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CN109052667A - A kind of preparation method of two-in-one water purification agent - Google Patents

A kind of preparation method of two-in-one water purification agent Download PDF

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Publication number
CN109052667A
CN109052667A CN201811035727.8A CN201811035727A CN109052667A CN 109052667 A CN109052667 A CN 109052667A CN 201811035727 A CN201811035727 A CN 201811035727A CN 109052667 A CN109052667 A CN 109052667A
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China
Prior art keywords
mixture
water purification
preparation
purification agent
mass ratio
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Granted
Application number
CN201811035727.8A
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Chinese (zh)
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CN109052667B (en
Inventor
张润利
赵鑫
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Xinrui Guoyuan (Inner Mongolia) Technology Co.,Ltd.
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Henan Liyuan Purification Material Co Ltd
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Priority to CN201811035727.8A priority Critical patent/CN109052667B/en
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/34Biological treatment of water, waste water, or sewage characterised by the microorganisms used
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/34Biological treatment of water, waste water, or sewage characterised by the microorganisms used
    • C02F3/342Biological treatment of water, waste water, or sewage characterised by the microorganisms used characterised by the enzymes used
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2305/00Use of specific compounds during water treatment
    • C02F2305/06Nutrients for stimulating the growth of microorganisms

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  • Life Sciences & Earth Sciences (AREA)
  • Microbiology (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Water Treatment By Sorption (AREA)
  • Biological Treatment Of Waste Water (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)

Abstract

The invention discloses a kind of preparation methods of two-in-one water purification agent, the two-in-one water purification agent is composed of mixture A and mixture B two parts, mixture A and mixture B places storage respectively when storage, and when use is taken up in order of priority in sewage is added mixture A and mixture B;Wherein mixture A includes polyaluminium chloride, cellulose, slag, clay, flyash and modified mineral matter, and mixture B includes microorganism formulation, complex enzyme and auxiliary material, has achieved the effect that enhance water purification agent water purification performance.

Description

A kind of preparation method of two-in-one water purification agent
Technical field
The present invention relates to a kind of water purification agents, more specifically, it relates to a kind of preparation method of two-in-one water purification agent.
Background technique
In recent years, with industry, agricultural development, all kinds of organic chemical industries, pharmaceutical wastewater, agricultural effluent (containing a large amount of pesticides, Insecticide and herbicide) production and sanitary wastewater without processing up to standard, be just discharged, river and underground water caused It greatly endangers, the great decline of drinking water source quality.
Existing market water purification agent is many kinds of, and quality is very different, and the effect of low price is bad, the market of high treating effect Price is too high, can not popularize, therefore research and development are a at low cost, and environmental-friendly water water purification agent is very necessary.
Existing AB type water purification agent single effect is not much different with effect when being used alone, fitness difference or even mutual shadow It rings to generate and repels effect, which has to be solved.
Summary of the invention
In view of the deficiencies of the prior art, the present invention intends to provide a kind of preparation side of two-in-one water purification agent Method, tool is mutually promoted there are two types of component of mixture enhances the advantage of purifying property.
To achieve the above object, the present invention provides the following technical scheme that
A kind of preparation method of two-in-one water purification agent, the two-in-one water purification agent are combined by mixture A and mixture B two parts It forms, mixture A and mixture B places storage respectively when storage, and when use is taken up in order of priority in sewage is added mixture A and mixed Close object B;
Wherein mixture A includes polyaluminium chloride, cellulose, slag, clay, flyash and modified mineral matter, preparation side Method is as follows:
Cellulose, slag, clay, flyash are pressed to mass ratio preroast under 600-700 DEG C of nitrogen protection of 1:2:2:1 1-2h, then be warming up to 1000-1400 DEG C and roast 3-6h under nitrogen protection, cooled to room temperature obtains mixture C;
It is 100 μm hereinafter, being impregnated 12 hours with the concentrated hydrochloric acid of 5mol/L, then use that montmorillonite or bentonite in powder, which are broken to partial size, Solution of zinc sulfate impregnates 12 hours, is washed after the completion with the concentrated hydrochloric acid of 5mol/L, is washed with water and washs repeatedly until during pH is in Property, modified mineral matter can be obtained in drying;
The mixture C of above-mentioned preparation, modified mineral matter and polyaluminium chloride are mixed by the mass ratio of 1:1:1 up to mixture A, sealed storage are spare;
Mixture B includes microorganism formulation, complex enzyme and auxiliary material, wherein microorganism formulation include bacillus subtilis, Bacillus licheniformis, Bacillus cercus, rhizopus, photosynthetic bacteria, Nitrosomas and Nitromonas, Escherichia coli, aerobacteria, Proteus;Complex enzyme is made of protease, cellulase, amylase and lipase;Auxiliary material is active carbon, vermiculite and pottery The hybrid fine particles and tartaric acid of grain.Mixture B's the preparation method is as follows:
The hybrid fine particles of active carbon, vermiculite and haydite are added to mass fraction by mass ratio is preset as 5-10% Tartaric acid solution in stand that obtain mixed liquor D stand-by after mixing;
The one or more kinds of of strain in microorganism formulation are added in mixed liquor D by preset proportion, then will One of complex enzyme or it is a variety of by it is preset proportion be added in mixed liquor D, after mixing stand 12 hours to obtain the final product To mixture B.
It preferably, further include polyacrylamide in mixture A, the mass ratio of polyacrylamide and polyaluminium chloride is 1:1.
Preferably, the mass ratio of microorganism formulation, complex enzyme and mixed liquor D is 10:1:100.
Preferably, microorganism formulation is by bacillus subtilis, proteus, rhizopus and nitrococcus 1:1 in mass ratio: 1:5 composition.
Preferably, complex enzyme is made of protease, cellulase 1:1 in mass ratio.
Preferably, active carbon, vermiculite, haydite equal proportion are ground to partial size and are mixed into hybrid fine particles for 80 microns or less.
Preferably, the mass ratio of hybrid fine particles and tartaric acid is 1:3.
Preferably, mixture A and mixture B is individually enclosed in container according to the ratio that mass ratio is 1:1, then by two A container collocation encapsulation forms a two-in-one water purification agent into same packaging bag.
In conclusion the invention has the following advantages:
1, the present invention is suitable for the processing of various sewage, and simple and fast economical and effective is particularly suitable for each big, medium-sized and small enterprises's work The processing of industry sewage.
2, A mixture and B mixture of the present invention are two-in-one, between the two with the use of it is existing it is organic scavenging also have it is inorganic net Change, there are also microbial cleanings, and A can provide additional nutrition and growth when combined use for the microorganism in B mixture Space promotes the clean-up effect of microorganism in B mixture, and the microorganism decomposition in B mixture allows in A mixture again and uses in turn Certain cyclical effect is capable of forming in the micropore of inorganic adsorbent, that is to say, that the micropore in A mixture is constantly adsorbed Effect, while adsorbed substance can be decomposed again by the Institute of Micro-biology in B mixture, the two synergistic effect forms 1+1 >'s 2 Effect can reach good treatment effect when dosage maintains lower level.
Specific embodiment
A kind of preparation method of two-in-one water purification agent, the two-in-one water purification agent are combined by mixture A and mixture B two parts It forms, mixture A and mixture B places storage respectively when storage, and when use is taken up in order of priority in sewage is added mixture A and mixed Close object B;Wherein mixture A includes polyaluminium chloride, cellulose, slag, clay, flyash and modified mineral matter, preparation Method is as follows: cellulose, slag, clay, flyash are pressed to mass ratio prebake under 600-700 DEG C of nitrogen protection of 1:2:2:1 1-2h is burnt, then is warming up to 1000-1400 DEG C and roasts 3-6h under nitrogen protection, cooled to room temperature obtains mixture C;It will It is 100 μm hereinafter, being impregnated 12 hours with the concentrated hydrochloric acid of 5mo l/L that montmorillonite or bentonite in powder, which are broken to partial size, then molten with zinc sulfate Liquid impregnates 12 hours, is washed after the completion with the concentrated hydrochloric acid of 5mol/L, is washed with water and washs repeatedly until pH is in neutrality, drying is Modified mineral matter can be obtained;The mixture C of above-mentioned preparation, modified mineral matter and polyaluminium chloride are mixed by the mass ratio of 1:1:1 Up to mixture A, sealed storage is spare;Mixture B includes microorganism formulation, complex enzyme and auxiliary material, wherein microorganism formulation Including bacillus subtilis, bacillus licheniformis, Bacillus cercus, rhizopus, photosynthetic bacteria, Nitrosomas and Nitromonas, Escherichia coli, aerobacteria, proteus;Complex enzyme is made of protease, cellulase, amylase and lipase;Auxiliary material For the hybrid fine particles and tartaric acid of active carbon, vermiculite and haydite.Mixture B's the preparation method is as follows: by active carbon, vermiculite with And the hybrid fine particles of haydite are uniformly mixed in the tartaric acid solution of 5-10% by presetting mass ratio to be added to mass fraction It is stand-by to obtain mixed liquor D for standing afterwards;The one or more kinds of of strain in microorganism formulation are added to by preset proportion In mixed liquor D, then by one of complex enzyme or it is a variety of by it is preset proportion be added in mixed liquor D, after mixing It stands 12 hours and obtains mixture B.Mixture A's and mixture B is individually enclosed in container according to the ratio that mass ratio is 1:1 In, then two container collocation are encapsulated and form a two-in-one water purification agents into same packaging bag.
It in a preferred embodiment, further include polyacrylamide, the quality of polyacrylamide and polyaluminium chloride in mixture A Than for 1:1.
In a preferred embodiment, the mass ratio of microorganism formulation, complex enzyme and mixed liquor D is 10:1:100.
In a preferred embodiment, microorganism formulation is by bacillus subtilis, proteus, rhizopus and nitrococcus The composition of 1:1:1:5 in mass ratio.
In a preferred embodiment, complex enzyme is made of protease, cellulase 1:1 in mass ratio.
In a preferred embodiment, active carbon, vermiculite, haydite equal proportion are ground to partial size and are mixed into for 80 microns or less Hybrid fine particles.
In a preferred embodiment, the mass ratio of hybrid fine particles and tartaric acid is 1:3.

Claims (9)

1. a kind of preparation method of two-in-one water purification agent, it is characterised in that: the two-in-one water purification agent is by mixture A and mixture B Two parts are composed, and mixture A and mixture B places storage respectively when storage, and when use is taken up in order of priority addition in sewage Mixture A and mixture B;
Wherein mixture A includes polyaluminium chloride, cellulose, slag, clay, flyash and modified mineral matter, and preparation method is such as Under:
By cellulose, slag, clay, flyash by 1:2:2:1 mass ratio under 600-700 DEG C of nitrogen protection preroast 1- 2h, then be warming up to 1000-1400 DEG C and roast 3-6h under nitrogen protection, cooled to room temperature obtains mixture C;
It is 100 μm hereinafter, being impregnated 12 hours with the concentrated hydrochloric acid of 5mol/L, then use sulfuric acid that montmorillonite or bentonite in powder, which are broken to partial size, Zinc solution impregnate 12 hours, washed after the completion with the concentrated hydrochloric acid of 5mol/L, be washed with water wash repeatedly until pH be in neutrality, do It is dry that modified mineral matter can be obtained;
The mixture C of above-mentioned preparation, modified mineral matter and polyaluminium chloride are mixed by the mass ratio of 1:1:1 up to mixture A, envelope Dress storage is spare;
Mixture B includes microorganism formulation, complex enzyme and auxiliary material, and wherein microorganism formulation includes bacillus subtilis, lichens Bacillus, Bacillus cercus, rhizopus, photosynthetic bacteria, Nitrosomas and Nitromonas, Escherichia coli, aerobacteria, deformation Bacillus;Complex enzyme is made of protease, cellulase, amylase and lipase;Auxiliary material is active carbon, vermiculite and haydite Hybrid fine particles and tartaric acid, mixture B's the preparation method is as follows:
The hybrid fine particles of active carbon, vermiculite and haydite are added to the wine that mass fraction is 5-10% by mass ratio is preset Stand that obtain mixed liquor D stand-by in stone acid solution after mixing;
The one or more kinds of of strain in microorganism formulation are added in mixed liquor D by preset proportion, then will be compound One of enzyme or it is a variety of by it is preset proportion be added in mixed liquor D, after mixing stand 12 hours i.e. mixed Close object B.
2. the preparation method of two-in-one water purification agent as described in claim 1, it is characterised in that: further include poly- third in mixture A Acrylamide.
3. the preparation method of two-in-one water purification agent as claimed in claim 2, it is characterised in that: polyacrylamide and polyaluminium chloride Mass ratio be 1:1.
4. the preparation method of two-in-one water purification agent as described in claim 1, it is characterised in that: microorganism formulation, complex enzyme and The mass ratio of mixed liquor D is 10:1:100.
5. the preparation method of two-in-one water purification agent as claimed in claim 4, it is characterised in that: microorganism formulation is by withered grass gemma Bacillus, proteus, rhizopus and nitrococcus 1:1:1:5 in mass ratio composition.
6. the preparation method of two-in-one water purification agent as claimed in claim 5, it is characterised in that: complex enzyme is by protease, fiber Plain enzyme 1:1 in mass ratio composition.
7. the preparation method of two-in-one water purification agent as claimed in claim 6, it is characterised in that: active carbon, vermiculite, haydite press phase Equal proportion is ground to partial size and is mixed into hybrid fine particles for 80 microns or less.
8. the preparation method of two-in-one water purification agent as claimed in claim 7, it is characterised in that: the matter of hybrid fine particles and tartaric acid Amount is than being 1:3.
9. the preparation method of two-in-one water purification agent as described in claim 1, it is characterised in that: mixture A is pressed with mixture B's It is individually enclosed in container according to the ratio that mass ratio is 1:1, then two container collocation encapsulation is formed one into same packaging bag The two-in-one water purification agent of part.
CN201811035727.8A 2018-09-06 2018-09-06 Preparation method of two-in-one water purifying agent Active CN109052667B (en)

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Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS56122886A (en) * 1980-03-03 1981-09-26 Yasushi Tawara Bottom material purifying agent
JPS56141898A (en) * 1980-04-09 1981-11-05 Sogo Biseibutsu Kenkyusho:Kk Composition of water purifying agent
CN1085877A (en) * 1992-08-20 1994-04-27 生化工业株式会社 A kind of one group of addition agent that improves the method for waters bottom layer quality and water quality and be used for this method
CN1528681A (en) * 2003-09-28 2004-09-15 无锡中顺生物技术有限公司 Live bacterial microorganism water modifier equipped with activating culture medium and manufacturing process thereof
EP1533275A1 (en) * 2003-11-20 2005-05-25 S.A. Minera Catalano-Aragonesa Ecological composition for treating and purifying waste water
CN102659238A (en) * 2012-05-18 2012-09-12 山东化友化学有限公司 Multifunctional suspended carrier for sewage treatment and preparation method of multifunctional suspended carrier
CN104193011A (en) * 2014-08-27 2014-12-10 镇江华域环保设备制造有限公司 Dyeing wastewater purifying agent
CN106430337A (en) * 2016-08-27 2017-02-22 长沙理工大学 Industrial production wastewater treating agent with plants as raw materials and application method thereof
CN107235541A (en) * 2017-06-26 2017-10-10 杭州益泰环境科技有限公司 A kind of application recirculating water purification agent, its preparation method and application method
CN108017110A (en) * 2017-12-08 2018-05-11 合浦县水利局 Industrial wastewater treatment microbial inoculum and preparation method thereof

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS56122886A (en) * 1980-03-03 1981-09-26 Yasushi Tawara Bottom material purifying agent
JPS56141898A (en) * 1980-04-09 1981-11-05 Sogo Biseibutsu Kenkyusho:Kk Composition of water purifying agent
CN1085877A (en) * 1992-08-20 1994-04-27 生化工业株式会社 A kind of one group of addition agent that improves the method for waters bottom layer quality and water quality and be used for this method
CN1528681A (en) * 2003-09-28 2004-09-15 无锡中顺生物技术有限公司 Live bacterial microorganism water modifier equipped with activating culture medium and manufacturing process thereof
EP1533275A1 (en) * 2003-11-20 2005-05-25 S.A. Minera Catalano-Aragonesa Ecological composition for treating and purifying waste water
CN102659238A (en) * 2012-05-18 2012-09-12 山东化友化学有限公司 Multifunctional suspended carrier for sewage treatment and preparation method of multifunctional suspended carrier
CN104193011A (en) * 2014-08-27 2014-12-10 镇江华域环保设备制造有限公司 Dyeing wastewater purifying agent
CN106430337A (en) * 2016-08-27 2017-02-22 长沙理工大学 Industrial production wastewater treating agent with plants as raw materials and application method thereof
CN107235541A (en) * 2017-06-26 2017-10-10 杭州益泰环境科技有限公司 A kind of application recirculating water purification agent, its preparation method and application method
CN108017110A (en) * 2017-12-08 2018-05-11 合浦县水利局 Industrial wastewater treatment microbial inoculum and preparation method thereof

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Effective date of registration: 20230725

Address after: No. 7, Jianye Road, Zhitian Town, Gongyi City, Zhengzhou City, Henan Province 451252

Patentee after: Henan Xinlong Environmental Protection Technology Co.,Ltd.

Address before: 451275 Shecun Town, Gongyi City, Zhengzhou City, Henan Province

Patentee before: HENAN LIYUAN PURIFICATION MATERIALS CO.,LTD.

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Address after: 017000 Ulanmulun Town, Ejin Horo Banner, Ordos City, Inner Mongolia Autonomous Region, 46 kilometers west of the Ada Line

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Country or region after: China

Address before: No. 7, Jianye Road, Zhitian Town, Gongyi City, Zhengzhou City, Henan Province 451252

Patentee before: Henan Xinlong Environmental Protection Technology Co.,Ltd.

Country or region before: China