CN109068649A

CN109068649A - Use of fluopyram and/or Bacillus subtilis for preventing and treating Fusarium wilt of Musaceae plants

Info

Publication number: CN109068649A
Application number: CN201780025452.7A
Authority: CN
Inventors: J.斯梅德马; A.塞古拉蒙格
Original assignee: Bayer CropScience AG
Current assignee: Bayer CropScience AG
Priority date: 2016-04-24
Filing date: 2017-04-19
Publication date: 2018-12-21
Also published as: WO2017186543A2; BR122021026787B1; MX2018012994A; WO2017186543A3; PH12018502245A1; MX2024000424A; BR112018071851A2

Abstract

本发明涉及氟吡菌酰胺和/或枯草芽孢杆菌用于芭蕉科，特别是芭蕉属植物的枯萎病的用途。其还涉及可用于防治芭蕉科，特别是芭蕉属植物的枯萎病的方法。The present invention relates to the use of fluopyram and/or Bacillus subtilis for Musaceae, especially Musa plants for fusarium wilt. It also relates to methods that can be used to control Fusarium wilt of plants of the Musaceae family, in particular of the Musa genus.

Description

Fluopyram and/or bacillus subtilis are used to prevent and treat the withered of Musaceae plant The purposes of disease

Invention field

The present invention relates generally to formula (I) compound (fluopyram) and/or bacillus subtilis, especially bacterial strains QST 713 is used to prevent and treat the purposes of the wilt disease (Fusarium wilt) of Musaceae, especially banana.

In addition, the present invention relates to be particularly useful for by using fluopyram and/or withered grass bud with different administration mode Spore bacillus, especially bacterial strain QST 713 are come the method that prevents and treats the wilt disease of Musaceae, especially banana.

Description of the prior art

Fluopyram is the compound according to formula (I)

,

Its N- { 2- [3- chloro- 5- (trifluoromethyl) -2- pyridyl group] ethyl } -2- trifluoromethylbenzene first with chemical name formula (I) Amide.In WO-A 2004/16088, eelworm-killing activity is described in WO-A 2008/ for Fungicidally active and its preparation description In 126922.

Bacillus subtilis subspecies are known as antifungal biological products.Bacillus subtilis strain QST 713 is especially Know as fungicide (US 6,060,051, US 6,103,228, US 6,291,426 and US 6,417,163) and like this with Trade name Serenade is sold.

Banana planting is influenced by many nosomycosises.Principal disease in banana is wilt disease or Panama disease (Panama Disease), this causes the heavy losses of banana planting in the whole world.

Wilt disease is by soil-borne fungus Fusarium oxysporum Cuba specialized form (Fusarium oxysporum f. sp. Cubense, FOC) cause.The different microspecies of identified FOC such as infect the TR4 of the banana of Cavendish kind (Tropical race 4) or the STR4(Suptropical race for needing other infection promotive factor such as low temperature and water logging 4).Other microspecies are microspecies 1 to 4.Fungi be dispersed throughout planting material, infection soil or water in.Common banana variety, such as Gros Anti- 2 bacterial strain of microspecies of Michel, Silk, Pome and Pisang awak cultivar, but it is sensitive to the bacterial strain of microspecies 1 and 4. The anti-bacterial strain of microspecies 1 and 2 of Cavendish cultivar, but it is sensitive to 4 bacterial strain of microspecies.Plantain and East African Highland bananas(EAHB) usually anti-1 bacterial strain of microspecies of cultivar.

Wilt disease is the typical wilt disease of vascular bundle.Fungi invades vascular tissue through root, to cause to change colour and wilt, most Plant is killed eventually.The process of internal sympton will affect first appearing for external symptom.Fruit does not show any symptom.It is withered The characteristic internal sympton of disease is dimension pipe discoloration, and light yellow from initial stage becomes the dark red of later period or almost black.Internal disease Shape initially develops in feeder root, this is primary infection position.Fungi spreads to rhizome, then arrives false stem (pseudostem). In outside, the initial sign of the disease is usually wilting and yellow of old leaf in perimeter.Yellow leaf can be able to maintain in petiole Uprightly or collapse.Sometimes, in addition to petiolar spot, leaf keeps green, but still falls.The leaf to collapse is hanged as skirt It hangs down on false stem.Finally, all leaves and withered.The division of false stem bottom is another common sympton.Other symptoms include The corrugation and distortion of irregular light border and blade on young leaves.The sucker (suckers) of infection until they about 4 months Great talent starts to show the symptom of wilt disease, and this case facilitates the disease and propagated by planting material.Fruit does not show Out any specified disease symptom (http://www.promusa.org/Fusarium+wiltWith Randy C. Ploetz, Phytopathology (2015), Vol 105, No 12, the 1512-1521 pages).

Classical agricultural chemicals or fungicide or fumigant can not prevent and treat wilt disease.The effort for preventing and treating the disease is spent in It cultivates on resistant variety, but limited success.

Summary of the invention

But, it has now been found that fluopyram and/or bacillus subtilis, especially bacterial strain QST 713 are for preventing and treating fragrant plant The wilt disease of Lowiaceae, especially banana.

Correspondingly, the invention further relates to include fluopyram and/or bacillus subtilis, especially bacterial strain QST 713 Composition be used for prevent and treat Musaceae plant wilt disease purposes.

Correspondingly, it is used to prevent and treat the use of the wilt disease of Musaceae, especially banana the invention further relates to composition On the way, the composition includes

A) fluopyram and/or bacillus subtilis, especially bacterial strain QST 713

B) at least one additional agricultural chemical activity compound and/or.

A kind of illustrative methods of the invention include by the fluorine pyrrole of the Musaceae that is used for of the invention, especially banana Bacterium amide and/or bacillus subtilis, especially bacterial strain QST 713 are administered on soil or plant to prevent and treat wilt disease.

In the context of the present invention, " prevention and treatment of wilt disease " refers to and reduces compared with untreated plant or plant product Fusarium oxysporum Cuba specialized form infects, as effect measure, preferably with untreated plant or plant product (100%) phase Than reducing 25-50%, 40-79% is reduced more preferably compared with untreated plant or plant product (100%), even more preferably completely Inhibit infecting for (70-100%) plant pathogenic microorganisms.The prevention and treatment can be it is therapeutic, i.e., for handling the plant infected Object or plant product or protective, for protecting not yet by the untreated plant infected or plant product.

In the context of the present invention, fluopyram and/or bacillus subtilis, especially bacterial strain QST 713 can be with It is comprising fluopyram, fluopyram and bacillus subtilis, especially bacterial strain QST 713 or fluopyram or withered grass The composition (that is, physical mixture) of bacillus, especially bacterial strain QST 713.It is also possible to by single active ingredient group Point, i.e. the fluopyram and withered that constitutes of the independent preparation of fluopyram and bacillus subtilis, especially bacterial strain QST 713 The combination (bucket mixture (tank-mix)) of careless bacillus, the especially compound of bacterial strain QST 713.Fluopyram and withered grass Another example of bacillus, the especially combination of bacterial strain QST 713 is fluopyram and bacillus subtilis, especially Bacterial strain QST 713 is present in not together in same preparation, but separately packaging (hybrid packed, combipack), i.e., is not common Preformulation.Therefore, hybrid packed includes one or more separated containers, such as bottle, tank, bottle, pouch, packet or cylinder, each container Independent component containing agrochemical composition is fluopyram and bacillus subtilis, especially bacterial strain QST herein 713.One example is that bi-component is hybrid packed.Therefore the invention further relates to a kind of bi-component is hybrid packed, it includes first group Divide and the second component, the first component include fluopyram, liquid or solid carrier and if appropriate, at least one surface work again Property agent and/or at least one adjuvants customary, the second component includes bacillus subtilis again, especially bacterial strain QST 713, liquid Or solid carrier and if appropriate, at least one surfactant and/or at least one adjuvants customary.It is described below and for example closes In the more details of suitable liquid and solid carrier, surfactant and adjuvants customary.

Combination according to the present invention should refer to/it include composition, bucket mixture or hybrid packed.

Wilt disease should include by Fusarium oxysporum Cuba specialized form, including all small of Fusarium oxysporum Cuba specialized form Kind, including but not limited to disease caused by microspecies 1,2,3,4, TR4, STR 4.

" effective quantity ", which refers to, to be enough to prevent and treat Fusarium oxysporum Cuba specialized form in a satisfactory manner or eradicates completely sharp Fusarium oxysporum Cuba specialized form is not and at the same time cause fluopyram and/or the withered grass of phytotoxic any manifest symptom Bacillus, the especially amount of bacterial strain QST 713.In general, this rate of application can change in relatively wide range.Its Depending on several factors, such as depending on life stage, plant, the weather conditions of the Fusarium oxysporum Cuba specialized form to be prevented and treated With the ingredient of composition of the invention.

Preferred embodiment description

Disclose fluopyram and/or bacillus subtilis, especially bacterial strain QST 713 for preventing and treating Musaceae, especially The purposes of the wilt disease of banana.

In one embodiment, fluopyram is disclosed for preventing and treating the withered of Musaceae, especially banana The purposes for disease of withering.

In one embodiment, the purposes of wilt disease of the fluopyram for preventing and treating cultivation banana plant is disclosed.

In one embodiment, bacillus subtilis, especially bacterial strain QST 713 is disclosed to be used to prevent and treat Musaceae, The especially purposes of the wilt disease of banana.

In one embodiment, disclose bacillus subtilis, especially bacterial strain QST 713 for prevent and treat cultivation banana The purposes of the wilt disease of plant.

In one embodiment, bacillus subtilis strain QST 713 is disclosed for preventing and treating Musaceae, especially fragrant plant The purposes of the wilt disease of any of several broadleaf plants platymiscium.

In one embodiment, bacillus subtilis strain QST 713 is disclosed for preventing and treating cultivation banana plant The purposes of wilt disease.

In another embodiment, it discloses comprising fluopyram and/or bacillus subtilis, especially bacterial strain QST 713 composition is used to prevent and treat the purposes of the wilt disease of Musaceae plant.

In another embodiment, it discloses comprising fluopyram and/or bacillus subtilis, especially bacterial strain QST 713 composition is used to prevent and treat the purposes of the wilt disease of cultivation banana plant.

In another embodiment, the composition comprising fluopyram is disclosed for preventing and treating the withered of Musaceae plant The purposes of disease.

In another embodiment, the composition comprising fluopyram is disclosed for preventing and treating the withered of cultivation banana plant The purposes for disease of withering.

In another embodiment, it discloses comprising bacillus subtilis, the composition of especially bacterial strain QST 713 is used for The purposes for preventing and treating the wilt disease of Musaceae plant.

In another embodiment, it discloses comprising bacillus subtilis, the composition of especially bacterial strain QST 713 is used for The purposes of the wilt disease of prevention and treatment cultivation banana plant.

In another embodiment, the composition comprising bacillus subtilis strain QST 713 is disclosed for preventing and treating fragrant plant The purposes of the wilt disease of Lowiaceae plant.

In another embodiment, disclose the composition comprising bacillus subtilis strain QST 713 for prevent and treat cultivation Train the purposes of the wilt disease of banana plant.

In another embodiment, composition is disclosed for preventing and treating the wilt disease of Musaceae, especially banana Purposes, the composition includes

A) fluopyram and/or bacillus subtilis, especially bacterial strain QST 713

B) at least one additional agricultural chemical activity compound and/or.

In another embodiment, the purposes of wilt disease of the composition for preventing and treating cultivation banana plant is disclosed, it is described Composition includes

A) fluopyram and/or bacillus subtilis, especially bacterial strain QST 713

B) at least one additional agricultural chemical activity compound and/or.

A) fluopyram

B) at least one additional agricultural chemical activity compound and/or.

A) fluopyram

B) at least one additional agricultural chemical activity compound and/or.

A) bacillus subtilis, especially bacterial strain QST 713

B) at least one additional agricultural chemical activity compound and/or.

A) bacillus subtilis, especially bacterial strain QST 713

B) at least one additional agricultural chemical activity compound and/or.

A) bacillus subtilis strain QST 713

B) at least one additional agricultural chemical activity compound and/or.

A) bacillus subtilis strain QST 713

B) at least one additional agricultural chemical activity compound and/or.

Musaceae is especially made of following species: fruitlet open country any of several broadleaf plants (Musa acuminata), wild any of several broadleaf plants (Musa Balbisiana), sharp leaf any of several broadleaf plants (Musa acuminata Colla) (has kind " Dwarf Cavendish ", " Giant Cavendish " and " Gros Michel "), Tom Thumb banana (Musa cavendishii Lamb. ex Paxt.), Musa Malaccensis Ridl., Musa angcorensis Gagnep., Musa aurantiaca, wild any of several broadleaf plants (Musa Balbisiana), Musa seminifera Lour., Musa banksii F. Muell., bajiao banana (Musa basjoo), Musa cheesmanii, Musa flaviflora Simmonds, Musa griersonii, M. itinerans (Musa Itinerans), brick red any of several broadleaf plants (Musa laterita), Musa mannii, Le Jiabu any of several broadleaf plants (Musa nagensium), Musa Ochracea, U.S. powder bajiao banana (Musa ornata Roxb.), Musa siamea, Musa sikkimensis, Musa Thomsonii Noltie, it is red towards day any of several broadleaf plants (Musa velutina Wendl. & Drude), it is Musa alinsanaya, cured red It is any of several broadleaf plants (Musa beccarii), Musa boman, Musa borne nsis, Musa bukensis, Musa campestris, red Any of several broadleaf plants (Musa coccinea Andrews), safflower any of several broadleaf plants (Musa uranoscopos Lour), Musa exotica Valmayor, Musa fitzalanii, Musa flavida, Musa gracilis, Musa hirta Becc., island mountain bajiao banana (Musa insularimontana Hayata), Musa jackeyi, Musa johnsii, finger any of several broadleaf plants (Musa Lawitiensis), Musa lolodensis, Musa maclayi, Musa monticola, Musa muluensis, river mouth Refer to day any of several broadleaf plants (Musa paracoccinea), Musa peekelii, Musa pigmaea Hotta, A Xijiao (Musa Rubra), Musa salaccensis, Musa splendida A. Chev., Musa suratii, abaca (Musa Textilis): Manila manila hemp (Abac á), Japanese hardy or fibre banana, banana (Musa Troglodytarum), Musa tuberculata, Musa violascens, huge bajiao banana (Musa ingens), Musa The Hybrid of paradisiaca sapientm, Musa paradisiaca normali and these species.

Banana group is preferably cultivated, it includes species point leaf any of several broadleaf plants (Musa acuminata Colla) and wild any of several broadleaf plants (Musa Balbisiana Colla) (original species) and Musa × paradisiaca L.(cenospecies M. acuminata × M. Balbisiana).

According to the present invention it is possible to handle all Musaceae plants.Musaceae plant is understood in the context of this article Refer to all plant parts and plant population, such as needs and unwanted wild plant or crop plants are (including naturally occurring Crop plants).Crop plants can be can by traditional breeding method and optimization method or by biotechnology and recombination method or this The Musaceae plant that the combination of a little methods obtains, including transgenosis Musaceae plant and including by with not by plant breeder's rights The plant variety of (Plant Breeders'Rights) protection, such as Gros Michel, Cavendish, Dwarf Cavendish、Dwarf Chinese、Enano、Caturra、Giant Cavendish、Gran Enano、Grande Naine、Williams Hybrid、Valery、Robusta、Poyo、Lacatan、Pisang masak hijau、Monte cristo、Bout rond。

Plant parts mean all positions above and below the ground and the organ of plant, as herb (herb), false stem, bud, leaf, Bud, leaf sheath, petiole, blade, Hua Hegen, it may be mentioned that example be leaf, needle, stalk, stem, flower, petiole, fructification, fruit, Banana hand, beam (bunches) and seed and root, stem tuber, rhizome, side shoot, sucker, secondary plant (secondary Growth).Plant parts further include crop material (crop material) and asexual and case of propagation material, such as are transplanted, block Stem, rhizome, sprout and seed.

As already mentioned above, all Musaceae plants can be handled according to the present invention.In a preferred embodiment, Handle field discovery or by standard biologic breeding method (such as hybridization, sediment diversion ratio, micropropagation, somatic embryo Occur, direct organ occur or protoplast fusion) obtain plant species and plant variety and they position.Another excellent It selects in embodiment, the transgenosis Musaceae plant that processing is obtained by recombination method (if appropriate, in conjunction with conventional method) With Musaceae plant variety (genetic modification biology), such as by Agrobacterium or the biolistic transformation of cells,primordial, and Micropropagation.Musaceae plant includes all plant parts as follows mentioned.

The fragrant plant of those of commercially available in each case or in use plant variety is particularly preferably handled according to the present invention Lowiaceae plant.Plant variety (Plant varieties) is understood to mean through conventional breeding, by mutagenesis or passes through recombination The plant with new property (" character ") that DNA technique obtains.They can be mutation (varieties), kind (breeds), Bion and genotype.Character may include such as herbicide or insect tolerance, to arid, heat or cold tolerance.

All plants and plant parts can be handled according to the present invention.Plant is herein understood to refer to all plants and plant Population such as needs and unwanted wild plant or crop plants (including naturally occurring crop plants).Crop plants can be with It can be obtained by conventional breeding and optimization method or by biotechnology and gene engineering method or a combination of these methods Plant, including genetically modified plants and including by with not by plant breeder's rights (plant breeders'rights) protect Plant cultivars.Plant parts are understood to mean all positions above and below the ground and the organ of plant, such as bud, leaf, Hua He Root, the example include leaf, needle, stalk, stem, flower, fructification, fruit and seed and root, stem tuber and rhizome.Plant parts are also Including cutting and asexual and case of propagation material, such as transplant, stem tuber, rhizome, sprout and seed.

Mixing partner (Mixing Partners)

One embodiment is related to comprising A) fluopyram and/or bacillus subtilis, especially bacterial strain QST 713 or fluorine The mixture and B of pyrrole bacterium amide and/or bacillus subtilis, especially bacterial strain QST 713) at least one other chemurgy Learn the purposes of the composition of reactive compound and/or at least one biocontrol agent.

In another embodiment, the present invention relates to include A) fluopyram and/or bacillus subtilis, especially The mixture and B of bacterial strain QST 713 or fluopyram and/or bacillus subtilis, especially bacterial strain QST 713) at least A kind of purposes of the composition of other agricultural chemical activity compound.

B the agricultural chemical activity compound is following active ingredients under)

The fungicide that can be mentioned is:

1) ergosterol biosynthesis inhibitor, such as (1.1) aldimorph, (1.2) azaconazole, (1.3) biphenyl three Azoles alcohol, (1.4) bromuconazole, (1.5) Cyproconazole, (1.6) diclobutrazol, (1.7) difenoconazole, (1.8) alkene azoles Alcohol, (1.9) olefin conversion-M, (1.10) dodemorfe, (1.11) dodemorph acetate, (1.12) epoxiconazole, (1.13) second ring Azoles, (1.14) Fenarimol, (1.15) benzoxazole, (1.16) fenhexamid, (1.17) fenpropidin, (1.18) butylbenzene Beautiful jade, (1.19) Fluquinconazole, (1.20) flurprimidol, (1.21) Flusilazole, (1.22) Flutriafol, (1.23) furconazole, (1.24) furconazole_cis (furconazole-cis), (1.25) hexaconazole, (1.26) imazalil, (1.27) sulfuric acid imazalil, (1.28) glyoxalin, (1.29) kind bacterium azoles, (1.30) metconazole, (1.31) nitrile bacterium azoles, (1.32) Naftifine, (1.33) Imidazoles, (1.35) paclobutrazol, (1.36) pefurazoate, (1.37) penconazole, (1.38) powder are disliked in nuarimol, (1.34) Sick spirit, (1.39) Prochloraz, (1.40) propiconazole, (1.41) prothioconazoles, (1.42) pyributicarb, (1.43) pyrifenox, (1.44) quinconazole, (1.45) simeconazoles, (1.46) volution bacterium amine, (1.47) Tebuconazole, (1.48) spy compare naphthalene Sweet smell, (1.49) tetraconazole, (1.50) triazolone, (1.51) Triadimenol, (1.52) tridemorph, (1.53) fluorine bacterium azoles, (1.54) triforine, (1.55) triticonazole, (1.56) uniconazole P, (1.57) high uniconazole P (uniconazole-p), (1.58) viniconazole, (1.59) voriconazole, (1.60) 1- (4- chlorphenyl) -2- (1H-1,2,4- triazole -1- Base) suberol, (1.61) 1- (2,2- dimethyl -2,3- dihydro -1H- indenes -1- base) -1H- imidazoles -5- methyl formate, (1.62) N'- { 5- (difluoromethyl) -2- methyl -4- [3- (trimethyl silyl) propoxyl group] phenyl }-N- ethyl-N-methyl carbonamidine, (1.63) N- ethyl-N-methyl-N'- { 2- methyl -5- (trifluoromethyl) -4- [3- (trimethyl silyl) propoxyl group] benzene Base } carbonamidine, (1.64) O- [1- (4- methoxyphenoxy) -3,3- dimethylbutane -2- base] 1H- imidazoles -1- bamic acid Ester, (1.65) oxazole (Pyrisoxazole).

2) respiratory chain inhibitor at complex I or II, for example, (2.1) biphenyl pyrrole bacterium amine, (2.2) Boscalid, (2.3) carboxin, (2.4) difluoro woods (diflumetorim), (2.5) fenfuram, (2.6) fluopyram, (2.7) Flutolanil, (2.8) fluxapyroxad, (2.9) furametpyr, (2.10) seed dressing amine, (2.11) isopyrazam (it is cis-- The mixture of epimerism racemate 1RS, 4SR, 9RS and trans--epimerism racemate 1RS, 4SR, 9SR), (2.12) Isopyrazam (trans--epimerism racemate 1RS, 4SR, 9SR), (2.13) isopyrazam (trans--epimerism Enantiomter 1R, 4S, 9S), (2.14) isopyrazam (trans--epimerism enantiomter 1S, 4R, 9R), (2.15) Isopyrazam (cis- epimerism racemate 1RS, 4SR, 9RS), (2.16) isopyrazam (cis--epimerism pair Reflect isomers 1R, 4S, 9R), (2.17) isopyrazam (cis--epimerism enantiomter 1S, 4R, 9S), (2.18) Mebenil, (2.19) oxycarboxin, (2.20) fluorine azoles bacterium aniline (penflufen), (2.21) pyrrole metsulfovax, (2.22) Fluorine azoles ring bacterium amine (sedaxane), (2.23) thifluzamide, (2.24) 1- methyl-N- [2- (1,1,2,2- tetrafluoro ethyoxyl) Phenyl] -3- (trifluoromethyl) -1H- pyrazole-4-carboxamide, (2.25) 3- (difluoromethyl) -1- methyl-N- [2- (1,1,2,2- Tetrafluoro ethyoxyl) phenyl] -1H- pyrazole-4-carboxamide, (2.26) 3- (difluoromethyl)-N- [fluoro- 2- (1,1,2,3,3,3- of 4- Hexafluoro propoxyl group) phenyl] -1- methyl-1 H- pyrazole-4-carboxamide, (2.27) N- [1- (2,4 dichloro benzene base) -1- methoxyl group Propyl- 2- yl] -3- (difluoromethyl) -1- methyl-1 H- pyrazole-4-carboxamide, the fluoro- N- of (2.28) 5,8- bis- [2- (the fluoro- 4- of 2- { [4- (trifluoromethyl) pyridine -2- base] oxygroup } phenyl) ethyl] quinazoline -4- amine, (2.29) benzo alkene fluorine bacterium azoles (benzovindiflupyr), (2.30) N- [(1S, 4R) -9- (dichloromethylene) -1,2,3,4- tetrahydro -1,4- endo-methylene group Naphthalene -5- base] -3- (difluoromethyl) -1- methyl-1 H- pyrazole-4-carboxamide, (2.31) N- [(1R, 4S) -9- (dichloro methylene Base) -1,2,3,4- tetrahydro -1,4- endo-methylene group naphthalene -5- base] -3- (difluoromethyl) -1- methyl-1 H- pyrazole-4-carboxamide, (2.32) 3- (difluoromethyl) -1- methyl-N- (1,1,3- trimethyl -2,3- dihydro -1H- indenes -4- base) -1H- pyrazoles -4- first Amide, (2.33) 1,3,5- trimethyl-N- (1,1,3- trimethyl -2,3- dihydro -1H- indenes -4- base) -1H- pyrazoles -4- formyl Amine, (2.34) 1- methyl -3- (trifluoromethyl)-N- (1,1,3- trimethyl -2,3- dihydro -1H- indenes -4- base) -1H- pyrazoles -4- Formamide, (2.35) 1- methyl -3- (trifluoromethyl)-N- [(3R) -1,1,3- trimethyl -2,3- dihydro -1H- indenes -4- base] - 1H- pyrazole-4-carboxamide, (2.36) 1- methyl -3- (trifluoromethyl)-N- [(3S) -1,1,3- trimethyl -2,3- dihydro -1H- Indenes -4- base] -1H- pyrazole-4-carboxamide, (2.37) 3- (difluoromethyl) -1- methyl-N- [trimethyl -2 (3S) -1,1,3-, 3- dihydro -1H- indenes -4- base] -1H- pyrazole-4-carboxamide, (2.38) 3- (difluoromethyl) -1- methyl-N- [(3R) -1,1,3- Trimethyl -2,3- dihydro -1H- indenes -4- base] -1H- pyrazole-4-carboxamide, (2.39) 1,3,5- trimethyl-N- [(3R) -1,1, 3- trimethyl -2,3- dihydro -1H- indenes -4- base] -1H- pyrazole-4-carboxamide, (2.40) 1,3,5- trimethyl-N- [(3S) -1, 1,3- trimethyl -2,3- dihydro -1H- indenes -4- base] -1H- pyrazole-4-carboxamide, (2.41) benodanil, the chloro- N- of (2.42) 2- (1,1,3- trimethyl -2,3- dihydro -1H- indenes -4- base) pyridine-3-carboxamide, (2.43) N- [1- (4- isopropoxy -2- first Base phenyl)-2- methyl-1-oxo propyl- 2- yl]-3 methyl thiophene-2- formamide.

3) respiratory chain inhibitor at complex III, such as (3.1) azoles mepanipyrim, (3.2) amisulbrom (amisulbrom), (3.3) Fluoxastrobin, (3.4) cyazofamid, (3.5) first fragrant bacterium ester (coumethoxystrobin), (3.6) coumoxystrobin, (3.7) dimoxystrobin, (3.8) Enestroburin (enoxastrobin), (3.9) Famoxate, (3.10) Fenamidone, (3.11) fluorine bacterium mite ester, (3.12) fluoxastrobin, (3.13) kresoxim-methyl, (3.14) benzene oxygen bacterium Amine, (3.15) orysastrobin, (3.16) ZEN 90160, (3.17) pyraclostrobin, (3.18) azoles amine bacterium ester, (3.19) azoles Bacterium ester, (3.20) pyribencarb, (3.21) chlorine nalidixic bacterium ester (triclopyricarb), (3.22) trifloxystrobin, (3.23) (2E) -2- (2- { [6- (3- chloro-2-methyl phenoxy group) -5-FU -4- base] oxygroup } phenyl) -2- (methoxyimino) - N- methylacetamide, (3.24) (2E) -2- (methoxyimino)-N- methyl -2- (2- { [({ (1E) -1- [3- (fluoroform Base) phenyl] ethylidene } amino) oxygroup] methyl } phenyl) acetamide, (3.25) (2E) -2- (methoxyimino)-N- first Base -2- { 2- [(E)-({ 1- [3- (trifluoromethyl) phenyl] ethyoxyl } imino group) methyl] phenyl } acetamide, (3.26) (2E) -2- { 2- [({ [(1E) -1- (3- { [the fluoro- 2- phenyl vinyl of (E) -1-] oxygroup } phenyl) ethylidene] amino } oxygroup) first Base] phenyl -2- (methoxyimino)-N- methylacetamide, (3.27) alkene oxime amine (Fenaminostrobin), (3.28) 5- methoxyl group -2- methyl -4- (2- { [({ (1E) -1- [3- (trifluoromethyl) phenyl] ethylidene } amino) oxygroup] first Base } phenyl) -2,4- dihydro -3H-1,2,4- triazole -3- ketone, (3.29) (2E) -2- { 2- [({ cyclopropyl [(4- methoxybenzene Base) imino group] methyl } sulfanyl) methyl] phenyl } -3- methoxy-methyl acrylate, (3.30) N- (3- ethyl -3,5,5- three Methylcyclohexyl) -3- formamido -2-Hydroxylbenzamide, (3.31) 2- { 2- [(2,5- dimethyl phenoxy) methyl] benzene Base } -2- methoxy N-methylacetamide, (3.32) 2- { 2- [(2,5- dimethyl phenoxy) methyl] phenyl } -2- methoxyl group - N- methylacetamide.

4) mitosis and fissional inhibitor, such as (4.1) benomyl, (4.2) carbendazim, (4.3) Chlorfenazole, (4.4) diethofencarb, (4.5) Guardian, (4.6) fluopicolide, (4.7) furidazol, (4.8) Pencycuron, (4.9) thiabendazole, (4.10) thiophanate-methyl, (4.11) thiophanate, (4.12) zoxamide, (4.13) The chloro- 7- of 5- (4- methyl piperidine -1- base) -6- (2,4,6- trifluorophenyl) [1,2,4] triazol [1,5-a] pyrimidine, (4.14) 3- Chloro- 5- (6- chloropyridine -3- base) -6- methyl -4- (2,4,6- trifluorophenyl) pyridazine.

5) can have a compound of multidigit point effect, for example, (5.1) bordeaux mixture, (5.2) difoltan, (5.3) captan, (5.4) Bravo, (5.5) Kocide SD, (5.6) copper naphthenate, (5.7) copper oxide, (5.8) king Copper, (5.9) copper sulphate (2+), (5.10) Euparen, (5.11) basudin, (5.12) dodine, the trip of (5.13) dodine From alkali, (5.14) fervam, (5.15) fluorofolpet, (5.16) folpet, (5.17) biguanides is pungent, (5.18) are double The pungent acetate of guanidine, (5.19) iminoctadine, (5.20) iminoctadine alkylbenzene sulfonate (iminoctadine Albesilate), (5.21) iminoctadine triacetate, (5.22) mancopper, (5.23) Mancozeb, (5.24) generation Gloomy manganese, (5.25) Carbatene, (5.26) Carbatene zinc, (5.27) copper 8-hydroxyquinolinate, (5.28) propamidine, (5.29) Propineb, (5.30) sulphur and sulphur preparation, including lime sulfur (calcium polysulfide), (5.31) thiram, (5.32) are to first Euparen, (5.33) zineb, (5.34) ziram, (5.35) anilazine.

6) compound of host defense can be induced, such as (6.1) my acid benzene-S-methyl (acibenzolar- S-methyl), (6.2) isotianil (isotianil), (6.3) probenazole, (6.4) tiadinil, (6.5) thallus laminariae are more Sugar.

7) inhibitor of amino acid and/or Protein synthesis, such as (7.1) andoprim, (7.2) blasticidin-S (blasticidin-S), (7.3) cyprodinil, (7.4) kasugarnycin, (7.5) hydration kasugamycini hydrochloride, (7.6) are phonetic Bacterium amine, (7.7) pyrimethanil, (7.8) 3- (the fluoro- 3,3,4,4- tetramethyl -3,4- dihydro-isoquinoline -1- base of 5-) quinoline, (7.9) Terramycin, (7.10) streptomysin.

8) ATP generate inhibitor, such as (8.1) triphen vinegar tin (fentin acetate), (8.2) Fentin chloride, (8.3) fentin hydroxide, (8.4) sulphur silicon bacterium amine (silthiofam).

9) inhibitor of Cell wall synthesis, such as (9.1) benzene metsulfovax (benthiavalicarb), (9.2) alkene acyl Morpholine, (9.3) flumorph, (9.4) Propineb, (9.5) mandipropamid, (9.6) polyoxin, (9.7) Polyoxin (polyoxorim), (9.8) Validacin (Takeda), (9.9) figured silk fabrics bacterium amine (valifenalate), (9.10) Polyoxin AL.

10) lipid and film synthesis inhibitor, such as (10.1) biphenyl, (10.2) chloroneb, (10.3) botran, (10.4) Hinosan, (10.5) kobam, (10.6) iodocarb, (10.7) different rice blast net, (10.8) Isoprothiolane, (10.9) Propamocarb, (10.10) propamocarb, (10.11) prothiocarb, (10.12) Ppyrazophos, (10.13) pentachloro- Nitrobenzene, (10.14) tecnazene, (10.15) tolelofos-methyl.

11) inhibitor of melanin biosynthesis, for example, (11.1) ring propionyl bacterium amine, (11.2) double chlorine zarilamid, (11.3) zarilamid, (11.4) phthalide, (11.5) pyroquilon, (11.6) tricyclazole, (11.7) { 3- methyl-1-[(4- first Base benzoyl) amino] butane -2- base } carbamic acid 2,2,2- trifluoro ethyl ester.

12) inhibitor of nucleic acid synthesis, for example, (12.1) M 9834, (12.2) smart M 9834 (kiralaxyl), (12.3) bupirimate, (12.4) clozylacon, (12.5) Milcurb, (12.6) Milstem, (12.7) furan frost Spirit, (12.8) hymexazol, (12.9) metalaxyl, (12.10) Metalaxyl-M (mefenoxam), (12.11) fenfuram, (12.12) Wakil, (12.13) oxolinic acid, (12.14) octhilinone.

13) inhibitor of signal transduction, for example, (13.1) chlozolinate, (13.2) fenpiclonil, (13.3) fludioxonil, (13.4) iprodione, (13.5) procymidone, (13.6) quinoxyfen, (13.7) vinclozolin, (13.8) the third oxygen quinoline (proquinazid).

14) compound of uncoupler, such as (14.1) binapacryl, (14.2) dinocap are potentially acted as (dinocap), (14.3) ferimzone, (14.4) fluazinam, (14.5) nitre benzene bacterium ester (meptyldinocap).

15) other compounds, such as (15.1) benthiozole, (15.2) bethoxazin, (15.3) kappa are western mould Element (capsimycin), (15.4) carvol, (15.5) chinomethionat, (15.6) pyriofenone(chlazafenone), (15.7) cufraneb, (15.8) cyflufenamid (cyflufenamid), (15.9) cymoxanil, (15.10) cyclopropyl-sulfonylamide (cyprosulfamide), (15.11) dazomet, (15.12) debacarb (debacarb), (15.13) antiphen, (15.14) Diclomezine, (15.15) difenzoquat, (15.16) difenzoquat metilsulfate (difenzoquat metilsulfate), (15.17) diphenylamines, (15.18) ecomate, (15.19) amine benzene pyrrole bacterium ketone (fenpyrazamine), (15.20) Flumetover, (15.21) fluorine acid imide (fluoroimide), (15.22) flusulfamide (flusulfamide), (15.23) Flutianil, (15.24) phosethyl-Al (fosetyl-aluminium), (15.25) ethane phosphonic acid calcium (fosetyl- Calcium), (15.26) ethane phosphonic acid sodium (fosetyl-sodium), (15.27) hexachloro-benzene, (15.28) irumamycin, (15.29) methasulfocarb, (15.30) methyl-isorhodanate, (15.31) metrafenone, (15.32) midolthromycin, (15.33) Natamycin, (15.34) nickel dimethyldithiocarbamate, (15.35) nitrothalisopropyl (nitrothal-isopropyl), (15.37) oxamocarb, (15.38) oxyfenthiin, (15.39) pentachlorophenol and salt, (15.40) phenothrin, (15.41) phosphorous acid and its salt, (15.42) Propamocarb ethyl phosphine hydrochlorate (propamocarb-fosetylate), (15.43) Propanosine-sodium, (15.44) pyrimorph (pyrimorph), (15.45) (2E) -3- (4- tert-butyl-phenyl) - 3- (2- chloropyridine -4- base) -1- (morpholine -4- base) propyl- 2- alkene -1- ketone, (15.46) (2Z) -3- (4- tert-butyl-phenyl) -3- (2- chloropyridine -4- base) -1- (morpholine -4- base) propyl- 2- alkene -1- ketone, (15.47) pyrrolnitrin (pyrrolnitrine), (15.48) tebufloquin, (15.49) tecloftalam, (15.50) first flusulfamide (tolnifanide), (15.51) imidazoles Piperazine (triazoxide), (15.52) trichlamide (trichlamide), (15.53) zarilamid (zarilamid), (15.54) 2 Methylpropionic acid (3S, 6S, 7R, 8R) -8- benzyl -3- [({ 3- [(isobutyl acyloxy) methoxyl group] -4- methoxyl group pyrrole Pyridine -2- base } carbonyl) amino] -6- methyl -4,9- dioxo -1,5- dioxane nonane -7- base ester, (15.55) 1- (4- { 4- [(5R) -5- (2,6- difluorophenyl) -4,5- dihydro -1,2- oxazole -3- base] -1,3- thiazol-2-yl } piperidin-1-yl) -2- [5- Methyl -3- (trifluoromethyl) -1H- pyrazol-1-yl] ethyl ketone, (15.56) 1- (4- 4- [(5S) -5- (2,6- difluorophenyl) -4, 5- dihydro -1,2- oxazole -3- base] -1,3- thiazol-2-yl } piperidin-1-yl) -2- [5- methyl -3- (trifluoromethyl) -1H- pyrrole Azoles -1- base] ethyl ketone, (15.57) 1- (4- { 4- [5- (2,6- difluorophenyl) -4,5- dihydro -1,2- oxazole -3- base] -1,3- thiophene Azoles -2- base } piperidin-1-yl) -2- [5- methyl -3- (trifluoromethyl) -1H- pyrazol-1-yl] ethyl ketone, (15.58) 1H- imidazoles - 1- formic acid 1- (4- methoxyphenoxy) -3,3- dimethyl butyrate -2- base ester, the chloro- 4- (sulfonyloxy methyl of (15.59) 2,3,5,6- tetra- Base) pyridine, (15.60) 2,3- dibutyl -6- chlorothiophene simultaneously [2,3-d] pyrimidine -4 (3H) -one, (15.61) 2,6- dimethyl - [1,4] two thiophene English of 1H, 5H- simultaneously -1,3,5,7 (2H, 6H)-tetrone of [2,3-c:5,6-c'] two pyrroles, (15.62) 2- [5- first Base -3- (trifluoromethyl) -1H- pyrazol-1-yl] -1- (4- 4- [(5R) -5- phenyl -4,5- dihydro -1,2- oxazole -3- base] -1, 3- thiazol-2-yl } piperidin-1-yl) ethyl ketone, (15.63) 2- [5- methyl -3- (trifluoromethyl) -1H- pyrazol-1-yl] -1- (4- { 4- [(5S) -5- phenyl -4,5- dihydro -1,2- oxazole -3- base] -1,3- thiazol-2-yl } piperidin-1-yl) ethyl ketone, (15.64) 2- [5- methyl -3- (trifluoromethyl) -1H- pyrazol-1-yl] -1- { 4- [4- (5- phenyl -4,5- dihydro -1,2- oxazole -3- base) - 1,3- thiazol-2-yl] piperidin-1-yl ethyl ketone, the iodo- 3- propyl -4H- benzopyran-4-one of (15.65) 2- butoxy -6-, (15.66) the chloro- 5- of 2- [the chloro- 1- of 2- (the fluoro- 4- methoxyphenyl of 2,6- bis-) -4- methyl-1 H- imidazoles -5- base] pyridine, (15.67) 2- phenyl phenol and salt, (15.68) 3- (the fluoro- 3,3- dimethyl -3,4- dihydro-isoquinoline -1- base of 4,4,5- tri-) quinoline Quinoline, (15.69) 3,4,5- trichloropyridine -2,6- dimethoxy nitrile, (15.70) 3- chloro- 5- (4- chlorphenyl) -4- (2,6- difluorobenzene Base) -6- methyl pyridazine, (15.71) 4- (4- chlorphenyl) -5- (2,6- difluorophenyl) -3,6- diformazan radical pyridazine, (15.72) 5- amino -1,3,4- thiadiazoles -2- mercaptan, the chloro- N'- phenyl-N'- of (15.73) 5- (propyl- 2- alkynes -1- base) thiophene -2- sulphonyl Hydrazine, the fluoro- 2- of (15.74) 5- [(4- luorobenzyl) oxygroup] pyrimidine -4- amine, the fluoro- 2- of (15.75) 5- [(4- methylbenzyl) oxygroup] Pyrimidine -4- amine, (15.76) 5- methyl -6- octyl [1,2,4] triazol [1,5-a] pyrimidine -7- amine, (15.77) (2Z) -3- Amino -2- cyano -3- ethyl phenylacrylate, (15.78) N'- (4- { [3- (4- chlorobenzyl) -1,2,4- thiadiazoles -5- base] Oxygroup } -2,5- 3,5-dimethylphenyl)-N- ethyl-N-methyl carbonamidine, (15.79) N- (4- chlorobenzyl) -3- [3- methoxyl group -4- (propyl- 2- alkynes -1- base oxygroup) phenyl] propionamide, (15.80) N- [(4- chlorphenyl) (cyano) methyl] -3- [3- methoxyl group -4- (propyl- 2- alkynes -1- base oxygroup) phenyl] propionamide, (15.81) N- [(the bromo- 3- chloropyridine -2- base of 5-) methyl] -2,4- dichloro cigarette Amide, two chloro-nicotinamide of (15.82) N- [1- (the bromo- 3- chloropyridine -2- base of 5-) ethyl] -2,4-, (15.83) N- [1- (5- Bromo- 3- chloropyridine -2- base) ethyl] the fluoro- 4- iodine niacinamide of -2-, (15.84) N- { (E)-[(cyclo propyl methoxy) imino group] [6- (difluoro-methoxy) -2,3- difluorophenyl] methyl } -2- phenyl-acetamides, (15.85) N- { (Z)-[(cyclopropyl-methoxy Base) imino group] [6- (difluoro-methoxy) -2,3- difluorophenyl] methyl } -2- phenyl-acetamides, (15.86) N'- { 4- [(3- Tert-butyl -4- cyano -1,2- thiazole -5- base) oxygroup] the chloro- 5- aminomethyl phenyl of -2- }-N- ethyl-N-methyl carbonamidine, (15.87) N- methyl -2- (1- { [5- methyl -3- (trifluoromethyl) -1H- pyrazol-1-yl] acetyl group } piperidin-4-yl)-N- (1,2,3,4- Naphthane -1- base) -1,3- thiazole -4-carboxamide, (15.88) N- methyl -2- (1- { [5- methyl -3- (trifluoromethyl) -1H- Pyrazol-1-yl] acetyl group } piperidin-4-yl)-N- [(1R) -1,2,3,4- naphthane -1- base] -1,3- thiazole -4-carboxamide, (15.89) N- methyl -2- (1- { [5- methyl -3- (trifluoromethyl) -1H- pyrazol-1-yl] acetyl group } piperidin-4-yl)-N- [(1S) -1,2,3,4- naphthane -1- base] -1,3- thiazole -4-carboxamide, (15.90) { 6- [({ [(1- methyl-1 H- tetrazolium - 5- yl) (phenyl) methylene] amino oxygroup) methyl] pyridine -2- base amyl carbamate, (15.91) azophenlyene -1- formic acid, (15.92) quinoline -8- alcohol, (15.93) quinoline -8- alcohol sulfate (2:1), (15.94) { 6- [({ [(1- methyl-1 H- tetra- Azoles -5- base) (phenyl) methylene] amino } oxygroup) methyl] pyridine -2- base } t-butyl carbamate, (15.95) 1- methyl - 3- (trifluoromethyl)-N- [2'- (trifluoromethyl) biphenyl -2- base] -1H- pyrazole-4-carboxamide, (15.96) N- (4'- chlorine connection Benzene -2- base) -3- (difluoromethyl) -1- methyl-1 H- pyrazole-4-carboxamide, (15.97) N- (2', 4'- dichlorobenzene -2- Base) -3- (difluoromethyl) -1- methyl-1 H- pyrazole-4-carboxamide, (15.98) 3- (difluoromethyl) -1- methyl-N- [4'- (trifluoromethyl) biphenyl -2- base] -1H- pyrazole-4-carboxamide, (15.99) N- (2', 5'- DfBP -2- base) -1- methyl - 3- (trifluoromethyl) -1H- pyrazole-4-carboxamide, (15.100) 3- (difluoromethyl) -1- methyl-N- [4'- (propyl- 1- alkynes -1- Base) biphenyl -2- base] -1H- pyrazole-4-carboxamide, the fluoro- 1,3- dimethyl-N-of (15.101) 5- [4'- (propyl- 1- alkynes -1- base) Biphenyl -2- base] -1H- pyrazole-4-carboxamide, the chloro- N- of (15.102) 2- [4'- (propyl- 1- alkynes -1- base) biphenyl -2- base] nicotinoyl Amine, (15.103) 3- (difluoromethyl)-N- [4'- (3,3- dimethyl butyrate -1- alkynes -1- base) biphenyl -2- base] -1- methyl-1 H- Pyrazole-4-carboxamide, (15.104) N- [4'- (3,3- dimethyl butyrate -1- alkynes -1- base) biphenyl -2- base] fluoro- 1,3- diformazan of -5- Base -1H- pyrazole-4-carboxamide, (15.105) 3- (difluoromethyl)-N- (4'- acetenyl biphenyl -2- base) -1- methyl-1 H- pyrrole Azoles -4- formamide, (15.106) N- (4'- acetenyl biphenyl -2- base) fluoro- 1,3- dimethyl -1H- pyrazole-4-carboxamide of -5-, (15.107) the chloro- N- of 2- (4'- acetenyl biphenyl -2- base) niacinamide, (15.108) 2- chloro- N- [4'- (3,3- dimethyl butyrate - 1- alkynes -1- base) biphenyl -2- base] niacinamide, (15.109) 4- (difluoromethyl) -2- methyl-N- [4'- (trifluoromethyl) biphenyl - 2- yl] -1,3- thiazole -5- formamide, the fluoro- N- of (15.110) 5- [4'- (3- hydroxy-3-methyl butyl- 1- alkynes -1- base) biphenyl - 2- yl] -1,3- dimethyl -1H- pyrazole-4-carboxamide, the chloro- N- of (15.111) 2- [4'- (3- hydroxy-3-methyl butyl- 1- alkynes - 1- yl) biphenyl -2- base] niacinamide, (15.112) 3- (difluoromethyl)-N- [4'- (3- methoxyl group -3- methyl butyl- 1- alkynes -1- Base) biphenyl -2- base] -1- methyl-1 H- pyrazole-4-carboxamide, the fluoro- N- of (15.113) 5- [4'- (3- methoxyl group -3- methyl butyl- 1- alkynes -1- base) biphenyl -2- base] -1,3- dimethyl -1H- pyrazole-4-carboxamide, (15.114) 2- chloro- N- [4'- (3- methoxy Base -3- methyl butyl- 1- alkynes -1- base) biphenyl -2- base] niacinamide, (15.115) (bromo- 2- methoxyl group -4- picoline -3- of 5- Base) (2,3,4- trimethoxy -6- aminomethyl phenyl) ketone, (15.116) N- [2- (4- { [3- (4- chlorphenyl) propyl- 2- alkynes -1- Base] oxygroup } -3- methoxyphenyl) ethyl]-N2- (methyl sulphonyl) valine amide, (15.117) 4- oxo -4- [(2- benzene Base ethyl) amino] butyric acid, (15.118) { 6- [({ [(Z)-(1- methyl-1 H- tetrazolium -5- base) (phenyl) methylene] amino } Oxygroup) methyl] pyridine -2- base } carbamic acid butyl- 3- alkynes -1- base ester, (15.119) 4- amino-5-fluorine pyrimidine -2- alcohol (inside disappears Rotation form: 4- amino-5-fluorine pyrimidine -2 (1H) -one), (15.120) Propylgallate, (15.121) 1, 3- dimethyl-N-(1,1,3- trimethyl -2,3- dihydro -1H- indenes -4- base) -1H- pyrazole-4-carboxamide, (15.122) 1,3- Dimethyl-N-[(3R) -1,1,3- trimethyl -2,3- dihydro -1H- indenes -4- base] -1H- pyrazole-4-carboxamide, (15.123) 1, 3- dimethyl-N-[(3S) -1,1,3- trimethyl -2,3- dihydro -1H- indenes -4- base] -1H- pyrazole-4-carboxamide, (15.124) [3- (the chloro- 2- fluorophenyl of 4-) -5- (2,4 difluorobenzene base) -1,2- oxazole -4- base] (pyridin-3-yl) methanol, (15.125) (S)-[3- (the chloro- 2- fluorophenyl of 4-) -5- (2,4 difluorobenzene base) -1,2- oxazole -4- base] (pyridin-3-yl) methanol, (15.126) (R)-[3- (the chloro- 2- fluorophenyl of 4-) -5- (2,4 difluorobenzene base) -1,2- oxazole -4- base] (pyridin-3-yl) first Alcohol, (15.127) 2- { [3- (2- chlorphenyl) -2- (2,4 difluorobenzene base) ethylene oxide -2- base] methyl } -2,4- dihydro -3H- 1,2,4- triazole -3- thioketones, (15.128) thiocyanic acid 1- { [3- (2- chlorphenyl) -2- (2,4 difluorobenzene base) ethylene oxide -2- Base] methyl } -1H-1,2,4- triazole -5- base ester, (15.129) 5- (allylsulfanyl) -1- { [3- (2- chlorphenyl) -2- (2,4 difluorobenzene base) ethylene oxide -2- base] methyl } -1H-1,2,4- triazole, (15.130) 2- [1- (2,4 dichloro benzene base) - 5- hydroxyl -2,6,6- trimethyl hept- 4- yl] -2,4- dihydro -3H-1,2,4- triazole -3- thioketones, (15.131) 2- { [rel (2R, 3S) -3- (2- chlorphenyl) -2- (2,4 difluorobenzene base) ethylene oxide -2- base] methyl } -2,4- dihydro -3H-1,2,4- three Azoles -3- thioketones, (15.132) 2- { [rel (2R, 3R) -3- (2- chlorphenyl) -2- (2,4 difluorobenzene base) ethylene oxide -2- base] Methyl } -2,4- dihydro -3H-1,2,4- triazole -3- thioketones, (15.133) thiocyanic acid 1- { [rel (2R, 3S) -3- (2- chlorobenzene Base) -2- (2,4 difluorobenzene base) ethylene oxide -2- base] methyl } -1H-1,2,4- triazole -5- base ester, (15.134) thiocyanic acid 1- { [rel (2R, 3R) -3- (2- chlorphenyl) -2- (2,4 difluorobenzene base) ethylene oxide -2- base] methyl } -1H-1,2,4- three Azoles -5- base ester, (15.135) 5- (allylsulfanyl) -1- { [rel (2R, 3S) -3- (2- chlorphenyl) -2- (2,4 difluorobenzene Base) ethylene oxide -2- base] methyl -1H-1,2,4- triazole, (15.136) 5- (allylsulfanyl) -1- [rel (2R, 3R) -3- (2- chlorphenyl) -2- (2,4 difluorobenzene base) ethylene oxide -2- base] methyl } -1H-1,2,4- triazole, (15.137) 2- [(2S, 4S, 5S) -1- (2,4 dichloro benzene base) -5- hydroxyl -2,6,6- trimethyl hept- 4- yl] -2,4- dihydro -3H-1,2,4- Triazole -3- thioketones, (15.138) 2- [(2R, 4S, 5S) -1- (2,4 dichloro benzene base) -5- hydroxyl -2,6,6- trimethyl hept- 4- Base] -2,4- dihydro -3H-1,2,4- triazole -3- thioketones, (15.139) 2- [(2R, 4R, 5R) -1- (2,4 dichloro benzene base) -5- Hydroxyl -2,6,6- trimethyl hept- 4- yl] -2,4- dihydro -3H-1,2,4- triazole -3- thioketones, (15.140) 2- [(2S, 4R, 5R) -1- (2,4 dichloro benzene base) -5- hydroxyl -2,6,6- trimethyl hept- 4- yl] -2,4- dihydro -3H-1,2,4- triazole -3- sulphur Ketone, (15.141) 2- [(2S, 4S, 5R) -1- (2,4 dichloro benzene base) -5- hydroxyl -2,6,6- trimethyl hept- 4- yl] -2,4- two Hydrogen -3H-1,2,4- triazole -3- thioketones, (15.142) 2- [(2R, 4S, 5R) -1- (2,4 dichloro benzene base) -5- hydroxyl -2,6,6- Trimethyl hept- 4- yl] -2,4- dihydro -3H-1,2,4- triazole -3- thioketones, (15.143) 2- [(2R, 4R, 5S) -1- (2,4- bis- Chlorphenyl) -5- hydroxyl -2,6,6- trimethyl hept- 4- yl] -2,4- dihydro -3H-1,2,4- triazole -3- thioketones, (15.144) 2- [(2S, 4R, 5S) -1- (2,4 dichloro benzene base) -5- hydroxyl -2,6,6- trimethyl hept- 4- yl] -2,4- dihydro -3H-1,2,4- three Azoles -3- thioketones, (15.145) 2- fluoro- 6- (trifluoromethyl)-N- (1,1,3- trimethyl -2,3- dihydro -1H- indenes -4- base) benzene first Amide, (15.146) 2- (6- benzyl pyridine -2- base) quinazoline, (15.147) 2- [6- (the fluoro- 4- methoxyphenyl of 3-) -5- Picoline -2- base] quinazoline, (15.148) 3- (the fluoro- 3,3- dimethyl -3,4- dihydro-isoquinoline -1- base of 4,4- bis-) quinoline Quinoline, (15.149) abscisic acid.

Classification (1) to (15) if all their functional groups of specified mixing partner allow, optionally with suitable alkali Or sour forming salt.

Wherein classification (1) to (15) if all their functional groups of specified mixing partner allow, optionally and properly Alkali or sour forming salt；

Preferred fungicide is selected from phosethyl-Al (Fosetyl-Al).

The fungicide that can be mentioned is: bronopol, antiphen, daxtron (nitrapyrin), dimethyl disulfide are for amino first Sour nickel, kasugarnycin, octhilinone, furancarboxylic acid, terramycin, probenazole, streptomysin, tecloftalam, copper sulphate and other copper agents.

Insecticide, acaricide and the nematicide that can be mentioned are:

(1) acetylcholinesterase (AChE) inhibitor, such as

Carbamates, for example, alanycarb, Aldicarb, Ficam, Benfuracard micro, butocarboxim, butanone sulfone prestige, sevin, Furadan, carbosulfan, ethiofencarb, Bassa, Carzol, furathiocarb, Mobucin, methiocarb, Methomyl, MTMC, Oxamyl, Aphox, arprocarb, thiodicarb, thiofanox, triaguron, Landrin, XMC and Meobal；Or

Organophosphorus compounds, such as orthene, methylpyridine phosphorus, triazotion, methyl azinphos-methyl, cadusafos, chlorine oxygen Phosphorus, chlorfenviphos, chlormephos, chlopyrifos, chlorpyrifos-methyl, Resistox, cynock, demeton-methyl, basudin, DDVP/ DDVP, Carbicron, Rogor, dimethylvinphos, disulfoton, EPN, Ethodan, phonamiphos, famphur, fenamiphos, fenifrothion, It is Entex, lythidathion, heptenophos, imicyafos, isofenphos, O- (Methoxyamino thiophosphoryl) isopropyl salicylate, different Isoxathion, malathion, Afos, acephatemet, methidathion, Menite, Azodrin, 2-dichloroethylk dimethyl phosphate, omethoate, metilomerkaptofosoksid (oxydemeton-methyl), parathion, parathion-methyl, phenthoate dimephenthoate cidial, thimet, Phosalone, phosmet, phosphamidon, pungent Sulphur phosphorus, pirimiphos-methyl, Profenofos, propetamphos, Toyodan, pyraclofos, pyridaphethione, quinalphos, sulfotep, butyl pyrimidine Phosphorus, Swebate, terbufos, Ravap, thiometon, Hostathion, metrifonate and Kilval.

(2) GABA- gated chloride channel antagonist, such as

Cyclopentadiene organochlorine class, such as Niran and 5a,6,9,9a-hexahydro-6,9-methano-2,4；Or

Phenyl pyrazoles (fiproles), such as ethiprole and Fipronil.

(3) sodium channel modulators/voltage dependent form sodium channel inhibitor, such as

Pyrethroid, such as acrinathrin, allethrin, dextrorotation-cis-trans allethrin, d-trans propylene chrysanthemum Ester, Biphenthrin, bioaeroprofen, bioaeroprofen S- cyclopentenyl isomers, bioresmethrin, cycloprothrin, Cyfloxylate, β-cyfloxylate, Cyhalothrin, λ-Cyhalothrin, γ-Cyhalothrin, cypermethrin, α-cypermethrin, β-cypermethrin, θ-cypermethrin, ζ-cypermethrin, cyphenothrin [(1R)-transisomer], bromine cyanogen chrysanthemum Ester, Prallethrin [(EZ)-(1R) isomers], esfenvalerate, Etofenprox, Fenpropathrin, fenvalerate, penta chrysanthemum of fluorine cyanogen Ester, flumethrin, tau- taufluvalinate, halfenprox, Imiprothrin, Kadethrin, permethrin, phenothrin [(1R)-transisomer], prallethrin, pyrethrins (Dalmatian chrysanthemum), resmethrin, silafluofene, Tefluthrin, amine chrysanthemum Ester, tetramethrin [(1R) isomers], tralomethrin and transfluthrin；Or

DDT；Or methoxychlor；

(4) nicotinic acetylcholine receptor (nAChR) agonist, such as

Anabasine, such as Acetamiprid, clothianidin, dinotefuran, imidacloprid, Nitenpyram, thiacloprid and Diacloden；Or

Nicotine；Or

Sulfoxaflor.

(5) nicotinic acetylcholine receptor (nAChR) allosteric activation agent, such as

Pleocidin class (spinosyns), such as ethyl pleocidin and pleocidin (spinosad).

(6) chloride channel activators, such as

Avermectins/milbemycins, such as abamectin, emamectin-benzoate, rayperidin and close It goes out spit of fland.

(7) juvenile hormone mimics, such as

Juvenoid, such as hydroprene (Hydroprene), kinoprene (Kinoprene) and methoprene (Methoprene)；Or

Fenoxycarb；Or Nylar.

(8) diversified non-specific (multidigit point) inhibitor, such as

Alkyl halide, such as methyl bromide and other alkyl halides；Or

Trichloronitromethane (Chloropicrin)；Or vikane；Or borax；Or tartar emetic.

(9) selective Homoptera feeds retarding agent, such as pymetrozine；Or flonicamid.

(10) mite growth inhibitor, such as clofentezine, Hexythiazox and flufenzine；Or

Etoxazole.

(11) microorganism agent interfering of insect midgut film, such as bacillus thuringiensis subsp israelensis (Bacillus Thuringiensis subspecies israelensis), bacillus thuringiensis (Bacillus Thuringiensis subspecies aizawai), bacillus thuringiensis Kurstaki (Bacillus Thuringiensis subspecies kurstaki), bacillus thuringiensis meal beetle subspecies (Bacillus Thuringiensis subspecies tenebrionis) and B.t. crop albumen: Cry1Ab, Cry1Ac, Cry1Fa, Cry1A.105,Cry2Ab,Vip3A,mCry3A,Cry3Ab,Cry3Bb,Cry34 Ab1/35Ab1；Or

Bacillus sphaericus.

(12) mitochondrial ATP synthase inhibitor, such as diafenthiuron；Or

Organotin acaricide, such as azacyclotin, plictran and fenbutatin oxide (Fenbutatin oxide)；Or

Propargite；Or tetradiphon.

(13) by interrupting the oxidative phosphorylation uncoupler of proton gradient, such as chlorfenapyr, DNOC and sulfluramid.

(14) nicotinic acetylcholine receptor (nAChR) channel blocker, such as bensultap, cartap hydrochloride, thiocyclam And dimehypo；

(15) benzoylurea derivertives, 0 type, such as bistrifluron, chlorfluazuron, diflubenzuron, flucycloxuron, flufenoxuron, Flubenzuron, lufenuron, novaluron (Novaluron), noviflumuron (Noviflumuron), Teflubenzuron and triflumuron.

(16) benzoylurea derivertives, 1 type, such as Buprofezin.

(17) husking agent interfering, such as cyromazine.

(18) moulting hormone (Ecdysone) receptor stimulating agent, such as ring tebufenozide, chlorine tebufenozide (Halofenozide), methoxyfenozide and tebufenozide.

(19) octopamine receptor agonist, such as Amitraz.

(20) mitochondrial complex III electron transfer inhibitor, such as hydramethylnon；Or acequinocyl；Or fluacrypyrim.

(21) mitochondrial complex I electron transfer inhibitor, such as

METI acaricide, such as fenazaquin, fenpyroximate, pyrimidifen, pyridaben, tebufenpyrad and Tolfenpyrad；Or

Rotenone (Derris).

(22) voltage dependent form sodium channel inhibitor, such as indoxacarb；Or metaflumizone.

(23) acetyl-CoA carboxylase inhibitor, such as

Tetronic acid (tetronic acid) and tetramic acid (tetramic acid) derivative, such as Envidor, spiral shell first mite Ester and spiral shell worm ethyl ester.

(24) mitochondrial complex IV electron transfer inhibitor, such as

Phosphine, such as aluminum phosphate, calcium phosphide, phosphine and zinc phosphide；Or

Cyanide.

(25) mitochondrial complex II electron transfer inhibitor, such as ss-ketonitriles (beta-ketonitrile) derivative, Such as nitrile pyrrole mite ester and cyflumetofen.

(28) blue Buddhist nun's alkali receptor modulators, such as

Diamide, such as Rynaxypyr, bromine cyanogen insect amide and fipronil bisamide.

Other active constituents with unknown or indefinite binding mode, such as sulfanilamide (SN) mite ester (Amidoflumet), print Chinaberry element, Benclothiaz, Citrazon, Bifenazate, fenisobromolate, chinomethionat, ice crystal, dicofol, flufenzine, connection fluorine Sulfone (Fluensulfone), phonetic worm amine, butene-fipronil (Flufiprole), fluopyram, furan tebufenozide, imidaclothiz, Iprodione, fluorine chlorine ether pyrethroids, pyridalyl, Pyrifluquinazon, etrafluorine ethofenprox and iodomethane；And it is based on strong bud The product (including but not limited to bacterial strain CNCM I-1582, such as VOTiVO, BioNem) of spore bacillus or following known activity One of compound: the bromo- N- of 3- { the chloro- 6- of the bromo- 4- of 2- [(1- cyclopropylethyl) carbamoyl] phenyl } -1- (3- chloropyridine -2- Base) -1H- pyrazoles -5- formamide (knowing from WO2005/077934), 4- { [(6- bromopyridine -3- base) methyl] (2- fluorine second Base) amino } furans -2 (5H) -one (knowing from WO2007/115644), 4- { [(6- fluorine pyridin-3-yl) methyl] (2,2- bis- Fluoro ethyl) amino } furans -2 (5H) -one (knowing from WO2007/115644), 4- { [(the chloro- 1,3- thiazole -5- base of 2-) first Base] (2- fluoro ethyl) amino } furans -2 (5H) -one (knowing from WO2007/115644), 4- { [(6- chloropyridine -3- base) first Base] (2- fluoro ethyl) amino } furans -2 (5H) -one (knowing from WO2007/115644), fluorine pyrrole furanone (Flupyradifurone), 4- { [(the chloro- 5- fluorine pyridin-3-yl of 6-) methyl] (methyl) amino } furans -2 (5H) -one (from Know in WO2007/115643), 4- { [(5,6- dichloropyridine -3- base) methyl] (2- fluoro ethyl) amino } furans -2 (5H) -one (knowing from WO2007/115646), 4- { [(the chloro- 5- fluorine pyridin-3-yl of 6-) methyl] (cyclopropyl) amino } furans -2 (5H) - Ketone (knowing from WO2007/115643), 4- { [(6- chloropyridine -3- base) methyl] (cyclopropyl) amino } furans -2 (5H) -one (knowing from EP-A-0 539 588), 4- { [(6- chloropyridine -3- base) methyl] (methyl) amino } furans -2 (5H) -one (from Know in EP-A-0 539 588), { [1- (6- chloropyridine -3- base) ethyl] (methyl) oxidation-λ 4- sulfurous alkyl } cyanamide (from Know in WO2007/149134) and its diastereomer { [(1R) -1- (6- chloropyridine -3- base) ethyl] (methyl) oxidation-λ 4- Sulfurous alkyl } cyanamide (A) and { [(1S) -1- (6- chloropyridine -3- base) ethyl] (methyl) oxidation-λ 4- sulfurous alkyl } cyanamide (B) (also knowing from WO2007/149134) and diastereomer [(R)-methyl (oxidation) { (1R) -1- [6- (trifluoromethyl) pyrrole Pyridine -3- base] ethyl }-λ 4- sulfurous alkyl] cyanamide (A1) and [(S)-methyl (oxidation) { (1S) -1- [6- (trifluoromethyl) pyridine - 3- yl] ethyl }-λ 4- sulfurous alkyl] cyanamide (A2), diastereomer A class is referred to as (from WO2010/074747, WO2010/ Know in 074751), [(R)-methyl (oxidation) { (1S) -1- [6- (trifluoromethyl) pyridin-3-yl] ethyl }-λ 4- sulfurous alkane Base] cyanamide (B1) and [(S)-methyl (oxidation) { (1R) -1- [6- (trifluoromethyl) pyridin-3-yl] ethyl }-λ 4- sulfurous alkyl] Cyanamide (B2), being referred to as diastereomer B class (also knowing from WO2010/074747, WO2010/074751) and 11-, (4- is chloro- 2,6- 3,5-dimethylphenyl) two spiral shell [4.2.4.2] of-12- hydroxyl-1,4- dioxa-9- azepine 14-11- alkene-10- ketone (from WO Know in 2006/089633), 3- (the fluoro- 2,4- dimethyl diphenyl -3- base of 4'-) -4- hydroxyl -8- oxa- -1- azaspiro [4.5] Decyl- 3- alkene -2- ketone (knowing from WO 2008/067911), 1- { the fluoro- 4- methyl -5- of 2- [(2,2,2- trifluoroethyl) thionyl Base] phenyl } -3- (trifluoromethyl) -1H-1,2,4- triazole -5- amine (knowing from WO 2006/043635), double third ring worm esters (Afidopyropen) (knowing from WO2008/066153), 2- cyano -3- (difluoro-methoxy)-N, N- dimethyl benzene sulphonyl Amine (knowing from WO2006/056433), 2- cyano -3- (difluoro-methoxy)-N- methyl benzenesulfonamide are (from WO2006/ Know in 100288), 2- cyano -3- (difluoro-methoxy)-N- ethyl beneznesulfonamide (knowing from WO2005/035486), 4- (difluoro-methoxy)-N- ethyl-N-methyl -1,2- benzothiazole -3- amine 1,1- dioxide (is obtained from WO2007/057407 Know), N- [1- (2,3- 3,5-dimethylphenyl) -2- (3,5- 3,5-dimethylphenyl) ethyl] -4,5- dihydro -1,3- thiazole -2- amine (from Know in WO2008/104503), { 1'- [(2E) -3- (4- chlorphenyl) propyl- 2- alkene -1- base] -5- fluorine spiral shell [indoles -3,4'- piperazine Pyridine] -1 (2H)-yl } (2- chloropyridine -4- base) ketone (knowing from WO2003/106457), 3- (2,5- 3,5-dimethylphenyl) -4- Hydroxyl -8- methoxyl group -1,8- diaza spiro [4.5] decyl- 3- alkene -2- ketone (knowing from WO2009/049851), carbonic acid 3- (2, 5- 3,5-dimethylphenyl) -8- methoxyl group -2- oxo -1,8- diaza spiro [4.5] decyl- 3- alkene -4- base ester ethyl ester is (from WO2009/ Know in 049851), 4- (butyl- 2- alkynes -1- base oxygroup) -6- (3,5- lupetidine -1- base) -5-FU is (from WO2004/ Know in 099160), (2,2,3,3,4,4,5,5- octafluoro amyl) (3,3,3- trifluoro propyl) malononitrile is (from WO2005/ Know in 063094), (2,2,3,3,4,4,5,5- octafluoro amyl) (five fluorine butyl of 3,3,4,4,4-) malononitrile is (from WO2005/ Know in 063094), 8- [2- (cyclo propyl methoxy) -4- (trifluoromethyl) phenoxy group] -3- [6- (trifluoromethyl) pyridazine -3- Base] -3- azabicyclo [3.2.1] octane (knowing from WO2007/040280), Flometoquin, PF1364(CAS- Reg.No. 1204776-60-2) (knowing from JP2010/018586), 5- [5- (3,5- dichlorophenyl) -5- (fluoroform Base) -4,5- dihydro -1,2- oxazole -3- base] -2- (1H-1,2,4- triazol-1-yl) benzonitrile (obtains from WO2007/075459 Know), 5- [5- (2- chloropyridine -4- base) -5- (trifluoromethyl) -4,5- dihydro -1,2- oxazole -3- base] -2- (1H-1,2,4- tri- Azoles -1- base) benzonitrile (knowing from WO2007/075459), 4- [5- (3,5- dichlorophenyl) -5- (trifluoromethyl) -4,5- two Hydrogen -1,2- oxazole -3- base] -2- methyl-N- { 2- oxo -2- [(2,2,2- trifluoroethyl) amino] ethyl } benzamide (from Know in WO2005/085216), 4- { [(6- chloropyridine -3- base) methyl] (cyclopropyl) amino } -1,3- oxazole -2 (5H) -one, 4- { [(6- chloropyridine -3- base) methyl] (2,2- bis-fluoro ethyls) amino } -1,3- oxazole -2 (5H) -one, 4- { [(6- chloropyridine - 3- yl) methyl] (ethyl) amino } -1,3- oxazole -2 (5H) -one, 4- { [(6- chloropyridine -3- base) methyl] (methyl) amino } - 1,3- oxazole -2 (5H) -one (knowing from WO2010/005692), Pyflubumide(are obtained from WO2002/096882 Know), 2- [2- ({ [the bromo- 1- of 3- (3- chloropyridine -2- base) -1H- pyrazoles -5- base] carbonyl } amino) chloro- 3- toluyl of -5- Base] -2- methyl methyl carbazate (knowing from WO2005/085216), 2- [2- ({ [the bromo- 1- of 3- (3- chloropyridine -2- base) - 1H- pyrazoles -5- base] carbonyl } amino) -5- cyano -3- methyl benzoyl] -2- ethyl methyl carbazate is (from WO2005/ Know in 085216), 2- [2- ({ [the bromo- 1- of 3- (3- chloropyridine -2- base) -1H- pyrazoles -5- base] carbonyl } amino) -5- cyano - 3- methyl benzoyl] -2- methyl methyl carbazate (knowing from WO2005/085216), 2- [the bromo- 2- ({ [3- of 3,5- bis- Bromo- 1- (3- chloropyridine -2- base) -1H- pyrazoles -5- base] carbonyl } amino) benzoyl] -1,2- diethyl hydrazine methyl formate (from Know in WO2005/085216), 2- [the bromo- 2- of 3,5- bis- ({ [the bromo- 1- of 3- (3- chloropyridine -2- base) -1H- pyrazoles -5- base] carbonyl Base } amino) benzoyl] -2- ethyl methyl carbazate (knowing from WO2005/085216), (5RS, 7RS;5RS,7SR)- 1- (6- chloro-3-pyridyl ylmethyl) -1,2,3,5,6,7- hexahydro -7- methyl -8- nitro -5- propoxyl group imidazo [1,2-a] pyrrole Pyridine (knowing from WO2007/101369), 2- { 6- [2- (5- fluorine pyridin-3-yl) -1,3- thiazole -5- base] pyridine -2- base } are phonetic Pyridine (knowing from WO2010/006713), 2- { 6- [2- (pyridin-3-yl) -1,3- thiazole -5- base] pyridine -2- base } pyrimidine (from Know in WO2010/006713), 1- (3- chloropyridine -2- base)-N- [4- cyano -2- methyl -6- (methylcarbamoyl) benzene Base] -3- { [5- (trifluoromethyl) -1H-TETRAZOLE -1- base] methyl } -1H- pyrazoles -5- formamide (obtains from WO2010/069502 Know), 1- (3- chloropyridine -2- base)-N- [4- cyano -2- methyl -6- (methylcarbamoyl) phenyl] -3- { [5- (fluoroform Base) -2H- tetrazolium -2- base] methyl } -1H- pyrazoles -5- formamide (knowing from WO2010/069502), N- [2- (tert-butyl ammonia Base formoxyl) -4- cyano -6- aminomethyl phenyl] -1- (3- chloropyridine -2- base) -3- { [5- (trifluoromethyl) -1H-TETRAZOLE -1- base] Methyl } -1H- pyrazoles -5- formamide (knowing from WO2010/069502), N- [2- (t-Butylcarbamoyl) -4- cyano - 6- aminomethyl phenyl] -1- (3- chloropyridine -2- base) -3- { [5- (trifluoromethyl) -2H- tetrazolium -2- base] methyl } -1H- pyrazoles -5- Formamide (knowing from WO2010/069502), (1E)-N- [(6- chloropyridine -3- base) methyl]-N'- cyano-N- (2,2- bis- Fluoro ethyl) ethanamidine (knowing from WO2008/009360), N- [2- (5- amino -1,3,4- thiadiazoles -2- base) chloro- 6- first of -4- Base phenyl] the bromo- 1- of -3- (3- chloropyridine -2- base) -1H- pyrazoles -5- formamide (knowing from CN102057925), 2- [3,5- Two bromo- 2- ({ [the bromo- 1- of 3- (3- chloropyridine -2- base) -1H- pyrazoles -5- base] carbonyl } amino) benzoyls] -2- ethyl -1- first Base methyl carbazate (knowing from WO2011/049233), seven fluorine methothrin (Heptafluthrin) of dextrorotation, pyriminostrobin (Pyriminostrobin), fluorine bacterium mite ester (Flufenoxystrobin) and the chloro- N2- of 3- (2- cyano propyl- 2- yl)-N1- [4- (seven fluorine propyl- 2- yl of 1,1,1,2,3,3,3-) -2- aminomethyl phenyl] phthalamide (knowing from WO2012/034472), cycloxaprid (Cycloxaprid) (1203791-41-6).

The molluscicide that can be mentioned is metacetaldehyde (metaldehyde) and methiocarb.

In a preferred embodiment, the present invention relates to the purposes of composition, the composition includes A) fluorine pyrrole bacterium acyl Amine and/or bacillus subtilis, especially bacterial strain QST 713 or fluopyram and/or bacillus subtilis, especially bacterium The mixture and B of strain QST 713) one or more following insecticides:

Nicotinic acetylcholine receptors alpha7, preferably Acetamiprid, dinotefuran, imidacloprid, clothianidin, thiacloprid, Diacloden, fluorine pyridine Worm amine nitrile and sodium channel modulators, preferably cypermethrin, α-cypermethrin, λ-Cyhalothrin, γ-Cyhalothrin, β-cyfloxylate, cyfloxylate, Tefluthrin, transfluthrin, decis, Biphenthrin, acrinathrin

Acetylcholinesterase inhibitor, preferably chlopyrifos, carbofuran, accephate, mercaptodimethur, thiodicarb, Aldicarb, Profenofos, Nemacur, lythidathion, phonamiphos, Phorate Metamoidophos

Blue Buddhist nun's alkali receptor modulators, preferably Chorantraniliprole, bromine cyanogen insect amide, fipronil bisamide

Chloride channel activators, preferably avermectin, emamectin benzoate (benzoate), close spit of fland of going out

Nicotinic acetylcholine receptor allosteric activation agent, preferably pleocidin (Spinosad), ethyl pleocidin (Spinetoram)

GABA- gated chloride channel antagonist, preferably Fipronil and ethiprole

Voltage dependent form sodium channel inhibitor, preferably indoxacarb, metaflumizone

Mitochondrial complex I electron transfer inhibitor, preferably tebufenpyrad, fenpyroximate

Mitochondrial complex II electron transfer inhibitor, preferably nitrile pyrrole mite ester, Cyflumentofen

Mitochondrial ATP synthase inhibitor, preferably diafenthiuron

Oxidative phosphorylation uncoupler, preferably chlorfenapyr (Chlofenapyr)

Benzoylurea derivertives, preferably lufenuron, methoxyfenozide, triflumuron, Buprofezin

Selective Homoptera feeds retarding agent, preferably pymetrozine, flonicamid

Additional nematicide, preferably oxamyl, fluopyram, connection fluorine sulfone (Fluensulfone)

Acetyl-CoA carboxylase inhibitor, preferably spiral shell worm ethyl ester, Envidor and Spiromesifen

The chloro- 5- ethylpyridine (1:1) of 4- [(2,2- bis-fluoro ethyls) amino] (5H) -one of furans-2-2-, fluorine pyrrole furanone (Flupyradifurone), Pyrifluquinazon, Flomentoquin, Pyflubumide, cycloxaprid (Cycloxaprid) and fumigant.

In another embodiment, the present invention relates to the purposes of composition, the composition includes A) fluopyram And/or bacillus subtilis, especially bacterial strain QST 713 or fluopyram and/or bacillus subtilis, especially bacterial strain The mixture and B of QST 713) at least one wireworm-killing biologic control agent.

Another exemplary method of the invention includes to soil or plant (such as foliar spray) application fluopyram and/or withered Careless bacillus, especially bacterial strain QST 713 or fluopyram and/or bacillus subtilis, especially bacterial strain QST 713 Mixture-or the fluopyram combined at least one biocontrol agent and/or bacillus subtilis, especially bacterial strain QST 713 or fluopyram and/or bacillus subtilis, the especially mixture-of bacterial strain QST 713 are to fight nematode danger Evil and/or raising crop yield.

It is suitable for the invention being specified under wireworm-killing biologic control agent (such as such as B)) it include bacterial antagonists and food line Worm fungi.

The bacterial antagonists that can be used for this paper include, but are not limited to obligatory parasitism bacterium (obligate parasitic Bacteria), chance parasitic bacteria (opportunistic parasitic bacteria), rhizosphere bacteria, companion's spore Cry albumen Matter forms bacterium, endophytic bacterium and symbiotic bacteria.

In specific embodiments, for fluopyram and/or bacillus subtilis, especially bacterial strain QST 713 The biocontrol agent of mixture can be strain selected from the following: actinomyces (ActinomycetesSpp.), agrobacterium Belong to (AgrobacteriumSpp.), Arthrobacter (ArthrobacteR spp.), alcaligenes (Alcaligenes Spp.), golden Bacillus (AureobacteriumSpp.), azotobacter (AzobacterSpp.), bacillus (BacillusSpp.), for example, Soil Bacillus (Bacillus agri),Bacillus aizawai、Bacillus albolactis, bacillus amyloliquefaciens (Bacillus amyloliquefaciens), especially bacterial strain IN973a or bacterial strain B3 or bacterial strain FZB42, Bacillus cercus (Bacillus cereus), especially bacterial strain CNCM I-1562, cutin spore bud Spore bacillus (Bacillus chitinosporus), Bacillus circulans (Bacillus circulans), bacillus coagulans (Bacillus coagulans),Bacillus endoparasiticus、Bacillus endorhythmos, strong gemma Bacillus (Bacillus firmus), especially bacterial strain CNCM 1-1582(is referred to as the production of Votivo, Flocter, Bionem Product),Bacillus kurstaki, the newborn bacillus that dwells (Bacillus lacticola), bacillus lentimorbus (Bacillus lactimorbus), lactobacillus (Bacillus lactis), bacillus laterosporus (Bacillus laterosporus), slow disease Bacillus (Bacillus lentimorbus), bacillus licheniformis (Bacillus licheniformis), huge gemma Bacillus (Bacillus megaterium),Bacillus medusa、Bacillus metiens, bafillus natto (Bacillus natto), food nematode bacillus (Bacillus nematocida),Bacillus nigrificans、Bacillus popillae, bacillus pumilus (Bacillus pumilus), especially bacterial strain GB34 or bacterial strain QST2808,Bacillus siamensis, Bacillus sphaericus (Bacillus sphaericus), bacillus (Bacillus spp.), bacillus subtilis (Bacillus subtilis), bacillus sp B16；Bacillus thuringiensis (Bacillus thuringiensis) (including forming the Cry albumen toxic to nematode and/or nematode larval, as Cry5, Cry6, Cryl2, Those of Cryl3, Cryl4 and Cry21), bacillus thuringiensis subsp israelensis (Bacillus thuringiensis Israelensis)；Bacillus thuringiensis Kurstaki (Bacillus thuringiensis Kurstaki)；Su Yun Golden Bacillus strain ATCC 55273；Bacillus thuringiensis aegyptii mutation (Bacillus thuringiensis var aegyptii)；Bacillus thuringiensis (Bacillus thuringiensis subspec aizawai), Especially strains A BTS-1857；Bacillus thuringiensis Cole write from memory mutation (Bacillus thuringiensis var colmeri)；Bacillus thuringiensis darmstadiensis mutation (Bacillus thuringiensis var darmstadiensis)；Bacillus thuringiensis dendrolimus mutation (Bacillus thuringiensis var dendrolimus)；Bacillus thuringiensis galleria mutation (Bacillus thuringiensis var galleria)； Bacillus thuringiensis japonensis mutation (Bacillus thuringiensis var japonensis)；Su Yun gold bud Spore bacillus morrisoni subspecies (Bacillus thuringiensis subspe. morrisoni)；Bacillus thuringiensis San Diego mutation (Bacillus thuringiensis var San Diego)；Bacillus thuringiensis tenebrionis Mutation (Bacillus thuringiensis var tenebrionis), especially bacterial strain NB176；Bacillus uniflagellates, and " Bergey's Manual of Systematic Bacteriology, the first edition (1986) " In bacillus classification in those of enumerate；Beijerinckia (Beijerinckia Spp.), bacillus brevis Belong to (BrevibacillusSpp.), for example, Brevibacillus brevis (Brevibacillus brevis), Brevibacillus laterosporus (Brevibacillus laterosporus), especially bacterial strain G4, Burkholderia (BurkholderiaSpp.), Such as Burkholderia cepacia (Burkholderia cepacia), Chromobacterium (ChromobacteriumSpp.), stick Shape Bacillus (ClavibacterSpp.), fusobacterium (ClostridiumSpp.),ComomonasBelong to, corynebacterium (CorynebacteriumSpp.), such asCorynebacterium paurometabolu、Corynebacterium pauronietabolum, Curtobacterium (CurtobacteriumSpp.),DesulforibtioBelong to；Enterobacter (EnterobacterSpp.), Flavobacterium (FlavobacteriumSpp.), Gluconobacter (Gluconobacter Spp.),HydrogenophageBelong to, Klebsiella (KlebsiellaSpp.), the molten bacillus of producing enzyme (Lysobacter enzymogenes), Methylobacter (MethylobacteriumSpp.), Pasteur bud Pseudomonas (PasteuriaSpp.), Such as puncture Pasteur bud bacterium (Pasteuria penetrans) (product referred to as EcoNem), thorniness Pasteur bud bacterium (Pasteuria thornei),Pasteuria nishizawae, especially bacterial strain Pn1(is referred to as Soyacyst LF/ST's Product),Pasteuria reniformis, especially bacterial strain Pr3；Pasteuria ramosa、Candidatus Pasteuria usgae sp. nov., pseudomonas (Pseudomonas), such as Pseudomonas aeruginosa spp. (Pseudomonas aeruginosa), golden pseudomonad (Pseudomonas aureofaciens), Pseudomonas cepacia (Pseudomonas cepacia), Pseudomonas chlororaphis (Pseudomonas chlororaphis), Pseudomonas fluorescens (Pseudomonas fluorescens), pseudomonas putida (Pseudomonas putida) and bacillus genus (PaenibacillusSpp.), for example, Paenibacillus macerans (Paenibacillus macerans) and honeycomb class gemma bar Bacterium (Paenibacillus alvei), Phyllobacterium (PhyllobacteriumSpp.),PhingobacteriumBelong to, shine Bacillus (PhotorhabdusSpp.), rhizosphere bacteria (Rhizobacteria), rhizobium (RhizobiumSpp.), husky Thunder Bordetella (SerratiaSpp.),StenotrotrophomonasBelong to, Xenorhabdus (XenorhabdusSpp.), covet Phagocytosis category (VariovoraxSpp.).

In an especially preferred embodiment, fluopyram and/or bacillus subtilis, especially bacterial strain are used for The wireworm-killing biologic control agent of the mixture of QST 713 is at least one heavily fortified point as disclosed in United States Patent (USP) No. 6,406,690 Strong bacillus CNCM 1-1582 spore and/or bacillus cereus strain CNCM 1-1562 spore.

In other preferred embodiments, it to be used for fluopyram and/or bacillus subtilis, especially bacterial strain QST The bacterium of 713 mixture is the bacillus subtilis of at least one bacillus amyloliquefaciens IN937a, at least one entitled GB03 Bacillus pumilus (B. pumulis) bacterial strain of bacteria strain or at least one entitled GB34.Four kinds of above-listed bacteriums and known table Other sporogenic for revealing agricultural benefit property grow the combination of bacterium within the scope and spirit of this invention.

Particularly preferred embodiment according to the present invention there are also comprising bacillus firmus CNCM 1-1582 spore and/ Or those of mutant of bacillus cereus strain CNCM 1-1562 spore composition.Pole, which particularly preferably has, kills line Those of worm activity mutant.

This technology also provides such embodiment, and wherein nematode antibionts control agent includes Nematophagous fungi, such as But it is not limited to, ARF18(Arkansas Fungus 18)；Arthrobotrys (ArthrobotrysSpp.), such as less spore Arthrobotrys Bacterium (Arthrobotrys oligospora),Arthrobotrys superbaWith finger-like section from spore (Arthrobotrys dactyloides)；Chaetomium (ChaetomiumSpp.), for example, chaetomium globosum (Chaetomium globosum)；Column spore Belong to (CylindrocarponSpp.), such asCylindrocarpon heteronema；Dactylaria (Dactylaria Spp.), such asDactylaria candida；Exophiala (Exophilia), such as Exophiala jeanselmei spp. (Exophiala jeanselmei) and the outer Saksenaea vasiformis of thermophilic fish (Exophiala pisciphila)；Fusarium (Fusarium Spp.), for example, Fusarium solani (Fusarium solani)；Gliocladium (GliocladiumSpp.), such as chain spore glues broom Mould (Gliocladium catenulatum), Gliocladium roseum (Gliocladium roseum) and G virens (Gliocladium virens)；Snag spore category (HarposporiumSpp.), as vinegar worm vinegar eel snag spore (Harposporium anguillulae)；Hirsutella Pat (HirsutellaCoat spore spp.), such as in Loews (Hirsutella rhossiliensis), Hirsutella minnesotensis (Hirsutella minnesotensis) and thompson coat spore (Hirsutella thompsonii)；Lecanium category (Lecanicillium), such as Verticillium lecanii spp. (Lecanicillium lecanii,=Verticillium lecanii)；The mould category of capping (MeristacrumSpp.), such asMeristacrum asterospermum；Monacrosporium (Monacrosporium), such as Jue Shi genus monacrosporium spp. (Monacrosporium drechsleri),Monacrosporium gephyropagumGenus monacrosporium is caught with column (Monacrosporium cionopagum)；Myrothecium (MyrotheciumSpp.), such asMyrotehcium verrucaria, product of the especially strains A ARC0255(referred to as 90 WG of Ditera)；The mould category of poisonous insect (Nematoctonus Spp.), such asNematoctonus geogenius、Nematoctonus leiosporus；Neocosmospora (NeocosmosporaSpp.), for example, invade Guan Xinchi shell bacterium (Neocosmospora vasinfecta)；Paecilomyces (PaecilomycesSpp.), as Paecilomyces lilacinus (Paecilomyces lilacinus) and paecilomyces varioti (Paecilomyces variotii)；Pukeniya genus (PochoniaSpp.), as chlamydospores Pukeniya bacteria (Pochonia chlamydosporia,=Vercillium chlamydosporium；Product referred to as KlamiC)；Stagonospora (StagonosporaSpp.), such asStagonospora heteroderaeWithStagonospora phaseoli；Strepto- Pseudomonas (StreptomycesSpp.), such asStreptomyces saraceticusAnd streptomyces venezuelae (Streptomyces venezuelae) and bubble arbuscular mycorrhizal fungi (vesicular-arbuscular mycorrhizal Fungi), trichoderma (Trichoderma Spp.), for example, Trichoderma asperellum (Trichoderma asperellum), navel spore wood Mould (Trichoderma brevicompactum), trichoderma harzianum (Trichoderma harzianum),Tsukamurella paurometabola, Verticillium chlamydosporium (Verticillium chlamydosporium).

Preparation

It include fluopyram the invention further relates to prevent and treat the wilt disease of Musaceae, especially banana And/or bacillus subtilis, the especially composition of bacterial strain QST 713.It includes agriculture suitable adjuvant that these, which are preferably, molten Agent, carrier, surfactant or incremental agent composition.

Fluopyram and/or bacillus subtilis, especially bacterial strain QST 713, which can be used as, is applied in combination.Fluorine pyrrole bacterium acyl Amine and/or bacillus subtilis, especially bacterial strain QST 713 are also possible to composition, bucket mixture or hybrid packed.

According to the present invention, carrier be for better workability, especially for be administered to plant or plant parts or Natural or synthetic, the organic or inorganic substance for mixing or merging on seed and with active constituent.It can be the load of solid or liquid Body is usually inert and should apply to agricultural.

Available solid carrier includes: such as ammonium salt and natural rock powder, such as kaolin, clay, talcum, chalk, quartz, green Palygorskite, montmorillonite or diatomite, and synthesis rock powder, such as silica fine crushing, aluminium oxide and silicate；It can be used for granule Solid carrier include: for example, the natural rock for crushing and being classified, such as calcite, marble, float stone, sepiolite and dolomite, with And inorganic and organic powder synthesis particle and organic material particle, such as paper, sawdust, coconut husk, corncob and tobacco rod；It is available Emulsifier and/or foam former include: such as nonionic and anion emulsifier, such as polyoxyethylene fatty acid ester, polyoxy second Alkene fatty alcohol ether, such as alkylaryl polyglycol ether, alkylsulfonate, alkyl sulfate, arylsulphonate and proteolysis Product；Suitable dispersing agent is nonionic and/or ionic species, such as selected from alcohol-POE and/or-POP ether, acid and/or POP POE ester, alkylaryl and/or POP POE ether, fat and/or POP POE adduct, POE- and/or POP- polyalcohol are derivative Object, POE- and/or POP- sorbitan or-sugar adduct, alkyl or aryl sulfate, alkyl-or arylsulphonate and alkane Base or aryl orthophosphate or corresponding PO- ether adduction species.In addition suitably oligomer or polymer, such as derived from second Those of vinyl monomer, acrylic acid, independent or EO in conjunction with such as (polynary) alcohol or (more) amine and/or PO.Also it can be used Lignin and its sulfonic acid, unmodified and modified cellulose, aromatics and/or aliphatic sulfonic acid and its adduct with formaldehyde.

Fluopyram and/or bacillus subtilis, especially bacterial strain QST 713 can be converted to conventional formulation, such as solution Agent, emulsion, wettable powder, water base and oil suspensions, pulvis (powders), pulvis (dusts), paste, soluble powder Agent, soluble granule broadcast sowing with granule, suspension concentrates (suspoemulsion concentrates), use active constituent The natural products of dipping, synthetic, fertilizer and the microcapsules in polymeric material impregnated with active constituent.

Fluopyram and/or bacillus subtilis, especially bacterial strain QST 713 can as former state, with their preparation or The form for the use form being made from it is applied, such as instant solution, emulsion, water base or oil suspensions, pulvis, wettable Pulvis, paste, soluble powder, pulvis (dusts), soluble granule, broadcast sowing with granule, suspension concentrates, with activity at The natural products of sub-dip stain, synthetic, fertilizer and the microcapsules in polymeric material impregnated with active constituent.With routine Mode realizes application, for example, by watering (watering), spray, be atomized, broadcast sowing, dusting, foaming, apply paving (spreading- On) etc..Active constituent can also be applied by ultra-low volume method or infuse active fluopyram preparation/fluopyram itself It is mapped in soil.

The preparation being previously mentioned can be prepared in a way known, such as by the way that active constituent and at least one is conventional Incremental agent, solvent or diluent, emulsifier, dispersing agent and/or adhesive or fixative, wetting agent, water repellent, (if appropriate) Desiccant and UV stabilizer and (if appropriate) dyestuff and pigment, antifoaming agent, preservative, secondary thickener (secondary Thickener), sticker, gibberellin and the mixing of other processing aids.

The present invention not only includes the preparation that i.e. usable and available suitable device is administered on plant or seed, further includes Using the preceding business concentrate that must be diluted with water.

Fluopyram and/or bacillus subtilis, especially bacterial strain QST 713 can exist as former state or with their (quotient Industry) preparation exists and with by these preparations and other (known) active constituents, as insecticide, attractant, bactericidal agent, fungicide, Acaricide, nematicide, fungicide, growth regulator, herbicide, fertilizer, safener and/or semiochemical mixture Manufactured use form exists.

Adjuvant used can be suitable for be the composition itself and/or be that preparation made of it is (such as spraying Liquid, seed dressing) special properties are provided, such as particular technology property and and/or those of particular organisms property substance.It is typical auxiliary Auxiliary agent includes: incremental agent, solvent and carrier.

Suitable incremental agent is such as water, polarity and nonpolar organic chemistry liquid, such as selected from aromatic hydrocarbons and non-aromatic hydro carbons (such as paraffin, alkylbenzene, alkylnaphthalene, chlorobenzene), pure and mild polyalcohols (it can also optionally be substituted, is etherified and/or be esterified), ketone (such as acetone, cyclohexanone), esters (including fat and oil) and (poly-) ethers, unsubstituted and substituted amine, amides, lactams Class (such as N- alkyl pyrrolidone) and lactone, sulfone class and sulfoxide type (such as dimethyl sulfoxide).

Liquefied gas incremental agent or carrier are understood to mean under normal temperature and are under standard pressure gaseous liquid Body, such as aerosol propellants, such as halogenated hydrocarbons or butane, propane, nitrogen and carbon dioxide.

Tackifier, such as carboxymethyl cellulose, the natural and conjunction of powder, particle or latex form can be used in said preparation At polymer, such as gum arabic, polyvinyl alcohol and polyvinyl acetate or natural phospholipid, such as cephalin and lecithin, and close At phosphatide.Other additive can be mineral and vegetable oil.

If incremental agent used is water, such as organic solvent also can be used as secondary solvent.Available liquid solvent Substantially: aromatic hydrocarbons, such as dimethylbenzene, toluene or alkylnaphthalene, chlorinated aromatics or chlorinated aliphatic hydrocarbons, such as chlorobenzene, vinyl chloride or dichloromethane Alkane, aliphatic hydrocarbon, such as hexamethylene or alkane, such as petroleum distillate, alcohol such as butanol or two they pure and mild ethers and ester, ketone such as third Ketone, methyl ethyl ketone, methyl iso-butyl ketone (MIBK) or cyclohexanone, intensive polar solvent, such as dimethylformamide and dimethyl sulfoxide or water.

It can be additionally comprised comprising fluopyram and/or bacillus subtilis, the especially composition of bacterial strain QST 713 Its component, such as surfactant.Suitable surfactant be emulsifier and/or foam former, dispersing agent or have from The mixture of the wetting agent or these surfactants of son or non-ionic nature.The example is the salt of polyacrylic acid, lignosulphonic acid Salt, phenol sulfonic acid or naphthalene sulfonic acids salt, ethylene oxide and fatty alcohol or with fatty acid or with the condensation polymer of fatty amine, substituted phenol (optimizing alkyl phenol or aryl phenol), the salt of sulfosuccinate, taurine derivatives (optimizing alkyl taurate), polyethoxy Change the phosphate of alcohol or phenol, the aliphatic ester of polyalcohol, and the derivative of the compound containing sulfate radical, sulfonate radical and phosphate radical Object, such as alkylaryl polyglycol ether, alkylsulfonate, alkyl sulfate, arylsulphonate, protein hydrolysate, lignin Sulfite waste liquor and methylcellulose.If one of active constituent and/or one of inert carrier are not soluble in water and ought be in water When being administered, the presence of surfactant is necessary.The ratio of surfactant is 5 to 40 weights of composition of the invention Measure %.

Dyestuff, such as inorganic pigment, such as iron oxide, titanium oxide and Prussian blue and organic dyestuff, such as alizarin can be used Dyestuff, azo dyes and metallized phthalocyanine dye and micronutrient, such as the salt of iron, manganese, boron, copper, cobalt, molybdenum and zinc.

Other additive can be essence (mineral or plant), optional modified oil, wax and nutrient (including micronutrient Element), such as the salt of iron, manganese, boron, copper, cobalt, molybdenum and zinc.

Annexing ingredient can be stabilizer, as low temperature stabilizer (cold stabilizers), preservative, antioxidant, Light stabilizer or the other reagents for improving chemistry and/or physical stability.

If appropriate, other annexing ingredients also may be present, such as protecting colloid, adhesive, adhesive, thickener, thixotroping Substance, bleeding agent, stabilizer, chelating agent, complexing agent.In general, active constituent can be usually used in prepare purposes it is any Solid or liquid additive combination.

Said preparation contains usual 0.05 to 99 weight %, 0.01 to 98 weight %, preferably 0.1 to 95 weight %, and more preferable 0.5 To 90% active constituent, most preferably 10 to 70 weight %.

Above-mentioned preparation can be used for preventing and treating the wilt disease of Musaceae plant, wherein will include fluopyram and/or withered grass bud Spore bacillus, the composition of especially bacterial strain QST 713 is administered to banana plant and/or their habitat, or is administered to sharp spore Sickle-like bacteria Cuba specialized form itself.

Method of administration

Fluopyram and/or bacillus subtilis, especially bacterial strain QST 713 are used according to the present invention or include fluopyram And/or bacillus subtilis, the especially composition of bacterial strain QST 713 directly carry out the processing of plant and plant parts or lead to It crosses and acts on their ambient enviroment, habitat or storage space with conventional treatment method to carry out, such as by impregnating, spraying It spills, be atomized, irrigating, stem's injection, the interior application of ditch, evaporation, dusting, haze (fogging), broadcast sowing, foam, smearing (painting), paving (spreading-on), watering (pouring water), trickle irrigation and in the case of propagation materials are applied, is especially being planted In the case where son, also as pulvis for dry seed treatment, for the solution of seed treatment, for the water-soluble of slurries processing Property pulvis, by involucrum, by one or more layers coating etc..Can also by ultra-low volume method apply fluopyram and/or Bacillus subtilis, especially bacterial strain QST 713, or active fluopyram preparation or fluopyram itself are injected into soil In earth.Preferably native applying method pours water, application, trickle irrigation or irrigation in ditch.Can prophylactically apply fluopyram and/or Bacillus subtilis, especially bacterial strain QST 713.

Rate of application

When using fluopyram, rate of application can be changed in relatively wide range according to application type.Fluorine pyrrole bacterium acyl The rate of application of amine is

In the case where handling plant parts such as leaf: 100 to 1000 g/ha, preferably 200 to 500 g/ha, more preferably 250 to 500/ha, most preferably 250/ha, 375 g/ha or 500/ha(by watering or trickle irrigation in the case where being applied, even Rate of application can be reduced, especially inert base is being used, when such as asbestos or perlite)；

In the case where soil treatment, 100 to 1000 g/ha, preferably 200 to 500 g/ha, more preferable 250 to 500/ha, Most preferably 250/ha, 375 g/ha or 500/ha.

It, can be according to application type in relatively wide model when using bacillus subtilis, especially bacterial strain QST 713 Enclose interior change rate of application.The rate of application of bacillus subtilis, especially bacterial strain QST 713 is

In the case where handling plant parts such as leaf: 10 to 3000 g/ha, preferably 50 to 1500 g/ha, more preferable 80 To 1500/ha, most preferably 80 to 300 g/ha(by watering or trickle irrigation in the case where being applied, it might even be possible to reduce application Rate is especially using inert base, when such as asbestos or perlite)；

In the case where soil treatment, 10 to 3000 g/ha, preferably 50 to 1500 g/ha, more preferable 80 to 1500/ha, Most preferably 80 to 300 g/ha.

These rate of application are only used as example and are not limiting for the object of the invention.

Embodiment

Embodiment 1

Using 0.01 ppm, 0.1 ppm, 1 ppm, 10 ppm, 100 ppm, 1000 ppm concentration under with potato The assessment of fungi growth on the Petri dish of dextrose culture-medium, EC 50 value of the assessment fluopyram to FOC.? 0.6 ppm fluopyram and the lower measurement EC50 of 0,0000013 ppm bacillus subtilis QST 713.

Embodiment 2

The grown on soil banana plant of Fusarium oxysporum Cuba specialized form microspecies 1 is inoculated in sterilizing before, then in single tank. Fluopyram is applied in the SC preparation (Verango SC) of 500 g/l with the ratio of 250 g/ha, 375 g/ha, 500 g/ha With being further diluted with water.Bacillus subtilis is in the 1,34 SC preparations comprising 134 g/l bacillus subtilis QST 713 In (it is equivalent to 1x10¹¹Colony forming unit (cfu)) it is applied with the ratio of 0.6 l.

80 WG of Aliette includes 80 % w/w phosethyl-Als.

Disease rating scale

0: health

1: light symptoms

2: moderate disease symptoms

3: severe disease symptoms

4: dead strain

Active constituent	Fluopyram rate of application	Bacillus subtilis Q713 rate of application	Phosethyl-Al rate of application	Disease severity
					Inoculation but non-treated reference material	0	0	0	1.68
Aliette	0	0	2 kg/ha	1.16
					Aliette			4 kg/ha	1.44
Fluopyram	375 g/ha	0	0	0.64
					0,6 L+ fluopyram 1L+ Aliette of bacillus subtilis Q713,2,5 Kg	500 g/ha	81.6 g/ha	2 kg/ha	0.84
0,6 L+ fluopyram 1L+ of bacillus subtilis Q713	500 g/ha	81.6 g/ha	0	0.68
					Fluopyram	500 g/ha	0	0	0.76

Embodiment 3

It is inoculated with the grown on soil of Fusarium oxysporum Cuba specialized form microspecies 1 in sterilizing before, then in single tank in the greenhouse The banana plant of Gros Michel kind.Fluopyram is in the SC preparation (Verango SC) of 500 g/l with 250 g/ The ratio application of ha, 375 g/ha, 500 g/ha, are further diluted with water.Bacillus subtilis is including 134 g/l withered grass (it is equivalent to 1x10 in the 1,34 SC preparations of bacillus QST 713¹¹Colony forming unit (cfu)) it is applied with the ratio of 0.6 l With.

80 WG of Aliette includes 80 % w/w phosethyl-Als.The sextuplicate progress of the test, provides five on every Mondays The average value of secondary assessment.

Disease rating scale

0: without decoloration, health

1: small decoloration point

2: the plant decoloration less than 1/3

The plant of 3:1/3 to 2/3 is decolourized

4: the plant decoloration more than 2/3

5: decoloration completely

Active constituent	Fluopyram rate of application	Bacillus subtilis Q713 rate of application	Phosethyl-Al rate of application	Disease severity
					Inoculation but non-treated reference material	0	0	0	3.4
Aliette	0	0	2 kg/ha	3
					Aliette			4 kg/ha	3.4
Fluopyram	375 g/ha	0	0	2.6
					0,6 L+ fluopyram 1L+ Aliette of bacillus subtilis Q713,2,5 Kg	500 g/ha	81.6 g/ha	2 kg/ha	2.6
0,6 L+ fluopyram 1L+ of bacillus subtilis Q713	500 g/ha	81.6 g/ha	0	2.6
					Fluopyram	500 g/ha	0	0	2.4

Embodiment 4

Plant the perfume (or spice) of Gros Michel kind on the no sterilizing soil for being present with or without machine object in single tank in the greenhouse Any of several broadleaf plants plant.(it is equivalent to bacillus subtilis in the 1,34 SC preparations comprising 134 g/l bacillus subtilis QST 713 1x10¹¹Colony forming unit (cfu)) it was applied with the ratio of 1 l, 3 L, 5L and 7L through 6 weeks periods, while overall ratio being divided At application 6 times once a week.Repeat number is 6.It is small with Fusarium oxysporum Cuba specialized form after the completion of bacillus subtilis application Kind inoculation soil.Show the average value of 5 data assessments.

Disease rating scale

0: without decoloration, health

1: small decoloration point

2: the plant decoloration less than 1/3

The plant of 3:1/3 to 2/3 is decolourized

4: the plant decoloration more than 2/3

5: decoloration completely

Active constituent	There are organic matters	Bacillus subtilis Q713 rate of application	Disease severity
				Inoculation but non-treated reference material	It is not present	0	1.6
Inoculation but non-treated reference material	In the presence of	0	1.2
				Bacillus subtilis QST 713	It is not present	134 g/ha	0.7
Bacillus subtilis QST 713	In the presence of	134 g/ha	0.8
				Bacillus subtilis QST 713	It is not present	402 g/ha	0.9
Bacillus subtilis QST 713	In the presence of	402 g/ha	0.5
				Bacillus subtilis QST 713	It is not present	670 g/ha	0.9
Bacillus subtilis QST 713	In the presence of	670 g/ha	0.4
				Bacillus subtilis QST 713	It is not present	938 g/ha	0.9
Bacillus subtilis QST 713	In the presence of	938 g/ha	0.8

Embodiment 5

Disease rating scale

0: without decoloration, health

1: small decoloration point

2: the plant decoloration less than 1/3

The plant of 3:1/3 to 2/3 is decolourized

4: the plant decoloration more than 2/3

5: decoloration completely

Active constituent	There are organic matters	Bacillus subtilis Q713 rate of application	Disease severity
				Without the non-treated reference material of inoculation	It is not present	0	1
Without the non-treated reference material of inoculation	In the presence of	0	1
				Inoculation but non-treated reference material	It is not present	0	5.4
Inoculation but non-treated reference material	In the presence of	0	3.7
				Bacillus subtilis QST 713	It is not present	134 g/ha	3.3
Bacillus subtilis QST 713	In the presence of	134 g/ha	2.9
				Bacillus subtilis QST 713	It is not present	402 g/ha	3.4
Bacillus subtilis QST 713	In the presence of	402 g/ha	3.4
				Bacillus subtilis QST 713	It is not present	670 g/ha	3.6
Bacillus subtilis QST 713	In the presence of	670 g/ha	2.6
				Bacillus subtilis QST 713	It is not present	938 g/ha	3.3
Bacillus subtilis QST 713	In the presence of	938 g/ha	2.9

Embodiment 6

In unpasteurized grown on soil banana plant in single tank.SC preparation (Verango of the fluopyram in 500 g/l SC it is applied in) with the ratio of 250 g/ha, 375 g/ha, 500 g/ha, is further diluted with water.Bacillus subtilis is being wrapped (it is equivalent to 1x10 in the 1,34 SC preparations containing 134 g/l bacillus subtilis QST 713¹¹Colony forming unit (cfu)) with The ratio of 2 l was applied through 6 weeks periods, while overall ratio being divided into and is applied 6 times once a week.Repeat number is 6.In fluorine pyrrole bacterium After the completion of amide/bacillus subtilis application, soil is inoculated with Fusarium oxysporum Cuba specialized form microspecies.Show that 5 data are commented The average value estimated.

Disease rating scale

0: health

1: light symptoms

2: moderate disease symptoms

3: severe disease symptoms

4: dead strain

Active constituent	Fluopyram rate of application	Bacillus subtilis Q713 rate of application	Disease severity
				Without the non-treated reference material of inoculation	0	0	0
Inoculation but non-treated reference material	0	0	1.1
				Fluopyram	375 g/ha	0	0.3
Fluopyram	375 g/ha	0	0.4
				Fluopyram	500 g/ha	0	0.2
2 L+ fluopyram 1L of bacillus subtilis Q713	500 g/ha	268 g/ha	0.2

Embodiment 7

0: without decoloration, health

1: small decoloration point

2: the plant decoloration less than 1/3

The plant of 3:1/3 to 2/3 is decolourized

4: the plant decoloration more than 2/3

5: decoloration completely

Active constituent	Fluopyram rate of application	The rate of application of bacillus subtilis Q713	Disease severity
				Without the non-treated reference material of inoculation	0	0	1
Inoculation but non-treated reference material	0	0	4.6
				Fluopyram	375 g/ha	0	1.4
Fluopyram	375 g/ha	0	1.7
				Fluopyram	500 g/ha	0	1.6
2 L+ fluopyram 1L of bacillus subtilis Q713	500 g/ha	268 g/ha	1.3

Claims

1. The chemical name is N-{2-[3-chloro-5-(trifluoromethyl)-2-pyridyl]ethyl}-2-trifluoromethylbenzamide (fluopyram) formula (1) Compound and/or Bacillus subtilis are used to control the purposes of Fusarium wilt of Musaceae plants

.

2. Use according to claim 1, wherein said plant belongs to the genus Musa.

3. Use according to any one of claims 1 to 2, wherein at least one additional agrochemically active compound or at least one nematicidal biocontrol agent is used.

4. Use according to any one of claims 1 to 3, wherein fluopyram is used.

5. Use according to any one of claims 1 to 3, wherein Bacillus subtilis is used.

6. Use according to claim 5, wherein the Bacillus subtilis strain QST 713 is used.

7. A method for controlling Fusarium wilt of Musaceae plants or the environment in which these plants grow by applying fluopyram and/or Bacillus subtilis to these plants.

8. The method of claim 7, wherein the plant belongs to the Musaceae family.

9. The method of claim 7, wherein fluopyram is applied to the plant or the environment in which the plant grows.

10. The method of claim 7, wherein Bacillus subtilis is applied to the plant or the environment in which the plant grows.

11. The method of claim 7, wherein Bacillus subtilis strain QST 713 is applied to the plant or the environment in which the plant grows.

12. Composition comprising fluopyram and/or Bacillus subtilis for controlling Fusarium wilt of plants in the family Musaceae.

13. Composition comprising fluopyram for controlling Fusarium wilt of plants in the family Musaceae.

14. A composition comprising Bacillus subtilis for use in controlling Fusarium wilt of plants in the family Musaceae.

15. Composition comprising Bacillus subtilis strain QST 713 for use in controlling Fusarium wilt of plants in the family Musaceae.