CN109019733A - Single packed tower humidification heat pump solution concentration systems and method - Google Patents
Single packed tower humidification heat pump solution concentration systems and method Download PDFInfo
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Abstract
一种单填料塔加湿热泵溶液浓缩系统及方法,属于节能领域。该系统包括冷凝器(2)、海水泵(3)、填料塔(7)、风机(9)、换热器(10)、气液分离器(11)、淡水罐(13)、循环水泵(14)、蒸发器(15)、压缩机(17)、节流阀(19)。该系统利用冷凝器(2)放出的热量,对总海水(1)进行加热;利用蒸发器(15)的冷量对高温空气(6)进行冷凝,这提高了系统循环热效率;另外空气在填料塔(7)和换热器(10)中分别发生加湿和除湿过程,此过程具有规模灵活、设备投资和操作成本适中、可利用低位热能、技术水平要求低、装置利于小型化等优点,所以该系统较常规系统更为节能。
A single-packed tower humidification heat pump solution concentration system and method belong to the field of energy saving. The system includes condenser (2), seawater pump (3), packed tower (7), fan (9), heat exchanger (10), gas-liquid separator (11), fresh water tank (13), circulating water pump ( 14), evaporator (15), compressor (17), throttle valve (19). The system uses the heat released by the condenser (2) to heat the total seawater (1); uses the cooling capacity of the evaporator (15) to condense the high-temperature air (6), which improves the thermal efficiency of the system cycle; The humidification and dehumidification processes occur in the tower (7) and the heat exchanger (10), respectively. This process has the advantages of flexible scale, moderate equipment investment and operating costs, low-level heat energy can be used, low technical level requirements, and equipment miniaturization, etc., so The system is more energy efficient than conventional systems.
Description
技术领域technical field
本发明涉及单填料塔加湿热泵溶液浓缩系统及方法,属于节能领域。The invention relates to a single-packed tower humidification heat pump solution concentration system and method, and belongs to the field of energy conservation.
技术背景technical background
随着淡水资源的短缺,海水淡化技术日益受到各个国家的重视,目前许多国家已经将海水淡化作为解决淡水资源短缺问题的关键技术。With the shortage of fresh water resources, seawater desalination technology has been paid more and more attention by various countries. At present, many countries have taken seawater desalination as a key technology to solve the problem of fresh water shortage.
海水淡化是将海水中的盐分和水分分离的过程,最终得到淡水和浓缩盐水,主要的传统海水淡化方法有反渗透法、蒸馏法等。其中反渗透法指的是在膜的原水一侧施加比溶液渗透压高的外界压力,原水透过半透膜时,只允许水透过,其他物质不能透过而被截留在膜表面的过程。但是在反渗透法中,海水的预处理要求严格,且原水利用率只有75-80%,另外需要高压设备,膜要定期清洗,清洗费用较高。蒸馏法常被用于是分离、纯化液态混合物,但是传统的蒸馏法存在耗能高,经济效益低且装置结构复杂,操作运行困难,换热效率低等问题。Seawater desalination is the process of separating the salt and water in seawater, and finally obtain fresh water and concentrated brine. The main traditional seawater desalination methods include reverse osmosis and distillation. Among them, the reverse osmosis method refers to the process of applying an external pressure higher than the osmotic pressure of the solution on the raw water side of the membrane. When the raw water passes through the semi-permeable membrane, only water is allowed to pass through, and other substances cannot pass through and are trapped on the surface of the membrane. However, in the reverse osmosis method, seawater pretreatment is strictly required, and the utilization rate of raw water is only 75-80%. In addition, high-pressure equipment is required, and the membrane needs to be cleaned regularly, and the cleaning cost is relatively high. Distillation is often used to separate and purify liquid mixtures, but traditional distillation has problems such as high energy consumption, low economic benefits, complex device structure, difficult operation, and low heat exchange efficiency.
加湿除湿海水淡化方法是目前研究的热点,其原理是将海水蒸发出水蒸气,然后冷凝出纯净的淡水,且规模灵活、设备投资和操作成本适中、可利用低位热能、技术水平要求低、装置利于小型化,该技术被认为是海水淡化中最具前景的方法。Humidification and dehumidification seawater desalination method is currently a research hotspot. Its principle is to evaporate seawater into water vapor, and then condense pure fresh water. It has flexible scale, moderate equipment investment and operation cost, low heat energy can be used, low technical level requirements, and the device is convenient. Miniaturized, this technology is considered to be the most promising method in seawater desalination.
热泵系统由于其COP较高,效率高等优点,在工业中得到了广泛的应用。且系统环保安全,没有燃烧过程,避免了排烟污染。Heat pump systems have been widely used in industry due to their advantages such as high COP and high efficiency. And the system is environmentally friendly and safe, there is no combustion process, and smoke pollution is avoided.
发明内容Contents of the invention
本发明的目的在于把热泵系统和加湿除湿淡化方法整合起来,且提出一种利用空气在不同温度下载湿能力的差异,利用填料塔进行直接接触式传热传质,降低能耗的单填料塔加湿热泵溶液浓缩系统及方法。The purpose of the present invention is to integrate the heat pump system and the humidification, dehumidification and desalination method, and propose a single-packed tower that utilizes the difference in humidification capacity of the air at different temperatures, uses the packed tower for direct contact heat and mass transfer, and reduces energy consumption Humidification heat pump solution concentration system and method.
该系统包括冷凝器、海水泵、填料塔、风机、换热器、气液分离器、淡水罐、循环水泵、蒸发器、压缩机、节流阀。冷凝器包括热侧进口、热侧出口、冷侧进口和冷侧出口;蒸发器包括热侧进口、热侧出口、冷侧进口和冷侧出口;填料塔包括总海水进口、浓海水出口、低温空气进口和高温空气出口;换热器包括热侧进口、热侧出口、冷侧进口、冷侧出口;气液分离器包括上进口、下出口、气体出口;冷凝器热侧出口经过节流阀与蒸发器冷侧进口相连,蒸发器冷侧出口与压缩机进口相连,压缩机出口与冷凝器热侧进口相连,如此往复循环;冷凝器冷侧出口与填料塔的总海水进口相连,填料塔浓海水出口和新海水混合后相连与海水泵进口,海水泵出口与冷凝器的冷侧进口相连,填料塔高温空气出口与换热器的热侧进口相连,换热器热侧出口与气液分离器的上进口相连,气液分离器的气体出口通过气泵与填料塔低温空气进口相连,其液体出口与淡水罐相连;换热器冷侧出口通过循环水泵与蒸发器热侧进口相连,蒸发器热侧出口与换热器冷侧进口相连;The system includes condenser, seawater pump, packed tower, fan, heat exchanger, gas-liquid separator, fresh water tank, circulating water pump, evaporator, compressor, and throttle valve. Condenser includes hot side inlet, hot side outlet, cold side inlet and cold side outlet; evaporator includes hot side inlet, hot side outlet, cold side inlet and cold side outlet; packed tower includes total seawater inlet, concentrated seawater outlet, low temperature Air inlet and high temperature air outlet; heat exchanger includes hot side inlet, hot side outlet, cold side inlet, cold side outlet; gas-liquid separator includes upper inlet, lower outlet, gas outlet; condenser hot side outlet passes throttling valve It is connected to the inlet of the cold side of the evaporator, the outlet of the cold side of the evaporator is connected to the inlet of the compressor, and the outlet of the compressor is connected to the inlet of the hot side of the condenser. The concentrated seawater outlet is mixed with new seawater and connected to the inlet of the seawater pump, the outlet of the seawater pump is connected to the cold side inlet of the condenser, the high temperature air outlet of the packed tower is connected to the hot side inlet of the heat exchanger, and the hot side outlet of the heat exchanger is connected to the gas-liquid The upper inlet of the separator is connected, the gas outlet of the gas-liquid separator is connected with the low-temperature air inlet of the packed tower through the air pump, and its liquid outlet is connected with the fresh water tank; the cold side outlet of the heat exchanger is connected with the hot side inlet of the evaporator through a circulating water pump, and the evaporation The outlet on the hot side of the heat exchanger is connected to the inlet on the cold side of the heat exchanger;
所述的单填料塔加湿热泵溶液浓缩系统及方法,其特征在于包括以下过程:制冷剂通过压缩机加压后,从冷凝器热侧进口进入其热端,将热量传给其冷端的海水,降温后的制冷剂再通入节流阀节流,后经过蒸发器冷侧进口进入其冷端,与其热端的冷水进行热交换,冷却热端的冷水,后循环进入压缩机;新海水和浓海水混合成总海水,总海水经过海水泵加压后,从冷凝器冷侧进口进入其冷端,与其热端的制冷剂进行热交换,总海水吸热升温,后通过填料塔的总海水进口进入填料塔;低温空气从低温空气进口进入填料塔,低温空气与总海水进行混合,由于低温空气的吸湿性,对总海水进行吸湿反应,总海水被浓缩,得到浓海水,浓海水通入海水泵被循环利用;当海水量不足时,通入新海水,保证系统正常运行;低温空气变成含有水蒸气的高温空气,高温空气从填料塔的高温空气出口流出,从换热器的热侧进口进入其热端,与其冷端的冷水进行热交换,高温空气被降温,冷凝出水分,空气和液态水混合物再经过气液分离器上进口进入气液分离器,被分离成两部分,分别是低温空气和淡水,低温空气从气液分离器的气体出口流出,经过风机加压后,重新从填料塔低温空气进口进入填料塔,往复循环;淡水从气液分离器的下出口流出,进入淡水罐储存; 冷水从蒸发器的热侧进口进入其热侧,与其冷侧的制冷剂进行热交换,吸收冷侧的冷量,温度降低,后从其热侧出口流出,经过换热器的冷侧进口进入其冷端,将冷量传递给其热侧的高温空气,使其冷凝出淡水,然后冷水从其冷侧出口流出,进入循环水泵,如此往复循环;The single-packed tower humidification heat pump solution concentration system and method is characterized in that it includes the following process: after the refrigerant is pressurized by the compressor, it enters the hot end from the hot side inlet of the condenser, and transfers heat to the seawater at the cold end, The cooled refrigerant flows into the throttling valve for throttling, and then enters the cold end through the cold side inlet of the evaporator, exchanges heat with the cold water at the hot end, cools the cold water at the hot end, and then circulates into the compressor; fresh seawater and concentrated seawater Mixed into the total seawater, the total seawater is pressurized by the seawater pump, enters the cold end from the cold side inlet of the condenser, and exchanges heat with the refrigerant at the hot end, the total seawater absorbs heat and heats up, and then enters the packing through the total seawater inlet of the packed tower Tower; low-temperature air enters the packed tower from the low-temperature air inlet, and the low-temperature air is mixed with the total seawater. Due to the hygroscopicity of the low-temperature air, the total seawater undergoes a hygroscopic reaction, and the total seawater is concentrated to obtain concentrated seawater. The concentrated seawater is passed into the seawater pump to be circulated Utilization; when the amount of seawater is insufficient, new seawater is introduced to ensure the normal operation of the system; the low-temperature air becomes high-temperature air containing water vapor, and the high-temperature air flows out from the high-temperature air outlet of the packed tower, and enters it from the hot side inlet of the heat exchanger The hot end exchanges heat with the cold water at the cold end, the high-temperature air is cooled, and moisture is condensed, and the mixture of air and liquid water enters the gas-liquid separator through the upper inlet of the gas-liquid separator, and is separated into two parts, namely, low-temperature air and Fresh water and low-temperature air flow out from the gas outlet of the gas-liquid separator. After being pressurized by the fan, they enter the packed tower from the low-temperature air inlet of the packed tower again, and reciprocate; fresh water flows out from the lower outlet of the gas-liquid separator and enters the fresh water tank for storage; The cold water enters the hot side from the hot side inlet of the evaporator, exchanges heat with the refrigerant on the cold side, absorbs the cooling capacity of the cold side, lowers the temperature, then flows out from the hot side outlet, and enters through the cold side inlet of the heat exchanger Its cold end transfers cold energy to the high-temperature air on its hot side, making it condense into fresh water, and then the cold water flows out from the outlet of its cold side and enters the circulating water pump, so that the cycle reciprocates;
对于该系统,海水利用冷凝器放出的热量吸热升温,冷水利用蒸发器的冷量,冷凝换热器中的高温空气,进而得到淡水,这提高了总的系统的热效率;另外,对于空气,其在填料塔中吸收海水的水分,发生吸湿反应,在换热器又通过冷凝将得到淡水,发生除湿反应,其过程可以得到淡水,且系统规模灵活、设备投资和操作成本适中、且装置小型化,节约成本。For this system, the seawater uses the heat released by the condenser to absorb heat and heat up, and the cold water uses the cooling capacity of the evaporator to condense the high-temperature air in the heat exchanger to obtain fresh water, which improves the thermal efficiency of the overall system; in addition, for air, It absorbs the moisture of seawater in the packed tower and undergoes a hygroscopic reaction, and then condenses in the heat exchanger to obtain fresh water and undergoes a dehumidification reaction. The process can obtain fresh water, and the system scale is flexible, the equipment investment and operating costs are moderate, and the device is small , saving costs.
附图说明Description of drawings
图1单填料塔加湿热泵溶液浓缩系统及方法。Fig. 1 The single-packed tower humidification heat pump solution concentration system and method.
图中标号名称:1、总海水,2、冷凝器,3、海水泵,4、新海水,5、浓海水,6、高温空气,7、填料塔,8、低温空气,9、风机,10、换热器,11、气液分离器,12、淡水,13、淡水罐,14、循环水泵,15、蒸发器,16、冷水,17、压缩机,18、制冷剂,19、节流阀。Label names in the figure: 1. Total seawater, 2. Condenser, 3. Seawater pump, 4. New seawater, 5. Concentrated seawater, 6. High temperature air, 7. Packed tower, 8. Low temperature air, 9. Fan, 10 , heat exchanger, 11, gas-liquid separator, 12, fresh water, 13, fresh water tank, 14, circulating water pump, 15, evaporator, 16, cold water, 17, compressor, 18, refrigerant, 19, throttle valve .
具体实施方法Specific implementation method
下面参照附图1说明该单填料塔加湿热泵溶液浓缩系统的运行过程:The operation process of the single-packed tower humidification heat pump solution concentration system is described below with reference to accompanying drawing 1:
启动循环水泵14,冷水16进入蒸发器15的热侧,与其冷侧的制冷剂18进行热交换,吸收冷侧的冷量,后从其热侧出口流出,进入换热器10的冷端,将冷量传递给热侧的高温空气6,使其冷凝出淡水12,然后从其冷侧出口流出,进入循环水泵14,如此往复循环。Start the circulating water pump 14, the cold water 16 enters the hot side of the evaporator 15, exchanges heat with the refrigerant 18 on the cold side, absorbs the cooling capacity of the cold side, then flows out from the outlet of the hot side, and enters the cold end of the heat exchanger 10, The cold energy is transferred to the high-temperature air 6 on the hot side, making it condense into fresh water 12, which then flows out from the outlet on the cold side and enters the circulating water pump 14, so that the cycle reciprocates.
启动海水泵3,新海水4和浓海水5混合成总海水1,总海水1经过海水泵3加压,进入冷凝器2的冷端,与其热端的制冷剂18进行热交换,总海水1吸热升温,后进入填料塔7,与低温空气8进行混合,由于低温空气8的吸湿性,水分被吸收,总海水1被浓缩,得到浓海水5,浓海水5通入海水泵3,循环利用;当海水量不足时,通入新海水4,保证系统正常运行。Start the seawater pump 3, the new seawater 4 and the concentrated seawater 5 are mixed into the total seawater 1, the total seawater 1 is pressurized by the seawater pump 3, enters the cold end of the condenser 2, and exchanges heat with the refrigerant 18 at the hot end, the total seawater 1 absorbs Heat up, then enter the packed tower 7, and mix with the low-temperature air 8. Due to the hygroscopicity of the low-temperature air 8, the water is absorbed, and the total seawater 1 is concentrated to obtain concentrated seawater 5, which is passed into the seawater pump 3 for recycling; When the amount of seawater is insufficient, new seawater 4 is introduced to ensure the normal operation of the system.
启动风机9,如上所属,低温空气8进入填料塔7,与总海水1发生脱湿反应,其变成高温空气6,高温空气6从填料塔7的高温空气出口流出,进入换热器10的热端,与其冷端的冷水16进行热交换,温度降低,冷凝出水分,空气和液态水混合物再进入气液分离器11进行气液分离,分离出两部分,分别是低温空气8和淡水12,低温空气8从气液分离器11的气体出口流出,经过风机9加压后,重新从填料塔7干空气进口进入填料塔7,往复循环;淡水12从气液分离器11的下出口流出,进入淡水罐13储存。Start the fan 9, as above, the low-temperature air 8 enters the packed tower 7, and dehumidifies the total seawater 1, and it becomes the high-temperature air 6, and the high-temperature air 6 flows out from the high-temperature air outlet of the packed tower 7, and enters the heat exchanger 10. The hot end exchanges heat with the cold water 16 at the cold end, the temperature drops, and moisture is condensed, and the mixture of air and liquid water enters the gas-liquid separator 11 for gas-liquid separation, and two parts are separated, namely low-temperature air 8 and fresh water 12, The low-temperature air 8 flows out from the gas outlet of the gas-liquid separator 11, and after being pressurized by the fan 9, it enters the packed tower 7 from the dry air inlet of the packed tower 7 again, and reciprocates; the fresh water 12 flows out from the lower outlet of the gas-liquid separator 11, Enter the fresh water tank 13 for storage.
最后启动压缩机17,制冷剂18通过压缩机17加压后,进入冷凝器2热端,将热量传给其冷端的海水,降温后的制冷剂18再通入节流阀19节流,进入蒸发器15冷端,与其热端的冷水16进行热交换,冷却热端的冷水16,后通过压缩机4进口进入压缩机4,如此往复循环;Finally, the compressor 17 is started, and the refrigerant 18 enters the hot end of the condenser 2 after being pressurized by the compressor 17, and transfers heat to the seawater at the cold end, and the cooled refrigerant 18 is then passed into the throttling valve 19 to throttle and enter The cold end of the evaporator 15 exchanges heat with the cold water 16 at the hot end, cools the cold water 16 at the hot end, and then enters the compressor 4 through the compressor 4 inlet, and thus reciprocates;
在结束系统运行时,依次关闭压缩机17、风机9、海水泵3和循环水泵14,系统停止运行。When the system operation is finished, the compressor 17, the blower fan 9, the seawater pump 3 and the circulating water pump 14 are closed in sequence, and the system stops running.
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CN109751095A (en) * | 2019-01-16 | 2019-05-14 | 南京航空航天大学 | Hydropower cogeneration system and working method for concentrating solution using waste heat of flue gas in cascade |
CN109809514A (en) * | 2019-01-30 | 2019-05-28 | 浙江海洋大学 | A heat pump seawater desalination device utilizing waste heat from cooling towers of power plants |
CN110180208A (en) * | 2019-05-09 | 2019-08-30 | 南京航空航天大学 | Heat pump film evaporating, concentrating and crystallizing system and method based on thermal sensitivity deep-etching raw material |
CN111056582A (en) * | 2020-01-08 | 2020-04-24 | 浙江工业大学 | Air heat dissipation cascade heat pump sea water desalination device of economic benefits and social benefits |
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CN109751095A (en) * | 2019-01-16 | 2019-05-14 | 南京航空航天大学 | Hydropower cogeneration system and working method for concentrating solution using waste heat of flue gas in cascade |
CN109809514A (en) * | 2019-01-30 | 2019-05-28 | 浙江海洋大学 | A heat pump seawater desalination device utilizing waste heat from cooling towers of power plants |
CN110180208A (en) * | 2019-05-09 | 2019-08-30 | 南京航空航天大学 | Heat pump film evaporating, concentrating and crystallizing system and method based on thermal sensitivity deep-etching raw material |
CN111056582A (en) * | 2020-01-08 | 2020-04-24 | 浙江工业大学 | Air heat dissipation cascade heat pump sea water desalination device of economic benefits and social benefits |
CN112939122A (en) * | 2021-01-26 | 2021-06-11 | 南京航空航天大学 | Cooling and dehumidifying type seawater desalination system with heat pump circulation and working method thereof |
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