CN109000075A - A kind of antifreeze heating tape of uniform cloth heat of water supply line - Google Patents
A kind of antifreeze heating tape of uniform cloth heat of water supply line Download PDFInfo
- Publication number
- CN109000075A CN109000075A CN201810908735.2A CN201810908735A CN109000075A CN 109000075 A CN109000075 A CN 109000075A CN 201810908735 A CN201810908735 A CN 201810908735A CN 109000075 A CN109000075 A CN 109000075A
- Authority
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- China
- Prior art keywords
- parts
- water supply
- supply line
- uniform cloth
- heating tape
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
- F16L53/00—Heating of pipes or pipe systems; Cooling of pipes or pipe systems
- F16L53/30—Heating of pipes or pipe systems
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/28—Nitrogen-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/11—Esters; Ether-esters of acyclic polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/28—Nitrogen-containing compounds
- C08K2003/282—Binary compounds of nitrogen with aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- General Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of antifreeze heating tapes of the uniform cloth heat of water supply line, it including two copper core buses disposed in parallel, is distributed between two copper core buses and plays the PTC polymer heating material of heat effect, and the interior insulation sheath being wrapped in outside the PTC polymer heating material；The PTC polymer heating material prepares the component that raw material includes following mass fraction: 100 parts of high density polyethylene (HDPE), 10~23 parts of aluminium nitride, 3~5 parts of carbon black, 0.5~0.8 part of zinc oxide, 2.5~3.5 parts of silane coupling agent, 1.5~2.0 parts of 4,4'- thiobis (6- tertiary butyl metacresol), 0.3~0.5 part of tetrapentaerythritol rouge, 0.8~1.0 part of sebacic acid dibutyl ester.A kind of antifreeze heating tape of the uniform cloth heat of water supply line provided by the invention, has good thermal conductivity, in the longitudinal direction so as to reduce temperature difference in the longitudinal direction as much as possible.
Description
Technical field
The present invention relates to a kind of heating tape product technical field, the antifreeze heat tracing of especially a kind of uniform cloth heat of water supply line
Band.
Background technique
The structure of self-limiting heating cable includes two conductive cores and is distributed between two conductive cores and plays heat effect
PTC high molecular material；When the power is turned on, with the fever of PTC high molecular material, internal PTC high molecular material expanded by heating
So that resistance is become larger, to reduce heating power, heating power and the resistance of PTC high molecular material is made to reach an equilibrium valve, from
And realize the self limiting temperature function of heating tape.
For the self-limiting heating cable of different application, there is different performance requirements, wherein for water supply line into
The heating tape of the antifreeze heat tracing of row, the requirement for heat tracing temperature is not high, as long as the highest of heat tracing belt surface maintains temperature that can reach
To 50 DEG C or more, the function of preventing water supply line from freezing can be realized；Flame retardant property requirement further for heating tape is not also high,
Even if heating tape is ignited in accident or since failure leads to that spontaneous combustion occurs, will not generally damage to water supply line, i.e.,
Just damaging to water supply line leads to pipe burst, and the water in water supply line can also rapidly stamp out the flames；But due to
The length of water supply line is longer, and mostly buried in underground, therefore it is required that heating tape needs to have biggish length, and heating tape
Length is too long, is influenced by PTC polymer heating material overall resistance, then the temperature of position there is larger difference,
The position heat tracing temperature resulted in has reached the upper limit, and some position heat tracing temperature are also not enough to play antifreezing effect.Base
In above-mentioned characteristic, it is necessary to develop a kind of antifreeze heating tape of uniform cloth heat of water supply line.
Summary of the invention
For overcome the deficiencies in the prior art, the present invention provides a kind of antifreeze heating tape of water supply line uniform cloth heat,
There is good thermal conductivity, so as to reduce temperature difference in the longitudinal direction as much as possible on length direction.
The technical solution adopted by the present invention to solve the technical problems is:
A kind of antifreeze heating tape of the uniform cloth heat of water supply line, including two copper core buses disposed in parallel, be distributed in described in two
The PTC polymer heating material of heat effect is played between copper core bus, and is wrapped in outside the PTC polymer heating material
Interior insulation sheath；The PTC polymer heating material prepares the component that raw material includes following mass fraction:
100 parts of high density polyethylene (HDPE),
10~23 parts of aluminium nitride,
3~5 parts of carbon black,
0.5~0.8 part of zinc oxide,
2.5~3.5 parts of silane coupling agent,
1.5~2.0 parts of 4,4'- thiobis (6- tertiary butyl metacresol),
0.3~0.5 part of tetrapentaerythritol rouge,
0.8~1.0 part of sebacic acid dibutyl ester.
As above-mentioned technical proposal further preferred, two copper core buses are that tin plating copper stranded conductor or nickel-clad copper twist
Line, the interior insulation sheath are made of ethylene-vinyl acetate copolymer material.
It is as above-mentioned technical proposal further preferred, it further include the cable shield being wrapped in outside the interior insulation sheath
Layer, the cable shield are that semi-conductive tape is wrapped, semiconductive material extrudes and one of metallic fiber mixed weaving or a variety of
It is compound.
It is as above-mentioned technical proposal further preferred, it further include the external insulation shield being wrapped in outside the cable shield
Set, the outer insulation jacket are made of EP rubbers material.
Compared with prior art, the beneficial effects of the present invention are:
A kind of antifreeze heating tape of the uniform cloth heat of water supply line provided by the present invention, the PTC polymer heating material of selection have
Good thermal conductivity, thermal conductivity in the longitudinal direction is 35~78 W/mK, so as to reduce as much as possible in length side
Upward temperature difference；It is 48~63 DEG C that heat tracing belt surface highest, which maintains temperature,.
Detailed description of the invention
Present invention will be further explained below with reference to the attached drawings and examples.
Fig. 1 is a kind of structural schematic diagram of the antifreeze heating tape of the uniform cloth heat of water supply line of the present invention.
Specific embodiment
Specific embodiment 1
Referring to Fig.1, Fig. 1 is a kind of antifreeze heating tape of the uniform cloth heat of water supply line provided in this embodiment, including two set in parallel
The copper core bus 1 set is distributed in the PTC polymer heating material 2 that heat effect is played between two copper core buses 1, and
The interior insulation sheath 3 being wrapped in outside the PTC polymer heating material 2；Two copper core buses 1 be tin plating copper stranded conductor or
Nickel plating copper stranded conductor, the interior insulation sheath 3 are made of ethylene-vinyl acetate copolymer material.
It further include the cable shield 4 being wrapped in outside the interior insulation sheath 3, the cable shield 4 is semi-conductive tape
Wrapped, semiconductive material extrudes and one of metallic fiber mixed weaving or a variety of compound.It further include being wrapped in the cable screens
The outer insulation jacket 5 outside layer 4 is covered, the outer insulation jacket 5 is made of EP rubbers material.
The PTC polymer heating material 2 prepares the component that raw material includes following mass fraction:
100 parts of high density polyethylene (HDPE), 23 parts of aluminium nitride, 3 parts of carbon black, 0.6 part of zinc oxide, 3.5 parts of silane coupling agent, 4,4'- sulphur
1.5 parts, 0.4 part of tetrapentaerythritol rouge, 0.8 part of sebacic acid dibutyl ester of Dai Shuan (6- tertiary butyl metacresol).
The partial size of carbon black is less than or equal to 200 nanometers, and the partial size of zinc oxide is less than or equal to 100 nanometers, and the partial size of aluminium nitride is small
In equal to 1.0 microns.
The preparation method of the PTC polymer heating material 2 the following steps are included:
Step 1: being put into mixing equipment after high density polyethylene (HDPE) master batch, aluminium nitride, carbon black and zinc oxide are mixed, with 130
~150 DEG C of temperature mixing 20~30 minutes, makes that high density polyethylene (HDPE) melts completely and each component is sufficiently mixed.
Step 2: silane coupling agent is put into mixing equipment, with temperature mixing 30~50 minutes of 110~120 DEG C,
Keep silane coupling agent evenly dispersed and abundant reaction.
Step 3: 4,4'- thiobis (6- tertiary butyl metacresol), tetrapentaerythritol rouge and sebacic acid dibutyl ester are mixed equal
It is put into after even in mixing equipment, with temperature mixing 10~20 minutes of 120~130 DEG C, component is made to be uniformly dispersed.
Step 4: the product of step 3 is put into twin-screw melting extrusion equipment, PTC polymer heating material is squeezed out
It is wrapped in outside two copper core buses disposed in parallel.
Step 5: the PTC polymer heating material squeezed out is cooled in 25 DEG C~28 DEG C of air lower than softening temperature
Afterwards, be placed in 80 DEG C~85 DEG C of sink and cooled down and kept the temperature 1~3 minute, be then fed into 65 DEG C~70 DEG C of sink into
Row is cooling simultaneously to keep the temperature 1~3 minute, is re-fed into and 1~3 minute is cooled down and kept the temperature in 45 DEG C~50 DEG C of sink, finally as
It is cooled to room temperature in air.
The heating conduction of the PTC polymer heating material 2 provided in this embodiment are as follows: thermal conductivity in the longitudinal direction
For 78 W/mK.
The waterproof test performance of the antifreeze heating tape of the uniform cloth heat of a kind of water supply line provided in this embodiment: according to GB/
T19835-2005 " self-limiting heating cable " national standard is tested, heating tape soak 48 h after bear 3.5 KV/1 min without
Breakdown.
The heating temperature of the antifreeze heating tape of the uniform cloth heat of a kind of water supply line provided in this embodiment: according to GB/T19835-
2005 " self-limiting heating cable " national standards are tested, and it is 55 DEG C that heat tracing belt surface highest, which maintains temperature,.
Specific embodiment 2
A kind of antifreeze heating tape of the uniform cloth heat of water supply line provided in this embodiment, structure and the PTC macromolecule heating material
The preparation method of material 2 is identical as specific embodiment 1, the difference is that:
The PTC polymer heating material 2 prepares the component that raw material includes following mass fraction:
100 parts of high density polyethylene (HDPE), 10 parts of aluminium nitride, 5 parts of carbon black, 0.8 part of zinc oxide .5 parts of silane coupling agent, 4,4'- is thio
1.6 parts, 0.3 part of tetrapentaerythritol rouge, 0.9 part of sebacic acid dibutyl ester of bis- (6- tertiary butyl metacresols).
The heating conduction of the PTC polymer heating material 2 provided in this embodiment are as follows: thermal conductivity in the longitudinal direction
For 35 W/mK.
The waterproof test performance of the antifreeze heating tape of the uniform cloth heat of a kind of water supply line provided in this embodiment: according to GB/
T19835-2005 " self-limiting heating cable " national standard is tested, heating tape soak 48 h after bear 3.5 KV/1 min without
Breakdown.
The heating temperature of the antifreeze heating tape of the uniform cloth heat of a kind of water supply line provided in this embodiment: according to GB/T19835-
2005 " self-limiting heating cable " national standards are tested, and it is 63 DEG C that heat tracing belt surface highest, which maintains temperature,.
Specific embodiment 3
A kind of antifreeze heating tape of the uniform cloth heat of water supply line provided in this embodiment, structure and the PTC macromolecule heating material
The preparation method of material 2 is identical as specific embodiment 1, the difference is that:
The PTC polymer heating material 2 prepares the component that raw material includes following mass fraction:
100 parts of high density polyethylene (HDPE), 20 parts of aluminium nitride, 4 parts of carbon black, 0.5 part of zinc oxide, 3.0 parts of silane coupling agent, 4,4'- sulphur
2.0 parts, 0.5 part of tetrapentaerythritol rouge, 1.0 parts of sebacic acid dibutyl ester of Dai Shuan (6- tertiary butyl metacresol).
The heating conduction of the PTC polymer heating material 2 provided in this embodiment are as follows: thermal conductivity in the longitudinal direction
For 63 W/mK.
The waterproof test performance of the antifreeze heating tape of the uniform cloth heat of a kind of water supply line provided in this embodiment: according to GB/
T19835-2005 " self-limiting heating cable " national standard is tested, heating tape soak 48 h after bear 3.5 KV/1 min without
Breakdown.
The heating temperature of the antifreeze heating tape of the uniform cloth heat of a kind of water supply line provided in this embodiment: according to GB/T19835-
2005 " self-limiting heating cable " national standards are tested, and it is 48 DEG C that heat tracing belt surface highest, which maintains temperature,.
Better embodiment of the invention is illustrated above, certainly, the present invention can also using with it is above-mentioned
The different form of embodiment, those skilled in the art are made equivalent on the premise of without prejudice to spirit of the invention
Transformation or corresponding change, all should belong in protection scope of the present invention.
Claims (5)
1. a kind of antifreeze heating tape of the uniform cloth heat of water supply line, including two copper core buses (1) disposed in parallel, it is distributed in two
The PTC polymer heating material (2) of heat effect is played between the copper core bus (1), and is wrapped in the PTC macromolecule hair
The interior insulation sheath (3) of hot material (2) outside；It is characterized in that, the raw material for preparing of the PTC polymer heating material (2) includes
The component of following mass fraction:
100 parts of high density polyethylene (HDPE),
10~23 parts of aluminium nitride,
3~5 parts of carbon black,
0.5~0.8 part of zinc oxide,
2.5~3.5 parts of silane coupling agent,
1.5~2.0 parts of 4,4'- thiobis (6- tertiary butyl metacresol),
0.3~0.5 part of tetrapentaerythritol rouge,
0.8~1.0 part of sebacic acid dibutyl ester.
2. a kind of antifreeze heating tape of the uniform cloth heat of water supply line according to claim 1, which is characterized in that the PTC high
Molecule heating material (2) prepares the component that raw material includes following mass fraction:
100 parts of high density polyethylene (HDPE),
23 parts of aluminium nitride, 3 parts of carbon black,
0.6 part of zinc oxide,
3.5 parts of silane coupling agent,
1.5 parts of 4,4'- thiobis (6- tertiary butyl metacresol),
0.4 part of tetrapentaerythritol rouge,
0.8 part of sebacic acid dibutyl ester.
3. a kind of antifreeze heating tape of the uniform cloth heat of water supply line according to claim 1, it is characterised in that: two copper
Core bus (1) is tin plating copper stranded conductor or nickel plating copper stranded conductor, and the interior insulation sheath (3) is ethylene-vinyl acetate copolymer material
Material is made.
4. a kind of antifreeze heating tape of the uniform cloth heat of water supply line according to claim 1, it is characterised in that: further include package
In the cable shield (4) of the interior insulation sheath (3) outside, the cable shield (4) wrapped, semiconductive material for semi-conductive tape
It extrudes and one of metallic fiber mixed weaving or a variety of compound.
5. a kind of antifreeze heating tape of the uniform cloth heat of water supply line according to claim 4, it is characterised in that: further include package
In the outer insulation jacket (5) of the cable shield (4) outside, the outer insulation jacket (5) is made of EP rubbers material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810908735.2A CN109000075A (en) | 2018-08-10 | 2018-08-10 | A kind of antifreeze heating tape of uniform cloth heat of water supply line |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810908735.2A CN109000075A (en) | 2018-08-10 | 2018-08-10 | A kind of antifreeze heating tape of uniform cloth heat of water supply line |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109000075A true CN109000075A (en) | 2018-12-14 |
Family
ID=64595231
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810908735.2A Withdrawn CN109000075A (en) | 2018-08-10 | 2018-08-10 | A kind of antifreeze heating tape of uniform cloth heat of water supply line |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109000075A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2025055053A1 (en) * | 2023-09-12 | 2025-03-20 | 安邦电气股份有限公司 | Ptc heat trace cable and preparation method therefor |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4444708A (en) * | 1979-05-10 | 1984-04-24 | Sunbeam Corporation | Flexible production of heating elements |
| CN101178959A (en) * | 2006-11-09 | 2008-05-14 | 聚鼎科技股份有限公司 | High voltage resistant overcurrent protection element |
| CN103304872A (en) * | 2013-05-24 | 2013-09-18 | 安邦电气集团有限公司 | High-density polyvinyl PTC high molecular exothermic material and preparation method thereof |
| CN103772782A (en) * | 2013-12-03 | 2014-05-07 | 上海神沃电子有限公司 | Self-limited flexible PTC (positive temperature coefficient) exothermic material and PTC core material prepared from same and preparation method of PTC core material |
| CN106332333A (en) * | 2016-09-08 | 2017-01-11 | 芜湖市旭辉电工新材料有限责任公司 | Anti-freezing self-regulating electric tracing band for water supply pipeline |
-
2018
- 2018-08-10 CN CN201810908735.2A patent/CN109000075A/en not_active Withdrawn
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4444708A (en) * | 1979-05-10 | 1984-04-24 | Sunbeam Corporation | Flexible production of heating elements |
| CN101178959A (en) * | 2006-11-09 | 2008-05-14 | 聚鼎科技股份有限公司 | High voltage resistant overcurrent protection element |
| CN103304872A (en) * | 2013-05-24 | 2013-09-18 | 安邦电气集团有限公司 | High-density polyvinyl PTC high molecular exothermic material and preparation method thereof |
| CN103772782A (en) * | 2013-12-03 | 2014-05-07 | 上海神沃电子有限公司 | Self-limited flexible PTC (positive temperature coefficient) exothermic material and PTC core material prepared from same and preparation method of PTC core material |
| CN106332333A (en) * | 2016-09-08 | 2017-01-11 | 芜湖市旭辉电工新材料有限责任公司 | Anti-freezing self-regulating electric tracing band for water supply pipeline |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2025055053A1 (en) * | 2023-09-12 | 2025-03-20 | 安邦电气股份有限公司 | Ptc heat trace cable and preparation method therefor |
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Application publication date: 20181214 |
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