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CN109022939A - A kind of aluminium alloy and its application for domestic air conditioning microchannel aluminium flat conduit - Google Patents

A kind of aluminium alloy and its application for domestic air conditioning microchannel aluminium flat conduit Download PDF

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Publication number
CN109022939A
CN109022939A CN201811179521.2A CN201811179521A CN109022939A CN 109022939 A CN109022939 A CN 109022939A CN 201811179521 A CN201811179521 A CN 201811179521A CN 109022939 A CN109022939 A CN 109022939A
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Prior art keywords
aluminium
aluminium alloy
refining
minutes
microchannel
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Pending
Application number
CN201811179521.2A
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Chinese (zh)
Inventor
孙浩明
高贵军
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JIANGSU ASIA-PACIFIC ANSINDAR ALUMINIUM Co Ltd
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JIANGSU ASIA-PACIFIC ANSINDAR ALUMINIUM Co Ltd
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Priority to CN201811179521.2A priority Critical patent/CN109022939A/en
Publication of CN109022939A publication Critical patent/CN109022939A/en
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/02Making non-ferrous alloys by melting
    • C22C1/026Alloys based on aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/06Making non-ferrous alloys with the use of special agents for refining or deoxidising
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22FCHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/04Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Waste-Gas Treatment And Other Accessory Devices For Furnaces (AREA)

Abstract

The invention discloses a kind of aluminium alloys for domestic air conditioning microchannel aluminium flat conduit, the mass percent of element and each element in the aluminium alloy are as follows: Si 0.4-0.5%, Fe≤0.2%, Cu 0.45-0.5%, Mn 1.2-1.3%, Mg≤0.03%, Zn≤0.05%, Ti≤0.3%, Cr≤0.03%, surplus Al.Micro-channel flat aluminium alloy of the present invention has environmental protection outstanding, synergy, energy conservation, the advantages such as drop this.

Description

A kind of aluminium alloy and its application for domestic air conditioning microchannel aluminium flat conduit
Technical field
The present invention relates to the casting technology fields of aluminium alloy, are used for domestic air conditioning microchannel aluminium flat conduit more particularly, to one kind Aluminium alloy and preparation method thereof.
Background technique
Domestic air conditioning currently on the market generally uses aluminium flat conduit as heat exchanger, this aluminium flat conduit is formed by squeezing Porous seamless flat tube, it is required that the inner wall smooth of aluminium flat conduit, or there is only simple straight troughs to increase heat exchange area, therefore Aluminium flat conduit heat exchange area is small, fluid flowing turbulent flow poison is unobvious, heat transfer efficiency is relatively low;It is flat that the quality of aluminium alloy directly affects aluminium The performance of pipe, research and develop it is a kind of with good heat conductivity, suitable for domestic air conditioning aluminum alloy flat tube become those skilled in the art The emphasis of research.
Summary of the invention
In view of the above-mentioned problems existing in the prior art, the applicant provides one kind to be used for domestic air conditioning microchannel aluminium The aluminium alloy of flat tube and its application.Micro-channel flat aluminium alloy of the present invention has environmental protection outstanding, synergy, energy conservation, drops this etc. Advantage.
Technical scheme is as follows:
A kind of aluminium alloy for domestic air conditioning microchannel aluminium flat conduit, the quality hundred of element and each element in the aluminium alloy Divide ratio are as follows:
Si 0.4-0.5%, Fe≤0.2%, Cu 0.45-0.5%, Mn 1.2-1.3%, Mg≤0.03%, Zn≤ 0.05%, Ti≤0.3%, Cr≤0.03%, surplus Al.
A kind of domestic air conditioning microchannel aluminium flat conduit of the aluminium alloy preparation, the system of the domestic air conditioning microchannel aluminium flat conduit Preparation Method includes the following steps:
(1) hot prepurging first is carried out to the bottom of stove and side with rake, clears up the residual aluminium and impurity of furnace bottom and furnace wall, then It is to be melted in 99.75% end of the bridge aluminium ingot investment smelting furnace by purity, fusion temperature control range is at 700~740 DEG C, fusing Time 3~4 hours, aluminium ingot carried out first time refining after dissolving completely;
(2) 0.3Kg/T particle refining agent is added, opens 15 minute/time of electromagnetic agitation, adjustment pressure 0.08-0.12Mpa's Argon gas carries out refining 15~20 minutes for the first time to molten aluminum, then carries out the dross for pulling down surface;
(3) ready silicon, copper intermediate alloy are added after skimming;It impregnates 10 minutes;0.5Kg/T particle refining agent is added; It skims after carrying out second of refining 15~25 minutes, electromagnetic agitation 15 minutes;
(4) manganese addition agent after skimming adds 0.5Kg/T particle refining progress third time refining 15~20 minutes, electromagnetism stirs It mixes 15 minutes and then skims;Impurity, the gas in molten aluminum are thoroughly removed completely by refining three times;
(5) it is then allowed to stand 15~30 minutes, molten aluminum is heated to cast required temperature, prepares casting;
(6) convective tank, Rose Box, mould painting nitridation coating prevent molten aluminum and refractory material from contacting and cause subsequent folder after furnace It is miscellaneous, then natural gas used for refractory material is preheated;
(7) after mould, chute are fully warmed-up, input casting parameter is cast, and 745-765 DEG C of casting temperature, speed 125 ± 10mm, 3300 ± 200ml/min of water flow cast out required rods and bars of aluminium alloy;
(8) the rods and bars of aluminium alloy progress homogenize process cast out, 605 ± 10 DEG C of homogenizing temperature;Homogenizing time 12+ 0.2H;The type of cooling;Natural cooling;
(9) the good rods and bars of aluminium alloy of homogeneous carries out being cut into stub, is then packed in storage, when warehouse prevents 7 days natures Subsequent extruding is carried out after effect;
(10) rods and bars of aluminium alloy is warmed to 460-480 DEG C into heating furnace;Mold is heated to 400-440 DEG C;Needed for squeezing out The domestic air conditioning microchannel aluminium flat conduit wanted.
The present invention is beneficial to be had the technical effect that
Microchannel aluminium flat conduit of the present invention replaces traditional copper pipe, has many advantages, such as environmental protection, synergy, energy conservation, drops this;
Microchannel aluminium flat conduit of the present invention has light-weight, excellent thermally conductive, electric conductivity, anticorrosive and plastic deformation ability The advantages that.
Specific embodiment
Below with reference to embodiment, the present invention is specifically described.
Embodiment 1
A kind of aluminium alloy for domestic air conditioning microchannel aluminium flat conduit, the quality hundred of element and each element in the aluminium alloy Divide ratio are as follows:
Si 0.5%, Fe 0.15%, Cu 0.5%, Mn 1.3%, Mg≤0.03%, Zn≤0.05%, Ti 0.3%, Cr≤0.03%, surplus Al.
A kind of domestic air conditioning microchannel aluminium flat conduit of the aluminium alloy preparation, preparation method include the following steps:
(1) hot prepurging first is carried out to the bottom of stove and side with rake, clears up the residual aluminium and impurity of furnace bottom and furnace wall, then It is that 99.75% end of the bridge aluminium ingot puts into smelting furnace and melts by purity, fusion temperature control range is at 740 DEG C, fusing time 3 Hour, aluminium ingot carries out first time refining after dissolving completely;
(2) 0.3Kg/T particle refining agent is added, opens 15 minute/time of electromagnetic agitation, adjusts the argon gas of pressure 0.12Mpa Refining 15 minutes for the first time are carried out to molten aluminum, then carry out the dross for pulling down surface;
(3) ready silicon, copper intermediate alloy are added after skimming;It impregnates 10 minutes;0.5Kg/T particle refining agent is added; It skims after carrying out second of refining 15 minutes, electromagnetic agitation 15 minutes;
(4) manganese addition agent after skimming adds the refining of 0.5Kg/T particle and carries out third time refining 20 minutes, electromagnetic agitation 15 Then minute skims;Impurity, the gas in molten aluminum are thoroughly removed completely by refining three times;
(5) it is then allowed to stand 30 minutes, molten aluminum is heated to cast required temperature, prepares casting;
(6) convective tank, Rose Box, mould painting nitridation coating prevent molten aluminum and refractory material from contacting and cause subsequent folder after furnace It is miscellaneous, then natural gas used for refractory material is preheated;
(7) after mould, chute are fully warmed-up, input casting parameter is cast, and 745 DEG C of casting temperature, speed 125 ± 10mm, 3300 ± 200ml/min of water flow cast out required rods and bars of aluminium alloy;
(8) the rods and bars of aluminium alloy progress homogenize process cast out, 605 ± 10 DEG C of homogenizing temperature;Homogenizing time 12+ 0.2H;The type of cooling;Natural cooling;
(9) the good rods and bars of aluminium alloy of homogeneous carries out being cut into stub, is then packed in storage, when warehouse prevents 7 days natures Subsequent extruding is carried out after effect;
(10) rods and bars of aluminium alloy is warmed to 460 DEG C into heating furnace;Mold is heated to 400 DEG C;Squeeze out required household Air-conditioning microchannel aluminium flat conduit.
Embodiment 2
A kind of aluminium alloy for domestic air conditioning microchannel aluminium flat conduit, the quality hundred of element and each element in the aluminium alloy Divide ratio are as follows:
Si 0.45%, Fe 0.1%, Cu 0.45%, Mn 1.2%, Mg≤0.03%, Zn≤0.05%, Ti 0.2%, Cr≤0.03%, surplus Al.
A kind of domestic air conditioning microchannel aluminium flat conduit of the aluminium alloy preparation, preparation method include the following steps:
(1) hot prepurging first is carried out to the bottom of stove and side with rake, clears up the residual aluminium and impurity of furnace bottom and furnace wall, then It is that 99.75% end of the bridge aluminium ingot puts into smelting furnace and melts by purity, fusion temperature control range is at 700 DEG C, fusing time 4 Hour, aluminium ingot carries out first time refining after dissolving completely;
(2) 0.3Kg/T particle refining agent is added, opens 15 minute/time of electromagnetic agitation, adjusts the argon gas of pressure 0.08Mpa Refining 20 minutes for the first time are carried out to molten aluminum, then carry out the dross for pulling down surface;
(3) ready silicon, copper intermediate alloy are added after skimming;It impregnates 10 minutes;0.5Kg/T particle refining agent is added; It skims after carrying out second of refining 25 minutes, electromagnetic agitation 15 minutes;
(4) manganese addition agent after skimming adds the refining of 0.5Kg/T particle and carries out third time refining 15 minutes, electromagnetic agitation 15 Then minute skims;Impurity, the gas in molten aluminum are thoroughly removed completely by refining three times;
(5) it is then allowed to stand 20 minutes, molten aluminum is heated to cast required temperature, prepares casting;
(6) convective tank, Rose Box, mould painting nitridation coating prevent molten aluminum and refractory material from contacting and cause subsequent folder after furnace It is miscellaneous, then natural gas used for refractory material is preheated;
(7) after mould, chute are fully warmed-up, input casting parameter is cast, and 755 DEG C of casting temperature, speed 125 ± 10mm, 3300 ± 200ml/min of water flow cast out required rods and bars of aluminium alloy;
(8) the rods and bars of aluminium alloy progress homogenize process cast out, 605 ± 10 DEG C of homogenizing temperature;Homogenizing time 12+ 0.2H;The type of cooling;Natural cooling;
(9) the good rods and bars of aluminium alloy of homogeneous carries out being cut into stub, is then packed in storage, when warehouse prevents 7 days natures Subsequent extruding is carried out after effect;
(10) rods and bars of aluminium alloy is warmed to 480 DEG C into heating furnace;Mold is heated to 440 DEG C;Squeeze out required household Air-conditioning microchannel aluminium flat conduit.
Embodiment 3
A kind of aluminium alloy for domestic air conditioning microchannel aluminium flat conduit, the quality hundred of element and each element in the aluminium alloy Divide ratio are as follows:
Si 0.5%, Fe 0.2%, Cu 0.45%, Mn 1.25%, Mg≤0.03%, Zn≤0.05%, Ti 0.25%, Cr≤0.03%, surplus Al.
A kind of domestic air conditioning microchannel aluminium flat conduit of the aluminium alloy preparation, preparation method include the following steps:
(1) hot prepurging first is carried out to the bottom of stove and side with rake, clears up the residual aluminium and impurity of furnace bottom and furnace wall, then It is that 99.75% end of the bridge aluminium ingot puts into smelting furnace and melts by purity, fusion temperature control range is at 720 DEG C, fusing time 4 Hour, aluminium ingot carries out first time refining after dissolving completely;
(2) 0.3Kg/T particle refining agent is added, opens 15 minute/time of electromagnetic agitation, adjusts the argon gas of pressure 0.10Mpa Refining 18 minutes for the first time are carried out to molten aluminum, then carry out the dross for pulling down surface;
(3) ready silicon, copper intermediate alloy are added after skimming;It impregnates 10 minutes;0.5Kg/T particle refining agent is added; It skims after carrying out second of refining 20 minutes, electromagnetic agitation 15 minutes;
(4) manganese addition agent after skimming adds the refining of 0.5Kg/T particle and carries out third time refining 20 minutes, electromagnetic agitation 15 Then minute skims;Impurity, the gas in molten aluminum are thoroughly removed completely by refining three times;
(5) it is then allowed to stand 15 minutes, molten aluminum is heated to cast required temperature, prepares casting;
(6) convective tank, Rose Box, mould painting nitridation coating prevent molten aluminum and refractory material from contacting and cause subsequent folder after furnace It is miscellaneous, then natural gas used for refractory material is preheated;
(7) after mould, chute are fully warmed-up, input casting parameter is cast, and 765 DEG C of casting temperature, speed 125 ± 10mm, 3300 ± 200ml/min of water flow cast out required rods and bars of aluminium alloy;
(8) the rods and bars of aluminium alloy progress homogenize process cast out, 605 ± 10 DEG C of homogenizing temperature;Homogenizing time 12+ 0.2H;The type of cooling;Natural cooling;
(9) the good rods and bars of aluminium alloy of homogeneous carries out being cut into stub, is then packed in storage, when warehouse prevents 7 days natures Subsequent extruding is carried out after effect;
(10) rods and bars of aluminium alloy is warmed to 470 DEG C into heating furnace;Mold is heated to 420 DEG C;Squeeze out required household Air-conditioning microchannel aluminium flat conduit.
The resulting aluminium flat conduit of Examples 1 to 3 is tested for the property, test result is as shown in table 1:
Table 1

Claims (2)

1. a kind of aluminium alloy for domestic air conditioning microchannel aluminium flat conduit, which is characterized in that element and each member in the aluminium alloy The mass percent of element are as follows:
Si 0.4-0.5%, Fe≤0.2%, Cu 0.45-0.5%, Mn 1.2-1.3%, Mg≤0.03%, Zn≤0.05%, Ti≤0.3%, Cr≤0.03%, surplus Al.
2. a kind of domestic air conditioning microchannel aluminium flat conduit of the preparation of aluminium alloy described in claim 1, which is characterized in that the household is empty The preparation method of microchannel aluminium flat conduit is adjusted to include the following steps:
(1) hot prepurging first is carried out to the bottom of stove and side with rake, clears up the residual aluminium and impurity of furnace bottom and furnace wall, then will be pure Degree is that 99.75% end of the bridge aluminium ingot puts into smelting furnace and melted, and fusion temperature control range is at 700~740 DEG C, fusing time 3~4 hours, aluminium ingot carried out first time refining after dissolving completely;
(2) 0.3Kg/T particle refining agent is added, opens 15 minute/time of electromagnetic agitation, adjusts the argon gas of pressure 0.08-0.12Mpa Refining 15~20 minutes for the first time are carried out to molten aluminum, then carry out the dross for pulling down surface;
(3) ready silicon, copper intermediate alloy are added after skimming;It impregnates 10 minutes;0.5Kg/T particle refining agent is added;It carries out Second of refining is skimmed after 15~25 minutes, electromagnetic agitation 15 minutes;
(4) manganese addition agent after skimming adds the refining of 0.5Kg/T particle and carries out third time refining 15~20 minutes, electromagnetic agitation 15 Then minute skims;Impurity, the gas in molten aluminum are thoroughly removed completely by refining three times;
(5) it is then allowed to stand 15~30 minutes, molten aluminum is heated to cast required temperature, prepares casting;
(6) convective tank after furnace, Rose Box, mould apply nitridation coating prevent molten aluminum and refractory material contact cause it is subsequent be mingled with, so Natural gas used for refractory material is preheated afterwards;
(7) after mould, chute are fully warmed-up, input casting parameter is cast, and 745-765 DEG C of casting temperature, speed 125 ± 10mm, 3300 ± 200ml/min of water flow cast out required rods and bars of aluminium alloy;
(8) the rods and bars of aluminium alloy progress homogenize process cast out, 605 ± 10 DEG C of homogenizing temperature;Homogenizing time 12+0.2H; The type of cooling;Natural cooling;
(9) the good rods and bars of aluminium alloy of homogeneous carries out being cut into stub, is then packed in storage, after warehouse prevents 7 days natrual ageing Carry out subsequent extruding;
(10) rods and bars of aluminium alloy is warmed to 460-480 DEG C into heating furnace;Mold is heated to 400-440 DEG C;Required for squeezing out Domestic air conditioning microchannel aluminium flat conduit.
CN201811179521.2A 2018-10-10 2018-10-10 A kind of aluminium alloy and its application for domestic air conditioning microchannel aluminium flat conduit Pending CN109022939A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112221913A (en) * 2020-10-20 2021-01-15 东莞市华昌铝业有限公司 High-corrosion-resistance aluminum profile and processing technology thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH11172388A (en) * 1997-12-08 1999-06-29 Furukawa Electric Co Ltd:The Aluminum alloy extruded pipe material for air conditioner piping and its production
US20010007720A1 (en) * 1997-02-10 2001-07-12 Noboru Soga Aluminum alloy brazing sheet
CN1938439A (en) * 2004-03-31 2007-03-28 海德鲁铝业德国有限责任公司 Heat-resistant aluminium alloy for heat exchangers
JP2007277706A (en) * 2006-03-13 2007-10-25 Sumitomo Light Metal Ind Ltd Aluminum alloy clad material for heat exchanger having excellent strength and brazability
CN102615139A (en) * 2012-04-01 2012-08-01 江苏格林威尔金属材料科技有限公司 Continuous extrusion process of circular aluminum alloy pipe
CN107619970A (en) * 2017-10-26 2018-01-23 江苏亚太安信达铝业有限公司 Aluminium alloy for domestic air conditioning composite pipe and preparation method thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20010007720A1 (en) * 1997-02-10 2001-07-12 Noboru Soga Aluminum alloy brazing sheet
JPH11172388A (en) * 1997-12-08 1999-06-29 Furukawa Electric Co Ltd:The Aluminum alloy extruded pipe material for air conditioner piping and its production
CN1938439A (en) * 2004-03-31 2007-03-28 海德鲁铝业德国有限责任公司 Heat-resistant aluminium alloy for heat exchangers
JP2007277706A (en) * 2006-03-13 2007-10-25 Sumitomo Light Metal Ind Ltd Aluminum alloy clad material for heat exchanger having excellent strength and brazability
CN102615139A (en) * 2012-04-01 2012-08-01 江苏格林威尔金属材料科技有限公司 Continuous extrusion process of circular aluminum alloy pipe
CN107619970A (en) * 2017-10-26 2018-01-23 江苏亚太安信达铝业有限公司 Aluminium alloy for domestic air conditioning composite pipe and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112221913A (en) * 2020-10-20 2021-01-15 东莞市华昌铝业有限公司 High-corrosion-resistance aluminum profile and processing technology thereof

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Application publication date: 20181218