CN108976693B - Marble-like grain color master batch suitable for ABS and use method thereof - Google Patents
Marble-like grain color master batch suitable for ABS and use method thereof Download PDFInfo
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- 239000004595 color masterbatch Substances 0.000 title claims abstract description 103
- 238000000034 method Methods 0.000 title description 10
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 claims abstract description 95
- 239000002994 raw material Substances 0.000 claims abstract description 60
- 239000004594 Masterbatch (MB) Substances 0.000 claims abstract description 23
- 238000001125 extrusion Methods 0.000 claims abstract description 20
- 239000000049 pigment Substances 0.000 claims abstract description 18
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 13
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 13
- 239000003086 colorant Substances 0.000 claims abstract description 11
- 239000012760 heat stabilizer Substances 0.000 claims abstract description 5
- 239000000314 lubricant Substances 0.000 claims abstract description 5
- 239000000463 material Substances 0.000 claims description 34
- 238000001816 cooling Methods 0.000 claims description 26
- 238000003756 stirring Methods 0.000 claims description 26
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 18
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical group [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 claims description 16
- 238000002156 mixing Methods 0.000 claims description 11
- QFFVPLLCYGOFPU-UHFFFAOYSA-N barium chromate Chemical compound [Ba+2].[O-][Cr]([O-])(=O)=O QFFVPLLCYGOFPU-UHFFFAOYSA-N 0.000 claims description 10
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 claims description 10
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 claims description 10
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical group O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 9
- CGLVZFOCZLHKOH-UHFFFAOYSA-N 8,18-dichloro-5,15-diethyl-5,15-dihydrodiindolo(3,2-b:3',2'-m)triphenodioxazine Chemical compound CCN1C2=CC=CC=C2C2=C1C=C1OC3=C(Cl)C4=NC(C=C5C6=CC=CC=C6N(C5=C5)CC)=C5OC4=C(Cl)C3=NC1=C2 CGLVZFOCZLHKOH-UHFFFAOYSA-N 0.000 claims description 8
- SUXCALIDMIIJCK-UHFFFAOYSA-L disodium;4-amino-3-[[4-[4-[(1-amino-4-sulfonatonaphthalen-2-yl)diazenyl]-3-methylphenyl]-2-methylphenyl]diazenyl]naphthalene-1-sulfonate Chemical compound [Na+].[Na+].C1=CC=CC2=C(N)C(N=NC3=CC=C(C=C3C)C=3C=C(C(=CC=3)N=NC=3C(=C4C=CC=CC4=C(C=3)S([O-])(=O)=O)N)C)=CC(S([O-])(=O)=O)=C21 SUXCALIDMIIJCK-UHFFFAOYSA-L 0.000 claims description 8
- 235000019359 magnesium stearate Nutrition 0.000 claims description 8
- 229920002545 silicone oil Polymers 0.000 claims description 8
- AYEKOFBPNLCAJY-UHFFFAOYSA-O thiamine pyrophosphate Chemical compound CC1=C(CCOP(O)(=O)OP(O)(O)=O)SC=[N+]1CC1=CN=C(C)N=C1N AYEKOFBPNLCAJY-UHFFFAOYSA-O 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 6
- 235000021355 Stearic acid Nutrition 0.000 claims description 5
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 5
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 5
- 239000008117 stearic acid Substances 0.000 claims description 5
- PRWJPWSKLXYEPD-UHFFFAOYSA-N 4-[4,4-bis(5-tert-butyl-4-hydroxy-2-methylphenyl)butan-2-yl]-2-tert-butyl-5-methylphenol Chemical compound C=1C(C(C)(C)C)=C(O)C=C(C)C=1C(C)CC(C=1C(=CC(O)=C(C=1)C(C)(C)C)C)C1=CC(C(C)(C)C)=C(O)C=C1C PRWJPWSKLXYEPD-UHFFFAOYSA-N 0.000 claims description 4
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 2
- YHMYGUUIMTVXNW-UHFFFAOYSA-N 1,3-dihydrobenzimidazole-2-thione Chemical compound C1=CC=C2NC(S)=NC2=C1 YHMYGUUIMTVXNW-UHFFFAOYSA-N 0.000 claims description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 2
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 2
- 239000005642 Oleic acid Substances 0.000 claims description 2
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 claims description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 2
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 2
- 239000000194 fatty acid Substances 0.000 claims description 2
- 229930195729 fatty acid Natural products 0.000 claims description 2
- 150000004665 fatty acids Chemical class 0.000 claims description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 2
- 238000002844 melting Methods 0.000 abstract description 16
- 230000008018 melting Effects 0.000 abstract description 16
- 230000000694 effects Effects 0.000 abstract description 10
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 abstract description 8
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 abstract 6
- 238000007599 discharging Methods 0.000 abstract 1
- 229920003023 plastic Polymers 0.000 description 10
- 239000004033 plastic Substances 0.000 description 10
- 238000007605 air drying Methods 0.000 description 9
- 239000011347 resin Substances 0.000 description 7
- 229920005989 resin Polymers 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 6
- 229920001897 terpolymer Polymers 0.000 description 4
- DDZUQFPWZCKEBL-UHFFFAOYSA-N C(=CC1=CC=CC=C1)/C/1=C/C(=O)OC1=O.C(C=C)#N Chemical compound C(=CC1=CC=CC=C1)/C/1=C/C(=O)OC1=O.C(C=C)#N DDZUQFPWZCKEBL-UHFFFAOYSA-N 0.000 description 3
- AGXUVMPSUKZYDT-UHFFFAOYSA-L barium(2+);octadecanoate Chemical compound [Ba+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O AGXUVMPSUKZYDT-UHFFFAOYSA-L 0.000 description 3
- 238000005520 cutting process Methods 0.000 description 3
- 239000004579 marble Substances 0.000 description 3
- 239000002023 wood Substances 0.000 description 3
- 238000009713 electroplating Methods 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000007639 printing Methods 0.000 description 2
- -1 ABS-g-MAH Chemical compound 0.000 description 1
- CEGOLXSVJUTHNZ-UHFFFAOYSA-K aluminium tristearate Chemical compound [Al+3].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CEGOLXSVJUTHNZ-UHFFFAOYSA-K 0.000 description 1
- 229940063655 aluminum stearate Drugs 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 239000008116 calcium stearate Substances 0.000 description 1
- 235000013539 calcium stearate Nutrition 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- SCUZVMOVTVSBLE-UHFFFAOYSA-N prop-2-enenitrile;styrene Chemical compound C=CC#N.C=CC1=CC=CC=C1 SCUZVMOVTVSBLE-UHFFFAOYSA-N 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 229920000638 styrene acrylonitrile Polymers 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
- C08J3/223—Packed additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
- C08J3/226—Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2355/00—Characterised by the use of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08J2323/00 - C08J2353/00
- C08J2355/02—Acrylonitrile-Butadiene-Styrene [ABS] polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2451/00—Characterised by the use of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2455/00—Characterised by the use of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08J2423/00 - C08J2453/00
- C08J2455/02—Acrylonitrile-Butadiene-Styrene [ABS] polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2467/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
- C08J2467/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2483/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers
- C08J2483/04—Polysiloxanes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/098—Metal salts of carboxylic acids
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/13—Phenols; Phenolates
- C08K5/134—Phenols containing ester groups
- C08K5/1345—Carboxylic esters of phenolcarboxylic acids
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/20—Carboxylic acid amides
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
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- Polymers & Plastics (AREA)
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- Processes Of Treating Macromolecular Substances (AREA)
Abstract
The invention provides an imitation marbling master batch suitable for ABS (acrylonitrile butadiene styrene), which comprises a first color master batch and a second color master batch, wherein the first color master batch comprises the following components in parts by weight: 60-80 parts of PET, 5-15 parts of ABS, 5-10 parts of first pigment, 2-5 parts of lubricant, 1-3 parts of compatilizer, 0.3-1 part of heat stabilizer and 0.3-1 part of antioxidant; the second color master batch comprises the following components in parts by weight: 60-80 parts of PBT, 5-15 parts of ABS and 5-10 parts of a second pigment. The marbleized master batch comprises a first color master batch and a second color master batch, wherein pigments of the first color master batch and the second color master batch can be matched according to appearance effects, the first color master batch and the second color master batch are uniformly mixed with ABS raw material master batches by utilizing the difference of the melting points of ABS, PET and PBT, and then are put into a screw extruder for mixed melting and extrusion, and the marbleized ABS plastic with various colors can be obtained during discharging, so that the grains are clear, the random matching effect of various colors is realized, and the ABS plastic has bright appearance effects.
Description
Technical Field
The invention relates to the field of color master batches, in particular to a marbleizing master batch suitable for ABS and a using method thereof.
Background
In order to give the plastic gorgeous, colorful and diversified appearances, the modes of painting, electroplating and printing ink on the plastic base material are generally adopted to achieve the beautiful appearance effect. However, the methods of spraying paint, electroplating and printing ink have the defects of complex flow, high cost, environmental pollution, harm to the health of workers, difficulty in recycling and the like, and the surface coating of the product is easy to fade, influences the appearance of the product and does not advocate the use.
In order to improve the problems, some enterprises develop plastic products with imitated marble and wood grain, and the preparation mechanism of the plastic products with imitated marble and wood grain is as follows: the special color master batch is prepared, the carrier resin in the color master batch and the plastic raw material have different melting points, when the color master batch and the plastic raw material are put into a screw extruder for blending and extrusion, the two materials form different flow rates in a screw barrel of the extruder due to the different melting points of the carrier resin and the plastic raw material, so that the pigment is irregularly distributed along with the flow of the carrier resin, and the plastic profile has marble and wood grain effects.
The common marbleizing master batch only has one color system, and can only be used for manufacturing marbleizing plastics with one color, and the plastic has monotonous color and is easy to generate aesthetic fatigue after being watched for a long time. In order to solve the problem, some manufacturers add a plurality of pigments into the color master batch simultaneously to achieve a multicolor effect. However, in this way, when a plurality of pigments are mixed and melted in a screw machine, the pigments are easily mixed and become a single mixed color, which affects the appearance, and these problems need to be solved.
Disclosure of Invention
Aiming at the problems, the invention provides the marbleized master batch suitable for ABS and the use method thereof, which can be used for manufacturing the marbleized ABS plastic with various colors.
In order to achieve the purpose, the invention is solved by the following technical scheme:
the marble-imitated color master batch suitable for ABS comprises a first color master batch and a second color master batch, wherein the first color master batch comprises the following components in parts by weight: 60-80 parts of PET, 5-15 parts of ABS, 5-10 parts of first pigment, 2-5 parts of lubricant, 1-3 parts of compatilizer, 0.3-1 part of heat stabilizer and 0.3-1 part of antioxidant;
the second color master batch comprises the following components in parts by weight: 60-80 parts of PBT, 5-15 parts of ABS and 5-10 parts of a second pigment.
Specifically, the first pigment is one or a combination of more of phthalocyanine red, phthalocyanine blue, phthalocyanine green, fast scarlet, permanent yellow, permanent violet and azoic red.
Specifically, the second pigment is one or a combination of more of phthalocyanine red, phthalocyanine blue, phthalocyanine green, fast scarlet, permanent yellow, permanent violet and azoic red.
Specifically, the lubricant is one or a combination of more of silicone oil, stearic acid, fatty acid amide, oleic acid and carboxylic acid.
Specifically, the compatilizer is one or a composition of more of maleic anhydride grafted styrene, acrylonitrile-styrene-maleic anhydride terpolymer, SEBS-g-MAH, ABS-g-MAH and styrene-acrylonitrile copolymer-glycidyl methacrylate terpolymer.
Specifically, the heat stabilizer is one or a combination of more of barium stearate, calcium stearate, magnesium stearate, stearic acid file and aluminum stearate.
Specifically, the antioxidant is one or a combination of several of antioxidant 1010, antioxidant TPP, antioxidant CA and antioxidant MB.
A use method of an imitated marbling master batch suitable for ABS comprises the following steps:
s1, taking ABS raw material master batches, putting the first color master batch, the second color master batch and the ABS raw material master batches into a high-speed stirrer, and stirring for 10 minutes at normal temperature to obtain a mixed raw material;
s2, adding the mixed raw materials into a feeding hopper of a double-screw extruder, and carrying out mixing and extrusion in the double-screw extruder, wherein the temperatures of all sections from the hopper to a die head of the double-screw extruder are respectively set to be 180-;
a die head of S3 is connected with a die, and the die head feeds the extruded material obtained in the step S2 into the die;
s4, after pressurization and cooling, the extruded material is molded in a die, and after demolding, the marbleized ABS plastic with various colors is obtained.
Specifically, in the step S1, the adding weight ratio of the first color master batch, the second color master batch, and the ABS raw material master batch is 1-5: 1-5: 1000.
the invention has the beneficial effects that:
the marbleized master batch comprises a first color master batch and a second color master batch, wherein pigments of the first color master batch and the second color master batch can be matched according to appearance effects, the first color master batch adopts PET as a carrier resin, the melting point of the PET is about 260 ℃, the second color master batch adopts PBT as a carrier resin, the melting point of the PBT is about 230 ℃, the natural color master batch is suitable for ABS plastics, the melting point of the ABS is about 170 ℃, the difference of the melting points of the ABS, the PET and the PBT is utilized, then the first color master batch, the second color master batch and ABS raw material master batches are uniformly mixed and then put into a screw extruder for mixing, melting and extruding, and when mixing, because the flow rates of the ABS, the PET and the PBT are different, the first pigment in the first color master batch is irregularly distributed in the ABS plastics along with the flow of the PET, the second pigment in the second color master batch is irregularly distributed in the ABS plastics along with the flow of the PBT, and the marbleized ABS plastics with various, clear lines and realizes the random matching effect of various colors, so that the ABS plastic has a bright appearance effect.
Detailed Description
The present invention will be described in further detail with reference to specific embodiments in order to provide a further understanding of the nature and technical means of the invention, as well as the specific objects and functions attained by the invention.
Example 1
The marble-imitated color master batch suitable for ABS comprises a first color master batch and a second color master batch, wherein the first color master batch comprises the following components in parts by weight: 60 parts of PET, 15 parts of ABS, 7 parts of phthalocyanine blue, 2 parts of silicone oil, 2 parts of maleic anhydride grafted styrene, 0.3 part of magnesium stearate and 0.3 part of antioxidant TPP;
the second color master batch comprises the following components in parts by weight: 60 parts of PBT, 15 parts of ABS and 7 parts of light fast scarlet.
Preparing a first color master batch:
(1) putting PET, ABS, phthalocyanine blue, silicone oil, maleic anhydride grafted styrene, magnesium stearate and antioxidant TPP into a high-speed stirrer according to a ratio, stirring for 10 minutes at 120 ℃, cooling, and then continuing stirring for 10 minutes to obtain a mixed raw material;
(2) the mixed raw materials are put into a double-screw extruder to be melted, the temperature of the double-screw extruder is gradually increased from 180 ℃ to 240 ℃ from a feed port to an extrusion head, and a strip-shaped material is extruded;
(3) and (3) cooling the extruded strip material with water, air-drying and cutting into granules to obtain the first-color master batch.
Preparing a second color master batch:
(4) putting PBT, ABS and fast scarlet into a high-speed stirrer according to a ratio, stirring for 10 minutes at 120 ℃, cooling, and continuing stirring for 10 minutes to obtain a mixed raw material;
(5) the mixed raw materials are put into a double-screw extruder to be melted, the temperature of the double-screw extruder is gradually increased from 180 ℃ to 240 ℃ from a feed port to an extrusion head, and a strip-shaped material is extruded;
(6) and cooling the extruded strip material with water, air-drying and dicing to obtain second color master batches.
A use method of an imitated marbling master batch suitable for ABS comprises the following steps:
s1, taking ABS raw material master batches, putting the first color master batch, the second color master batch and the ABS raw material master batches into a high-speed stirrer, and stirring for 10 minutes at normal temperature to obtain a mixed raw material;
s2, adding the mixed raw materials into a feeding hopper of a double-screw extruder, carrying out mixing melting extrusion in the double-screw extruder, setting the temperatures of all sections of the double-screw extruder from the hopper to a die head to be 190 ℃, 200 ℃, 210 ℃ and 220 ℃, and setting the screw rotating speed to be 300 rpm;
a die head of S3 is connected with a die, and the die head feeds the extruded material obtained in the step S2 into the die;
s4, after pressurization and cooling, the extruded material is molded in a die, and after demolding, the marbleized ABS plastic with various colors is obtained.
Preferably, in step S1, the adding weight ratio of the first color masterbatch, the second color masterbatch, and the ABS raw material masterbatch is 3: 3: 1000.
example 2
The marble-imitated color master batch suitable for ABS comprises a first color master batch and a second color master batch, wherein the first color master batch comprises the following components in parts by weight: 70 parts of PET, 10 parts of ABS, 7 parts of phthalocyanine blue, 2 parts of stearic acid, 2 parts of compatilizer, 0.3 part of barium stearate and 0.3 part of antioxidant CA;
the second color master batch comprises the following components in parts by weight: 70 parts of PBT, 10 parts of ABS and 7 parts of permanent yellow.
Preferably, the compatilizer is a composition composed of maleic anhydride grafted styrene and ABS-g-MAH according to the weight ratio of 1:2, and the compatibility of the first color master batch and the ABS raw material can be improved by adding the maleic anhydride grafted styrene and the ABS-g-MAH into the first color master batch.
Preparing a first color master batch:
(1) putting PET, ABS, phthalocyanine blue, stearic acid, maleic anhydride grafted styrene, ABS-g-MAH, barium stearate and antioxidant CA into a high-speed stirrer according to a ratio, stirring for 10 minutes at 120 ℃, cooling, and then continuing stirring for 10 minutes to obtain a mixed raw material;
(2) the mixed raw materials are put into a double-screw extruder to be melted, the temperature of the double-screw extruder is gradually increased from 180 ℃ to 240 ℃ from a feed port to an extrusion head, and a strip-shaped material is extruded;
(3) and cooling, air-drying and dicing the extruded strip-shaped material to obtain the first-color master batch.
Preparing a second color master batch:
(4) putting PBT, ABS and permanent yellow into a high-speed stirrer according to a ratio, stirring for 10 minutes at 120 ℃, cooling, and continuing stirring for 10 minutes to obtain a mixed raw material;
(5) the mixed raw materials are put into a double-screw extruder to be melted, the temperature of the double-screw extruder is gradually increased from 180 ℃ to 240 ℃ from a feed port to an extrusion head, and a strip-shaped material is extruded;
(6) and (3) cooling the extruded strip material by water, air-drying and dicing to obtain the second color master batch.
A use method of an imitated marbling master batch suitable for ABS comprises the following steps:
s1, taking ABS raw material master batches, putting the first color master batch, the second color master batch and the ABS raw material master batches into a high-speed stirrer, and stirring for 10 minutes at normal temperature to obtain a mixed raw material;
s2, adding the mixed raw materials into a feeding hopper of a double-screw extruder, carrying out mixing melting extrusion in the double-screw extruder, setting the temperatures of all sections of the double-screw extruder from the hopper to a die head to be 190 ℃, 200 ℃, 210 ℃ and 220 ℃, and setting the screw rotating speed to be 300 rpm;
a die head of S3 is connected with a die, and the die head feeds the extruded material obtained in the step S2 into the die;
s4, after pressurization and cooling, the extruded material is molded in a die, and after demolding, the marbleized ABS plastic with various colors is obtained.
Preferably, in step S1, the adding weight ratio of the first color masterbatch, the second color masterbatch, and the ABS raw material masterbatch is 3: 3: 1000.
example 3
The marble-imitated color master batch suitable for ABS comprises a first color master batch and a second color master batch, wherein the first color master batch comprises the following components in parts by weight: 80 parts of PET, 5 parts of ABS, 7 parts of permanent violet, 2 parts of silicone oil, 2 parts of acrylonitrile-styrene-maleic anhydride terpolymer, 0.3 part of magnesium stearate and 0.3 part of antioxidant TPP;
the second color master batch comprises the following components in parts by weight: 80 parts of PBT, 5 parts of ABS and 7 parts of permanent yellow.
Preparing a first color master batch:
(1) putting PET, ABS, permanent violet, silicone oil, acrylonitrile-styrene-maleic anhydride terpolymer, magnesium stearate and antioxidant TPP into a high-speed stirrer according to a ratio, stirring for 10 minutes at 120 ℃, cooling, and continuing to stir for 10 minutes to obtain a mixed raw material;
(2) the mixed raw materials are put into a double-screw extruder to be melted, the temperature of the double-screw extruder is gradually increased from 180 ℃ to 240 ℃ from a feed port to an extrusion head, and a strip-shaped material is extruded;
(3) and cooling, air-drying and dicing the extruded strip-shaped material to obtain the first-color master batch.
Preparing a second color master batch:
(4) putting PBT, ABS and permanent yellow into a high-speed stirrer according to a ratio, stirring for 10 minutes at 120 ℃, cooling, and continuing stirring for 10 minutes to obtain a mixed raw material;
(5) the mixed raw materials are put into a double-screw extruder to be melted, the temperature of the double-screw extruder is gradually increased from 180 ℃ to 240 ℃ from a feed port to an extrusion head, and a strip-shaped material is extruded;
(6) and (3) cooling the extruded strip material by water, air-drying and dicing to obtain the second color master batch.
A use method of an imitated marbling master batch suitable for ABS comprises the following steps:
s1, taking ABS raw material master batches, putting the first color master batch, the second color master batch and the ABS raw material master batches into a high-speed stirrer, and stirring for 10 minutes at normal temperature to obtain a mixed raw material;
s2, adding the mixed raw materials into a feeding hopper of a double-screw extruder, carrying out mixing melting extrusion in the double-screw extruder, setting the temperatures of all sections of the double-screw extruder from the hopper to a die head to be 190 ℃, 200 ℃, 210 ℃ and 220 ℃, and setting the screw rotating speed to be 300 rpm;
a die head of S3 is connected with a die, and the die head feeds the extruded material obtained in the step S2 into the die;
s4, after pressurization and cooling, the extruded material is molded in a die, and after demolding, the marbleized ABS plastic with various colors is obtained.
Preferably, in step S1, the adding weight ratio of the first color masterbatch, the second color masterbatch, and the ABS raw material masterbatch is 3: 3: 1000.
example 4
The marble-imitated color master batch suitable for ABS comprises a first color master batch and a second color master batch, wherein the first color master batch comprises the following components in parts by weight: 80 parts of PET, 5 parts of ABS, 7 parts of permanent violet, 2 parts of silicone oil, 2 parts of maleic anhydride grafted styrene, 0.3 part of magnesium stearate and 0.3 part of antioxidant TPP;
the second color master batch comprises the following components in parts by weight: 80 parts of PBT, 5 parts of ABS, 3 parts of phthalocyanine red and 3 parts of permanent yellow.
Preparing a first color master batch:
(1) putting PET, ABS, permanent violet, silicone oil, maleic anhydride grafted styrene, magnesium stearate and antioxidant TPP into a high-speed stirrer according to a ratio, stirring for 10 minutes at 120 ℃, cooling, and continuing stirring for 10 minutes to obtain a mixed raw material;
(2) the mixed raw materials are put into a double-screw extruder to be melted, the temperature of the double-screw extruder is gradually increased from 180 ℃ to 240 ℃ from a feed port to an extrusion head, and a strip-shaped material is extruded;
(3) and (3) cooling the extruded strip material with water, air-drying and cutting into granules to obtain the first-color master batch.
Preparing a second color master batch:
(4) putting PBT, ABS, phthalocyanine red and permanent yellow into a high-speed stirrer according to a ratio, stirring for 10 minutes at 120 ℃, cooling, and continuing stirring for 10 minutes to obtain a mixed raw material;
(5) the mixed raw materials are put into a double-screw extruder to be melted, the temperature of the double-screw extruder is gradually increased from 180 ℃ to 240 ℃ from a feed port to an extrusion head, and a strip-shaped material is extruded;
(6) and cooling the extruded strip material with water, air-drying and dicing to obtain second color master batches.
A use method of an imitated marbling master batch suitable for ABS comprises the following steps:
s1, taking ABS raw material master batches, putting the first color master batch, the second color master batch and the ABS raw material master batches into a high-speed stirrer, and stirring for 10 minutes at normal temperature to obtain a mixed raw material;
s2, adding the mixed raw materials into a feeding hopper of a double-screw extruder, carrying out mixing melting extrusion in the double-screw extruder, setting the temperatures of all sections of the double-screw extruder from the hopper to a die head to be 190 ℃, 200 ℃, 210 ℃ and 220 ℃, and setting the screw rotating speed to be 300 rpm;
a die head of S3 is connected with a die, and the die head feeds the extruded material obtained in the step S2 into the die;
s4, after pressurization and cooling, the extruded material is molded in a die, and after demolding, the marbleized ABS plastic with various colors is obtained.
Preferably, in step S1, the adding weight ratio of the first color masterbatch, the second color masterbatch, and the ABS raw material masterbatch is 3: 3: 1000.
comparative example 1
The common color master batch comprises 166.6 parts of ABS, 7 parts of fast scarlet and 7 parts of phthalocyanine blue.
Preparing a common color master batch:
(1) adding ABS, fast scarlet and phthalocyanine blue into a high-speed stirrer according to a ratio, stirring for 10 minutes at 120 ℃, cooling, and continuing stirring for 10 minutes to obtain a mixed raw material;
(2) the mixed raw materials are put into a double-screw extruder to be melted, the temperature of the double-screw extruder is gradually increased from 180 ℃ to 240 ℃ from a feed port to an extrusion head, and a strip-shaped material is extruded;
(3) and carrying out water cooling, air drying and grain cutting on the extruded strip-shaped material to obtain the common color master batch.
Preparing common ABS plastic:
s1, taking ABS raw material master batches, putting the common master batches and the ABS raw material master batches into a high-speed stirrer, and stirring for 10 minutes at normal temperature to obtain a mixed raw material;
s2, adding the mixed raw materials into a feeding hopper of a double-screw extruder, carrying out mixing melting extrusion in the double-screw extruder, setting the temperatures of all sections of the double-screw extruder from the hopper to a die head to be 190 ℃, 200 ℃, 210 ℃ and 220 ℃, and setting the screw rotating speed to be 300 rpm;
a die head of S3 is connected with a die, and the die head feeds the extruded material obtained in the step S2 into the die;
s4, after pressurization and cooling, the extruded material is molded in a die, and after demolding, the common ABS plastic is obtained.
Preferably, in the step S1, the adding weight ratio of the common color master batch to the ABS raw material master batch is 6: 1000.
and (3) performance detection:
the performance tests of the marbled ABS plastics obtained in examples 1-4 and the ordinary ABS plastics obtained in comparative example 1 were performed, and the results are reported in Table 1 below.
TABLE 1 test results
It can be seen from the data in table 1 that the master batches of the invention are used for the mixed melting extrusion of the ABS raw material in the examples 1-4 to obtain the marbleized ABS plastic with clear lines and two colors, while the ordinary master batches and the ABS raw material in the comparative example 1 are used for the mixed melting extrusion to obtain the ordinary ABS plastic without the marbleized effect, and the color is disordered and not beautiful.
On the other hand, in examples 1-4, compared with comparative example 1, the carrier resins of examples 1-4 are PET and PBT, the carrier resin of comparative example 1 is ABS, and in the test results of examples 1-4, the notched impact strength, elongation at break, tensile strength and flexural strength are all improved compared with the test results of comparative example 1, which shows that the PET added to the first color master batch and the PBT added to the second color master batch can be used as reinforcing materials, and the mechanical properties of ABS are improved.
The above examples only show 4 embodiments of the present invention, and the description thereof is more specific and detailed, but not construed as limiting the scope of the present invention. It should be noted that, for a person skilled in the art, several variations and modifications can be made without departing from the inventive concept, which falls within the scope of the present invention. Therefore, the protection scope of the present patent shall be subject to the appended claims.
Claims (6)
1. The marbleizing master batch suitable for ABS is characterized by comprising a first color master batch and a second color master batch, wherein the first color master batch comprises the following components in parts by weight: 60-80 parts of PET, 5-15 parts of ABS, 5-10 parts of first pigment, 2-5 parts of lubricant, 1-3 parts of compatilizer, 0.3-1 part of heat stabilizer and 0.3-1 part of antioxidant;
the second color master batch comprises the following components in parts by weight: 60-80 parts of PBT, 5-15 parts of ABS and 5-10 parts of a second pigment;
the compatilizer is maleic anhydride grafted styrene;
the heat stabilizer is magnesium stearate.
2. The imitation marbled master batch suitable for ABS according to claim 1, wherein the first pigment is one or a combination of phthalocyanine red, phthalocyanine blue, phthalocyanine green, fast scarlet, permanent yellow, permanent violet and azoic red.
3. The imitation marbled master batch suitable for ABS according to claim 1, wherein the second pigment is one or a combination of phthalocyanine red, phthalocyanine blue, phthalocyanine green, fast scarlet, permanent yellow, permanent violet and azoic red.
4. The imitation marbled master batch suitable for ABS according to claim 1, characterized in that the lubricant is one or a combination of silicone oil, stearic acid, fatty acid amide, oleic acid and carboxylic acid.
5. The imitation marbled master batch suitable for ABS according to claim 1, wherein the antioxidant is one of antioxidant 1010, antioxidant TPP, antioxidant CA and antioxidant MB.
6. Use of the marbleized master batch according to any one of claims 1 to 5, characterized in that it comprises the following steps:
s1, taking ABS raw material master batches, and mixing the first color master batch, the second color master batch and the ABS raw material master batches according to a weight ratio of 1-5: 1-5: 1000, putting the mixture into a high-speed stirrer, stirring the mixture for 10 minutes at 120 ℃, cooling the mixture, and continuing stirring the mixture for 10 minutes to obtain a mixed raw material;
s2, adding the mixed raw materials into a feeding hopper of a double-screw extruder, and carrying out mixing and extrusion in the double-screw extruder, wherein the temperatures of all sections from the hopper to a die head of the double-screw extruder are respectively set to be 180-;
a die head of S3 is connected with a die, and the die head feeds the extruded material obtained in the step S2 into the die;
s4, after pressurization and cooling, the extruded material is molded in a die, and after demolding, the marbleized ABS plastic with various colors is obtained.
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| CN110746898A (en) * | 2019-10-25 | 2020-02-04 | 深圳市象形科技有限公司 | High strength protection film that shocks resistance |
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| CN114133711A (en) * | 2021-12-14 | 2022-03-04 | 长虹美菱股份有限公司 | Stone-like color master batch and preparation method thereof |
| CN114634636B (en) * | 2022-02-22 | 2024-01-02 | 金发科技股份有限公司 | Color master batch with fluorescent moire effect and preparation method and application thereof |
| CN115558234B (en) * | 2022-09-19 | 2024-12-06 | 上海锦湖日丽塑料有限公司 | Flow pattern masterbatch suitable for medium temperature hard plastic injection molding and preparation method thereof |
| CN115716969A (en) * | 2022-11-30 | 2023-02-28 | 珠海格力新材料有限公司 | Natural texture imitating material with stable texture and preparation process thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102617975A (en) * | 2012-04-06 | 2012-08-01 | 广州远华色母厂有限公司 | Marble vision effect color master batch composition for acrylonitrile-butadiene-styrene (ABS) copolymer resin |
| CN102617933A (en) * | 2012-04-06 | 2012-08-01 | 广州远华色母厂有限公司 | Color master batch composition for marble vision effect of polypropylene resin |
| CN103571127A (en) * | 2012-08-03 | 2014-02-12 | 深圳市富恒塑胶新材料有限公司 | Modified PC/ABS (Poly Carbonate)/(Acrylonitrile Butadiene Styrene) with marble strip appearance and preparation method thereof |
| CN107488323A (en) * | 2016-06-13 | 2017-12-19 | 邵建其 | A kind of imitating natural marble grain material shells and its preparation method and application |
| CN108822535A (en) * | 2018-05-31 | 2018-11-16 | 东莞市米辰实业科技有限公司 | A kind of formula and technique for making marble texture |
-
2018
- 2018-08-07 CN CN201810889558.8A patent/CN108976693B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102617975A (en) * | 2012-04-06 | 2012-08-01 | 广州远华色母厂有限公司 | Marble vision effect color master batch composition for acrylonitrile-butadiene-styrene (ABS) copolymer resin |
| CN102617933A (en) * | 2012-04-06 | 2012-08-01 | 广州远华色母厂有限公司 | Color master batch composition for marble vision effect of polypropylene resin |
| CN103571127A (en) * | 2012-08-03 | 2014-02-12 | 深圳市富恒塑胶新材料有限公司 | Modified PC/ABS (Poly Carbonate)/(Acrylonitrile Butadiene Styrene) with marble strip appearance and preparation method thereof |
| CN107488323A (en) * | 2016-06-13 | 2017-12-19 | 邵建其 | A kind of imitating natural marble grain material shells and its preparation method and application |
| CN108822535A (en) * | 2018-05-31 | 2018-11-16 | 东莞市米辰实业科技有限公司 | A kind of formula and technique for making marble texture |
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