[go: up one dir, main page]

CN109141028B - Chain grate machine-rotary kiln pellet low NOx production device and pellet production method - Google Patents

Chain grate machine-rotary kiln pellet low NOx production device and pellet production method Download PDF

Info

Publication number
CN109141028B
CN109141028B CN201710456579.6A CN201710456579A CN109141028B CN 109141028 B CN109141028 B CN 109141028B CN 201710456579 A CN201710456579 A CN 201710456579A CN 109141028 B CN109141028 B CN 109141028B
Authority
CN
China
Prior art keywords
section
reducing agent
air
drying section
rotary kiln
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201710456579.6A
Other languages
Chinese (zh)
Other versions
CN109141028A (en
Inventor
胡兵
代友训
周志安
王兆才
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhongye Changtian International Engineering Co Ltd
Original Assignee
Zhongye Changtian International Engineering Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zhongye Changtian International Engineering Co Ltd filed Critical Zhongye Changtian International Engineering Co Ltd
Priority to CN201710456579.6A priority Critical patent/CN109141028B/en
Publication of CN109141028A publication Critical patent/CN109141028A/en
Application granted granted Critical
Publication of CN109141028B publication Critical patent/CN109141028B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27BFURNACES, KILNS, OVENS OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
    • F27B19/00Combinations of different kinds of furnaces that are not all covered by any single one of main groups F27B1/00 - F27B17/00
    • F27B19/04Combinations of different kinds of furnaces that are not all covered by any single one of main groups F27B1/00 - F27B17/00 arranged for associated working
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B1/00Preliminary treatment of ores or scrap
    • C22B1/02Roasting processes
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D15/00Handling or treating discharged material; Supports or receiving chambers therefor
    • F27D15/02Cooling
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D17/00Arrangements for using waste heat; Arrangements for using, or disposing of, waste gases
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D17/00Arrangements for using waste heat; Arrangements for using, or disposing of, waste gases
    • F27D17/10Arrangements for using waste heat
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D17/00Arrangements for using waste heat; Arrangements for using, or disposing of, waste gases
    • F27D17/20Arrangements for treatment or cleaning of waste gases
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/25Process efficiency

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Geology (AREA)
  • Manufacturing & Machinery (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Manufacture And Refinement Of Metals (AREA)

Abstract

Grate-rotary kiln pellet low NOxThe mode production device comprises a chain grate (3), a rotary Kiln (Kiln) connected with the chain grate (3) and a ring cooling machine (C) connected with the rotary Kiln (Kiln), wherein a reducing agent injection device (1) is arranged on a transition section (2) between a second preheating section (PH) of the chain grate (3) and the tail end of the rotary Kiln (Kiln), reducing gas is injected in a reverse direction of the flue gas to fully mix and react with high-temperature flue gas after roasting of iron ore pellet materials, and therefore NO is achievedxTo reduce NO in flue gasxWhile the flue gas from the second preheating stage (PH) is partially recycled back to the first cooling stage (C1) of the ring cooler (Kiln) via the after-draft drying stage (DDD) to reduce the escape of reducing agent and further reduce NOxThe amount of discharge of (c). The low NO of the grate-rotary kiln pellets is realized by the synergistic effect of the two technical meansxThe production is carried out in a mode.

Description

链篦机-回转窑球团低NOx生产装置及球团生产方法Chain grate machine-rotary kiln pellet low NOx production device and pellet production method

技术领域technical field

本发明涉及工程链篦机-回转窑球团技术领域,具体涉及一种链篦机-回转窑球团低 NOx(氮氧化物)生产装置及铁矿球团生产方法。The invention relates to the technical field of engineering chain grate-rotary kiln pellets, in particular to a chain grate-rotary kiln pellet low NOx (nitrogen oxide) production device and a production method for iron ore pellets.

背景技术Background technique

球团矿是我国高炉炼铁生成的主要含铁炉料,2015年我国球团矿产量为12800万吨。相比烧结矿,由于球团生产过程能耗低、环境相对友好,且产品具有强度好、品位高、冶金性能好的优点,应用到高炉冶炼中可起到增产节焦、改善炼铁技术经济指标、降低生铁成本、提高经济效益的作用,因此球团矿在我国得到了较好的发展。Pellets are the main iron-containing charge produced in blast furnace ironmaking in my country. In 2015, the output of pellets in my country was 128 million tons. Compared with sintered ore, because the pellet production process has low energy consumption, relatively friendly environment, and the product has the advantages of good strength, high grade and good metallurgical performance, the application in blast furnace smelting can increase production and save coke, and improve the technical economy of ironmaking. Therefore, the pellets have been well developed in my country.

我国球团生产以链篦机-回转窑工艺为主,其产量占球团总产量的60%以上。链篦机-回转窑工艺在生产氧化球团过程中会产生一定数量的NOx。近年来,随着铁矿原料和燃料的日趋复杂,赤铁矿比例的提高(导致焙烧温度升高)、低品质燃料的规模利用、气基回转窑含氮焦炉煤气的应用等,使得不少企业球团生产过程NOx排放浓度呈上升趋势;加之我国环保要求的日益严苛,NOx排放被纳入排放的考核体系,从2015年起,球团生产NOx(以NO2计)排放限值300mg/m3,使得这部分企业需要增设脱硝设施才能满足国家的排放标准。The production of pellets in my country is mainly based on the chain grate-rotary kiln process, and its output accounts for more than 60% of the total output of pellets. The chain grate-rotary kiln process produces a certain amount of NO x during the production of oxidized pellets. In recent years, with the increasing complexity of iron ore raw materials and fuels, the increase in the proportion of hematite (leading to an increase in roasting temperature), the large-scale utilization of low-quality fuels, and the application of nitrogen-containing coke oven gas in gas-based rotary kilns, etc. The NO x emission concentration in the pellet production process of few enterprises is on the rise; coupled with the increasingly stringent environmental protection requirements in China, NO x emission has been included in the emission assessment system. The limit is 300mg/m 3 , which makes these enterprises need to add denitrification facilities to meet the national emission standards.

虽然球团企业在环保方面做了大量的工作,除尘和脱硫得到了有效控制,能够满足排放要求,但是目前NOx因脱除成本高、工艺复杂,在钢铁形式低迷的环境下,这给球团产业带来了新的挑战,部分企业因NOx超标不得不大量减产,甚至面临关停。从目前大多数的球团生产情况来看,NOx一般排放超标30~100mg/m3,如果能从源头和过程出发,减少NOx产生,从而能够满足排放要求,可以省去末端脱硝净化设备,对链篦机-回转窑球团生产意义重大,有利于进一步提高球团生产的生命力和竞争力。Although the pelletizing enterprises have done a lot of work in environmental protection, dust removal and desulfurization have been effectively controlled and can meet the emission requirements, but the current NOx removal cost is high and the process is complicated. The group industry has brought new challenges. Some enterprises have to reduce production in large quantities due to excessive NOx , or even face shutdown. Judging from the current production situation of most pellets, the emission of NO x generally exceeds the standard by 30-100 mg/m 3 . If the source and process can be used to reduce the generation of NO x , the emission requirements can be met, and the terminal denitration purification equipment can be omitted. , is of great significance to the production of chain grate-rotary kiln pellets, and is conducive to further improving the vitality and competitiveness of pellet production.

现有脱除烟气中氮氧化物的方法主要有选择性催化还原技术(SCR)和非选择性催化还原技术(SNCR)。其中,温度对SNCR脱硝技术起主导作用。一般认为温度范围为800℃~1100℃较为适宜,当温度过高时,NH3氧化生成NO,可能造成NO的浓度升高,导致NOx的脱除率降低;当温度过低时,NH3的反应速率下降,NOx脱除率也会下降,同时NH3的逃逸量也会增加。通常第二预热段、第二预热段和回转窑之间过渡段的温度范围在950℃~1100℃之间,满足SNCR脱硝方法的条件。Existing methods for removing nitrogen oxides from flue gas mainly include selective catalytic reduction (SCR) and non-selective catalytic reduction (SNCR). Among them, temperature plays a leading role in SNCR denitration technology. It is generally considered that the temperature range of 800℃~1100℃ is suitable. When the temperature is too high, NH 3 is oxidized to form NO, which may increase the concentration of NO and reduce the removal rate of NO x ; when the temperature is too low, NH 3 The reaction rate decreases, the NOx removal rate also decreases, and the amount of NH3 escape increases. Usually, the temperature range of the second preheating section, the transition section between the second preheating section and the rotary kiln is between 950°C and 1100°C, which meets the conditions of the SNCR denitration method.

现有的链篦机-回转窑球团生产工艺如图1所示,链篦机分成鼓风干燥段、抽风干燥段、第一预热段和第二预热段,环冷机分成第一冷却段、第二冷却段及第三冷却段。其中,第一冷却段的风直接进入回转窑中焙烧球团矿,经第二预热段加热预热球后鼓入到抽风干燥段对生球进行抽风干燥,再经抽风干燥段向外排放(排放之前经过烟气净化处理);第二冷却段的风进入第一预热段加热生球后向外排放;第三冷却段的风进入鼓风干燥段对生球进行鼓风干燥,从而实现链篦机-回转窑-环冷机风流系统的合理分配。The existing chain grate-rotary kiln pellet production process is shown in Figure 1. The chain grate is divided into a blast drying section, a suction drying section, a first preheating section and a second preheating section, and the ring cooler is divided into the first section. cooling section, second cooling section and third cooling section. Among them, the air in the first cooling section directly enters the rotary kiln to roast the pellets, and after heating the preheating balls in the second preheating section, they are blown into the exhaust air drying section for exhaust air drying, and then discharged to the outside through the exhaust air drying section. (the flue gas is purified before being discharged); the wind in the second cooling section enters the first preheating section to heat the green balls and then discharges to the outside; the wind in the third cooling section enters the blast drying section to blast and dry the green balls, thereby Realize the reasonable distribution of the air flow system of the chain grate-rotary kiln-ring cooler.

公开号为CN 106268270 A,公开日为2017年1月4日,名称为“一种链篦机-回转窑脱硝系统”的专利文献公开了一种链篦机-回转窑脱硝系统,该方法通过在第二预热段的内腔增加脱硝装置,喷嘴喷射方向与烟气的流动方向相同。虽然该技术能够一定程度的减少NOx的排放量,但是减少幅度有限,喷的还原剂量较难控制,过多则造成NH3逃逸,污染环境,过少则 NOx的排放仍然不能达到排放的要求。The publication number is CN 106268270 A, the publication date is January 4, 2017, and the patent document titled "a chain grate-rotary kiln denitration system" discloses a chain grate-rotary kiln denitration system. A denitrification device is added to the inner cavity of the second preheating section, and the injection direction of the nozzle is the same as the flow direction of the flue gas. Although this technology can reduce the amount of NOx emissions to a certain extent, the reduction range is limited, and the amount of reductant sprayed is difficult to control. Too much will cause NH 3 to escape and pollute the environment. Require.

在现有技术中,由于没有系统的研究和可靠的链篦机-回转窑球团生产过程低NOx生成和控制技术,造成球团厂生产过程NOx排放不达标成为常态和企业面临的最大挑战之一。为此,企业只能通过降低球团矿产量,从而减少煤气或煤粉喷入量、降低球团矿强度要求,从而降低回转窑温度和采用较低NOx的原料和燃料等方式来降低NOx的生成。这些方式不仅在产量和质量上影响了球团矿生产,对原燃料的质量要求也很高,造成成本的增加,而且不能从根本上解决球团低NOx生产的难题。除此之外,在主抽风机之后增设脱硝装置,如采用选择性催化还原技术(SCR)和非选择性催化还原技术(SNCR),虽然可以达到低NOx排放的要求,但由于其投资成本高、设备要求高、能耗大、脱硝成本高及存在二次污染,在球团企业没有得到推广应用,目前国内外球团厂NOx控制方式主要还是通过过程控制实现。In the prior art, due to the lack of systematic research and reliable grate-rotary kiln pellet production process with low NO x generation and control technology, the non-compliance of NO x emission in the production process of the pellet plant has become the norm and the biggest problem faced by enterprises. one of the challenges. For this reason, enterprises can only reduce NO by reducing the output of pellets, thereby reducing the amount of gas or pulverized coal injected, reducing the requirements for the strength of pellets, thereby reducing the temperature of the rotary kiln and using raw materials and fuels with lower NOx . Generation of x . These methods not only affect the production of pellets in terms of output and quality, but also have high requirements on the quality of raw fuels, resulting in increased costs, and cannot fundamentally solve the problem of low- NOx production of pellets. In addition, adding a denitrification device after the main exhaust fan, such as the use of selective catalytic reduction (SCR) and non-selective catalytic reduction (SNCR) technology, although it can meet the requirements of low NOx emissions, but due to its investment cost High requirements, high equipment requirements, high energy consumption, high denitration cost and secondary pollution have not been popularized and applied in pelletizing enterprises. At present, the NO x control method of pelletizing plants at home and abroad is mainly realized through process control.

为了满足链篦机-回转窑球团生产过程NOx排放要求,响应国家的节能减排号召,必须从工艺流程本身出发,发明出更加先进的风流系统,同时利用系统自身的特点,实现低NOx球团生产。In order to meet the requirements of NO x emission in the production process of grate-rotary kiln pellets, and to respond to the national call for energy conservation and emission reduction, it is necessary to invent a more advanced air flow system from the process itself, and at the same time use the characteristics of the system itself to achieve low NO x x pellet production.

发明内容SUMMARY OF THE INVENTION

针对上述现有技术中存在的缺陷和问题,本发明通过优化链篦机-回转窑系统的工艺流程,对抽风干燥段的部分热废气进行循环利用,抽回到环冷机的第一冷却段,因此提高了第一冷却段的废气温度,减少了中央烧嘴的煤气量,同时在第二预热段和回转窑之间的过渡段增加SNCR法脱NOx的装置,通过二者的协同治理能够很大程度上减少链篦机-回转窑球团生产过程NOx的排放量,以此解决上述面临的技术难题,具有“节能、减排和低NOx生产”的特点。In view of the above-mentioned defects and problems in the prior art, the present invention, by optimizing the technological process of the chain grate-rotary kiln system, recycles part of the hot waste gas in the extraction and drying section, and extracts it back to the first cooling section of the ring cooler. Therefore, the exhaust gas temperature in the first cooling section is increased, the gas volume of the central burner is reduced, and the SNCR method for removing NOx is added in the transition section between the second preheating section and the rotary kiln. The treatment can greatly reduce the NOx emission in the production process of the grate-rotary kiln pellets, so as to solve the above-mentioned technical problems, and has the characteristics of "energy saving, emission reduction and low NOx production".

根据本发明提供的第一种实施方案,提供一种链篦机-回转窑(铁矿)球团低NOx生产装置:According to the first embodiment provided by the present invention, a chain grate-rotary kiln (iron ore) pellet low NOx production device is provided:

一种链篦机-回转窑球团低NOx生产装置,它包括链篦机,与链篦机的末端相连的回转窑及位于回转窑的前端的环冷机。并且,按照工艺走向,所述链篦机依次设置有鼓风干燥段、抽风干燥段、第一预热段及第二预热段;环冷机依次设置有第一冷却段、第二冷却段及第三冷却段,回转窑的尾端连接链篦机的第二预热段和另一端(即前端)连接环冷机的第一冷却段。A chain grate machine-rotary kiln pellet low NOx production device comprises a chain grate machine, a rotary kiln connected with the end of the chain grate machine, and an annular cooler located at the front end of the rotary kiln. Moreover, according to the process trend, the chain grate machine is sequentially provided with a blast drying section, a suction drying section, a first preheating section and a second preheating section; the ring cooler is sequentially provided with a first cooling section and a second cooling section. And the third cooling section, the tail end of the rotary kiln is connected to the second preheating section of the grate machine and the other end (ie the front end) is connected to the first cooling section of the ring cooler.

其中第二冷却段的出风口经由第一管道连接至第一预热段的进风口。第三冷却段的出风口经由第二管道连接至鼓风干燥段的底部风箱的进风口并且在第二管道上设有第一抽风机。第二预热段的底部风箱的出风口经由第三管道连接至抽风干燥段的顶部的进风口并且在第三管道设有第二抽风机。从第一预热段的底部风箱的出风口引出的第四管道连接至烟囱并且在第四管道上设有第三抽风机。从鼓风干燥段的顶部的出风口引出的第五管道连接至烟囱并且在第五管道上设有第四抽风机。第一鼓风机的出风口通过第六管道与第二冷却段的进风口连接。第二鼓风机的出风口通过第七管道与第三冷却段的进风口连接。回转窑(Kiln)的前端配有一台鼓风机(回转窑鼓风机或第三鼓风机),用于向回转窑的中央烧嘴中供应助燃风。The air outlet of the second cooling section is connected to the air inlet of the first preheating section via the first pipeline. The air outlet of the third cooling section is connected to the air inlet of the bottom bellows of the blast drying section via a second duct and a first exhaust fan is provided on the second duct. The air outlet of the bottom bellows of the second preheating section is connected to the air inlet at the top of the extraction and drying section via a third duct, and a second exhaust fan is arranged in the third duct. The fourth duct drawn from the air outlet of the bottom bellows of the first preheating section is connected to the chimney and a third exhaust fan is arranged on the fourth duct. A fifth duct drawn from the air outlet at the top of the blast drying section is connected to the chimney and a fourth exhaust fan is provided on the fifth duct. The air outlet of the first blower is connected to the air inlet of the second cooling section through a sixth duct. The air outlet of the second blower is connected to the air inlet of the third cooling section through a seventh duct. The front end of the rotary kiln (Kiln) is equipped with a blower (rotary kiln blower or third blower) to supply combustion air to the central burner of the rotary kiln.

在本发明中,该生产装置还包括设置在第二预热段与回转窑之间的过渡段,及设置在过渡段的还原剂喷射装置。In the present invention, the production device further comprises a transition section arranged between the second preheating section and the rotary kiln, and a reducing agent injection device arranged in the transition section.

在本发明中,所述还原剂喷射装置包括依次连接的还原剂储存罐、压力输送泵、混合室、气化炉、气体分配室及处于过渡段之内的反应腔体。其中反应腔体中设有还原剂输送管,还原剂输送管与气体分配室连通并且还原剂输送管上设有喷嘴。In the present invention, the reductant injection device includes a reductant storage tank, a pressure delivery pump, a mixing chamber, a gasifier, a gas distribution chamber and a reaction chamber within the transition section, which are connected in sequence. The reaction chamber is provided with a reducing agent conveying pipe, the reducing agent conveying pipe is communicated with the gas distribution chamber, and the reducing agent conveying pipe is provided with a nozzle.

优选的是,所述还原剂喷射装置包括依次连接的还原剂储存罐、压力输送泵、混合室及处于过渡段之内的反应腔体。其中反应腔体内设有气体分配室及与气体分配室连通的还原剂输送管,还原剂输送管上设有喷嘴,混合室经由管道连通至位于反应腔体内的气体分配室。Preferably, the reductant injection device comprises a reductant storage tank, a pressure delivery pump, a mixing chamber and a reaction chamber within the transition section, which are connected in sequence. The reaction chamber is provided with a gas distribution chamber and a reducing agent conveying pipe communicating with the gas distribution chamber, the reducing agent conveying pipe is provided with a nozzle, and the mixing chamber is connected to the gas distribution chamber in the reaction chamber through a pipeline.

一般,还原剂是液氨、氨气或氨水的水溶液。Generally, the reducing agent is an aqueous solution of liquid ammonia, ammonia gas or ammonia water.

优选的是,所述还原剂喷射装置还包括设置在压力输送泵与混合室之间的液体流量调节阀。Preferably, the reducing agent injection device further includes a liquid flow regulating valve disposed between the pressure delivery pump and the mixing chamber.

优选的是,所述还原剂喷射装置还包括设置在气化炉与气体分配室之间的气体流量调节阀。Preferably, the reducing agent injection device further comprises a gas flow regulating valve arranged between the gasifier and the gas distribution chamber.

优选的是,所述还原剂喷射装置还包括设置在气体分配室上的气体(或空气)供应管和气体流量调节阀。Preferably, the reducing agent injection device further comprises a gas (or air) supply pipe and a gas flow regulating valve arranged on the gas distribution chamber.

一般,抽风干燥段的底部风箱的出风口也连通至第四管道,进而连通至烟囱。优选,该生产装置还包括从抽风干燥段的底部风箱的出风口引出的第八管道,且第八管道连接至环冷机的第一冷却段的进风口,第八管道上设有第五鼓风机。Generally, the air outlet of the bottom bellows of the extraction and drying section is also connected to the fourth duct, and then connected to the chimney. Preferably, the production device further comprises an eighth pipe drawn from the air outlet of the bottom bellows of the extraction and drying section, and the eighth pipe is connected to the air inlet of the first cooling section of the ring cooler, and the eighth pipe is provided with a fifth blower .

在本发明中,所述抽风干燥段进一步分成第一抽风干燥段和第二抽风干燥段。其中第一抽风干燥段与鼓风干燥段连接,第二抽风干燥段与第一预热段连接。从第二抽风干燥段的底部风箱的出风口引出的第八管道连接至环冷机的第一冷却段的进风口。从第一抽风干燥段的底部风箱的出风口引出的第九管道与从第一预热段的出风口引出的第四管道两者在合并或汇合之后连接至烟囱。In the present invention, the suction drying section is further divided into a first suction drying section and a second suction drying section. The first exhaust drying section is connected with the blast drying section, and the second exhaust drying section is connected with the first preheating section. The eighth pipe drawn from the air outlet of the bottom bellows of the second air extraction and drying section is connected to the air inlet of the first cooling section of the ring cooler. Both the ninth duct drawn from the air outlet of the bottom bellows of the first extraction and drying section and the fourth duct drawn from the air outlet of the first preheating section are connected to the chimney after being merged or merged.

优选的是,所述还原剂输送管分成前后1-3排(例如2排),每排中还原剂输送管的数量为 2-15根,优选3-10根。Preferably, the reducing agent conveying pipes are divided into 1-3 front and rear rows (for example, 2 rows), and the number of reducing agent conveying pipes in each row is 2-15, preferably 3-10.

优选的是,每根还原剂输送管上的喷嘴的数量为2-20个,优选为4-15个,更优选6-12 个。Preferably, the number of nozzles on each reducing agent delivery pipe is 2-20, preferably 4-15, more preferably 6-12.

根据本发明提供的第二种实施方案,提供一种链篦机-回转窑球团的(低NOx方式)生产方法:According to the second embodiment provided by the present invention, a production method of chain grate-rotary kiln pellets (low NOx mode) is provided:

一种链篦机-回转窑球团生产方法或一种使用上述链篦机-回转窑球团低NOx生产装置生产球团的方法,该方法包括以下步骤:A chain grate-rotary kiln pellet production method or a method for producing pellets using the above-mentioned chain grate-rotary kiln pellet low- NOx production device, the method comprising the following steps:

1)铁矿的生球依次经过链篦机的鼓风干燥段与抽风干燥段被干燥、然后经过第一预热段与第二预热段被加热,1) The raw balls of iron ore are dried in sequence through the blast drying section and the exhaust drying section of the chain grate machine, and then heated through the first preheating section and the second preheating section,

2)加热后的铁矿生球进一步经过在第二预热段与回转窑之间的设有还原剂喷射装置的过渡段,其中在该过渡段中,通过与流过过渡段的热烟气逆向喷射还原性气体来让还原性气体与铁矿球团物料焙烧后的含有NOx的高温烟气进行充分混合和较长时间的反应,从而实现 NOx的非催化还原来降低过渡段的烟气中NOx的含量,和2) The heated iron ore green balls further pass through a transition section between the second preheating section and the rotary kiln provided with a reducing agent injection device, wherein in the transition section, the hot flue gas flowing through the transition section passes through the transition section. Reverse injection of reducing gas to make the reducing gas and the high temperature flue gas containing NO x after roasting the iron ore pellets fully mixed and reacted for a long time, so as to realize the non-catalytic reduction of NO x and reduce the smoke in the transition section the amount of NOx in the gas, and

3)从过渡段中输出的铁矿生球进入回转窑中进行焙烧,焙烧后经过环冷机的冷却得到球团矿产品;3) The iron ore green pellets output from the transition section enter the rotary kiln for roasting, and after roasting, the pellets are obtained through the cooling of the ring cooler;

其中,环冷机的第一冷却段上部空间的风从回转窑的前端直接进入回转窑中参与球团焙烧,然后流经第二预热段后进入抽风干燥段对生球进行抽风干燥,随后抽风干燥段下部的热废气经由第四管道向外排放至烟囱或经由第八管道循环至第一冷却段的进风口;第二冷却段的风进入第一预热段预热生球后向外排放至烟囱;第三冷却段的风进入鼓风干燥段对生球进行鼓风干燥后向外排放至烟囱;从第二预热段的底部风箱抽出的风经由第三管道输送至抽风干燥段的顶部的进风口。Among them, the air in the upper space of the first cooling section of the ring cooler enters the rotary kiln directly from the front end of the rotary kiln to participate in the pellet roasting, and then flows through the second preheating section and then enters the exhaust drying section to exhaust and dry the green pellets. The hot exhaust gas in the lower part of the extraction and drying section is discharged to the chimney through the fourth pipe or circulated to the air inlet of the first cooling section through the eighth pipe; the air of the second cooling section enters the first preheating section to preheat the green balls and then flows outwards. Discharge to the chimney; the air in the third cooling section enters the blast drying section to blast and dry the green pellets and then discharges to the chimney; the air extracted from the bottom bellows of the second preheating section is transported to the exhaust drying section through the third pipe the air inlet at the top.

优选,抽风干燥段进一步分成第一抽风干燥段和第二抽风干燥段,第二抽风干燥段的热废气经由第八管道循环至第一冷却段,而第一抽风干燥段的热废气经由第四管道向外排放至烟囱。Preferably, the extraction and drying section is further divided into a first extraction and drying section and a second extraction and drying section, the hot exhaust gas of the second extraction and drying section is circulated to the first cooling section through the eighth pipeline, and the hot exhaust gas of the first extraction and drying section is passed through the fourth The pipe discharges out to the chimney.

优选,在还原剂储存罐中贮存的还原剂(例如液氨)在压力输送泵的抽吸下被输送到混合室中与输入其中的稀释剂(例如水或空气或氮气)进行混合,然后输送到气化炉进行气化,气化后的还原剂混合物经过位于反应腔体外部的气体分配室的分配而进入到各个还原剂输送管中并通过输送管上的喷嘴被喷入到处于过渡段内的反应腔体之中,在其中还原剂与流过反应腔体的热废气所含有的氮氧化物(NOx)进行反应。Preferably, the reducing agent (eg liquid ammonia) stored in the reducing agent storage tank is transported into the mixing chamber under the suction of the pressure delivery pump to be mixed with the diluent (eg water or air or nitrogen) fed into it, and then transported To the gasifier for gasification, the gasified reducing agent mixture enters into each reducing agent conveying pipe through the distribution of the gas distribution chamber outside the reaction chamber, and is sprayed into the transition section through the nozzle on the conveying pipe. In a reaction chamber within the reactor in which the reducing agent reacts with nitrogen oxides (NO x ) contained in the hot exhaust gas flowing through the reaction chamber.

或,作为另一种方案,在还原剂储存罐中贮存的还原剂(例如液氨或氨水)在压力输送泵的抽吸下被输送到混合室中与输入其中的稀释剂(例如水或空气或氮气)进行混合,然后直接输送到位于反应腔体内的气体分配室中,然后还原剂混合物进入到各个还原剂输送管中并通过输送管上的喷嘴被喷入到处于过渡段内的反应腔体之中,在其中还原剂与流过反应腔体的热废气所含有的氮氧化物(NOx)进行反应,产生氮气。Or, as another solution, the reducing agent (such as liquid ammonia or ammonia water) stored in the reducing agent storage tank is transported into the mixing chamber under the suction of the pressure feed pump and the diluent (such as water or air) fed into it or nitrogen) for mixing, and then directly transported to the gas distribution chamber located in the reaction chamber, and then the reducing agent mixture enters each reducing agent delivery pipe and is sprayed into the reaction chamber in the transition section through the nozzle on the delivery pipe A body in which the reducing agent reacts with nitrogen oxides ( NOx ) contained in the hot exhaust gas flowing through the reaction chamber, producing nitrogen gas.

在本申请中,稀释剂可以使用液体型和/或气体型的稀释剂,例如水或空气或氮气。In the present application, the diluent may use liquid and/or gaseous diluents, such as water or air or nitrogen.

一般,在气体分配室中通入压缩空气。Typically, compressed air is passed through the gas distribution chamber.

在本发明中,所述抽风干燥段进一步分成第一抽风干燥段和第二抽风干燥段,其中第一抽风干燥段和第二抽风干燥段具有相等或者不相等的间距。第一抽风干燥段与鼓风干燥段连接,第二抽风干燥段与第一预热段连接,由于第一抽风干燥段的热废气中水分含量较高,因此仅对第二抽风干燥段的部分或全部热废气循环至第一冷却段,作为第一冷却段的冷却风。与现有技术中鼓入冷风冷却方式相比,循环回来的热废气能够把第一冷却段的热废气温度适当提高,从而可以适当减少回转窑中央烧嘴提供的热量,也就是中央烧嘴出口烟气的温度降低,这是减少热力型NOx的有效措施,同时消耗的燃料也会减少,因此也是减少燃料型NOx的有效措施。In the present invention, the suction drying section is further divided into a first suction drying section and a second suction drying section, wherein the first suction drying section and the second suction drying section have equal or unequal distances. The first exhaust drying section is connected with the blast drying section, and the second exhaust drying section is connected with the first preheating section. Since the moisture content of the hot exhaust gas in the first exhaust drying section is relatively high, only the second exhaust drying section is used for the drying section. Or all the hot exhaust gas is circulated to the first cooling section as the cooling air of the first cooling section. Compared with the cooling method of blowing cold air in the prior art, the circulating hot exhaust gas can appropriately increase the temperature of the hot exhaust gas in the first cooling section, thereby appropriately reducing the heat provided by the central burner of the rotary kiln, that is, the outlet of the central burner. The temperature of the flue gas is reduced, which is an effective measure to reduce thermal NOx , and the fuel consumption is also reduced, so it is also an effective measure to reduce fuel-type NOx .

在本发明中,所述还原剂喷射装置为SNCR法脱NOx的装置,还原剂喷射装置包括设置在压力输送泵与混合室之间的液体流量调节阀,液体流量调节阀的设置有利于根据生产需要实时调节还原剂的液体流量。还原剂喷射装置包括气体流量调节阀,气体流量调节阀的设置有利于根据生产需要实时调节气化后的还原剂的气体流量。还原剂喷射装置包括有还原剂输送管,还原剂输送管分成前后1-3排,每排中还原剂输送管的数量不做限制,一般为2-15根,优选3-10根。每根还原剂输送管上设有喷嘴,喷嘴的数量不做限制,一般为2-20个,优选为4-15个,更优选6-12个。In the present invention, the reducing agent injection device is a device for removing NOx by SNCR method, and the reducing agent injection device includes a liquid flow regulating valve arranged between the pressure delivery pump and the mixing chamber. Production requires real-time regulation of the liquid flow of the reducing agent. The reducing agent injection device includes a gas flow regulating valve, and the setting of the gas flow regulating valve is beneficial to adjust the gas flow of the gasified reducing agent in real time according to production needs. The reducing agent injection device includes reducing agent conveying pipes, which are divided into 1-3 rows before and after, and the number of reducing agent conveying pipes in each row is not limited, generally 2-15, preferably 3-10. Each reducing agent conveying pipe is provided with nozzles, and the number of nozzles is not limited, generally 2-20, preferably 4-15, more preferably 6-12.

在实际生产中,通常在混合室中添加稀释剂(例如水或空气或氮气)来稀释还原剂(例如液氨或氨气),以提高还原剂的分散性,另外在气化炉中通入压缩空气,确保还原气体按照一定的流速喷入反应腔体中。作为优选,取消气化炉,将气体分配室置于反应腔体中,稀释后的还原剂直接进入气体分配室后实现气化,并在气体分配室中通入压缩空气,确保还原气体按照一定的流速喷入反应腔体中。其中,喷入的还原气体在过渡段中发生如下反应:In actual production, a diluent (such as water or air or nitrogen) is usually added in the mixing chamber to dilute the reducing agent (such as liquid ammonia or ammonia gas) to improve the dispersibility of the reducing agent. Compress the air to ensure that the reducing gas is sprayed into the reaction chamber at a certain flow rate. Preferably, the gasification furnace is cancelled, the gas distribution chamber is placed in the reaction chamber, the diluted reducing agent directly enters the gas distribution chamber to realize gasification, and compressed air is introduced into the gas distribution chamber to ensure that the reducing gas is in accordance with a certain The flow rate is sprayed into the reaction chamber. Wherein, the injected reducing gas reacts as follows in the transition section:

4NO+4NH3+O2→4N2+6H2O4NO+4NH 3 +O 2 →4N 2 +6H 2 O

6NO+4NH3→5N2+6H2O6NO+4NH 3 →5N 2 +6H 2 O

2NO2+4NH3+O2→3N2+6H2O2NO 2 +4NH 3 +O 2 →3N 2 +6H 2 O

6NO2+8NH3→7N2+12H2O6NO 2 +8NH 3 →7N 2 +12H 2 O

通过上述反应,可以实现烟气中的NOx(包括NO、NO2)转化为N2,有效降低了烟气中NOx的排放量。另外,未反应的还原剂还可以在第二预热段的烟罩和料层中进一步发生上述反应,由此提高NOx的脱除率,同时尽可能减少NH3的逃逸。Through the above reaction, NO x (including NO, NO 2 ) in the flue gas can be converted into N 2 , which effectively reduces the emission of NO x in the flue gas. In addition, the unreacted reducing agent can further undergo the above reaction in the fume hood and the material layer of the second preheating section, thereby improving the removal rate of NO x and reducing the escape of NH 3 as much as possible.

在本申请中,回转窑的烧嘴方向是前端或窑头。而进物料的一端则是窑尾。In this application, the burner direction of the rotary kiln is the front end or kiln head. The end of the incoming material is the kiln tail.

在本申请中,对于还原剂的喷嘴,一般要求它具有耐磨性。在操作中,混合气喷射压力要求大于该处回热风的压力,以避免粉尘和颗粒堵塞喷嘴。In this application, for the nozzle of the reducing agent, it is generally required to have wear resistance. In operation, the mixed gas injection pressure is required to be greater than the pressure of the return hot air to avoid dust and particles from clogging the nozzles.

在本申请中,链篦机的长度一般是20-80米,优选是30-70米,更优选40-60米。回转窑的长度一般是20-60米,优选是25-50米,更优选30-45米,例如35或40米。In the present application, the length of the grate machine is generally 20-80 meters, preferably 30-70 meters, more preferably 40-60 meters. The length of the rotary kiln is generally 20-60 meters, preferably 25-50 meters, more preferably 30-45 meters, such as 35 or 40 meters.

与现有技术相比,本发明具有的有益效果:Compared with the prior art, the present invention has the following beneficial effects:

1、本发明基于链篦机-回转窑球团生产的工艺特点,创造性的开发了一种球团低NOx生产工艺,该工艺在保证球团矿产质量的同时实现高NOx烟气的循环利用,充分利用烟气中的余热资源,不仅减少了燃料型和热力型NOx的产生量,而且高NOx烟气得到循环利用,以达到节能减排的目的;1. Based on the process characteristics of chain grate-rotary kiln pellet production, the present invention creatively develops a low NOx production process for pellets, which realizes high NOx flue gas circulation while ensuring the quality of pellets. Utilize and make full use of the waste heat resources in the flue gas, which not only reduces the production of fuel-type and thermal-type NOx , but also the high- NOx flue gas is recycled to achieve the purpose of energy saving and emission reduction;

2、本发明结合SNCR法脱硝技术,在第二预热段和回转窑之间的过渡段增加SNCR法还原剂喷射装置,可以处理循环回去的烟气中的NOx,以及生产过程产生的NOx,以最终实现低NOx生产的目的;2. The present invention combines the SNCR method denitrification technology, and the SNCR method reducing agent injection device is added in the transition section between the second preheating section and the rotary kiln, which can treat the NO x in the circulating flue gas and the NO generated in the production process. x , in order to finally achieve the purpose of low NO x production;

3、本发明从工艺流程和NOx的分解机理着手降低链篦机-回转窑球团生产过程NOx的排放,工艺简单,脱NOx成本低,解决了目前球团企业NOx排放超标的技术难题,具有“节能、减排和低NOx生产”的特点。3. The present invention starts from the process flow and the decomposition mechanism of NOx to reduce the NOx emission in the production process of the grate-rotary kiln pelletizing process, the process is simple, the cost of removing NOx is low, and the problem that the NOx emission of the current pelletizing enterprise exceeds the standard is solved. Technical difficulties, with the characteristics of "energy saving, emission reduction and low NOx production".

4、尤其,在链篦机的第二预热段和回转窑的前端之间增加过渡段并且在过渡段上设有还原剂喷射装置,通过与烟气逆向喷射还原性气体来让还原性气体与铁矿球团物料焙烧后产生的高温烟气进行充分混合和较长时间的反应,从而实现NOx的非催化还原来降低烟气中NOx的含量,同时,作为另一个技术手段,将反应后的烟气经抽风干燥段部分循环回到环冷机的第一段,以减少还原剂的逃逸和进一步减少NOx的排放量。通过这两个技术手段的协同作用来实现链篦机-回转窑球团低NOx方式生产。4. In particular, a transition section is added between the second preheating section of the grate machine and the front end of the rotary kiln, and a reducing agent injection device is provided on the transition section, and the reducing gas is injected in the opposite direction with the flue gas. It is fully mixed and reacted for a long time with the high temperature flue gas produced by the roasting of iron ore pellets, so as to realize the non-catalytic reduction of NO x to reduce the content of NO x in the flue gas. At the same time, as another technical means, the The reacted flue gas is partially circulated back to the first section of the ring cooler through the exhaust air drying section to reduce the escape of the reducing agent and further reduce the emission of NOx . Through the synergy of these two technical means, the chain grate-rotary kiln pelletizing low NOx production is realized.

附图说明Description of drawings

图1为现有技术链篦机-回转窑球团生产工艺简图;1 is a schematic diagram of the prior art chain grate-rotary kiln pellet production process;

图2为本发明一种链篦机-回转窑球团低NOx生产工艺简图;Fig. 2 is a kind of chain grate machine-rotary kiln pellet low NOx production process schematic diagram of the present invention;

图3为本发明另一种链篦机-回转窑球团低NOx生产工艺简图;Fig. 3 is another kind of chain grate of the present invention - a schematic diagram of the low NOx production process of rotary kiln pellets;

图4为本发明还原剂喷射装置的结构示意图;4 is a schematic structural diagram of the reducing agent injection device of the present invention;

图5为本发明还原剂喷射装置另一种设计的结构示意图。FIG. 5 is a schematic structural diagram of another design of the reducing agent injection device of the present invention.

附图标记:1:还原剂喷射装置;101:还原剂储存罐;102:压力输送泵;103:液体流量调节阀;104:混合室;105:气化炉;106:气体流量调节阀;106a:空气供应管或气体供应管;107:气体分配室;108:还原剂输送管;109:喷嘴;110:反应腔体;2:过渡段;3:链篦机;UDD:鼓风干燥段;UDDa:鼓风干燥段的进风口;UDDb:鼓风干燥段的出风口; DDD:抽风干燥段;DDDa:抽风干燥段的进风口;DDDb:抽风干燥段的出风口;DDD1:第一抽风干燥段;DDD1b:第一抽风干燥段的出风口;DDD2:第二抽风干燥段;DDD2b:第二抽风干燥段的出风口;TPH:第一预热段;TPHa:第一预热段的进风口;TPHb:第一预热段的出风口;PH:第二预热段;PHb:第二预热段的出风口;Kiln:回转窑;C:环冷机; C1:第一冷却段;C1a:第一冷却段的进风口;C2:第二冷却段;C2a:第二冷却段的进风口; C2b:第二冷却段的出风口;C3:第三冷却段;C3a:第三冷却段的进风口;C3b:第三冷却段的出风口;4:回转窑鼓风机(或称作第三鼓风机);5:第一抽风机;6:第二抽风机;7:烟囱;8:第三抽风机;9:第四抽风机;10:第一鼓风机;11:第二鼓风机;12:第五鼓风机;L1:第一管道;L2:第二管道;L3:第三管道;L4:第四管道;L5:第五管道;L6:第六管道;L7:第七管道;L8:第八管道;L9:第九管道。Reference numerals: 1: reducing agent injection device; 101: reducing agent storage tank; 102: pressure delivery pump; 103: liquid flow regulating valve; 104: mixing chamber; 105: gasifier; 106: gas flow regulating valve; 106a : air supply pipe or gas supply pipe; 107: gas distribution chamber; 108: reducing agent delivery pipe; 109: nozzle; 110: reaction chamber; 2: transition section; 3: chain grate machine; UDD: blast drying section; UDDa: the air inlet of the blast drying section; UDDb: the air outlet of the blast drying section; DDD: the exhaust drying section; DDDa: the air inlet of the exhaust drying section; DDDb: the air outlet of the exhaust drying section; DDD1: the first exhaust drying DDD1b: the air outlet of the first extraction and drying section; DDD2: the second extraction and drying section; DDD2b: the air outlet of the second extraction and drying section; TPH: the first preheating section; TPHa: the air inlet of the first preheating section ;TPHb: air outlet of the first preheating section; PH: second preheating section; PHb: air outlet of the second preheating section; Kiln: rotary kiln; C: ring cooler; C1: first cooling section; C1a : the air inlet of the first cooling section; C2: the second cooling section; C2a: the air inlet of the second cooling section; C2b: the air outlet of the second cooling section; C3: the third cooling section; C3a: the third cooling section Air inlet; C3b: Air outlet of the third cooling section; 4: Rotary kiln blower (or the third blower); 5: First exhaust fan; 6: Second exhaust fan; 7: Chimney; 8: Third exhaust air 9: fourth exhaust fan; 10: first blower; 11: second blower; 12: fifth blower; L1: first duct; L2: second duct; L3: third duct; L4: fourth duct ; L5: the fifth pipe; L6: the sixth pipe; L7: the seventh pipe; L8: the eighth pipe; L9: the ninth pipe.

具体实施方式Detailed ways

根据本发明提供的第一种实施方案,提供一种链篦机-回转窑球团低NOx生产装置:According to the first embodiment provided by the present invention, a chain grate-rotary kiln pellet low NOx production device is provided:

一种链篦机-回转窑球团低NOx生产装置,它包括链篦机3,与链篦机3的末端相连的回转窑Kiln及位于回转窑Kiln的前端的环冷机C。并且,按照工艺走向,所述链篦机3依次设置有鼓风干燥段UDD、抽风干燥段DDD、第一预热段TPH及第二预热段PH;环冷机C依次设置有第一冷却段C1、第二冷却段C2及第三冷却段C3,回转窑Kiln的前端连接第二预热段PH和另一端(即前端)连接环冷机C的第一冷却段C1。A chain grate-rotary kiln pellet low NOx production device comprises a chain grate 3, a rotary kiln Kiln connected to the end of the chain grate 3, and an annular cooler C located at the front end of the rotary kiln Kiln. Moreover, according to the process trend, the chain grate machine 3 is sequentially provided with a blast drying section UDD, a suction drying section DDD, a first preheating section TPH and a second preheating section PH; the ring cooler C is sequentially provided with a first cooling section. Section C1, second cooling section C2 and third cooling section C3, the front end of the rotary kiln Kiln is connected to the second preheating section PH and the other end (ie the front end) is connected to the first cooling section C1 of the ring cooler C.

其中第二冷却段C2的出风口C2b经由第一管道L1连接至第一预热段TPH的进风口TPHa。第三冷却段C3的出风口C3b经由第二管道L2连接至鼓风干燥段UDD的底部风箱的进风口UDDa并且在第二管道L2上设有第一抽风机5。第二预热段PH的底部风箱的出风口 PHb经由第三管道L3连接至抽风干燥段DDD的顶部的进风口DDDa并且在第三管道L3设有第二抽风机6。从第一预热段TPH的底部风箱的出风口TPHb引出的第四管道L4连接至烟囱7并且在第四管道L4上设有第三抽风机8。从鼓风干燥段UDD的顶部的出风口UDDb引出的第五管道L5连接至烟囱7并且在第五管道L5上设有第四抽风机9。第一鼓风机10的出风口通过第六管道L6与第二冷却段C2的进风口C2a连接。第二鼓风机11的出风口通过第七管道L7与第三冷却段C3的进风口C3a连接。回转窑(Kiln)的前端配有回转窑鼓风机4 (或第三鼓风机),后者用于向前者的中央烧嘴输送助燃风。The air outlet C2b of the second cooling section C2 is connected to the air inlet TPHa of the first preheating section TPH via the first pipeline L1. The air outlet C3b of the third cooling section C3 is connected to the air inlet UDDa of the bottom bellows of the blast drying section UDD via the second duct L2 and a first exhaust fan 5 is provided on the second duct L2. The air outlet PHb of the bottom bellows of the second preheating section PH is connected to the air inlet DDDa at the top of the suction drying section DDD via the third duct L3 and a second suction fan 6 is provided in the third duct L3. The fourth duct L4 drawn from the air outlet TPHb of the bottom bellows of the first preheating stage TPH is connected to the chimney 7 and a third exhaust fan 8 is provided on the fourth duct L4. A fifth duct L5 drawn from the air outlet UDDb at the top of the blow drying section UDD is connected to the chimney 7 and a fourth exhaust fan 9 is provided on the fifth duct L5. The air outlet of the first blower 10 is connected to the air inlet C2a of the second cooling section C2 through the sixth duct L6. The air outlet of the second blower 11 is connected to the air inlet C3a of the third cooling section C3 through the seventh duct L7. The front end of the rotary kiln (Kiln) is equipped with a rotary kiln blower 4 (or a third blower), which is used to deliver combustion-supporting air to the former central burner.

在本发明中,该生产装置还包括设置在第二预热段PH与回转窑Kiln之间的过渡段2,及设置在过渡段2的还原剂喷射装置1。In the present invention, the production device further includes a transition section 2 arranged between the second preheating section PH and the rotary kiln Kiln, and a reducing agent injection device 1 arranged in the transition section 2 .

在本发明中,所述还原剂喷射装置1包括依次连接的还原剂储存罐101、压力输送泵102、混合室104、气化炉105、气体分配室107及处于过渡段2内的反应腔体110。其中反应腔体 110中设有还原剂输送管108,还原剂输送管108与气体分配室107连通并且还原剂输送管 108上设有喷嘴109。In the present invention, the reductant injection device 1 includes a reductant storage tank 101 , a pressure delivery pump 102 , a mixing chamber 104 , a gasifier 105 , a gas distribution chamber 107 and a reaction chamber in the transition section 2 , which are connected in sequence. 110. The reaction chamber 110 is provided with a reducing agent delivery pipe 108, the reducing agent delivery pipe 108 communicates with the gas distribution chamber 107, and a nozzle 109 is provided on the reducing agent delivery pipe 108.

优选的是,所述还原剂喷射装置1包括依次连接的还原剂储存罐101、压力输送泵102、混合室104及处于过渡段2内的反应腔体110。其中反应腔体110内设有气体分配室107及与气体分配室107连通的还原剂输送管108,还原剂输送管108上设有喷嘴109,混合室104经由管道连通至位于反应腔体110内的气体分配室107(一般同时向其中供应压缩空气和还原剂混合物)。Preferably, the reducing agent injection device 1 includes a reducing agent storage tank 101 , a pressure delivery pump 102 , a mixing chamber 104 and a reaction chamber 110 in the transition section 2 , which are connected in sequence. The reaction chamber 110 is provided with a gas distribution chamber 107 and a reducing agent delivery pipe 108 communicating with the gas distribution chamber 107 , the reducing agent delivery pipe 108 is provided with a nozzle 109 , and the mixing chamber 104 is connected to the reaction chamber 110 through a pipeline. The gas distribution chamber 107 (to which the compressed air and reducing agent mixture are generally supplied simultaneously).

优选的是,所述还原剂喷射装置1还包括设置在压力输送泵102与混合室104之间的液体流量调节阀103。Preferably, the reducing agent injection device 1 further includes a liquid flow regulating valve 103 disposed between the pressure delivery pump 102 and the mixing chamber 104 .

优选的是,所述还原剂喷射装置1还包括设置在气化炉105与气体分配室107之间的气体流量调节阀106。Preferably, the reducing agent injection device 1 further includes a gas flow regulating valve 106 disposed between the gasifier 105 and the gas distribution chamber 107 .

优选的是,所述还原剂喷射装置1还包括设置在气体分配室107上的空气供应管106a和气体流量调节阀106。Preferably, the reducing agent injection device 1 further includes an air supply pipe 106a and a gas flow regulating valve 106 arranged on the gas distribution chamber 107 .

优选,该生产装置还包括从抽风干燥段DDD的底部风箱的出风口DDDb引出的第八管道L8,且第八管道L8连接至环冷机C的第一冷却段C1的进风口C1a,第八管道L8上设有第五鼓风机12。Preferably, the production device further includes an eighth pipe L8 drawn from the air outlet DDDb of the bottom bellows of the extraction and drying section DDD, and the eighth pipe L8 is connected to the air inlet C1a of the first cooling section C1 of the ring cooler C, and the eighth pipe L8 is A fifth blower 12 is provided on the duct L8.

在本发明中,所述抽风干燥段DDD进一步分成第一抽风干燥段DDD1和第二抽风干燥段DDD2。其中第一抽风干燥段DDD1与鼓风干燥段UDD连接,第二抽风干燥段DDD2与第一预热段TPH连接。从第二抽风干燥段DDD2的底部风箱的出风口DDD2b引出的第八管道L8连接至环冷机C的第一冷却段C1的进风口C1a。从第一抽风干燥段DDD1的底部风箱的出风口DDD1b引出的第九管道L9与从第一预热段TPH的出风口TPHb引出的第四管道 L4两者在合并或汇合之后连接至烟囱7。In the present invention, the suction drying section DDD is further divided into a first suction drying section DDD1 and a second suction drying section DDD2. The first draft drying section DDD1 is connected with the blast drying section UDD, and the second draft drying section DDD2 is connected with the first preheating section TPH. The eighth pipe L8 drawn from the air outlet DDD2b of the bottom bellows of the second air extraction and drying section DDD2 is connected to the air inlet C1a of the first cooling section C1 of the ring cooler C. The ninth duct L9 drawn from the air outlet DDD1b of the bottom bellows of the first extraction and drying section DDD1 and the fourth duct L4 drawn from the air outlet TPHb of the first preheating section TPH are connected to the chimney 7 after being merged or merged.

优选的是,所述还原剂输送管108分成前后1-3排(例如2排),每排中还原剂输送管108 的数量为2-15根,优选3-10根。Preferably, the reducing agent delivery pipes 108 are divided into 1-3 front and rear rows (for example, 2 rows), and the number of reducing agent delivery pipes 108 in each row is 2-15, preferably 3-10.

优选的是,每根还原剂输送管108上的喷嘴109的数量为2-20个,优选为4-15个,更优选6-12个,例如10个。Preferably, the number of nozzles 109 on each reducing agent delivery pipe 108 is 2-20, preferably 4-15, more preferably 6-12, for example, 10.

根据本发明提供的第二种实施方案,提供一种链篦机-回转窑球团的(低NOx方式)生产方法。According to the second embodiment provided by the present invention, there is provided a production method of grate-rotary kiln pellets (low NOx mode).

一种链篦机-回转窑球团生产方法或一种使用上述链篦机-回转窑球团低NOx生产装置生产球团的方法,该方法包括以下步骤:A chain grate-rotary kiln pellet production method or a method for producing pellets using the above-mentioned chain grate-rotary kiln pellet low- NOx production device, the method comprising the following steps:

1)铁矿的生球依次经过链篦机的鼓风干燥段UDD与抽风干燥段DDD被干燥、然后经过第一预热段TPH与第二预热段PH被加热,1) The raw balls of iron ore are dried in sequence through the blast drying section UDD and the exhaust drying section DDD of the chain grate machine, and then heated through the first preheating section TPH and the second preheating section PH,

2)加热后的铁矿球团进一步经过在第二预热段PH与回转窑Kiln之间的设有还原剂喷射装置1的过渡段2,其中在该过渡段2中,通过与流过过渡段2的热烟气逆向喷射还原性气体来让还原性气体与焙烧后铁矿球团物料上方的含有NOx的高温烟气进行充分混合和较长时间的反应,从而实现NOx的非催化还原来降低过渡段2的烟气中NOx的含量,和2) The heated iron ore pellets further pass through the transition section 2 provided with the reducing agent injection device 1 between the second preheating section PH and the rotary kiln Kiln, wherein in the transition section 2, the The hot flue gas in section 2 injects the reducing gas in reverse to make the reducing gas and the high-temperature flue gas containing NO x above the iron ore pellet material after roasting to be fully mixed and react for a long time, so as to realize the non-catalytic NO x . reduction to reduce the NOx content in the flue gas of transition section 2, and

3)从过渡段2中输出的铁矿生球进入回转窑Kiln中进行焙烧,焙烧后经过环冷机C的冷却得到球团矿产品;3) the iron ore green pellets outputted from the transition section 2 enter the rotary kiln Kiln and carry out roasting, and obtain pellets through the cooling of the ring cooler C after the roasting;

其中,环冷机C的第一冷却段C1上部空间的风从回转窑Kiln的前端直接进入回转窑Kiln 中参与生球焙烧,然后流经第二预热段PH预热球团后进入抽风干燥段DDD对生球进行抽风干燥,随后抽风干燥段DDD下部的热废气经由第四管道L4向外排放至烟囱7或经由第八管道L8循环至第一冷却段C1的进风口;第二冷却段C2的风进入第一预热段TPH预热生球后向外排放至烟囱7;第三冷却段C3的风进入鼓风干燥段UDD对生球进行鼓风干燥后向外排放至烟囱7;从第二预热段PH的底部风箱抽出的风经由第三管道L3输送至抽风干燥段DDD的顶部的进风口DDDa。Among them, the air in the upper space of the first cooling section C1 of the ring cooler C directly enters the rotary kiln Kiln from the front end of the rotary kiln to participate in the roasting of green pellets, and then flows through the second preheating section PH to preheat the pellets and then enters the exhaust air drying. Section DDD carries out suction drying on the raw balls, and then the hot waste gas at the lower part of the suction drying section DDD is discharged to the chimney 7 through the fourth pipeline L4 or circulated to the air inlet of the first cooling section C1 through the eighth pipeline L8; the second cooling section The wind of C2 enters the first preheating section TPH to preheat the green balls and then discharges to the chimney 7; the wind of the third cooling section C3 enters the blast drying section UDD to blast and dry the green balls and then discharges to the chimney 7; The air drawn from the bottom wind box of the second preheating section PH is delivered to the air inlet DDDa at the top of the suction drying section DDD through the third duct L3.

优选,抽风干燥段DDD进一步分成第一抽风干燥段DDD1和第二抽风干燥段DDD2,第二抽风干燥段DDD2的热废气经由第八管道L8循环至第一冷却段C1,而第一抽风干燥段DDD1的热废气经由第四管道L4向外排放至烟囱7。Preferably, the extraction and drying section DDD is further divided into a first extraction and drying section DDD1 and a second extraction and drying section DDD2, the hot exhaust gas of the second extraction and drying section DDD2 is circulated to the first cooling section C1 through the eighth pipeline L8, and the first extraction and drying section DDD2 The hot exhaust gas of DDD1 is discharged to the chimney 7 through the fourth pipe L4.

因此,进一步在第二预热段PH与回转窑Kiln之间设置过渡段2,并且在过渡段2设置还原剂喷射装置1,通过向过渡段的含有NOx的烟气中逆向喷射还原性气体来还原NOx以产生氮气。从链篦机排出的球团经由过渡段2被输送到回转窑中。Therefore, a transition section 2 is further provided between the second preheating section PH and the rotary kiln Kiln, and a reducing agent injection device 1 is provided in the transition section 2, by injecting the reducing gas backward into the flue gas containing NO x in the transition section to reduce NOx to produce nitrogen. The pellets discharged from the chain grate are conveyed via the transition section 2 into the rotary kiln.

优选,在还原剂储存罐101中贮存的还原剂(例如液氨或氨水)在压力输送泵102的抽吸下被输送到混合室104中与输入其中的稀释剂(例如水或空气或氮气)进行混合,然后输送到气化炉105进行气化,气化后的还原剂混合物经过位于反应腔体110外部的气体分配室107 的分配而进入到各个还原剂输送管108中并通过输送管108上的喷嘴109被喷入到处于过渡段2内的反应腔体110之中,在其中还原剂与流过反应腔体110的热废气所含有的氮氧化物 (NOx)进行反应。Preferably, the reducing agent (such as liquid ammonia or ammonia water) stored in the reducing agent storage tank 101 is transported into the mixing chamber 104 under the suction of the pressure feeding pump 102 and the diluent (such as water or air or nitrogen) input therein After mixing, it is transported to the gasifier 105 for gasification. The gasified reducing agent mixture is distributed through the gas distribution chamber 107 located outside the reaction chamber 110 and enters into each reducing agent delivery pipe 108 and passes through the delivery pipe 108 The upper nozzle 109 is injected into the reaction chamber 110 in the transition section 2 where the reducing agent reacts with nitrogen oxides (NO x ) contained in the hot exhaust gas flowing through the reaction chamber 110 .

或,优选,在还原剂储存罐101中贮存的还原剂(例如液氨或氨水)在压力输送泵102的抽吸下被输送到混合室104中与输入其中的稀释剂(例如水或空气或氮气)进行混合,然后直接输送到位于反应腔体110内的气体分配室107中,然后进入到各个还原剂输送管108中并通过输送管108上的喷嘴109被喷入到处于过渡段2内的反应腔体110之中,在其中还原剂与流过反应腔体110的热废气所含有的氮氧化物(NOx)进行反应。Or, preferably, the reducing agent (such as liquid ammonia or ammonia water) stored in the reducing agent storage tank 101 is transported into the mixing chamber 104 under the suction of the pressure feeding pump 102 and the diluent (such as water or air or Nitrogen) for mixing, and then directly delivered to the gas distribution chamber 107 in the reaction chamber 110, and then into each reducing agent delivery pipe 108 and injected into the transition section 2 through the nozzle 109 on the delivery pipe 108 In the reaction chamber 110 of the reaction chamber 110 , the reducing agent reacts with nitrogen oxides (NO x ) contained in the hot exhaust gas flowing through the reaction chamber 110 .

优选,在气体分配室107中同时通入压缩空气和(气体形式的)还原剂混合物。Preferably, the compressed air and the reducing agent mixture (in gaseous form) are fed simultaneously into the gas distribution chamber 107 .

实施例1Example 1

如图2,一种链篦机-回转窑球团低NOx生产装置,它包括链篦机3,与链篦机3的末端相连的回转窑Kiln及位于回转窑Kiln的前端的环冷机C。并且,按照工艺走向,所述链篦机 3依次设置有鼓风干燥段UDD、抽风干燥段DDD、第一预热段TPH及第二预热段PH。环冷机C依次设置有第一冷却段C1、第二冷却段C2及第三冷却段C3,回转窑Kiln的尾端连接第二预热段PH和前端连接环冷机C的第一冷却段C1。As shown in Figure 2, a chain grate-rotary kiln pellet low NOx production device includes a chain grate 3, a rotary kiln Kiln connected to the end of the chain grate 3 and an annular cooler located at the front end of the rotary kiln Kiln C. Moreover, according to the process trend, the chain grate machine 3 is sequentially provided with a blast drying section UDD, a suction drying section DDD, a first preheating section TPH and a second preheating section PH. The ring cooler C is sequentially provided with a first cooling section C1, a second cooling section C2 and a third cooling section C3. The rear end of the rotary kiln Kiln is connected to the second preheating section PH and the front end is connected to the first cooling section of the ring cooler C. C1.

其中第二冷却段C2的出风口C2b经由第一管道L1连接至第一预热段TPH的进风口TPHa。第三冷却段C3的出风口C3b经由第二管道L2连接至鼓风干燥段UDD的底部风箱的进风口UDDa并且在第二管道L2上设有第一抽风机5。第二预热段PH的底部风箱的出风口 PHb经由第三管道L3连接至抽风干燥段DDD的顶部的进风口DDDa并且在第三管道L3设有第二抽风机6。从第一预热段TPH的底部风箱的出风口TPHb引出的第四管道L4连接至烟囱7并且在第四管道L4上设有第三抽风机8。从鼓风干燥段UDD的顶部的出风口UDDb引出的第五管道L5连接至烟囱7并且在第五管道L5上设有第四抽风机9。第一鼓风机10的出风口通过第六管道L6与第二冷却段C2的进风口C2a连接。第二鼓风机11的出风口通过第七管道L7与第三冷却段C3的进风口C3a连接。回转窑(Kiln)的前端配有回转窑鼓风机4 (或第三鼓风机),后者用于向前者的中央烧嘴输送助燃风。The air outlet C2b of the second cooling section C2 is connected to the air inlet TPHa of the first preheating section TPH via the first pipeline L1. The air outlet C3b of the third cooling section C3 is connected to the air inlet UDDa of the bottom bellows of the blast drying section UDD via the second duct L2 and a first exhaust fan 5 is provided on the second duct L2. The air outlet PHb of the bottom bellows of the second preheating section PH is connected to the air inlet DDDa at the top of the suction drying section DDD via the third duct L3 and a second suction fan 6 is provided in the third duct L3. The fourth duct L4 drawn from the air outlet TPHb of the bottom bellows of the first preheating stage TPH is connected to the chimney 7 and a third exhaust fan 8 is provided on the fourth duct L4. A fifth duct L5 drawn from the air outlet UDDb at the top of the blow drying section UDD is connected to the chimney 7 and a fourth exhaust fan 9 is provided on the fifth duct L5. The air outlet of the first blower 10 is connected to the air inlet C2a of the second cooling section C2 through the sixth duct L6. The air outlet of the second blower 11 is connected to the air inlet C3a of the third cooling section C3 through the seventh duct L7. The front end of the rotary kiln (Kiln) is equipped with a rotary kiln blower 4 (or a third blower), which is used to deliver combustion-supporting air to the former central burner.

该生产装置还包括从抽风干燥段DDD的底部风箱的出风口DDDb引出的第八管道L8,且第八管道L8连接至环冷机C的第一冷却段C1的进风口C1a,第八管道L8上设有第五鼓风机12。The production device also includes an eighth pipe L8 drawn from the air outlet DDDb of the bottom bellows of the extraction and drying section DDD, and the eighth pipe L8 is connected to the air inlet C1a of the first cooling section C1 of the ring cooler C, and the eighth pipe L8 A fifth blower 12 is provided thereon.

该生产装置还包括设置在第二预热段PH与回转窑Kiln之间的过渡段2,及设置在过渡段2的还原剂喷射装置1。The production device also includes a transition section 2 arranged between the second preheating section PH and the rotary kiln Kiln, and a reducing agent injection device 1 arranged in the transition section 2 .

如图4,还原剂喷射装置1包括依次连接的还原剂储存罐101、压力输送泵102、液体流量调节阀103、混合室104、气化炉105、气体流量调节阀106、气体分配室107及处于过渡段2内的反应腔体110。其中反应腔体110内设有还原剂输送管108,还原剂输送管108与气体分配室107连通且还原剂输送管108上设有喷嘴109。还原剂输送管108的数量为6根,每根还原剂输送管108上的喷嘴109的数量为10个。4, the reducing agent injection device 1 includes a reducing agent storage tank 101, a pressure delivery pump 102, a liquid flow regulating valve 103, a mixing chamber 104, a gasifier 105, a gas flow regulating valve 106, a gas distribution chamber 107 and The reaction chamber 110 in the transition section 2 . The reaction chamber 110 is provided with a reducing agent delivery pipe 108 , the reducing agent delivery pipe 108 communicates with the gas distribution chamber 107 and a nozzle 109 is provided on the reducing agent delivery pipe 108 . The number of reducing agent delivery pipes 108 is 6, and the number of nozzles 109 on each reducing agent delivery pipe 108 is 10.

实施例2Example 2

重复实施例1,只是如图3,该装置的抽风干燥段DDD进一步分成第一抽风干燥段DDD1 和第二抽风干燥段DDD2。其中第一抽风干燥段DDD1与鼓风干燥段UDD连接,第二抽风干燥段DDD2与第一预热段TPH连接。从第二抽风干燥段DDD2的底部风箱的出风口DDD2b 引出的第八管道L8连接至环冷机C的第一冷却段C1的进风口C1a。从第一抽风干燥段DDD1 的底部风箱的出风口DDD1b引出的第九管道L9与从第一预热段TPH的出风口TPHb引出的第四管道L4两者在合并之后连接至烟囱7。Example 1 is repeated, except that as shown in Figure 3, the suction drying section DDD of the device is further divided into a first suction drying section DDD1 and a second suction drying section DDD2. The first draft drying section DDD1 is connected with the blast drying section UDD, and the second draft drying section DDD2 is connected with the first preheating section TPH. The eighth pipe L8 drawn from the air outlet DDD2b of the bottom bellows of the second air extraction and drying section DDD2 is connected to the air inlet C1a of the first cooling section C1 of the ring cooler C. The ninth duct L9 drawn from the air outlet DDD1b of the bottom bellows of the first extraction and drying section DDD1 and the fourth duct L4 drawn from the air outlet TPHb of the first preheating section TPH are connected to the chimney 7 after being merged.

实施例3Example 3

重复实施例2,只是如图5,该装置的还原剂喷射装置1包括依次连接的还原剂储存罐 101、压力输送泵102、液体流量调节阀103、混合室104及处于过渡段2内的反应腔体110。其中反应腔体110内设有气体分配室107及与气体分配室107连通的还原剂输送管108,还原剂输送管108上设有喷嘴109。还原剂喷射装置1还包括设置在气体分配室107上的气体流量调节阀106。混合室104经由管道连通至位于反应腔体110内的气体分配室107,一般同时向气体分配室107中供应压缩空气和还原剂混合物。Example 2 is repeated, except that as shown in FIG. 5 , the reducing agent injection device 1 of the device includes a reducing agent storage tank 101 , a pressure delivery pump 102 , a liquid flow regulating valve 103 , a mixing chamber 104 and a reaction in the transition section 2 , which are connected in sequence. cavity 110 . The reaction chamber 110 is provided with a gas distribution chamber 107 and a reducing agent delivery pipe 108 communicating with the gas distribution chamber 107 , and a nozzle 109 is provided on the reducing agent delivery pipe 108 . The reducing agent injection device 1 also includes a gas flow regulating valve 106 provided on the gas distribution chamber 107 . The mixing chamber 104 communicates via conduits to a gas distribution chamber 107 located within the reaction chamber 110, and the compressed air and reducing agent mixture are generally supplied to the gas distribution chamber 107 at the same time.

实施例4Example 4

一种链篦机-回转窑球团低NOx方式生产方法,使用实施例1中的装置,该方法包括以下步骤:A method for producing a chain grate-rotary kiln pellet in a low NOx mode, using the device in Example 1, the method comprises the following steps:

1)铁矿的生球依次经过链篦机的鼓风干燥段UDD与抽风干燥段DDD被干燥、然后经过第一预热段TPH与第二预热段PH被加热,1) The raw balls of iron ore are dried in sequence through the blast drying section UDD and the exhaust drying section DDD of the chain grate machine, and then heated through the first preheating section TPH and the second preheating section PH,

2)加热后的铁矿球团进一步经过在第二预热段PH与回转窑Kiln之间的设有还原剂喷射装置1的过渡段2,其中在该过渡段2中,通过与流过过渡段2的热烟气逆向喷射还原性气体来让还原性气体与铁矿球团物料焙烧后产生的含有NOx的高温烟气进行充分混合和较长时间的反应,从而实现NOx的非催化还原来降低过渡段2的烟气中NOx的含量,和2) The heated iron ore pellets further pass through the transition section 2 provided with the reducing agent injection device 1 between the second preheating section PH and the rotary kiln Kiln, wherein in the transition section 2, the The hot flue gas in section 2 injects the reducing gas in reverse to make the reducing gas and the high-temperature flue gas containing NO x produced by the roasting of the iron ore pellets fully mixed and reacted for a long time, so as to realize the non-catalytic NO x reduction to reduce the NOx content in the flue gas of transition section 2, and

3)从过渡段2中输出的铁矿生球进入回转窑Kiln中进行焙烧,焙烧后经过环冷机C的冷却得到球团矿产品;3) the iron ore green pellets outputted from the transition section 2 enter the rotary kiln Kiln and carry out roasting, and obtain pellets through the cooling of the ring cooler C after the roasting;

其中,环冷机C的第一冷却段C1上部空间的风从回转窑Kiln的前端直接进入回转窑Kiln 中参与生球焙烧,然后流经第二预热段PH预热球团后进入抽风干燥段DDD对生球进行抽风干燥,随后抽风干燥段DDD下部的热废气经由第四管道L4向外排放至烟囱7或经由第八管道L8循环至第一冷却段C1的进风口;第二冷却段C2的风进入第一预热段TPH预热生球后向外排放至烟囱7;第三冷却段C3的风进入鼓风干燥段UDD对生球进行鼓风干燥后向外排放至烟囱7;从第二预热段PH的底部风箱抽出的风经由第三管道L3输送至抽风干燥段DDD的顶部的进风口DDDa。Among them, the air in the upper space of the first cooling section C1 of the ring cooler C directly enters the rotary kiln Kiln from the front end of the rotary kiln to participate in the roasting of green pellets, and then flows through the second preheating section PH to preheat the pellets and then enters the exhaust air drying. Section DDD carries out suction drying on the raw balls, and then the hot waste gas at the lower part of the suction drying section DDD is discharged to the chimney 7 through the fourth pipeline L4 or circulated to the air inlet of the first cooling section C1 through the eighth pipeline L8; the second cooling section The wind of C2 enters the first preheating section TPH to preheat the green balls and then discharges to the chimney 7; the wind of the third cooling section C3 enters the blast drying section UDD to blast and dry the green balls and then discharges to the chimney 7; The air drawn from the bottom wind box of the second preheating section PH is delivered to the air inlet DDDa at the top of the suction drying section DDD through the third duct L3.

其中,在还原剂储存罐101中贮存的还原剂(例如液氨)在压力输送泵102的抽吸下被输送到混合室104中与输入其中的稀释剂(例如水或空气)进行混合,然后输送到气化炉105进行气化,气化后的还原剂混合物经过位于反应腔体110外部的气体分配室107的分配而进入到各个还原剂输送管108中并通过输送管108上的喷嘴109被喷入到处于过渡段2内的反应腔体110之中,在其中还原剂与流过反应腔体110的热废气所含有的氮氧化物(NOx)进行反应。在气体分配室107中同时通入压缩空气和(气体形式的)还原剂混合物。The reducing agent (such as liquid ammonia) stored in the reducing agent storage tank 101 is transported to the mixing chamber 104 under the suction of the pressure feeding pump 102 to be mixed with the diluent (such as water or air) input into it, and then It is transported to the gasifier 105 for gasification, and the gasified reducing agent mixture is distributed through the gas distribution chamber 107 located outside the reaction chamber 110 and enters each reducing agent delivery pipe 108 and passes through the nozzle 109 on the delivery pipe 108 It is injected into the reaction chamber 110 in the transition section 2 where the reducing agent reacts with nitrogen oxides (NO x ) contained in the hot exhaust gas flowing through the reaction chamber 110 . The compressed air and the reducing agent mixture (in gaseous form) are simultaneously fed into the gas distribution chamber 107 .

实施例5Example 5

一种链篦机-回转窑球团低NOx生产方法,使用实施例2中的装置,该方法包括以下步骤:A kind of chain grate-rotary kiln pellet low NOx production method, using the device in embodiment 2, the method comprises the following steps:

1)铁矿的生球依次经过链篦机的鼓风干燥段UDD与抽风干燥段DDD被干燥、然后经过第一预热段TPH与第二预热段PH被加热,1) The raw balls of iron ore are dried in sequence through the blast drying section UDD and the exhaust drying section DDD of the chain grate machine, and then heated through the first preheating section TPH and the second preheating section PH,

2)加热后的铁矿球团进一步经过在第二预热段PH与回转窑Kiln之间的设有还原剂喷射装置1的过渡段2,其中在该过渡段2中,通过与流过过渡段2的热烟气逆向喷射还原性气体来让还原性气体与铁矿球团物料焙烧后产生的含有NOx的高温烟气进行充分混合和较长时间的反应,从而实现NOx的非催化还原来降低过渡段2的烟气中NOx的含量,和2) The heated iron ore pellets further pass through the transition section 2 provided with the reducing agent injection device 1 between the second preheating section PH and the rotary kiln Kiln, wherein in the transition section 2, the The hot flue gas in section 2 injects the reducing gas in reverse to make the reducing gas and the high-temperature flue gas containing NO x produced by the roasting of the iron ore pellets fully mixed and reacted for a long time, so as to realize the non-catalytic NO x reduction to reduce the NOx content in the flue gas of transition section 2, and

3)从过渡段2中输出的铁矿生球进入回转窑Kiln中进行焙烧,焙烧后经过环冷机C的冷却得到球团矿产品;3) the iron ore green pellets outputted from the transition section 2 enter the rotary kiln Kiln and carry out roasting, and obtain pellets through the cooling of the ring cooler C after the roasting;

其中,第一冷却段C1的风从回转窑Kiln的前端直接进入回转窑Kiln参与球团焙烧,然后流经第二预热段PH预热球团后进入抽风干燥段DDD对生球进行抽风干燥;抽风干燥段 DDD进一步分成第一抽风干燥段DDD1和第二抽风干燥段DDD2,第二抽风干燥段DDD2 的热废气经由第八管道L8循环至第一冷却段C1,而第一抽风干燥段DDD1的热废气经由第四管道L4向外排放至烟囱7;第二冷却段C2的风进入第一预热段TPH预热生球后向外排放至烟囱7;第三冷却段C3的风进入鼓风干燥段UDD对生球进行鼓风干燥后向外排放至烟囱 7;从第二预热段PH的底部风箱抽出的风经由第三管道L3输送至抽风干燥段DDD的顶部的进风口DDDa。Among them, the air in the first cooling section C1 directly enters the rotary kiln Kiln from the front end of the rotary kiln Kiln to participate in the pellet roasting, and then flows through the second preheating section PH to preheat the pellets and then enters the draft drying section DDD for draft drying of the green pellets. The suction drying section DDD is further divided into the first suction drying section DDD1 and the second suction drying section DDD2, the hot waste gas of the second suction drying section DDD2 is circulated to the first cooling section C1 through the eighth pipeline L8, and the first suction drying section DDD1 The hot exhaust gas is discharged to the chimney 7 through the fourth pipe L4; the wind of the second cooling section C2 enters the first preheating section TPH to preheat the green balls and is discharged to the chimney 7; the wind of the third cooling section C3 enters the chimney 7. The air drying section UDD blows and dries the raw balls and then discharges them to the chimney 7; the air drawn from the bottom bellows of the second preheating section PH is transported to the air inlet DDDa at the top of the draft drying section DDD through the third duct L3.

其中,在还原剂储存罐101中贮存的还原剂(例如液氨)在压力输送泵102的抽吸下被输送到混合室104中与输入其中的稀释剂(例如水或空气)进行混合,然后输送到气化炉105进行气化,气化后的还原剂混合物经过位于反应腔体110外部的气体分配室107的分配而进入到各个还原剂输送管108中并通过输送管108上的喷嘴109被喷入到处于过渡段2内的反应腔体110之中,在其中还原剂与流过反应腔体110的热废气所含有的氮氧化物(NOx)进行反应。在气体分配室107中同时通入压缩空气和(气体形式的)还原剂混合物。The reducing agent (such as liquid ammonia) stored in the reducing agent storage tank 101 is transported to the mixing chamber 104 under the suction of the pressure feeding pump 102 to be mixed with the diluent (such as water or air) input into it, and then It is transported to the gasifier 105 for gasification, and the gasified reducing agent mixture is distributed through the gas distribution chamber 107 located outside the reaction chamber 110 and enters each reducing agent delivery pipe 108 and passes through the nozzle 109 on the delivery pipe 108 It is injected into the reaction chamber 110 in the transition section 2 where the reducing agent reacts with nitrogen oxides (NO x ) contained in the hot exhaust gas flowing through the reaction chamber 110 . The compressed air and the reducing agent mixture (in gaseous form) are simultaneously fed into the gas distribution chamber 107 .

实施例6Example 6

重复实施例5,只是:其中,在还原剂储存罐101中贮存的还原剂(例如液氨)在压力输送泵102的抽吸下被输送到混合室104中与输入其中的稀释剂(例如水或空气)进行混合,然后直接输送到位于反应腔体110内的气体分配室107中,然后进入到各个还原剂输送管108中并通过输送管108上的喷嘴109被喷入到处于过渡段2内的反应腔体110之中,在其中还原剂与流过反应腔体110的热废气所含有的氮氧化物(NOx)进行反应。在气体分配室107中同时通入压缩空气和(气体形式的)还原剂混合物。Example 5 is repeated, except: wherein the reducing agent (eg liquid ammonia) stored in the reducing agent storage tank 101 is transported into the mixing chamber 104 under the suction of the pressure delivery pump 102 and the diluent (eg water) input therein or air) for mixing, and then directly delivered to the gas distribution chamber 107 in the reaction chamber 110, and then into each reducing agent delivery pipe 108 and injected into the transition section 2 through the nozzle 109 on the delivery pipe 108 Inside the reaction chamber 110 , in which the reducing agent reacts with nitrogen oxides (NO x ) contained in the hot exhaust gas flowing through the reaction chamber 110 . The compressed air and the reducing agent mixture (in gaseous form) are simultaneously fed into the gas distribution chamber 107 .

Claims (20)

1. Grate-rotary kiln pellet low NOxThe production device comprises a chain grate (3), a rotary Kiln (Kiln) connected with the tail end of the chain grate (3) and a ring cooling machine (C) connected with the front end of the rotary Kiln (Kiln), wherein the chain grate (3) is sequentially provided with an air blowing drying section (UDD), an air blowing drying section (DDD), a first preheating section (TPH) and a second preheating section (PH) according to the process trend, the ring cooling machine (C) is sequentially provided with a first cooling section (C1), a second cooling section (C2) and a third cooling section (C3), and the tail end of the rotary Kiln (Kiln) is connected with the second preheating section (PH) of the chain grate (3) and the first cooling section (C1) of the ring cooling machine (C) at the other end;
wherein the air outlet (C2b) of the second cooling section (C2) is connected via a first conduit (L1) to the air inlet (TPHa) of the first preheating section (TPH), the air outlet (C3b) of the third cooling section (C3) is connected via a second conduit (L2) to the air inlet (UDDa) of the bottom windbox of the forced air drying section (UDD) and is provided with a first suction fan (5) on a second conduit (L2), the air outlet (PHb) of the bottom windbox of the second preheating section (PH) is connected via a third conduit (L3) to the air inlet (DDDa) at the top of the forced air drying section (DDD) and is provided with a second suction fan (6) on a third conduit (L3), a fourth conduit (L4) leading from the air outlet (TPHb) of the bottom windbox of the first preheating section (TPH) is connected to a chimney (7) and is provided with a third suction fan (8) on a fourth conduit (L4), the air outlet (TPHb) of the forced air drying section (TPH) is connected to a chimney (dhb) and is connected to a fifth conduit (dhl 5) at the top of the chimney (dh A fourth exhaust fan (9) is arranged on the passage (L5), an air outlet of the first air blower (10) is connected with an air inlet (C2a) of the second cooling section (C2) through a sixth pipeline (L6), and an air outlet of the second air blower (11) is connected with an air inlet (C3a) of the third cooling section (C3) through a seventh pipeline (L7);
the method is characterized in that: the production device also comprises a transition section (2) arranged between the second preheating section (PH) and the rotary Kiln (Kiln), and a reducing agent injection device (1) arranged on the transition section (2);
the production device also comprises an eighth pipeline (L8) led out from an air outlet (DDDb) of the bottom bellows of the air draft drying section (DDD), the eighth pipeline (L8) is connected to an air inlet (C1a) of the first cooling section (C1) of the ring cooling machine (C), and a fifth air blower (12) is arranged on the eighth pipeline (L8).
2. The apparatus of claim 1, wherein: the reducing agent injection device (1) comprises a reducing agent storage tank (101), a pressure delivery pump (102), a mixing chamber (104), a gasification furnace (105), a gas distribution chamber (107) and a reaction cavity (110) in a transition section (2), wherein the reaction cavity (110) is internally provided with a reducing agent delivery pipe (108), the reducing agent delivery pipe (108) is communicated with the gas distribution chamber (107), and the reducing agent delivery pipe (108) is provided with a nozzle (109).
3. The apparatus of claim 1, wherein: the reducing agent injection device (1) comprises a reducing agent storage tank (101), a pressure delivery pump (102), a mixing chamber (104) and a reaction cavity (110) located in a transition section (2), wherein the reaction cavity (110) is internally provided with a gas distribution chamber (107) and a reducing agent delivery pipe (108) communicated with the gas distribution chamber (107), the reducing agent delivery pipe (108) is provided with a nozzle (109), and the mixing chamber (104) is communicated to the gas distribution chamber (107) located in the reaction cavity (110) through a pipeline.
4. The apparatus of claim 2 or 3, wherein: the reducing agent injection device (1) further comprises a liquid flow regulating valve (103) arranged between the pressure delivery pump (102) and the mixing chamber (104).
5. The apparatus of claim 2, wherein: the reducing agent injection device (1) further comprises a gas flow regulating valve (106) arranged between the gasification furnace (105) and the gas distribution chamber (107).
6. The apparatus of claim 3, wherein: the reducing agent injection device (1) further includes an air supply pipe (106a) and a gas flow rate adjustment valve (106) provided on the gas distribution chamber (107).
7. The apparatus of any one of claims 1-3, 5-6, wherein: the air draft drying section (DDD) is further divided into a first air draft drying section (DDD1) and a second air draft drying section (DDD2), wherein the first air draft drying section (DDD1) is connected with the air blast drying section (UDD), the second air draft drying section (DDD2) is connected with the first preheating section (TPH), an eighth pipeline (L8) led out from an air outlet (DDD2b) of a bottom bellows of the second air draft drying section (DDD2) is connected to an air inlet (C1a) of a first cooling section (C1) of the ring cooling machine (C), and a ninth pipeline (L9) led out from an air outlet (DDD1b) of the bottom bellows of the first air draft drying section (DDD1) and a fourth pipeline (L4) led out from an air outlet (TPHb) of the first preheating section (TPH) are connected to a chimney (7) after being combined or joined.
8. The apparatus of claim 4, wherein: the air draft drying section (DDD) is further divided into a first air draft drying section (DDD1) and a second air draft drying section (DDD2), wherein the first air draft drying section (DDD1) is connected with the air blast drying section (UDD), the second air draft drying section (DDD2) is connected with the first preheating section (TPH), an eighth pipeline (L8) led out from an air outlet (DDD2b) of a bottom bellows of the second air draft drying section (DDD2) is connected to an air inlet (C1a) of a first cooling section (C1) of the ring cooling machine (C), and a ninth pipeline (L9) led out from an air outlet (DDD1b) of the bottom bellows of the first air draft drying section (DDD1) and a fourth pipeline (L4) led out from an air outlet (TPHb) of the first preheating section (TPH) are connected to a chimney (7) after being combined or joined.
9. The apparatus of any one of claims 2-3, 5-6, 8, wherein: the reducing agent delivery pipes (108) are divided into front and rear 1-3 rows, and the number of the reducing agent delivery pipes (108) in each row is 2-15.
10. The apparatus of claim 4, wherein: the reducing agent delivery pipes (108) are divided into front and rear 1-3 rows, and the number of the reducing agent delivery pipes (108) in each row is 2-15.
11. The apparatus of claim 9, wherein: the reducing agent delivery pipes (108) are divided into front and rear 1-3 rows, and the number of the reducing agent delivery pipes (108) in each row is 3-10.
12. The apparatus of claim 10, wherein: the reducing agent delivery pipes (108) are divided into front and rear 1-3 rows, and the number of the reducing agent delivery pipes (108) in each row is 3-10.
13. The apparatus of claim 9, wherein: the number of the nozzles (109) on each reducing agent delivery pipe (108) is 2-20.
14. The apparatus according to any one of claims 10-12, wherein: the number of the nozzles (109) on each reducing agent delivery pipe (108) is 2-20.
15. The apparatus of claim 13, wherein: the number of the nozzles (109) on each reducing agent delivery pipe (108) is 4-15.
16. The apparatus of claim 14, wherein: the number of the nozzles (109) on each reducing agent delivery pipe (108) is 4-15.
17. Grate-rotary kiln pellet low NOxMethod of production or use of grate-kiln pellets according to any of claims 1-16 for low NOxA method for producing pellets in a production facility, the method comprising the steps of:
1) the raw pellets of the iron ore are dried by a blast drying section (UDD) and a draft drying section (DDD) of a chain grate in sequence, and then heated by a first preheating section (TPH) and a second preheating section (PH),
2) the heated iron ore green pellets further pass through a transition section (2) which is arranged between a second preheating section (PH) and a rotary Kiln (Kiln) and is provided with a reducing agent injection device (1), wherein in the transition section (2), reducing gas and NO-containing gas above the roasted iron ore pellet materials are sprayed by the reducing gas in a reverse direction with hot flue gas flowing through the transition section (2)xThe high-temperature flue gas is fully mixed and reacted for a longer time, thereby realizing NOxTo reduce NO in the flue gas of the transition section (2)xIn an amount of, and
3) the iron ore pellets output from the transition section (2) enter a rotary Kiln (Kiln) for roasting, and are cooled by a circular cooler (C) after roasting to obtain pellet products;
wherein, the air in the upper space of the first cooling section (C1) of the circular cooler (C) directly enters the rotary Kiln (Kiln) from the front end of the rotary Kiln (Kiln) to participate in pellet roasting, then flows through the second preheating section (PH) to preheat pellets, then enters the air draft drying section (DDD) to perform air draft drying on the pellets, and then the hot waste gas at the lower part of the air draft drying section (DDD) is discharged outwards to a chimney (7) through a fourth pipeline (L4) or circulates to the air inlet of the first cooling section (C1) through an eighth pipeline (L8); the wind of the second cooling section (C2) enters the first preheating section (TPH) to preheat green pellets and then is discharged to a chimney (7); air of the third cooling section (C3) enters a blast drying section (UDD) to blast dry the green pellets and then is discharged to a chimney (7); the air drawn out of the bottom windbox of the second preheating stage (PH) is conveyed via a third duct (L3) to an air inlet (DDDa) at the top of the updraft drying stage (DDD).
18. The method of claim 17, wherein the updraft drying section (DDD) is further divided into a first updraft drying section (DDD1) and a second updraft drying section (DDD2), hot exhaust gas of the second updraft drying section (DDD2) being recycled to the first cooling section (C1) via an eighth duct (L8), and hot exhaust gas of the first updraft drying section (DDD1) being discharged outwardly to the chimney (7) via a fourth duct (L4).
19. The method according to claim 17 or 18, characterized in that: the reducing agent stored in the reducing agent storage tank (101) is conveyed into a mixing chamber (104) under the suction of a pressure conveying pump (102) to be mixed with the diluent input into the mixing chamber, then conveyed into a gasification furnace (105) to be gasified, the gasified reducing agent mixture enters into each reducing agent conveying pipe (108) through the distribution of a gas distribution chamber (107) positioned outside a reaction cavity (110) and is sprayed into the reaction cavity (110) in a transition section (2) through a nozzle (109) on the conveying pipe (108), and the reducing agent and Nitrogen Oxides (NO) contained in hot waste gas flowing through the reaction cavity (110) are in the reducing agent storage tank and the Nitrogen Oxides (NO) contained in the hot waste gas flowing through the reaction cavity (110)x) Carrying out reaction; or
The reducing agent stored in the reducing agent storage tank (101) is conveyed into a mixing chamber (104) under the suction of a pressure conveying pump (102) to be mixed with the diluent fed into the mixing chamber, then is directly conveyed into a gas distribution chamber (107) positioned in a reaction cavity (110), finally enters into each reducing agent conveying pipe (108) and is sprayed into the reaction cavity (110) in a transition section (2) through a nozzle (109) on the conveying pipe (108), wherein the reducing agent and Nitrogen Oxides (NO) contained in hot exhaust gas flowing through the reaction cavity (110)x) The reaction is carried out.
20. The method of claim 19, wherein: compressed air is introduced into the gas distribution chamber (107).
CN201710456579.6A 2017-06-16 2017-06-16 Chain grate machine-rotary kiln pellet low NOx production device and pellet production method Active CN109141028B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710456579.6A CN109141028B (en) 2017-06-16 2017-06-16 Chain grate machine-rotary kiln pellet low NOx production device and pellet production method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710456579.6A CN109141028B (en) 2017-06-16 2017-06-16 Chain grate machine-rotary kiln pellet low NOx production device and pellet production method

Publications (2)

Publication Number Publication Date
CN109141028A CN109141028A (en) 2019-01-04
CN109141028B true CN109141028B (en) 2020-07-03

Family

ID=64830360

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710456579.6A Active CN109141028B (en) 2017-06-16 2017-06-16 Chain grate machine-rotary kiln pellet low NOx production device and pellet production method

Country Status (1)

Country Link
CN (1) CN109141028B (en)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110129501B (en) * 2019-06-10 2020-10-27 成渝钒钛科技有限公司 Technical improvement method for optimizing nitrate reduction of vanadium-titanium pellet fuel gas
CN113908677B (en) * 2020-07-10 2022-12-06 中冶长天国际工程有限责任公司 Flue gas treatment process and treatment system
CN113916010B (en) * 2020-07-10 2023-11-10 中冶长天国际工程有限责任公司 Rotary kiln-grate machine flue gas treatment process and system for flue gas treatment
CN113477050A (en) * 2021-08-06 2021-10-08 江苏鑫华能环保工程股份有限公司 A dry-type denitrification facility for pelletizing production line
CN114622051B (en) * 2021-12-30 2023-03-14 中冶长天国际工程有限责任公司 Direct reduction method and device for iron-containing pellets based on internal circulation of hot air at each section of rotary kiln
CN115216574B (en) * 2022-01-25 2023-10-03 中冶长天国际工程有限责任公司 Direct reduction process and direct reduction device for iron-containing composite pellets
CN115046387A (en) * 2022-04-24 2022-09-13 中国科学院过程工程研究所 High-proportion circulating reduction system and method for flue gas generated by roasting pellets in grate-rotary kiln

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101024845B1 (en) * 2010-07-14 2011-03-24 주식회사 기스코 Regeneration of Denitration Catalyst Using Dry Ice
CN102252530A (en) * 2011-07-15 2011-11-23 中冶北方工程技术有限公司 Novel waste heat utilization and emission reduction process for hot air systems of chain grate machine, rotary kiln and circular cooler
CN106268270A (en) * 2016-10-21 2017-01-04 福建龙净脱硫脱硝工程有限公司 A kind of grate kiln denitrating system

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101024845B1 (en) * 2010-07-14 2011-03-24 주식회사 기스코 Regeneration of Denitration Catalyst Using Dry Ice
CN102252530A (en) * 2011-07-15 2011-11-23 中冶北方工程技术有限公司 Novel waste heat utilization and emission reduction process for hot air systems of chain grate machine, rotary kiln and circular cooler
CN106268270A (en) * 2016-10-21 2017-01-04 福建龙净脱硫脱硝工程有限公司 A kind of grate kiln denitrating system

Also Published As

Publication number Publication date
CN109141028A (en) 2019-01-04

Similar Documents

Publication Publication Date Title
CN109141028B (en) Chain grate machine-rotary kiln pellet low NOx production device and pellet production method
CN109136545B (en) Grate-rotary kiln pellet low NOxProduction process and system thereof
CN109373767B (en) A production process and system for ultra-low NOx emission from pellet flue gas
CN109055721B (en) Grate-rotary kiln pellet low NOxProduction process and system
CN109136544B (en) Grate-rotary kiln pellet low NOxProduction process and system thereof
CN110614025A (en) Denitration treatment system and method for pellet roasting flue gas of rotary kiln of chain grate
CN209197491U (en) A kind of production system of pelletizing flue gas ultra-low NOx emission
CN209854219U (en) Grate-rotary kiln pellet low NOx emission system
CN207163232U (en) The low NOx process units of grate-kiln pelletizing process
CN110894573B (en) Production process and system for oxidizing pellets by using grate-rotary kiln system
CN211367682U (en) Grate-rotary kiln system
CN110894574B (en) A kind of chain grate machine, chain grate machine rotary kiln oxidation pellet denitrification system and method
CN109569183B (en) Comprehensive circulation treatment method and treatment device for flue gas of double-series sintering system
CN109813129A (en) A kind of pellet production process and preparation system based on tail gas circulating O2-CO2 combustion
CN209386821U (en) A kind of production system of pelletizing flue gas ultra-low NOx emission
CN211367681U (en) Novel rotary kiln system and pellet upgrading low-oxygen low-NOx production system
CN209386820U (en) A kind of production system of pelletizing flue gas ultra-low NOx emission
CN107029554B (en) Flue gas circulation denitration system based on sintering flue gas autocatalysis
CN106807193A (en) A kind of flue-gas denitration process system
CN211373267U (en) System for pelletizing ring cooling waste gas waste heat high-efficient utilization
CN209960990U (en) Grate-rotary kiln pellet low NOx production system
CN108043213A (en) System and method for denitrification transformation of industrial kiln
CN209188501U (en) The system of NOx in a kind of efficient removal pelletizing flue gas
CN210922235U (en) Production system for efficiently utilizing waste heat of pellet ring cooling waste gas
CN207970688U (en) An industrial kiln denitrification transformation system

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant