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CN108949014A - A kind of high temperature resistant switchgear - Google Patents

A kind of high temperature resistant switchgear Download PDF

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Publication number
CN108949014A
CN108949014A CN201810675717.4A CN201810675717A CN108949014A CN 108949014 A CN108949014 A CN 108949014A CN 201810675717 A CN201810675717 A CN 201810675717A CN 108949014 A CN108949014 A CN 108949014A
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CN
China
Prior art keywords
parts
high temperature
temperature resistant
protective layer
added
Prior art date
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Pending
Application number
CN201810675717.4A
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Chinese (zh)
Inventor
姚军
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhenjiang Yi Bao Electrical Technology Co Ltd
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Zhenjiang Yi Bao Electrical Technology Co Ltd
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Publication date
Application filed by Zhenjiang Yi Bao Electrical Technology Co Ltd filed Critical Zhenjiang Yi Bao Electrical Technology Co Ltd
Priority to CN201810675717.4A priority Critical patent/CN108949014A/en
Publication of CN108949014A publication Critical patent/CN108949014A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/04Polysiloxanes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2227Oxides; Hydroxides of metals of aluminium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2296Oxides; Hydroxides of metals of zinc
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Insulating Materials (AREA)
  • Glass Compositions (AREA)

Abstract

The invention discloses a kind of high temperature resistant switchgears, are related to switchgear technical field.Including cabinet body, cabinet body surface is coated with protective layer, and the chemical constituent and parts by weight of protective layer are as follows: organic siliconresin: 3~5 parts, silica solution: 3~5 parts, kaolin: 1~3 part, mica: 1~2 part, glass powder with low melting point D250:2~3 part, aluminium oxide ceramics: 1~3 part, zinc oxide: 2~3 parts, chrome oxide green: 1~2 part, weight complex acid potassium: 1~2 part, filler: 4~7 parts.The high temperature resistance and corrosion resistance of cabinet body can be improved in protective layer of the invention, improves the service life of switchgear.

Description

A kind of high temperature resistant switchgear
Technical field
The present invention relates to switchgear technical fields, more particularly to a kind of high temperature resistant switchgear.
Background technique
Switchgear is a kind of electrical equipment, is the mster-control centre in circuit, and open-air atmosphere is often arranged in switchgear, Switchgear therein can generate heat, along with extraneous solar exposure, it is likely that cause tank surface temperature higher, at present case Body surface face may be cracked at high temperature using common coating, rise it is swollen, situations such as falling off, further, extraneous rainwater Corrosivity is stronger, and the corrosion resistance of common coating is not good enough, is easy to cause cabinet by seriously corroded, switchgear cabinet uses at present Common coating high temperature resistance and corrosion resistance are poor, substantially reduce the service life of switchgear.
Summary of the invention
The common coating high temperature resistance that is used the technical problem to be solved by the present invention is to current switchgear cabinet and resistance to Corrosive nature is poor, substantially reduces the service life of switchgear.
In order to solve the above technical problems, the present invention provides a kind of high temperature resistant switchgear, including cabinet body, the coating of cabinet body surface There is protective layer, the chemical constituent and parts by weight of protective layer are as follows: organic siliconresin: 3~5 parts, silica solution: 3~5 parts, kaolinite Soil: 1~3 part, mica: 1~2 part, glass powder with low melting point D250:2~3 part, aluminium oxide ceramics: 1~3 part, zinc oxide: 2~3 Part, chrome oxide green: 1~2 part, weight complex acid potassium: 1~2 part, filler: 4~7 parts.
Technical effect: the present invention is arranged one layer of protective layer on the surface of cabinet body and improves the entirety of cabinet body for protecting cabinet body Performance, using organic siliconresin and silica solution as base-material in protective layer, the two can be crosslinked film forming at normal temperature, can tolerate 250- 300 DEG C of high temperature, wherein when temperature is increased to 350 DEG C or more, organic siliconresin can be decomposed, in aluminium oxide ceramics and chromium oxide Under green cooperation, a kind of heat-resisting pottery enamel-like substance is generated, high temperature resistant degree can achieve 400-450 DEG C, can be true The temperature capacity of protective layer is protected, so that the high temperature resistance of cabinet body is improved, in addition, the glass powder with low melting point D250 of addition, 200 When DEG C high temperature, it can start to melt, the bondability of protective layer and cabinet body on the one hand can be improved, protection on the other hand can be improved The compactness of layer, tissue protective layer are corroded by external substance, and the chrome oxide green of addition can also slow down protective layer and be corroded, due to adding The silica solution of the addition added can gradually be dissolved at 400 DEG C, gradually lose the bonding ability with cabinet body, the aluminium oxide pottery of addition Porcelain starts to melt in 400 DEG C of high temperature, substitution silica solution by each component stick together and it is stable be integrated on cabinet body, shape At new coating more resistant to high temperature, 550-600 DEG C of high temperature can tolerate, therefore, the resistance to height of cabinet body can be improved in protective layer of the invention Warm nature energy and corrosion resistance improve the service life of switchgear.
The technical solution that the present invention further limits is: the chemical constituent and parts by weight of protective layer are as follows: organosilicon tree Rouge: 5 parts, silica solution: 5 parts, kaolin: 3 parts, mica: 2 parts, D250:3 parts of glass powder with low melting point, aluminium oxide ceramics: 3 parts, oxygen Change zinc: 3 parts, chrome oxide green: 2 parts, weight complex acid potassium: 2 parts, filler: 7 parts.
Further, the chemical constituent and parts by weight of protective layer are as follows: organic siliconresin: 4 parts, silica solution: 4 parts, high Ridge soil: 2 parts, mica: 1.5 parts, D250:2.5 parts of glass powder with low melting point, aluminium oxide ceramics: 2 parts, zinc oxide: 2.5 parts, chromium oxide It is green: 1.5 parts, weight complex acid potassium: 1.5 parts, filler: 5.5 parts.
A kind of preceding high temperature resistant switchgear, filler includes calcinated argil silicate and AlN, the calcinated argil silicic acid The content of salt and AlN ratio are 1:3.
A kind of preceding high temperature resistant switchgear, the partial size of glass powder with low melting point D250 are 12~15 nanometers.
A kind of preceding high temperature resistant switchgear, the partial size of aluminium oxide ceramics are 11~14 μm.
A kind of preceding high temperature resistant switchgear, the preparation of protective layer the following steps are included:
A, water is added into reaction kettle, organic siliconresin and silica solution is added, while stirring with 550~600r/min high speed dispersion Mixing is obtained after 20~25min;
B, the mixing in step a is added in mixer, is warming up to 55 DEG C, be kneaded 7min, then eutectic is added into mixer Point glass powder D250, is warming up to 300 DEG C, is kneaded 6min, by aluminium oxide ceramics, mica, zinc oxide, chrome oxide green, weight complex acid potassium It is added in mixer with kaolin, is warming up to 450 DEG C, be kneaded 35min, slurry is made;
C, it is added later in ball mill and grinds whether the mixing for testing coating twice reaches requirement, stop grinding after reaching requirement;
D, finished product is obtained with 300~400r/min, 45~55min of uniform stirring with filler tune slurry viscosity.
The beneficial effects of the present invention are:
(1) silica solution added in the present invention is that colloid made of nanoscale SiO2 particle disperses in aqueous solution or solvent is molten Liquid is modified silica solution using zinc oxide, and silica solution after modified can be formed a film with normal temperature cure, and prepared coating makes With temperature generally at 200 DEG C or so, and cooperate organic siliconresin and zinc oxide, protective layer can be improved at 200-250 DEG C High temperature resistant time and thermal stability;
(2) kaolin, the mica being added in the present invention can increase anti-while improving temperature capability as high-temperature adhesives The adhesive force of sheath and cabinet body makes it be not easy to be scratched by external substance furthermore, it is possible to improve the impact resistance degree of protective layer, thus Stable protection cabinet body;
(3) corrosion resistance that the heavy complex acid potassium added in the present invention can cooperate chrome oxide green to further increase protective layer.
Specific embodiment
Embodiment 1: a kind of high temperature resistant switchgear, including cabinet body, cabinet body surface are coated with protective layer, the chemical group of protective layer Divide and parts by weight are as follows: organic siliconresin: 3~5 parts, silica solution: 3~5 parts, kaolin: 1~3 part, mica: 1~2 part, low Melting glass frit D250:2~3 part, aluminium oxide ceramics: 1~3 part, zinc oxide: 2~3 parts, chrome oxide green: 1~2 part, weight complex acid Potassium: 1~2 part, filler: 4~7 parts, the chemical constituent and parts by weight of the protective layer of the present embodiment selection are as follows: organosilicon tree Rouge: 5kg, silica solution: 5kg, kaolin: 3kg, mica: 2kg, glass powder with low melting point D250:3kg, aluminium oxide ceramics: 3kg, oxygen Change zinc: 3kg, chrome oxide green: 2kg, weight complex acid potassium: 2kg, filler: 7kg.
Filler includes calcinated argil silicate and AlN, and the content ratio of calcinated argil silicate and AlN are 1:3, low melting point glass The partial size of glass powder D250 is 12~15 nanometers, and the partial size of aluminium oxide ceramics is 11~14 μm.
The preparation of protective layer the following steps are included:
A, water is added into reaction kettle, organic siliconresin and silica solution is added, while stirring with 550~600r/min high speed dispersion Mixing is obtained after 20~25min;
B, the mixing in step a is added in mixer, is warming up to 55 DEG C, be kneaded 7min, then eutectic is added into mixer Point glass powder D250, is warming up to 300 DEG C, is kneaded 6min, by aluminium oxide ceramics, mica, zinc oxide, chrome oxide green, weight complex acid potassium It is added in mixer with kaolin, is warming up to 450 DEG C, be kneaded 35min, slurry is made;
C, it is added later in ball mill and grinds whether the mixing for testing coating twice reaches requirement, stop grinding after reaching requirement;
D, finished product is obtained with 300~400r/min, 45~55min of uniform stirring with filler tune slurry viscosity.
Embodiment 2: a kind of high temperature resistant switchgear, difference from Example 1 be, the chemical constituent and weight of protective layer Number is as follows: organic siliconresin: 4kg, silica solution: 4kg, kaolin: 2kg, mica: 1.5kg, glass powder with low melting point D250: 2.5kg, aluminium oxide ceramics: 2kg, zinc oxide: 2.5kg, chrome oxide green: 1.5kg, weight complex acid potassium: 1.5kg, filler: 5.5kg.
Embodiment 3: a kind of high temperature resistant switchgear, difference from Example 1 be, the chemical constituent and weight of protective layer Number is as follows: organic siliconresin: 3kg, silica solution: 3kg, kaolin: 1kg, mica: 1kg, glass powder with low melting point D250:2kg, Aluminium oxide ceramics: 1kg, zinc oxide: 2kg, chrome oxide green: 1kg, weight complex acid potassium: 1kg, filler: 4kg.
Test process and result are as follows:
Comparative example: using the protective coating sold in the market;
Protective layer and comparative example prepared by embodiment 1- embodiment 3 are compared into application test, properties are carried out by national standard Measurement, experimental condition and other experimental materials are all the same, and test result is as follows:
As seen from the above table, protective layer prepared by the present invention substantially mentions in terms of high temperature resistance, corrosion resistance and hardness Height, protection cabinet body that can be stable improve the service life of switchgear.
In addition to the implementation, the present invention can also have other embodiments.It is all to use equivalent substitution or equivalent transformation shape At technical solution, fall within the scope of protection required by the present invention.

Claims (7)

1. a kind of high temperature resistant switchgear, including cabinet body, it is characterised in that: the cabinet body surface is coated with protective layer, the protection The chemical constituent and parts by weight of layer are as follows: organic siliconresin: 3~5 parts, silica solution: and 3~5 parts, kaolin: 1~3 part, cloud It is female: 1~2 part, glass powder with low melting point D250:2~3 part, aluminium oxide ceramics: 1~3 part, zinc oxide: 2~3 parts, chrome oxide green: 1 ~2 parts, weight complex acid potassium: 1~2 part, filler: 4~7 parts.
2. a kind of high temperature resistant switchgear according to claim 1, it is characterised in that: the chemical constituent of the protective layer and again It is as follows to measure number: organic siliconresin: 5 parts, silica solution: 5 parts, kaolin: 3 parts, mica: 2 parts, glass powder with low melting point D250:3 Part, aluminium oxide ceramics: 3 parts, zinc oxide: 3 parts, chrome oxide green: 2 parts, weight complex acid potassium: 2 parts, filler: 7 parts.
3. a kind of high temperature resistant switchgear according to claim 1, it is characterised in that: the chemical constituent of the protective layer and again It is as follows to measure number: organic siliconresin: 4 parts, silica solution: 4 parts, kaolin: 2 parts, mica: 1.5 parts, glass powder with low melting point D250: 2.5 parts, aluminium oxide ceramics: 2 parts, zinc oxide: 2.5 parts, chrome oxide green: 1.5 parts, weight complex acid potassium: 1.5 parts, filler: 5.5 parts.
4. a kind of high temperature resistant switchgear according to claim 1, it is characterised in that: the filler includes calcinated argil silicic acid The content ratio of salt and AlN, the calcinated argil silicate and AlN are 1:3.
5. a kind of high temperature resistant switchgear according to claim 1, it is characterised in that: the grain of the glass powder with low melting point D250 Diameter is 12~15 nanometers.
6. a kind of high temperature resistant switchgear according to claim 1, it is characterised in that: the partial size of the aluminium oxide ceramics is 11 ~14 μm.
7. a kind of high temperature resistant switchgear according to claim 1, it is characterised in that: the preparation of the protective layer includes following Step:
A, water is added into reaction kettle, organic siliconresin and silica solution is added, while stirring with 550 ~ 600r/min high speed dispersion Mixing is obtained after 20 ~ 25min;
B, the mixing in step a is added in mixer, is warming up to 55 DEG C, be kneaded 7min, then eutectic is added into mixer Point glass powder D250, is warming up to 300 DEG C, is kneaded 6min, by aluminium oxide ceramics, mica, zinc oxide, chrome oxide green, weight complex acid potassium It is added in mixer with kaolin, is warming up to 450 DEG C, be kneaded 35min, slurry is made;
C, it is added later in ball mill and grinds whether the mixing for testing coating twice reaches requirement, stop grinding after reaching requirement;
D, finished product is obtained with 300 ~ 400r/min, 45 ~ 55min of uniform stirring with filler tune slurry viscosity.
CN201810675717.4A 2018-06-27 2018-06-27 A kind of high temperature resistant switchgear Pending CN108949014A (en)

Priority Applications (1)

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Application Number Priority Date Filing Date Title
CN201810675717.4A CN108949014A (en) 2018-06-27 2018-06-27 A kind of high temperature resistant switchgear

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CN108949014A true CN108949014A (en) 2018-12-07

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111995949A (en) * 2020-07-14 2020-11-27 陈子辉 High-temperature-resistant coating and preparation method thereof
CN114456708A (en) * 2022-02-25 2022-05-10 海鹰空天材料研究院(苏州)有限责任公司 High-temperature-resistant packaging coating and preparation method thereof
CN114836128A (en) * 2022-05-16 2022-08-02 中国科学院长春应用化学研究所 Temperature-indicating luminous coating and preparation method and application thereof
CN116285440A (en) * 2023-02-28 2023-06-23 四川大学 A composite high-entropy alloy reinforced organic coating and its application

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101544855A (en) * 2009-04-24 2009-09-30 景德镇陶瓷学院 Environmental protecting multifunctional coating and its preparing method
CN105315795A (en) * 2015-12-08 2016-02-10 赵建南 Intelligent high-temperature-resistant far infrared conductive heating energy-saving material
CN105368248A (en) * 2015-11-10 2016-03-02 江苏宇恒电气有限公司 High-temperature-resistant low-voltage switchgear cabinet
CN106479355A (en) * 2016-09-29 2017-03-08 广东美的厨房电器制造有限公司 A kind of hydrophobic type anti-settling absorbing material and preparation method thereof
CN106519908A (en) * 2016-11-29 2017-03-22 广西大学 Anticorrosive coating in radiator

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101544855A (en) * 2009-04-24 2009-09-30 景德镇陶瓷学院 Environmental protecting multifunctional coating and its preparing method
CN105368248A (en) * 2015-11-10 2016-03-02 江苏宇恒电气有限公司 High-temperature-resistant low-voltage switchgear cabinet
CN105315795A (en) * 2015-12-08 2016-02-10 赵建南 Intelligent high-temperature-resistant far infrared conductive heating energy-saving material
CN106479355A (en) * 2016-09-29 2017-03-08 广东美的厨房电器制造有限公司 A kind of hydrophobic type anti-settling absorbing material and preparation method thereof
CN106519908A (en) * 2016-11-29 2017-03-22 广西大学 Anticorrosive coating in radiator

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111995949A (en) * 2020-07-14 2020-11-27 陈子辉 High-temperature-resistant coating and preparation method thereof
CN114456708A (en) * 2022-02-25 2022-05-10 海鹰空天材料研究院(苏州)有限责任公司 High-temperature-resistant packaging coating and preparation method thereof
CN114836128A (en) * 2022-05-16 2022-08-02 中国科学院长春应用化学研究所 Temperature-indicating luminous coating and preparation method and application thereof
CN116285440A (en) * 2023-02-28 2023-06-23 四川大学 A composite high-entropy alloy reinforced organic coating and its application
CN116285440B (en) * 2023-02-28 2024-03-15 四川大学 A composite high-entropy alloy reinforced organic coating and its application

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Application publication date: 20181207