Carbon dioxide concentration measurement scaling system device
Technical field
Wish to reach high-acruracy survey CO the invention belongs to atmospheric laser radar field, especially satellite-bone laser radar2It is dense
In the case where degree, need in laboratory environments to satellite-bone laser radar CO2Column measurement of concetration accuracy and sensitivity is calibrated.
Background technique
As the harm of global warming is increasingly significant, the research of greenhouse gases is become more and more important.CO2As main
Greenhouse gases, to Atmospheric CO2The monitoring of concentration has received widespread attention.Path of integration Difference Absorption (IPDA) laser radar
It is realized from space using the reflection or scattering of hard goal to Atmospheric CO2The detected with high accuracy of column concentration.Path of integration Difference Absorption
The measuring principle of radar is the absorption difference by gas in path of integration to different wavelengths of light, obtains gas using differential signal
Concentration information.Before laser radar carries out spaceborne operation, need under ground experiment room environmental to its CO2Column measurement of concetration essence
Degree and sensitivity are calibrated.When carrying out field testing, gas concentration lwevel is easy the interference by mankind's activity and air-flow,
Cause gas concentration lwevel to be unevenly distributed, lidar measurement precision can not accurately be verified, while satellite borne laser thunder
It is high for working environment purity requirements up to system, it cannot be exposed to the atmosphere.It is dedicated it is therefore desirable to be used in laboratory
Targeting device verifies lidar measurement CO2Concentration accuracy and sensitivity.
Summary of the invention
It is an object of the present invention to provide a kind of carbon dioxide concentration measurement scaling system device, which can be in laboratory item
Under part, the differential optical thickness of satellite borne laser path of integration is simulated, to lidar measurement CO2The precision of concentration is calibrated,
Unified Laboratory Calibration measurement standard can be provided by providing convenient and experimental result for scaling experiment.
Basic principle of the invention is to calculate corresponding satellite-bone laser radar CO based on IPDA technology2Differential optical thickness feelings
Pure CO needed under condition2Concentration and required integration path lengths.Utilize CO2Fill exhaust equipment and temperature control system high-precision
Control CO in absorption cell2Air pressure and temperature obtain CO identical with Space-borne situation2Differential optical thickness is absorbed, to simulate
Spaceborne CO2Column concentration.Laser issue light obtained after this system echo-signal identical with spaceborne situation and simulation
Spaceborne CO2Therefore column concentration is it is known that quantitatively change CO in pond2Gas concentration can calibrate the detection accuracy of laser radar and sensitive
Degree.
The technology of the present invention solution is as follows:
A kind of carbon dioxide concentration measurement scaling system device, it is characterized in that, including light splitting and energy detection unit, the
One CO2Gas absorption cell, optical path replicating structure and the 2nd CO2Gas absorption cell;
First CO2Gas absorption cell passes through optical path replicating structure and the 2nd CO2Gas absorption cell is connected, and is formed close
The absorption cell of envelope is whole;
The light splitting and energy detection unit is located at the first CO2In front of gas absorption cell optical window, by laser radar
Transmitting light point takes part energy to be detected and decayed, and remainder energy enters the first CO2Gas absorption cell;
The optical path replicating structure is for adjusting optical path length, and the first CO of adjustment2Gas absorption cell (2) and second
CO2The distance between gas absorption cell, to guarantee that the emergent light of light splitting and energy detection unit can enter the first CO2Gas absorbs
Pond, and the 2nd CO2The outgoing luminous energy of gas absorption cell receives system by laser radar and receives;
In the first CO2Gas absorption cell or the 2nd CO2Gas cell pond temperature control system is installed on the outer wall of gas absorption cell
System, gas cell Measurement System of Air Pressure, pumped vacuum systems and CO2Inflation system, the gas cell pond temperature control system is to suction
Gas temperature is controlled in receives pond entirety, gas cell Measurement System of Air Pressure, pumped vacuum systems and the CO2Inflation system group
At CO2Exhaust total system is filled, is vacuumized for absorption cell whole interior and CO2Pressure control.
It further include CO2Absorption spectrum measuring system and reflector are used for CO2CO in pond before measurement of concetration scaling experiment2
Absorption spectrum measurement;
CO2When absorption spectrum measurement experiment, CO2Absorption spectrum measuring system emits adjustable frequency light, by the 2nd CO2Gas
Body absorption cell, optical path replicating structure and the first CO2After gas absorption cell, after being reflected by reflector, successively through described first
CO2Gas absorption cell, optical path replicating structure and the 2nd CO2Backtracking is to CO after gas absorption cell2Absorption spectrum measuring system.
The light splitting and energy detection unit include the first reflecting mirror, the second reflecting mirror, spectroscope, the first attenuator,
First energy-probe, the second attenuator;
First reflecting mirror and the second reflecting mirror, for reflecting and translating laser radar transmitting light;Second reflecting mirror
Emit light level position for adjusting, allows to enter the first CO2Gas absorption cell optical window;
Incident light is incident on the second reflecting mirror after the reflection of the first reflecting mirror, after the reflection of the second reflecting mirror, is incident on point
Light microscopic is divided into reflected light and transmitted light through the spectroscope, and the reflected light enters the first energy after the first attenuator and visits
Device is surveyed, the transmitted light enters the first CO after the second attenuator2Gas absorption cell.
The optical path replicating structure includes reflecting mirror I and reflecting mirror II, including reflecting mirror I and reflecting mirror II, reflecting mirror I
With reflecting mirror II for optical path of turning back.
The CO2Absorption spectrum measuring system includes Frequency Adjustable light source, light source frequency scanning controller, collimating mirror, polarization point
Light prism, quarter-wave plate, the second energy-probe;
The Frequency Adjustable light source is located at collimating mirror focal point, the light source frequency scanning controller and Frequency Adjustable light source phase
Even, for adjusting Frequency Adjustable source emissioning light frequency, the light of transmitting is expanded by collimating mirror as directional light, through polarization splitting prism
Transmitted light after quarter-wave plate enter the 2nd CO2Gas absorption cell;
First CO2After the emergent light of gas absorption cell is reflected by reflector, successively through the first CO2Gas absorption cell and
Optical path replicating structure is incident on the 2nd CO2Gas absorption cell, through the 2nd CO2The emergent light of gas absorption cell is through quarter-wave
It is reflected after piece transmission by polarization splitting prism, into the second energy-probe.
Carry out CO2When measurement of concetration scaling experiment, CO2Absorption spectrum measuring system reflector does not work.Carry out CO2It absorbs
When spectral measurement, laser radar does not work.
Laser radar transmitting light is split using light splitting and energy detection unit, carries out energy using a portion light
Amount detection, and at the same time adjustable emergent light horizontal position, makes laser radar emit light into the first CO2Gas absorption cell.
First CO2Gas absorption cell, optical path replicating structure and the 2nd CO2Gas absorption cell forms biabsorption pool structure, can be with
The light for emitting laser radar laser is received system reception after absorption cell.Light unidirectionally passes in biabsorption pool structure
It broadcasts, avoids the error that light roundtrip in absorption cell interferes with each other generation.
Gas cell pond temperature control system, gas cell Measurement System of Air Pressure, pumped vacuum systems and CO2Inflation system can be accurate
The first CO of control and measurement2Gas absorption cell, optical path replicating structure and the 2nd CO2In the absorption cell entirety of gas absorption cell composition
Temperature and the CO that is filled with2Air pressure, to accurately simulate the titanium dioxide of entire atmosphere height layer under Space-borne equivalent condition
Carbon absorption optical thickness.By changing air pressure and temperature parameter in absorption cell, reach the spaceborne CO of equivalent simulation2Optical thickness changes
The requirement of change measures CO to laser radar system2Concentration precision is calibrated.
CO is measured in calibration laser radar system2Before concentration precision, CO is utilized2Absorption spectrum measuring system and reflector
To the CO in pond2Absorption spectrum measures, and calculates relevant Absorption Line parameter to optical thickness for the later period and is corrected.
Laser radar carries out CO using 1572nm light2When concentration is calibrated, the first CO2Gas absorption cell and the 2nd CO2
Gas absorption cell is 7.5m, and bore is greater than 250mm.First CO2Gas absorption cell, optical path replicating structure and the 2nd CO2Gas is inhaled
The absorption cell entirety vacuum-pumping of receives pond composition, vacuum degree are better than 1x10-3Pa。
The gas cell Measurement System of Air Pressure pressure measurement accuracy is better than 1mbar, CO2Inflation system pressure controling precision
Higher than 2mbar.
The gas cell pond temperature control system temperature controlling range is 20-40 DEG C, and accuracy of temperature control is better than 1 DEG C.With it is existing
Technology is compared, the present invention has the advantages that
1 can complete the scaling experiment of laser radar system measurement accuracy in laboratory, ungentle by mankind's activity
The interference of stream avoids the various uncertain factors and environmental pollution of field testing.Not by the constraint in experiment place, can save
Because of time spent by the demand of these experimental sites and environment, goods and materials.
2 can in laboratory temperature and gas concentration lwevel and pressure in autonomous high-precision control absorption cell according to demand
Power, step simple operations are convenient, and controllability is strong.
The parameter of each component of 3 present apparatus can set up a unified CO2Concentration Testing standard has repeatability, is
The detection of laser radar and Performance Evaluation provide a better application environment.
Detailed description of the invention
Fig. 1 is carbon dioxide concentration measurement scaling system apparatus structure block diagram of the present invention.
In figure: 1-light splitting and energy detection unit, the 2-the one CO2Gas absorption cell, 3-optical paths turnover adjustment mechanism,
4-the two CO2 gas absorption cell, 5-gas cell pond temperature control systems, 6-gas cell Measurement System of Air Pressure, 7-, which vacuumize, is
System, 8-CO2Inflation system, 9-CO2Absorption spectrum measuring system, 10-reflectors.
Fig. 2 is the internal structure block diagram of light splitting and energy detection unit.
In figure: the first reflecting mirror of 1-1-, the second reflecting mirror of 1-2-, 1-3-spectroscope, the first attenuator of 1-4-, 1-
5-the first energy-probe, the second attenuator of 1-6-.
Fig. 3 is CO2The internal structure block diagram of absorption spectrum measuring system.
In figure: 9-1-Frequency Adjustable light source, 9-2-light source frequency scanning controller, 9-3-collimating mirror, 9-4-polarization spectro rib
Mirror, 9-5-quarter-wave plate, the second energy-probe of 9-6-.
Specific embodiment
Below with reference to embodiment and attached drawing, the invention will be further described, but protection model of the invention should not be limited with this
It encloses.Schematic diagram 1 is please referred to, Fig. 1 is that the present invention is based on the schematic diagram of carbon dioxide concentration measurement robot scaling equipment, a kind of carbon dioxide
Measurement of concetration scaling system device, including light splitting and energy detection unit, the first CO2Gas absorption cell, optical path replicating structure, the
Two CO2Gas absorption cell, gas cell pond temperature control system, gas cell Measurement System of Air Pressure, pumped vacuum systems, CO2Inflation system,
CO2Absorption spectrum measuring system, reflector.The positional relationship of above-mentioned component is as follows:
The light splitting and energy detection unit is located at the first CO2In front of gas absorption cell optical window, by laser radar
Transmitting light point takes part energy to be detected and decayed, and remainder energy enters the first CO2Gas absorption cell.Described
One CO2Gas absorption cell passes through optical path replicating structure and the 2nd CO2Gas absorption cell is connected, and the absorption cell for forming sealing is whole.Light
Road replicating structure is for adjusting optical path length, and the first CO of adjustment2Gas absorption cell and the 2nd CO2Between gas absorption cell away from
From to guarantee that the emergent light of light splitting and energy detection unit can enter the first CO2Gas absorption cell, and the 2nd CO2Gas absorbs
The outgoing luminous energy in pond receives system by laser radar and receives.The gas cell pond temperature control system, gas cell air pressure detection system
System, pumped vacuum systems and CO2Inflation system is mounted on the 2nd CO2Gas absorption cell outer wall.Gas cell pond temperature control system is to suction
Gas temperature is controlled in receives pond entirety.Gas cell Measurement System of Air Pressure, pumped vacuum systems and CO2Inflation system forms CO2
Exhaust total system is filled, is vacuumized for absorption cell whole interior and CO2Pressure control.Carry out CO2When measurement of concetration scaling experiment,
CO2Absorption spectrum measuring system reflector does not work.The CO2Absorption spectrum measuring system and reflector are used for CO2Concentration is surveyed
CO in pond before amount scaling experiment2Absorption spectrum measurement.CO2When absorption spectrum measurement experiment, CO2Absorption spectrum measuring system
Emit adjustable frequency light, by the 2nd CO2Gas absorption cell, optical path replicating structure and the first CO2It is anti-after gas absorption cell
Emitter reflection, light backtracking to CO2Absorption spectrum measuring system.Carry out CO2When absorption spectrum measures, laser radar does not work.
Fig. 2 is the internal structure block diagram of light splitting and energy detection unit, and light splitting and energy detection unit include the first reflection
Mirror, the second reflecting mirror, spectroscope, the first attenuator, the first energy-probe, the second attenuator.It closes the position of above-mentioned component
It is as follows: the first reflecting mirror and the second reflecting mirror, for reflecting and translating laser radar transmitting light.Second reflecting mirror is for adjusting
Emit light level position, allows to enter the first CO2Gas absorption cell optical window.By the position of the second reflector alignment
Afterwards, transmitting light is divided into two-way by spectroscope, and wherein reflected light enters the first energy-probe, transmission after the first attenuator
Light enters the first CO after the second attenuator2Gas absorption cell.
Fig. 3 is CO2The internal structure block diagram of absorption spectrum measuring system, CO2Absorption spectrum measuring system includes Frequency Adjustable light
Source, light source frequency scanning controller, collimating mirror, polarization splitting prism, quarter-wave plate, the second energy-probe.Above-mentioned component
Positional relationship it is as follows: Frequency Adjustable light source is located at collimating mirror focal point, and the light of transmitting is expanded by collimating mirror as directional light.Light source
Frequency scanning controller is connected with Frequency Adjustable light source, for adjusting Frequency Adjustable source emissioning light frequency.Collimating mirror expand after directional light,
By polarization splitting prism, enter the 2nd CO after quarter-wave plate2Gas absorption cell.First CO2The emergent light of gas absorption cell
It is reflected by reflector, reenters absorption cell.2nd CO2The emergent light of gas absorption cell again passes by quilt after quarter-wave plate
Polarization splitting prism reflection, into the second energy-probe.
Laser radar carries out CO using 1572nm light2When concentration is calibrated, the first CO2Gas absorption cell and the first CO2
Gas absorption cell is 7.5m, and bore is greater than 250mm.First CO2Gas absorption cell, optical path replicating structure and the 2nd CO2Gas is inhaled
The absorption cell entirety vacuum-pumping of receives pond composition, vacuum degree are better than 1x10-3Pa。
The gas cell Measurement System of Air Pressure pressure measurement accuracy is better than 1mbar, CO2Inflation system pressure controling precision
Higher than 2mbar.
The gas cell pond temperature control system temperature controlling range is 20-40 DEG C, and accuracy of temperature control is better than 1 DEG C.
Carbon dioxide concentration measurement robot scaling equipment of the present invention completes path of integration differential absorption lidar scaling experiment, tool
Steps are as follows for gymnastics work:
1. combining the definition of the measuring principle and differential optical thickness of IPDA technology can obtain:
Wherein DAOD is carbon dioxide differential optical thickness, Nco2(r) dense for the carbon dioxide gas molecular number at distance r
Degree, Δ σ are carbon dioxide gas differential absorption cross-section at distance r.Therefore measurement optical wavelength can be required and corresponded to according to calibration,
It calculates and absorbs pond length and temperature and the CO being filled with needed for absorption cell2Concentration (CO2Air pressure) come simulate satellite-bone laser radar measurement
Optical thickness.
2. gas cell Measurement System of Air Pressure, pumped vacuum systems and CO2Inflation system makes the first CO2Absorption cell and the 2nd CO2
It is first vacuumized in absorption cell, then the CO poured2Gas, so that CO in absorption cell entirety2Concentration (pressure) reaches predetermined value.
3. reaching predetermined value using gas cell temperature control system control absorption cell temperature.
4. using CO2Absorption spectrum measuring system emits Frequency Adjustable light, returns to CO after absorption cell entirety and reflector2
Absorption spectrum measuring system.Utilize CO2The second energy-probe in absorption spectrum measuring system receives the inverting of echo power energy
CO in absorption cell entirety2Absorption spectrum.
5. formally carry out carbon dioxide concentration measurement scaling experiment, laser radar system laser emits laser, passes through
Transmitting light beam is divided into two beams by light splitting and energy detection unit, and light beam injects the first energy-probe and carries out energy monitoring, prison
It measures power and is denoted as PonmAnd Poffm, another beam light emission enters the first CO2Absorption cell.
6. entering the first CO2The light of absorption cell injects the second heavy caliber CO by light turnover adjustment mechanism2Absorption cell, outgoing
Light is integrated path differential absorption lidar and receives system reception, receives echo power and is denoted as PonAnd Poff.It is transferred and is adjusted by light
Complete machine structure connects the first CO2Absorption cell and the 2nd CO2Absorption cell, the luminous energy for emitting laser radar laser are received system and connect
It receives, and the path that light back and forth is passed by is different, will not interfere with each other influence.
7. laser radar system has measured a CO2After the result of concentration, by gas cell Measurement System of Air Pressure, vacuumize
System and CO2Inflation system changes CO in carbon dioxide concentration measurement robot scaling equipment2Concentration, the precision for calibrating its knots modification
It is required that.
8. using CO2CO in absorption spectrum measuring system measuring cell2Absorption spectrum.
9. laser radar system laser emits laser again, CO in absorption cell is measured2Energy monitoring after concentration change
Signal and reception system echoes signal.
10. comparing that laser radar system measures twice as a result, judging whether laser radar system reaches the calibration precision.