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CN109055808A - A kind of ormolu - Google Patents

A kind of ormolu Download PDF

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Publication number
CN109055808A
CN109055808A CN201811260896.1A CN201811260896A CN109055808A CN 109055808 A CN109055808 A CN 109055808A CN 201811260896 A CN201811260896 A CN 201811260896A CN 109055808 A CN109055808 A CN 109055808A
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CN
China
Prior art keywords
parts
ormolu
degrees celsius
raw material
smelting furnace
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811260896.1A
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Chinese (zh)
Inventor
项安华
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhejiang Xingyikang Copper Industry Co Ltd
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Zhejiang Xingyikang Copper Industry Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zhejiang Xingyikang Copper Industry Co Ltd filed Critical Zhejiang Xingyikang Copper Industry Co Ltd
Priority to CN201811260896.1A priority Critical patent/CN109055808A/en
Publication of CN109055808A publication Critical patent/CN109055808A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C9/00Alloys based on copper
    • C22C9/04Alloys based on copper with zinc as the next major constituent
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/02Making non-ferrous alloys by melting
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22FCHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/08Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of copper or alloys based thereon

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Mold Materials And Core Materials (AREA)

Abstract

The invention discloses a kind of ormolu, the formula of raw material by weight is as follows: 60-80 parts of copper, 30-40 parts of Zn-ef ficiency, 2-6 parts of manganese element, 2-6 parts of nickel element, 2-6 parts of magnesium elements, 0.5-0.9 parts of aluminium element, 0.5-0.9 parts of cobalt element, 0.1-0.5 parts of niobium element, 0.1-0.5 parts of element silicon.The present invention adds auxiliary material using copper and Zn-ef ficiency as essential element, reasonably matches between, can be under the premise of guaranteeing copper alloy intensity, and improves the corrosion resistance of copper alloy simultaneously, can satisfy requirement of the different field to it.

Description

A kind of ormolu
Technical field
The present invention relates to ormolu preparation technical field more particularly to a kind of ormolus.
Background technique
Ormolu is a kind of memorial alloy.Color golden yellow, as gold, is commonly called as brass.Existing China consumes every year Copper and copper alloy, in addition to account for about 58% for other than electrical field, there are also about 20% copper or copper alloy to be used for tubing Or the fields such as valve.This is primarily due to the performance torpescence of copper, the strong reason of antiseptic property, but in these areas because The liquid such as the water of contact and environment can still generate certain corrosiveness to this kind of equipment, we are often able to discovery at home Or tubing or the viridescent patina of valve knot in other places, this not only influences the beautiful use longevity for similarly reducing these materials Life.And in the prior art, traditional ormolu is no longer satisfied demand.For this purpose, we have proposed a kind of ormolus.
Summary of the invention
The invention proposes a kind of ormolus, to solve the problems mentioned in the above background technology.
The invention proposes a kind of ormolu, the formula of raw material by weight is as follows: 60-80 parts of copper, Zn-ef ficiency 30-40 parts, 2-6 parts of manganese element, 2-6 parts of nickel element, 2-6 parts of magnesium elements, 0.5-0.9 parts of aluminium element, 0.5-0.9 parts of cobalt element, 0.1-0.5 parts of niobium element, 0.1-0.5 parts of element silicon.
Preferably, the formula of raw material by weight is as follows: 65-75 parts of copper, 32-37 parts of Zn-ef ficiency, manganese element 3-5 Part, 3-5 parts of nickel element, 3-5 parts of magnesium elements, 0.6-0.8 parts of aluminium element, 0.6-0.8 parts of cobalt element, 0.2-0.4 parts of niobium element, silicon 0.2-0.4 parts of element.
Preferably, the formula of raw material by weight is as follows: 70 parts of copper, 35 parts of Zn-ef ficiency, 4 parts of manganese element, nickel element 4,4 parts of magnesium elements, 0.7 part of aluminium element, 0.7 part of cobalt element, 0.3 part of niobium element, 0.3 part of element silicon.
The present invention also provides a kind of preparation processes of ormolu, include the following steps:
S1, above-mentioned raw materials are chosen in proportion, and raw material is respectively placed in sonic cleaning device, and at 50-70 degrees Celsius It is cleared up in environment, so as to remove the dust on raw material surface and impurity;
S2, the material composition chosen in S1 is successively added in smelting furnace according to the height of fusing point, and Celsius in 1600-1800 Heating melting is carried out in the environment of degree, and during melting, smelting furnace inside is mixed, so as to will be former Material is uniformly mixed, and after being then filtered, mixed solution is made;
S3, alloy mold is chosen again, and mixed solution obtained in S2 is poured into mold, and teeming rate remains In 12-20ml/s, also disposal pouring is needed to form, after its casting complete, mold is placed in cooling oil, it is cooled down Molding;
S4, it after being cooled to room temperature, is drawn off, obtains alloy blank, and carry out hot place under conditions of 300-500 degrees Celsius Reason, and heat treatment time is 2-4min, needs during the treatment, in real time to rotate alloy blank, to guarantee at its Reason is uniform;
S5, finally, carry out corner angle processing and polishing, polishing to alloy blank surface, after the completion to get arriving ormolu.
Preferably, in S2, the temperature in smelting furnace is increased to 800-1000 degrees Celsius with the speed of 8-14 degrees Celsius/s Afterwards, 2-4min is waited, is again raised to required temperature, then so as to which the damage to smelting furnace is effectively reduced.
Preferably, the cooling oil is specially the mixing of one or more of machinery oil, quenching oil either silicone oil Object.
Preferably, alloy mold is before use, need to clear up its inside, then in 400-600 degrees Celsius of environment In preheated, and preheating time be 40-60s.
A kind of ormolu proposed by the invention, beneficial effect are: the present invention is based on copper and Zn-ef ficiency Element is wanted, and adds auxiliary material, is reasonably matched between, it can be under the premise of guaranteeing copper alloy intensity, and simultaneously The corrosion resistance for improving copper alloy, can satisfy requirement of the different field to it.
Specific embodiment
It is next combined with specific embodiments below that the present invention will be further described.
Embodiment 1
The invention proposes a kind of ormolu, the formula of raw material by weight is as follows: 60 parts of copper, 30 parts of Zn-ef ficiency, manganese 2 parts of element, 2 parts of nickel element, 2 parts of magnesium elements, 0.5 part of aluminium element, 0.5 part of cobalt element, 0.1 part of niobium element, 0.1 part of element silicon.
The present invention also provides a kind of preparation processes of ormolu, include the following steps:
S1, above-mentioned raw materials are chosen in proportion, and raw material is respectively placed in sonic cleaning device, and in 50 degrees Celsius of environment In cleared up, so as to by the dust on raw material surface and impurity removal;
S2, the material composition chosen in S1 is successively added in smelting furnace according to the height of fusing point, and at 1600 degrees Celsius Heating melting is carried out in environment, and during melting, smelting furnace inside is mixed, so as to mix raw material It closes uniformly, after being then filtered, mixed solution is made;
S3, alloy mold is chosen again, and mixed solution obtained in S2 is poured into mold, and teeming rate remains In 12-20ml/s, also disposal pouring is needed to form, after its casting complete, mold is placed in cooling oil, it is cooled down Molding;
S4, it after being cooled to room temperature, is drawn off, obtains alloy blank, and be heat-treated under conditions of 300 degrees Celsius, and Heat treatment time is 2min, needs during the treatment, in real time to rotate alloy blank, to guarantee that its processing is uniform;
S5, finally, carry out corner angle processing and polishing, polishing to alloy blank surface, after the completion to get arriving ormolu.
In S2, after the temperature in smelting furnace is increased to 800 degrees Celsius with the speed of 8-14 degrees Celsius/s, 2min is waited, Then it is again raised to required temperature, so as to which the damage to smelting furnace is effectively reduced.
The cooling oil is specially one or more of machinery oil, quenching oil either silicone oil mixture.
Then alloy mold is preheated before use, need to clear up its inside in 400 degrees Celsius of environment, And preheating time is 40s.
Embodiment 2
The invention proposes a kind of ormolu, the formula of raw material by weight is as follows: 65 parts of copper, 32 parts of Zn-ef ficiency, manganese 3 parts of element, 3 parts of nickel element, 3 parts of magnesium elements, 0.6 part of aluminium element, 0.6 part of cobalt element, 0.2 part of niobium element, 0.2 part of element silicon.
The present invention also provides a kind of preparation processes of ormolu, include the following steps:
S1, above-mentioned raw materials are chosen in proportion, and raw material is respectively placed in sonic cleaning device, and in 55 degrees Celsius of environment In cleared up, so as to by the dust on raw material surface and impurity removal;
S2, the material composition chosen in S1 is successively added in smelting furnace according to the height of fusing point, and at 1650 degrees Celsius Heating melting is carried out in environment, and during melting, smelting furnace inside is mixed, so as to mix raw material It closes uniformly, after being then filtered, mixed solution is made;
S3, alloy mold is chosen again, and mixed solution obtained in S2 is poured into mold, and teeming rate remains In 12-20ml/s, also disposal pouring is needed to form, after its casting complete, mold is placed in cooling oil, it is cooled down Molding;
S4, it after being cooled to room temperature, is drawn off, obtains alloy blank, and be heat-treated under conditions of 350 degrees Celsius, and Heat treatment time is 2.5min, needs during the treatment, in real time to rotate alloy blank, to guarantee that its processing is equal It is even;
S5, finally, carry out corner angle processing and polishing, polishing to alloy blank surface, after the completion to get arriving ormolu.
In S2, after the temperature in smelting furnace is increased to 850 degrees Celsius with the speed of 8-14 degrees Celsius/s, wait Then 2.5min is again raised to required temperature, so as to which the damage to smelting furnace is effectively reduced.
The cooling oil is specially one or more of machinery oil, quenching oil either silicone oil mixture.
Then alloy mold is preheated before use, need to clear up its inside in 450 degrees Celsius of environment, And preheating time is 45s.
Embodiment 3
The invention proposes a kind of ormolu, the formula of raw material by weight is as follows: 70 parts of copper, 35 parts of Zn-ef ficiency, manganese 4 parts of element, nickel element 4,4 parts of magnesium elements, 0.7 part of aluminium element, 0.7 part of cobalt element, 0.3 part of niobium element, 0.3 part of element silicon.
The present invention also provides a kind of preparation processes of ormolu, include the following steps:
S1, above-mentioned raw materials are chosen in proportion, and raw material is respectively placed in sonic cleaning device, and in 60 degrees Celsius of environment In cleared up, so as to by the dust on raw material surface and impurity removal;
S2, the material composition chosen in S1 is successively added in smelting furnace according to the height of fusing point, and at 1700 degrees Celsius Heating melting is carried out in environment, and during melting, smelting furnace inside is mixed, so as to mix raw material It closes uniformly, after being then filtered, mixed solution is made;
S3, alloy mold is chosen again, and mixed solution obtained in S2 is poured into mold, and teeming rate remains In 12-20ml/s, also disposal pouring is needed to form, after its casting complete, mold is placed in cooling oil, it is cooled down Molding;
S4, it after being cooled to room temperature, is drawn off, obtains alloy blank, and be heat-treated under conditions of 400 degrees Celsius, and Heat treatment time is 3min, needs during the treatment, in real time to rotate alloy blank, to guarantee that its processing is uniform;
S5, finally, carry out corner angle processing and polishing, polishing to alloy blank surface, after the completion to get arriving ormolu.
In S2, after the temperature in smelting furnace is increased to 900 degrees Celsius with the speed of 8-14 degrees Celsius/s, 3min is waited, Then it is again raised to required temperature, so as to which the damage to smelting furnace is effectively reduced.
The cooling oil is specially one or more of machinery oil, quenching oil either silicone oil mixture.
Then alloy mold is preheated before use, need to clear up its inside in 500 degrees Celsius of environment, And preheating time is 50s.
Embodiment 4
The invention proposes a kind of ormolu, the formula of raw material by weight is as follows: 75 parts of copper, 37 parts of Zn-ef ficiency, manganese 5 parts of element, 5 parts of nickel element, 5 parts of magnesium elements, 0.8 part of aluminium element, 0.8 part of cobalt element, 0.4 part of niobium element, 0.4 part of element silicon.
The present invention also provides a kind of preparation processes of ormolu, include the following steps:
S1, above-mentioned raw materials are chosen in proportion, and raw material is respectively placed in sonic cleaning device, and in 65 degrees Celsius of environment In cleared up, so as to by the dust on raw material surface and impurity removal;
S2, the material composition chosen in S1 is successively added in smelting furnace according to the height of fusing point, and at 1750 degrees Celsius Heating melting is carried out in environment, and during melting, smelting furnace inside is mixed, so as to mix raw material It closes uniformly, after being then filtered, mixed solution is made;
S3, alloy mold is chosen again, and mixed solution obtained in S2 is poured into mold, and teeming rate remains In 12-20ml/s, also disposal pouring is needed to form, after its casting complete, mold is placed in cooling oil, it is cooled down Molding;
S4, it after being cooled to room temperature, is drawn off, obtains alloy blank, and be heat-treated under conditions of 450 degrees Celsius, and Heat treatment time is 3.5min, needs during the treatment, in real time to rotate alloy blank, to guarantee that its processing is equal It is even;
S5, finally, carry out corner angle processing and polishing, polishing to alloy blank surface, after the completion to get arriving ormolu.
In S2, after the temperature in smelting furnace is increased to 950 degrees Celsius with the speed of 8-14 degrees Celsius/s, wait Then 3.5min is again raised to required temperature, so as to which the damage to smelting furnace is effectively reduced.
The cooling oil is specially one or more of machinery oil, quenching oil either silicone oil mixture.
Then alloy mold is preheated before use, need to clear up its inside in 550 degrees Celsius of environment, And preheating time is 55s.
Embodiment 5
The invention proposes a kind of ormolu, the formula of raw material by weight is as follows: 80 parts of copper, 40 parts of Zn-ef ficiency, manganese 6 parts of element, 6 parts of nickel element, 6 parts of magnesium elements, 0.9 part of aluminium element, 0.9 part of cobalt element, 0.5 part of niobium element, 0.5 part of element silicon.
The present invention also provides a kind of preparation processes of ormolu, include the following steps:
S1, above-mentioned raw materials are chosen in proportion, and raw material is respectively placed in sonic cleaning device, and in 70 degrees Celsius of environment In cleared up, so as to by the dust on raw material surface and impurity removal;
S2, the material composition chosen in S1 is successively added in smelting furnace according to the height of fusing point, and at 1800 degrees Celsius Heating melting is carried out in environment, and during melting, smelting furnace inside is mixed, so as to mix raw material It closes uniformly, after being then filtered, mixed solution is made;
S3, alloy mold is chosen again, and mixed solution obtained in S2 is poured into mold, and teeming rate remains In 12-20ml/s, also disposal pouring is needed to form, after its casting complete, mold is placed in cooling oil, it is cooled down Molding;
S4, it after being cooled to room temperature, is drawn off, obtains alloy blank, and be heat-treated under conditions of 500 degrees Celsius, and Heat treatment time is 4min, needs during the treatment, in real time to rotate alloy blank, to guarantee that its processing is uniform;
S5, finally, carry out corner angle processing and polishing, polishing to alloy blank surface, after the completion to get arriving ormolu.
In S2, after the temperature in smelting furnace is increased to 1000 degrees Celsius with the speed of 8-14 degrees Celsius/s, 4min is waited, Then it is again raised to required temperature, so as to which the damage to smelting furnace is effectively reduced.
The cooling oil is specially one or more of machinery oil, quenching oil either silicone oil mixture.
Then alloy mold is preheated before use, need to clear up its inside in 600 degrees Celsius of environment, And preheating time is 60s.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto, Anyone skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.

Claims (7)

1. a kind of ormolu, which is characterized in that the formula of its raw material by weight is as follows: 60-80 parts of copper, Zn-ef ficiency 30- 40 parts, 2-6 parts of manganese element, 2-6 parts of nickel element, 2-6 parts of magnesium elements, 0.5-0.9 parts of aluminium element, 0.5-0.9 parts of cobalt element, niobium member It is 0.1-0.5 parts plain, 0.1-0.5 parts of element silicon.
2. ormolu according to claim 1, which is characterized in that the formula of its raw material by weight is as follows: copper 65- 75 parts, 32-37 parts of Zn-ef ficiency, 3-5 parts of manganese element, 3-5 parts of nickel element, 3-5 parts of magnesium elements, 0.6-0.8 parts of aluminium element, cobalt element 0.6-0.8 parts, 0.2-0.4 parts of niobium element, 0.2-0.4 parts of element silicon.
3. ormolu according to claim 2, which is characterized in that the formula of its raw material by weight is as follows: copper 70 Part, 35 parts of Zn-ef ficiency, 4 parts of manganese element, nickel element 4,4 parts of magnesium elements, 0.7 part of aluminium element, 0.7 part of cobalt element, niobium element 0.3 Part, 0.3 part of element silicon.
4. a kind of preparation process of ormolu according to claim 1, which comprises the steps of:
S1, above-mentioned raw materials are chosen in proportion, and raw material is respectively placed in sonic cleaning device, and at 50-70 degrees Celsius It is cleared up in environment, so as to remove the dust on raw material surface and impurity;
S2, the material composition chosen in S1 is successively added in smelting furnace according to the height of fusing point, and Celsius in 1600-1800 Heating melting is carried out in the environment of degree, and during melting, smelting furnace inside is mixed, so as to will be former Material is uniformly mixed, and after being then filtered, mixed solution is made;
S3, alloy mold is chosen again, and mixed solution obtained in S2 is poured into mold, and teeming rate remains In 12-20ml/s, also disposal pouring is needed to form, after its casting complete, mold is placed in cooling oil, it is cooled down Molding;
S4, it after being cooled to room temperature, is drawn off, obtains alloy blank, and carry out hot place under conditions of 300-500 degrees Celsius Reason, and heat treatment time is 2-4min, needs during the treatment, in real time to rotate alloy blank, to guarantee at its Reason is uniform;
S5, finally, carry out corner angle processing and polishing, polishing to alloy blank surface, after the completion to get arriving ormolu.
5. the preparation process of ormolu according to claim 4, which is characterized in that the temperature in S2, in smelting furnace After being increased to 800-1000 degrees Celsius with the speed of 8-14 degrees Celsius/s, 2-4min is waited, required temperature is then again raised to Degree, so as to which the damage to smelting furnace is effectively reduced.
6. the preparation process of ormolu according to claim 4, which is characterized in that the cooling oil is specially machinery One or more of oil, quenching oil either silicone oil mixture.
7. the preparation process of ormolu according to claim 4, which is characterized in that alloy mold is before use, need pair It is cleared up inside it, is then preheated in 400-600 degrees Celsius of environment, and preheating time is 40-60s.
CN201811260896.1A 2018-10-26 2018-10-26 A kind of ormolu Pending CN109055808A (en)

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CN201811260896.1A CN109055808A (en) 2018-10-26 2018-10-26 A kind of ormolu

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Citations (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0872564A1 (en) * 1997-04-14 1998-10-21 Mitsubishi Shindoh Co., Ltd. Corrosion-resistant high-strength copper based alloy having excellent blankability
US6136104A (en) * 1998-07-08 2000-10-24 Kobe Steel, Ltd. Copper alloy for terminals and connectors and method for making same
JP3797882B2 (en) * 2001-03-09 2006-07-19 株式会社神戸製鋼所 Copper alloy sheet with excellent bending workability
JP3838521B1 (en) * 2005-12-27 2006-10-25 株式会社神戸製鋼所 Copper alloy having high strength and excellent bending workability and method for producing the same
WO2008041584A1 (en) * 2006-10-02 2008-04-10 Kabushiki Kaisha Kobe Seiko Sho Copper alloy plate for electrical and electronic components
WO2010082637A1 (en) * 2009-01-16 2010-07-22 株式会社神戸製鋼所 Display device
CN102828064A (en) * 2012-09-28 2012-12-19 合肥工业大学 Lead-free free-cutting brass alloy and preparation method thereof
JP5619391B2 (en) * 2009-08-12 2014-11-05 古河電気工業株式会社 Copper alloy material and method for producing the same
DE102013107011A1 (en) * 2013-07-03 2015-01-08 Thyssenkrupp Steel Europe Ag Process for coating long Cu products with a metallic protective layer and a Cu long product provided with a metallic protective layer
CN104630555A (en) * 2015-03-10 2015-05-20 济南大学 High-strength corrosion resisting brass material and preparation method thereof
CN106756280A (en) * 2017-01-13 2017-05-31 大楚神驰车轮股份有限公司 A kind of preparation technology of enhanced type wheel rim flange ring
US20170208680A1 (en) * 2016-01-15 2017-07-20 Jx Nippon Mining & Metals Corporation Copper Foil, Copper-Clad Laminate Board, Method For Producing Printed Wiring Board, Method For Producing Electronic Apparauts, Method For Producing Transmission Channel, And Method For Producing Antenna
CN107552712A (en) * 2017-10-17 2018-01-09 杭州立琪燃气设备有限公司 The production technology and production equipment of one Albatra metal valve forging
CN107723505A (en) * 2017-09-19 2018-02-23 浙江力博实业股份有限公司 A kind of wear-resistant copper alloy and preparation method thereof

Patent Citations (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0872564A1 (en) * 1997-04-14 1998-10-21 Mitsubishi Shindoh Co., Ltd. Corrosion-resistant high-strength copper based alloy having excellent blankability
US6136104A (en) * 1998-07-08 2000-10-24 Kobe Steel, Ltd. Copper alloy for terminals and connectors and method for making same
JP3797882B2 (en) * 2001-03-09 2006-07-19 株式会社神戸製鋼所 Copper alloy sheet with excellent bending workability
JP3838521B1 (en) * 2005-12-27 2006-10-25 株式会社神戸製鋼所 Copper alloy having high strength and excellent bending workability and method for producing the same
WO2008041584A1 (en) * 2006-10-02 2008-04-10 Kabushiki Kaisha Kobe Seiko Sho Copper alloy plate for electrical and electronic components
WO2010082637A1 (en) * 2009-01-16 2010-07-22 株式会社神戸製鋼所 Display device
JP5619391B2 (en) * 2009-08-12 2014-11-05 古河電気工業株式会社 Copper alloy material and method for producing the same
CN102828064A (en) * 2012-09-28 2012-12-19 合肥工业大学 Lead-free free-cutting brass alloy and preparation method thereof
DE102013107011A1 (en) * 2013-07-03 2015-01-08 Thyssenkrupp Steel Europe Ag Process for coating long Cu products with a metallic protective layer and a Cu long product provided with a metallic protective layer
CN104630555A (en) * 2015-03-10 2015-05-20 济南大学 High-strength corrosion resisting brass material and preparation method thereof
US20170208680A1 (en) * 2016-01-15 2017-07-20 Jx Nippon Mining & Metals Corporation Copper Foil, Copper-Clad Laminate Board, Method For Producing Printed Wiring Board, Method For Producing Electronic Apparauts, Method For Producing Transmission Channel, And Method For Producing Antenna
CN106756280A (en) * 2017-01-13 2017-05-31 大楚神驰车轮股份有限公司 A kind of preparation technology of enhanced type wheel rim flange ring
CN107723505A (en) * 2017-09-19 2018-02-23 浙江力博实业股份有限公司 A kind of wear-resistant copper alloy and preparation method thereof
CN107552712A (en) * 2017-10-17 2018-01-09 杭州立琪燃气设备有限公司 The production technology and production equipment of one Albatra metal valve forging

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Application publication date: 20181221

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