine, specific ball milling use zirconia ball grinding jar and diameter 6mm zirconia ball.
Embodiment 1
A kind of preparation method of the water of novel U.S. face and makeup removing function, comprising the following steps:
(1) drinking pure water is taken；
(2) mineral ball activates: by mineral Ceramic Balls as in filter element shell 1, face shell cover board 2 uses ultrasonic bonding
Securely.It is respectively arranged with the water through-hole excessively of diameter equal distribution in the end face of shell 1 and housing cover 2, mineral ceramics will be filled
The shell 1 of ball is placed among spray bottle 3, and step (1) drinking pure water is poured into spray bottle 3, impregnates 3 hours to get described in
The water of novel U.S. face and makeup removing function.
Embodiment 2
A kind of preparation method of the water of novel U.S. face and makeup removing function, comprising the following steps:
(1) drinking pure water is taken；
(2) mineral ball activates: drinking pure water and mineral ball 100:10 in mass ratio being mixed, impregnated 3 hours, is used
200 mesh filter-cloth filterings obtain the water of the novel U.S. face and makeup removing function.
The mineral ball is Terahertz ceramic mineral ball.
Embodiment 3
A kind of preparation method of the water of novel U.S. face and makeup removing function, comprising the following steps:
(1) drinking pure water is taken；
(2) mineral ball activates: drinking pure water and mineral ball 100:10 in mass ratio being mixed, impregnated 3 hours, is used
200 mesh filter-cloth filterings obtain the water of the novel U.S. face and makeup removing function.
The mineral ball is MPH+ ceramic mineral ball.
The MPH+ ceramic mineral ball is prepared using following methods, and wherein part is parts by weight:
(1) 0.5 part of adhesive is added in 15 parts of water, is stirred 15 minutes at 80 DEG C with 200 revs/min, obtains adhesive
Solution, by 30 parts of albite, 20 parts of conch meal of pretreatment, 15 parts of medical stone powder, 15 parts of zeolite powder, 10 parts of tourmaline powder, oxidation
10 parts of zinc mixing, are stirred 50 minutes with 800 revs/min, mixed powder are obtained, then binder solution is added in mixed powder, with 800
Revs/min stirring 2 hours, obtain mixed slurry, then mixed slurry is processed into as the spheric granules of 4mm by diameter by bowling machine；
(2) spheric granules is 3 hours dry at 45 DEG C, sintering furnace is placed into, is warming up to 350 DEG C with 10 DEG C/min, and protect
Temperature sintering 25 minutes, then 700 DEG C, and heat preservation sintering 25 minutes are warming up to 20 DEG C/min, then be warming up to 1050 with 20 DEG C/min
DEG C, and heat preservation sintering 2 hours, room temperature is cooled to the furnace to get MPH+ ceramic mineral ball.
Described adhesive is sodium alginate.
The pretreatment conch meal is prepared using following methods, and wherein part is parts by weight:
(1) shell is cleaned, cleans, drains surface moisture, crush the shell coarse powder for 0.5mm；
(2) it by 25 parts of aqueous sodium carbonate mixing of 8 parts of shell coarse powder and 5wt%, is stirred 50 minutes with 200 revs/min, it is quiet
It sets 6 hours, then is stirred 30 minutes with 800 revs/min, using 100 mesh filter-cloth filterings, filter cake is with water washing 2 times of 25 parts, 110
DEG C dry 3 hours, obtain the shell coarse powder of removal cuticula；
(3) the shell coarse powder for the removal cuticula that step (2) obtains is packed into ball grinder and carries out ball milling, using zirconium oxide
8 parts of ethyl alcohol are added as ball-milling medium in ball, material ball ratio 1:3, and rotational speed of ball-mill is 450 revs/min, ball milling 22 hours, obtains ball milling
Slurries；
(4) by ball milling slurries in 90 DEG C of dryings, 800 meshes are crossed in grinding, obtain pretreatment conch meal.
The shell is mussel shell.
Embodiment 4
A kind of preparation method of the water of novel U.S. face and makeup removing function, comprising the following steps:
(1) drinking pure water is taken；
(2) mineral ball activates: drinking pure water and mineral ball 100:10 in mass ratio being mixed, impregnated 3 hours, is used
200 mesh filter-cloth filterings obtain the water of the novel U.S. face and makeup removing function.
The mineral ball MPH+ ceramic mineral ball.
The MPH+ ceramic mineral ball is prepared using following methods, and wherein part is parts by weight:
(1) 0.5 part of adhesive is added in 15 parts of water, is stirred 15 minutes at 80 DEG C with 200 revs/min, obtains adhesive
Solution, by 30 parts of albite, 20 parts of conch meal of pretreatment, modified 15 parts of medical stone powder, 15 parts of zeolite powder, 10 parts of tourmaline powder,
10 parts of zinc oxide mixing, are stirred 50 minutes with 800 revs/min, obtain mixed powder, then binder solution is added in mixed powder,
It is stirred 2 hours with 800 revs/min, obtains mixed slurry, then mixed slurry is processed by the spherical shape that diameter is 4mm by bowling machine
Particle；
(2) spheric granules is 3 hours dry at 45 DEG C, sintering furnace is placed into, is warming up to 350 DEG C with 10 DEG C/min, and protect
Temperature sintering 25 minutes, then 700 DEG C, and heat preservation sintering 25 minutes are warming up to 20 DEG C/min, then be warming up to 1050 with 20 DEG C/min
DEG C, and heat preservation sintering 2 hours, room temperature is cooled to the furnace to get MPH+ ceramic mineral ball.
Described adhesive is sodium alginate.
The pretreatment conch meal is prepared using following methods, and wherein part is parts by weight:
(1) shell is cleaned, cleans, drains surface moisture, crush the shell coarse powder for 0.5mm；
(2) it by 25 parts of aqueous sodium carbonate mixing of 8 parts of shell coarse powder and 5wt%, is stirred 50 minutes with 200 revs/min, it is quiet
It sets 6 hours, then is stirred 30 minutes with 800 revs/min, using 100 mesh filter-cloth filterings, filter cake is with water washing 2 times of 25 parts, 110
DEG C dry 3 hours, obtain the shell coarse powder of removal cuticula；
(3) the shell coarse powder for the removal cuticula that step (2) obtains is packed into ball grinder and carries out ball milling, using zirconium oxide
8 parts of ethyl alcohol are added as ball-milling medium in ball, material ball ratio 1:3, and rotational speed of ball-mill is 450 revs/min, ball milling 22 hours, obtains ball milling
Slurries；
(4) by ball milling slurries in 90 DEG C of dryings, 800 meshes are crossed in grinding, obtain pretreatment conch meal.
The shell is mussel shell.
The modified medical stone powder is prepared using following methods, and wherein part is parts by weight:
(1) it by 8 parts and 100 parts of 4wt% hydrochloric acid mixing of medical stone powder, is stirred 30 minutes at 45 DEG C with 80 revs/min, with 5000
Rev/min centrifugation 30 minutes, obtained precipitating, which is washed with water to can't detect with the silver nitrate solution of 0.1mol/L, Cl in washing lotion-
In the presence of what is obtained is precipitated as pretreatment medical stone powder；
(2) medical stone powder will be pre-processed and is warming up to 250 DEG C with 10 DEG C/min, and keep the temperature 3.5 hours at 250 DEG C, then certainly with furnace
It is so cooled to room temperature, grinds, cross 800 meshes to get heat modification medical stone；
(3) 6 parts and 50 parts water of heat modification medical stone are mixed, 0.1 part of calgon is added, at 70 DEG C with 80 revs/min
Stirring 15 minutes, is added 0.01 part of metal oxide, is stirred 8 minutes at 70 DEG C with 80 revs/min, then stirred at 25 DEG C with 80 revs/min
Mix 25 minutes, stand 50 minutes, with 5000 revs/min be centrifuged 30 minutes, lower sediment with 50 parts water washing 2 times, then 90 DEG C do
Dry 6 hours, grinding crossed 800 meshes, obtains the modified medical stone powder.
The metal oxide is cerium oxide.
Embodiment 5
Substantially the same manner as Example 4, difference is only that:
The modified medical stone powder is prepared using following methods, and wherein part is parts by weight:
(1) it by 8 parts and 100 parts of 4wt% hydrochloric acid mixing of medical stone powder, is stirred 30 minutes at 45 DEG C with 80 revs/min, with 5000
Rev/min centrifugation 30 minutes, obtained precipitating, which is washed with water to can't detect with the silver nitrate solution of 0.1mol/L, Cl in washing lotion-
In the presence of what is obtained is precipitated as pretreatment medical stone powder；
(2) medical stone powder will be pre-processed and is warming up to 250 DEG C with 10 DEG C/min, and keep the temperature 3.5 hours at 250 DEG C, then certainly with furnace
It is so cooled to room temperature, grinds, cross 800 meshes to get heat modification medical stone；
(3) 6 parts and 50 parts water of heat modification medical stone are mixed, 0.1 part of calgon is added, at 70 DEG C with 80 revs/min
Stirring 15 minutes, is added 0.01 part of metal oxide, is stirred 8 minutes at 70 DEG C with 80 revs/min, then stirred at 25 DEG C with 80 revs/min
Mix 25 minutes, stand 50 minutes, with 5000 revs/min be centrifuged 30 minutes, lower sediment with 50 parts water washing 2 times, then 90 DEG C do
Dry 6 hours, grinding crossed 800 meshes, obtains the modified medical stone powder.
The metal oxide is zirconium oxide.
Embodiment 6
Substantially the same manner as Example 4, difference is only that:
The modified medical stone powder is prepared using following methods, and wherein part is parts by weight:
(1) it by 8 parts and 100 parts of 4wt% hydrochloric acid mixing of medical stone powder, is stirred 30 minutes at 45 DEG C with 80 revs/min, with 5000
Rev/min centrifugation 30 minutes, obtained precipitating, which is washed with water to can't detect with the silver nitrate solution of 0.1mol/L, Cl in washing lotion-
In the presence of what is obtained is precipitated as pretreatment medical stone powder；
(2) medical stone powder will be pre-processed and is warming up to 250 DEG C with 10 DEG C/min, and keep the temperature 3.5 hours at 250 DEG C, then certainly with furnace
It is so cooled to room temperature, grinds, cross 800 meshes to get heat modification medical stone；
(3) 6 parts and 50 parts water of heat modification medical stone are mixed, 0.1 part of calgon is added, at 70 DEG C with 80 revs/min
Stirring 15 minutes, is added 0.01 part of metal oxide, is stirred 8 minutes at 70 DEG C with 80 revs/min, then stirred at 25 DEG C with 80 revs/min
Mix 25 minutes, stand 50 minutes, with 5000 revs/min be centrifuged 30 minutes, lower sediment with 50 parts water washing 2 times, then 90 DEG C do
Dry 6 hours, grinding crossed 800 meshes, obtains the modified medical stone powder.
The metal oxide is titanium oxide.
Embodiment 7
A kind of preparation method of the water of novel U.S. face and makeup removing function, comprising the following steps:
(1) drinking pure water is taken；
(2) mineral ball activates: drinking pure water and mineral ball 100:10 in mass ratio being mixed, impregnated 3 hours, is used
200 mesh filter-cloth filterings obtain the water of the novel U.S. face and makeup removing function.
The mineral ball is MPH+ ceramic mineral ball.
The MPH+ ceramic mineral ball is prepared using following methods, and wherein part is parts by weight:
(1) 0.5 part of adhesive is added in 15 parts of water, is stirred 15 minutes at 80 DEG C with 200 revs/min, obtains adhesive
Solution, by 30 parts of albite, 20 parts of conch meal of pretreatment, modified 15 parts of medical stone powder, 15 parts of zeolite powder, 10 parts of tourmaline powder,
10 parts of zinc oxide mixing, are stirred 50 minutes with 800 revs/min, obtain mixed powder, then binder solution is added in mixed powder,
It is stirred 2 hours with 800 revs/min, obtains mixed slurry, then mixed slurry is processed by the spherical shape that diameter is 4mm by bowling machine
Particle；
(2) spheric granules is 3 hours dry at 45 DEG C, sintering furnace is placed into, is warming up to 350 DEG C with 10 DEG C/min, and protect
Temperature sintering 25 minutes, then 700 DEG C, and heat preservation sintering 25 minutes are warming up to 20 DEG C/min, then be warming up to 1050 with 20 DEG C/min
DEG C, and heat preservation sintering 2 hours, room temperature is cooled to the furnace to get MPH+ ceramic mineral ball.
Described adhesive is sodium alginate.
The pretreatment conch meal is prepared using following methods, and wherein part is parts by weight:
(1) shell is cleaned, cleans, drains surface moisture, crush the shell coarse powder for 0.5mm；
(2) it by 25 parts of aqueous sodium carbonate mixing of 8 parts of shell coarse powder and 5wt%, is stirred 50 minutes with 200 revs/min, it is quiet
It sets 6 hours, then is stirred 30 minutes with 800 revs/min, using 100 mesh filter-cloth filterings, filter cake is with water washing 2 times of 25 parts, 110
DEG C dry 3 hours, obtain the shell coarse powder of removal cuticula；
(3) the shell coarse powder for the removal cuticula that step (2) obtains and 0.03 part of lanthanium titanate are packed into ball grinder and carry out ball
Mill, using zirconia ball, 8 parts of ethyl alcohol are added as ball-milling medium in material ball ratio 1:3, and rotational speed of ball-mill is 450 revs/min, ball milling 22
Hour, obtain ball milling slurries；
(4) by ball milling slurries in 90 DEG C of dryings, 800 meshes are crossed in grinding, obtain pretreatment conch meal.
The shell is mussel shell.
The modified medical stone powder is prepared using following methods, and wherein part is parts by weight:
(1) it by 8 parts and 100 parts of 4wt% hydrochloric acid mixing of medical stone powder, is stirred 30 minutes at 45 DEG C with 80 revs/min, with 5000
Rev/min centrifugation 30 minutes, obtained precipitating, which is washed with water to can't detect with the silver nitrate solution of 0.1mol/L, Cl in washing lotion-
In the presence of what is obtained is precipitated as pretreatment medical stone powder；
(2) medical stone powder will be pre-processed and is warming up to 250 DEG C with 10 DEG C/min, and keep the temperature 3.5 hours at 250 DEG C, then certainly with furnace
It is so cooled to room temperature, grinds, cross 800 meshes to get heat modification medical stone；
(3) 6 parts and 50 parts water of heat modification medical stone are mixed, 0.1 part of calgon is added, at 70 DEG C with 80 revs/min
Stirring 15 minutes, is added 0.01 part of metal oxide, is stirred 8 minutes at 70 DEG C with 80 revs/min, then stirred at 25 DEG C with 80 revs/min
Mix 25 minutes, stand 50 minutes, with 5000 revs/min be centrifuged 30 minutes, lower sediment with 50 parts water washing 2 times, then 90 DEG C do
Dry 6 hours, grinding crossed 800 meshes, obtains the modified medical stone powder.
The metal oxide is cerium oxide.
Embodiment 8
A kind of preparation method of the water of novel U.S. face and makeup removing function, comprising the following steps:
(1) drinking pure water is taken；
(2) mineral ball activates: drinking pure water and mineral ball 100:10 in mass ratio being mixed, impregnated 3 hours, is used
200 mesh filter-cloth filterings obtain the water of the novel U.S. face and makeup removing function.
The mineral ball is MPH+ ceramic mineral ball.
The MPH+ ceramic mineral ball is prepared using following methods, and wherein part is parts by weight:
(1) 0.5 part of adhesive is added in 15 parts of water, is stirred 15 minutes at 80 DEG C with 200 revs/min, obtains adhesive
Solution, by 30 parts of albite, 20 parts of conch meal of pretreatment, modified 15 parts of medical stone powder, 15 parts of zeolite powder, 10 parts of tourmaline powder,
10 parts of zinc oxide mixing, are stirred 50 minutes with 800 revs/min, obtain mixed powder, then binder solution is added in mixed powder,
It is stirred 2 hours with 800 revs/min, obtains mixed slurry, then mixed slurry is processed by the spherical shape that diameter is 4mm by bowling machine
Particle；
(2) spheric granules is 3 hours dry at 45 DEG C, sintering furnace is placed into, is warming up to 350 DEG C with 10 DEG C/min, and protect
Temperature sintering 25 minutes, then 700 DEG C, and heat preservation sintering 25 minutes are warming up to 20 DEG C/min, then be warming up to 1050 with 20 DEG C/min
DEG C, and heat preservation sintering 2 hours, room temperature is cooled to the furnace to get MPH+ ceramic mineral ball.
Described adhesive is sodium alginate.
The pretreatment conch meal is prepared using following methods, and wherein part is parts by weight:
(1) shell is cleaned, cleans, drains surface moisture, crush the shell coarse powder for 0.5mm；
(2) it by 25 parts of aqueous sodium carbonate mixing of 8 parts of shell coarse powder and 5wt%, is stirred 50 minutes with 200 revs/min, it is quiet
It sets 6 hours, then is stirred 30 minutes with 800 revs/min, using 100 mesh filter-cloth filterings, filter cake is with water washing 2 times of 25 parts, 110
DEG C dry 3 hours, obtain the shell coarse powder of removal cuticula；
(3) the shell coarse powder for the removal cuticula that step (2) obtains and 0.03 part of lanthanium titanate are packed into ball grinder and carry out ball
Mill, using zirconia ball, 8 parts of ethyl alcohol are added as ball-milling medium in material ball ratio 1:3, and rotational speed of ball-mill is 450 revs/min, ball milling 20
After hour, 3 parts of 10wt% modifier aqueous solutions are added, continues ball milling 2 hours, obtains ball milling slurries；
(4) ball milling slurries are warming up to 70 DEG C, are stirred 2 hours at 70 DEG C with 200 revs/min, obtained modified slurries, will be modified
Slurries cross 800 meshes in 90 DEG C of dryings, grinding, obtain pretreatment conch meal.
The shell is mussel shell.
The modifying agent is N- sodium lauroyl sarcosine.
The modified medical stone powder is prepared using following methods, and wherein part is parts by weight:
(1) it by 8 parts and 100 parts of 4wt% hydrochloric acid mixing of medical stone powder, is stirred 30 minutes at 45 DEG C with 80 revs/min, with 5000
Rev/min centrifugation 30 minutes, obtained precipitating, which is washed with water to can't detect with the silver nitrate solution of 0.1mol/L, Cl in washing lotion-
In the presence of what is obtained is precipitated as pretreatment medical stone powder；
(2) medical stone powder will be pre-processed and is warming up to 250 DEG C with 10 DEG C/min, and keep the temperature 3.5 hours at 250 DEG C, then certainly with furnace
It is so cooled to room temperature, grinds, cross 800 meshes to get heat modification medical stone；
(3) 6 parts and 50 parts water of heat modification medical stone are mixed, 0.1 part of calgon is added, at 70 DEG C with 80 revs/min
Stirring 15 minutes, is added 0.01 part of metal oxide, is stirred 8 minutes at 70 DEG C with 80 revs/min, then stirred at 25 DEG C with 80 revs/min
Mix 25 minutes, stand 50 minutes, with 5000 revs/min be centrifuged 30 minutes, lower sediment with 50 parts water washing 2 times, then 90 DEG C do
Dry 6 hours, grinding crossed 800 meshes, obtains the modified medical stone powder.
The metal oxide is cerium oxide.
Embodiment 9
A kind of preparation method of the water of novel U.S. face and makeup removing function, comprising the following steps:
(1) drinking pure water is taken；
(2) mineral ball activates: drinking pure water and mineral ball 100:10 in mass ratio being mixed, impregnated 3 hours, is used
200 mesh filter-cloth filterings obtain the water of the novel U.S. face and makeup removing function.
The mineral ball is MPH+ ceramic mineral ball.
The MPH+ ceramic mineral ball is prepared using following methods, and wherein part is parts by weight:
(1) 0.5 part of adhesive is added in 15 parts of water, is stirred 15 minutes at 80 DEG C with 200 revs/min, obtains adhesive
Solution, by 30 parts of albite, 20 parts of conch meal of pretreatment, modified 15 parts of medical stone powder, 15 parts of zeolite powder, 10 parts of tourmaline powder,
10 parts of zinc oxide mixing, are stirred 50 minutes with 800 revs/min, obtain mixed powder, then binder solution is added in mixed powder,
It is stirred 2 hours with 800 revs/min, obtains mixed slurry, then mixed slurry is processed by the spherical shape that diameter is 4mm by bowling machine
Particle；
(2) spheric granules is 3 hours dry at 45 DEG C, sintering furnace is placed into, is warming up to 350 DEG C with 10 DEG C/min, and protect
Temperature sintering 25 minutes, then 700 DEG C, and heat preservation sintering 25 minutes are warming up to 20 DEG C/min, then be warming up to 1050 with 20 DEG C/min
DEG C, and heat preservation sintering 2 hours, room temperature is cooled to the furnace to get MPH+ ceramic mineral ball.
Described adhesive is sodium alginate.
The pretreatment conch meal is prepared using following methods, and wherein part is parts by weight:
(1) shell is cleaned, cleans, drains surface moisture, crush the shell coarse powder for 0.5mm；
(2) it by 25 parts of aqueous sodium carbonate mixing of 8 parts of shell coarse powder and 5wt%, is stirred 50 minutes with 200 revs/min, it is quiet
It sets 6 hours, then is stirred 30 minutes with 800 revs/min, using 100 mesh filter-cloth filterings, filter cake is with water washing 2 times of 25 parts, 110
DEG C dry 3 hours, obtain the shell coarse powder of removal cuticula；
(3) the shell coarse powder for the removal cuticula that step (2) obtains and 0.03 part of lanthanium titanate are packed into ball grinder and carry out ball
Mill, using zirconia ball, 8 parts of ethyl alcohol are added as ball-milling medium in material ball ratio 1:3, and rotational speed of ball-mill is 450 revs/min, ball milling 20
After hour, 3 parts of 10wt% modifier aqueous solutions are added, continues ball milling 2 hours, obtains ball milling slurries；
(4) ball milling slurries are warming up to 70 DEG C, are stirred 2 hours at 70 DEG C with 200 revs/min, obtained modified slurries, will be modified
Slurries cross 800 meshes in 90 DEG C of dryings, grinding, obtain pretreatment conch meal.
The shell is mussel shell.
The modifying agent is pungent capric acid acyl oat amino acid nano.
The modified medical stone powder is prepared using following methods, and wherein part is parts by weight:
(1) it by 8 parts and 100 parts of 4wt% hydrochloric acid mixing of medical stone powder, is stirred 30 minutes at 45 DEG C with 80 revs/min, with 5000
Rev/min centrifugation 30 minutes, obtained precipitating, which is washed with water to can't detect with the silver nitrate solution of 0.1mol/L, Cl in washing lotion-
In the presence of what is obtained is precipitated as pretreatment medical stone powder；
(2) medical stone powder will be pre-processed and is warming up to 250 DEG C with 10 DEG C/min, and keep the temperature 3.5 hours at 250 DEG C, then certainly with furnace
It is so cooled to room temperature, grinds, cross 800 meshes to get heat modification medical stone；
(3) 6 parts and 50 parts water of heat modification medical stone are mixed, 0.1 part of calgon is added, at 70 DEG C with 80 revs/min
Stirring 15 minutes, is added 0.01 part of metal oxide, is stirred 8 minutes at 70 DEG C with 80 revs/min, then stirred at 25 DEG C with 80 revs/min
Mix 25 minutes, stand 50 minutes, with 5000 revs/min be centrifuged 30 minutes, lower sediment with 50 parts water washing 2 times, then 90 DEG C do
Dry 6 hours, grinding crossed 800 meshes, obtains the modified medical stone powder.
The metal oxide is cerium oxide.
Embodiment 10
A kind of preparation method of the water of novel U.S. face and makeup removing function, comprising the following steps:
(1) drinking pure water is taken；
(2) mineral ball activates: drinking pure water and mineral ball 100:10 in mass ratio being mixed, impregnated 3 hours, is used
200 mesh filter-cloth filterings obtain the water of the novel U.S. face and makeup removing function.
The mineral ball is MPH+ ceramic mineral ball.
The MPH+ ceramic mineral ball is prepared using following methods, and wherein part is parts by weight:
(1) 0.5 part of adhesive is added in 15 parts of water, is stirred 15 minutes at 80 DEG C with 200 revs/min, obtains adhesive
Solution, by 30 parts of albite, 20 parts of conch meal of pretreatment, modified 15 parts of medical stone powder, 15 parts of zeolite powder, 10 parts of tourmaline powder,
10 parts of zinc oxide mixing, are stirred 50 minutes with 800 revs/min, obtain mixed powder, then binder solution is added in mixed powder,
It is stirred 2 hours with 800 revs/min, obtains mixed slurry, then mixed slurry is processed by the spherical shape that diameter is 4mm by bowling machine
Particle；
(2) spheric granules is 3 hours dry at 45 DEG C, sintering furnace is placed into, is warming up to 350 DEG C with 10 DEG C/min, and protect
Temperature sintering 25 minutes, then 700 DEG C, and heat preservation sintering 25 minutes are warming up to 20 DEG C/min, then be warming up to 1050 with 20 DEG C/min
DEG C, and heat preservation sintering 2 hours, room temperature is cooled to the furnace to get MPH+ ceramic mineral ball.
Described adhesive is sodium alginate.
The pretreatment conch meal is prepared using following methods, and wherein part is parts by weight:
(1) shell is cleaned, cleans, drains surface moisture, crush the shell coarse powder for 0.5mm；
(2) it by 25 parts of aqueous sodium carbonate mixing of 8 parts of shell coarse powder and 5wt%, is stirred 50 minutes with 200 revs/min, it is quiet
It sets 6 hours, then is stirred 30 minutes with 800 revs/min, using 100 mesh filter-cloth filterings, filter cake is with water washing 2 times of 25 parts, 110
DEG C dry 3 hours, obtain the shell coarse powder of removal cuticula；
(3) the shell coarse powder for the removal cuticula that step (2) obtains and 0.03 part of lanthanium titanate are packed into ball grinder and carry out ball
Mill, using zirconia ball, 8 parts of ethyl alcohol are added as ball-milling medium in material ball ratio 1:3, and rotational speed of ball-mill is 450 revs/min, ball milling 20
After hour, 3 parts of 10wt% modifier aqueous solutions are added, continues ball milling 2 hours, obtains ball milling slurries；
(4) ball milling slurries are warming up to 70 DEG C, are stirred 2 hours at 70 DEG C with 200 revs/min, obtained modified slurries, will be modified
Slurries cross 800 meshes in 90 DEG C of dryings, grinding, obtain pretreatment conch meal.
The shell is mussel shell.
The modifying agent is the mixture of N- sodium lauroyl sarcosine and pungent capric acid acyl oat amino acid nano, the N- laurel
Acylsarcosine sodium and the mass ratio of pungent capric acid acyl oat amino acid nano are 1:3.
Specifically, the capric acid acyl oat amino acid nano of the sodium lauroyl sarcosine aqueous solution of 10wt% and 10wt% is water-soluble
Liquid is 1:3 mixing in mass ratio, is stirred 10 minutes with 100 revs/min, obtains 10wt% modifier aqueous solution.
The modified medical stone powder is prepared using following methods, and wherein part is parts by weight:
(1) it by 8 parts and 100 parts of 4wt% hydrochloric acid mixing of medical stone powder, is stirred 30 minutes at 45 DEG C with 80 revs/min, with 5000
Rev/min centrifugation 30 minutes, obtained precipitating, which is washed with water to can't detect with the silver nitrate solution of 0.1mol/L, Cl in washing lotion-
In the presence of what is obtained is precipitated as pretreatment medical stone powder；
(2) medical stone powder will be pre-processed and is warming up to 250 DEG C with 10 DEG C/min, and keep the temperature 3.5 hours at 250 DEG C, then certainly with furnace
It is so cooled to room temperature, grinds, cross 800 meshes to get heat modification medical stone；
(3) 6 parts and 50 parts water of heat modification medical stone are mixed, 0.1 part of calgon is added, at 70 DEG C with 80 revs/min
Stirring 15 minutes, is added 0.01 part of metal oxide, is stirred 8 minutes at 70 DEG C with 80 revs/min, then stirred at 25 DEG C with 80 revs/min
Mix 25 minutes, stand 50 minutes, with 5000 revs/min be centrifuged 30 minutes, lower sediment with 50 parts water washing 2 times, then 90 DEG C do
Dry 6 hours, grinding crossed 800 meshes, obtains the modified medical stone powder.
The metal oxide is cerium oxide.
Embodiment 11
A kind of preparation method of the water of novel U.S. face and makeup removing function, comprising the following steps:
(1) drinking pure water is taken；
(2) mineral ball activates: drinking pure water and mineral ball 100:10 in mass ratio being mixed, impregnated 3 hours, is used
200 mesh filter-cloth filterings obtain the water of the novel U.S. face and makeup removing function.
The mineral ball is Terahertz ceramic mineral ball and the MPH+ ceramic mineral ball mixture of 1:1 in mass ratio.
The MPH+ ceramic mineral ball is prepared using following methods, and wherein part is parts by weight:
(1) 0.5 part of adhesive is added in 15 parts of water, is stirred 15 minutes at 80 DEG C with 200 revs/min, obtains adhesive
Solution, by 30 parts of albite, 20 parts of conch meal of pretreatment, modified 15 parts of medical stone powder, 15 parts of zeolite powder, 10 parts of tourmaline powder,
10 parts of zinc oxide mixing, are stirred 50 minutes with 800 revs/min, obtain mixed powder, then binder solution is added in mixed powder,
It is stirred 2 hours with 800 revs/min, obtains mixed slurry, then mixed slurry is processed by the spherical shape that diameter is 4mm by bowling machine
Particle；
(2) spheric granules is 3 hours dry at 45 DEG C, sintering furnace is placed into, is warming up to 350 DEG C with 10 DEG C/min, and protect
Temperature sintering 25 minutes, then 700 DEG C, and heat preservation sintering 25 minutes are warming up to 20 DEG C/min, then be warming up to 1050 with 20 DEG C/min
DEG C, and heat preservation sintering 2 hours, room temperature is cooled to the furnace to get MPH+ ceramic mineral ball.
Described adhesive is sodium alginate.
The pretreatment conch meal is prepared using following methods, and wherein part is parts by weight:
(1) shell is cleaned, cleans, drains surface moisture, crush the shell coarse powder for 0.5mm；
(2) it by 25 parts of aqueous sodium carbonate mixing of 8 parts of shell coarse powder and 5wt%, is stirred 50 minutes with 200 revs/min, it is quiet
It sets 6 hours, then is stirred 30 minutes with 800 revs/min, using 100 mesh filter-cloth filterings, filter cake is with water washing 2 times of 25 parts, 110
DEG C dry 3 hours, obtain the shell coarse powder of removal cuticula；
(3) the shell coarse powder for the removal cuticula that step (2) obtains and 0.03 part of lanthanium titanate are packed into ball grinder and carry out ball
Mill, using zirconia ball, 8 parts of ethyl alcohol are added as ball-milling medium in material ball ratio 1:3, and rotational speed of ball-mill is 450 revs/min, ball milling 20
After hour, 3 parts of 10wt% modifier aqueous solutions are added, continues ball milling 2 hours, obtains ball milling slurries；
(4) ball milling slurries are warming up to 70 DEG C, are stirred 2 hours at 70 DEG C with 200 revs/min, obtained modified slurries, will be modified
Slurries cross 800 meshes in 90 DEG C of dryings, grinding, obtain pretreatment conch meal.
The shell is mussel shell.
The modifying agent is the mixture of N- sodium lauroyl sarcosine and pungent capric acid acyl oat amino acid nano, the N- laurel
Acylsarcosine sodium and the mass ratio of pungent capric acid acyl oat amino acid nano are 1:3.
The modified medical stone powder is prepared using following methods, and wherein part is parts by weight:
(1) it by 8 parts and 100 parts of 4wt% hydrochloric acid mixing of medical stone powder, is stirred 30 minutes at 45 DEG C with 80 revs/min, with 5000
Rev/min centrifugation 30 minutes, obtained precipitating, which is washed with water to can't detect with the silver nitrate solution of 0.1mol/L, Cl in washing lotion-
In the presence of what is obtained is precipitated as pretreatment medical stone powder；
(2) medical stone powder will be pre-processed and is warming up to 250 DEG C with 10 DEG C/min, and keep the temperature 3.5 hours at 250 DEG C, then certainly with furnace
It is so cooled to room temperature, grinds, cross 800 meshes to get heat modification medical stone；
(3) 6 parts and 50 parts water of heat modification medical stone are mixed, 0.1 part of calgon is added, at 70 DEG C with 80 revs/min
Stirring 15 minutes, is added 0.01 part of metal oxide, is stirred 8 minutes at 70 DEG C with 80 revs/min, then stirred at 25 DEG C with 80 revs/min
Mix 25 minutes, stand 50 minutes, with 5000 revs/min be centrifuged 30 minutes, lower sediment with 50 parts water washing 2 times, then 90 DEG C do
Dry 6 hours, grinding crossed 800 meshes, obtains the modified medical stone powder.
The metal oxide is cerium oxide.
Test case 1
Using the IR-2 type two waveband emissivity measurement instrument measurement 25 of upper Haicheng glistening light of waves power technology Science and Technology Ltd. production
DEG C when the far infrared transmissivity of MPH+ ceramic mineral ball that is prepared of embodiment 3-10, test scope is 8-14 μm, specific to tie
Fruit is shown in Table 1.
1 far infrared transmissivity test result table of table
| Far infrared transmissivity | |
| Embodiment 3 | 0.76 |
| Embodiment 4 | 0.81 |
| Embodiment 5 | 0.78 |
| Embodiment 6 | 0.77 |
| Embodiment 7 | 0.84 |
| Embodiment 8 | 0.86 |
| Embodiment 9 | 0.87 |
| Embodiment 10 | 0.93 |
Test case 2
The pH of the water of the embodiment 2-11 novel U.S. face and makeup removing function being prepared is tested, specific test result
It is shown in Table 2.
Take the water 0.6mL of novel U.S. face and makeup removing function in nuclear magnetic tube, by Institute of Analysis of Fudan University with17O
The width of the nuclear magnetic resonance measuring line of the water of novel U.S. face and makeup removing function is prepared in nuclear magnetic resonance method measurement embodiment 1-10
Half-breadth is high, and concrete outcome is shown in Table 2.
The pH and nuclear magnetic resonance test result table of the water of the novel U.S. face of table 2 and makeup removing function
The water of the novel U.S. face of the present invention and makeup removing function contains the minerals beneficial there are many human body, and water can be hydrolyzed
Reaction, so that the pH of water becomes alkalescent by faintly acid.Meanwhile point of the water of novel U.S. face prepared by the present invention and makeup removing function
Son group is substantially reduced, thus has excellent permeability and dissolubility, has good makeup removing effect.
Test case 3
The makeup removing effect of the water of the obtained novel U.S. face and makeup removing function of embodiment 2-11 is tested.
The specific test method is as follows: 200 women that tested crowd is 20-40 years old, skin health, no allergies.It will be by
Examination person is divided into 10 groups, every group of 20 people, and subject's face uses after identical cosmetic makeup respectively using the new of embodiment 2-11
The water of type U.S. face and makeup removing function wipes face makeup removing, is used continuously 7 days, evaluates makeup removing effect, and evaluation criterion is as follows:
Significant: makeup removing is clean, wipes noresidue after face.
It is general: to have after makeup removing and slightly remain.
Nothing: there is no makeup removing effect.
Concrete outcome is shown in Table 3.
The water makeup removing effect test result table of table 3 novel U.S. face and makeup removing function
Claims (10)
1. a kind of preparation method of the water of novel U.S. face and makeup removing function, which comprises the following steps:
(1) drinking pure water is taken；
(2) mineral ball activates: by drinking pure water and mineral ball 100:(5-30 in mass ratio) mixing, it impregnates 2-4 hours, mistake
Filter obtains the water of the novel U.S. face and makeup removing function.
2. the preparation method of the water of novel U.S. face as described in claim 1 and makeup removing function, which is characterized in that the mineral ball
For Terahertz ceramic mineral ball and/or MPH+ ceramic mineral ball.
3. the preparation method of the water of novel U.S. face as claimed in claim 2 and makeup removing function, which is characterized in that the MPH+ pottery
Porcelain mineral ball is prepared using following methods, and wherein part is parts by weight:
(1) 0.2-2 parts of adhesive are added in 10-20 parts of water, 75-85 DEG C with 100-300 revs/min stirring 10-20 minutes,
Binder solution is obtained, by 20-40 parts of albite, conch meal 15-25 parts of pretreatment, modified medical stone powder 10-20 parts, zeolite powder
10-20 parts, 8-12 parts of tourmaline powder, 8-12 parts of zinc oxide mixing, with 500-1000 revs/min stirring 40-60 minutes, mixed
Powder, then binder solution is added in mixed powder, with 500-1000 revs/min stirring 1-3 hours, obtain mixed slurry, then lead to
It crosses bowling machine and mixed slurry is processed into the spheric granules that diameter is 3-6mm；
(2) spheric granules is 2-4 hours dry at 40-50 DEG C, sintering furnace is placed into, 300-400 is warming up to 8-12 DEG C/min
DEG C, and heat preservation sintering 20-30 minutes, then 650-750 DEG C, and heat preservation sintering 20-30 minutes are warming up to 15-25 DEG C/min, then
1000-1100 DEG C, and heat preservation sintering 1-3 hours are warming up to 15-25 DEG C/min, cool to room temperature with the furnace to get MPH+ ceramics
Mineral ball；
Described adhesive is one of sodium alginate, polyvinyl alcohol, sodium carboxymethylcellulose or a variety of mixtures.
4. the preparation method of the water of novel U.S. face as claimed in claim 3 and makeup removing function, which is characterized in that the pretreatment
Conch meal is prepared using following methods, and wherein part is parts by weight:
(1) shell is cleaned, cleans, drains surface moisture, crush the shell coarse powder for 0.1-1mm；
(2) it by 20-30 parts of aqueous sodium carbonate mixing of 5-10 parts of shell coarse powder and 3-8wt%, is stirred with 100-300 revs/min
40-60 minutes, stand 5-10 hours, then with 500-1000 revs/min stirring 20-40 minutes, using 100-300 mesh filter-cloth filtering,
Filter cake is 2-5 hours dry at 100-120 DEG C with water washing 1-3 times of 20-30 parts, obtains the shell coarse powder of removal cuticula；
(3) the shell coarse powder for the removal cuticula that step (2) obtains is packed into ball grinder and carries out ball milling, 5-10 parts of ethyl alcohol are added and make
Ball milling slurries are obtained after rotational speed of ball-mill is 400-600 revs/min, ball milling 16-28 hours for ball-milling medium；
(4) ball milling slurries are warming up to 60-80 DEG C, 60-80 DEG C with 100-300 revs/min stirring 1-3 hours, obtain modified slurry
Liquid, by modified slurries in 80-100 DEG C of drying, grinding obtains pretreatment conch meal.
5. the preparation method of the water of novel U.S. face as claimed in claim 3 and makeup removing function, which is characterized in that the pretreatment
Conch meal is prepared using following methods, and wherein part is parts by weight:
(1) shell is cleaned, cleans, drains surface moisture, crush the shell coarse powder for 0.1-1mm；
(2) it by 20-30 parts of aqueous sodium carbonate mixing of 5-10 parts of shell coarse powder and 3-8wt%, is stirred with 100-300 revs/min
40-60 minutes, stand 5-10 hours, then with 500-1000 revs/min stirring 20-40 minutes, using 100-300 mesh filter-cloth filtering,
Filter cake is 2-5 hours dry at 100-120 DEG C with water washing 1-3 times of 20-30 parts, obtains the shell coarse powder of removal cuticula；
(3) the shell coarse powder for the removal cuticula that step (2) obtains and 0.01-0.05 parts of lanthanium titanates are packed into ball grinder and carry out ball
Mill is added 5-10 parts of ethyl alcohol as ball-milling medium, after rotational speed of ball-mill is 400-600 revs/min, ball milling 15-25 hours, 1-5 is added
Part 8-12wt% modifier aqueous solution, continues ball milling 1-3 hours, obtains ball milling slurries；
(4) ball milling slurries are warming up to 60-80 DEG C, 60-80 DEG C with 100-300 revs/min stirring 1-3 hours, obtain modified slurry
Liquid, will modified slurries with 4000-6000 revs/min centrifugation 20-30 minutes, what is obtained is deposited in 80-100 DEG C of drying, grinds, obtains
Pre-process conch meal.
6. the preparation method of the water of novel U.S. face as claimed in claim 5 and makeup removing function, which is characterized in that the modifying agent
For N- sodium lauroyl sarcosine and/or pungent capric acid acyl oat amino acid nano.
7. the preparation method of the water of novel U.S. face and makeup removing function as described in claim 4 or 5, which is characterized in that the shellfish
Shell is one of mussel shell, scallop shell, oyster shell, cycle of sixty years shell or a variety of mixtures.
8. the preparation method of the water of novel U.S. face as claimed in claim 3 and makeup removing function, which is characterized in that the modified wheat
Meal mountain flour is prepared using following methods, and wherein part is parts by weight:
(1) it by 5-10 parts and 80-120 parts of 3-5wt% hydrochloric acid mixing of medical stone powder, is stirred at 40-50 DEG C with 60-100 revs/min
20-40 minutes, with 4000-6000 revs/min centrifugation 20-30 minutes, obtained precipitating is washed with water to the nitric acid with 0.1mol/L
Silver-colored solution can't detect in washing lotion with the presence of Cl-, and what is obtained is precipitated as pretreatment medical stone powder；
(2) pretreatment medical stone powder with 8-12 DEG C/min is warming up to 200-300 DEG C, 200-300 DEG C heat preservation 3-4 hours, then
With furnace cooled to room temperature, grind to get heat modification medical stone；
(3) 4-8 parts and 40-60 parts water of heat modification medical stone are mixed, 0.05-0.2 parts of calgons is added, at 60-80 DEG C
With 60-100 revs/min stirring 10-20 minutes, 0.01 part of metal oxide is added, at 60-80 DEG C with 60-100 revs/min of stirring 5-
10 minutes, then 20-30 DEG C with 60-100 revs/min stirring 20-30 minutes, stand 40-60 minutes, with 5000 revs/min of centrifugation 20-
30 minutes, lower sediment with 40-60 parts water washing 1-3 times, then it is 4-8 hours dry at 80-100 DEG C, obtain the modified wheat meal
Mountain flour；
The metal oxide is one of cerium oxide, zirconium oxide, titanium oxide.
9. the preparation method of the water of novel U.S. face as claimed in claim 8 and makeup removing function, which is characterized in that the metal oxygen
Compound is cerium oxide.
10. a kind of water of novel U.S. face and makeup removing function, which is characterized in that using any one of claim 1-9 method preparation
It obtains.
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109589293A (en) * | 2019-01-28 | 2019-04-09 | 周华军 | A kind of labradorite facial mask and its preparation process |
| CN109771309A (en) * | 2019-03-20 | 2019-05-21 | 北京周整无为健康管理有限责任公司 | A kind of facial cleanser and application thereof based on labradorite |
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| CN109589293A (en) * | 2019-01-28 | 2019-04-09 | 周华军 | A kind of labradorite facial mask and its preparation process |
| CN109846732A (en) * | 2019-01-28 | 2019-06-07 | 北京周整无为健康管理有限责任公司 | A kind of labradorite after shave powder and its preparation process |
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| CN112679219A (en) * | 2021-03-15 | 2021-04-20 | 潍坊特钢集团有限公司 | Tundish composite coating for clean steel and preparation method thereof |
| CN112679219B (en) * | 2021-03-15 | 2021-06-04 | 潍坊特钢集团有限公司 | Tundish composite coating for clean steel and preparation method thereof |
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