CN109126898A - It is a kind of to be passivated various metals simultaneously, improve light oil and the passivator of total liquid recovery and preparation method thereof - Google Patents
It is a kind of to be passivated various metals simultaneously, improve light oil and the passivator of total liquid recovery and preparation method thereof Download PDFInfo
- Publication number
- CN109126898A CN109126898A CN201811122326.6A CN201811122326A CN109126898A CN 109126898 A CN109126898 A CN 109126898A CN 201811122326 A CN201811122326 A CN 201811122326A CN 109126898 A CN109126898 A CN 109126898A
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- China
- Prior art keywords
- parts
- passivator
- light oil
- passivated
- total liquid
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 229910052751 metal Inorganic materials 0.000 title claims abstract description 18
- 239000002184 metal Substances 0.000 title claims abstract description 18
- 239000007788 liquid Substances 0.000 title claims abstract description 15
- 150000002739 metals Chemical class 0.000 title claims abstract description 12
- 238000011084 recovery Methods 0.000 title claims abstract description 12
- 238000002360 preparation method Methods 0.000 title claims abstract description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 36
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 16
- 238000006243 chemical reaction Methods 0.000 claims abstract description 11
- 235000021355 Stearic acid Nutrition 0.000 claims abstract description 10
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims abstract description 10
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims abstract description 10
- 239000008116 calcium stearate Substances 0.000 claims abstract description 10
- 235000013539 calcium stearate Nutrition 0.000 claims abstract description 10
- OZECDDHOAMNMQI-UHFFFAOYSA-H cerium(3+);trisulfate Chemical compound [Ce+3].[Ce+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O OZECDDHOAMNMQI-UHFFFAOYSA-H 0.000 claims abstract description 10
- 229910000333 cerium(III) sulfate Inorganic materials 0.000 claims abstract description 10
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims abstract description 10
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000012188 paraffin wax Substances 0.000 claims abstract description 10
- 239000008117 stearic acid Substances 0.000 claims abstract description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 10
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 claims abstract description 9
- 229910000029 sodium carbonate Inorganic materials 0.000 claims abstract description 8
- 238000009835 boiling Methods 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 9
- 239000003002 pH adjusting agent Substances 0.000 claims description 9
- 238000002156 mixing Methods 0.000 claims description 7
- 238000003756 stirring Methods 0.000 claims description 7
- LJCFOYOSGPHIOO-UHFFFAOYSA-N antimony pentoxide Chemical group O=[Sb](=O)O[Sb](=O)=O LJCFOYOSGPHIOO-UHFFFAOYSA-N 0.000 claims description 4
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 claims description 2
- 229910021536 Zeolite Inorganic materials 0.000 claims description 2
- 229910000410 antimony oxide Inorganic materials 0.000 claims description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 2
- HDFXRQJQZBPDLF-UHFFFAOYSA-L disodium hydrogen carbonate Chemical compound [Na+].[Na+].OC([O-])=O.OC([O-])=O HDFXRQJQZBPDLF-UHFFFAOYSA-L 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims description 2
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 claims description 2
- 235000017550 sodium carbonate Nutrition 0.000 claims description 2
- 239000010457 zeolite Substances 0.000 claims description 2
- IPCXNCATNBAPKW-UHFFFAOYSA-N zinc;hydrate Chemical compound O.[Zn] IPCXNCATNBAPKW-UHFFFAOYSA-N 0.000 claims description 2
- XIVNZHXRIPJOIZ-UHFFFAOYSA-N octadecanoic acid;zinc Chemical compound [Zn].CCCCCCCCCCCCCCCCCC(O)=O XIVNZHXRIPJOIZ-UHFFFAOYSA-N 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 7
- 238000002161 passivation Methods 0.000 abstract description 3
- 239000003054 catalyst Substances 0.000 description 12
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 9
- 239000003921 oil Substances 0.000 description 8
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 7
- 229910052708 sodium Inorganic materials 0.000 description 7
- 239000011734 sodium Substances 0.000 description 7
- 239000012467 final product Substances 0.000 description 5
- 229910052759 nickel Inorganic materials 0.000 description 5
- 229910052720 vanadium Inorganic materials 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 238000004523 catalytic cracking Methods 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000011651 chromium Substances 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- 229910001385 heavy metal Inorganic materials 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 206010027439 Metal poisoning Diseases 0.000 description 1
- 241000772415 Neovison vison Species 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- JOPOVCBBYLSVDA-UHFFFAOYSA-N chromium(6+) Chemical compound [Cr+6] JOPOVCBBYLSVDA-UHFFFAOYSA-N 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 210000002249 digestive system Anatomy 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000012847 fine chemical Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 230000002779 inactivation Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 210000004400 mucous membrane Anatomy 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 210000002345 respiratory system Anatomy 0.000 description 1
- 210000003491 skin Anatomy 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- WQEVDHBJGNOKKO-UHFFFAOYSA-K vanadic acid Chemical compound O[V](O)(O)=O WQEVDHBJGNOKKO-UHFFFAOYSA-K 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J33/00—Protection of catalysts, e.g. by coating
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Catalysts (AREA)
- Lubricants (AREA)
Abstract
The passivator that the invention discloses one kind can be passivated various metals simultaneously, improves light oil and total liquid recovery, including following components in percentage by weight: 20 ~ 30 parts of sb oxide, 10 ~ 20 parts of cerous sulfate, 1 ~ 10 part of paraffin, 1 ~ 5 part of stearic acid, 1 ~ 5 part of calcium stearate, 5 ~ 10 parts of sodium carbonate, 10 ~ 15 parts of triethanolamine, 1 ~ 5 part of sodium hydroxide, 1 ~ 5 part of zinc stearate and 10 ~ 15 parts of water.Meanwhile the invention also discloses the preparation methods of above-mentioned passivator.The present invention has the function of while improving FCC reaction selectivity and conversion ratio, compared with former passivator, is keeping passivation effect, light oil yield and total liquid yield improve 0.8% again respectively on the basis of not reducing.
Description
Technical field
The invention belongs to function Field of Fine Chemicals, can be passivated various metals simultaneously more particularly to one kind, improve light oil
And passivator of total liquid recovery and preparation method thereof.
Background technique
In catalytic cracking process, especially using mink cell focus to contain in the catalytic cracking process of raw material in feedstock oil
Heavy metal, such as nickel, vanadium, copper, iron heavy metal can be deposited on catalyst surface and cause catalyst poisoning inactivation and selectivity decline,
To make yield of light oil decline, hydrogen and coke yield rise.For the metallic pollution of catalytic cracking catalyst, industrially remove
Demetalization pretreatment is carried out, outside the catalyst for selecting anti-metal ability strong to raw material, it can also setting using larger catalyst
Throw-over rate improves the property of catalyst, and inhibits toxic action of the metal in raw material to catalyst using passivator.
It wherein, the use of passivator is most simple, effective method.Metal passivating technique is the organic or inorganic chemical combination using certain metals
Object is injected in catalytic cracking reaction-regenerative system with liquid, and is allowed to deposition on a catalyst, with the middle metal on catalyst
It has an effect.When existing simultaneously a large amount of nickel, vanadium, sodium in crude oil, need to be added blunt nickel agent, blunt vanadium agent and blunt sodium agent simultaneously,
Or it is added while having the multi-functional passivator of anti-nickel anti-vanadium the resistance against sodium energy.The prior art is frequently with sexavalence chromium type passivator conduct
Passivator.But sexavalence chromium type passivator passivation effect is larger with the changes of contents of Cr VI, while passivation effect also less stable,
Corrosion resistance is poor, can not be effectively protected nickel layer surface.Simultaneously as hexavalent chromium compound is easily absorbed by the body, can lead to
Digestive system, respiratory tract, skin and mucous membrane intrusion human body are crossed, therefore environment and human body are endangered larger.And other traditional gold
The stability for belonging to passivator is shorter, and general storage period can generate a large amount of precipitatings in 3 ~ 6 months, long term storage and use process,
Serious even blocking pipeline.Conventional metals passivator is mostly acidic materials, ph in 2 ~ 4 or so (PH high influences product stabilities),
Iron pipe or container are touched in storage and use process, acceleration equipment corrosive pipeline causes product effect to decline or fail,
Even aggravate catalyst contamination.
Summary of the invention
Goal of the invention: in view of the above-mentioned deficiencies in the prior art, it is an object of the present invention to which a variety of gold can be passivated simultaneously by providing one kind
Belong to, improve the passivator of light oil and total liquid recovery.
Another object of the present invention is to disclose the preparation method of above-mentioned passivator.
Technical solution: in order to achieve the above object of the invention, what the present invention specifically completed in this way: one kind can be passivated more simultaneously
Kind metal, the passivator for improving light oil and total liquid recovery, including following components in percentage by weight: 20 ~ 30 parts of sb oxide,
10 ~ 20 parts of cerous sulfate, 1 ~ 10 part of paraffin, 1 ~ 5 part of stearic acid, 1 ~ 5 part of calcium stearate, 5 ~ 10 parts of sodium carbonate, 10 ~
15 parts of triethanolamine, 1 ~ 5 part of sodium hydroxide, 1 ~ 5 part of zinc stearate and 10 ~ 15 parts of water.
Wherein, the sb oxide is antimony pentoxide or antimony oxide.
The method for preparing the above-mentioned passivator that can be passivated various metals simultaneously, improve light oil and total liquid recovery, including it is following
Step:
(1) sb oxide, paraffin, stearic acid, calcium stearate, sodium carbonate and triethanolamine are measured by formula and successively puts into reaction kettle
Stirring, temperature are controlled at 75 ~ 80 DEG C, are heated 50 ~ 60min, are then heated to boiling, and flow back 30 ~ 50min, are cooled to room temperature；
(2) cerous sulfate, sodium hydroxide, zinc stearate and water being measured by formula, temperature is controlled at 65 ~ 70 DEG C, 40 ~ 50min is heated,
It is then heated to boiling, flow back 20 ~ 40min, is cooled to room temperature；
(3) mixture obtained by step (1) and step (2) is subjected to 20 ~ 30min of mixing, by pH adjusting agent control pH7 ~
8 to get.
Wherein, the pH adjusting agent is sodium carbonate, sodium bicarbonate, disodium bicarbonate or sodium hydroxide.
Wherein, the step (1), the zeolite of mixture quality percentage 1 ~ 2% is added in step (2) heating process.
The utility model has the advantages that the present invention, compared with traditional technology, there are following advantages:
(1) present invention has the function of while improving FCC reaction selectivity and conversion ratio, compared with former passivator, is keeping blunt
Change effect, light oil yield and total liquid yield improve 0.8% again respectively on the basis of not reducing；
(2) present invention selects a kind of weakly alkaline metal oxide according to the mechanism of metal poisoning to act on vanadic acid, generates one
The highly stable solid metal hydrochlorate of kind, achievees the purpose that passivating vanadium；
(3) when 100ppm is added in the present invention, less than 1, catalyst consumption controls when less than 0.8 H/C ratio in catalytic cracked dry gas,
Catalyst activity not low 62.
Specific embodiment
Embodiment 1:
20 parts of sb oxide, 1 part of paraffin, 1 part of stearic acid, 1 part of calcium stearate, 5 parts of carbon are taken by weight percentage
Sour sodium and 10 parts of triethanolamine successively put into reaction kettle stirring, temperature control at 75 ~ 80 DEG C, heat 50 ~ 60min, then plus
Heat is to boiling, and flow back 30 ~ 50min, is cooled to room temperature；10 parts of cerous sulfate, 1 part of sodium hydroxide, 1 part are taken by weight percentage
Zinc stearate and 10 parts of water, temperature controls at 65 ~ 70 DEG C, heats 40 ~ 50min, be then heated to boiling, flow back 20 ~
40min is cooled to room temperature；Above-mentioned gained mixture is subjected to 20 ~ 30min of mixing, pH7 ~ 8 are controlled by pH adjusting agent,
To obtain the final product.
Embodiment 2:
30 parts of sb oxide, 10 parts of paraffin, 5 parts of stearic acid, 5 parts of calcium stearate, 10 parts are taken by weight percentage
Sodium carbonate and 15 parts of triethanolamine successively put into reaction kettle stirring, and temperature is controlled at 75 ~ 80 DEG C, heat 50 ~ 60min, then
It is heated to boiling, flow back 30 ~ 50min, is cooled to room temperature；20 parts of cerous sulfate, 5 parts of sodium hydroxide, 5 are taken by weight percentage
Part zinc stearate and 15 parts of water, temperature controls at 65 ~ 70 DEG C, heats 40 ~ 50min, be then heated to boiling, flow back 20 ~
40min is cooled to room temperature；Above-mentioned gained mixture is subjected to 20 ~ 30min of mixing, pH7 ~ 8 are controlled by pH adjusting agent,
To obtain the final product.
Embodiment 3:
25 parts of sb oxide, 5 parts of paraffin, 3 parts of stearic acid, 3 parts of calcium stearate, 8 parts of carbon are taken by weight percentage
Sour sodium and 12 parts of triethanolamine successively put into reaction kettle stirring, temperature control at 75 ~ 80 DEG C, heat 50 ~ 60min, then plus
Heat is to boiling, and flow back 30 ~ 50min, is cooled to room temperature；15 parts of cerous sulfate, 3 parts of sodium hydroxide, 3 parts are taken by weight percentage
Zinc stearate and 13 parts of water, temperature controls at 65 ~ 70 DEG C, heats 40 ~ 50min, be then heated to boiling, flow back 20 ~
40min is cooled to room temperature；Above-mentioned gained mixture is subjected to 20 ~ 30min of mixing, pH7 ~ 8 are controlled by pH adjusting agent,
To obtain the final product.
Embodiment 4:
22 parts of sb oxide, 2 parts of paraffin, 2 parts of stearic acid, 2 parts of calcium stearate, 6 parts of carbon are taken by weight percentage
Sour sodium and 11 parts of triethanolamine successively put into reaction kettle stirring, temperature control at 75 ~ 80 DEG C, heat 50 ~ 60min, then plus
Heat is to boiling, and flow back 30 ~ 50min, is cooled to room temperature；12 parts of cerous sulfate, 2 parts of sodium hydroxide, 3 parts are taken by weight percentage
Zinc stearate and 11 parts of water, temperature controls at 65 ~ 70 DEG C, heats 40 ~ 50min, be then heated to boiling, flow back 20 ~
40min is cooled to room temperature；Above-mentioned gained mixture is subjected to 20 ~ 30min of mixing, pH7 ~ 8 are controlled by pH adjusting agent,
To obtain the final product.
Embodiment 5:
28 parts of sb oxide, 9 parts of paraffin, 4 parts of stearic acid, 3 parts of calcium stearate, 8 parts of carbon are taken by weight percentage
Sour sodium and 14 parts of triethanolamine successively put into reaction kettle stirring, temperature control at 75 ~ 80 DEG C, heat 50 ~ 60min, then plus
Heat is to boiling, and flow back 30 ~ 50min, is cooled to room temperature；18 parts of cerous sulfate, 3 parts of sodium hydroxide, 4 parts are taken by weight percentage
Zinc stearate and 14 parts of water, temperature controls at 65 ~ 70 DEG C, heats 40 ~ 50min, be then heated to boiling, flow back 20 ~
40min is cooled to room temperature；Above-mentioned gained mixture is subjected to 20 ~ 30min of mixing, pH7 ~ 8 are controlled by pH adjusting agent,
To obtain the final product.
Claims (5)
1. the passivator that one kind can be passivated various metals simultaneously, improve light oil and total liquid recovery, which is characterized in that including following heavy
The component of amount percentage: 20 ~ 30 parts of sb oxide, 10 ~ 20 parts of cerous sulfate, 1 ~ 10 part of paraffin, 1 ~ 5 part of stearic acid, 1
~ 5 parts of calcium stearate, 5 ~ 10 parts of sodium carbonate, 10 ~ 15 parts of triethanolamine, 1 ~ 5 part of sodium hydroxide, 1 ~ 5 part of stearic acid
Zinc and 10 ~ 15 parts of water.
2. the passivator that can be passivated various metals simultaneously according to claim 1, improve light oil and total liquid recovery, feature exist
In the sb oxide is antimony pentoxide or antimony oxide.
3. the method that can be passivated various metals, the passivator for improving light oil and total liquid recovery described in preparation power 1 simultaneously, feature exist
In, comprising the following steps:
(1) sb oxide, paraffin, stearic acid, calcium stearate, sodium carbonate and triethanolamine are measured by formula and successively puts into reaction kettle
Stirring, temperature are controlled at 75 ~ 80 DEG C, are heated 50 ~ 60min, are then heated to boiling, and flow back 30 ~ 50min, are cooled to room temperature；
(2) cerous sulfate, sodium hydroxide, zinc stearate and water being measured by formula, temperature is controlled at 65 ~ 70 DEG C, 40 ~ 50min is heated,
It is then heated to boiling, flow back 20 ~ 40min, is cooled to room temperature；
(3) mixture obtained by step (1) and step (2) is subjected to 20 ~ 30min of mixing, by pH adjusting agent control pH7 ~
8 to get.
4. preparing the side that can be passivated various metals, the passivator for improving light oil and total liquid recovery simultaneously according to claim 3
Method, which is characterized in that the pH adjusting agent is sodium carbonate, sodium bicarbonate, disodium bicarbonate or sodium hydroxide.
5. preparing the side that can be passivated various metals, the passivator for improving light oil and total liquid recovery simultaneously according to claim 3
Method, which is characterized in that the zeolite of mixture quality percentage 1 ~ 2% is added in the step (1), step (2) heating process.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811122326.6A CN109126898A (en) | 2018-09-26 | 2018-09-26 | It is a kind of to be passivated various metals simultaneously, improve light oil and the passivator of total liquid recovery and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811122326.6A CN109126898A (en) | 2018-09-26 | 2018-09-26 | It is a kind of to be passivated various metals simultaneously, improve light oil and the passivator of total liquid recovery and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109126898A true CN109126898A (en) | 2019-01-04 |
Family
ID=64812518
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811122326.6A Pending CN109126898A (en) | 2018-09-26 | 2018-09-26 | It is a kind of to be passivated various metals simultaneously, improve light oil and the passivator of total liquid recovery and preparation method thereof |
Country Status (1)
| Country | Link |
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| CN (1) | CN109126898A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111054449A (en) * | 2019-12-31 | 2020-04-24 | 宜兴汉光高新石化有限公司 | Environment-friendly multi-metal passivator and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104066819A (en) * | 2011-11-21 | 2014-09-24 | 巴斯夫公司 | Improved metal passivator/trap for FCC processes |
| CN104818045A (en) * | 2014-01-31 | 2015-08-05 | 环球油品公司 | Resid catalytic cracker and catalyst for increasing propylene yield |
| CN104841490A (en) * | 2015-04-08 | 2015-08-19 | 宜兴市中大凯化工有限公司 | Method for preparing double metal deactivator |
-
2018
- 2018-09-26 CN CN201811122326.6A patent/CN109126898A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104066819A (en) * | 2011-11-21 | 2014-09-24 | 巴斯夫公司 | Improved metal passivator/trap for FCC processes |
| CN104818045A (en) * | 2014-01-31 | 2015-08-05 | 环球油品公司 | Resid catalytic cracker and catalyst for increasing propylene yield |
| CN104841490A (en) * | 2015-04-08 | 2015-08-19 | 宜兴市中大凯化工有限公司 | Method for preparing double metal deactivator |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111054449A (en) * | 2019-12-31 | 2020-04-24 | 宜兴汉光高新石化有限公司 | Environment-friendly multi-metal passivator and preparation method thereof |
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Application publication date: 20190104 |