CN108947833A - A kind of environmental type light emitting composition - Google Patents
A kind of environmental type light emitting composition Download PDFInfo
- Publication number
- CN108947833A CN108947833A CN201810856186.9A CN201810856186A CN108947833A CN 108947833 A CN108947833 A CN 108947833A CN 201810856186 A CN201810856186 A CN 201810856186A CN 108947833 A CN108947833 A CN 108947833A
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- Prior art keywords
- parts
- light emitting
- type light
- environmental type
- emitting composition
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/34—Esters of acyclic saturated polycarboxylic acids having an esterified carboxyl group bound to an acyclic carbon atom
- C07C69/36—Oxalic acid esters
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01K—ANIMAL HUSBANDRY; AVICULTURE; APICULTURE; PISCICULTURE; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
- A01K93/00—Floats for angling, with or without signalling devices
- A01K93/02—Floats for angling, with or without signalling devices with signalling devices
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
- C07C15/40—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals
- C07C15/56—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals polycyclic condensed
- C07C15/60—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals polycyclic condensed containing three rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C65/00—Compounds having carboxyl groups bound to carbon atoms of six—membered aromatic rings and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
- C07C65/01—Compounds having carboxyl groups bound to carbon atoms of six—membered aromatic rings and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups containing hydroxy or O-metal groups
- C07C65/03—Compounds having carboxyl groups bound to carbon atoms of six—membered aromatic rings and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups containing hydroxy or O-metal groups monocyclic and having all hydroxy or O-metal groups bound to the ring
- C07C65/05—Compounds having carboxyl groups bound to carbon atoms of six—membered aromatic rings and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups containing hydroxy or O-metal groups monocyclic and having all hydroxy or O-metal groups bound to the ring o-Hydroxy carboxylic acids
- C07C65/10—Salicylic acid
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/06—Luminescent, e.g. electroluminescent, chemiluminescent materials containing organic luminescent materials
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental Sciences (AREA)
- Animal Husbandry (AREA)
- Biodiversity & Conservation Biology (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
Abstract
The invention discloses a kind of environmental type light emitting compositions, including luminous agent and oxidant, luminous agent includes 100 parts of oxalate, 0.01-0.05 parts of catalyst A and 1-1.5 parts of fluorescer by weight, and oxidant includes 1-60 parts of tributyl citrate class, 1-100 parts of dimethyl ether, 2-5 parts of the hydrogen peroxide that volume fraction is 90% and 0.01-0.05 parts of catalyst B by weight.Wherein, the benzoates solvent being harmful to the human body is replaced with green and environment-friendly solvent tributyl citrate class and dimethyl ether, it is nontoxic, adverse effect will not be generated to human health；Furthermore, the present invention is the solvent of fluorescer and oxalate with nontoxic and environmentally friendly tributyl citrate class and dimethyl ether mixture, there is good intermiscibility to each other, and achieve same illumination effect, complete alternative toxic phthalate is the chemical luminous system of solvent.Component in the present invention is environment-friendly materials, and pollution will not be generated to water body in float for fishing by applying, and prospect is extensive, is worthy to be popularized.
Description
Technical field
The invention belongs to chemical luminous composite field, in particular to a kind of environmental type light emitting composition.
Background technique
Chemiluminescence refers to the visible light issued during certain chemical reactions, and chemiluminescence principle is from 20th century
Since the seventies is found, by nearly development in 40 years and research, chemiluminescent technology is increasingly mature, is widely used in more
A field.In toy handicraft, the manufacture of the object to be shone by chemical reaction mode is it is well known that being based on two already
Component mixing needs two components to keep isolation come the chemiluminescence generated before shining, contact two components when needing to shine
Mixing generates chemiluminescence, and two components are usually oxidant and luminous agent, it is desirable that selected solvent must be able to sufficiently mix.
Pulvis chemical illumination float currently on the market is all benzoates solvent (DMP and DBP), such solvent
Influence may cause on the health of the mankind, phthalate is since there are potential carcinogenicity, the country such as America and Europe is tight
Lattice control its use.China has also worked out relevant laws and rules, will be phased out phthalate in food
Packaging material, medical apparatus and toy for children etc. use.
Therefore, the solvent of oxidant and luminous agent has certain toxicity in existing chemiluminescent objects, and safety is low.
Summary of the invention
To overcome the above insufficient or defect in the prior art, the present invention provides a kind of environmental type luminescent compositions
Object, the composition is nontoxic, environmentally protective, highly-safe, has excellent chemiluminescence performance.
The technical solution used in the present invention is: a kind of environmental type light emitting composition, including luminous agent and oxidant,
It is characterized in that, the luminous agent includes 100 parts of oxalate, 0.01-0.05 parts of catalyst A and fluorescer 1- by weight
1.5 parts, the oxidant includes 60 parts of tributyl citrate class, 1~100 part of dimethyl ether, dioxygen by weight
2-5 parts and 0.01-0.05 parts of catalyst B of water.
Wherein, dimethyl ether and tributyl citrate class are as mixed solvent, its hair of light emitting composition obtained
Luminous intensity and effective fluorescent lifetime and use benzoates are essentially identical for the luminescence system of solvent.
Tributyl citrate (TBC) is a kind of good environment-friendly plasticizer, lubricant.Be under room temperature it is nontoxic, fruity,
Colourless transparent oil liquid.170 DEG C of boiling point (133.3Pa), 185 DEG C of flash-point (opening cup).It is dissolved in most organic solvents.Volatility
Small, good with the compatibility of resin, plasticizing efficiency is high, is allowed for food packaging and medical product in countries such as America and Europes, with
And the industries such as the soft toy of children, pharmacy, medical product, flavors and fragrances, cosmetics manufacture.It is good cold-resistant that product can be given
Property, water resistance and fungus resistance.The good transparency and low temperature flex performance is presented in resin after this product is plasticized, and in different medium
In have low volatility and low extractable, thermal stability is good, and heat is non-discolouring.
Dimethyl ether (DMM) is nontoxic, has higher safety to human body, the states such as the U.S. and European Union are classified as
The green solvent of NON HAP/NAP.Simultaneously as butyl citrate can dissolve oxalate CIPO well, and dipropylene glycol two
Methyl ether can dissolve oxalate again and can dissolve 5% water, therefore the two mixes in appropriate proportion, and the mixing that may be selected as oxidant is molten
Agent, obtains the Chemiluminescence System of safety and environmental protection, and its luminous intensity and effective fluorescent lifetime with use benzoic ether
Class is that the luminescence system of solvent is essentially the same.
As a further improvement of the foregoing solution, the mass ratio of the luminous agent and oxidant is 1:(2~3).
As a further improvement of the foregoing solution, the oxalate is bis- (2,4,5- tri- chloro-salicylic acid's n-pentyl ester) oxalates
Or bis- (2,4,5- trichlorine isoamyl salicylate) oxalates.
As a further improvement of the foregoing solution, the fluorescer be 2- ethyl, 9,10 tolans base anthracenes, 2- methyl,
9,10 tolans base anthracenes, 9,10- diphenylanthrancene, 9,10- tolans base anthracene, chloro- 9, the 10- tolans base anthracene of 1,8- bis-,
Bis- (2,5 diisopropyl phenyls) -3 of 1,6,7,12- tetraphenoxy-N, N ' -, one of 4,9,10- dicarboximides.
As a further improvement of the foregoing solution, the tributyl citrate class includes tributyl citrate and acetyl lemon
Sour tributyl.
As a further improvement of the foregoing solution, the catalyst A is sodium salicylate.
As a further improvement of the foregoing solution, the catalyst B is sodium salicylate or tetrabutyl ammonium salicylate.
A kind of application of environmental type light emitting composition, the environmental type light emitting composition are applied on float for fishing.
The beneficial effects of the present invention are: the present invention provides a kind of environmental type light emitting composition, with environmentally protective molten
Agent tributyl citrate class and dimethyl ether replace the benzoates solvent being harmful to the human body, nontoxic, to people
Body health will not generate adverse effect；In addition, with nontoxic and environmentally friendly tributyl citrate class and dipropylene glycol two in the present invention
Methyl ether mixture is the solvent of luminescence system, there is good intermiscibility each other, complete alternative toxic phthalic acid ester
Class is the chemical luminous system of solvent, and achieves same illumination effect.Meanwhile the present invention also provides a kind of environmentally protective
The application of type light emitting composition, since the component in the present invention is environment-friendly materials, water body will not be generated in float for fishing by applying
Pollution, prospect is extensive, is worthy to be popularized.
Specific embodiment
The present invention is specifically described below with reference to embodiment, in order to technical field personnel to of the invention
Understand.It is necessary to it is emphasized that embodiment is only intended to, the present invention will be further described herein, should not be understood as to this
The limitation of invention protection scope, fields person skilled in the art, according to foregoing invention content non-to made by the present invention
The modifications and adaptations of matter should still fall within protection scope of the present invention.Mentioned raw materials following simultaneously are unspecified,
For commercial product；The processing step or preparation method not referred in detail be processing step known to a person skilled in the art or
Preparation method.
A kind of environmental type light emitting composition, including luminous agent and oxidant, the luminous agent include by weight
100 parts of oxalate, 0.01-0.05 parts of catalyst A and 1-1.5 parts of fluorescer, the oxidant includes citric acid by weight
1-60 parts of tributyl class, 1-100 parts of dimethyl ether, 2-5 parts of the hydrogen peroxide and catalyst B that volume fraction is 90%
0.01-0.05 parts.
As further preferred embodiment, the mass ratio of the luminous agent and oxidant is 1:(2~3).
As further preferred embodiment, the oxalate is bis- (2,4,5- tri- chloro-salicylic acid's n-pentyl ester) oxalates
Or bis- (2,4,5- trichlorine isoamyl salicylate) oxalates.
As further preferred embodiment, the fluorescer be 2- ethyl, 9,10 tolans base anthracenes, 2- methyl,
9,10 tolans base anthracenes, 9,10- diphenylanthrancene, 9,10- tolans base anthracene, chloro- 9, the 10- tolans base anthracene of 1,8- bis-,
Bis- (2,5 diisopropyl phenyls) -3 of 1,6,7,12- tetraphenoxy-N, N ' -, one of 4,9,10- dicarboximides.
As further preferred embodiment, the tributyl citrate class includes tributyl citrate and acetyl lemon
Sour tributyl.
As further preferred embodiment, the catalyst A is sodium salicylate.
As further preferred embodiment, the catalyst B is sodium salicylate or tetrabutyl ammonium salicylate.
Embodiment 1
Oxidant: 50 parts of tributyl citrate (TBC), 50 parts of dimethyl ether (DMM), volume fraction are 90%
3 parts and 0.03 part of tetrabutyl ammonium salicylate of hydrogen peroxide；
Luminous agent: 100 parts of oxalate (CIPO), 0.05 part of sodium salicylate and 2- ethyl, 9,10 tolans base anthracenes 1.2
Part；
Being packed into luminous agent after mixing by above-mentioned formula is component A in glass tube, by above-mentioned formula by hydrogen peroxide,
Catalyst mixing, adding dimethyl ether mixing to add tributyl citrate and mix is B component；Finally by A group
Part is that 1:2 is fitted into sealing as luminous product in polyethylene (PE) or polypropylene (PP) pipe with B component in mass ratio.
Use: bending outer tube keeps its inner glass tube broken, and A, B component mixing shine.
Meanwhile the present invention also provides a kind of application of environmental type light emitting composition, above-mentioned environmental type is sent out
Light composition is applied on float for fishing, is shone using the environmental type light emitting composition in float for fishing to the feedback feelings that a fish snapped at the bait
Condition will not produce water body to transmit information more precise and high efficiency, and the component environmental protection of environmental type light emitting composition
Raw pollution.
Embodiment 2
Oxidant: 50 parts of tributyl 2-acetylcitrate (ATBC), 50 parts of dimethyl ether (DMM), volume fraction are
3 parts and 0.03 part of tetrabutyl ammonium salicylate of 90% hydrogen peroxide；
Luminous agent: 100 parts of oxalate (CIPO), 0.05 part of sodium salicylate and 2 methyl, 9,10 tolans base anthracene 1-1.5
Part；
It is packed into glass tube after mixing luminous agent by above-mentioned formula, obtains component A；It is by volume fraction by above-mentioned formula
After 90% hydrogen peroxide and catalyst mixing, dimethyl ether mixing is added and adds tributyl 2-acetylcitrate mixing i.e.
For B component；In mass ratio it is finally that 1:3 is mixed with B component by component A, is fitted into polyethylene (PE) or polypropylene (PP) pipe and seals
Mouth is luminous product.
Use: bending outer tube keeps its inner glass tube broken, and A, B component mixing start to shine.
Meanwhile the present invention also provides a kind of application of environmental type light emitting composition, above-mentioned environmental type is sent out
Light composition is applied on float for fishing, is shone using the environmental type light emitting composition in float for fishing to the feedback feelings that a fish snapped at the bait
Condition will not produce water body to transmit information more precise and high efficiency, and the component environmental protection of environmental type light emitting composition
Raw pollution.
For those of ordinary skill in the art to which the present invention belongs, without departing from the inventive concept of the premise also
Several simple deduction or replace can be made, without having to go through creative labor.Therefore, those skilled in the art are according to this hair
Bright announcement, the simple modifications made to the present invention all should be within protection scope of the present invention.Above-described embodiment is this hair
Bright preferred embodiment, it is all with similar technique of the invention and made equivalence changes, it should belong to protection category of the invention.
Claims (8)
1. a kind of environmental type light emitting composition, including luminous agent and oxidant, it is characterised in that: the luminous agent is by weight
Part meter includes 100 parts of oxalate, 0.01-0.05 parts of catalyst A and 1-1.5 parts of fluorescer, and the oxidant wraps by weight
It includes 1-60 parts of tributyl citrate class, 1-100 parts of dimethyl ether, 2-5 parts of the hydrogen peroxide that volume fraction is 90% and urges
0.01-0.05 parts of agent B.
2. a kind of environmental type light emitting composition according to claim 1, it is characterised in that: the luminous agent and oxidation
The mass ratio of agent is 1:(2~3).
3. a kind of environmental type light emitting composition according to claim 1, it is characterised in that: the oxalate is double
(2,4,5- tri- chloro-salicylic acid's n-pentyl ester) oxalate or bis- (2,4,5- trichlorine isoamyl salicylate) oxalates.
4. a kind of environmental type light emitting composition according to claim 1, it is characterised in that: the fluorescer is 2- second
Base, 9,10 tolans base anthracenes, 2- methyl, 9,10 tolans base anthracenes, 9,10- diphenylanthrancene, 9,10- tolans base anthracene,
1,8- bis- chloro- 9,10- tolans base anthracene, 1,6,7,12- tetraphenoxy-N, N '-bis- (2,5 diisopropyl phenyls) -3,4,9,
One of 10- dicarboximide.
5. a kind of environmental type light emitting composition according to claim 1, it is characterised in that: the tributyl citrate
Class includes tributyl citrate and tributyl 2-acetylcitrate.
6. a kind of environmental type light emitting composition according to claim 1, it is characterised in that: the catalyst A is water
Poplar acid sodium.
7. a kind of environmental type light emitting composition according to claim 1, it is characterised in that: the catalyst B is water
Poplar acid sodium or tetrabutyl ammonium salicylate.
8. a kind of application of environmental type light emitting composition, which is characterized in that by the described in any item greens of claim 1-7
Environment protection luminous composition is applied on float for fishing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810856186.9A CN108947833A (en) | 2018-07-31 | 2018-07-31 | A kind of environmental type light emitting composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810856186.9A CN108947833A (en) | 2018-07-31 | 2018-07-31 | A kind of environmental type light emitting composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108947833A true CN108947833A (en) | 2018-12-07 |
Family
ID=64466691
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810856186.9A Pending CN108947833A (en) | 2018-07-31 | 2018-07-31 | A kind of environmental type light emitting composition |
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Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN85201854U (en) * | 1985-05-14 | 1986-06-25 | 郝庆丰 | Chemical illumination float |
| CN101070469A (en) * | 2007-06-08 | 2007-11-14 | 金朝阳 | Novel use of carbonats compound |
| CN102105556A (en) * | 2008-07-23 | 2011-06-22 | 克禄美科技股份有限公司 | Pressure activatable chemiluminescent system useful for covert intrusion detection |
| CN102753649A (en) * | 2010-02-09 | 2012-10-24 | 株式会社乐美加 | Oxidizing liquid for chemiluminescence and chemiluminescence system using same |
| CN103013499A (en) * | 2011-09-20 | 2013-04-03 | 金朝阳 | Luminescence composition, preparation method and applications thereof |
| CN103348214A (en) * | 2010-10-24 | 2013-10-09 | 克禄美科技股份有限公司 | Multi-marker marking system |
| CN204707789U (en) * | 2015-04-17 | 2015-10-21 | 吴光照 | Float for fishing |
| CN106087549A (en) * | 2016-06-17 | 2016-11-09 | 湖北工程学院 | A kind of luminescent paper, its manufacture method and the method drawing shining color Color Pattern |
| CN106479488A (en) * | 2016-09-26 | 2017-03-08 | 宁波美乐雅荧光科技股份有限公司 | A kind of chemical luminous composite of environmental protection |
| CN106577571A (en) * | 2015-10-14 | 2017-04-26 | 宜城市第三高级中学 | Float capable of shining |
-
2018
- 2018-07-31 CN CN201810856186.9A patent/CN108947833A/en active Pending
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN85201854U (en) * | 1985-05-14 | 1986-06-25 | 郝庆丰 | Chemical illumination float |
| CN101070469A (en) * | 2007-06-08 | 2007-11-14 | 金朝阳 | Novel use of carbonats compound |
| CN102105556A (en) * | 2008-07-23 | 2011-06-22 | 克禄美科技股份有限公司 | Pressure activatable chemiluminescent system useful for covert intrusion detection |
| CN102753649A (en) * | 2010-02-09 | 2012-10-24 | 株式会社乐美加 | Oxidizing liquid for chemiluminescence and chemiluminescence system using same |
| CN103348214A (en) * | 2010-10-24 | 2013-10-09 | 克禄美科技股份有限公司 | Multi-marker marking system |
| CN103013499A (en) * | 2011-09-20 | 2013-04-03 | 金朝阳 | Luminescence composition, preparation method and applications thereof |
| CN204707789U (en) * | 2015-04-17 | 2015-10-21 | 吴光照 | Float for fishing |
| CN106577571A (en) * | 2015-10-14 | 2017-04-26 | 宜城市第三高级中学 | Float capable of shining |
| CN106087549A (en) * | 2016-06-17 | 2016-11-09 | 湖北工程学院 | A kind of luminescent paper, its manufacture method and the method drawing shining color Color Pattern |
| CN106479488A (en) * | 2016-09-26 | 2017-03-08 | 宁波美乐雅荧光科技股份有限公司 | A kind of chemical luminous composite of environmental protection |
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Application publication date: 20181207 |