CN108947008A - A kind of river water contamination treating equipment - Google Patents

Abstract

A kind of river water pollution control equipment, the pharmaceutical mixing equipment is equipped with honeycomb reactor and steam injection pipe, the pharmaceutical mixing equipment and the upper part of the turbulent state processor are connected by pipelines; the turbulent flow shell of the turbulent state processor is equipped with exhaust The mud and liquid drainage pipelines, and the inner cavity is provided with a spray pipe network, a turbulent state adsorption mechanism and an annular aeration pipe in sequence; the spray pipe network is connected to the external water pump through the pipeline; the turbulent state adsorption mechanism is equipped with The reaction ball is equipped with an active resonant device and a booster impeller. The active resonant device is equipped with a resonant head and a vibrating rod. The resonant head is equipped with a high-frequency vibrator; The interior of the body is sequentially provided with a dispersion unit, a steady flow buffer unit, and a steady flow oscillation unit; the dispersion unit is composed of two polyaluminum chloride dispersion tubes; the steady flow buffer unit is composed of multiple polymer steady flow screens; The unit is composed of a plurality of steady-flow oscillating monomers. The device can facilitate rapid treatment of river sewage.

Description

A kind of river water pollution treatment equipment

technical field

The invention belongs to the technical field of sewage treatment, and in particular relates to river water pollution control equipment.

Background technique

As an important part of human living space, water provides high-quality fresh water resources for human beings. However, with the increasingly serious environmental pollution in our country, the problem of water pollution is also becoming more and more serious.

In the process of production and life, a lot of sewage will be produced, most of which are directly discharged into the river, causing serious pollution to the river. At present, the domestic river polluted water is generally treated simply by sedimentation tanks. There are also a few manufacturers that use flocculation and sedimentation for treatment. However, the existing devices for polluting river water have complex structures and high manufacturing costs, which are unfavorable for convenient treatment of river polluted water.

Contents of the invention

Aiming at the problems existing in the above-mentioned prior art, the present invention provides a river water pollution control device, which has a simple structure and low manufacturing cost, and can facilitate rapid treatment of river polluted water, and has strong popularization.

In order to achieve the above object, the present invention provides a kind of river water pollution control equipment, which includes a work platform supported by a bracket-suspension, and also includes a medicament mixing device, a mobile gas transmission station and a control system. One side of the work platform A turbulent state processor is installed through the suspension support of the second bracket, and the medicine mixing equipment is fixed and supported on the lower part of the work platform through the base;

The medicament mixing device includes a medicament mixing shell, the middle and lower parts of the medicament mixing shell are respectively fixed with a honeycomb reactor and a steam injection pipeline, and the bottom of the medicament mixing shell is fixedly connected with a mixing chamber communicating with its inner cavity. The chemical discharge pipeline, the upper part of the chemical mixing shell is fixedly connected with the chemical injection pipeline and the additive filling pipeline communicating with the inner cavity, and a temperature sensor is also fixedly arranged in the chemical mixing shell; the section of the honeycomb reactor is Honeycomb shape, and up and down, it is composed of a plurality of vertical pipes arranged in a honeycomb shape; the steam injection pipeline is in the shape of a ring, and its upper surface is provided with through holes communicating with its inner cavity all over the place, connecting the steam injection pipeline The steam supply pipeline passes through the medicament mixing shell and is connected to the external high-pressure steam pipeline; the liquid outlet end of the mixed medicament discharge pipeline is fixedly connected to the addition pipeline on the upper part of the turbulent flow processor through a pressure pump The liquid inlet end is fixedly connected, and a solenoid valve A is set on the adding pipeline; a solenoid valve A, a solenoid Valve B, solenoid valve C, solenoid valve D and solenoid valve E;

The mobile gas transmission station is arranged at the lower part of the turbulent state processor, and the mobile gas transmission station includes a mobile bearing plate, two pairs of moving wheels rotatably connected to the lower part of the mobile bearing plate, and an aerator fixedly assembled on the upper part of the mobile bearing plate. An air pump, a gas flow meter connected to the gas outlet of the aeration pump, a gas delivery pipeline, and a gas delivery valve arranged on the gas delivery pipeline;

The turbulent state processor includes a turbulent flow shell with an open upper end, a spray pipe network fixedly connected to the middle and upper part of the inner cavity of the turbulent flow shell, a turbulent state adsorption mechanism fixedly connected to the middle part of the inner cavity of the turbulent flow shell, and a fixed connection in the turbulent flow shell. The aeration tube in the lower part of the cavity, the temperature detector and the liquid level gauge fixedly arranged inside the turbulent shell;

The spraying pipe network is composed of a plurality of interconnected spraying pipes, and the lower part of each spraying pipe is connected with a plurality of nozzles which are distributed along its length and communicated with its inner cavity, and connected to the liquid inlet of the spraying pipe network. The fixedly connected liquid inlet pipeline passes through the upper end of the turbulent flow housing and is connected to the outlet end of the external water pump. The liquid inlet pipeline is connected with a liquid inlet solenoid valve. The turbulent state adsorption mechanism is composed of several turbulent flow The turbulent state booster consists of a reaction ball grid surrounding a cylindrical structure, a booster impeller that is rotatably arranged at the bottom of the reaction ball grid cavity and fixedly arranged in the reaction ball grid The active resonant device at the lower part of the chamber; the booster impeller is driven by a waterproof motor located at the lower part of the turbulent state; a large number of reaction balls are supported on the upper part of the active resonant device, and the outer diameter of the reaction ball is larger than that of the reaction ball grid The grid gap and the mesh diameter of the active resonant device; a large number of reaction balls fill the upper space of the entire reaction ball grid; a temperature sensing device is installed inside the reaction ball grid; there is also a spray on the upper part of the reaction ball grid. device, the spraying device comprises annular sodium dimethyl dithiocarbamate medicament pipe, a plurality of sodium dimethyl dithiocarbamate nozzles fixedly connected in the lower part of the sodium dimethyl dithiocarbamate medicament pipe evenly in the circumferential direction, and The spray main pipe connected to the cavity of the sodium methyl dithiocarbamate drug tube is connected to the external pressurized water pump; the active resonance device includes a cylindrical grille shell that penetrates up and down, and is fixedly connected to the opening on the cylindrical grille shell. There are two resonant filter screens at the end and the lower open end. There are multiple resonant units inside the cylindrical grid shell. Each resonant unit consists of multiple resonant heads evenly distributed along the length direction, connecting adjacent resonant heads It is composed of a plurality of transmission rods, and the cylindrical grille shell is composed of a plurality of vertical rods uniformly arranged in the circumferential direction and a collar fixedly connected to the periphery of the plurality of vertical rods at intervals in the longitudinal direction; The rod is a cavity structure, and the power line of the high-frequency vibrator passes through the transmission rod and then passes out of the turbulence shell to connect with the control system; the aeration pipe is ring-shaped, and its upper part is provided with an aeration hole communicating with its inner cavity ; The outlet end of the gas pipeline passes through the turbulence shell and the inlet end of the aeration pipe;

The lower part of the turbulence shell is a funnel-shaped settling part, the settling part includes a settling part shell, and inside the settling part shell, a dispersing unit, a steady flow buffer unit, a steady flow Oscillating unit; the dispersing unit is composed of two polyaluminum chloride dispersing tubes arranged side by side parallel to each other and a plurality of nozzles evenly connected to the lower part of each polyaluminum chloride dispersing tube; the steady flow The buffer unit is composed of a plurality of polymer flow stabilization screens stacked vertically; the flow stabilization oscillation unit is composed of a plurality of flow stabilization oscillation units arranged at equal intervals from left to right, and the flow stabilization oscillation unit The body is composed of two electromagnetic vibrating rods fixedly connected to the bottom of the shell of the sedimentation part and a stabilizing vane fixedly connected to the upper ends of the two electromagnetic vibrating rods. The vertical section of the stabilizing vane is in an inverted W shape; The middle part and the lower end of the shell of the sedimentation part are respectively fixedly connected with a liquid discharge pipeline and a mud discharge pipeline connected with the inner cavity, and the mud discharge pipeline and the liquid discharge pipeline are respectively connected with a mud discharge valve and a liquid discharge valve. The liquid inlet ends of the mud pipeline and the liquid discharge pipeline are respectively located at the bottom and middle of the shell of the sedimentation part; a middle storage tank and a water pump of the middle storage tank are arranged outside the shell of the sedimentation part, and polymerized chloride is stored in the middle storage tank. Aluminum solution, the liquid inlet end of the water pump in the middle storage tank communicates with the bottom of the inner cavity of the middle storage tank through the pipeline, and the liquid outlet end of the water pump in the middle storage tank communicates with the inner cavity of the two polyaluminum chloride dispersion pipes through the pipeline respectively ;

Solenoid valve A, aeration pump, gas flow meter, gas delivery valve, temperature detector, liquid level gauge, water pump, liquid inlet solenoid valve, mud outlet valve, liquid outlet valve, temperature sensor, solenoid valve B, solenoid valve C, Electromagnetic valve D, electromagnetic vibrating rod, middle storage tank water pump, waterproof motor, temperature sensing equipment and pressurized water pump are all connected with the control system.

In this technical scheme, the medicament and the additive are respectively injected into the medicament mixing equipment from the medicament injection pipe and the additive injection pipe, and the high-temperature steam ejected from the steam injection pipe promotes the reaction of the medicament in the honeycomb reactor to form an inorganic flocculant, and ends Then it is discharged from the mixed agent discharge pipe. The injection of the inorganic flocculant into the turbulent processor can be conveniently realized by setting the chemical mixing equipment connected to it through the adding pipeline and the mixed chemical discharge pipe on one side of the turbulent processor, so as to effectively promote the removal of waste in the sewage. Rapid settlement; the upper part of the turbulent flow processor is equipped with a spray pipe network, which can facilitate the rapid and uniform injection of sewage, and the setting of multiple spray pipes and multiple nozzles can facilitate the rapid dispersion of added sewage, thereby It can facilitate good contact with the injected inorganic flocculant, thereby improving the flocculation effect and shortening the flocculation time. The setting of the aeration tube can facilitate the uniform and rapid addition of fresh air, and can evenly and fully contact with the falling liquid, so that the anaerobic microorganisms in the anaerobic sewage can be effectively killed. During the process, the carbon tetrachloride in the water is fully dissolved and discharged into the air through the upper open end of the turbulence shell. The turbulent state adsorber arranged in a matrix inside the turbulent state processor is equipped with reaction balls, and the sodium dimethyldithiocarbamate nozzle can facilitate the atomization and spraying of the external sodium dimethyldithiocarbamate, so as to Improve the efficacy of sewage treatment chemicals, under the action of the reaction ball, can effectively adsorb the microorganisms in the sewage, and can promote the decomposition of the adsorbed microorganisms, thereby further improving the sewage treatment effect. The resonant head in the active resonant device will vibrate at high frequency after being energized, thereby activating the solution entering the cylindrical grid shell and allowing it to pass through quickly. The booster impeller can realize the turbulent rotation of the discharged water under the drive of the waterproof motor, which can further improve the sewage treatment effect. The temperature sensing device can monitor the temperature near the reaction ball, which can help to understand the adsorption progress; the temperature detector can And the liquid level gauge can detect the temperature and liquid level in the turbulent state processor in real time, so as to effectively monitor the progress of sewage treatment. When the sewage falls into the shell of the sedimentation part, it meets with the polyaluminum chloride sprayed from the polyaluminum chloride dispersion pipe supplied by the water pump in the middle storage tank to sterilize, deodorize and decolorize the sewage, and then stabilize the flow in the polymer Under the buffering effect of the screen, it falls into the lower part of the shell of the sedimentation part; the steady flow flap is driven by the electromagnetic vibrating rod to vibrate horizontally, and at the same time, the electromagnetic vibrating rod itself will also vibrate horizontally to a certain extent, thereby accelerating flocculation Reaction, when the stabilizing flap and the electromagnetic vibrating rod stop working, the organic matter flocculates and settles and is discharged from the mud discharge pipe at the bottom, and the clear water is discharged from the liquid discharge pipe in the middle; the device has a simple structure, low manufacturing cost, and is easy to operate and maintain. It can conveniently realize the treatment of river polluted water, and it has strong popularization.

Further, in order to clean the inside of the medicament mixing device, the medicament mixing device also includes a washing pipeline fixedly connected to the top of the medicament mixing housing, and the end of the washing pipeline outside the medicament mixing housing is connected to the water outlet of the washing water pump. Connection, one end inside the medicament mixing shell is fixedly connected to the lotus spray head arranged on the upper part of the honeycomb reactor; the washing pipeline is provided with a solenoid valve F; the solenoid valve F is connected to the control system. The lower spray hole of the lotus nozzle is facing the honeycomb reactor. When cleaning is required, the high-pressure water sprayed from the lotus nozzle will perform high-pressure cleaning on the honeycomb reactor.

As a preference, the water outlet end of the drainage pipeline communicates with an external liquid collection tank.

As a preference, the mesh aperture of the steady flow screen is 5 mm to 16 mm; the number of steady flow screens is 10; the number of the steady flow oscillation units is 10, and The distance between them is 2cm-6cm; the two electromagnetic vibrating rods in the same steady-flow vibrating unit are distributed in the front-rear direction, with a distance of 10cm-60cm.

As a preference, the number of the aeration pumps is two.

As a preference, the shell of the precipitation part is a square pyramid structure; the number of the spraying pipelines is not less than 6.

As a preference, the working platform is made of stainless steel plate with a thickness between 1cm and 1.5cm, and a safety guardrail is arranged around the working platform, and the height of the safety guardrail is between 80cm and 120cm. There is a ladder attached.

Further, in order to obtain a resonant filter screen with good corrosion resistance and long service life, the resonant filter screen is composed of the following components in parts by weight:

341.0-566.2 parts of distilled water, 133.3-175.5 parts of 3-methylundecanonitrile, 2-methoxy-5-methyl-4-[(4-methyl-2-nitrophenyl)azo]benzene Nitrogen (T-4) tetrachlorozincate (2:1) 136.2-245.1 parts, ethyl 3-methylthiobutyrate 132.6-149.7 parts, golden leuco body 135.2-192.9 parts, 2,2'-[ (1-methylethylene)bis[[2-(2-propenyl)-4,1-phenylene]oxymethylene]dioxirane with hydrogen-terminated polydimethylsiloxane 138.4 to 199.1 parts of polymers, 140.9 to 195.2 parts of lead nanoparticles, polymerized [oxy-1,4-phenylene (1-methylethylene)-1,4-phenyleneoxy-1,4- phenyleneiminocarbyl (dicarboxycyclobutanediyl)carbylimino-1,4-phenylene] 133.5-175.9 parts, polymerization of formaldehyde with dinonylphenol, nonylphenol and ethylene oxide 135.1-175.6 parts of copper phosphate, 135.6-158.1 parts of basic copper phosphate, 124.4-160.8 parts of methyl ethyl ketone oxime-capped 1,1'-methylene bis(isocyanatobenzene), 123.2-166.8 parts of 7-methyl-octanoic acid , 132.6-177.2 parts of hexyl formate, 142.1-186.1 parts of polyurethane resin, 165.7-219.5 parts of hexadecyl phosphate potassium salt with a mass concentration of 132 mg/L-399 mg/L.

Further, in order to obtain a resonant filter screen with good corrosion resistance and long service life, the manufacturing method of the resonant filter screen is as follows:

Step 1: In the multi-pot reactor, add distilled water and 3-methylundecanonitrile, start the mixer in the multi-pot reactor, set the speed at 134rpm-180rpm, start the steam seal heat in the multi-pot reactor Exchanger, raise the temperature to 149.0℃～150.2℃, add 2-methoxy-5-methyl-4-[(4-methyl-2-nitrophenyl)azo]benzenediazo (T- 4) Stir tetrachlorozincate (2:1) evenly, react for 126.3-137.5 minutes, add ethyl 3-methylthiobutyrate, and feed fluorine with a flow rate of 125.1m ³ /min-166.7m ³ /min Gas for 126.3 to 137.5 minutes; then add the golden leuco body into the multi-pot reactor, start the vapor-sealed steam heat exchanger in the multi-pot reactor again, raise the temperature to 166.2°C to 199.1°C, and keep the heat for 126.6 to 137.7 minutes. Add 2,2'-[(1-methylethylene)bis[[2-(2-propenyl)-4,1-phenylene]oxymethylene]dioxirane with hydrogen-terminated For the polymer of polydimethylsiloxane, adjust the pH value of the solution in the multi-torch reactor to 4.2-8.9, and keep the temperature for 126.2-366.2 minutes;

Step 2: Take another lead nanoparticle and ultrasonically treat the lead nanoparticle at a power of 6.66KW to 12.1KW for 0.132 to 1.199 hours; add the lead nanoparticle to another multi-pot reactor with a mass concentration of 136mg /L～366mg/L of polymerized [oxyl-1,4-phenylene (1-methylethylene)-1,4-phenoxy-1,4-phenyleneiminocarbonyl (di Carboxycyclobutanediyl) carboimino-1,4-phenylene] disperse lead nanoparticles, start the vapor-sealed steam heat exchanger in the multi-pot reactor, and make the solution temperature between 46°C and 86°C, Start the mixer in the multi-pot reactor, and stir at a speed of 4×10 ² rpm to 8×10 ² rpm, adjust the pH value between 4.4 and 8.8, keep stirring for 132 to 199 minutes; then stop the reaction and let it stand for 6.66× 10～12.1×10 minutes, remove impurities; add formaldehyde, dinonylphenol, nonylphenol and ethylene oxide polymer to the suspension, adjust the pH value between 1.4～2.8, form a precipitate and elute with distilled water , the solids were obtained by a centrifuge at a rotational speed of 4.732×10 ³ rpm to 9.23×10 ³ rpm, dried at a temperature of 2.95×10 ² ℃ to 3.419×10 ² ℃, and ground at a temperature of 0.732×10 ³ to 1.23×10 ³ Mesh sieve, spare;

Step 3: Separately take basic copper phosphate and lead nanoparticles treated in step 2, mix them uniformly and then irradiate them with ionizing radiation. The irradiation time is 135.2 to 160.8 minutes, and the mixture of basic copper phosphate and lead nanoparticles with changed properties is obtained; the mixture of basic copper phosphate and lead nanoparticles is placed in another multi-pot reactor, and the steam in the multi-pot reactor is started. Seal the steam heat exchanger, set the temperature at 134.6°C to 180.2°C, start the mixer in the multi-tank reactor with a rotation speed of 126rpm to 521rpm, adjust the pH to 4.1 to 8.1, dehydrate for 135.1 to 149.1 minutes, and set aside;

Step 4: Add the modified basic copper phosphate and lead nanoparticle mixture obtained in step 3 to the 1,1'-methylenebis( isocyanatobenzene), and flow into the multi-pot reactor in the first step, the flow rate is 271mL/min～999mL/min; start the multi-pot reactor mixer, set the speed at 140rpm～180rpm; stir for 4 ~ 8 minutes; then add 7-methyl-octanoic acid, start the vapor-sealed steam heat exchanger in the multi-pot reactor, raise the temperature to 170.7°C ~ 207.5°C, adjust the pH to 4.7 ~ 8.5, and introduce fluorine gas to ventilate 125.293m ³ /min～166.410m ³ /min, heat preservation and standing for 160.0～190.2 minutes; start the multi-pot reactor mixer again, the speed is 135rpm～180rpm, add hexyl formate, and adjust the pH to 4.7～8.5 , heat preservation and standing for 159.3 to 199.5 minutes;

Step 5: Start the mixer in the multi-tank reactor, set the speed at 132rpm to 199rpm, start the steam seal heat exchanger in the multi-tank reactor, and set the temperature in the multi-tank reactor to 1.581×10 ² ℃ ～2.462×10 ² ℃, add polyurethane resin, react for 126.2～137.1 minutes; then add cetyl phosphate potassium salt, start the steam seal steam heat exchanger in the multi-tank reactor, set the temperature in the multi-tank reactor The temperature is 210.6℃～266.7℃, the pH is adjusted to 4.2～8.2, the pressure is 1.32MPa～1.33MPa, and the reaction time is 0.4～0.9 hours; after that, the pressure is reduced to 0MPa, and the temperature is lowered to 126.2℃～137.1℃. The material is fed into the compression molding machine, and the resonant filter screen is obtained;

The particle size of the lead nanoparticles is 140 μm˜150 μm.

Description of drawings

Fig. 1 is a structural representation of the present invention;

Fig. 2 is a schematic structural view of a medicament mixing device in the present invention;

Fig. 3 is the structural representation of turbulent state processor among the present invention;

Fig. 4 is the structural representation of turbulent state accelerator reactor among the present invention;

Fig. 5 is a schematic structural view of an active resonant device in the present invention;

Fig. 6 is a schematic structural view of the precipitation part in the present invention;

Fig. 7 is the structural representation of mobile gas transmission station in the present invention;

Fig. 8 is a graph showing the variation of corrosion resistance of the resonant filter screen with service time in the present invention.

In the figure: 1. Ladder, 2. Working platform, 3. Chemical mixing equipment, 3-1, Mixed chemical discharge pipeline, 3-2, Steam injection pipeline, 3-3, Honeycomb reactor, 3-4, Additive filling pipeline, 3-5, chemical injection pipeline, 3-6, washing pipeline, 3-7, temperature sensor, 3-8, base, 3-9, chemical mixing shell, 3-10, Steam supply pipeline, 4, adding pipeline, 5, turbulent flow processor, 5-1, liquid inlet solenoid valve, 5-2, spray pipeline, 5-3, turbulent flow accelerator, 5-3-1 , booster impeller, 5-3-2, active resonance device, 5-3-2-1, cylindrical grille shell, 5-3-2-2, transmission rod, 5-3-2-3, resonance Screen, 5-3-2-4, Pole, 5-3-2-5, Resonant Head, 5-3-2-6, Collar, 5-3-3, Reaction Ball Grille, 5-3 -4, reaction ball, 5-3-5, temperature sensing equipment, 5-3-6, multiple sodium dimethyl dithiocarbamate nozzles, 5-3-7, sodium methyl dithiocarbamate drug tube , 5-4, Precipitation Department, 5-4-1, Electromagnetic Vibrator, 5-4-2, Steady Flow Wing, 5-4-3, Polymer Steady Flow Screen, 5-4-4, Polymerized Chlorine Aluminum dispersing pipe, 5-4-5, precipitation part shell, 5-4-6, middle storage tank, 5-4-7, middle storage tank water pump, 5-5, liquid outlet valve, 5-6, temperature Detector, 5-7, liquid level gauge, 5-8, aeration pipe, 5-9, mud discharge pipeline, 5-10, liquid discharge pipeline, 5-11, turbulent flow shell, 5-12, discharge Mud valve, 6, mobile gas transmission station, 6-1, mobile wheel, 6-2, mobile bearing plate, 6-3, aeration pump, 6-4, gas flow meter, 6-5, gas transmission valve, 6-6. Gas pipeline, 7. Control system.

Detailed ways

The present invention will be further described below in conjunction with accompanying drawing.

As shown in Figures 1 to 7, a river water pollution treatment equipment includes a work platform 2 supported by a bracket, a medicament mixing device 3, a mobile gas transmission station 6 and a control system 7. The operation One side of the platform 2 is suspended with a turbulent state processor 5 through the bracket 2, and the medicine mixing device 3 is fixedly supported on the lower part of the working platform 2 through the base 3-8;

The medicament mixing device 3 includes a medicament mixing housing 3-9, the middle and lower parts of the medicament mixing housing 3-9 are respectively fixed with a honeycomb reactor 3-3 and a steam injection pipeline 3-2, the medicament The bottom of the mixing housing 3-9 is fixedly connected with a mixed medicament discharge pipeline 3-1 communicating with its inner cavity, and the upper part of the medicament mixing housing 3-9 is fixedly connected with a medicament injection pipeline 3-5 communicating with its inner cavity and The additive filling pipeline 3-4 and the temperature sensor 3-7 are fixedly installed in the medicament mixing housing 3-9; Composed of vertical pipes arranged in a honeycomb shape; the steam injection pipeline 3-2 is in the shape of a ring, and its upper surface is provided with through holes communicating with its inner cavity all over the place, connecting the steam supply pipeline of the steam injection pipeline 3-2 3-10 passes through the agent mixing shell 3-9 and connects with the external high-pressure steam pipeline; through the setting of the steam injection pipeline 3-2, high-temperature steam can be evenly injected to the upper honeycomb reactor 3-3, To promote the reaction of the medicament; the liquid outlet end of the mixed medicament discharge pipeline 3-1 is fixedly connected to the liquid inlet end of the side addition pipeline 4 fixedly connected to the upper part of the turbulent flow processor 5 through a pressure pump, and the addition pipeline 4 is provided with a solenoid valve A; the addition pipeline 4, the mixed medicine discharge pipeline 3-1, the medicine injection pipeline 3-5, the additive filling pipeline 3-4 and the steam supply pipeline 3-10 respectively Solenoid valve A, solenoid valve B, solenoid valve C, solenoid valve D and solenoid valve E are provided; medicines and additives are injected into medicine mixing equipment 3 from medicine injection pipe 3-5 and medicine injection pipe 3-5 respectively, and steam The high-temperature steam ejected from the injection pipe 3-2 promotes the chemical reaction inside the honeycomb reactor 3-3, and is discharged from the mixed chemical discharge pipe 3-1 after completion;

The mobile gas transmission station 6 is arranged at the lower part of the turbulent state processor 5, and the mobile gas transmission station 6 includes a mobile bearing plate 6-2, and two pairs of moving wheels 6 rotatably connected to the lower part of the mobile bearing plate 6-2 -1. The aeration pump 6-3 fixedly assembled on the upper part of the mobile loading plate 6-2, connected to the gas flow meter 6-4 at the gas outlet of the aeration pump 6-3 and the gas pipeline 6-6, arranged on the gas pipeline The air delivery valve 6-5 on the road 6-6; the moving wheel 6-1 can be provided with a braking device, and can also be provided with a driving motor for driving it to rotate.

The turbulent state processor 5 includes a turbulent flow shell 5-11 with an open upper end, a spray pipe network fixedly connected to the middle and upper part of the inner cavity of the turbulent flow shell 5-11, and a fixed connection to the middle part of the inner cavity of the turbulent flow shell 5-11. The turbulent state adsorption mechanism, the aeration tube 5-8 fixedly connected to the middle and lower part of the inner cavity of the turbulent flow housing 5-11, the temperature detector 5-6 and the liquid level gauge 5-6 fixedly arranged inside the turbulent flow housing 5-11 7;

The spraying pipe network is composed of a plurality of interconnected spraying pipelines 5-2, and the lower part of each spraying pipeline 5-2 is connected with a plurality of nozzles which are distributed along its length and communicated with its inner cavity, and are connected with the spraying pipelines 5-2. The liquid inlet pipeline 5-13 fixedly connected to the liquid inlet end of the shower pipe network passes through the upper end of the turbulent flow housing 5-11 and is connected with the water outlet end of the external water pump. The liquid inlet pipeline 5-13 is connected with a liquid inlet electromagnetic Valve 5-1, the turbulent state adsorption mechanism is composed of several turbulent state accelerators 5-3 distributed in an array, and the turbulent state adsorption mechanism is composed of several turbulent state accelerators 5-3 arranged in an array 3, the turbulent state booster 5-3 includes a reaction ball grid 5-3-3 surrounding a cylindrical structure, and a pressurization device rotatably arranged at the bottom of the inner cavity of the reaction ball grid 5-3-3 The impeller 5-3-1 and the active resonance device 5-3-2 fixedly arranged at the lower part of the inner chamber of the reaction ball grid 5-3-3; The waterproof motor at the lower part of 5-3 is driven to rotate; a large number of reaction balls 5-3-4 are supported on the upper part of the active resonance device 5-3-2, and the outer diameter of the reaction balls 5-3-4 is larger than the reaction ball grid 5 -3-3 gap and the mesh diameter of the active resonant device 5-3-2; a large number of reaction balls 5-3-4 fill the upper space of the entire reaction ball grid 5-3-3; in the reaction ball grid 5 -3-3 is equipped with a temperature sensing device 5-3-5; a spray device is also provided on the upper part of the reaction ball grid 5-3-3, and the spray device includes an annular sodium dimethyldithiocarbamate agent Pipe 5-3-7, a plurality of sodium dimethyl dithiocarbamate nozzles 5-3-6 fixedly connected to the lower part of the sodium dimethyl dithiocarbamate drug pipe 5-3-7 uniformly in the circumferential direction, and methyl The sodium dithiocarbamate drug pipe 5-3-7 is connected to the spray main pipe connected to the inner cavity of the external pressurized water pump; the active resonance device 5-3-2 includes a cylindrical grille shell 5-3 penetrating up and down -2-1. Two resonant filter screens 5-3-2-3 fixedly connected to the upper opening end and the lower opening end of the cylindrical grille shell 5-3-2-1 respectively, and the cylindrical grille shell 5- 3-2-1 is equipped with a plurality of resonant units, and each resonant unit is composed of a plurality of resonant heads 5-3-2-5 uniformly distributed along the length direction, connected between adjacent resonant heads 5-3-2-5 Composed of a plurality of transmission rods 5-3-2-2, the cylindrical grille shell 5-3-2-1 is composed of a plurality of vertical rods 5-3-2-4 uniformly arranged in the circumferential direction and longitudinally spaced and fixedly connected A plurality of vertical rods 5-3-2-4 are composed of collars 5-3-2-6; the resonant head 5-3-2-5 is provided with a high-frequency vibrator inside, and the transmission rod 5-3-2- 2 is a cavity structure, the power line of the high-frequency vibrator passes through the transmission rod 5-3-2-2 and then passes through the turbulent flow housing 5-11 to connect with the control system 7, and the resonant filter screen 5-3-2- 3 has a mesh aperture of 5 mm to 20 mm; the aeration pipe 5-8 is ring-shaped, and its upper part is provided with an aeration hole communicating with its inner cavity; after with The inlet end of the aeration pipe 5-8;

The lower part of the turbulence housing 5-11 is a funnel-shaped sedimentation part 5-4, the sedimentation part 5-4 includes a sedimentation part housing 5-4-5, and the sedimentation part housing 5-4-5 Inside, there are dispersing unit, steady-flow buffer unit, and steady-flow oscillating unit fixed in order from top to bottom; the dispersing unit consists of two polyaluminum chloride dispersing tubes 5-4-4 arranged side by side in parallel and arranged side by side in a rectangular ring shape. and a plurality of nozzles evenly connected to the lower part of each polyaluminum chloride dispersion pipe 5-4-4; the steady-flow buffer unit is composed of a plurality of polymer steady-flow screens 5-4-3 arranged vertically ; The steady-flow oscillation unit is composed of a plurality of steady-flow oscillation units arranged at equal intervals from left to right, and the steady-flow oscillation unit is fixedly connected to the bottom of the sedimentation part housing 5-4-5 It consists of two electromagnetic vibrating rods 5-4-1 and a flow stabilizing vane 5-4-2 fixedly connected to the upper ends of the two electromagnetic vibrating rods 5-4-1. The longitudinal direction of the stabilizing vane 5-4-2 The cross-section is in an inverted W shape; the middle and lower ends of the shell 5-4-5 of the sedimentation part are respectively fixedly connected with a liquid discharge pipeline 5-10 and a mud discharge pipeline 5-9 communicating with its inner cavity. The mud pipeline 5-9 and the liquid discharge pipeline 5-10 are respectively connected with a mud outlet valve 5-12 and a liquid outlet valve 5-5, and the liquid inlet of the mud discharge pipeline 5-9 and the liquid discharge pipeline 5-10 The ends are respectively located at the bottom and middle of the sedimentation part housing 5-4-5, and the liquid inlet end of the discharge pipeline 5-10 is located between the steady flow buffer unit and the steady flow oscillation unit; in the sedimentation part housing 5-4- The outside of the 5 is provided with a middle storage tank 5-4-6 and a middle storage tank water pump 5-4-7, wherein polyaluminum chloride solution is stored in the middle storage tank 5-4-6, and the middle storage tank water pump 5-4-7 The liquid inlet end of the middle storage tank 5-4-6 through the pipeline communicates with the bottom of the inner cavity, and the liquid outlet end of the middle storage tank water pump 5-4-7 is respectively connected to the two polyaluminum chloride dispersion pipes 5 through the pipeline. - The inner cavity of 4-4 is connected; the mesh aperture of the steady flow screen 5-4-3 is 5 mm to 16 mm; the number of steady flow screens 5-4-3 is 10; the steady flow oscillating monomer The number of oscillating cells is 10, and the distance between adjacent oscillating cells is 2cm to 6cm; the two electromagnetic vibrating rods 5-4-1 in the same oscillating cell are distributed in the front and rear directions, and the distance between them is 10cm. ~60cm. The sewage enters from the upper part of the shell 5-4-5 of the sedimentation part, meets the polyaluminum chloride sprayed from the polyaluminum chloride dispersion pipe 5-4-4, and is buffered by the polymer steady flow screen 5-4-3 Under the action, it falls into the lower part of the shell 5-4-5 of the sedimentation part; at this time, the stabilizing wing plate 5-4-2 is shaken horizontally under the drive of the electromagnetic vibrating rod 5-4-1, and at the same time, the electromagnetic vibrating rod 5-4-1 itself will also vibrate horizontally to a certain extent, which can accelerate the flocculation reaction. When the steady flow vane 5-4-2 and the electromagnetic vibrating rod 5-4-1 stop working, the organic matter flocculates and settles from the bottom The mud discharge pipe 5-9 is discharged, and the clear water is discharged from the liquid discharge pipeline 5-10 in the middle;

Solenoid valve A, aeration pump 6-3, gas flow meter 6-4, gas delivery valve 6-5, temperature detector 5-6, liquid level gauge 5-7, water pump, inlet solenoid valve 5-1, outlet Mud valve 5-12, liquid outlet valve 5-5, temperature sensor 3-7, solenoid valve B, solenoid valve C, solenoid valve D, electromagnetic vibrator 5-4-1, middle storage tank water pump 5-4-7, The waterproof motor, the temperature sensing device 5-3-5 and the pressurized water pump are all connected with the control system 7 .

The medicament mixing device 3 also includes a washing pipeline 3-6 fixedly connected to the top of the medicament mixing housing 3-9. Connection, one end inside the medicament mixing shell 3-9 is fixedly connected with the lotus shower head arranged on the upper part of the honeycomb reactor 3-3; the washing pipeline 3-6 is provided with a solenoid valve F; the solenoid valve F is connected with the control System 7 is connected.

The temperature detector 5-6 is installed on the inner wall of the turbulent flow housing 5-11, and the distance from the upper end of the turbulent flow housing 5-11 is between 15 cm and 25 cm; the liquid level gauge 5-7 is arranged on the inner wall , the distance between the liquid level gauge 5-7 and the bottom end of the turbulent flow housing 5-11 is between 40cm and 60cm.

The water outlet end of the drainage pipeline 5-10 communicates with the external liquid collection tank.

The moving plate 6-2 is a rectangular galvanized plate.

The number of the aeration pumps 6-3 is two.

The casing 5-4-5 of the precipitation part is a square pyramid structure; the number of the spraying pipelines 5-2 is not less than 6.

The working platform 2 is made of a stainless steel plate with a thickness between 1cm and 1.5cm, and a safety guardrail is arranged around the working platform 2, and the height of the safety guardrail is between 80cm and 120cm. The working platform 2 is connected with Ladder 1.

Further, in order to obtain a resonant filter screen 5-3-2-3 with good corrosion resistance and long service life, the resonant filter screen 5-3-2-3 is composed of the following components in parts by weight:

341.0-566.2 parts of distilled water, 133.3-175.5 parts of 3-methylundecanonitrile, 2-methoxy-5-methyl-4-[(4-methyl-2-nitrophenyl)azo]benzene Nitrogen (T-4) tetrachlorozincate (2:1) 136.2-245.1 parts, ethyl 3-methylthiobutyrate 132.6-149.7 parts, golden leuco body 135.2-192.9 parts, 2,2'-[ (1-methylethylene)bis[[2-(2-propenyl)-4,1-phenylene]oxymethylene]dioxirane with hydrogen-terminated polydimethylsiloxane 138.4 to 199.1 parts of polymers, 140.9 to 195.2 parts of lead nanoparticles, polymerized [oxy-1,4-phenylene (1-methylethylene)-1,4-phenyleneoxy-1,4- phenyleneiminocarbyl (dicarboxycyclobutanediyl)carbylimino-1,4-phenylene] 133.5-175.9 parts, polymerization of formaldehyde with dinonylphenol, nonylphenol and ethylene oxide 135.1-175.6 parts of copper phosphate, 135.6-158.1 parts of basic copper phosphate, 124.4-160.8 parts of methyl ethyl ketone oxime-capped 1,1'-methylene bis(isocyanatobenzene), 123.2-166.8 parts of 7-methyl-octanoic acid , 132.6-177.2 parts of hexyl formate, 142.1-186.1 parts of polyurethane resin, 165.7-219.5 parts of hexadecyl phosphate potassium salt with a mass concentration of 132 mg/L-399 mg/L.

Further, in order to obtain a resonant filter screen 5-3-2-3 with good corrosion resistance and long service life, the manufacturing method of the resonant filter screen 5-3-2-3 is as follows:

Step 1: In the multi-pot reactor, add distilled water and 3-methylundecanonitrile, start the mixer in the multi-pot reactor, set the speed at 134rpm-180rpm, start the steam seal heat in the multi-pot reactor Exchanger, raise the temperature to 149.0℃～150.2℃, add 2-methoxy-5-methyl-4-[(4-methyl-2-nitrophenyl)azo]benzenediazo (T- 4) Stir tetrachlorozincate (2:1) evenly, react for 126.3-137.5 minutes, add ethyl 3-methylthiobutyrate, and feed fluorine with a flow rate of 125.1m ³ /min-166.7m ³ /min Gas for 126.3 to 137.5 minutes; then add the golden leuco body into the multi-pot reactor, start the vapor-sealed steam heat exchanger in the multi-pot reactor again, raise the temperature to 166.2°C to 199.1°C, and keep the heat for 126.6 to 137.7 minutes. Add 2,2'-[(1-methylethylene)bis[[2-(2-propenyl)-4,1-phenylene]oxymethylene]dioxirane with hydrogen-terminated For the polymer of polydimethylsiloxane, adjust the pH value of the solution in the multi-torch reactor to 4.2-8.9, and keep the temperature for 126.2-366.2 minutes;

Step 2: Take another lead nanoparticle and ultrasonically treat the lead nanoparticle at a power of 6.66KW to 12.1KW for 0.132 to 1.199 hours; add the lead nanoparticle to another multi-pot reactor with a mass concentration of 136mg /L～366mg/L of polymerized [oxyl-1,4-phenylene (1-methylethylene)-1,4-phenoxy-1,4-phenyleneiminocarbonyl (di Carboxycyclobutanediyl) carboimino-1,4-phenylene] disperse lead nanoparticles, start the vapor-sealed steam heat exchanger in the multi-pot reactor, and make the solution temperature between 46°C and 86°C, Start the mixer in the multi-pot reactor, and stir at a speed of 4×10 ² rpm to 8×10 ² rpm, adjust the pH value between 4.4 and 8.8, keep stirring for 132 to 199 minutes; then stop the reaction and let it stand for 6.66× 10～12.1×10 minutes, remove impurities; add formaldehyde, dinonylphenol, nonylphenol and ethylene oxide polymer to the suspension, adjust the pH value between 1.4～2.8, form a precipitate and elute with distilled water , the solids were obtained by a centrifuge at a rotational speed of 4.732×10 ³ rpm to 9.23×10 ³ rpm, dried at a temperature of 2.95×10 ² ℃ to 3.419×10 ² ℃, and ground at a temperature of 0.732×10 ³ to 1.23×10 ³ Mesh sieve, spare;

Step 3: Separately take basic copper phosphate and lead nanoparticles treated in step 2, mix them uniformly and then irradiate them with ionizing radiation. The irradiation time is 135.2 to 160.8 minutes, and the mixture of basic copper phosphate and lead nanoparticles with changed properties is obtained; the mixture of basic copper phosphate and lead nanoparticles is placed in another multi-pot reactor, and the steam in the multi-pot reactor is started. Seal the steam heat exchanger, set the temperature at 134.6°C to 180.2°C, start the mixer in the multi-tank reactor with a rotation speed of 126rpm to 521rpm, adjust the pH to 4.1 to 8.1, dehydrate for 135.1 to 149.1 minutes, and set aside;

Step 4: Add the modified basic copper phosphate and lead nanoparticle mixture obtained in step 3 to the 1,1'-methylenebis( isocyanatobenzene), and flow into the multi-pot reactor in the first step, the flow rate is 271mL/min～999mL/min; start the multi-pot reactor mixer, set the speed at 140rpm～180rpm; stir for 4 ~ 8 minutes; then add 7-methyl-octanoic acid, start the vapor-sealed steam heat exchanger in the multi-pot reactor, raise the temperature to 170.7°C ~ 207.5°C, adjust the pH to 4.7 ~ 8.5, and introduce fluorine gas to ventilate 125.293m ³ /min～166.410m ³ /min, heat preservation and standing for 160.0～190.2 minutes; start the multi-pot reactor mixer again, the speed is 135rpm～180rpm, add hexyl formate, and adjust the pH to 4.7～8.5 , heat preservation and standing for 159.3 to 199.5 minutes;

Step 5: Start the mixer in the multi-tank reactor, set the speed at 132rpm to 199rpm, start the steam seal heat exchanger in the multi-tank reactor, and set the temperature in the multi-tank reactor to 1.581×10 ² ℃ ～2.462×10 ² ℃, add polyurethane resin, react for 126.2～137.1 minutes; then add cetyl phosphate potassium salt, start the steam seal steam heat exchanger in the multi-tank reactor, set the temperature in the multi-tank reactor The temperature is 210.6℃～266.7℃, the pH is adjusted to 4.2～8.2, the pressure is 1.32MPa～1.33MPa, and the reaction time is 0.4～0.9 hours; after that, the pressure is reduced to 0MPa, and the temperature is lowered to 126.2℃～137.1℃. The material is fed into the compression molding machine to obtain the resonant filter screen 5-3-2-3;

The particle size of the lead nanoparticles is 140 μm˜150 μm.

The following examples further illustrate the content of the present invention. As the resonant filter screen 5-3-2-3, it is an important component of the present invention. Due to its existence, the service life of the overall equipment has been increased, and it is the safety and security of the overall equipment. Smooth operation plays a key role. Therefore, through the following examples, it is further verified that the resonant filter screen 5-3-2-3 of the present invention exhibits higher physical properties than other related patents.

Example 1

Prepare the resonant filter screen 5-3-2-3 of the present invention according to the following steps, and in parts by weight:

Step 1: In the multi-tank reactor, add 341.0 parts of distilled water and 133.3 parts of 3-methylundecanonitrile, start the mixer in the multi-tank reactor, set the speed at 134rpm, and start the steam seal in the multi-tank reactor Steam heat exchanger, raise the temperature to 149.0°C, add 2-methoxy-5-methyl-4-[(4-methyl-2-nitrophenyl)azo]benzenediazo (T-4 ) 136.2 parts of tetrachlorozincate (2:1) were stirred evenly, and the reaction was carried out for 126.3 minutes, 132.6 parts of 3-methylthiobutyrate ethyl ester were added, and the flow rate was 125.1m ³ /min of fluorine gas for 126.3 minutes; after that Add 135.2 parts of golden-yellow leuco body into the multi-pot reactor, start the vapor seal steam heat exchanger in the multi-pot reactor again, raise the temperature to 166.2°C, keep the temperature for 126.6 minutes, add 2,2'-[(1- Polymer of methylethylene)bis[[2-(2-propenyl)-4,1-phenylene]oxymethylene]dioxirane and hydrogen-terminated polydimethylsiloxane 138.4 parts, adjust the pH value of the solution in the multi-torch reactor to be 4.2, and keep warm for 126.2 minutes;

Step 2: Take 140.9 parts of lead nanoparticles in addition, after the lead nanoparticles are ultrasonically treated for 0.132 hours under the power of 6.66KW; the lead nanoparticles are added to another multi-pot reactor, and the mass concentration is 136mg/L Poly[oxy-1,4-phenylene(1-methylethylene)-1,4-phenyleneoxy-1,4-phenyleneiminocarbyl(dicarboxycyclobutanediyl) Carboimino-1,4-phenylene] 133.5 parts of dispersed lead nanoparticles, start the steam seal steam heat exchanger in the multi-pot reactor, make the solution temperature at 46 ° C, start the stirrer in the multi-pot reactor, and Stir at a speed of 4×10 ² rpm, adjust the pH value to 4.4, and keep stirring for 132 minutes; then stop the reaction and let stand for 6.66×10 minutes to remove impurities; add formaldehyde, dinonylphenol, nonylphenol and cyclic 135.1 parts of the polymer of ethylene oxide, adjust the pH value at 1.4, form a precipitate, elute with distilled water, obtain a solid through a centrifuge at a speed of 4.732×10 ³ rpm, dry it at a temperature of 2.95×10 ² ℃, and grind it Pass through a 0.732×10 ³ mesh sieve and set aside;

Step 3: Take another basic copper phosphate 135.6 and the lead nanoparticles treated in the second step, mix them uniformly and then irradiate them with ionizing radiation. The energy of ionizing radiation is 123.2 MeV, the dose is 171.2 kGy, and the irradiation time is 135.2 minutes. , to obtain a mixture of basic copper phosphate and lead nanoparticles with changed properties; place the mixture of basic copper phosphate and lead nanoparticles in another multi-pot reactor, start the steam-sealed steam heat exchanger in the multi-pot reactor, and set Set the temperature at 134.6°C, start the mixer in the multi-tank reactor, the rotation speed is 126rpm, adjust the pH to 4.1, dehydrate for 135.1 minutes, and set aside;

Step 4: Add the modified basic copper phosphate and lead nanoparticle mixture obtained in step 3 to the 1,1'-methylene bis(isocyanate) with a mass concentration of 136 mg/L. Benzene) in 124.4 parts, and flow into the multi-pot reactor of the first step, the flow rate is 271mL/min; start the multi-pot reactor mixer, set the speed at 140rpm; stir for 4 minutes; then add 7-methyl - 123.2 parts of octanoic acid, start the vapor-sealed steam heat exchanger in the multi-tank reactor, raise the temperature to 170.7°C, adjust the pH to 4.7, feed in fluorine gas with a ventilation rate of 125.293m ³ /min, keep the heat for 160.0 minutes; start again Multi-pot reactor mixer with a rotating speed of 135rpm, adding 132.6 parts of hexyl formate, and adjusting the pH to 4.7, and keeping the temperature for 159.3 minutes;

Step 5: start the mixer in the multi-tank reactor, set the rotating speed to be 132rpm, start the vapor seal steam heat exchanger in the multi-tank reactor, set the temperature in the multi-tank reactor to be 1.581×10 ² ℃, add 142.1 parts of polyurethane resin, reacted for 126.2 minutes; then add 165.7 parts of hexadecyl phosphate potassium salt with a mass concentration of 132 mg/L, start the steam-sealed steam heat exchanger in the multi-tank reactor, set the multi-tank reactor The temperature is 210.6°C, the pH is adjusted to 4.2, the pressure is 1.32MPa, and the reaction time is 0.4 hours; after that, the pressure is reduced to 0MPa, the temperature is lowered to 126.2°C, and the material is discharged into the compression molding machine to obtain the resonance filter 5-3 -2-3; The particle size of the lead nanoparticles is 140 μm.

Example 2

Prepare the resonant filter screen 5-3-2-3 of the present invention according to the following steps, and in parts by weight:

Step 1: In the multi-pot reactor, add 566.2 parts of distilled water and 175.5 parts of 3-methylundecanonitrile, start the mixer in the multi-pot reactor, set the speed at 180rpm, and start the steam seal in the multi-pot reactor Steam heat exchanger, raise the temperature to 150.2°C, add 2-methoxy-5-methyl-4-[(4-methyl-2-nitrophenyl)azo]benzenediazo (T-4 ) 245.1 parts of tetrachlorozincate (2:1) were stirred evenly, and the reaction was carried out for 137.5 minutes, 149.7 parts of ethyl 3-methylthiobutyrate were added, and the flow rate was 166.7m ³ /min of fluorine gas for 137.5 minutes; after that Add 192.9 parts of the golden leuco body into the multi-pot reactor, start the vapor seal steam heat exchanger in the multi-pot reactor again, raise the temperature to 199.1°C, keep the temperature for 137.7 minutes, add 2,2'-[(1- Polymer of methylethylene)bis[[2-(2-propenyl)-4,1-phenylene]oxymethylene]dioxirane and hydrogen-terminated polydimethylsiloxane 199.1 parts, adjust the pH value of the solution in the multi-torch reactor to be 8.9, and keep the temperature for 366.2 minutes;

Step 2: Take 195.2 parts of lead nanoparticles in addition, after the lead nanoparticles are ultrasonically treated for 1.199 hours at a power of 12.1KW; the lead nanoparticles are added to another multi-pot reactor, and the mass concentration is 366mg/L Poly[oxy-1,4-phenylene(1-methylethylene)-1,4-phenyleneoxy-1,4-phenyleneiminocarbyl(dicarboxycyclobutanediyl) Carboimino-1,4-phenylene] 175.9 parts disperse lead nanoparticles, start the steam seal heat exchanger in the multi-pot reactor, make the solution temperature between 86 ° C, start the mixer in the multi-pot reactor , and stirred at a speed of 8×10 ² rpm, adjusted the pH value at 8.8, kept stirring for 199 minutes; then stopped the reaction and stood still for 12.1×10 minutes to remove impurities; added formaldehyde, dinonylphenol and nonylphenol to the suspension and 175.6 parts of the polymer of ethylene oxide, adjust the pH value at 2.8, form a precipitate and elute with distilled water, obtain a solid through a centrifuge at a rotational speed of 9.23×10 ³ rpm, and dry it at a temperature of 3.419×10 ² ℃, Pass through a 1.23×10 ³ -mesh sieve after grinding, and set aside;

Step 3: Take another 158.1 parts of basic copper phosphate and lead nanoparticles treated in step 2, mix them evenly and then irradiate them with ionizing radiation. Minutes, obtain the basic copper phosphate and the lead nanoparticle mixture of character change; Place the basic copper phosphate and the lead nanoparticle mixture in another multi-pot reactor, start the steam-sealed steam heat exchanger in the multi-still reactor, Set the temperature to 180.2°C, start the mixer in the multi-tank reactor, the rotation speed is 521rpm, adjust the pH to 8.1, dehydrate for 149.1 minutes, and set aside;

Step 4: Add the modified basic copper phosphate and lead nanoparticle mixture obtained in step 3 to the 1,1'-methylene bis(isocyanate) with a mass concentration of 366mg/L. Benzene) in 160.8 parts, and flow into the multi-pot reactor of the first step, the flow rate is 999mL/min; start the multi-pot reactor mixer, set the speed at 180rpm; stir for 8 minutes; then add 7-methyl - 166.8 parts of octanoic acid, start the vapor-sealed steam heat exchanger in the multi-tank reactor, raise the temperature to 207.5°C, adjust the pH to 8.5, feed in fluorine gas with a ventilation rate of 166.410m ³ /min, and keep the heat for 190.2 minutes; start again Multi-pot reactor mixer with a rotating speed of 180rpm, adding 177.2 parts of hexyl formate, and adjusting the pH to 8.5, and keeping the temperature for 199.5 minutes;

Step 5: Start the mixer in the multi-tank reactor, set the rotating speed to be 199rpm, start the vapor seal steam heat exchanger in the multi-tank reactor, set the temperature in the multi-tank reactor to be 2.462×10 ² ℃, add 186.1 parts of polyurethane resin, reacted for 137.1 minutes; then add 219.5 parts of hexadecyl phosphate potassium salt with a mass concentration of 399 mg/L, start the steam-sealed steam heat exchanger in the multi-tank reactor, and set the multi-tank reactor The temperature is 266.7°C, the pH is adjusted to 8.2, the pressure is 1.33MPa, and the reaction time is 0.9 hours; after that, the pressure is reduced to 0MPa, the temperature is lowered to 137.1°C, and the material is discharged into the compression molding machine to obtain the resonance filter 5-3 -2-3; The particle size of the lead nanoparticles is 150 μm.

Example 3

Prepare the resonant filter screen 5-3-2-3 of the present invention according to the following steps, and in parts by weight:

Step 1: In the multi-pot reactor, add 341.9 parts of distilled water and 133.9 parts of 3-methylundecanonitrile, start the mixer in the multi-pot reactor, set the speed at 134rpm, and start the steam seal in the multi-pot reactor Steam heat exchanger, raise the temperature to 149.9°C, add 2-methoxy-5-methyl-4-[(4-methyl-2-nitrophenyl)azo]benzenediazo (T-4 ) 136.9 parts of tetrachlorozincate (2:1) were stirred evenly, and the reaction was carried out for 126.9 minutes, 132.9 parts of ethyl 3-methylthiobutyrate were added, and the flow rate was 125.9m ³ /min of fluorine gas for 126.9 minutes; after that Add 135.9 parts of golden-yellow leuco body into the multi-pot reactor, start the vapor seal steam heat exchanger in the multi-pot reactor again, raise the temperature to 166.9°C, keep the temperature for 126.9 minutes, add 2,2'-[(1- Polymer of methylethylene)bis[[2-(2-propenyl)-4,1-phenylene]oxymethylene]dioxirane and hydrogen-terminated polydimethylsiloxane 138.9 parts, adjust the pH value of the solution in the multi-torch reactor to be 4.9, and keep warm for 126.9 minutes;

Step 2: Take another 140.9 parts of lead nanoparticles, and ultrasonically treat the lead nanoparticles at a power of 6.669KW for 0.1329 hours; add the lead nanoparticles to another multi-pot reactor, and add a mass concentration of 136.9mg/L Polymerization of [oxy-1,4-phenylene(1-methylethylene)-1,4-phenoxy-1,4-phenyleneiminocarbyl (dicarboxycyclobutanediyl ) carboimino-1,4-phenylene] 133.9 parts of dispersed lead nanoparticles, start the vapor-sealed steam heat exchanger in the multi-tank reactor, make the solution temperature at 46.9 ° C, start the stirrer in the multi-tank reactor, And stir at a speed of 4.9×10 ² rpm, adjust the pH value to 4.9, keep stirring for 132.9 minutes; then stop the reaction and let stand for 6.66×10 minutes to remove impurities; add formaldehyde, dinonylphenol, nonylphenol and 135.9 parts of the polymer of ethylene oxide, adjust the pH value at 1.9, form a precipitate, elute with distilled water, obtain a solid through a centrifuge at a speed of 4.732×10 ³ rpm, dry at a temperature of 2.95×10 ² ℃, and grind Pass through a 0.732×10 ³ -mesh sieve and set aside;

Step 3: Take another basic copper phosphate 135.9 and the lead nanoparticles treated in the second step, mix them uniformly and then irradiate them with ionizing radiation. The energy of ionizing radiation is 123.9 MeV, the dose is 171.9 kGy, and the irradiation time is 135.9 minutes. , to obtain a mixture of basic copper phosphate and lead nanoparticles with changed properties; place the mixture of basic copper phosphate and lead nanoparticles in another multi-pot reactor, start the steam-sealed steam heat exchanger in the multi-pot reactor, and set Set the temperature at 134.9°C, start the mixer in the multi-kettle reactor, the rotation speed is 126rpm, adjust the pH to 4.9, dehydrate for 135.9 minutes, and set aside;

Step 4: Add the modified basic copper phosphate and lead nanoparticle mixture obtained in step 3 to the 1,1'-methylene bis(isocyanate) with a mass concentration of 136.9 mg/L. benzene) in 124.9 parts, and flow into the multi-pot reactor of the first step, the flow rate is 271.9mL/min; start the multi-pot reactor mixer, set the speed at 140rpm; stir for 4.9 minutes; then add 7- 123.9 parts of methyl-octanoic acid, start the vapor-sealed steam heat exchanger in the multi-tank reactor, raise the temperature to 170.9°C, adjust the pH to 4.9, feed the fluorine gas with a ventilation rate of 125.9m ³ /min, and keep the temperature for 160.9 minutes; Start the mixer of the multi-pot reactor again, the speed is 135rpm, add 132.9 parts of hexyl formate, and adjust the pH to 4.9, and keep it for 159.9 minutes;

Step 5: start the mixer in the multi-tank reactor, set the rotating speed to be 132rpm, start the vapor seal steam heat exchanger in the multi-tank reactor, set the temperature in the multi-tank reactor to be 1.581×10 ² ℃, add 142.9 parts of polyurethane resins, reacted for 126.9 minutes; then add 165.7 parts of cetyl phosphate potassium salt with a mass concentration of 132 mg/L, start the steam-sealed steam heat exchanger in the multi-tank reactor, set the multi-tank reactor The temperature is 210.9°C, the pH is adjusted to 4.9, the pressure is 1.32MPa, and the reaction time is 0.41 hours; after that, the pressure is reduced to 0MPa, the temperature is lowered to 126.9°C, and the material is discharged into the compression molding machine to obtain the resonance filter 5-3 -2-3; The particle size of the lead nanoparticles is 140 μm.

Comparative example

As a control example, a commercially available resonant filter of a certain brand was used for performance testing.

Example 4

The resonant filter screen 5-3-2-3 obtained in Examples 1 to 3 and the comparative example was subjected to a performance test. After the test, the increase rate of compressive strength, the increase rate of deformation resistance, the increase rate of the service life of the separator, Parameters such as the improvement rate of impact resistance were analyzed. Data analysis is shown in Table 1.

It can be seen from Table 1 that the resonant filter screen 5-3-2-3 of the present invention is obviously higher than the products produced in the prior art in related technical indicators.

In addition, as shown in FIG. 8 , in the relevant technical indicators of Examples 1 to 3, they are all significantly better than the products produced by the prior art.

A kind of working method of river water pollution control equipment among the present invention, this method comprises the following several steps:

Step 1: Control the solenoid valve E, solenoid valve C and solenoid valve D to open through the control system 7, supply steam through the steam supply pipeline 3-10, and add steam through the agent injection pipe 3-5 and the agent injection pipe 3-5 respectively Agents, additives, and the liquid entering the agent mixing shell 3-9 evenly enter the honeycomb reactor 3-3, and the reaction is accelerated under the action of steam, and the inorganic flocculant generated after the reaction passes through the mixed agent discharge pipeline 3 -1 discharge;

Step 2, open the liquid inlet solenoid valve 5-1 through the control system 7, use the pressure pump to supply the underground engineering wastewater, and spray it into the turbulent state processor 5 evenly through the spraying pipeline 5-2 and the nozzle, After 15 minutes, start the aeration pump 6-3 and the waterproof motor on the mobile gas transmission station 6 through the control system 7, and open the gas transmission valve 6-5 on the gas transmission pipeline 6-6 at the same time, and pass through the aeration pipe 5 -8 Fresh air is supplied to the turbulent state processor 5 to increase the oxygen content in the turbulent state processor 5 to kill anaerobic microorganisms. After 10 minutes, open the solenoid valve A on the adding pipeline 4 through the control system 7 , add inorganic flocculant to the turbulent flow processor 5, fully react with the sewage, when the sewage falls into the shell 5-4-5 of the sedimentation part, the control system 7 starts the middle storage tank water pump 5-4-7 and The electromagnetic vibrating rod 5-4-1 is fed into the polyaluminum chloride through the polyaluminum chloride dispersing pipe 5-4-4 to degerm, deodorize and decolorize the sewage, and the electromagnetic vibrating rod 5-4-1 is controlled to drive the stable The flow flap 5-4-2 vibrates to a certain extent in the horizontal direction, and the falling sewage is mixed with the inorganic flocculation under the double buffering action of the polymer flow stabilization screen 5-4-3 and the flow stabilization flap 5-4-2. The sediment will fall into the lower part of the shell 5-4-5 of the sedimentation part; after the set time of reaction, the flocculated sediment will be discharged through the mud discharge pipeline 5-9, and the stabilizing flap 5- The clear water near 4-2 is discharged from the drain pipe 5-10 into the liquid collection tank;

In this process, the control system 7 controls the external supply pump to spray sodium dimethyl dithiocarbamate from the sodium dimethyl dithiocarbamate nozzle 5-3-6, and from the turbulent state to promote the reactor 5- 3. The upper part flows into the solution to mix, and reacts under the action of the reaction ball 5-3-4 to improve the efficacy of the medicine; at the same time, the booster impeller 5-3-1 located at the bottom pressurizes the solution, and the final solution is released from the turbulent state of the reactor 5. -3 four-wall through-hole spray; temperature sensing equipment 5-3-5 is a prior art product, FY-45-6F type reaction rate sensor, produced by Shanghai Luji Electromechanical Technology Co., Ltd.;

Step 3: The reaction ball 5-4-3 in the turbulent state adsorber 5-3 adsorbs and degrades the microorganisms in the incoming sewage. During this process, the temperature detector 5-6 monitors the turbulent state processor in real time 5; when it is detected that the temperature is higher than the system set point T, the temperature detector 5-6 feeds back the electrical signal to the control system 7, and the control system 7 controls the alarm connected to it to send an alarm to notify the operator take cooling measures;

Step 4: through the control system 7, connect the power supply of the high-frequency vibrator of the active resonance device 5-3-2, and the resonance head 5-3-2-5 and the transmission rod 5-3-2-2 together generate a larger amplitude vibration, and acts on the resonant filter screen 5-3-2-3 at the upper and lower opening ends of the cylindrical grid housing 5-3-2-1, which promotes the activation of the mixed liquid and allows the liquid to pass through quickly;

Step 5: The liquid level meter 5-7 monitors the liquid level of the mixed liquid in the turbulent flow promoting reactor 5-3 in real time; when the liquid level meter 5-7 detects that the clear water liquid level is higher than the system setting value M, the The meter 5-7 feeds back the signal to the control system 7, and the control system 7 opens the liquid outlet valve 5-5, and discharges the treated clean water in time through the liquid discharge pipeline 5-10;

Step 6: The gas flowmeter 6-4 on the mobile gas transmission station 6 monitors the delivery volume of air in real time; when the gas flowmeter 6-4 detects that the delivery volume is lower than the system set value P, the gas flowmeter 6- 4. Send the feedback signal to the control system 7, and the control system 7 increases the speed of the aeration pump 6-3, and at the same time increases the opening of the gas delivery valve 6-5 to ensure the supply of gas.

Claims (10)

1. a kind of river water contamination treating equipment, including the job platform (2) vacantly installed by bracket one, which is characterized in that It further include that medicament mixing apparatus (3), mobile gas transmission station (6) and control system (7), the side of the job platform (2) pass through Bracket two has vacantly installed Turbulent Flow processor (5), and the medicament mixing apparatus (3) is located at work by pedestal (3-8) fixed branch The lower part of industry platform (2)；

The medicament mixing apparatus (3) includes medicament mixing shell (3-9), the middle part in the medicament mixing shell (3-9) and Lower part is fixedly installed cellular reactor (3-3) and vapor injection line (3-2), the bottom of medicament mixing shell (3-9) respectively Portion is fixedly connected with the confection discharge pipe (3-1) being connected to its inner cavity, and the top of medicament mixing shell (3-9) is fixed to be connected It is connected to the medicament filling line (3-5) and additive charging line (3-4) being connected to its inner cavity, medicament mixing shell (3-9) is interior It is further fixedly arranged on temperature sensor (3-7)；The section of the cellular reactor (3-3) is honeycomb, and up and down, It is made of the standpipe of more honeycomb arrangements；The vapor injection line (3-2) is annular in shape, and upper surface is provided with throughout ground The steam supply pipe road (3-10) of the through-hole being connected to its inner cavity, connection vapor injection line (3-2) is pierced by medicament mixing shell (3-9) is connect with external high steam pipeline afterwards；The outlet end of the confection discharge pipe (3-1) by pressure pump with The liquid feeding end for being fixedly connected on side addition pipeline (4) on Turbulent Flow processor (5) top is fixedly connected, in addition pipeline (4) It is provided with solenoid valve A；The addition pipeline (4), confection discharge pipe (3-1), medicament filling line (3-5), additive Solenoid valve A, solenoid valve B, solenoid valve C, solenoid valve D are respectively arranged on charging line (3-4) and steam supply pipe road (3-10) With solenoid valve E；

The movable type gas transmission station (6) is arranged in the lower part of Turbulent Flow processor (5), and mobile gas transmission station (6) includes that movement is held Support plate (6-2), two pairs of movable pulleys (6-1) for being rotatably connected to the lower part mobile loading plate (6-2) are securely fitted in mobile hold The aeration pump (6-3) on the top support plate (6-2) is connected to gas flowmeter (6-4) and air delivering pipeline at the gas outlet aeration pump (6-3) (6-6), the gas valve (6-5) being arranged on air delivering pipeline (6-6)；

The Turbulent Flow processor (5) includes the turbulent flow shell (5-11) of upper end opening, is fixedly connected on turbulent flow shell (5-11) The spray pipe network of inner cavity middle and upper part is fixedly connected on the Turbulent Flow adsorbing mechanism at middle part, fixation in the inner cavity turbulent flow shell (5-11) It is connected to the aeration tube (5-8) of the inner cavity middle and lower part turbulent flow shell (5-11), is fixed at the internal temperature of turbulent flow shell (5-11) Spend detector (5-6) and liquidometer (5-7)；

The spray pipe network is made of more interconnected spraying pipelines (5-2), and the lower part of every spraying pipeline (5-2) connects It is connected to multiple nozzles being connected to its inner cavity distributed along its length, the inlet tube being fixedly connected with spray pipe network liquid feeding end Road (5-13) is pierced by by the upper end of turbulent flow shell (5-11) and is connect with the water outlet of external water pump, in inlet pipe (5-13) It is connected with liquid inlet electromagnetic valve (5-1), the Turbulent Flow adsorbing mechanism promotees reactor by several Turbulent Flows being distributed in display (5-3) composition, the Turbulent Flow promote reactor (5-3) and include the reaction sphere grid (5-3-3) for being surrounded by tubular construction, can be rotated Ground is set to the supercharging impeller (5-3-1) of reaction sphere grid (5-3-3) intracavity bottom and is fixed at reaction sphere grid (5-3- 3) the active resonance device (5-3-2) of inner cavity lower part；The supercharging impeller (5-3-1) promotees reactor (5-3) by being located at Turbulent Flow The waterproof machine of lower part drives rotation；On the top active resonance device (5-3-2), support has a large amount of reaction sphere (5-3-4), instead Answer the mesh diameter of gap of the outer diameter of ball (5-3-4) greater than reaction sphere grid (5-3-3) and active resonance device (5-3-2)； A large amount of reaction sphere (5-3-4) is full of the upper space of entire reaction sphere grid (5-3-3)；In reaction sphere grid (5-3-3) Portion is provided with temperature sensing device (5-3-5)；Spray equipment, spray equipment packet are additionally provided on the top reaction sphere grid (5-3-3) It includes the sodium dimethyl dithiocarbamate medicament pipe (5-3-7) of annular, be circumferentially uniformly fixedly connected on dimethyl disulfide for ammonia Multiple sodium dimethyl dithiocarbamate spray heads (5-3-6) of the lower part base sodium formate medicament pipe (5-3-7) are thio with methyl two The spray supervisor of the carbamic acid sodium medicament pipe inner cavity (5-3-7) connection connect with external pressure pump；The active resonance dress (5-3-2) is set to include tubular grid shell (5-3-2-1) up and down, be respectively fixedly connected in tubular grid shell (5-3- 2-1) two resonance strainers (5-3-2-3) at upper open end and lower open end, setting inside tubular grid shell (5-3-2-1) There are multiple resonant elements, each resonant element is adjacent by multiple resonance heads (5-3-2-5) equally distributed along its length, connection Multiple drive rods (5-3-2-2) composition between resonance head (5-3-2-5), tubular grid shell (5-3-2-1) is by circumferential uniform More upright bars (5-3-2-4) being arranged and longitudinal gap setting and the lantern ring for being fixedly connected on more upright bar (5-3-2-4) peripheries (5-3-2-6) composition；The resonance head (5-3-2-5) is internally provided with dither, and drive rod (5-3-2-2) is cavity knot Structure, the power supply line of dither are pierced by turbulent flow shell (5-11) and control system (7) after being pierced by by drive rod (5-3-2-2) again Connection；In a ring, upper part is provided with the solarization air cap being connected to its inner cavity to the aeration tube (5-8)；Air delivering pipeline (6-6) goes out Gas end passes through turbulent flow shell (5-11) input end with aeration tube (5-8) afterwards；

The lower part of the turbulent flow shell (5-11) is precipitation section (5-4) funnel-shaped, and the precipitation section (5-4) includes precipitation section Shell (5-4-5), and successively it is fixedly installed dispersal unit, current stabilization buffering from top to bottom inside precipitation section shell (5-4-5) Unit, current stabilization shake unit；Two aluminium polychlorides in rectangular ring that the dispersal unit is arranged side by side in parallel by left and right Dispersion pipe (5-4-4) and the multiple nozzles composition for being evenly connected at each aluminium polychloride dispersion pipe (5-4-4) lower part；It is described Current stabilization buffer cell is made of the multiple macromolecule current stabilization sieves (5-4-3) being longitudinally stacked；Current stabilization concussion unit by From left to right successively multiple current stabilizations of equidistant intervals arrangement shake monomer composition, and the current stabilization concussion monomer is by being fixedly connected on Two electric and magnetic oscillation sticks (5-4-1) of the bottom end precipitation section shell (5-4-5) and it is fixedly connected on two electric and magnetic oscillation sticks (5-4-1) The current stabilization wing plate (5-4-2) of upper end forms, and the vertical section of the current stabilization wing plate (5-4-2) is in the W type toppled over；The precipitation section shell The middle part and lower end of body (5-4-5) are respectively fixedly connected with the drain line (5-10) being connected to its inner cavity and mud line (5- 9) it, is connected separately with mud valve (5-12) and liquid valve (5-5) in the mud line (5-9) and drain line (5-10), is arranged Mud pipeline (5-9) and the liquid feeding end of drain line (5-10) are located at the bottom and middle part of precipitation section shell (5-4-5)；Heavy The outside of shallow lake portion shell (5-4-5) is provided with middle storage tank (5-4-6) and middle storage tank water pump (5-4-7), storage in middle storage tank (5-4-6) There is polymeric aluminum chlorides solution, the liquid feeding end of middle storage tank water pump (5-4-7) passes through the bottom of pipeline and the inner cavity middle storage tank (5-4-6) Perforation connection, the outlet end of middle storage tank water pump (5-4-7) pass through pipeline and two aluminium polychloride dispersion pipes (5-4-4) respectively Inner cavity connection；

Solenoid valve A, aeration pump (6-3), gas flowmeter (6-4), gas valve (6-5), temperature detector (5-6), liquidometer (5- 7), water pump, liquid inlet electromagnetic valve (5-1), mud valve (5-12), liquid valve (5-5), temperature sensor (3-7), solenoid valve B, electromagnetism Valve C, solenoid valve D, electric and magnetic oscillation stick (5-4-1), middle storage tank water pump (5-4-7), waterproof machine, temperature sensing device (5-3-5) It is connect with control system (7) with pressure pump.

2. a kind of river water contamination treating equipment according to claim 1, which is characterized in that the medicament mixing apparatus It (3) further include the washing pipeline (3-6) for being fixedly connected on the top medicament mixing shell (3-9), washing pipeline (3-6) is mixed in medicament It closes the external one end shell (3-9) and the connection of the water outlet of washing water pump, one end inside medicament mixing shell (3-9) and sets The lotus spray-head on the top cellular reactor (3-3) is set to be fixedly connected；Solenoid valve F is provided on the washing pipeline (3-6)； Solenoid valve F is connect with control system (7).

3. a kind of river water contamination treating equipment according to claim 1 or 2, which is characterized in that the drain line (5- 10) water outlet is connected to external collecting tank.

4. a kind of river water contamination treating equipment according to claim 3, which is characterized in that the current stabilization sieve (5-4- 3) mesh aperture is 5mm~16mm；The quantity of current stabilization sieve (5-4-3) is 10；The quantity of current stabilization concussion monomer is 10, the distance between adjacent current stabilization concussion monomer is 2cm~6cm；Two electromagnetic vibrations among the same current stabilization concussion monomer It is distributed to dynamic stick (5-4-1) front-rear direction, and at a distance of 10cm~60cm.

5. a kind of river water contamination treating equipment according to claim 4, which is characterized in that aeration pump (6-3) number Amount is two.

6. a kind of river water contamination treating equipment according to claim 5, which is characterized in that the precipitation section shell (5- It is 4-5) square cone structure；Spraying pipeline (5-2) quantity is no less than 6.

7. a kind of river water contamination treating equipment according to claim 6, which is characterized in that the job platform (2) by Stainless steel plate of the thickness between 1cm~1.5cm is made, and job platform (2) periphery is provided with safety barrier, the safety protective Column height is connected with ladder (1) on the job platform (2) between 80cm~120cm.

8. a kind of river water contamination treating equipment according to claim 7, which is characterized in that the resonance strainer (5-3- It is 2-3) composed of the following components by ratio of weight and the number of copies:

341.0~566.2 parts of distilled water, 133.3~175.5 parts of 3- methyl undecanonitrile, 2- methoxyl group -5- methyl -4- [(4- first Base -2- nitrobenzophenone) azo] four 136.2~245.1 parts of chlorozincate (2:1) of benzene diazonium (T-4), 3- methylmercapto butyric acid ethyl ester 132.6~149.7 parts, 135.2~192.9 parts of golden yellow leuco compound, 2,2'- [(1- methyl ethylidene) bis- [[2- (2- acrylic)- 4,1- phenylenes] Oxymethylene] 138.4~199.1 parts of polymer of dimethyl silicone polymer of bisoxirane and hydrogen sealing end, 140.9~195.2 parts of Pb nanoparticles, it polymerize [Oxy-1, the Asia 4- benzene (1- methyl ethylidene)-Isosorbide-5-Nitrae-Asia phenoxy group-Isosorbide-5-Nitrae-Asia Carbon-based (the dicarboxyl cyclobutane diyl) carbon-based imino group-Isosorbide-5-Nitrae-Asia benzene of phenylimino] 133.5~175.9 parts, formaldehyde and dinonyl 135.1~175.6 parts of the polymer of phenol, nonyl phenol and ethylene oxide, 135.6~158.1 parts of alkali formula cupric phosphate, methyl ethyl ketoxime envelope 124.4~160.8 parts of 1, the 1'- di-2-ethylhexylphosphine oxide (isocyanato- benzene) at end, 123.2~166.8 parts of 7- methyl-octanoic, formic acid 132.6~177.2 parts of own ester, 142.1~186.1 parts of polyurethane resin, mass concentration is the phosphoric acid of 132mg/L~399mg/L 165.7~219.5 parts of cetyl ester sylvite.

9. a kind of river water contamination treating equipment according to claim 8, which is characterized in that the resonance strainer (5-3- 2-3) the production method is as follows:

Step 1: in more kettle reactors, being added distilled water and 3- methyl undecanonitrile, start the blender in more kettle reactors, if Determine revolving speed be 134rpm~180rpm, start the seal steam heat exchanger in more kettle reactors, make temperature rise to 149.0 DEG C~ 150.2 DEG C, four chlorozincate of 2- methoxyl group -5- methyl -4- [(4- methyl -2- nitrobenzophenone) azo] benzene diazonium (T-4) is added (2:1) is stirred evenly, and carries out reaction 126.3~137.5 minutes, 3- methylmercapto butyric acid ethyl ester is added, being passed through flow is 125.1m³/ min~166.7m³The fluorine gas of/min 126.3~137.5 minutes；Golden yellow procrypsis is added in more kettle reactors later Body, the seal steam heat exchanger being again started up in more kettle reactors make temperature rise to 166.2 DEG C~199.1 DEG C, heat preservation 126.6~137.7 minutes, 2,2'- [(1- methyl ethylidene) bis- [[2- (2- acrylic) -4,1- phenylene] oxygen methylenes are added Base] bisoxirane and hydrogen sealing end dimethyl silicone polymer polymer, adjust solution in more kettle reactors pH value be 4.2 ~8.9, keep the temperature 126.2~366.2 minutes；

Step 2: separately taking Pb nanoparticles, by Pb nanoparticles power be 6.66KW~12.1KW under ultrasonication 0.132 After~1.199 hours；Pb nanoparticles are added in another more kettle reactor, addition mass concentration be 136mg/L~ [Oxy-1, the Asia 4- benzene (1- methyl ethylidene) Asia -1,4- phenoxy group -1,4- phenylene imino group are carbon-based for the polymerization of 366mg/L (dicarboxyl cyclobutane diyl) carbon-based imino group-Isosorbide-5-Nitrae-Asia benzene] dispersion Pb nanoparticles, start the seal steam in more kettle reactors Heat exchanger makes solution temperature between 46 DEG C~86 DEG C, starts the blender in more kettle reactors, and with 4 × 10²Rpm~8 ×10²The speed of rpm stirs, and adjusts pH value between 4.4~8.8, and insulated and stirred 132~199 minutes；It is quiet to stop reaction later It sets 6.66 × 10~12.1 × 10 minutes, removes impurity；Formaldehyde and binonylphenol, nonyl phenol and ethylene oxide is added in suspension Polymer, adjust pH value between 1.4~2.8, formed sediment with distillation water elution, by centrifuge in revolving speed 4.732 ×10³Rpm~9.23 × 10³Solid content is obtained under rpm, 2.95 × 10²DEG C~3.419 × 10²It is dry at a temperature of DEG C, grinding 0.732 × 10 is crossed afterwards³~1.23 × 10³Mesh, it is spare；

Step 3: Pb nanoparticles after separately taking alkali formula cupric phosphate and step 2 to handle use ionizing radiation, electricity after mixing Energy from radiation is 123.2MeV~151.8MeV, dosage is 171.2kGy~211.8kGy, irradiation time 135.2 ~160.8 minutes, obtain the alkali formula cupric phosphate and Pb nanoparticles mixture of character change；Alkali formula cupric phosphate and lead nanometer is micro- Grain mixture is placed in another more kettle reactors, starts the seal steam heat exchanger in more kettle reactors, set temperature 134.6 DEG C~180.2 DEG C, start the blender in more kettle reactors, revolving speed is 126rpm~521rpm, pH be adjusted to 4.1~8.1 it Between, it is dehydrated 135.1~149.1 minutes, it is spare；

Step 4: the alkali formula cupric phosphate and Pb nanoparticles mixture that the character that step 3 is obtained changes, adding to mass concentration is In 1, the 1'- di-2-ethylhexylphosphine oxide (isocyanato- benzene) of the methyl ethyl ketoxime sealing end of 136mg/L~366mg/L, cocurrent adds to step 1 In more kettle reactors, flow acceleration is 271mL/min~999mL/min；Start more kettle reaction mechanical stirrers, setting speed is 140rpm~180rpm；Stirring 4~8 minutes；7- methyl-octanoic is added, the seal steam heat started in more kettle reactors is handed over Parallel operation is warming up to 170.7 DEG C~207.5 DEG C, and pH is adjusted between 4.7~8.5, and being passed through fluorine gas ventilatory capacity is 125.293m³/ Min~166.410m³/ min, heat preservation stand 160.0~190.2 minutes；More kettle reaction mechanical stirrers are again started up, revolving speed is 135rpm~180rpm is added hexyl formate, and pH is adjusted between 4.7~8.5, and heat preservation stands 159.3~199.5 points Clock；

Step 5: starting the blender in more kettle reactors, and setting speed is 132rpm~199rpm, starts in more kettle reactors Seal steam heat exchanger, set temperature in more kettle reactors as 1.581 × 10²DEG C~2.462 × 10²DEG C, poly- ammonia is added Ester resin reacts 126.2~137.1 minutes；Phosphoric acid cetyl ester sylvite is added later, starts the packing in more kettle reactors Steam heat-exchanger sets the temperature in more kettle reactors as 210.6 DEG C~266.7 DEG C, and pH is adjusted between 4.2~8.2, pressure Power is 1.32MPa~1.33MPa, and the reaction time is 0.4~0.9 hour；Being depressurized to gauge pressure later is 0MPa, is cooled to 126.2 DEG C~137.1 DEG C discharge into molding press to get to resonance strainer (5-3-2-3).

10. a kind of river water contamination treating equipment according to claim 9, which is characterized in that the Pb nanoparticles Partial size is 140 μm~150 μm.