CN108948575A - Environment-friendly floor material and preparation method thereof - Google Patents
Environment-friendly floor material and preparation method thereof Download PDFInfo
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- CN108948575A CN108948575A CN201810610631.3A CN201810610631A CN108948575A CN 108948575 A CN108948575 A CN 108948575A CN 201810610631 A CN201810610631 A CN 201810610631A CN 108948575 A CN108948575 A CN 108948575A
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- 239000000463 material Substances 0.000 title claims abstract description 83
- 238000002360 preparation method Methods 0.000 title claims abstract description 23
- 239000000843 powder Substances 0.000 claims abstract description 51
- 239000002699 waste material Substances 0.000 claims abstract description 50
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 46
- 239000006260 foam Substances 0.000 claims abstract description 38
- 239000002994 raw material Substances 0.000 claims abstract description 28
- 239000006087 Silane Coupling Agent Substances 0.000 claims abstract description 24
- 239000011521 glass Substances 0.000 claims abstract description 24
- 239000003365 glass fiber Substances 0.000 claims abstract description 23
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical class O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims abstract description 21
- -1 polyethylene Polymers 0.000 claims abstract description 21
- 235000017166 Bambusa arundinacea Nutrition 0.000 claims abstract description 20
- 235000017491 Bambusa tulda Nutrition 0.000 claims abstract description 20
- 241001330002 Bambuseae Species 0.000 claims abstract description 20
- 235000015334 Phyllostachys viridis Nutrition 0.000 claims abstract description 20
- 239000011425 bamboo Substances 0.000 claims abstract description 20
- 239000003610 charcoal Substances 0.000 claims abstract description 20
- 239000004800 polyvinyl chloride Substances 0.000 claims abstract description 20
- 229920000915 polyvinyl chloride Polymers 0.000 claims abstract description 20
- 239000002245 particle Substances 0.000 claims abstract description 19
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims abstract description 19
- 229920000747 poly(lactic acid) Polymers 0.000 claims abstract description 19
- 229920001610 polycaprolactone Polymers 0.000 claims abstract description 19
- 239000004632 polycaprolactone Substances 0.000 claims abstract description 19
- 239000004626 polylactic acid Substances 0.000 claims abstract description 19
- 239000004698 Polyethylene Substances 0.000 claims abstract description 12
- 229920000573 polyethylene Polymers 0.000 claims abstract description 12
- 239000004359 castor oil Substances 0.000 claims abstract description 11
- 235000019438 castor oil Nutrition 0.000 claims abstract description 11
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims abstract description 11
- 238000007731 hot pressing Methods 0.000 claims description 28
- 238000001035 drying Methods 0.000 claims description 24
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 21
- 239000000377 silicon dioxide Substances 0.000 claims description 21
- 229910021647 smectite Inorganic materials 0.000 claims description 20
- 239000002023 wood Substances 0.000 claims description 20
- 239000000428 dust Substances 0.000 claims description 19
- 239000003963 antioxidant agent Substances 0.000 claims description 18
- 230000003078 antioxidant effect Effects 0.000 claims description 18
- 230000007613 environmental effect Effects 0.000 claims description 18
- 239000003063 flame retardant Substances 0.000 claims description 18
- 239000012760 heat stabilizer Substances 0.000 claims description 18
- 239000000203 mixture Substances 0.000 claims description 18
- 229910052901 montmorillonite Inorganic materials 0.000 claims description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 17
- 238000002156 mixing Methods 0.000 claims description 15
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 14
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 14
- XQVWYOYUZDUNRW-UHFFFAOYSA-N N-Phenyl-1-naphthylamine Chemical compound C=1C=CC2=CC=CC=C2C=1NC1=CC=CC=C1 XQVWYOYUZDUNRW-UHFFFAOYSA-N 0.000 claims description 14
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 14
- 230000000754 repressing effect Effects 0.000 claims description 14
- 238000000227 grinding Methods 0.000 claims description 9
- OBETXYAYXDNJHR-SSDOTTSWSA-M (2r)-2-ethylhexanoate Chemical group CCCC[C@@H](CC)C([O-])=O OBETXYAYXDNJHR-SSDOTTSWSA-M 0.000 claims description 7
- BJELTSYBAHKXRW-UHFFFAOYSA-N 2,4,6-triallyloxy-1,3,5-triazine Chemical compound C=CCOC1=NC(OCC=C)=NC(OCC=C)=N1 BJELTSYBAHKXRW-UHFFFAOYSA-N 0.000 claims description 7
- 235000002918 Fraxinus excelsior Nutrition 0.000 claims description 7
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 7
- 235000011449 Rosa Nutrition 0.000 claims description 7
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 7
- HVVWZTWDBSEWIH-UHFFFAOYSA-N [2-(hydroxymethyl)-3-prop-2-enoyloxy-2-(prop-2-enoyloxymethyl)propyl] prop-2-enoate Chemical compound C=CC(=O)OCC(CO)(COC(=O)C=C)COC(=O)C=C HVVWZTWDBSEWIH-UHFFFAOYSA-N 0.000 claims description 7
- 239000002956 ash Substances 0.000 claims description 7
- 238000001354 calcination Methods 0.000 claims description 7
- 239000008367 deionised water Substances 0.000 claims description 7
- 229910021641 deionized water Inorganic materials 0.000 claims description 7
- 238000007865 diluting Methods 0.000 claims description 7
- 235000019441 ethanol Nutrition 0.000 claims description 7
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 7
- 239000008188 pellet Substances 0.000 claims description 7
- 238000005453 pelletization Methods 0.000 claims description 7
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims description 7
- 238000010792 warming Methods 0.000 claims description 7
- 238000005406 washing Methods 0.000 claims description 7
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 5
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 5
- 239000011734 sodium Substances 0.000 claims description 5
- 229910052708 sodium Inorganic materials 0.000 claims description 5
- SJECZPVISLOESU-UHFFFAOYSA-N 3-trimethoxysilylpropan-1-amine Chemical compound CO[Si](OC)(OC)CCCN SJECZPVISLOESU-UHFFFAOYSA-N 0.000 claims description 4
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 claims description 4
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims description 4
- DCQBZYNUSLHVJC-UHFFFAOYSA-N 3-triethoxysilylpropane-1-thiol Chemical compound CCO[Si](OCC)(OCC)CCCS DCQBZYNUSLHVJC-UHFFFAOYSA-N 0.000 claims description 3
- 239000004114 Ammonium polyphosphate Substances 0.000 claims description 3
- 229910019142 PO4 Inorganic materials 0.000 claims description 3
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 3
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 3
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims description 3
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 3
- 235000019826 ammonium polyphosphate Nutrition 0.000 claims description 3
- 229920001276 ammonium polyphosphate Polymers 0.000 claims description 3
- 239000004202 carbamide Substances 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- 239000010452 phosphate Substances 0.000 claims description 3
- XZTOTRSSGPPNTB-UHFFFAOYSA-N phosphono dihydrogen phosphate;1,3,5-triazine-2,4,6-triamine Chemical compound NC1=NC(N)=NC(N)=N1.OP(O)(=O)OP(O)(O)=O XZTOTRSSGPPNTB-UHFFFAOYSA-N 0.000 claims description 3
- FGHOOJSIEHYJFQ-UHFFFAOYSA-N (2,4-ditert-butylphenyl) dihydrogen phosphite Chemical class CC(C)(C)C1=CC=C(OP(O)O)C(C(C)(C)C)=C1 FGHOOJSIEHYJFQ-UHFFFAOYSA-N 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 claims description 2
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 2
- XFZRQAZGUOTJCS-UHFFFAOYSA-N phosphoric acid;1,3,5-triazine-2,4,6-triamine Chemical compound OP(O)(O)=O.NC1=NC(N)=NC(N)=N1 XFZRQAZGUOTJCS-UHFFFAOYSA-N 0.000 claims description 2
- 235000019260 propionic acid Nutrition 0.000 claims description 2
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 claims description 2
- 210000002268 wool Anatomy 0.000 claims description 2
- ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical compound NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 claims 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- CHJJGSNFBQVOTG-UHFFFAOYSA-N N-methyl-guanidine Natural products CNC(N)=N CHJJGSNFBQVOTG-UHFFFAOYSA-N 0.000 claims 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims 1
- 235000004443 Ricinus communis Nutrition 0.000 claims 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims 1
- 239000005864 Sulphur Substances 0.000 claims 1
- 235000013339 cereals Nutrition 0.000 claims 1
- 238000002485 combustion reaction Methods 0.000 claims 1
- SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Natural products CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 claims 1
- CWAFVXWRGIEBPL-UHFFFAOYSA-N ethoxysilane Chemical compound CCO[SiH3] CWAFVXWRGIEBPL-UHFFFAOYSA-N 0.000 claims 1
- 235000013312 flour Nutrition 0.000 claims 1
- 229910052698 phosphorus Inorganic materials 0.000 claims 1
- 239000011574 phosphorus Substances 0.000 claims 1
- 239000008159 sesame oil Substances 0.000 claims 1
- 235000011803 sesame oil Nutrition 0.000 claims 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims 1
- 229920002554 vinyl polymer Polymers 0.000 claims 1
- 229920003023 plastic Polymers 0.000 abstract description 7
- 239000004033 plastic Substances 0.000 abstract description 7
- 238000004519 manufacturing process Methods 0.000 abstract description 6
- 238000004064 recycling Methods 0.000 abstract description 4
- 230000006835 compression Effects 0.000 abstract description 2
- 238000007906 compression Methods 0.000 abstract description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 abstract 2
- 239000005543 nano-size silicon particle Substances 0.000 abstract 1
- 235000012239 silicon dioxide Nutrition 0.000 abstract 1
- 239000011787 zinc oxide Substances 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 15
- 239000001993 wax Substances 0.000 description 8
- 238000009408 flooring Methods 0.000 description 7
- 239000010410 layer Substances 0.000 description 7
- 230000007797 corrosion Effects 0.000 description 5
- 238000005260 corrosion Methods 0.000 description 5
- 229920005989 resin Polymers 0.000 description 5
- 239000011347 resin Substances 0.000 description 5
- 238000001291 vacuum drying Methods 0.000 description 5
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- 239000004411 aluminium Substances 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 4
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- 238000006243 chemical reaction Methods 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 239000002131 composite material Substances 0.000 description 3
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical group CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 description 3
- 210000004209 hair Anatomy 0.000 description 3
- 230000013011 mating Effects 0.000 description 3
- 229910000077 silane Inorganic materials 0.000 description 3
- LPKCJFLRJWWIDI-UHFFFAOYSA-N (diaminomethylideneamino)phosphonic acid Chemical compound NC(N)=NP(O)(O)=O LPKCJFLRJWWIDI-UHFFFAOYSA-N 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 2
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- 239000004166 Lanolin Substances 0.000 description 2
- 239000004640 Melamine resin Substances 0.000 description 2
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- 230000003712 anti-aging effect Effects 0.000 description 2
- 230000002742 anti-folding effect Effects 0.000 description 2
- 229960000892 attapulgite Drugs 0.000 description 2
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- VSGNNIFQASZAOI-UHFFFAOYSA-L calcium acetate Chemical compound [Ca+2].CC([O-])=O.CC([O-])=O VSGNNIFQASZAOI-UHFFFAOYSA-L 0.000 description 2
- 239000001639 calcium acetate Substances 0.000 description 2
- 235000011092 calcium acetate Nutrition 0.000 description 2
- 229960005147 calcium acetate Drugs 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- BCAARMUWIRURQS-UHFFFAOYSA-N dicalcium;oxocalcium;silicate Chemical compound [Ca+2].[Ca+2].[Ca]=O.[O-][Si]([O-])([O-])[O-] BCAARMUWIRURQS-UHFFFAOYSA-N 0.000 description 2
- 229940039717 lanolin Drugs 0.000 description 2
- 235000019388 lanolin Nutrition 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 229910052625 palygorskite Inorganic materials 0.000 description 2
- 239000010451 perlite Substances 0.000 description 2
- 235000019362 perlite Nutrition 0.000 description 2
- 235000019353 potassium silicate Nutrition 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 230000002035 prolonged effect Effects 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 239000010453 quartz Substances 0.000 description 2
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- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 2
- 235000017557 sodium bicarbonate Nutrition 0.000 description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- 235000019976 tricalcium silicate Nutrition 0.000 description 2
- 229910021534 tricalcium silicate Inorganic materials 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 1
- AOJJSUZBOXZQNB-VTZDEGQISA-N 4'-epidoxorubicin Chemical group O([C@H]1C[C@@](O)(CC=2C(O)=C3C(=O)C=4C=CC=C(C=4C(=O)C3=C(O)C=21)OC)C(=O)CO)[C@H]1C[C@H](N)[C@@H](O)[C@H](C)O1 AOJJSUZBOXZQNB-VTZDEGQISA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 239000010431 corundum Substances 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- 239000011121 hardwood Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- KWUZCAVKPCRJPO-UHFFFAOYSA-N n-ethyl-4-(6-methyl-1,3-benzothiazol-2-yl)aniline Chemical compound C1=CC(NCC)=CC=C1C1=NC2=CC=C(C)C=C2S1 KWUZCAVKPCRJPO-UHFFFAOYSA-N 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 125000002467 phosphate group Chemical group [H]OP(=O)(O[H])O[*] 0.000 description 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
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- 239000010703 silicon Substances 0.000 description 1
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- 230000001954 sterilising effect Effects 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/20—Recycled plastic
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Floor Finish (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
- Dry Formation Of Fiberboard And The Like (AREA)
Abstract
The invention discloses an environment-friendly floor material and a preparation method thereof, relating to the field of floor materials, and comprising raw materials of 30-40 parts of waste polyvinyl chloride foam, 15-22 parts of waste phenolic foam, 22-28 parts of polylactic acid, 8-15 parts of polycaprolactone, 5-10 parts of castor oil, 8-15 parts of sawdust powder, 15-20 parts of waste glass particles, 4-9 parts of nano zinc oxide, 8-15 parts of nano silicon dioxide, 10-18 parts of glass fiber, 8-15 parts of modified montmorillonite powder, 6-12 parts of bamboo charcoal powder, 3-7 parts of polyethylene wax, 1.5-3.5 parts of silane coupling agent and the like in parts by weight; the floor disclosed by the invention takes waste plastics and waste glass as raw materials, has good strength, breaking and compression resistance and flame retardance through the cooperation of the waste plastics and the waste glass and other components, can solve the problems of space occupation and recycling of wastes, reduces the production cost, and is green and environment-friendly.
Description
Technical field
The present invention relates to flooring material fields, and in particular to a kind of Environmental protection floor material and preparation method thereof.
Background technique
Timber floor is from nineteen ninety-five till now after development in more than 20 years, and ground decoration effect warmth is naturally, solid resistance to
With in the traditional understanding of people, timber floor is exactly a kind of floor decorative material, other than material pattern, as not having
What considers reference, and with the raising of people's quality of the life, people are when choosing the floor decorative materials such as floor, other than stressing
It sees, timber floor, which lacks waterproofness, crack resistance and durability, also has become focus of attention.
Pure wooden floor is very poor on the durability of wetness and sunlight, and humidity enables floor expand, and after parching and can receive
Contracting causes the gap between floor to expand, and wearability is weaker, makes floor embrittlement, and flexibility, which weakens, influences service life and glossiness,
And the common disadvantage of always these materials is kept the temperature, while wood floors cause a large amount of trees felling to destroy ecological environments.Therefore
More and more composition floors replace Wood-plastic floor now.
Chinese patent CN1285449A discloses a kind of super-high wear-resistant and water soak resistance Strong floor and its manufacturing method,
Its wearing layer is manufactured gummed paper layer, decorations with melamine resin pure wood pulp paper of the dipping containing 5~30% corundum
Surface layer is so that melamine resin is impregnated containing the paper that 30~35% titanium dioxide needle and hardwood pulp form and is made
At gummed paper layer, sandwich layer is to impregnate twig wood pulp paper and manufactured gummed paper layer with phenolic resin.Above-mentioned technology makes laminated board exist
Wearability or corrosion resistance, crack resistance etc. are improved, but due to preparation method complexity, in actual production also
It is not used widely.
Chinese patent CN103275416A discloses a kind of Wood-plastic floor, including base layer, the material packet of the base layer
PVC powder, plasticizer, Plant Powder and stabilizer are included, repressed method is made, and preparation method is simple, but the flame retardant property of material is not
Enough excellent, there are some potential safety problemss.
Summary of the invention
Aiming at the problems existing in the prior art, the present invention provides a kind of Environmental protection floor materials and preparation method thereof, originally
Floor is invented using waste plastic and scrap glass as raw material, by the mating reaction with other components, there is good intensity, resist
Crushing resistance and anti-flammability are rolled over, and can solve the space hold and recycling problem of waste, reduces production cost, green
Environmental protection.
In order to achieve the above object, the present invention is achieved through the following technical solutions:
A kind of Environmental protection floor material, the raw material including following parts by weight meter:
30-40 parts of waste polyvinyl chloride foam, 15-22 parts of waste phenolic foam, 22-28 parts of polylactic acid, polycaprolactone 8-
15 parts, 5-10 parts of castor oil, 8-15 parts of wood dust, 15-20 parts of post-consumer glass particle, 4-9 parts of nano zine oxide, nanometer titanium dioxide
8-15 parts of silicon, 10-18 parts of glass fibre, 8-15 parts of smectite powder, 6-12 parts of bamboo charcoal powder, 3-7 parts of polyethylene wax, silane are even
Agent 1.5-3.5 parts of connection, 1.2-2.5 parts of antioxidant, 1.2-2.5 parts of heat stabilizer and 3-5 parts of fire retardant.
Preferably, the raw material including following parts by weight meter: 32-38 parts of waste polyvinyl chloride foam, waste phenolic foam 17-
20 parts, 24-26 parts of polylactic acid, 10-13 parts of polycaprolactone, 7-9 parts of castor oil, 10-13 parts of wood dust, post-consumer glass particle 16-
19 parts, 5-8 parts of nano zine oxide, 10-13 parts of nano silica, 12-16 parts of glass fibre, 10-13 parts of smectite powder,
8-10 parts of bamboo charcoal powder, 4-6 parts of polyethylene wax, 2.2-2.8 parts of silane coupling agent, 1.6-2.1 parts of antioxidant, heat stabilizer 1.6-
2.1 parts and fire retardant 3.5-4.5 parts.
Preferably, the raw material including following parts by weight meter: 35 parts of waste polyvinyl chloride foam, 18 parts of waste phenolic foam,
25 parts of polylactic acid, 12 parts of polycaprolactone, 8 parts of castor oil, 12 parts of wood dust, 18 parts of post-consumer glass particle, 7 parts of nano zine oxide,
It is 12 parts of nano silica, 15 parts of glass fibre, 12 parts of smectite powder, 9 parts of bamboo charcoal powder, 5 parts of polyethylene wax, silane coupled
2.6 parts of agent, 1.8 parts of antioxidant, 1.9 parts of heat stabilizer and 4 parts of fire retardant.
Preferably, the smectite powder the preparation method is as follows:
(a) montmorillonite is placed in calcining furnace and is roasted 5 hours under 450-500 degrees Celsius, be sent into grinder and grind, mistake
It after 100-200 mesh, is impregnated 3-5 hours with 18% hydrogen peroxide solution of mass fraction, deionized water washing, dewatered drying is added；
(b) stalk ashes, the 1-2% carbonic acid for being equivalent to its weight 30-40% is added in the montmorillonite handled to step (a)
Hydrogen sodium after mixed at high speed is uniform, is added in grinder, and being ground to grain diameter is 350-450 mesh；
(c) hydroxide of the Rosa Damascana, 5-7% that are equivalent to its weight 2-3% is added in the mixture into step (b)
Aluminium, 1-2% Sodium Laurylsulfate, the pentaerythritol triacrylate of 3-5%, the triallyl cyanurate of 1-2%, 2-3% sheep
Hair rouge, is put into grinder after continuing grinding 30-45 minutes, is put into blender and is stirred with 2000-2500 revs/min
20-25 minutes, stand 5 hours to get.
Preferably, the silane coupling agent is vinyltriethoxysilane, 3- aminopropyl trimethoxysilane and γ-mercapto
One or more of propyl-triethoxysilicane combines.
Preferably, antioxidant four (3- (3, the 5- di-tert-butyl-hydroxy phenyl) propionic acid) pentaerythritol ester, β-(3,
5- di-tert-butyl-hydroxy phenyl) propionic acid octadecanol ester, thio-2 acid dilaurate and three (2,4- di-tert-butyl-phenyls)
The mixing of one or more of phosphite.
Preferably, the heat stabilizer is 2 ethyl hexanoic acid salt, fourth octyl ZDDP and N- phenyl-α-naphthylamine according to mass ratio
2:1:1 mixing composition.
Preferably, the fire retardant be ammonium polyphosphate, phosphoguanidine, phosphoric acid narrow base urea, phosphate, melamine phosphate,
One or more of melamine pyrophosphate.
A kind of preparation method of above-mentioned Novel environmental-protection floor board material is also disclosed in the present invention, specifically, including following step
It is rapid:
(1) waste polyvinyl chloride foam, waste phenolic foam, polylactic acid, polycaprolactone are added in high-speed mixer and are mixed
After closing uniformly, it is added in mixer under 120-125 degrees Celsius, after being kneaded 8-15 minutes, adds twin-screw extrude
Under 150-155 degrees Celsius, extruding pelletization, pellet is placed in material 1 obtained by drying in vacuum oven；
(2) post-consumer glass particle is impregnated 2 hours in 10% sulfuric acid solution, after washes clean, continuously adds 10%
Sodium hydroxide solution in impregnate 2 hours, washed with clear water to neutrality, after drying, be put into ball mill and grind, cross 300-
After 400 meshes, it is added with wood dust, nano zine oxide, nano silica, glass fibre, smectite powder, bamboo charcoal powder high
It is uniformly mixed in fast mixing machine；
(3) after by silane coupling agent and ethyl alcohol, acetone according to mass ratio 1:3:7 mixed diluting, it is slowly dropped into step (2) system
In the mixture obtained, it is warming up to 80-90 degrees Celsius, after being stirred 20-25 minutes with 1200-1500 revs/min of speed, is put
Enter in vacuum oven under conditions of 80-90 degrees Celsius, dries 5 hours, be cooled to room temperature, obtain material 2；
(4) material 1 and material 3 and remaining raw material are added in high-speed mixer after mixing, are put into mold
Hot pressing is carried out, 150-158 degrees Celsius of press temperature, hot pressing pressure 40-45MPa, demoulding is cooled to room temperature to get the environmental protection
Flooring material.
Preferably, the hot pressing mode in the step (4) is first preheating of mixed material 2 minutes in mold, and hot repressing 1 divides
Clock opens mold upper cover and deflates 5 seconds, continues hot pressing 1 minute, then deflate 5 seconds, last hot repressing 5 minutes.
The present invention have it is following the utility model has the advantages that
(1) floor of the present invention, by the mating reaction with other components, has using waste plastic and scrap glass as raw material
Good intensity, anti-folding and anti-pressing and anti-flammability, and can solve the space hold and recycling problem of waste, it reduces
Production cost, it is environmentally protective.
(2) nano silica is added in raw material of the present invention, since nano silica granularity is small, is filled into resin,
Resin can be made to become finer and close, its intensity, toughness, waterproof performance and anti-aging property can be improved, prolonged so as to improve material
Stretch rate, wearability and the finish for improving material surface.
(3) proportional glass fibre and wood dust are added in the present invention, the crack resistance and corrosion resistant for improving material can be enhanced
Corrosion, while modified modified montmorillonite powder can effectively enhance the intensity and mechanical shock resistance on floor, bamboo charcoal powder has removal
Peculiar smell, the function of sterilization can effectively remove the peculiar smell in resin floor.
Specific embodiment
Below with reference to embodiment, further description of the specific embodiments of the present invention, and following embodiment is only used for more
Technical solution of the present invention is clearly demonstrated, and not intended to limit the protection scope of the present invention.
Embodiment 1
A kind of Environmental protection floor material, the raw material including following parts by weight meter:
30 parts of waste polyvinyl chloride foam, 15 parts of waste phenolic foam, 22 parts of polylactic acid, 8 parts of polycaprolactone, castor oil 5
Part, is modified 8 parts of wood dust, 15 parts of post-consumer glass particle, 4 parts of nano zine oxide, 8 parts of nano silica, 10 parts of glass fibre
8 parts of montmorillonite powder, 6 parts of bamboo charcoal powder, 3 parts of polyethylene wax, 1.5 parts of silane coupling agent, 1.2 parts of antioxidant, 1.2 parts of heat stabilizer and
3 parts of fire retardant.
Smectite powder the preparation method is as follows:
(a) montmorillonite is placed in calcining furnace and is roasted 5 hours under 450 degrees Celsius, be sent into grinder and grind, cross 100
It after mesh, is impregnated 3-5 hours with 18% hydrogen peroxide solution of mass fraction, deionized water washing, dewatered drying is added；
(b) stalk ashes, 1% sodium bicarbonate for being equivalent to its weight 30% is added in the montmorillonite handled to step (a),
It after mixed at high speed is uniform, is added in grinder, being ground to grain diameter is 350 mesh；
(c) in the mixture into step (b) be added be equivalent to its weight 2% Rosa Damascana, 5% aluminium hydroxide,
1% Sodium Laurylsulfate, 3% pentaerythritol triacrylate, 1% triallyl cyanurate, 2% lanolin, are put into and grind
It after continuing grinding in grinding machine 30 minutes, is put into blender and is stirred 20 minutes with 2000 revs/min, stand 5 hours, i.e.,
?.
Silane coupling agent is vinyltriethoxysilane.
Antioxidant four (3- (3,5- di-tert-butyl-hydroxy phenyl) propionic acid) pentaerythritol ester.
Heat stabilizer is 2 ethyl hexanoic acid salt, fourth octyl ZDDP and N- phenyl-α-naphthylamine according to mass ratio 2:1:1 mixing group
At.
Fire retardant is ammonium polyphosphate.
The preparation method of Novel environmental-protection floor board material in the present embodiment, specifically, comprising the following steps:
(1) waste polyvinyl chloride foam, waste phenolic foam, polylactic acid, polycaprolactone are added in high-speed mixer and are mixed
After closing uniformly, it is added in mixer at one hundred and twenty degrees centigrade, after being kneaded 8 minutes, adds twin-screw extrude at 150 degrees Celsius
Under, extruding pelletization, pellet is placed in material 1 obtained by drying in vacuum oven；
(2) post-consumer glass particle is impregnated 2 hours in 10% sulfuric acid solution, after washes clean, continuously adds 10%
Sodium hydroxide solution in impregnate 2 hours, washed with clear water to neutrality, after drying, be put into ball mill and grind, cross 300 mesh
After sieve, high speed is added and mixes with wood dust, nano zine oxide, nano silica, glass fibre, smectite powder, bamboo charcoal powder
It is uniformly mixed in conjunction machine；
(3) after by silane coupling agent and ethyl alcohol, acetone according to mass ratio 1:3:7 mixed diluting, it is slowly dropped into step (2) system
In the mixture obtained, 80 degrees Celsius are warming up to, is stirred after twenty minutes with 1200 revs/min of speed, vacuum drying is put into
In case under conditions of 80 degrees Celsius, dries 5 hours, be cooled to room temperature, obtain material 2；
(4) material 1 and material 3 and remaining raw material are added in high-speed mixer after mixing, are put into mold
Hot pressing is carried out, 150 degrees Celsius of press temperature, hot pressing pressure 40MPa, demoulding is cooled to room temperature to get the environmental protection flooring board
Material.
Hot pressing mode in step (4) is that mold hot repressing 1 minute, is first opened in preheating of mixed material 2 minutes in mold
Upper cover is deflated 5 seconds, is continued hot pressing 1 minute, then deflate 5 seconds, last hot repressing 5 minutes.
Embodiment 2
A kind of Environmental protection floor material, the raw material including following parts by weight meter:
40 parts of waste polyvinyl chloride foam, 22 parts of waste phenolic foam, 28 parts of polylactic acid, 15 parts of polycaprolactone, castor oil
10 parts, 15 parts of wood dust, 20 parts of post-consumer glass particle, 9 parts of nano zine oxide, 15 parts of nano silica, 18 parts of glass fibre,
15 parts of smectite powder, 12 parts of bamboo charcoal powder, 7 parts of polyethylene wax, 3.5 parts of silane coupling agent, 2.5 parts of antioxidant, heat stabilizer
2.5 parts and 5 parts of fire retardant.
Smectite powder the preparation method is as follows:
(a) montmorillonite is placed in calcining furnace and is roasted 5 hours under 500 degrees Celsius, be sent into grinder and grind, cross 200
It after mesh, is impregnated 5 hours with 18% hydrogen peroxide solution of mass fraction, deionized water washing, dewatered drying is added；
(b) stalk ashes, 2% sodium bicarbonate for being equivalent to its weight 40% is added in the montmorillonite handled to step (a),
It after mixed at high speed is uniform, is added in grinder, being ground to grain diameter is 450 mesh；
(c) in the mixture into step (b) be added be equivalent to its weight 3% Rosa Damascana, 7% aluminium hydroxide,
2% Sodium Laurylsulfate, 5% pentaerythritol triacrylate, 2% triallyl cyanurate, 3% lanolin, are put into and grind
It after continuing grinding in grinding machine 45 minutes, is put into blender and is stirred 25 minutes with 2500 revs/min, stand 5 hours, i.e.,
?.
Silane coupling agent is 3- aminopropyl trimethoxysilane.
Antioxidant β-(3,5- di-tert-butyl-hydroxy phenyl) propionic acid octadecanol ester.
Heat stabilizer is 2 ethyl hexanoic acid salt, fourth octyl ZDDP and N- phenyl-α-naphthylamine according to mass ratio 2:1:1 mixing group
At.
Fire retardant is phosphoguanidine.
The preparation method of Novel environmental-protection floor board material in the present embodiment, specifically, comprising the following steps:
(1) waste polyvinyl chloride foam, waste phenolic foam, polylactic acid, polycaprolactone are added in high-speed mixer and are mixed
After closing uniformly, it is added in mixer under 125 degrees Celsius, after being kneaded 15 minutes, adds twin-screw extrude at 155 degrees Celsius
Under, extruding pelletization, pellet is placed in material 1 obtained by drying in vacuum oven；
(2) post-consumer glass particle is impregnated 2 hours in 10% sulfuric acid solution, after washes clean, continuously adds 10%
Sodium hydroxide solution in impregnate 2 hours, washed with clear water to neutrality, after drying, be put into ball mill and grind, cross 400 mesh
After sieve, high speed is added and mixes with wood dust, nano zine oxide, nano silica, glass fibre, smectite powder, bamboo charcoal powder
It is uniformly mixed in conjunction machine；
(3) after by silane coupling agent and ethyl alcohol, acetone according to mass ratio 1:3:7 mixed diluting, it is slowly dropped into step (2) system
In the mixture obtained, 90 degrees Celsius are warming up to, after being stirred 25 minutes with 1500 revs/min of speed, is put into vacuum drying
In case under conditions of 90 degrees Celsius, dries 5 hours, be cooled to room temperature, obtain material 2；
(4) material 1 and material 3 and remaining raw material are added in high-speed mixer after mixing, are put into mold
Hot pressing is carried out, 158 degrees Celsius of press temperature, hot pressing pressure 45MPa, demoulding is cooled to room temperature to get the environmental protection flooring board
Material.
Hot pressing mode in step (4) is that mold hot repressing 1 minute, is first opened in preheating of mixed material 2 minutes in mold
Upper cover is deflated 5 seconds, is continued hot pressing 1 minute, then deflate 5 seconds, last hot repressing 5 minutes.
Embodiment 3
A kind of Environmental protection floor material, the raw material including following parts by weight meter:
32 parts of waste polyvinyl chloride foam, 17 parts of waste phenolic foam, 24 parts of polylactic acid, 10 parts of polycaprolactone, castor oil 7
Part, 12 parts of glass fibre, changes 10 parts of wood dust, 16 parts of post-consumer glass particle, 5 parts of nano zine oxide, 10 parts of nano silica
Property 10 parts of montmorillonite powder, 8 parts of bamboo charcoal powder, 4 parts of polyethylene wax, 2.2 parts of silane coupling agent, 1.6 parts of antioxidant, heat stabilizer 1.6
Part and 3.5 parts of fire retardant.
Smectite powder the preparation method is as follows:
(a) montmorillonite is placed in calcining furnace and is roasted 5 hours under 460 degrees Celsius, be sent into grinder and grind, cross 120
It after mesh, is impregnated 3.5 hours with 18% hydrogen peroxide solution of mass fraction, deionized water washing, dewatered drying is added；
(b) stalk ashes, the 1-2% bicarbonate for being equivalent to its weight 34% is added in the montmorillonite handled to step (a)
Sodium after mixed at high speed is uniform, is added in grinder, and being ground to grain diameter is 380 mesh；
(c) hydroxide of the Rosa Damascana, 5.5% that are equivalent to its weight 2.4% is added in the mixture into step (b)
Aluminium, 1.5% Sodium Laurylsulfate, 3.5% pentaerythritol triacrylate, the triallyl cyanurate of 1-2%, 2-3% sheep
Hair rouge, is put into grinder after continuing grinding 38 minutes, is put into blender and is stirred 22 minutes with 2200 revs/min, quiet
Set 5 hours to get.
Silane coupling agent is gamma-mercaptopropyltriethoxysilane.
Antioxidant tetrathio dipropionic acid dilaurate.
Heat stabilizer is 2 ethyl hexanoic acid salt, fourth octyl ZDDP and N- phenyl-α-naphthylamine according to mass ratio 2:1:1 mixing group
At.
Fire retardant is that phosphoric acid narrows base urea.
The preparation method of Novel environmental-protection floor board material in the present embodiment, specifically, comprising the following steps:
(1) waste polyvinyl chloride foam, waste phenolic foam, polylactic acid, polycaprolactone are added in high-speed mixer and are mixed
After closing uniformly, it is added in mixer under 123 degrees Celsius, is kneaded after ten minutes, adds twin-screw extrude at 152 degrees Celsius
Under, extruding pelletization, pellet is placed in material 1 obtained by drying in vacuum oven；
(2) post-consumer glass particle is impregnated 2 hours in 10% sulfuric acid solution, after washes clean, continuously adds 10%
Sodium hydroxide solution in impregnate 2 hours, washed with clear water to neutrality, after drying, be put into ball mill and grind, cross 330 mesh
After sieve, high speed is added and mixes with wood dust, nano zine oxide, nano silica, glass fibre, smectite powder, bamboo charcoal powder
It is uniformly mixed in conjunction machine；
(3) after by silane coupling agent and ethyl alcohol, acetone according to mass ratio 1:3:7 mixed diluting, it is slowly dropped into step (2) system
In the mixture obtained, 85 degrees Celsius are warming up to, after being stirred 22 minutes with 1300 revs/min of speed, is put into vacuum drying
In case under conditions of 83 degrees Celsius, dries 5 hours, be cooled to room temperature, obtain material 2；
(4) material 1 and material 3 and remaining raw material are added in high-speed mixer after mixing, are put into mold
Hot pressing is carried out, 153 degrees Celsius of press temperature, hot pressing pressure 42MPa, demoulding is cooled to room temperature to get the environmental protection flooring board
Material.
Hot pressing mode in step (4) is that mold hot repressing 1 minute, is first opened in preheating of mixed material 2 minutes in mold
Upper cover is deflated 5 seconds, is continued hot pressing 1 minute, then deflate 5 seconds, last hot repressing 5 minutes.
Embodiment 4
A kind of Environmental protection floor material, the raw material including following parts by weight meter:
38 parts of waste polyvinyl chloride foam, 20 parts of waste phenolic foam, 26 parts of polylactic acid, 13 parts of polycaprolactone, castor oil 9
Part, 16 parts of glass fibre, changes 13 parts of wood dust, 19 parts of post-consumer glass particle, 8 parts of nano zine oxide, 13 parts of nano silica
Property 13 parts of montmorillonite powder, 10 parts of bamboo charcoal powder, 6 parts of polyethylene wax, 2.8 parts of silane coupling agent, 2.1 parts of antioxidant, heat stabilizer 2.1
Part and 4.5 parts of fire retardant.
Smectite powder the preparation method is as follows:
(a) montmorillonite is placed in calcining furnace and is roasted 5 hours under 480 degrees Celsius, be sent into grinder and grind, cross 160
It after mesh, is impregnated 4 hours with 18% hydrogen peroxide solution of mass fraction, deionized water washing, dewatered drying is added；
(b) stalk ashes, the 1-2% bicarbonate for being equivalent to its weight 36% is added in the montmorillonite handled to step (a)
Sodium after mixed at high speed is uniform, is added in grinder, and being ground to grain diameter is 400 mesh；
(c) hydroxide of the Rosa Damascana, 5.8% that are equivalent to its weight 2.6% is added in the mixture into step (b)
Aluminium, 1.5% Sodium Laurylsulfate, 4% pentaerythritol triacrylate, 1.5% triallyl cyanurate, 2.5% wool
Rouge is put into grinder after continuing grinding 36 minutes, is put into blender and is stirred 23 minutes with 2200 revs/min, stands 5
Hour to get.
Silane coupling agent is vinyltriethoxysilane, 3- aminopropyl trimethoxysilane and γ-three ethoxy of mercapto propyl
One or more of base silane combines.
Antioxidant three (2,4- di-tert-butyl-phenyl) phosphite.
Heat stabilizer is 2 ethyl hexanoic acid salt, fourth octyl ZDDP and N- phenyl-α-naphthylamine according to mass ratio 2:1:1 mixing group
At.
Fire retardant is phosphate.
The preparation method of Novel environmental-protection floor board material in the present embodiment, specifically, comprising the following steps:
(1) waste polyvinyl chloride foam, waste phenolic foam, polylactic acid, polycaprolactone are added in high-speed mixer and are mixed
After closing uniformly, it is added in mixer under 121 degrees Celsius, is kneaded after ten minutes, adds twin-screw extrude at 152 degrees Celsius
Under, extruding pelletization, pellet is placed in material 1 obtained by drying in vacuum oven；
(2) post-consumer glass particle is impregnated 2 hours in 10% sulfuric acid solution, after washes clean, continuously adds 10%
Sodium hydroxide solution in impregnate 2 hours, washed with clear water to neutrality, after drying, be put into ball mill and grind, cross 360 mesh
After sieve, high speed is added and mixes with wood dust, nano zine oxide, nano silica, glass fibre, smectite powder, bamboo charcoal powder
It is uniformly mixed in conjunction machine；
(3) after by silane coupling agent and ethyl alcohol, acetone according to mass ratio 1:3:7 mixed diluting, it is slowly dropped into step (2) system
In the mixture obtained, 86 degrees Celsius are warming up to, after being stirred 21 minutes with 1400 revs/min of speed, is put into vacuum drying
In case under conditions of 88 degrees Celsius, dries 5 hours, be cooled to room temperature, obtain material 2；
(4) material 1 and material 3 and remaining raw material are added in high-speed mixer after mixing, are put into mold
Hot pressing is carried out, 156 degrees Celsius of press temperature, hot pressing pressure 44MPa, demoulding is cooled to room temperature to get the environmental protection flooring board
Material.
Hot pressing mode in step (4) is that mold hot repressing 1 minute, is first opened in preheating of mixed material 2 minutes in mold
Upper cover is deflated 5 seconds, is continued hot pressing 1 minute, then deflate 5 seconds, last hot repressing 5 minutes.
Embodiment 5
A kind of Environmental protection floor material, the raw material including following parts by weight meter:
35 parts of waste polyvinyl chloride foam, 18 parts of waste phenolic foam, 25 parts of polylactic acid, 12 parts of polycaprolactone, castor oil 8
Part, 15 parts of glass fibre, changes 12 parts of wood dust, 18 parts of post-consumer glass particle, 7 parts of nano zine oxide, 12 parts of nano silica
Property 12 parts of montmorillonite powder, 9 parts of bamboo charcoal powder, 5 parts of polyethylene wax, 2.6 parts of silane coupling agent, 1.8 parts of antioxidant, heat stabilizer 1.9
Part and 4 parts of fire retardant.
Smectite powder the preparation method is as follows:
(a) montmorillonite is placed in calcining furnace and is roasted 5 hours under 490 degrees Celsius, be sent into grinder and grind, cross 100-
It after 200 meshes, is impregnated 4.5 hours with 18% hydrogen peroxide solution of mass fraction, deionized water washing, dewatered drying is added；
(b) stalk ashes, the 1-2% bicarbonate for being equivalent to its weight 38% is added in the montmorillonite handled to step (a)
Sodium after mixed at high speed is uniform, is added in grinder, and being ground to grain diameter is 430 mesh；
(c) hydroxide of the Rosa Damascana, 6.2% that are equivalent to its weight 2.8% is added in the mixture into step (b)
Aluminium, 1.6% Sodium Laurylsulfate, 4.8% pentaerythritol triacrylate, 1.5% triallyl cyanurate, 2.7% sheep
Hair rouge, is put into grinder after continuing grinding 42 minutes, is put into blender and is stirred 24 minutes with 2400 revs/min, quiet
Set 5 hours to get.
Silane coupling agent is gamma-mercaptopropyltriethoxysilane.
Antioxidant four (3- (3,5- di-tert-butyl-hydroxy phenyl) propionic acid) pentaerythritol ester.
Heat stabilizer is 2 ethyl hexanoic acid salt, fourth octyl ZDDP and N- phenyl-α-naphthylamine according to mass ratio 2:1:1 mixing group
At.
Fire retardant is melamine pyrophosphate.
The preparation method of Novel environmental-protection floor board material in the present embodiment, specifically, comprising the following steps:
(1) waste polyvinyl chloride foam, waste phenolic foam, polylactic acid, polycaprolactone are added in high-speed mixer and are mixed
After closing uniformly, it is added in mixer under 124 degrees Celsius, after being kneaded 13 minutes, adds twin-screw extrude at 153 degrees Celsius
Under, extruding pelletization, pellet is placed in material 1 obtained by drying in vacuum oven；
(2) post-consumer glass particle is impregnated 2 hours in 10% sulfuric acid solution, after washes clean, continuously adds 10%
Sodium hydroxide solution in impregnate 2 hours, washed with clear water to neutrality, after drying, be put into ball mill and grind, cross 380 mesh
After sieve, high speed is added and mixes with wood dust, nano zine oxide, nano silica, glass fibre, smectite powder, bamboo charcoal powder
It is uniformly mixed in conjunction machine；
(3) after by silane coupling agent and ethyl alcohol, acetone according to mass ratio 1:3:7 mixed diluting, it is slowly dropped into step (2) system
In the mixture obtained, 88 degrees Celsius are warming up to, after being stirred 23 minutes with 1400 revs/min of speed, is put into vacuum drying
In case under conditions of 88 degrees Celsius, dries 5 hours, be cooled to room temperature, obtain material 2；
(4) material 1 and material 3 and remaining raw material are added in high-speed mixer after mixing, are put into mold
Hot pressing is carried out, 156 degrees Celsius of press temperature, hot pressing pressure 43MPa, demoulding is cooled to room temperature to get the environmental protection flooring board
Material.
Hot pressing mode in step (4) is that mold hot repressing 1 minute, is first opened in preheating of mixed material 2 minutes in mold
Upper cover is deflated 5 seconds, is continued hot pressing 1 minute, then deflate 5 seconds, last hot repressing 5 minutes.
Comparative example 1
A kind of composite floor board, the raw material including following parts by weight: 6.5 parts of expanded perlite, 11 parts of attapulgite, bauxite
8 parts, 10.5 parts of tricalcium silicate, 8 parts of glass fibre, 6.5 parts of acrylic resin, 8 parts of quartz, 9 parts of calcium acetate, 15 parts of waterglass
With water 15.
A kind of preparation method of composite floor board, comprising the following steps:
(1) each raw material is weighed according to the parts by weight of above-mentioned raw materials；
(2) expanded perlite, attapulgite, bauxite, tricalcium silicate, glass fibre, quartz, calcium acetate are added high
It is uniformly mixed in fast blender；
(3) it is successively slowly added to acrylic resin, water and waterglass in the mixture in step (2), with 800-1000
Rev/min speed be stirred 20-25 minutes；
(4) it by the mixture injection moulding mold in step (3), is press-formed to get molding mass；
(5) molding mass in step (4) is dried, drying temperature is 80 degrees Celsius, and drying time is 6 hours, i.e.,
?.
Environmental protection floor made from embodiment 1-5 and composite floor board made from comparative example 1 are tested for the property, it is as a result as follows
Table 1:
| Index | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Comparative example 1 |
| Flexural strength (MPa) | 47.5 | 52.9 | 49.6 | 53.5 | 56.2 | 31.2 |
| Compression strength (MPa) | 108.2 | 109.6 | 106.3 | 100.5 | 107.9 | 82.6 |
| Crack index | 1.1 | 0.8 | 0.9 | 1.0 | 0.9 | 1.6 |
| Anti-flammability | B1 | B1 | B1 | B1 | B1 | B1 |
Can be seen that from upper 1 data of table the invention has the following advantages that
(1) floor of the present invention, by the mating reaction with other components, has using waste plastic and scrap glass as raw material
Good intensity, anti-folding and anti-pressing and anti-flammability, and can solve the space hold and recycling problem of waste, it reduces
Production cost, it is environmentally protective.
(2) nano silica is added in raw material of the present invention, since nano silica granularity is small, is filled into resin,
Resin can be made to become finer and close, its intensity, toughness, waterproof performance and anti-aging property can be improved, prolonged so as to improve material
Stretch rate, wearability and the finish for improving material surface.
(3) proportional glass fibre and wood dust are added in the present invention, the crack resistance and corrosion resistant for improving material can be enhanced
Corrosion, while modified modified montmorillonite powder can effectively enhance the intensity and mechanical shock resistance on floor.
The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention, although referring to aforementioned reality
Applying example, invention is explained in detail, for those skilled in the art, still can be to aforementioned each implementation
Technical solution documented by example is modified or equivalent replacement of some of the technical features.It is all in essence of the invention
Within mind and principle, any modification, equivalent replacement, improvement and so on be should all be included in the protection scope of the present invention.
Claims (10)
1. a kind of Novel environmental-protection floor board material, which is characterized in that the raw material including following parts by weight meter: waste polyvinyl chloride foam
30-40 parts, 15-22 parts of waste phenolic foam, 22-28 parts of polylactic acid, 8-15 parts of polycaprolactone, 5-10 parts of castor oil, wood dust
8-15 parts, 15-20 parts of post-consumer glass particle, 4-9 parts of nano zine oxide, 8-15 parts of nano silica, glass fibre 10-18
Part, 8-15 parts of smectite powder, 6-12 parts of bamboo charcoal powder, 3-7 parts of polyethylene wax, 1.5-3.5 parts of silane coupling agent, antioxidant
1.2-2.5 parts, 1.2-2.5 parts of heat stabilizer and 3-5 parts of fire retardant.
2. Novel environmental-protection floor board material according to claim 1, which is characterized in that the raw material including following parts by weight meter:
32-38 parts of waste polyvinyl chloride foam, 17-20 parts of waste phenolic foam, 24-26 parts of polylactic acid, 10-13 parts of polycaprolactone, castor
7-9 parts of sesame oil, 10-13 parts of wood dust, 16-19 parts of post-consumer glass particle, 5-8 parts of nano zine oxide, nano silica 10-13
Part, 12-16 parts of glass fibre, 10-13 parts of smectite powder, 8-10 parts of bamboo charcoal powder, 4-6 parts of polyethylene wax, silane coupling agent
2.2-2.8 parts, 1.6-2.1 parts of antioxidant, 1.6-2.1 parts of heat stabilizer and 3.5-4.5 parts of fire retardant.
3. Novel environmental-protection floor board material according to claim 1, which is characterized in that the raw material including following parts by weight meter:
35 parts of waste polyvinyl chloride foam, 18 parts of waste phenolic foam, 25 parts of polylactic acid, 12 parts of polycaprolactone, 8 parts of castor oil, sawdust
12 parts of powder, 18 parts of post-consumer glass particle, 7 parts of nano zine oxide, 12 parts of nano silica, 15 parts of glass fibre, modified cover take off
12 parts of mountain flour, 9 parts of bamboo charcoal powder, 5 parts of polyethylene wax, 2.6 parts of silane coupling agent, 1.8 parts of antioxidant, 1.9 parts of heat stabilizer and resistance
4 parts of agent of combustion.
4. Novel environmental-protection floor board material according to claim 1, which is characterized in that the preparation side of the smectite powder
Method is as follows:
(a) montmorillonite is placed in calcining furnace and is roasted 5 hours under 450-500 degrees Celsius, be sent into grinder and grind, cross 100-
It after 200 meshes, is impregnated 3-5 hours with 18% hydrogen peroxide solution of mass fraction, deionized water washing, dewatered drying is added；
(b) stalk ashes, the 1-2% bicarbonate for being equivalent to its weight 30-40% is added in the montmorillonite handled to step (a)
Sodium after mixed at high speed is uniform, is added in grinder, and being ground to grain diameter is 350-450 mesh；
(c) be added in the mixture into step (b) be equivalent to the Rosa Damascana of its weight 2-3%, 5-7% aluminium hydroxide,
1-2% Sodium Laurylsulfate, the pentaerythritol triacrylate of 3-5%, the triallyl cyanurate of 1-2%, 2-3% wool
Rouge is put into grinder after continuing grinding 30-45 minutes, is put into blender and is stirred 20- with 2000-2500 revs/min
25 minutes, stand 5 hours to get.
5. Novel environmental-protection floor board material according to claim 1, which is characterized in that the silane coupling agent is vinyl three
One or more of Ethoxysilane, 3- aminopropyl trimethoxysilane and gamma-mercaptopropyltriethoxysilane combine.
6. Novel environmental-protection floor board material according to claim 1, which is characterized in that four (3- (3,5- bis- uncles of antioxidant
Butyl -4- hydroxy phenyl) propionic acid) pentaerythritol ester, β-(3,5- di-tert-butyl-hydroxy phenyl) propionic acid octadecanol ester, sulphur
It is mixed for one or more of dipropionic acid dilaurate and three (2,4- di-tert-butyl-phenyl) phosphites.
7. Novel environmental-protection floor board material according to claim 1, which is characterized in that the heat stabilizer is 2 ethyl hexanoic acid
Salt, fourth octyl ZDDP and N- phenyl-α-naphthylamine are mixed according to mass ratio 2:1:1 and are formed.
8. Novel environmental-protection floor board material according to claim 1, which is characterized in that the fire retardant is ammonium polyphosphate, phosphorus
Sour guanidine, phosphoric acid narrow one or more of base urea, phosphate, melamine phosphate, melamine pyrophosphate.
9. a kind of preparation method of such as described in any item Novel environmental-protection floor board materials of claim 1-8, which is characterized in that including
Following steps:
(1) waste polyvinyl chloride foam, waste phenolic foam, polylactic acid, polycaprolactone are added in high-speed mixer and are mixed
After even, it is added in mixer under 120-125 degrees Celsius, after being kneaded 8-15 minutes, adds twin-screw extrude in 150-155
Under degree Celsius, extruding pelletization, pellet is placed in material 1 obtained by drying in vacuum oven；
(2) post-consumer glass particle is impregnated 2 hours in 10% sulfuric acid solution, after washes clean, continuously adds 10% hydrogen
It is impregnated 2 hours in sodium hydroxide solution, is washed with clear water to neutrality, after drying, be put into ball mill and grind, cross 300-400 mesh
After sieve, high speed is added and mixes with wood dust, nano zine oxide, nano silica, glass fibre, smectite powder, bamboo charcoal powder
It is uniformly mixed in conjunction machine；
(3) after by silane coupling agent and ethyl alcohol, acetone according to mass ratio 1:3:7 mixed diluting, it is obtained to be slowly dropped into step (2)
In mixture, it is warming up to 80-90 degrees Celsius, after being stirred 20-25 minutes with 1200-1500 revs/min of speed, is put into true
In empty drying box under conditions of 80-90 degrees Celsius, dries 5 hours, be cooled to room temperature, obtain material 2；
(4) material 1 and material 3 and remaining raw material are added in high-speed mixer after mixing, are put into mold and carry out
Hot pressing, 150-158 degrees Celsius of press temperature, hot pressing pressure 40-45MPa, demoulding is cooled to room temperature to get the Environmental protection floor
Material.
10. the preparation method of Novel environmental-protection floor board material according to claim 9, which is characterized in that in the step (4)
Hot pressing mode be first hot repressing 1 minute preheating of mixed material 2 minutes in mold, open mold upper cover and deflate 5 seconds, continue
Hot pressing 1 minute, then deflate 5 seconds, last hot repressing 5 minutes.
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| CN201810610631.3A CN108948575A (en) | 2018-06-14 | 2018-06-14 | Environment-friendly floor material and preparation method thereof |
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| CN116140330A (en) * | 2023-04-10 | 2023-05-23 | 重庆鼎华电脑配件有限公司 | Dry-method mould-pressing environment-friendly composite tray and process |
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Application publication date: 20181207 |