CN109070150A - The cleaning method of hard surface - Google Patents
The cleaning method of hard surface Download PDFInfo
- Publication number
- CN109070150A CN109070150A CN201780025687.6A CN201780025687A CN109070150A CN 109070150 A CN109070150 A CN 109070150A CN 201780025687 A CN201780025687 A CN 201780025687A CN 109070150 A CN109070150 A CN 109070150A
- Authority
- CN
- China
- Prior art keywords
- ingredient
- mass
- hereinafter
- hard surface
- liquid ceanser
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 238000004140 cleaning Methods 0.000 title claims abstract description 190
- 238000000034 method Methods 0.000 title claims abstract description 121
- 239000004615 ingredient Substances 0.000 claims abstract description 284
- 239000000203 mixture Substances 0.000 claims abstract description 239
- 239000007788 liquid Substances 0.000 claims abstract description 214
- 239000007787 solid Substances 0.000 claims abstract description 47
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 47
- 239000004519 grease Substances 0.000 claims abstract description 40
- 239000004094 surface-active agent Substances 0.000 claims abstract description 26
- 239000002738 chelating agent Substances 0.000 claims abstract description 17
- 229910052799 carbon Inorganic materials 0.000 claims description 98
- 125000000217 alkyl group Chemical group 0.000 claims description 78
- 150000001721 carbon Chemical group 0.000 claims description 76
- -1 1 mass % or more Substances 0.000 claims description 70
- 150000003839 salts Chemical class 0.000 claims description 52
- 150000001875 compounds Chemical class 0.000 claims description 35
- 239000003945 anionic surfactant Substances 0.000 claims description 29
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims description 17
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 14
- 239000003795 chemical substances by application Substances 0.000 claims description 13
- 239000002280 amphoteric surfactant Substances 0.000 claims description 12
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 12
- 125000001118 alkylidene group Chemical group 0.000 claims description 10
- GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 claims description 10
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical compound NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 claims description 8
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- BAERPNBPLZWCES-UHFFFAOYSA-N (2-hydroxy-1-phosphonoethyl)phosphonic acid Chemical compound OCC(P(O)(O)=O)P(O)(O)=O BAERPNBPLZWCES-UHFFFAOYSA-N 0.000 claims description 5
- 230000003213 activating effect Effects 0.000 claims description 4
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- 238000004519 manufacturing process Methods 0.000 description 23
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- NPYPAHLBTDXSSS-UHFFFAOYSA-N Potassium ion Chemical compound [K+] NPYPAHLBTDXSSS-UHFFFAOYSA-N 0.000 description 8
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- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 8
- 238000005406 washing Methods 0.000 description 8
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- 238000010411 cooking Methods 0.000 description 7
- 239000003960 organic solvent Substances 0.000 description 7
- 159000000000 sodium salts Chemical class 0.000 description 7
- CIEZZGWIJBXOTE-UHFFFAOYSA-N 2-[bis(carboxymethyl)amino]propanoic acid Chemical compound OC(=O)C(C)N(CC(O)=O)CC(O)=O CIEZZGWIJBXOTE-UHFFFAOYSA-N 0.000 description 6
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 6
- QPCDCPDFJACHGM-UHFFFAOYSA-N N,N-bis{2-[bis(carboxymethyl)amino]ethyl}glycine Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(=O)O)CCN(CC(O)=O)CC(O)=O QPCDCPDFJACHGM-UHFFFAOYSA-N 0.000 description 6
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- 239000003054 catalyst Substances 0.000 description 6
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- 239000008399 tap water Substances 0.000 description 6
- 235000020679 tap water Nutrition 0.000 description 6
- URDCARMUOSMFFI-UHFFFAOYSA-N 2-[2-[bis(carboxymethyl)amino]ethyl-(2-hydroxyethyl)amino]acetic acid Chemical compound OCCN(CC(O)=O)CCN(CC(O)=O)CC(O)=O URDCARMUOSMFFI-UHFFFAOYSA-N 0.000 description 5
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- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 5
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- 238000000576 coating method Methods 0.000 description 5
- 238000011010 flushing procedure Methods 0.000 description 5
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- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- YAVVGPBYBUYPSR-UHFFFAOYSA-N benzene;oxygen Chemical compound [O].C1=CC=CC=C1 YAVVGPBYBUYPSR-UHFFFAOYSA-N 0.000 description 1
- 229960003237 betaine Drugs 0.000 description 1
- 238000000071 blow moulding Methods 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- XTHPWXDJESJLNJ-UHFFFAOYSA-N chlorosulfonic acid Substances OS(Cl)(=O)=O XTHPWXDJESJLNJ-UHFFFAOYSA-N 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 229940028356 diethylene glycol monobutyl ether Drugs 0.000 description 1
- 239000000539 dimer Substances 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 235000019301 disodium ethylene diamine tetraacetate Nutrition 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- 150000002170 ethers Polymers 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 239000003349 gelling agent Substances 0.000 description 1
- 229930182478 glucoside Natural products 0.000 description 1
- 150000008131 glucosides Chemical class 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 1
- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000005661 hydrophobic surface Effects 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 150000002500 ions Chemical group 0.000 description 1
- 239000011344 liquid material Substances 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- JCGNDDUYTRNOFT-UHFFFAOYSA-N oxolane-2,4-dione Chemical compound O=C1COC(=O)C1 JCGNDDUYTRNOFT-UHFFFAOYSA-N 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- UWJJYHHHVWZFEP-UHFFFAOYSA-N pentane-1,1-diol Chemical compound CCCCC(O)O UWJJYHHHVWZFEP-UHFFFAOYSA-N 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920001281 polyalkylene Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- HNDXKIMMSFCCFW-UHFFFAOYSA-N propane-2-sulphonic acid Chemical compound CC(C)S(O)(=O)=O HNDXKIMMSFCCFW-UHFFFAOYSA-N 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- FSYKKLYZXJSNPZ-UHFFFAOYSA-N sarcosine Chemical compound C[NH2+]CC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-N 0.000 description 1
- 238000009991 scouring Methods 0.000 description 1
- 150000003333 secondary alcohols Chemical class 0.000 description 1
- UELAIMNOXLAYRW-UHFFFAOYSA-M sodium;1,4-dicyclohexyloxy-1,4-dioxobutane-2-sulfonate Chemical compound [Na+].C1CCCCC1OC(=O)C(S(=O)(=O)[O-])CC(=O)OC1CCCCC1 UELAIMNOXLAYRW-UHFFFAOYSA-M 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 230000001180 sulfating effect Effects 0.000 description 1
- 230000019635 sulfation Effects 0.000 description 1
- 238000005670 sulfation reaction Methods 0.000 description 1
- 229940117986 sulfobetaine Drugs 0.000 description 1
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 1
- 239000013638 trimer Substances 0.000 description 1
- OHOTVSOGTVKXEL-UHFFFAOYSA-K trisodium;2-[bis(carboxylatomethyl)amino]propanoate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)C(C)N(CC([O-])=O)CC([O-])=O OHOTVSOGTVKXEL-UHFFFAOYSA-K 0.000 description 1
- SOBHUZYZLFQYFK-UHFFFAOYSA-K trisodium;hydroxy-[[phosphonatomethyl(phosphonomethyl)amino]methyl]phosphinate Chemical compound [Na+].[Na+].[Na+].OP(O)(=O)CN(CP(O)([O-])=O)CP([O-])([O-])=O SOBHUZYZLFQYFK-UHFFFAOYSA-K 0.000 description 1
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- ABDKAPXRBAPSQN-UHFFFAOYSA-N veratrole Chemical compound COC1=CC=CC=C1OC ABDKAPXRBAPSQN-UHFFFAOYSA-N 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B3/00—Cleaning by methods involving the use or presence of liquid or steam
- B08B3/04—Cleaning involving contact with liquid
- B08B3/08—Cleaning involving contact with liquid the liquid having chemical or dissolving effect
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/92—Sulfobetaines ; Sulfitobetaines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/08—Liquid soap, e.g. for dispensers; capsuled
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/36—Organic compounds containing phosphorus
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- General Chemical & Material Sciences (AREA)
- Detergent Compositions (AREA)
Abstract
The present invention is a kind of cleaning method of tableware, it is to contact tableware liquid ceanser compositions with the tableware for being attached with the greasy dirt comprising solid grease, and it is cleaned in the case where not applying mechanical force, it is [following that the tableware liquid ceanser compositions contain surfactant, referred to as (I) ingredient] 1 mass % or more, chelating agent be [following, referred to as (II) ingredient] 1 mass % or more and water, and (I) ingredient/(II) ingredient mass ratio is 0.25 or more, the conductivity at 25 DEG C is 0.70S/m or more.
Description
Technical field
The present invention relates to the cleaning method of hard surface and hard surface liquid ceanser compositions.The present invention is especially
It is related to the cleaning method and tableware liquid ceanser compositions of tableware.
Background technique
For hand washing cleaning agent for dinnerware, industry is strongly required the cleaning force to greasy dirt.Especially in plastic box lunch
Box or lunch box etc. have in the tableware class of hydrophobic surface, and the greasy dirt comprising the solids rouge such as a large amount of butter or lard is not easily to fall off,
More demanding cleaning force.Thus it is common to use implementing to do using about 40 DEG C~45 DEG C of 2 cleanings of hot water or progress etc.
The cleaning method of method.
Following content is recorded in Japanese Unexamined Patent Publication 2004-217908 bulletin: spraying by using a kind of wash dishes
Formula cleaning agent product is adhered in a manner of the spot on drop or blister covering cleaning object object surface, and is played excellent clear
Wash power, which is characterized in that: it is will to contain following (a)~(c) and include (a)
And the liquid ceanser that 3~20 mass %, mass ratio (a): (b) is 2:1~20:1 that adds up to of surfactant (b) combines
Object be filled in convert thereof into droplet-like or blister and spue container form,
(a) anionic surfactant,
(b) Semi-polar surfactants,
(c) 0.1~20 mass % of ethyl alcohol.
Following content is recorded in Japanese Unexamined Patent Publication 2013-82846 bulletin: being selected from (a) sulphur containing 2~8 mass %
Base amber acid alkyl ester or its salt, (b) alkyl sulfate or its salt and (c) hydroxycarboxylic acid, aminopolycarboxylic and they
The hand washing of the compound of one or more of salt shows the spot around sink with tableware cleansing composition excellent clear
Power is washed, the duration of bubble when foaming characteristic abundant and cleaning is showed in cleaning, when rinsing, bubble disappears in the twinkling of an eye, benefit
It completes to rinse with a small amount of water.
Summary of the invention
The present invention relates to the hard surface use that the cleaning force for the greasy dirt comprising solid grease for being attached to hard surface is excellent
The cleaning method of liquid ceanser compositions and the hard surface using the hard surface liquid ceanser compositions.More in detail
For thin, the present invention relates to the tableware liquid rinses that the cleaning force for the greasy dirt comprising solid grease being attached on tableware is excellent
The cleaning method of agent composition and the tableware using the tableware liquid ceanser compositions.
The present invention relates to a kind of cleaning method of hard surface, be make hard surface liquid ceanser compositions with it is attached
Have the greasy dirt comprising solid grease hard surface contact and cleaned in the case where not applying mechanical force, the hard
Surface liquid ceanser compositions contain (I) surfactant [hereinafter referred to as (I) ingredient] of 1 mass % or more, 1 matter
(II) chelating agent [hereinafter referred to as (II) ingredient] and water of % or more are measured, and contains (a) anionic surfactant and is used as (I)
Ingredient, (II) ingredient/(I) ingredient mass ratio are 0.25 or more, and above-mentioned hard surface liquid ceanser compositions are at 25 DEG C
Conductivity be 0.70S/m or more.
As cleaning method of the invention, can be listed below the cleaning method of tableware: it is to make tableware liquid ceanser
Composition is contacted with the tableware for being attached with the greasy dirt comprising solid grease and is cleaned in the case where not applying mechanical force,
The tableware liquid ceanser compositions contain (I) surfactant [hereinafter referred to as (I) ingredient] of 1 mass % or more, 1 matter
(II) chelating agent [hereinafter referred to as (II) ingredient] and water of % or more are measured, and contains (a) anionic surfactant and is used as (I)
Ingredient, (II) ingredient/(I) ingredient mass ratio are 0.25 or more, conductivity of the tableware liquid ceanser compositions at 25 DEG C
For 0.70S/m or more.
Also, containing (I) table of 1 mass % or more the present invention relates to a kind of hard surface liquid ceanser compositions
(II) chelating agent [hereinafter referred to as (II) ingredient] and water of face activating agent [hereinafter referred to as (I) ingredient], 1 mass % or more, and
Contain (a) anionic surfactant and be used as (I) ingredient, (II) ingredient/(I) ingredient mass ratio is 0.25 or more, hard table
Face is 0.70S/m or more in 25 DEG C of conductivity with liquid ceanser compositions.
As hard surface liquid ceanser compositions of the invention, tableware can be listed below and combined with liquid ceanser
Object: (II) chelating agent of its (I) surfactant for containing 1 mass % or more [hereinafter referred to as (I) ingredient], 1 mass % or more
[hereinafter referred to as (II) ingredient] and water, and containing (a) anionic surfactant [hereinafter referred to as (a) ingredient] as (I) at
Point, (II) ingredient/(I) ingredient mass ratio is 0.25 or more, and conductivity of the tableware with liquid ceanser compositions at 25 DEG C is
0.70S/m or more.
In accordance with the invention it is possible to which even if providing a kind of wiped without using flexible materials such as sponges does not apply machinery
Power can also clean the greasy dirt comprising solid grease of the article, especially tableware that are attached to plastics etc. with hard surface
The cleaning method and hard surface liquid ceanser compositions of the excellent hard surface of cleaning force.
Specific embodiment
[cleaning method of hard surface]
The cleaning method of hard surface of the invention is the cleaning method of following hard surface: it is to make hard surface liquid
Body cleansing composition contacts with the hard surface such as tableware for being attached with the greasy dirt comprising solid grease and is not applying machinery
It is cleaned in the case where power, which contains the anion table comprising 1 mass % or more
The surfactant [(I) ingredient] of face activating agent, the chelating agent [(II) ingredient] of 1 mass % or more and water, and (II) ingredient/
(I) mass ratio of ingredient is 0.25 or more, hard surface with liquid ceanser compositions 25 DEG C of conductivity be 0.70S/m with
On.The cleaning method includes the following cleaning method that hard surface is substituted for tableware.
In the present invention, thus it is speculated that: by content to the surfactant comprising anionic surfactant and chelating agent and
The conductivity of mass ratio and composition is provided, so that the cleaning ability of surfactant is promoted, it is used in the present invention
The surfactant that hard surface liquid ceanser compositions are included is readily permeable into the greasy dirt comprising solid grease, Gu
Body grease is easy to remove from hard surface, as a result, can get the promotion effect of cleaning force.
Also, cleaning method of the invention so that method that above-mentioned composition is directly contacted with hard surface and use
In situation, due to applying the concentration in the surfactant of hard surface to be higher than what the aqueous sponge of use contacted with hard surface
Situation, so its effect can be showed significantly more.
According to these situations, about cleaning method of the invention, to be attached to the hard surfaces such as plastics comprising solid oil
The greasy dirt of rouge, even by wipe etc. without using the flexible materials such as sponge, not applying the cleaning method of mechanical force, also
Excellent cleaning force can be obtained.
Hereinafter, being illustrated for hard surface used in cleaning method of the invention with liquid ceanser compositions.
[(I) ingredient]
(I) ingredient is surfactant.Hard surface used in the present invention liquid ceanser compositions include (a) yin
Ionic surface active agent is used as (I) ingredient.
For the viewpoint of cleaning force, surfactant includes (a) anionic surfactant.As other surfaces activity
Agent can enumerate a kind in (b) amphoteric surfactant, (c) nonionic surfactant and cationic surfactant
Above surfactant.
As surfactant, for the viewpoint of cleaning force, preferably (a) anionic surfactant be selected from (b)
The surfactant of one or more of amphoteric surfactant and (c) nonionic surfactant [hereinafter referred to as (c) ingredient]
Combination, the more preferably group of (a) anionic surfactant and (b) amphoteric surfactant [hereinafter referred to as (b) ingredient]
It closes.
< (a) ingredient >
(a) ingredient is anionic surfactant.As anionic surfactant, it is preferably selected from (a1) the following general formula
(a1) sulfosuccinate or its salt [hereinafter referred to as (a1) ingredient] and (a2) represented by have carbon atom number 8 or more 21 with
Under alkyl and sulfate group or sulfonic anionic surfactant [wherein, in addition to (a1) ingredient] [hereinafter referred to as
(a2) ingredient] one or more of anionic surfactant.
[in formula, R1a、R2aIt independently, is the alkyl below of carbon atom number 5 or more and 18；A1、A2It is separately carbon
The alkylidene below of atomicity 2 or more and 4, x, y are average addition molal quantity, and are separately 0 or more and 6 or less；M1
For hydrogen atom or cation.]
< (a1) ingredient >
(a1) ingredient used in the present invention is sulfosuccinate or its salt represented by the following general formula (a1).
[in formula, R1a、R2aIt independently, is the alkyl below of carbon atom number 5 or more and 18；A1、A2It is separately carbon
The alkylidene below of atomicity 2 or more and 4, x, y are average addition molal quantity, and are separately 0 or more and 6 or less；M1
For hydrogen atom or cation]
In general formula (a1), R1a、R2aIndependently, for 5 or more carbon atom number, preferably 6 or more, more preferably 7 or more,
And 18 or less carbon atom number, preferably 16 or less and then preferably 14 alkyl below.Alkyl is preferably the alkyl of branch.
R1a、R2aIndependently, the preferably alkyl of linear chain or branched chain, the more preferably alkyl of branch.
In general formula (a1), A1、A2It independently, is 2 or more carbon atom number and 4 or less carbon atom number, preferably 3 or less
Alkylidene.
In general formula (a1), x, y are average addition molal quantity, are 0 or more independently for the viewpoint of cleaning force, and
And be 6 hereinafter, preferably 4 hereinafter, more preferably 2 hereinafter, in turn be preferably 0.
Also, about x+y, for the viewpoint of cleaning force, preferably 0 or more, also, preferably 12 hereinafter, more preferably 6
Hereinafter, being in turn preferably 3 hereinafter, further preferably 0.
In general formula (a1), R1a、R2aBe respectively preferably selected from hexyl, octyl, nonyl, decyl, dodecyl, tridecyl,
Myristyl, 2- ethylhexyl, n-octyl, secondary octyl, isopentyl, isononyl, isodecyl, the alkyl in cyclohexyl, more preferably
For the alkyl in n-octyl, secondary octyl, decyl, isodecyl and 2- ethylhexyl, and then it is preferably selected from 2- ethyl hexyl
Alkyl in base and tridecyl, further preferably 2- ethylhexyl.
In general formula (a1), M1For hydrogen atom or cation.As cation, can enumerate sodium ion, ammonium ion, potassium ion,
The inorganic cations such as magnesium ion；Organic sun such as monoethanol ammonium ion, diethanol ammonium ion, triethanol ammonium ion, morpholinium ion
Ion.Cation is preferably selected from the inorganic cation in sodium ion, ammonium ion, potassium ion and magnesium ion.
About (a1) ingredient, as R1a、R2aThe preparation method of identical compound, is not particularly limited, such as can refer to
The 2nd, 028, No. 091 bulletin of US Patent specification record method and manufacture, in addition, R1a、R2aDifferent asymmetrical compounds
Such as it can refer to Japanese Unexamined Patent Application 58-24555 bulletin and manufacture.It when using the situation of commercially available compound, can be used: flower
Pelex OT-P (the R of king's (strain) manufacture1a、R2aSimultaneously be 2- ethylhexyl compound), flower king (strain) manufacture Pelex TR
(R1a、R2aSimultaneously be tridecyl compound), BASF AG manufacture LuensitA-BO (R1a、R2aIt is simultaneously 2- ethyl hexyl
The compound of base), the Airrol CT-1L (R that manufactures of eastern nation's chemical industry (strain)1a、R2aIt is simultaneously the chemical combination of 2- ethylhexyl
Object), can from Mitsui Cytec Co., Ltd. obtain aerosol AY-100 (R1a、R2aSimultaneously be amyl compound), can
Aerosol A-196 (the R obtained from Mitsui Cytec Co., Ltd.1a、R2aSimultaneously it is the compound of cyclohexyl) etc..As
(a1) substance made of the alcohol addition alkylene oxide to specific carbon atom number also can be used in the raw material of ingredient.
< (a2) ingredient >
(a2) ingredient used in the present invention be with carbon atom number 8 or more and 21 alkyl and sulfate group below or
Sulfonic anionic surfactant [wherein, in addition to (a1) ingredient].
About the alkyl of (a2) ingredient, for the viewpoint of cleaning force, carbon atom number is 8 or more, preferably 10 or more, more
Preferably 12 or more, also, be 21 hereinafter, preferably 18 hereinafter, more preferably 14 hereinafter, in turn be preferably 12 or less.(a2)
The alkyl of ingredient is preferably alkyl or aryl.
As the anionic surfactant of (a2) ingredient, it is preferably selected from alkyl sulfate salt, polyoxyalkylene alkyl
One or more of ether sulfuric ester salt and alkyl sulfonate.
As the above-mentioned anionic surfactant with sulfate group, for the viewpoint of cleaning force, it is however preferred to have
Carbon atom number is 8 or more, is preferably 10 or more and 21 or less, is preferably 18 or less, being more preferably 14 or less, is preferred in turn
For the alkyl sulfate salt of the alkyl of 12 linear chain or branched chains below.
Also, as the above-mentioned anionic surfactant with sulfate group and polyoxy alkylidene, with regard to the viewpoint of cleaning force
For, it is however preferred to have carbon atom number is 8 or more, is preferably 10 or more and 21 or less, is preferably 18 or less, more preferably
14 or less, and then the alkyl of preferably 12 linear chain or branched chains below and have the oxygen below of carbon atom number 2 or more and 3 sub-
The average addition molal quantity of alkyl is preferably 0.1 or more, more preferably 0.3 or more and then preferably 0.4 or more and preferably
For 6 or less, more preferably 3 or less and then the polyoxyalkylene alkyl ether sulfuric ester of preferably 1.5 polyoxy alkylidenes below
Salt.
Also, being preferably selected from for the viewpoint of cleaning force as with sulfonic above-mentioned anionic surfactant
(1) alkylbenzene sulfonate with the alkyl below of carbon atom number 6 or more and 15 and 8 or more (2) carbon atom number, preferably 10
Above and 21 or less, preferably 18 or less, more preferably 14 or less, and then preferably 12 alkyl sulfonates below in a kind
Above anionic surfactant.
The salt of anionic surfactant as (a2) ingredient, preferably are as follows: in sodium salt, ammonium salt, sylvite, magnesium salts etc.
Inorganic salts；Organic ammonium salt in single ethanol ammonium salt, diethanolammonium salts, tri ethanol ammonium salt, alkylbenzyldimethylasaltsum saltsum etc..
As (a2) ingredient, for the viewpoint of fitment stability and foaming characteristic, the preferably chemical combination of the following general formula (a2)
Object.
R11a-O-(R12aO)n-SO3M2 (a2)
[in formula, R11aFor the alkyl of the linear chain or branched chain below of carbon atom number 8 or more and 21, R12aFor ethylidene and/or Asia
Propyl, n are average addition molal quantity, and are 0 or more and 6 numbers below；M2It is preferably inorganic or have for hydrogen atom or cation
The cation of machine.]
In general formula (a2), about R11a, for the viewpoint of cleaning force, be 8 or more carbon atom number, preferably 10 or more, simultaneously
And 21 or less, preferably 18 or less, more preferably 14 or less, and then preferably 12 linear chain or branched chains below alkyl, preferably
For straight chained alkyl.Specifically, R11aThe alkane being preferably selected from octyl, decyl, dodecyl, tridecyl and myristyl
Base, more preferably dodecyl.
In general formula (a2), about n, for the viewpoint of cleaning force, preferably 0.1 or more, more preferably 0.3 or more, into
And preferably 0.4 or more and preferably 6 or less, more preferably 3 or less and then preferably 1.5 numbers below.
In general formula (a2), in R12aFor ethylidene situation when, for the viewpoint of cleaning force, n is preferably 0.1 or more, more
Preferably 0.5 or more and preferably 6 or less, 3 numbers below are more preferably.
Also, in general formula (a2), in R12aFor propylidene situation when, for the viewpoint of cleaning force, n be preferably 0.1 with
Upper, more preferably 0.2 or more and then preferably 0.4 or more and preferably 1.5 or less, more preferably 1.0 or less, Jin Eryou
It is selected as 0.8 number below.
Also, in general formula (a2), in R12aWhen for the situation of ethylidene and propylidene, n can be selected respectively from their ranges.
In general formula (a2), M2The inorganic cations such as hydrogen atom or sodium ion, ammonium ion, potassium ion, magnesium ion can be enumerated；
The organic cations such as monoethanol ammonium ion, diethanol ammonium ion, triethanol ammonium ion, morpholinium ion；Preferably sodium ion, potassium
Ion, ammonium ion, magnesium ion inorganic cation.
The preparation method of compound as general formula (a2), is not particularly limited, for example, as follows manufacture: to
R11aFatty alcohol represented by-OH is aoxidized using selected from three thereafter according to the ethylene oxide and/or oxypropylene of purpose addition specific quantity
Sulphur (liquid or gas) carries out Sulfation containing the sulfating agent in sulfur trioxide gas, oleum, chlorosulfonic acid, and utilizes
Specific alkaline agent is neutralized.The addition reaction of ethylene oxide (hereinafter, being labeled as EO) and/or oxypropylene (hereinafter, being labeled as PO)
Catalyst is needed, the alkali metal hydroxides such as NaOH, KOH can be used.Also, Japanese Unexamined Patent Publication 8-323200 bulletin note can be used
Carry using magnesia as the catalyst of principal component, the former can get addition molal quantity be distributed it is relatively wide polyxyethylated
Ether, the latter can get the compound with the distribution of relatively narrow addition molal quantity.Also, also can be such as Japanese Unexamined Patent Publication 10-
By the way that basic catalyst and metal oxide catalyst to be used in combination as No. 158384 bulletins are disclosed, and control addition molal quantity point
Cloth.
In general formula (a2), R is being obtained11aWhen the situation of the compound of the alkyl comprising branch, as raw material with
R11aAlcohol represented by-OH can be enumerated: carry out hydrogen hydroformylation alcohol obtained (packet to the 1- alkene below of carbon atom number 8 or more and 14
There is the alkyl of methyl in the position the β branch below in OH base containing 15 moles of % or more and 70 mole of %), make carbon atom number 4 or more and 8
Restored after aldehyde below condensation and obtain Guerbet (Guerbet) type alcohol (comprising 100 moles of % in OH base
There are the group of the structure of the alkyl below of carbon atom number 3 or more and 6 in β branches), carry out hydrogen hydroformylation to the dimer of isobutene and
The 3,5,5- trimethyl hexanol of acquisition, the multiple-limb tridecanol (branching ratio that hydrogen hydroformylation is carried out to the trimer of isobutene and is obtained
For 100 moles of %), using petroleum, coal, as the synthol of raw material, (branching ratio is that about 20 moles of % or more and 100 mole of % are below
Alkyl).
In the present invention, as (a2) ingredient, it is compound represented by general formula (a2), preferably following compound: includes
Preferably 8 or more carbon atom number, more preferably 10 or more and preferably 18 or less, more preferably 14 or less, and then preferably
12 straight chained alkyls below are as R11a, comprising propylidene as R12a, n is preferably 0.1 or more, more preferably 0.2 or more, in turn
Preferably 0.4 or more and preferably 1.5 hereinafter, more preferably 1.0 or less and then preferably 0.8 number below.
As other anionic surfactants, the fatty acid below of carbon atom number 10 or more and 14 or its salt can be enumerated
Deng.
< (b) ingredient >
Hard surface liquid ceanser compositions used in the present invention are preferably that the amphoteric surface for containing (b) ingredient lives
Property agent be used as (I) ingredient.As amphoteric surfactant, can enumerate in amine oxide, sulfobetaines and carboxybetaine
1 kind or more of amphoteric surfactant.Amphoteric surfactant is preferably sulfobetaines.
As amine oxide, the preferably compound of the following general formula (b1).
[in formula, R1bIndicate the alkyl below of carbon atom number 8 or more 22, preferably alkyl or alkenyl, more preferably alkyl,
R2bAnd R3bIt is identical or different, indicate the alkyl below of carbon atom number 1 or more and 3.D expression-NHC (=O)-base or-C (=O)
NH- base, E indicate the alkylidene below of carbon atom number 1 or more and 5；M and p expression m=0 and p=0 or m=1 and p=1.]
In above-mentioned general formula (b1), for the viewpoint of the cleaning force of solid grease, R1bPreferably carbon atom number
10 or more and 18 alkyl below, the more preferably alkyl below of carbon atom number 12 or more and 16, and then preferably carbon atom number
12 or more and 14 alkyl below, the further preferably alkyl of carbon atom number 12.With respect to the cleaning force of solid grease
For viewpoint, R2b、R3bThe preferably methyl of carbon atom number 1.
As sulfobetaines, can enumerate: the carbon atom number of alkyl is preferably 10 or more, is preferably 18 or less, more preferable
For 14 N- alkyl-N, N- dimethyl-N-sulfopropyl ammonium sulfobetaines below；The carbon atom number of alkyl is preferably 10 or more,
Preferably 18 or less, 14 N- alkyl-N, N- dimethyl-N-(2- hydroxyl sulfopropyl) ammonium sulfobetaines below are more preferably；
The carbon atom number of alkanoyl is preferably 10 or more, preferably 18 or less, more preferably 14 N- alkanoylamino propyl-N below,
N- dimethyl-N-sulfopropyl ammonium sulfobetaines；The carbon atom number of alkanoyl is preferably 10 or more, is preferably 18 or less, more excellent
It is selected as 14 N- alkanoylamino propyl-N, N- dimethyl-N-(2- hydroxyl sulfopropyl) ammonium sulfobetaines below.
As carboxybetaine, the carbon atom number that can enumerate alkyl is preferably 10 or more, is preferably 18 or less, is more preferably
Compound represented by 14 N- alkyl-N, N- dimethyl-N-carboxymethyl group ammonium glycine betaines below or the following general formula (b2) is just clear
It washes for the viewpoint of power, preferably compound represented by the following general formula (b2).
[in formula, R4bIndicate the alkyl or alkenyl below of carbon atom number 7 or more and 21, R5bIndicate propylidene, R6bAnd R7bPoint
It is not independent, indicate the alkyl below of carbon atom number 1 or more and 3.]
In general formula (b2), R4bPreferably 9 or more, be more preferably 11 or more and preferably 15 or less, more preferably 13 with
Under alkyl or alkenyl, preferably nonyl, decyl, undecyl, dodecyl, tridecyl.
In general formula (b2), R6bAnd R7bIndependently, preferably methyl.
< (c) nonionic surfactant >
The non-ionic surface that hard surface liquid ceanser compositions used in the present invention can contain (c) ingredient is living
Property agent be used as (I) ingredient.
As nonionic surfactant, it is 6 or more and 18 alkyl below that can enumerate, which has carbon atom number selected from (c1),
Glycerin ether [hereinafter referred to as (c1) ingredient] and (c2) the following general formula (c2) represented by compound [hereinafter referred to as (c2) at
Point] one or more of nonionic surfactant.About (c) ingredient, (c1) ingredient and (c2) ingredient can be used in combination, also may be used
Using only any one.For the viewpoint of washability, (c) ingredient is preferably (c1) ingredient.
R2cO-(EO)z-H (c2)
[in formula, R2cFor the alkyl of carbon atom number 6 or more and 18 straight chain and/or branch below, EO is inferior ethoxyl, z table
Show the average addition molal quantity of EO, for more than 0 and 100 numbers below.]
As (c1) ingredient, the preferably compound of the following general formula (c1).
R1c-O-(Gly)r-H (c1)
[in formula, R1cIndicate the alkyl below of carbon atom number 6 or more and 18, Gly indicates the structural unit for being originated from glycerol, excellent
It is selected as removing residue made of 1 hydroxyl and 1 hydrogen atom from glycerol, r indicates 1 or more and 4 numbers below.]
In general formula (c1), R1cPreferably 6 or more carbon atom number, more preferably 7 or more carbon atom number and then preferably carbon
8 or more atomicity and preferably 18 or less carbon atom number, more preferably 12 or less carbon atom number and then preferably carbon atom
The alkyl below of number 10.As R1c, straight chained alkyl and branched alkyl can be enumerated.As straight chained alkyl, can enumerate hexyl, heptyl,
The straight chained alkyls such as octyl, nonyl, decyl.In the present invention, for the viewpoint of cleaning force, preferably branched alkyl.As branch
Alkyl, the group being preferably selected from 2- ethylhexyl, secondary octyl, isononyl and isodecyl, more preferably 2- ethylhexyl or
Isodecyl, and then preferably 2- ethylhexyl.
In general formula (c1), r is preferably 1 or more, also, preferably 2 hereinafter, more preferably r be 1 compound.In turn
Preferred compound is R1cFor 2- ethylhexyl and compound that r is 1.
In general formula (c1), structure represented by Gly is 1 of the glycerol-CH being bonded with 3 hydroxyls2CH(OH)CH2-
- CH (the CH of 1 of represented structure or glycerol and 2 hydroxyl bonds2OH)CH2Represented structure, because of catalyst or
Reaction condition and it is different.
In order to obtain the compound of general formula (c1), such as following method can be used: using R1cAlkylol represented by-OH is made
For the alcohol of carbon atom number 6~10, BF is used3Equal acid catalysts or Al catalysts make the epoxies such as itself and epihalohydrins or glycide
Compound is reacted and is manufactured.
For example, when using the situation of 2-Ethylhexyl Alcohol, 2- ethylhexyl list glycerin ether such as Japanese Unexamined Patent Publication obtained
As 2001-49291 bulletin is recorded, for the mixture that may include multi-products.
(c2) ingredient is compound represented by the following general formula (c2).
R2cO-(EO)z-H (c2)
[in formula, R2cFor the alkyl of the branch below of carbon atom number 6 or more and 18, EO is inferior ethoxyl, and z indicates that EO's is flat
Equal addition molal quantity, for more than 0 and 100 numbers below.]
R for the viewpoint of cleaning, in general formula (c2)2cCarbon atom number be 6 or more, preferably 8 or more, more preferably
It is 10 or more, and then preferably 12 or more, also, for 18 hereinafter, preferably 14 or less.
R for the viewpoint of cleaning, in general formula (c2)2cPreferably secondary alkyl.Herein, so-called secondary alkyl is from secondary
Alcohol removes residue obtained by hydroxyl-removal, the R in general formula (c2)2cR in O, with O bond2cCarbon atom become secondary carbon.This
In invention, secondary alkyl is included in the alkyl of branch.
In general formula (c2), for the viewpoint of cleaning, the average addition molal quantity z of EO is more than 0, preferably 1 or more, more
Preferably 3 or more, and then preferably 5 or more, also, be 110 hereinafter, preferably 50 hereinafter, more preferably 30 hereinafter, excellent in turn
20 are selected as hereinafter, further preferably 12 hereinafter, still more preferably for 10 or less.
Furthermore as long as lossless effect of the invention, the compound of general formula (c2) also can so that addition oxypropylene.
As other nonionic surfactants, alkyl polyglycoside (glucoside type nonionic surfactant) etc. can be enumerated.
The content > of < (I) ingredient etc.
The hard surface liquid ceanser compositions used in the present invention contain for the viewpoint of cleaning force
(I) 1 mass % of ingredient or more, preferably 2 mass % or more, more preferably 3 mass % or more, so preferably 4 mass % with
On, also, with regard to the reduction of cost of material, discharge viewpoint for, preferably 18 mass % are hereinafter, more preferably 15 mass %
Hereinafter, being in turn preferably 12 mass % hereinafter, being in turn preferably 10 mass % hereinafter, being in turn preferably 8 mass % hereinafter, in turn
Preferably 6 mass % or less.
The hard surface liquid ceanser compositions used in the present invention, for the viewpoint of cleaning force, preferably
For containing 0.25 mass % of (a) ingredient or more, more preferably 0.5 mass % or more, and then preferably 1 mass % or more, in turn
Preferably 2 mass % or more, and then preferably 4 mass % or more, also, with regard to the reduction of cost of material, the viewpoint of discharge and
Speech, preferably 10 mass % hereinafter, more preferably 8 mass % hereinafter, in turn be preferably 6 mass % hereinafter, in turn be preferably 5 matter
Measure % or less.
(I) in ingredient, about the ratio of (a) ingredient, for the viewpoint of cleaning force, preferably 10 mass % or more, more
Preferably 20 mass % or more, and then preferably 30 mass % or more, and then preferably 40 mass % or more, also, just with two
Property surfactant, nonionic surfactant and use and make cleaning force promoted viewpoint for, preferably 90 mass % hereinafter,
More preferably 80 mass % hereinafter, be preferably 70 mass % hereinafter, being in turn preferably 60 mass % or less in turn.
The hard surface liquid ceanser compositions used in the present invention, for the viewpoint of cleaning force, preferably
For containing 0.25 mass % of (a1) ingredient or more, more preferably 0.5 mass % or more, and then preferably 0.8 mass % or more, into
One step is preferably 1 mass % or more, further preferably 1.7 mass % or more, also, with regard to the reduction of cost of material, discharge
Viewpoint for, preferably 30 mass % hereinafter, more preferably 20 mass % hereinafter, in turn be preferably 15 mass % hereinafter, into
One step is preferably 10 mass % hereinafter, further preferably 8 mass % are hereinafter, further preferably 5 mass % or less.
Furthermore in the present invention, the record (quality % or mass ratio) of the quality about (a1) ingredient is based on M1It is assumed that
Quality (ratio in terms of sodium salt conversion) when for sodium.
Also, the hard surface liquid ceanser compositions used in the present invention contain for the viewpoint of cleaning force
Have a 0 mass % of (a2) ingredient or more, also, 3 mass % hereinafter, preferably 2.5 mass % hereinafter, more preferably 2 mass % with
Under, so preferably 1.5 mass % hereinafter, further preferably 1 mass % hereinafter, further preferably not up to 1 mass %, into
One step be preferably 0.5 mass % hereinafter, further preferably not up to 0.5 mass %, further preferably 0.1 mass % hereinafter,
Further preferably not up to 0.1 mass %.It also can be 0 mass % in the composition about the content of (a2) ingredient.
Also, the hard surface liquid ceanser compositions used in the present invention, just by the hard surface liquid
It, also can be preferred containing (a2) ingredient for the viewpoint for increasing foam specific volume when the situation that cleansing composition is used in the form of blister
For 0.1 mass % or more, more preferably 0.3 mass % or more.Upper limit value when this situation can be selected from above range.
In the present invention, the record (quality % or mass ratio) of the quality about (a2) ingredient is based on leading to (a2) ingredient
M in formula (a2)2It is assumed to the quality (ratio in terms of sodium salt conversion) when sodium.
Also, the hard surface liquid ceanser compositions used in the present invention, for the viewpoint of cleaning force,
(a2) ingredient/(a1) ingredient mass ratio is preferably 1 hereinafter, more preferably 0.8 hereinafter, being in turn preferably 0.6 hereinafter, excellent in turn
Be selected as 0.4 hereinafter, in turn be preferably 0.2 hereinafter, in turn be preferably 0.1 hereinafter, in turn preferably not up to 0.1, and then preferably
0.05 hereinafter, also, preferably 0 or more, also can be 0.
The hard surface liquid ceanser compositions used in the present invention, for the viewpoint of cleaning force, (a1)
Ingredient/(I) ingredient mass ratio is preferably 0.1 or more, more preferably 0.3 or more, also, preferably 0.9 hereinafter, more preferably
0.7 or less.
The hard surface liquid ceanser compositions used in the present invention, for the viewpoint of cleaning force, (a2)
Ingredient/(I) ingredient mass ratio is preferably 0 or more, also, preferably 0.5 hereinafter, more preferably 0.3 or less.
The hard surface liquid ceanser compositions used in the present invention, for the viewpoint of cleaning force, preferably
For containing 0.25 mass % of (b) ingredient or more, more preferably 0.5 mass % or more, and then preferably 1 mass % or more, also,
Preferably 8 mass % hereinafter, more preferably 6 mass % hereinafter, in turn be preferably 4 mass % or less.
The hard surface liquid ceanser compositions used in the present invention, for the viewpoint of cleaning force, preferably
For containing 0.25 mass % of sulfobetaines or more, more preferably 0.5 mass % or more, and then preferably 1 mass % or more, and
And preferably 8 mass % hereinafter, more preferably 6 mass % hereinafter, in turn be preferably 4 mass % or less.
The hard surface liquid ceanser compositions being used in the present invention contain (a) ingredient and (b) situation of ingredient
When, for the viewpoint of cleaning force, the mass ratio of (a) ingredient/(b) ingredient is more than 0, preferably 0.1 or more, more preferably 0.2
More than, and then preferably 0.3 or more, further preferably 0.5 or more, further preferably 0.7 or more, also, it is just identical
For viewpoint, preferably 10 hereinafter, more preferably 8 hereinafter, in turn be preferably 6 hereinafter, in turn be preferably 4 hereinafter, in turn preferably
It is 3 or less.
The hard surface liquid ceanser compositions used in the present invention, for the viewpoint of cleaning force, (b) at
Point/mass ratio of (I) ingredient is preferably 0.1 or more, more preferably 0.3 or more, also, preferably 0.9 hereinafter, more preferably
0.7 or less.
The hard surface liquid ceanser compositions used in the present invention, for the viewpoint of cleaning force, (a1)
The mass ratio of ingredient/(b) ingredient is preferably 0.1 or more, and more preferably 0.3 or more, also, preferably 10 hereinafter, more preferably 3
Below.
When the hard surface liquid ceanser compositions being used in the present invention contain the situation of (c) ingredient, just clean
For the viewpoint of power, the composition preferably contains 0.1 mass % of (c) ingredient or more, more preferably 0.3 mass % or more, into
And preferably 0.5 mass % or more, further preferably 1 mass % or more, further preferably 1.5 mass % or more, also,
With regard to reduce cost of material viewpoint for, preferably 30 mass % hereinafter, more preferably 20 mass % hereinafter, in turn be preferably 15
Quality % is hereinafter, be still more preferably 10 mass % hereinafter, being still more preferably 8 mass % hereinafter, still more preferably
For 5 mass % hereinafter, being still more preferably 3 mass % or less.
[(II) ingredient]
(II) ingredient is chelating agent.
As chelating agent, it is preferably selected from one or more of amino carboxylic acid, hydroxycarboxylic acid, hydroxyethylidene diphosphonic acid and their salt
Compound.
As amino carboxylic acid and its salt, can enumerate selected from ethylenediamine tetra-acetic acid (EDTA), itrile group triacetic acid (NTA), imido
Base oxalic acid, diethylene-triamine pentaacetic acid (DPTA), N- hydroxyethyl-ethylenediamine triacetic acid (HEDTA), methylglycine two
It is one kind or two or more in acetic acid (MGDA), aspartic acid oxalic acid (ASDA), glutamic acid diacetic acid (GLDA) and their salt.
Amino carboxylic acid and its salt are preferably selected from ethylenediamine tetra-acetic acid and its salt, methylglycine diacetic acid and its salt and L- paddy ammonia
It is one kind or two or more in sour oxalic acid and its salt.
As hydroxycarboxylic acid and its salt, the compound being preferably selected from aliphatic hydroxyl carboxylic acid and its salt.As hydroxyl
Carboxylic acid and its salt can enumerate the compound in malic acid, citric acid and its salt.
As hydroxyethylidene diphosphonic acid and its salt, can enumerate in 1-Hydroxy ethylene-1,1-diphosphonic acid (HEDP) and its salt
Compound.
The salt of chelating agent can enumerate alkali metal salt, ammonium salt, amine salt etc..Preferably alkali metal salt, more preferably sodium salt or potassium
Salt.
Chelating agent is preferably hydroxycarboxylic acid and its salt, more preferably aliphatic hydroxyl carboxylic acid and its salt, and then preferably lemon
Lemon acid and its salt, further preferably citrate.
Contain for the viewpoint of cleaning force about hard surface liquid ceanser compositions used in the present invention
(II) 1 mass % of ingredient or more, preferably 1.5 mass % or more, more preferably 1.8 mass % or more, and then preferably 2 matter
% or more is measured, also, cost is reduced, for the viewpoint of cleaning force, preferably 18 mass % are hereinafter, more preferably 15 mass %
Hereinafter, being in turn preferably 12 mass % hereinafter, being in turn preferably 10 mass % hereinafter, being in turn preferably 8 mass % hereinafter, in turn
Preferably 5 mass % or less.Furthermore in the present invention, the quality of (II) ingredient is the amount of acid conversion.
About hard surface liquid ceanser compositions used in the present invention, for the viewpoint of cleaning force, (II)
Ingredient/(I) ingredient mass ratio is 0.25 or more, preferably 0.30 or more, and then preferably 0.35 or more, and then preferably
0.40 or more, and then preferably 0.50 or more, and then preferably 0.60 or more, also, with regard to the reduction of cost of material, cleaning force
For viewpoint, preferably 5.0 hereinafter, more preferably 4.0 hereinafter, in turn be preferably 3.0 hereinafter, in turn be preferably 2.0 hereinafter, into
And preferably 1.5 hereinafter, in turn be preferably 1.0 hereinafter, in turn be preferably 0.90 hereinafter, in turn be preferably 0.70 or less.
The hard surface liquid ceanser compositions being especially used in the present invention contain (a) ingredient and (b) ingredient
Situation when, about hard surface liquid ceanser compositions used in the present invention, for the viewpoint of cleaning force, (II)
Ingredient/(I) ingredient mass ratio is 0.25 or more, preferably 0.30 or more, and then preferably 0.35 or more, and then preferably
0.40 or more, and then preferably 0.50 or more, and then preferably 0.60 or more, also, with regard to the reduction of cost of material, cleaning force
For viewpoint, preferably 5.0 hereinafter, more preferably 4.0 hereinafter, in turn be preferably 3.0 hereinafter, in turn be preferably 2.0 hereinafter, into
And preferably 1.5 hereinafter, in turn be preferably 1.0 hereinafter, in turn be preferably 0.90 or less.
[conductivity]
About hard surface liquid ceanser compositions used in the present invention, for the viewpoint of cleaning force, conductance
Rate (or conductivity) (stoste, 25 DEG C, S/m) is 0.70 or more, preferably 0.80 or more, more preferably 1.0 or more, and then preferably
It is 1.2 or more, and then preferably 1.4 or more, and then preferably 1.6 or more, also, for identical viewpoint, preferably 10
Hereinafter, more preferably 9.0 hereinafter, in turn be preferably 8.0 hereinafter, in turn be preferably 7.0 hereinafter, in turn be preferably 6.0 hereinafter, into
And preferably 5.5 or less.
Conductivity can make its rising by addition salt etc..
As long as conductivity is in above range, no matter hard surface liquid ceanser compositions used in the present invention
Preparation sequence how.For example, sodium citrate can be directly added to raw material, it also can be by adding citric acid and NaOH respectively
Make the presence of neutralization salt in composition Deng acid and alkali is added respectively.Also, for example also can be by being respectively cooperating with methylglycine diethyl
Sour trisodium and HCl, and pH value is adjusted to neutrality and is adjusted so as to conductivity higher.With regard to hard surface used in the present invention
For viewpoint with the conformability of liquid ceanser compositions, the methods of (II) ingredient as salt such as citric acid are preferably added.
The measuring method of conductivity is as recorded in embodiment.
[pH value]
About hard surface liquid ceanser compositions used in the present invention, just make the conductivity of composition rise and
It is preferably 4 or more in 25 DEG C of pH value for the viewpoint for improving cleaning force, more preferably 5 or more, and then preferably 5.5 or more,
Also, for the viewpoint of cleaning force, preferably 10 hereinafter, preferably 9 hereinafter, more preferably 8 hereinafter, in turn be preferably 7 with
Under.
[other compositions etc.]
Hard surface liquid ceanser compositions used in the present invention can be containing in addition to (I) ingredient, (II) ingredient
Ingredient.
< (III) ingredient >
The hard surface liquid ceanser compositions used in the present invention, for the viewpoint of fitment stability,
Preferably contain solvent and is used as (III) ingredient.Solvent is preferably water-miscible organic solvent, which is preferably carbon
2 or more atomicity, more preferably 3 or more carbon atom number, preferably carbon atom number 10 hereinafter, more preferably carbon atom number 8 hereinafter,
As concrete example, it is more preferably selected from ethyl alcohol, isopropanol, ethylene glycol, propylene glycol, diethylene glycol, dipropylene glycol, glycerol, isoamyl
Glycol, propylene glycol monomethyl ether, dihydroxypropane single-ether, 3- methyl -3- methoxybutanol, phenoxetol, benzoglycols, phenoxy group
Water-miscible organic solvent in isopropanol, butyl (diethylene glycol monobutyl ether), dibutyl ethylene glycol ether and benzylalcohol.
Wherein, the water-miscible organic solvent for one or more of and then being preferably selected from butyl, ethyl alcohol and propylene glycol.This
Place, so-called water-miscible organic solvent refer to that Octanol/water Partition Coefficients (LogPow) is 3.5 solvents below.
The hard surface liquid ceanser compositions used in the present invention, with regard to the sight of cleaning force and fitment stability
For point, preferably contain 0.5 mass % of (III) ingredient or more, more preferably 2 mass % or more, and then preferably 4 mass %
More than, also, preferably 30 mass % hereinafter, more preferably 20 mass % hereinafter, in turn be preferably 10 mass % or less.
When the hard surface liquid ceanser compositions being used in the present invention contain the situation of (III) ingredient, about
(III) mass ratio of the content of ingredient and total content of (I) ingredient is (III) ingredient/(I) ingredient mass ratio, is just cooperated
For stability, the viewpoint of cleaning force, preferably 0.5 or more, more preferably 1 or more, and then preferably 1.2 or more, further
Preferably 1.5 or more, also, for identical viewpoint, preferably 5 hereinafter, more preferably 4 hereinafter, be preferably in turn 3 with
Under, further preferably 2.5 or less.
< (IV) ingredient >
The hard surface liquid ceanser compositions used in the present invention, for the viewpoint of fitment stability,
Solubilizer can be contained and be used as (IV) ingredient.As solubilizer, toluenesulfonic acid, xylene monosulfonic acid, isopropyl sulfonic acid or their sodium,
Potassium or magnesium salts are good, and especially p-methyl benzenesulfonic acid or its salt is good.
The hard surface liquid ceanser compositions used in the present invention, for the viewpoint of fitment stability,
Preferably contain 0.5 mass % of (IV) ingredient or more, more preferably 1 mass % or more, and then preferably 1.5 mass % or more,
Also, preferably 15 mass % hereinafter, more preferably 10 mass % hereinafter, in turn be preferably 5 mass % or less.
In addition to them, hard surface liquid ceanser compositions used in the present invention can also contain polyalkylene two
The tackifiers such as the anti-gelling agents such as alcohol, polyacrylic acid, enzyme, fragrance, dyestuff, pigment, fungicide, preservative, pH adjuster etc.
Ingredient.
In the hard surface liquid ceanser compositions being used in the present invention, about the content of solid content ingredient, just
It is 2 mass % or more, preferably 3 mass % or more, more preferably 4 mass % or more for the viewpoint of cleaning force, also, just
Reduce cost of material viewpoint and using have sprayer container when discharge viewpoint for, preferably 60 mass % with
Under, more preferably 50 mass % hereinafter, be preferably 45 mass % hereinafter, further preferably 40 mass % are hereinafter, into one in turn
Step be preferably 35 mass % hereinafter, further preferably 30 mass % hereinafter, further preferably 25 mass % hereinafter, further
Preferably 20 mass % or less.
Herein, so-called solid content ingredient, be above-mentioned (I)~(IV) ingredient and other any ingredients, i.e., than water at
Point.
Hard surface liquid ceanser compositions used in the present invention contain water.That is, removing above-mentioned (I)~(IV) ingredient
And the remainder other than any ingredient is water.Hard surface liquid ceanser compositions used in the present invention preferably contain
There are 30 mass % of water or more, more preferably 50 mass % or more, and then preferably 60 mass % or more, further preferably 70 matter
Measure % or more, also, preferably 99 mass % hereinafter, more preferably 95 mass % hereinafter, further preferably 90 mass % with
Under.Water preferably uses ion exchange water, sterilization ion exchange water etc..
Hard surface used in the present invention with liquid ceanser compositions 20 DEG C of viscosity be preferably 0.5mPas with
On, more preferably 1mPas or more, also, preferably 50mPas hereinafter, more preferably 20mPas hereinafter, in turn preferably
For 10mPas hereinafter, further preferably 7mPas is hereinafter, further preferably 5mPas or less.Viscosity can utilize solvent
Or solubilizer etc. is adjusted.
< cleaning method >
The cleaning method of hard surface of the invention is to make above-mentioned hard surface liquid ceanser compositions and be attached with
The hard surface of greasy dirt comprising solid grease especially tableware contacts, and cleaned in the case where not applying mechanical force
The cleaning method of hard surface.This method is suitable for the position that hand or stage property reach or is difficult to the clear of the discreet portions got at
It washes.
The cleaning method of hard surface of the invention preferably makes above-mentioned hard surface liquid ceanser compositions not
It is contacted in diluted situation with the hard surface for being attached with the greasy dirt comprising solid grease.
The cleaning method of hard surface of the invention preferably makes above-mentioned hard surface liquid ceanser compositions not
It is contacted in diluted situation with the hard surface for being attached with the greasy dirt comprising solid grease, and in the case where not applying mechanical force
It is cleaned.
Cleaning method of the invention preferably makes above-mentioned hard surface liquid ceanser compositions in undiluted situation
It is lower to be contacted with the hard surface for being attached with the greasy dirt comprising solid grease, and place and carry out in the case where not applying mechanical force
Cleaning.
About the cleaning hard surfaces in the case where not applying mechanical force, for example, in addition to the contact of composition, not into
The operation deliberately of behavior cleaning.For example, the composition of contact flows down or is not intended to be cleaned naturally in hard surface
Vibration reach hard surface etc. and can be regarded as the cleaning hard surfaces in the case where not applying mechanical force.On the other hand, such as
Clean the method for hard surface or the water flow that hard surface applications include composition is cleaned method, by hard surface
Be immersed in the cleansing medium comprising composition and be stirred and the method etc. cleaned can be regarded as applying mechanical force it is clear
Wash hard surface.
It is so-called to make above-mentioned hard surface liquid ceanser compositions in undiluted situation and be attached with comprising solid
The hard surface of the greasy dirt of grease contacts, be make the cleansing composition not after being purposely diluted using water etc. with it is attached
Have the greasy dirt comprising solid grease hard surface contact.For example, following situation can be regarded as making above-mentioned hard surface liquid
Body cleansing composition contacts in undiluted situation with the hard surface for being attached with the greasy dirt comprising solid grease: making above-mentioned
Hard surface liquid ceanser compositions are contacted with the hard surface for being attached with water droplet etc.；Or make above-mentioned hard surface liquid
After cleansing composition is contacted with hard surface, water droplet is attached to hard surface.
It is usually rinsed using water after placing.When flushing, apply mechanical force (physical force) using hand etc., it also can be only
It is rinsed using water flow.
As cleaning method of the invention, cleaning method can be listed below: make above-mentioned hard surface liquid ceanser group
It closes object to contact with the hard surface for being attached with the greasy dirt comprising solid grease, without the cleaning using flexible material, benefit
With the cleaning of flowing water and using ultrasonic wave cleaning it is any in the case where, directly put in the case where not applying mechanical force
It sets.That is, as cleaning method of the invention cleaning method can be listed below: combining above-mentioned hard surface with liquid ceanser
Object is contacted with the hard surface for being attached with the greasy dirt comprising solid grease, without using the friction using flexible materials such as sponges
Power, the flowing water power using water jet in automatic tableware cleaning machine etc. and any situation of the vibration using ultrasonic wave
Under, it is directly placed in the case where not applying mechanical force.
Greasy dirt comprising solid grease is the grease-contained spot of packet, which is under room temperature (such as 20 DEG C) in solid
Person.It is the greasy dirt comprising solid grease for greasy dirt comprising solid grease is typical, and then to include solid grease and liquid oil
Greasy dirt.The form of the greasy dirt comprising solid grease when contacting above-mentioned hard surface with liquid ceanser compositions can be solid
The state that body grease and liquid oil are mixed.
The present invention is preferably that the stoste of above-mentioned hard surface liquid ceanser compositions is made directly, i.e. not change composition
In the case where be attached to the hard surface for being attached with the greasy dirt comprising solid grease.For example, it is preferable to use above-mentioned hard surface
Liquid ceanser compositions it is non-cohesive in the case wheres aqueous sponge etc. be attached with the hard of the greasy dirt comprising solid grease
The contact of matter surface.After being contacted with hard surface, the composition variable of above-mentioned hard surface liquid ceanser compositions.That is,
After contacting with hard surface, the composition of above-mentioned hard surface liquid ceanser compositions can be made to dilute or be concentrated.
Also, also can previously prepared include the dense composition of (I) ingredient of the invention and (II) ingredient, and benefit is diluted with water
The dense composition and prepare hard surface liquid ceanser compositions used in the present invention, and connect it with hard surface
Touching.That is, also can be the cleaning method of following hard surface: benefit be diluted with water containing (I) ingredient of the invention and (II) ingredient
Dense composition and prepare hard surface liquid ceanser compositions used in the present invention, and make the hard surface liquid
Cleansing composition contacts in undiluted situation with the hard surface for being attached with the greasy dirt comprising solid grease, and is not applying
It is cleaned in the case where adding mechanical force.
The cleaning method of hard surface of the invention is to make above-mentioned hard surface liquid ceanser compositions and hard table
After face contact, placed in the case where not applying and (not assigning) mechanical force.That is, cleaning method can be listed below: not using
Make its contact in the case where the flexible materials such as sponge or finger etc., and is directly placed in the case where not applying mechanical force.It puts
After setting, usually it is rinsed using water.When flushing, apply mechanical force (physical force) using hand etc., it also can be merely with water flow
It is rinsed.
The cleaning method of hard surface of the invention preferably makes above-mentioned hard surface liquid ceanser compositions with phase
For the area 100cm of the hard surface as object2, preferably 0.1g or more, it is more preferably 0.3g or more, is preferred in turn
For 0.4g or more and preferably 5g or less, more preferably 3g or less and then preferably 2g ratio below contacts, in turn, into
Row coating is spraying.
In the cleaning method of hard surface of the invention, for improving the viewpoint of cleaning force, make hard surface liquid
After cleansing composition is contacted with hard surface, preferably place 10 seconds or more, more preferably 20 seconds or more, and then preferably
30 seconds or more, further preferably 40 seconds or more, further preferably 50 seconds or more, further preferably 1 minute or more, and
And for identical viewpoint, preferably 60 minutes hereinafter, more preferably 30 minutes hereinafter, in turn be preferably 20 minutes hereinafter,
Further preferably 10 minutes hereinafter, further preferably 5 minutes or less.When in this respect, initially and firmly by above-mentioned composition
The time point of matter surface contact is set as the beginning placed.
Furthermore temperature when placement is room temperature, such as can enumerate 10 DEG C or more and 30 DEG C or less.
Also, for improving the viewpoint of cleaning force, preferably making above-mentioned hard in the cleaning method of hard surface of the invention
Matter surface liquid cleansing composition contacts 10 seconds or more, more preferably 20 seconds or more with the hard surface as cleaning object,
And then preferably 30 seconds or more, further preferably 40 seconds or more, further preferably 50 seconds or more, further preferably 1 point
More than clock, also, for identical viewpoint, preferably 60 minutes hereinafter, more preferably 30 minutes hereinafter, in turn be preferably 20
Minute hereinafter, further preferably 10 minutes hereinafter, further preferably 5 minutes or less.
Furthermore the temperature during contact is room temperature, such as can enumerate 10 DEG C or more and 30 DEG C or less.
In the cleaning method of hard surface of the invention, the hard surface leaching for being attached with the greasy dirt comprising solid grease can be made
Stain is contacted in above-mentioned hard surface in liquid ceanser compositions, for efficiently improving the viewpoint of cleaning force,
Preferably it is sprayed or is coated with above-mentioned hard surface liquid ceanser compositions and makes it and be attached with the oil comprising solid grease
The method of dirty hard surface contact.
Make above-mentioned hard surface liquid ceanser compositions and the hard surface for being attached with the greasy dirt comprising solid grease
The method of contact is preferably spraying or is coated with, and droplet-like more preferably is made with liquid ceanser compositions in above-mentioned hard surface
It carries out spraying or the method that blister is coated is made.Specifically, it is preferable that use above-mentioned hard surface using spraying means
Liquid ceanser compositions are contacted with the hard surface for being attached with the greasy dirt comprising solid grease.More preferably using will be of the invention
Used in hard surface be filled in the container for have sprayer with liquid ceanser compositions made of hard surface with clear
Lotion article makes above-mentioned hard surface liquid ceanser compositions and the hard surface for being attached with the greasy dirt comprising solid grease
Contact.The present invention provides a kind of automiser spray dress hard surface cleaning agent article, and being will be above-mentioned hard used in the present invention
Matter surface is filled in the container for having sprayer with liquid ceanser compositions and forms.
The above-mentioned container for having sprayer can be enumerated: trigger spray container, pump spray container etc. do not use stock solution
Hand spraying device, use aerosol of stock solution etc..The above-mentioned container for having sprayer is preferably capable content
Droplet-like is made or blister carries out trigger-type sprayer that is spraying or being coated with, more preferably has and content is sprayed into droplet-like
Mechanism trigger-type sprayer or have the trigger-type sprayer of the mechanism (formation of foam mechanism) to form foam.
In above-mentioned automiser spray dress hard surface in cleaning agent article, using it is above-mentioned have hard surface liquid is clear
When the situation of the trigger-type sprayer of the spraying mechanism at droplet-like of detergent composition, about the spraying appearance for being packed into above-mentioned composition
The spout diameter of the jet blower of device, in order to spraying easness or the drop sprayed be not fierce, not linearly it is spraying, can spray
The area of mist does not become extremely narrow, preferably 0.1mm or more, more preferably 0.3mm or more and preferably 2mm or less, more excellent
It is selected as 1mm range below.
When using the situation for the trigger-type sprayer for having the spraying mechanism at droplet-like, above-mentioned automiser spray fills hard
Surface is with cleaning agent article with 1 operation preferably by spraying 0.1mL or more, more preferably 0.3mL or more and preferably 5mL
Below, it is more preferably 2mL composition below.
Also, using the trigger-type for having formation of foam mechanism in above-mentioned automiser spray dress hard surface cleaning agent article
When the situation of sprayer, it is however preferred to have rotary components and the space segment of the round in 4~8mm of diameter are provided with several sticks
The liquid of the protrusion of shape is preferred by plate person.Herein, so-called rotary components are assigned by flow direction of the rotary components to liquid material
Rotation finally can refer to Japanese Unexamined Patent Publication 8-332422 bulletin or day as its detailed structure from the mechanism that nozzle spues
Fig. 4 (b), Fig. 1 of Japanese Unexamined Patent Publication 2002-68265 bulletin of this Japanese Laid-Open Patent Publication 8-108102 bulletin etc..
When using the situation for the trigger-type sprayer for having formation of foam mechanism, above-mentioned automiser spray dress hard surface is used
Cleaning agent article is with 1 operation preferably by spraying 0.5mL or more, more preferably 1mL or more and preferably 30mL or less, more
Preferably 15mL or less and then preferably 5mL composition below.
The liquid of another component as formation of foam mechanism passes through the spatial portion that plate is in the round of 5~7mm of diameter
Set up separately and be equipped with preferably 3~8 rodlike protrusion persons, when observing the situation of the plate passed through under plane, preferably width 0.8~
The rodlike protrusion of the oblong-shaped of 1.2mm, 2~4mm of length is preferred.Also, rodlike protrusion relative to except rodlike protrusion with
Area shared by outer space segment is preferably 30 area % or more, more preferably 40 area % or more, also, preferably 90 faces
Product % hereinafter, more preferably 80 area % hereinafter, be in turn preferably 70 area % hereinafter, by such liquid being arranged by plate,
Foam becomes good in the attachment anelasticity of vertical surface.
General used container can be used in the container of above-mentioned automiser spray dress hard surface cleaning agent article.For example,
For using polyethylene or polypropylene, polyethylene terephthalate as raw material and winner, can be manufactured by blow molding etc..
The thickness of container can be different with bottom surface and side, and preferably 0.01~2mm, the capacity of container is preferably 100~1000mL.About
The amount of filling hard surface liquid ceanser compositions in a reservoir, just in terms of operability for, it is more satisfactory be 200~
500mL.Also, the filling of liquid is to reserve the gap of common-sense and carry out.
The cleaning method of hard surface of the invention is preferably the hard surface for being used as hard article and then tableware and kitchen
The cleaning method of the hard surface of the hard article on periphery and then the hard surface of tableware and then tableware.Also, preferably conduct
The hand washing cleaning method of the hard surface of hard article and then the hand washing of the hard surface of tableware and the hard article on kitchen periphery
Cleaning method and then the hand washing cleaning method of tableware and then the hand washing cleaning method of the hard surface of tableware.
The cleaning method of hard surface of the invention is with the hard surface of hard article, preferably tableware and kitchen periphery
The hard surface of hard article, the more preferably hard surface of tableware and then preferably tableware are as cleaning object.As hard
Article can enumerate the food manufacturings such as pipeline pipe, part machine, the hard article on kitchen periphery, tableware etc..
The hard article on kitchen periphery is the article used in the periphery in kitchen, specifically, are as follows:
(1) place of retention of the food such as refrigerator, kitchen cabinet, tableware, cooking apparatus；
(2) the culinary art place of the food such as discharge outlet, cooking table, enclosure, sink, gas oven, micro-wave oven；And
(3) floor on the periphery in above-mentioned place of retention or above-mentioned culinary art place or wall etc..
In the present invention, for convenience's sake, they are denoted as " hard article on kitchen periphery ".
Also, as tableware, specifically, the component or utensil of food materials contact below can be enumerated:
(i) the so-called tableware such as disk, bowl；
(ii) boxed cassette, bottle etc. save container；
(iii) cooking apparatus such as kitchen knife or chopping board, pot, frying pan, grilled fish frame；
(iv) conditioning such as food processor, mixing machine household electrical appliances etc..
In the present invention, for convenience's sake, they are denoted as " tableware ".
Also, the cleaning method of hard surface of the invention is preferably selected from tableware, preservation container, cooking apparatus and tune
The hard surface of the article to keep house in electricity is object, so more preferably with selected from disk, bowl, boxed cassette, hopper, kitchen knife, chopping board,
Pot, frying pan, grilled fish frame, food processor and the article in mixing machine hard surface be object.
The material of the hard surface of the object of cleaning method as hard surface of the invention, can enumerate plastics (includes
Silicone resin etc.), metal, pottery, timber and their combination.
Also, the cleaning method of hard surface of the invention can effectively clean be attached to these hard surfaces include
The greasy dirt of solid grease.
In the cleaning method of hard surface of the invention, combine hard surface used in the present invention with liquid ceanser
Object is directly contacted with hard surface.Also, due to being placed with the state for contacting above-mentioned composition, so in cleaning, nothing
Need the operation of the application mechanical force such as using the scouring of sponge flexible material.
Therefore, the cleaning method of hard surface of the invention can also be applied following such using pliabilities such as sponges
The difficult article etc. of the cleaning of material:
(1) the pipeline pipe, part and rhone of food manufacturing machine, refrigerator, kitchen cabinet etc., kettle, tumbler or tank,
The inconvenient hard article of the hand washings such as pot cleaning；
(2) food, tableware, the place of retention of cooking apparatus, cooking table, enclosure, sink, gas oven, micro-wave oven etc. are eaten
The tool that the greasy dirt comprising solid grease on the culinary art place of product and its kitchens periphery such as the floor on periphery or wall etc. involves extensively
There is the article of hard surface；
(3) hand washings such as blade of kitchen knife, skinning machine, parer, slicer, the blade of juicer, food processor are cleaned
When with dangerous article；
(4) has the article of complex-shaped part.
Furthermore the present invention also can optionally be cleaned in the case where not applying mechanical force after cleaning hard surfaces.
In turn, the cleaning method of hard surface of the invention is due to being by above-mentioned hard surface liquid ceanser compositions
The above-mentioned composition of preferably blister is coated on hard surface and directly places, so above-mentioned composition can be made to stay in for a long time
Hard surface.
The cleaning method of hard surface of the invention may include being rinsed with water to make above-mentioned hard surface liquid ceanser group
The step of closing the hard surface that object contacted, contacted above-mentioned hard surface with liquid ceanser compositions hard
The step of matter surface is rinsed with water after being placed.
< hard surface liquid ceanser compositions >
Hard surface of the invention is following hard surface liquid ceanser compositions with liquid ceanser compositions: its
Contain surfactant [hereinafter referred to as (I) ingredient] 1 mass % or more, chelating agent [hereinafter referred to as (II) ingredient] 1 mass %
Above and water, and (I) ingredient/(II) ingredient mass ratio is 0.25 or more, is 0.70S/m or more in 25 DEG C of conductivity.It should
Liquid ceanser compositions include the following middle liquid ceanser compositions that hard surface is substituted for tableware.
In hard surface liquid ceanser compositions of the invention, can suitably apply (I) ingredient, (II) ingredient it is specific
Example and preferably the cleaning side of the invention such as preferred range of mode, (I) ingredient/(II) ingredient mass ratio, conductivity etc.
Item described in hard surface liquid ceanser compositions used in method.Hard used in cleaning method of the invention
Surface can be hard surface liquid ceanser compositions of the invention with liquid ceanser compositions.
Hard surface of the invention is preferably oily removal hard surface liquid ceanser with liquid ceanser compositions
Composition.
Hard surface of the invention is preferably used for hard surface with liquid ceanser compositions in undiluted situation
Cleaning, more preferably directly contact it with hard surface in undiluted situation and use.
Hard surface of the invention is used with the hard surface that liquid ceanser compositions are preferably hard article, and then tableware
Or the hard surface of the hard article on kitchen periphery is used, and then tableware is used, and then the hard surface of tableware is used.
Specifically, the hard surface of the invention hard surface that liquid ceanser compositions are preferably in hard article
Coating cleaning agent, more preferably tableware or kitchen periphery hard article hard surface coating cleaning agent, into
And preferably in the coating cleaning agent of tableware, and then preferably in the coating cleaning agent of the hard surface of tableware.
Also, specifically, the hard surface of the invention hard that liquid ceanser compositions are preferably in hard article
The spraying of surface uses cleaning agent, more preferably uses cleaning in the spraying of hard surface of the hard article on tableware or kitchen periphery
Agent, and then cleaning agent preferably is used in the spraying of tableware, further preferably cleaning agent is used in being sprayed for the hard surface of tableware.
Hard surface liquid ceanser compositions of the invention are since the cleaning of solid grease is excellent, so with hard
Article, preferably tableware and the hard article on kitchen periphery, more preferably tableware are cleaning object.
Hard article, the hard article on kitchen periphery, tableware can enumerate above-mentioned person.
Also, hard surface of the invention is preferably selected from tableware with liquid ceanser compositions, saves container, cooking pot
Tool and conditioning household electrical appliances in article use, and then more preferably selected from disk, bowl, boxed cassette, hopper, kitchen knife, chopping board, pot, frying pan,
Article in grilled fish frame, food processor and mixing machine is used.
Also, cleaning object, that is, hard surface of the invention and then the hard surface on tableware and kitchen periphery and then tableware
The material of hard surface can enumerate plastics (comprising silicone resin etc.), metal, pottery, timber and their combination.
In mode of the invention illustrated below.The cleaning side of hard surface of the invention can be suitably applied in these modes
Item described in method and hard surface liquid ceanser compositions.These modes also include that hard surface is substituted for meal
The mode of tool.
1 > of <
A kind of cleaning method of hard surface is to make hard surface liquid ceanser compositions and be attached with comprising solid
The hard surface of the greasy dirt of body grease contacts, and is cleaned in the case where not applying mechanical force, the hard surface liquid
Cleansing composition contains (I) surfactant [hereinafter referred to as (I) ingredient] 1 mass % or more, (II) chelating agent [hereinafter, claiming
For (II) ingredient] 1 mass % or more and water, and contain (a) anionic surfactant [hereinafter referred to as (a) ingredient] conduct
(I) ingredient, (II) ingredient/(I) ingredient mass ratio are 0.25 or more, are 0.70S/m or more in 25 DEG C of conductivity.
2 > of <
The cleaning method of hard surface as described in above-mentioned 1 > of <, wherein (a) ingredient is selected from by (a1) the following general formula
(a1) sulfosuccinate or its salt [hereinafter referred to as (a1) ingredient] and (a2) represented by have carbon atom number 8 or more and 21
Alkyl and sulfate group below or sulfonic anionic surfactant [wherein, in addition to (a1) ingredient] are [hereinafter, claim
One or more of for (a2) ingredient].
[in formula, R1a、R2aIt independently, is the alkyl below of carbon atom number 5 or more and 18；A1、A2It is separately carbon
The alkylidene below of atomicity 2 or more and 4, x, y are average addition molal quantity, and are separately 0 or more and 6 or less；M1
For hydrogen atom or cation.]
3 > of <
The cleaning method of hard surface as described in above-mentioned 2 > of <, in formula of (a1), R1a、R2aIndependently, it is
5 or more carbon atom number, preferably 6 or more, more preferably 7 or more and 18 or less carbon atom number, preferably 16 or less, in turn
Preferably 14 alkyl below.
4 > of <
The cleaning method of hard surface as described in above-mentioned 2 > of < or 3 > of <, in formula of (a1), R1a、R2aRespectively
It is preferably selected from hexyl, octyl, nonyl, decyl, dodecyl, tridecyl, myristyl, 2- ethylhexyl, n-octyl, secondary
Octyl, isopentyl, isononyl, isodecyl, the alkyl in cyclohexyl, are more preferably selected from n-octyl, secondary octyl, decyl, isodecyl
Alkyl in base and 2- ethylhexyl, and then the alkyl being preferably selected from 2- ethylhexyl and tridecyl, it is further excellent
It is selected as 2- ethylhexyl.
5 > of <
The cleaning method of hard surface as described in any one of above-mentioned 2 > of <~<, 4 >, in formula of (a1), M1
Cation be selected from the inorganic cation selected from sodium ion, ammonium ion, potassium ion and magnesium ion and from monoethanol
Ammonium ion, diethanol ammonium ion, triethanol ammonium ion, the cation in the organic cation that selects in morpholinium ion, preferably
For the inorganic cation in sodium ion, ammonium ion, potassium ion and magnesium ion.
6 > of <
The cleaning method of hard surface as described in any one of above-mentioned 2 > of <~<, 5 >, wherein the alkyl of (a2) ingredient
Carbon atom number be 8 or more, preferably 10 or more, more preferably 12 or more, and be 21 hereinafter, preferably 18 hereinafter, more excellent
14 are selected as hereinafter, being in turn preferably 12 or less.
7 > of <
The cleaning method of hard surface as described in any one of above-mentioned 2 > of <~<, 6 >, wherein (a2) ingredient is following
The compound of general formula (a2).
R11a-O-(R12aO)n-SO3M2 (a2)
[in formula, R11aFor the alkyl of the linear chain or branched chain below of carbon atom number 8 or more and 21, R12aFor ethylidene and/or Asia
Propyl, n are average addition molal quantity and are 0 or more and 6 numbers below；M2It is preferably inorganic or have for hydrogen atom or cation
The cation of machine.]
8 > of <
The cleaning method of hard surface as described in above-mentioned 7 > of <, in formula of (a2), R11aFor carbon atom number 8 with
Above, preferably 10 or more and 21 or less, preferably 18 or less, more preferably 14 or less and then preferably 12 straight chains below
Or the alkyl of branch.
9 > of <
The cleaning method of hard surface as described in any one of above-mentioned 1 > of <~<, 8 >, wherein above-mentioned hard surface is used
Liquid ceanser compositions contain (b) amphoteric surfactant [hereinafter referred to as (b) ingredient] and are used as (I) ingredient.
10 > of <
The cleaning method of hard surface as described in above-mentioned 9 > of <, wherein (b) ingredient is sulfobetaines.
11 > of <
The cleaning method of hard surface as described in above-mentioned 10 > of <, wherein sulfobetaines is the carbon atom selected from alkyl
Number preferably 10 or more, preferably 18 or less, more preferably 14 N- alkyl-N, N- dimethyl-N-sulfopropyl ammonium sulfo groups below
Glycine betaine, alkyl carbon atom number be preferably 10 or more, preferably 18 or less, more preferably 14 N- alkyl-N, N- bis- below
Methyl-N- (2- hydroxyl sulfopropyl) ammonium sulfobetaines, alkanoyl carbon atom number be preferably 10 or more, preferably 18 or less,
The carbon of more preferably 14 N- alkanoylamino propyl-N, N- dimethyl-N-sulfopropyl ammonium sulfobetaines and alkanoyl below
Atomicity is preferably 10 or more, preferably 18 or less, more preferably 14 N- alkanoylamino propyl-N, N- dimethyl-below
Sulfobetaines in N- (2- hydroxyl sulfopropyl) ammonium sulfobetaines.
12 > of <
The cleaning method of hard surface as described in any one of above-mentioned 1 > of <~<, 11 >, wherein above-mentioned hard surface
Contain 1 mass % of (I) ingredient or more, preferably 2 mass % or more with liquid ceanser compositions, more preferably 3 mass % with
On, and then preferably 4 mass % or more, also, preferably 18 mass % are hereinafter, more preferably 15 mass % are hereinafter, excellent in turn
12 mass % are selected as hereinafter, being in turn preferably 10 mass % hereinafter, being in turn preferably 8 mass % hereinafter, being in turn preferably 6 matter
Measure % or less.
13 > of <
The cleaning method of hard surface as described in any one of above-mentioned 1 > of <~<, 12 >, wherein above-mentioned hard surface
Containing (a) ingredient with liquid ceanser compositions is preferably 0.25 mass % or more, more preferably 0.5 mass % or more, in turn
Preferably 1 mass % or more, and then preferably 2 mass % or more, and then preferably 4 mass % or more, also, preferably 10 matter
% is measured hereinafter, more preferably 8 mass % hereinafter, be preferably 6 mass % hereinafter, being in turn preferably 5 mass % or less in turn.
14 > of <
The cleaning method of hard surface as described in any one of above-mentioned 1 > of <~<, 13 >, wherein above-mentioned hard surface
With in (I) ingredient of liquid ceanser compositions, the ratio of (a) ingredient is preferably 10 mass % or more, more preferably 20 matter
Measure % or more, and then preferably 30 mass % or more, and then preferably 40 mass % or more, also, preferably 90 mass % with
Under, more preferably 80 mass % hereinafter, be preferably 70 mass % hereinafter, being in turn preferably 60 mass % or less in turn.
15 > of <
The cleaning method of hard surface as described in any one of above-mentioned 2 > of <~<, 14 >, wherein above-mentioned hard surface
Preferably contain 0.25 mass % of (a1) ingredient or more, more preferably 0.5 mass % or more with liquid ceanser compositions, in turn
Preferably 0.8 mass % or more, further preferably 1 mass % or more, further preferably 1.7 mass % or more, also, it is excellent
30 mass % are selected as hereinafter, more preferably 20 mass % hereinafter, be preferably 15 mass % hereinafter, further preferably 10 matter in turn
% is measured hereinafter, further preferably 8 mass % are hereinafter, further preferably 5 mass % or less.
16 > of <
The cleaning method of hard surface as described in any one of above-mentioned 2 > of <~<, 15 >, wherein above-mentioned hard surface
Contain 0 mass % of (a2) ingredient or more with liquid ceanser compositions, also, 3 mass % hereinafter, preferably 2.5 mass % with
Under, more preferably 2 mass % hereinafter, in turn be preferably 1.5 mass % hereinafter, further preferably 1 mass % hereinafter, further
Preferably not up to 1 mass %, further preferably 0.5 mass % hereinafter, further preferably not up to 0.5 mass %, further
Preferably 0.1 mass % is not hereinafter, further preferably up to 0.1 mass %.
17 > of <
The cleaning method of hard surface as described in any one of above-mentioned 2 > of <~<, 16 >, wherein above-mentioned hard surface
It is preferably 1 hereinafter, more preferably 0.8 hereinafter, in turn with (a2) ingredient of liquid ceanser compositions/(a1) ingredient mass ratio
Preferably 0.6 hereinafter, be preferably 0.4 hereinafter, being in turn preferably 0.2 hereinafter, being in turn preferably 0.1 hereinafter, in turn preferably in turn
For not up to 0.1, and then preferably 0.05 hereinafter, also, preferably 0 or more or be 0.
18 > of <
The cleaning method of hard surface as described in any one of above-mentioned 2 > of <~<, 17 >, wherein above-mentioned hard surface
It is preferably 0.1 or more with (a1) ingredient of liquid ceanser compositions/(I) ingredient mass ratio, more preferably 0.3 or more, and
And preferably 0.9 hereinafter, more preferably 0.7 or less.
19 > of <
The cleaning method of hard surface as described in any one of above-mentioned 9 > of <~<, 18 >, wherein above-mentioned hard surface
Preferably contain 0.25 mass % of (b) ingredient or more, more preferably 0.5 mass % or more with liquid ceanser compositions, in turn
Preferably 1 mass % or more, also, preferably 8 mass % hereinafter, more preferably 6 mass % hereinafter, in turn be preferably 4 matter
Measure % or less.
20 > of <
The cleaning method of hard surface as described in any one of above-mentioned 10 > of <~<, 19 >, wherein above-mentioned hard surface
Preferably contain 0.25 mass % of sulfobetaines or more, more preferably 0.5 mass % or more with liquid ceanser compositions, into
And preferably 1 mass % or more, also, preferably 8 mass % hereinafter, more preferably 6 mass % hereinafter, in turn be preferably 4 matter
Measure % or less.
21 > of <
The cleaning method of hard surface as described in any one of above-mentioned 9 > of <~<, 20 >, wherein above-mentioned hard surface
Contain (a) ingredient and (b) ingredient with liquid ceanser compositions, and the mass ratio of (a) ingredient/(b) ingredient is more than 0, preferably
0.1 or more, more preferably 0.2 or more, and then preferably 0.3 or more, and then preferably 0.5 or more, further preferably 0.7 with
On, also, preferably 10 hereinafter, more preferably 8 hereinafter, be preferably 6 hereinafter, being in turn preferably 4 hereinafter, being preferably in turn in turn
3 or less.
22 > of <
The cleaning method of hard surface as described in any one of above-mentioned 9 > of <~<, 21 >, wherein above-mentioned hard surface
It is preferably 0.1 or more with (b) of liquid ceanser compositions ingredient/(I) ingredient mass ratio, more preferably 0.3 or more, and
And preferably 0.9 hereinafter, more preferably 0.7 or less.
23 > of <
The cleaning method of hard surface as described in any one of above-mentioned 1 > of <~<, 22 >, wherein (II) ingredient is choosing
From the compound of one or more of amino carboxylic acid, hydroxycarboxylic acid, hydroxyethylidene diphosphonic acid and their salt.
24 > of <
The cleaning method of hard surface as described in above-mentioned 23 > of <, wherein amino carboxylic acid and its salt are selected from ethylenediamine tetraacetic
Acetic acid (EDTA), itrile group triacetic acid (NTA), iminodiacetic acid, diethylene-triamine pentaacetic acid (DPTA), N- hydroxyethyl-
Ethylenediamine triacetic acid (HEDTA), methylglycine diacetic acid (MGDA), aspartic acid oxalic acid (ASDA), glutamic acid diacetic acid
(GLDA) one kind or two or more and in their salt.
24 > of <
The cleaning method of hard surface as described in above-mentioned 22 > of < or 23 > of <, wherein hydroxycarboxylic acid and its salt be selected from
Compound in aliphatic hydroxyl carboxylic acid and its salt, and then be the compound in malic acid, citric acid and its salt.
25 > of <
The cleaning method of hard surface as described in any one of above-mentioned 1 > of <~<, 24 >, wherein above-mentioned hard surface
Contain hydroxycarboxylic acid and its salt with liquid ceanser compositions so aliphatic hydroxyl carboxylic acid and its salt and then citric acid and its
Salt, citrate is used as (II) ingredient in turn.
26 > of <
The cleaning method of hard surface as described in any one of above-mentioned 1 > of <~<, 25 >, wherein above-mentioned hard surface
Contain 1 mass % of (II) ingredient or more, preferably 1.5 mass % or more, more preferably 1.8 matter with liquid ceanser compositions
Measure % or more, and then preferably 2 mass % or more, also, preferably 18 mass % hereinafter, more preferably 15 mass % hereinafter,
And then preferably 12 mass % hereinafter, be preferably 10 mass % hereinafter, being in turn preferably 8 mass % hereinafter, in turn preferably in turn
For 5 mass % or less.
27 > of <
The cleaning method of hard surface as described in any one of above-mentioned 1 > of <~<, 26 >, wherein above-mentioned hard surface
It is 0.25 or more with (II) ingredient/(I) ingredient mass ratio of liquid ceanser compositions, preferably 0.30 or more, Jin Eryou
It is selected as 0.35 or more, and then preferably 0.40 or more, and then preferably 0.50 or more, and then preferably 0.60 or more, also, excellent
Be selected as 5.0 hereinafter, more preferably 4.0 hereinafter, in turn be preferably 3.0 hereinafter, in turn be preferably 2.0 hereinafter, in turn be preferably 1.5
Hereinafter, being in turn preferably 1.0 hereinafter, being in turn preferably 0.90 hereinafter, being in turn preferably 0.70 or less.
28 > of <
The cleaning method of hard surface as described in any one of above-mentioned 9 > of <~<, 27 >, wherein above-mentioned hard surface
Contain (a) ingredient and (b) ingredient, and (II) of above-mentioned hard surface liquid ceanser compositions with liquid ceanser compositions
Ingredient/(I) ingredient mass ratio is 0.25 or more, preferably 0.30 or more, and then preferably 0.35 or more, and then preferably
0.40 or more, and then preferably 0.50 or more, and then preferably 0.60 or more, also, preferably 5.0 hereinafter, more preferably 4.0
Hereinafter, in turn be preferably 3.0 hereinafter, in turn be preferably 2.0 hereinafter, in turn be preferably 1.5 hereinafter, in turn be preferably 1.0 hereinafter,
And then preferably 0.90 or less.
29 > of <
The cleaning method of hard surface as described in any one of above-mentioned 1 > of <~<, 28 >, wherein above-mentioned hard surface
It is 0.70 or more, preferably 0.80 or more with the conductivity (stoste, 25 DEG C, S/m) of liquid ceanser compositions, more preferably
1.0 or more, and then preferably 1.2 or more, and then preferably 1.4 or more, and then preferably 1.6 or more, also, preferably 10 with
Under, more preferably 9.0 hereinafter, be preferably 8.0 hereinafter, being in turn preferably 7.0 hereinafter, being in turn preferably 6.0 hereinafter, in turn in turn
Preferably 5.5 or less.
30 > of <
The cleaning method of hard surface as described in any one of above-mentioned 1 > of <~<, 29 >, wherein above-mentioned hard surface
Contain (III) solvent [hereinafter referred to as (III) ingredient] with liquid ceanser compositions.
31 > of <
The cleaning method of hard surface as described in above-mentioned 30 > of <, wherein (III) ingredient be preferably carbon atom number 2 with
Upper, more preferably 3 or more carbon atom number, preferably 10 or less carbon atom number, the more preferably water solubility below of carbon atom number 8 has
Solvent, in turn, for selected from ethyl alcohol, isopropanol, ethylene glycol, propylene glycol, diethylene glycol, dipropylene glycol, glycerol, isoprene,
Propylene glycol monomethyl ether, dihydroxypropane single-ether, 3- methyl -3- methoxybutanol, phenoxetol, benzoglycols, phenoxy group isopropyl
Water-miscible organic solvent in alcohol, butyl, dibutyl ethylene glycol ether and benzylalcohol.
32 > of <
The cleaning method of hard surface as described in above-mentioned 30 > of < or 31 > of <, wherein above-mentioned hard surface liquid is clear
Detergent composition preferably contains 0.5 mass % of (III) ingredient or more, more preferably 2 mass % or more, and then preferably 4 matter
Measure % or more, also, preferably 30 mass % hereinafter, more preferably 20 mass % hereinafter, in turn be preferably 10 mass % or less.
33 > of <
The cleaning method of hard surface as described in any one of above-mentioned 30 > of <~<, 32 >, wherein above-mentioned hard surface
It is preferably 0.5 or more with (III) ingredient of liquid ceanser compositions/(I) ingredient mass ratio, more preferably 1 or more, in turn
Preferably 1.2 or more, further preferably 1.5 or more, also, preferably 5 hereinafter, more preferably 4 hereinafter, in turn be preferably 3
Hereinafter, further preferably 2.5 or less.
34 > of <
The cleaning method of hard surface as described in any one of above-mentioned 1 > of <~<, 33 >, wherein above-mentioned hard surface
Content with the solid content ingredient of liquid ceanser compositions is 2 mass % or more, preferably 3 mass % or more, more preferably 4
Quality % or more, also, preferably 60 mass % hereinafter, more preferably 50 mass % hereinafter, in turn be preferably 45 mass % with
Under, further preferably 40 mass % hereinafter, further preferably 35 mass % hereinafter, further preferably 30 mass % with
Under, further preferably 25 mass % are hereinafter, further preferably 20 mass % or less.
35 > of <
The cleaning method of hard surface as described in any one of above-mentioned 1 > of <~<, 34 > makes above-mentioned hard table
After face liquid ceanser compositions are contacted with hard surface, preferably place 10 seconds or more, more preferably 20 seconds or more, in turn
Preferably 30 seconds or more, further preferably 40 seconds or more, further preferably 50 seconds or more, further preferably 1 minute with
On, also, preferably 60 minutes hereinafter, more preferably 30 minutes hereinafter, in turn be preferably 20 minutes hereinafter, further preferably
10 minutes hereinafter, further preferably 5 minutes or less.
36 > of <
The cleaning method of hard surface as described in any one of above-mentioned 1 > of <~<, 35 > preferably makes above-mentioned hard
Matter surface liquid ceanser compositions contact 10 seconds or more, more preferably 20 seconds or more, and then preferably 30 with hard surface
Second or more, further preferably 40 seconds or more, further preferably 50 seconds or more, further preferably 1 minute or more, also,
Preferably 60 minutes hereinafter, more preferably 30 minutes hereinafter, in turn be preferably 20 minutes hereinafter, further preferably 10 minutes with
Under, further preferably 5 minutes or less.
37 > of <
The cleaning method of hard surface as described in any one of above-mentioned 1 > of <~<, 36 > is to make above-mentioned hard table
Face with liquid ceanser compositions in undiluted situation, preferably be sprayed or be coated in undiluted situation and with
Hard surface contact.
38 > of <
The cleaning method of hard surface as described in any one of above-mentioned 1 > of <~<, 37 >, wherein hard surface is hard
The hard surface of matter article, and then be tableware and the hard surface of the hard article on kitchen periphery, and then be tableware, and then be meal
The hard surface of tool.
39 > of <
The cleaning method of hard surface as described in any one of above-mentioned 1 > of <~<, 38 >, wherein composition is at 25 DEG C
Under pH value be preferably 4 or more, more preferably 5 or more, and then preferably 5.5 or more, preferably 10 hereinafter, preferably 9 hereinafter,
More preferably 8 hereinafter, be preferably 7 or less in turn.
40 > of <
A kind of hard surface liquid ceanser compositions contain (I) surfactant [hereinafter referred to as (I) ingredient] 1
Quality % or more, (II) chelating agent [hereinafter referred to as (II) ingredient] 1 mass % or more and water, and contain (a) anionic surface
Activating agent [hereinafter referred to as (a) ingredient] is used as (I) ingredient, and (II) ingredient/(I) ingredient mass ratio is 0.25 or more, at 25 DEG C
Conductivity be 0.70S/m or more.
41 > of <
Hard surface liquid ceanser compositions as described in above-mentioned 40 > of <, wherein (a) ingredient is selected from by (a1)
Sulfosuccinate represented by the following general formula (a1) or its salt [hereinafter referred to as (a1) ingredient] and (a2) have carbon atom number 8
Above and 21 alkyl and sulfate group below or sulfonic anionic surfactant [wherein, in addition to (a1) ingredient]
One or more of [hereinafter referred to as (a2) ingredient].
[in formula, R1a、R2aIt independently, is the alkyl below of carbon atom number 5 or more and 18；A1、A2It is separately carbon
The alkylidene below of atomicity 2 or more and 4, x, y are average addition molal quantity, and are separately 0 or more and 6 or less；M1
For hydrogen atom or cation.]
42 > of <
Hard surface liquid ceanser compositions as described in above-mentioned 41 > of <, in formula of (a1), R1a、R2aPoint
It is not independent, it is 5 or more carbon atom number, is preferably 6 or more, more preferably 7 or more and 18 or less carbon atom number, preferably 16
And then preferably 14 alkyl below below,.
43 > of <
Hard surface liquid ceanser compositions as described in above-mentioned 41 > of < or 42 > of <, in formula of (a1),
R1a、R2aIt is respectively preferably selected from hexyl, octyl, nonyl, decyl, dodecyl, tridecyl, myristyl, 2- ethyl hexyl
Base, n-octyl, secondary octyl, isopentyl, isononyl, isodecyl, the alkyl in cyclohexyl, are more preferably selected from n-octyl, Zhong Xin
Alkyl in base, decyl, isodecyl and 2- ethylhexyl, and then the alkane being preferably selected from 2- ethylhexyl and tridecyl
Base, further preferably 2- ethylhexyl.
44 > of <
Hard surface liquid ceanser compositions as described in any one of above-mentioned 41 > of <~<, 43 >, formula of
(a1) in, M1Cation be selected from the inorganic cation selected from sodium ion, ammonium ion, potassium ion and magnesium ion and
From in the organic cation selected in monoethanol ammonium ion, diethanol ammonium ion, triethanol ammonium ion, morpholinium ion sun from
Son, the inorganic cation being preferably selected from sodium ion, ammonium ion, potassium ion and magnesium ion.
45 > of <
Hard surface liquid ceanser compositions as described in any one of above-mentioned 41 > of <~<, 44 >, wherein (a2)
The carbon atom number of the alkyl of ingredient is 8 or more, preferably 10 or more, more preferably 12 or more, and for 21 hereinafter, preferably 18
Hereinafter, more preferably 14 hereinafter, in turn be preferably 12 or less.
46 > of <
Hard surface liquid ceanser compositions as described in any one of above-mentioned 41 > of <~<, 45 >, wherein (a2)
Ingredient is the compound of the following general formula (a2).
R11a-O-(R12aO)n-SO3M2 (a2)
[in formula, R11aFor the alkyl of the linear chain or branched chain below of carbon atom number 8 or more and 21, R12aFor ethylidene and/or Asia
Propyl, n are average addition molal quantity and are 0 or more and 6 numbers below；M2It is preferably inorganic or have for hydrogen atom or cation
The cation of machine.]
47 > of <
Hard surface liquid ceanser compositions as described in above-mentioned 46 > of <, in formula of (a2), R11aFor carbon original
8 or more subnumber, preferably 10 or more and 21 or less, preferably 18 or less, more preferably 14 or less, and then preferably 12 with
Under linear chain or branched chain alkyl.
48 > of <
Hard surface liquid ceanser compositions as described in any one of above-mentioned 40 > of <~<, 47 >, contain
(b) amphoteric surfactant [hereinafter referred to as (b) ingredient] is used as (I) ingredient.
49 > of <
Hard surface liquid ceanser compositions as described in above-mentioned 48 > of <, wherein (b) ingredient is sulfobetaines.
50 > of <
Hard surface liquid ceanser compositions as described in above-mentioned 49 > of <, wherein sulfobetaines is selected from alkyl
Carbon atom number be preferably 10 or more, preferably 18 or less, more preferably 14 N- alkyl-N, N- dimethyl-N-sulphurs third below
Base ammonium sulfobetaines, alkyl carbon atom number be preferably 10 or more, preferably 18 or less, more preferably 14 N- alkane below
Base-N, N- dimethyl-N-(2- hydroxyl sulfopropyl) ammonium sulfobetaines, alkanoyl carbon atom number be preferably 10 or more, preferably
For 18 or less, more preferably 14 N- alkanoylamino propyl-N, N- dimethyl-N-sulfopropyl ammonium sulfobetaines below and
The carbon atom number of alkanoyl is preferably 10 or more, preferably 18 or less, more preferably 14 N- alkanoylamino propyl-N below,
Sulfobetaines in N- dimethyl-N-(2- hydroxyl sulfopropyl) ammonium sulfobetaines.
51 > of <
Hard surface liquid ceanser compositions as described in any one of above-mentioned 40 > of <~<, 50 >, contain
(I) 1 mass % of ingredient or more, preferably 2 mass % or more, more preferably 3 mass % or more, so preferably 4 mass % with
On, also, preferably 18 mass % hereinafter, more preferably 15 mass % hereinafter, in turn be preferably 12 mass % hereinafter, excellent in turn
10 mass % are selected as hereinafter, being in turn preferably 8 mass % hereinafter, being in turn preferably 6 mass % or less.
52 > of <
Hard surface liquid ceanser compositions as described in any one of above-mentioned 40 > of <~<, 51 > are preferably
Containing 0.25 mass % of (a) ingredient or more, more preferably 0.5 mass % or more, and then preferably 1 mass % or more, Jin Eryou
2 mass % or more, and then preferably 4 mass % or more are selected as, also, preferably 10 mass % are hereinafter, more preferably 8 mass %
Hereinafter, being in turn preferably 6 mass % hereinafter, being in turn preferably 5 mass % or less.
53 > of <
Hard surface liquid ceanser compositions as described in any one of above-mentioned 40 > of <~<, 52 >, wherein (I)
In ingredient, the ratio of (a) ingredient is preferably 10 mass % or more, more preferably 20 mass % or more, and then preferably 30 matter
Measure % or more, and then preferably 40 mass % or more, also, preferably 90 mass % hereinafter, more preferably 80 mass % hereinafter,
And then preferably 70 mass % hereinafter, be preferably 60 mass % or less in turn.
54 > of <
Hard surface liquid ceanser compositions as described in any one of above-mentioned 41 > of <~<, 53 > are preferably
Containing 0.25 mass % of (a1) ingredient or more, more preferably 0.5 mass % or more, and then preferably 0.8 mass % or more, into one
Step is preferably 1 mass % or more, further preferably 1.7 mass % or more, also, preferably 30 mass % hereinafter, more preferably
For 20 mass % hereinafter, being in turn preferably 15 mass % hereinafter, further preferably 10 mass % are hereinafter, further preferably 8
Quality % is hereinafter, further preferably 5 mass % or less.
55 > of <
Hard surface liquid ceanser compositions as described in any one of above-mentioned 41 > of <~<, 54 >, contain
(a2) 0 mass % of ingredient or more, also, 3 mass % hereinafter, preferably 2.5 mass % hereinafter, more preferably 2 mass % hereinafter,
And then preferably 1.5 mass % hereinafter, further preferably 1 mass % hereinafter, further preferably not up to 1 mass %, into one
Step be preferably 0.5 mass % hereinafter, further preferably not up to 0.5 mass %, further preferably 0.1 mass % hereinafter, into
One step is not preferably up to 0.1 mass %.
56 > of <
Hard surface liquid ceanser compositions as described in any one of above-mentioned 41 > of <~<, 55 >, wherein (a2)
Ingredient/(a1) ingredient mass ratio is preferably 1 hereinafter, more preferably 0.8 hereinafter, being in turn preferably 0.6 hereinafter, being preferably in turn
0.4 hereinafter, be preferably 0.2 hereinafter, being in turn preferably 0.1 hereinafter, in turn preferably not up to 0.1 in turn, and then preferably 0.05
Hereinafter, also, preferably 0 or more or 0.
57 > of <
Hard surface liquid ceanser compositions as described in any one of above-mentioned 41 > of <~<, 56 >, wherein (a1)
Ingredient/(I) ingredient mass ratio is preferably 0.1 or more, more preferably 0.3 or more, also, preferably 0.9 hereinafter, more preferably
0.7 or less.
58 > of <
Hard surface liquid ceanser compositions as described in any one of above-mentioned 48 > of <~<, 57 > are preferably
Containing 0.25 mass % of (b) ingredient or more, more preferably 0.5 mass % or more, and then preferably 1 mass % or more, also, it is excellent
8 mass % are selected as hereinafter, more preferably 6 mass % hereinafter, be preferably 4 mass % or less in turn.
59 > of <
Hard surface liquid ceanser compositions as described in any one of above-mentioned 49 > of <~<, 58 > are preferably
Containing 0.25 mass % of sulfobetaines or more, more preferably 0.5 mass % or more, and then preferably 1 mass % or more, and
And preferably 8 mass % hereinafter, more preferably 6 mass % hereinafter, in turn be preferably 4 mass % or less.
60 > of <
Hard surface liquid ceanser compositions as described in any one of above-mentioned 48 > of <~<, 59 >, contain
(a) ingredient and (b) ingredient, and the mass ratio of (a) ingredient/(b) ingredient be more than 0, preferably 0.1 or more, more preferably 0.2 with
On, and then preferably 0.3 or more, and then preferably 0.5 or more, further preferably 0.7 or more, also, preferably 10 hereinafter,
More preferably 8 hereinafter, be preferably 6 hereinafter, being in turn preferably 4 hereinafter, being in turn preferably 3 or less in turn.
61 > of <
Hard surface liquid ceanser compositions as described in any one of above-mentioned 48 > of <~<, 60 >, wherein (b)
Ingredient/(I) ingredient mass ratio is preferably 0.1 or more, more preferably 0.3 or more, also, preferably 0.9 hereinafter, more preferably
0.7 or less.
62 > of <
Hard surface liquid ceanser compositions as described in any one of above-mentioned 40 > of <~<, 61 >, wherein (II)
Ingredient is the compound selected from one or more of amino carboxylic acid, hydroxycarboxylic acid, hydroxyethylidene diphosphonic acid and their salt.
63 > of <
Hard surface liquid ceanser compositions as described in above-mentioned 62 > of <, wherein amino carboxylic acid and its salt be selected from
Ethylenediamine tetra-acetic acid (EDTA), itrile group triacetic acid (NTA), iminodiacetic acid, diethylene-triamine pentaacetic acid (DPTA), N- hydroxyl
Base ethyl-ethylenediamine triacetic acid (HEDTA), methylglycine diacetic acid (MGDA), aspartic acid oxalic acid (ASDA), glutamic acid
It is one kind or two or more in oxalic acid (GLDA) and their salt.
64 > of <
Hard surface liquid ceanser compositions as described in above-mentioned 62 > of < or 63 > of <, wherein hydroxycarboxylic acid and its
Salt is the compound in aliphatic hydroxyl carboxylic acid and its salt, in turn, for the chemical combination in malic acid, citric acid and its salt
Object.
65 > of <
Hard surface liquid ceanser compositions as described in any one of above-mentioned 40 > of <~<, 64 >, contain hydroxyl
Yl carboxylic acid and its salt and then aliphatic hydroxyl carboxylic acid and its salt and then citric acid and its salt and then citrate as (II) at
Point.
66 > of <
Hard surface liquid ceanser compositions as described in any one of above-mentioned 40 > of <~<, 65 >, contain
(II) 1 mass % of ingredient or more, preferably 1.5 mass % or more, more preferably 1.8 mass % or more, and then preferably 2 matter
Measure % or more, also, preferably 18 mass % hereinafter, more preferably 15 mass % hereinafter, in turn be preferably 12 mass % hereinafter,
And then preferably 10 mass % hereinafter, be preferably 8 mass % hereinafter, being in turn preferably 5 mass % or less in turn.
67 > of <
Hard surface liquid ceanser compositions as described in any one of above-mentioned 40 > of <~<, 66 >, wherein (II)
Ingredient/(I) ingredient mass ratio is 0.25 or more, preferably 0.30 or more, and then preferably 0.35 or more, and then preferably
0.40 or more, and then preferably 0.50 or more, and then preferably 0.60 or more, also, preferably 5.0 hereinafter, more preferably 4.0
Hereinafter, in turn be preferably 3.0 hereinafter, in turn be preferably 2.0 hereinafter, in turn be preferably 1.5 hereinafter, in turn be preferably 1.0 hereinafter,
Preferably 0.90 hereinafter, be preferably 0.70 or less in turn in turn.
68 > of <
Hard surface liquid ceanser compositions as described in any one of above-mentioned 48 > of <~<, 67 >, contain
(a) ingredient and (b) ingredient, and (II) ingredient/(I) ingredient mass ratio is 0.25 or more, preferably 0.30 or more, and then preferably
It is 0.35 or more, and then preferably 0.40 or more, and then preferably 0.50 or more, and then preferably 0.60 or more, also, preferably
For 5.0 hereinafter, more preferably 4.0 hereinafter, in turn be preferably 3.0 hereinafter, in turn be preferably 2.0 hereinafter, in turn be preferably 1.5 with
Under, so preferably 1.0 hereinafter, in turn be preferably 0.90 or less.
69 > of <
Hard surface liquid ceanser compositions as described in any one of above-mentioned 40 > of <~<, 68 >, conductivity
(stoste, 25 DEG C, S/m) are 0.70 or more, preferably 0.80 or more, more preferably 1.0 or more, and then preferably 1.2 or more, into
And preferably 1.4 or more, and then preferably 1.6 or more, also, preferably 10 hereinafter, more preferably 9.0 hereinafter, in turn preferably
For 8.0 hereinafter, being in turn preferably 7.0 hereinafter, being in turn preferably 6.0 hereinafter, being in turn preferably 5.5 or less.
70 > of <
Hard surface liquid ceanser compositions as described in any one of above-mentioned 40 > of <~<, 69 >, containing molten
Agent [hereinafter referred to as (III) ingredient].
71 > of <
Hard surface liquid ceanser compositions as described in above-mentioned 70 > of <, wherein (III) ingredient is preferably carbon original
2 or more subnumber, more preferably 3 or more carbon atom number, preferably 10 or less carbon atom number, more preferably carbon atom number 8 are below
Water-miscible organic solvent, in turn, for selected from ethyl alcohol, isopropanol, ethylene glycol, propylene glycol, diethylene glycol, dipropylene glycol, glycerol, different
Pentanediol, propylene glycol monomethyl ether, dihydroxypropane single-ether, 3- methyl -3- methoxybutanol, phenoxetol, benzoglycols, benzene oxygen
Water-miscible organic solvent in base isopropanol, butyl, dibutyl ethylene glycol ether and benzylalcohol.
72 > of <
Hard surface liquid ceanser compositions as described in above-mentioned 70 > of < or 71 > of < preferably contain
(III) 0.5 mass % of ingredient or more, more preferably 2 mass % or more, and then preferably 4 mass % or more, also, preferably
30 mass % hereinafter, more preferably 20 mass % hereinafter, in turn be preferably 10 mass % or less.
73 > of <
Hard surface liquid ceanser compositions as described in any one of above-mentioned 70 > of <~<, 72 >, wherein
(III) ingredient/(I) ingredient mass ratio is preferably 0.5 or more, and more preferably 1 or more, and then preferably 1.2 or more, further
Preferably 1.5 or more, also, preferably 5 hereinafter, more preferably 4 hereinafter, be preferably 3 hereinafter, further preferably 2.5 in turn
Below.
74 > of <
Hard surface liquid ceanser compositions as described in any one of above-mentioned 40 > of <~<, 73 >, wherein solid
The content of object ingredient is 2 mass % or more, preferably 3 mass % or more, more preferably 4 mass % or more, also, preferably 60
Quality % hereinafter, more preferably 50 mass % hereinafter, in turn be preferably 45 mass % hereinafter, further preferably 40 mass % with
Under, further preferably 35 mass % hereinafter, further preferably 30 mass % hereinafter, further preferably 25 mass % with
Under, further preferably 20 mass % or less.
75 > of <
Hard surface liquid ceanser compositions as described in any one of above-mentioned 40 > of <~<, 74 >, are not
Cleaning in diluted situation used in hard surface is directly contacted with hard surface in undiluted situation and is used in turn.
76 > of <
Hard surface liquid ceanser compositions as described in any one of above-mentioned 40 > of <~<, 75 >, are hard
The hard surface of article is used, and then the hard surface of tableware or the hard article on kitchen periphery is used, and then tableware is used, and then tableware
Hard surface.
77 > of <
Hard surface liquid ceanser compositions as described in any one of above-mentioned 40 > of <~<, 76 >, wherein combining
PH value of the object at 25 DEG C is preferably 4 or more, more preferably 5 or more, and then preferably 5.5 or more, also, preferably 10 with
Under, preferably 9 hereinafter, more preferably 8 hereinafter, in turn be preferably 7 or less.
78 > of <
A kind of composition is as hard surface liquid ceanser and then is used as the purposes of tableware liquid ceanser, this
Composition contains (I) surfactant [hereinafter referred to as (I) ingredient] 1 mass % or more, (II) chelating agent [hereinafter referred to as (II)
Ingredient] 1 mass % or more and water, and it is used as (I) ingredient containing (a) anionic surfactant [hereinafter referred to as (a) ingredient],
(II) ingredient/(I) ingredient mass ratio is 0.25 or more, is 0.70S/m or more in 25 DEG C of conductivity.
79 > of <
A kind of purposes of the composition as described in any one of above-mentioned 40 > of <~<, 77 > is used as hard surface liquid
Body cleaning agent, and then as tableware liquid ceanser.
[embodiment]
Using following gradation compositions, hard surface liquid ceanser compositions shown in table 1 are prepared, and be directed to following item
Mesh is evaluated.Result is shown in table 1.
The hard surface of table 1 is to be prepared by conventional method with liquid ceanser compositions.That is, to suitable ion
Exchanged water adds (I) ingredient, (II) ingredient and the butyl in addition to (a1) ingredient, keeps it molten in room temperature (25 DEG C)
Solution adds sodium hydroxide and/or hydrochloric acid and adjusts pH value (25 DEG C) to value shown in table 1, thereafter, cooperation (a1) ingredient thereafter
And it is stirred and prepares formula.Furthermore all numerical value based on effective component of the quality % of the gradation composition in table 1.(a)
Ingredient indicates the quality % based on sodium salt.
< gradation composition >
(a) ingredient
(a1) ingredient
Two -2- ethylhexyl sodium of sulfosuccinic acid (product name " Airrol CT-1L ", eastern nation chemical (strain) manufacture),
In general formula (a1), R1a、R2a: while being 2- ethylhexyl；X, y: while being 0；M1: the compound of sodium
(a2) ingredient
EO2 lauryl sulfate ester sodium: in general formula (a2), R11aFor dodecyl, R12aFor ethylidene, n 2, M2For
The compound of sodium
Lauryl sulfate ester sodium: in general formula (a2), R11aFor dodecyl, n 0, M2For the compound of sodium
(b) ingredient
Lauryl hydroxyl sulfo betaine: N- dodecyl-N, N- dimethyl-N-(2- hydroxyl sulfopropyl) ammonium sulfo group sweet tea
Dish alkali (product name " AMPHITOL 20HD ", flower king (strain) manufacture)
(II) ingredient
Sodium citrate: " purification citric acid (acid anhydride) " of Fukawa Chemical Industries Co., Ltd.'s manufacture is matched with composition
In, and the pH value of composition is adjusted to 6 using 48 mass % sodium hydrate aqueous solutions (South Sea chemical industry (strain) manufacture), by
Sodium salt is made in a part of above-mentioned citric acid by this.
Citric acid: product name " purification citric acid (acid anhydride) ", Fukawa Chemical Industries Co., Ltd.'s manufacture
Disodium edta: product name " KK-07 ", the manufacture of middle part CHELEST Co., Ltd.
Methylglycine diacetic acid sodium salt: product name " Trilon M Powder ", the manufacture of BASF SE company
1-Hydroxy ethylene-1,1-diphosphonic acid sodium salt: product name " Dequest 2010CS ", Italmatch Japan
Co., Ltd.'s manufacture
(III) ingredient
Butyl: product name " BDG-NS ", Japanese emulsifier Co., Ltd. manufacture (1) cleaning force (solution leaching
Stain evaluation)
Butter and rapeseed oil are carried out the person of mixing with the mass ratio of 9:1 by production, (include solid oil as model stain
The model stain of the greasy dirt of rouge, same as below).To the matter of 30mm (cross) × 80mm (perpendicular) × 1mm (thickness) polypropylene test piece
Amount is measured (x) using 4 balances.Be produced on the two sides of above-mentioned polypropylene test piece from lower end until the height of 50mm with
The total mode as 0.02~0.03g in two sides is equably coated with model stain, as spot part.To the quality benefit of the spot part
(y) is measured with 4 balances.
50mL container (internal diameter 35mm × height 68mm cylinder is added in hard surface liquid ceanser compositions 50g
Shape), then, 1 spot part, which is stood, contacts it with above-mentioned composition in the container.At this point, spot part is attached with spot
Part be all immersed in the above-mentioned composition in container.
Spot part is impregnated into the time shown in table 1 in the hard surface liquid ceanser compositions in said vesse,
Thereafter, above-mentioned spot part is taken out, and carries out flowing water using tap water and rinses 1 minute.At this point, the condition that flowing water rinses are as follows: originally
The temperature of water is 25 DEG C, and flow velocity is about 4L/min, and the diameter of the opening portion of tap is about 15mm.Relative to being located at from being open
The tap water of portion's spot part drippage of 5cm vertically downward, holds spot part in a manner of becoming 45 ° therewith, and is fixing the angle
Receive flowing water using the unattached upper part for having spot of spot part in the case where degree, trickles originally using on spot part
Water is rinsed the entire single side in cleaning part.At this point, every 10 seconds ground changes front and the back side is alternately carried out flushing.Rinse knot
Shu Hou keeps spot part dry, thereafter, is measured (z) to quality using 4 balances.Clean rate is found out using following formula.
Clean rate (%)={ (y)-(z) }/{ (y)-(x) } × 100
(2) cleaning force (foam impregnation evaluation)
Butter and rapeseed oil are carried out the person of mixing with the mass ratio of 9:1 by production, as model stain.To 30mm (cross)
The quality of × 80mm (perpendicular) × 1mm (thickness) polypropylene test piece is measured (x) using 4 balances.It is produced on above-mentioned poly- third
The two sides of alkene test piece is equably coated with model stain to the height away from lower end 5cm in such a way that two sides is total as 0.02~0.03g
It spends and winner, as spot part.(y) is measured using 4 balances to the quality of the spot part.
Hard surface is filled in trigger spray container (Magiclean Handy with liquid ceanser compositions
Spray, flower king (strain) manufacture), it is interior to 50mL container (internal diameter 35mm × height 68mm is cylindric), by above-mentioned composition blister
Ground is 5 times spraying.The discharge-amount of composition adds up to about 5g.
Then, 1 spot part is stood in the container, makes the hard surface of the blister in above-mentioned spot part and said vesse
It is contacted with liquid ceanser compositions.At this point, the part for being attached with spot of spot part is all immersed in the blister in container
In above-mentioned composition.In the foam by spot part dipping, thereafter, it places the time shown in table 1 and takes out spot part later, and utilize
Tap water carries out flowing water and rinses 1 minute.At this point, the condition that flowing water rinses are as follows: the temperature of tap water is 25 DEG C, and flow velocity is about 4L/
Min, the diameter of the opening portion of tap are about 15mm.Relative to be located at from opening portion vertically downward 5cm spot part drippage
Tap water, hold spot part in a manner of becoming 45 ° therewith, it is unattached using spot part in the case where fixing the angle
There is the upper part of spot to receive flowing water, the entire single side in cleaning part is rushed using the tap water to trickle on spot part
It washes.At this point, every 10 seconds ground changes front and the back side is alternately carried out flushing.After flushing, keep spot part dry, thereafter, benefit
(z) is measured to quality with 4 balances.Clean rate is found out using following formula.
Clean rate (%)={ (y)-(z) }/{ (y)-(x) } × 100
(3) conductivity
The conductivity meter (CM-30R type) manufactured using DKK Toa Corp., according in the operational manual of machine
The measuring method is measured (25 DEG C).
About the use level of table 1, (a) ingredient is sodium salt scaled value, and (II) ingredient is sour scaled value.
The cleaning force of embodiment 1,3 is being averaged for 2 measurements.
< Formulation Example >
Hard surface liquid ceanser compositions of the invention are shown in table 2.
[table 2]
A part of (b) ingredient in table 2, (c) ingredient are following person, other compositions be with used in table 1 at split-phase
Same person.
(b) ingredient
Carboxybetaine: product name " AMPHITOL 20AB ", flower king (strain) manufacture
Amine oxide: product name " AMPHITOL 20N ", flower king (strain) manufacture
(c) ingredient
2- Sensiva SC50 ether: product name " Penetol GE-EH ", flower king (strain) manufacture.
Claims (16)
1. a kind of cleaning method of tableware is to make tableware liquid ceanser compositions and be attached with the oil comprising solid grease
Dirty tableware contact, and cleaned in the case where not applying mechanical force, which contains:
(I) surfactant, hereinafter referred to as (I) ingredient, 1 mass % or more,
(II) chelating agent, hereinafter referred to as (II) ingredient, 1 mass % or more, and
Water,
And contain (a) anionic surfactant be used as (I) ingredient, hereinafter, will (a) anionic surfactant referred to as (a) at
Point,
(II) ingredient/(I) ingredient mass ratio is 0.25 or more,
The tableware is 0.70S/m or more with conductivity of the liquid ceanser compositions at 25 DEG C.
2. cleaning method as described in claim 1, wherein (II) ingredient be selected from amino carboxylic acid, hydroxycarboxylic acid, hydroxyethylidene diphosphonic acid,
And the compound of one or more of their salt.
3. cleaning method as claimed in claim 1 or 2, wherein the tableware liquid ceanser compositions contain 0.25 matter
Measure % or more and 10 mass % (a) below ingredients.
4. cleaning method as claimed any one in claims 1 to 3, wherein (a) ingredient be selected from (a1) ingredient and (a2) at
Point more than one,
(a1) sulfosuccinate or its salt represented by the following general formula (a1),
(a2) having carbon atom number is 8 or more and 21 alkyl and sulfate group below or sulfonic anion surface active
Agent, wherein except (a1) ingredient,
In formula, R1a、R2aIt independently, be carbon atom number is 5 or more and 18 alkyl below；A1、A2It is separately former for carbon
Subnumber is 2 or more and 4 alkylidenes below, and x, y are average addition molal quantity, and are separately 0 or more and 6 or less；M1
For hydrogen atom or cation.
5. cleaning method as claimed in claim 4, wherein (a2) ingredient in the tableware liquid ceanser compositions/
(a1) mass ratio of ingredient is 1 or less.
6. the cleaning method as described in any one of claims 1 to 5, wherein the tableware liquid ceanser compositions contain
(b) amphoteric surfactant is used as (I) ingredient, hereinafter, (b) amphoteric surfactant is known as (b) ingredient.
7. cleaning method as claimed in claim 6, wherein the tableware liquid ceanser compositions contain 0.25 mass %
Above and 8 mass % (b) below ingredients.
8. cleaning method as claimed in claims 6 or 7, wherein (a) ingredient in the tableware liquid ceanser compositions/
(b) mass ratio of ingredient is 10 or less.
9. the cleaning method as described in any one of claim 6 to 8, wherein amphoteric surfactant includes sulfobetaines.
10. cleaning method as claimed in any one of claims 1-9 wherein, wherein make the tableware liquid ceanser compositions
It is contacted in undiluted situation with the tableware for being attached with the greasy dirt comprising solid grease.
11. the cleaning method as described in any one of claims 1 to 10, wherein combine the tableware with liquid ceanser
Object contacts 10 seconds or more with the tableware.
12. a kind of tableware liquid ceanser compositions, contain:
(I) surfactant, hereinafter referred to as (I) ingredient, 1 mass % or more,
(II) chelating agent, hereinafter referred to as (II) ingredient, 1 mass % or more, and
Water,
And contain (a) anionic surfactant be used as (I) ingredient, hereinafter, will (a) anionic surfactant referred to as (a) at
Point,
(II) ingredient/(I) ingredient mass ratio is 0.25 or more,
The tableware is 0.70S/m or more with conductivity of the liquid ceanser compositions at 25 DEG C.
13. tableware liquid ceanser compositions as claimed in claim 12, wherein (a) ingredient is selected from following (a1) ingredient
One or more of (a2) ingredient,
(a1) sulfosuccinate or its salt represented by the following general formula (a1),
(a2) having carbon atom number is 8 or more and 21 alkyl and sulfate group below or sulfonic anion surface active
Agent, wherein except (a1) ingredient,
In formula, R1a、R2aIt independently, be carbon atom number is 5 or more and 18 alkyl below；A1、A2It is separately former for carbon
Subnumber is 2 or more and 4 alkylidenes below, and x, y are average addition molal quantity, and are separately 0 or more and 6 or less；M1
For hydrogen atom or cation.
14. tableware liquid ceanser compositions as claimed in claim 13, wherein (a2) ingredient/(a1) ingredient mass ratio
It is 1 or less.
15. the tableware liquid ceanser compositions as described in any one of claim 12 to 14, contain (b) amphoteric surface
Activating agent is used as (I) ingredient, hereinafter, (b) amphoteric surfactant is known as (b) ingredient.
16. tableware liquid ceanser compositions as claimed in claim 15, wherein the mass ratio of (a) ingredient/(b) ingredient is
10 or less.
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2016106274 | 2016-05-27 | ||
| JP2016-106274 | 2016-05-27 | ||
| JP2016215002A JP6707294B2 (en) | 2016-05-27 | 2016-11-02 | How to clean hard surfaces |
| JP2016-215002 | 2016-11-02 | ||
| PCT/JP2017/018999 WO2017204148A1 (en) | 2016-05-27 | 2017-05-22 | Method for washing hard surface |
Publications (2)
| Publication Number | Publication Date |
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| CN109070150A true CN109070150A (en) | 2018-12-21 |
| CN109070150B CN109070150B (en) | 2022-01-11 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201780025687.6A Active CN109070150B (en) | 2016-05-27 | 2017-05-22 | Method for cleaning hard surfaces |
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| CN (1) | CN109070150B (en) |
| WO (1) | WO2017204148A1 (en) |
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| EP3839028B1 (en) | 2019-12-17 | 2025-01-15 | The Procter & Gamble Company | Cleaning product |
| EP3839025A1 (en) | 2019-12-17 | 2021-06-23 | The Procter & Gamble Company | Cleaning product |
| EP3858965B1 (en) | 2020-01-28 | 2022-05-11 | The Procter & Gamble Company | Cleaning product |
| EP3858961A1 (en) | 2020-01-28 | 2021-08-04 | The Procter & Gamble Company | Cleaning product |
| EP4124651B1 (en) | 2021-07-27 | 2023-11-29 | The Procter & Gamble Company | Cleaning product |
| EP4481025A1 (en) | 2023-06-20 | 2024-12-25 | The Procter & Gamble Company | Cleaning product |
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| CN109070150B (en) | 2022-01-11 |
| WO2017204148A1 (en) | 2017-11-30 |
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