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CN109130423A - A kind of bacteriostatic antistatic wood bamboo-plastic floorboard and preparation method thereof - Google Patents

A kind of bacteriostatic antistatic wood bamboo-plastic floorboard and preparation method thereof Download PDF

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Publication number
CN109130423A
CN109130423A CN201810781657.4A CN201810781657A CN109130423A CN 109130423 A CN109130423 A CN 109130423A CN 201810781657 A CN201810781657 A CN 201810781657A CN 109130423 A CN109130423 A CN 109130423A
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CN
China
Prior art keywords
parts
wood bamboo
antibacterial agent
functional layer
antioxidant
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810781657.4A
Other languages
Chinese (zh)
Inventor
袁俊
钱海庆
薛华
蒋蓉
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangsu Fuhua New Material Technology Co Ltd
Original Assignee
Jiangsu Fuhua New Material Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jiangsu Fuhua New Material Technology Co Ltd filed Critical Jiangsu Fuhua New Material Technology Co Ltd
Priority to CN201810781657.4A priority Critical patent/CN109130423A/en
Publication of CN109130423A publication Critical patent/CN109130423A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/36Layered products comprising a layer of synthetic resin comprising polyesters
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B21/00Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B21/00Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board
    • B32B21/04Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board comprising wood as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/18Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by features of a layer of foamed material
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/02Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/04Antistatic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/06Properties of polyethylene
    • C08L2207/066LDPE (radical process)

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention proposes a kind of bacteriostatic antistatic wood bamboo-plastic floorboard, functional layer, UV coating, flower-pattern layer, wood bamboo including setting gradually from outside to inside mould foaming layer;The proportion of each ingredient is respectively as follows: 35 parts of polyethylene terephthalate, 1-1.4 parts of low density polyethylene (LDPE), 0.5-4 parts of nm-class active calcium carbonate, 0.5-1.3 parts of epoxy aliphatic acid methyl ester, 150-193 parts of isothiazolinone, 116 parts of silver ion modified Nano antibacterial agent, 3-5 parts of antioxidant, 7 parts of dodecanediol amide in the functional layer.The inorganic antiseptic that floor of the invention uses nanotechnology modified, it is small with partial size, the features such as large specific surface area, there are a large amount of dangling bond and unsaturated bond in surface, increase the contact area with bacterium, nano antibacterial agent can penetrate the cell wall of bacterium and enter in cell body simultaneously, destroy the activity of cell synzyme, make cell loss division growth ability and dead.

Description

A kind of bacteriostatic antistatic wood bamboo-plastic floorboard and preparation method thereof
Technical field
The present invention relates to a kind of bacteriostatic antistatic wood bamboo-plastic floorboards.
Background technique
Plastic floor, i.e., the floor being laid with plastic material.For the shelf-life for extending floor, plastic floor uses shape by it State can be divided into two kinds of bulk (or floor tile) and coiled material (or flooring laminate).The major advantage of floor tile: in use, such as go out Existing local damage, can appearance of the local replacing without influencing entire ground.But seam is more, and speed of application is slower.Flooring laminate Major advantage: laying speed is fast, and seam is few.For thicker coiled material, adhesive can not had to and be directly layered in base.But part It is inconvenient that breakage is repaired, and all waste lot of materials, plastic floor can be divided into polyvinyl chloride (PVC) by its base stock and mould again for replacement Material, polyethylene (PE) plastics and polypropylene (PP) plastics etc. are several.
Currently, for plastic floor there are the disadvantages of antistatic, fungistatic effect is poor, therefore, it is necessary to develop a kind of anti-ageing in the world The property changed, antistatic, anti odour bacteriostatic, weatherability, toughness, the preferable floor of wearability.
Summary of the invention
The technical problem to be solved by the present invention is to overcome the defects of the prior art, provide a kind of bacteriostatic antistatic wood bamboo modeling ground Plate.
In order to solve the above-mentioned technical problems, the present invention provides the following technical solutions:
A kind of bacteriostatic antistatic wood bamboo-plastic floorboard of the present invention, including set gradually from outside to inside functional layer, UV coating, decorative pattern Layer, wood bamboo mould foaming layer;The proportion of each ingredient is respectively as follows: 35 parts of polyethylene terephthalate, low close in the functional layer Spend polyethylene 1-1.4 parts, 0.5-4 parts of nm-class active calcium carbonate, 0.5-1.3 parts of epoxy aliphatic acid methyl ester, isothiazolinone 150- 193 parts, 116 parts of silver ion modified Nano antibacterial agent, 3-5 parts of antioxidant, 7 parts of dodecanediol amide.
Further, the proportion of each ingredient is respectively as follows: 35 parts of polyethylene terephthalate, low close in the functional layer 1 part of polyethylene of degree, 0.5 part of nm-class active calcium carbonate, 0.5 part of epoxy aliphatic acid methyl ester, 150 parts of isothiazolinone, silver ion change Property 116 parts of nano antibacterial agent, 3 parts of antioxidant, 7 parts of dodecanediol amide.
Further, the proportion of each ingredient is respectively as follows: 35 parts of polyethylene terephthalate, low close in the functional layer 1.1 parts of polyethylene of degree, 1 part of nm-class active calcium carbonate, 0.7 part of epoxy aliphatic acid methyl ester, 193 parts of isothiazolinone, silver ion change Property 116 parts of nano antibacterial agent, 5 parts of antioxidant, 7 parts of dodecanediol amide.
Further, 35 parts of polyethylene terephthalate, 1.2 parts of low density polyethylene (LDPE), nm-class active calcium carbonate 2 Part, 0.9 part of epoxy aliphatic acid methyl ester, 180 parts of isothiazolinone, 116 parts of silver ion modified Nano antibacterial agent, 4 parts of antioxidant, ten 7 parts of two alkylolamides of dialkyl group.
Further, 35 parts of polyethylene terephthalate, 1.3 parts of low density polyethylene (LDPE), nm-class active calcium carbonate 3 Part, 1.1 parts of epoxy aliphatic acid methyl ester, 150 parts of isothiazolinone, 116 parts of silver ion modified Nano antibacterial agent, 5 parts of antioxidant, ten 7 parts of two alkylolamides of dialkyl group.
Further, 35 parts of polyethylene terephthalate, 1.4 parts of low density polyethylene (LDPE), nm-class active calcium carbonate 4 Part, 1.3 parts of epoxy aliphatic acid methyl ester, 193 parts of isothiazolinone, 116 parts of silver ion modified Nano antibacterial agent, 3 parts of antioxidant, ten 7 parts of two alkylolamides of dialkyl group.
The invention has the benefit that
Bacteriostatic antistatic wood bamboo-plastic floorboard produced by the present invention have fabulous high and low temperature resistance, superpower acid-proof alkaline, The performances such as wear-resisting, impact resistance.The inorganic antiseptic that floor of the invention uses nanotechnology modified has partial size small, than There are a large amount of dangling bond and unsaturated bond in the features such as surface area is big, surface, increase the contact area with bacterium, while nano-antibacterial The cell wall that agent can penetrate bacterium enters in cell body, destroys the activity of cell synzyme, makes cell loss division growth ability And it is dead.Therefore, have excellent antibacterial effect, and it is safe and non-toxic, timeliness is long, had good sustained release effect, improve floor packaging peace Quan Xing, extends the shelf-life, and antistatic property is excellent.
Specific embodiment
Hereinafter, preferred embodiments of the present invention will be described, it should be understood that preferred embodiment described herein is only used In the description and interpretation present invention, it is not intended to limit the present invention.
Bacteriostatic antistatic wood bamboo-plastic floorboard of the invention includes the functional layer set gradually from outside to inside, UV coating, decorative pattern Layer, wood bamboo mould foaming layer;The proportion of each ingredient is respectively as follows: 35 parts of polyethylene terephthalate, low close in the functional layer Spend polyethylene 1-1.4 parts, 0.5-4 parts of nm-class active calcium carbonate, 0.5-1.3 parts of epoxy aliphatic acid methyl ester.
When it is implemented, the proportion of each ingredient of first embodiment of bacteriostatic antistatic wood bamboo-plastic floorboard of the invention is distinguished Are as follows: 35 parts of polyethylene terephthalate, 1 part of low density polyethylene (LDPE), 0.5 part of nm-class active calcium carbonate, epoxyfatty acid first 0.5 part of ester, 150 parts of isothiazolinone, 116 parts of silver ion modified Nano antibacterial agent, 3 parts of antioxidant, dodecanediol amide 7 Part.
The proportion of each ingredient of second embodiment of bacteriostatic antistatic wood bamboo-plastic floorboard of the invention is respectively as follows: poly- to benzene two 35 parts of formic acid glycol ester, 1.1 parts of low density polyethylene (LDPE), 1 part of nm-class active calcium carbonate, 0.7 part of epoxy aliphatic acid methyl ester, different thiophene 193 parts of oxazoline ketone, 116 parts of silver ion modified Nano antibacterial agent, 5 parts of antioxidant, 7 parts of dodecanediol amide.
The proportion of each ingredient of third embodiment of bacteriostatic antistatic wood bamboo-plastic floorboard of the invention is respectively as follows: poly- to benzene two 35 parts of formic acid glycol ester, 1.2 parts of low density polyethylene (LDPE), 2 parts of nm-class active calcium carbonate, 0.9 part of epoxy aliphatic acid methyl ester, different thiophene 180 parts of oxazoline ketone, 116 parts of silver ion modified Nano antibacterial agent, 4 parts of antioxidant, 7 parts of dodecanediol amide.
The proportion of 4th each ingredient of embodiment of bacteriostatic antistatic wood bamboo-plastic floorboard of the invention is respectively as follows: poly- to benzene two 35 parts of formic acid glycol ester, 1.3 parts of low density polyethylene (LDPE), 3 parts of nm-class active calcium carbonate, 1.1 parts of epoxy aliphatic acid methyl ester, different thiophene 150 parts of oxazoline ketone, 116 parts of silver ion modified Nano antibacterial agent, 5 parts of antioxidant, 7 parts of dodecanediol amide.
The proportion of 5th each ingredient of embodiment of bacteriostatic antistatic wood bamboo-plastic floorboard of the invention is respectively as follows: poly- to benzene two 35 parts of formic acid glycol ester, 1.4 parts of low density polyethylene (LDPE), 4 parts of nm-class active calcium carbonate, 1.3 parts of epoxy aliphatic acid methyl ester, different thiophene 193 parts of oxazoline ketone, 116 parts of silver ion modified Nano antibacterial agent, 3 parts of antioxidant, 7 parts of dodecanediol amide.
Finally, it should be noted that the foregoing is only a preferred embodiment of the present invention, it is not intended to restrict the invention, Although the present invention is described in detail referring to the foregoing embodiments, for those skilled in the art, still may be used To modify the technical solutions described in the foregoing embodiments or equivalent replacement of some of the technical features. All within the spirits and principles of the present invention, any modification, equivalent replacement, improvement and so on should be included in of the invention Within protection scope.

Claims (7)

1. a kind of bacteriostatic antistatic wood bamboo-plastic floorboard, which is characterized in that including set gradually from outside to inside functional layer, UV apply Layer, flower-pattern layer, wood bamboo mould foaming layer;The proportion of each ingredient is respectively as follows: polyethylene terephthalate 35 in the functional layer Part, 1-1.4 parts of low density polyethylene (LDPE), 0.5-4 parts of nm-class active calcium carbonate, 0.5-1.3 parts of epoxy aliphatic acid methyl ester, isothiazoline 150-193 parts of ketone, 116 parts of silver ion modified Nano antibacterial agent, 3-5 parts of antioxidant, 7 parts of dodecanediol amide.
2. bacteriostatic antistatic wood bamboo-plastic floorboard as described in claim 1, it is characterised in that: each ingredient matches in the functional layer Than being respectively as follows: 35 parts of polyethylene terephthalate, 1 part of low density polyethylene (LDPE), 0.5 part of nm-class active calcium carbonate, epoxy rouge 0.5 part of fatty acid methyl esters, 150 parts of isothiazolinone, 116 parts of silver ion modified Nano antibacterial agent, 3 parts of antioxidant, dodecyl two 7 parts of alkylolamides.
3. bacteriostatic antistatic wood bamboo-plastic floorboard as described in claim 1, it is characterised in that: each ingredient matches in the functional layer Than being respectively as follows: 35 parts of polyethylene terephthalate, 1.1 parts of low density polyethylene (LDPE), 1 part of nm-class active calcium carbonate, epoxy rouge 0.7 part of fatty acid methyl esters, 193 parts of isothiazolinone, 116 parts of silver ion modified Nano antibacterial agent, 5 parts of antioxidant, dodecyl two 7 parts of alkylolamides.
4. bacteriostatic antistatic wood bamboo-plastic floorboard as described in claim 1, it is characterised in that: each ingredient matches in the functional layer Than being respectively as follows: 35 parts of polyethylene terephthalate, 1.2 parts of low density polyethylene (LDPE), 2 parts of nm-class active calcium carbonate, epoxy rouge 0.9 part of fatty acid methyl esters, 180 parts of isothiazolinone, 116 parts of silver ion modified Nano antibacterial agent, 4 parts of antioxidant, dodecyl two 7 parts of alkylolamides.
5. bacteriostatic antistatic wood bamboo-plastic floorboard as described in claim 1, it is characterised in that: each ingredient matches in the functional layer Than being respectively as follows: 35 parts of polyethylene terephthalate, 1.3 parts of low density polyethylene (LDPE), 3 parts of nm-class active calcium carbonate, epoxy rouge 1.1 parts of fatty acid methyl esters, 150 parts of isothiazolinone, 116 parts of silver ion modified Nano antibacterial agent, 5 parts of antioxidant, dodecyl two 7 parts of alkylolamides.
6. bacteriostatic antistatic wood bamboo-plastic floorboard as described in claim 1, it is characterised in that: each ingredient matches in the functional layer Than being respectively as follows: 35 parts of polyethylene terephthalate, 1.4 parts of low density polyethylene (LDPE), 4 parts of nm-class active calcium carbonate, epoxy rouge 1.3 parts of fatty acid methyl esters, 193 parts of isothiazolinone, 116 parts of silver ion modified Nano antibacterial agent, 3 parts of antioxidant, dodecyl two 7 parts of alkylolamides.
7. the preparation method of the bacteriostatic antistatic wood bamboo-plastic floorboard as described in claim 1 ~ 6 is any, it is characterised in that: will be formulated Be added together after ratio weighing high-speed mixer heat it is mixed be stirred to 110 DEG C and be put into cold puddling and mix be cooled to 40 DEG C, extruder is added Foam, Vacuum shaping form wood bamboo and mould foaming layer, and the thermal transfer decorative pattern film on the layer, heat rolling is formed on the decorative pattern film Three-dimensional pattern structure, then to above structure lamination UV oil, ultraviolet curing, cutting punching, packaging, storage;Wherein UV oil is Dispersion machine ultrasonic disperse, high speed magnetic stirring preparation is added after weighing by formula together;Extruder temperature is: 160-175 DEG C, vacuum Degree -0.04-0.06MPa;Cooling cooling water temperature≤40 DEG C.
CN201810781657.4A 2018-07-17 2018-07-17 A kind of bacteriostatic antistatic wood bamboo-plastic floorboard and preparation method thereof Pending CN109130423A (en)

Priority Applications (1)

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CN201810781657.4A CN109130423A (en) 2018-07-17 2018-07-17 A kind of bacteriostatic antistatic wood bamboo-plastic floorboard and preparation method thereof

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CN201810781657.4A CN109130423A (en) 2018-07-17 2018-07-17 A kind of bacteriostatic antistatic wood bamboo-plastic floorboard and preparation method thereof

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CN109130423A true CN109130423A (en) 2019-01-04

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Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN201184039Y (en) * 2008-03-05 2009-01-21 吴怡君 Floor with additional function
CN102277945A (en) * 2010-04-30 2011-12-14 肖氏工业集团公司 Non-vinyl resilient flooring product and methods of making same
CN202370214U (en) * 2011-12-30 2012-08-08 东莞矽孚复合材料有限公司 Composite sound-absorbing and anti-seismic insulation floor
CN203257055U (en) * 2013-05-22 2013-10-30 苏州富通高新材料科技股份有限公司 Mothproof and antibacterial floor film
CN104072902A (en) * 2014-06-06 2014-10-01 泰州市华丽塑料有限公司 Antibacterial antistatic wood bamboo plastic floor and manufacturing method thereof
CN204662864U (en) * 2015-05-09 2015-09-23 浙江乐泰塑胶有限公司 Multifunctional floor film
CN105860328A (en) * 2016-04-21 2016-08-17 武汉馨雅美纺织品有限公司 Antifouling and antibacterial tablecloth
CN107160789A (en) * 2017-04-06 2017-09-15 江阴中达软塑新材料股份有限公司 A kind of pharmaceutical pack film special

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN201184039Y (en) * 2008-03-05 2009-01-21 吴怡君 Floor with additional function
CN102277945A (en) * 2010-04-30 2011-12-14 肖氏工业集团公司 Non-vinyl resilient flooring product and methods of making same
CN202370214U (en) * 2011-12-30 2012-08-08 东莞矽孚复合材料有限公司 Composite sound-absorbing and anti-seismic insulation floor
CN203257055U (en) * 2013-05-22 2013-10-30 苏州富通高新材料科技股份有限公司 Mothproof and antibacterial floor film
CN104072902A (en) * 2014-06-06 2014-10-01 泰州市华丽塑料有限公司 Antibacterial antistatic wood bamboo plastic floor and manufacturing method thereof
CN204662864U (en) * 2015-05-09 2015-09-23 浙江乐泰塑胶有限公司 Multifunctional floor film
CN105860328A (en) * 2016-04-21 2016-08-17 武汉馨雅美纺织品有限公司 Antifouling and antibacterial tablecloth
CN107160789A (en) * 2017-04-06 2017-09-15 江阴中达软塑新材料股份有限公司 A kind of pharmaceutical pack film special

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