CN108904311A - A kind of no silicone oil shampoo - Google Patents
A kind of no silicone oil shampoo Download PDFInfo
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- CN108904311A CN108904311A CN201811160305.3A CN201811160305A CN108904311A CN 108904311 A CN108904311 A CN 108904311A CN 201811160305 A CN201811160305 A CN 201811160305A CN 108904311 A CN108904311 A CN 108904311A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/345—Alcohols containing more than one hydroxy group
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/365—Hydroxycarboxylic acids; Ketocarboxylic acids
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
- A61K8/375—Esters of carboxylic acids the alcohol moiety containing more than one hydroxy group
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/42—Amides
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/60—Sugars; Derivatives thereof
- A61K8/602—Glycosides, e.g. rutin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/86—Polyethers
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/30—Characterized by the absence of a particular group of ingredients
- A61K2800/34—Free of silicones
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Abstract
The invention belongs to daily cosmetics fields, and in particular to a kind of no silicone oil shampoo.A kind of no silicone oil shampoo, by weight percentage, raw material composition includes：Propylene glycol 0.1-2%；Cation opsonizing agent 0.05-0.5%；Coconut oil list isopropanol amide 0.5-3%；Disodium ethylene diamine tetraacetate 0.05-0.2%；Citric acid 0.05-0.5%；Sodium citrate 0.05-2%；Anionic surfactant 10-21%；Gel water-in-oil emulsion composition 0.1-2%；PEG-7 cocounut oil acid glyceride 2-4%；Zwitterionic surfactant 1-9%；Essence 0.05-1%；Cithrol 0.1-1%；Inorganic salts thickener 0.1-2%；Alkyl glycosides 1-3%；Preservative 0.0001-0.1%；Pigment 0.0001-0.01%；Water 53-83%.Inventive formulation significant decrease is stimulated caused by scalp, widely applied silicone oil in gel water-in-oil emulsion composition substitution shampoo in formula, it is attached to hair surface layer and repairs the hair scale piece being damaged, scalp can be made clearly to breathe freely, solve because silicone oil deposition caused by hair it is flat collapse, hair follicle blocking, alopecia hair loss the problems such as.
Description
Technical field
The invention belongs to daily cosmetics fields, and in particular to a kind of no silicone oil shampoo.
Background technique
Shampoo also known as shampoo, be a kind of collection Surfactants solution, oily matter solubilising, dispersion suspend, high score
The complex system that sub- colloidal solution is integrated.The major function of shampoo is cleaning hair and scalp, and is beaten for the maintenance of hair
Lower basis.With the development of technology, also increasingly increase the effect of shampoo, nowadays have evolved into degreasing, anti-dandruff, taste
The product of the multiple functions such as profit, hair care, anticreep, hair tonic.Now, while people pursue conditioning effect, shampoo is also required
Adverse effect will not be generated to scalp, hair and human health.And the conditioning ingredients in most of shampoo have skin
Certain irritation, and smooth feel is brought to moisten hair, usually using silicone oil conditioner.It is used for a long time siliceous
The shampoo of oil, silicone oil easily adsorb and are deposited on scalp, are difficult to rinse on hair, make that hair is greasy, it is short-tempered to dry up or even is easy to draw
Play dandruff problem.
In view of the above problems, the present invention provides a kind of no silicone oil shampoos, wherein using the gel oil of air permeable humidity retaining
Water-in type emulsion compositions replace silicone oil to be attached on hair, fill up and repair impaired hair scale piece.And in shampoo product,
Gel water-in-oil emulsion composition and coconut oil list isopropanol amide show synergistic function, a small amount of efficient promotion
System stability reduces the stimulation to skin, enhances the moistening effect of shampoo.
Summary of the invention
Above-mentioned technical purpose of the invention technical scheme is that：
A kind of no silicone oil shampoo, by mass percentage, raw material composition includes：
Propylene glycol 0.1-2%；Cation opsonizing agent 0.05-0.5%；Coconut oil list isopropanol amide 0.5-3%；Ethylenediamine
Tetraacethyl disodium 0.05-0.2%；Citric acid 0.05-0.5%；Sodium citrate 0.05-2%；；Anionic surfactant 10-
21%；Gel water-in-oil emulsion composition 0.1-2%；PEG-7 cocounut oil acid glyceride 2-4%；Amphoteric ion surface-active
Agent 1-9%；Essence 0.05-1%；Cithrol 0.1-1%；Inorganic salts thickener 0.1-2%；Alkyl glycosides 1-
3%；Preservative 0.0001-0.1%；Pigment 0.0001-0.01%；Water 53-83%.
Preferably, a kind of no silicone oil shampoo, by mass percentage, raw material composition includes：
Propylene glycol 0.1-2%；Guar hydroxypropyltrimonium ammonium chloride 0.05-0.5%；Coconut oil list isopropanol amide
0.5-3%；Disodium ethylene diamine tetraacetate 0.05-0.2%；Citric acid 0.05-0.5%；Sodium citrate 0.05-2%；Dodecyl
Sodium sulphate 0.5-3%；Sodium sulfate of polyethenoxy ether of fatty alcohol 10-17%；Gel water-in-oil emulsion composition 0.1-2%；
PEG-7 cocounut oil acid glyceride 2-4%；Cocoamidopropyl betaine 1-9%；Essence menthol 0.05-1%；PEG-6000 bis-
Stearate 0.1-1%；Sodium chloride 0.1-2%；APG0810 alkyl glycosides 1-3%；Kathon CG 0.0001-0.1%；Lemon yellow
0.0001-0.01%；Brilliant blue 0.0001-0.01%；Water 53-83%.
It is further preferred that a kind of no silicone oil shampoo, by mass percentage, composed of the following components：
Propylene glycol 0.5%；Guar hydroxypropyltrimonium ammonium chloride 0.15%；Coconut oil list isopropanol amide 1%；Second two
Amine tetraacethyl disodium 0.1%；Citric acid 0.15%；Sodium citrate 1.25%；Lauryl sodium sulfate 1%；Fatty alcohol polyoxy second
Alkene ether sodium sulfate 14%；Gel water-in-oil emulsion composition 1%；PEG-7 cocounut oil acid glyceride 2%；Cocamidopropyl propyl amide
Glycine betaine 3.33%；Essence menthol 0.1%；PEG-6000 distearate 0.6%；APG0810 alkyl glycosides 1.5%；Chlorine
Change sodium 0.5%；Kathon CG 0.04%；Lemon yellow 0.0004%；Brilliant blue 0.0004%；Surplus is water.
Preferably, the gel water-in-oil emulsion composition is trimethylolpropane tris caprylate, saualane, Ci A
The composition of dry tree benevolence oil, polyglycereol -2 three isostearates and water, by mass percentage, raw material composition includes：60-
80% trimethylolpropane tris caprylate；The saualane of 1-10%；The thorn A Gan tree benevolence oil of 1-10%；Gathering for 1-10% is sweet
Oily -2 three isostearates；The water of 1-10%.
It is further preferred that the gel water-in-oil emulsion composition is prepared by following methods：
(1) by the trimethylolpropane tris caprylate of 60-80%, the thorn A Gan tree benevolence of the saualane of 1-10%, 1-10%
Oil is put into oily phase pot, stirs evenly, obtain mixed liquor A；(2) three isostearate of the polyglycereol -2 of 1-10% is added mixed
Where closing liquid A in oily phase pot, stirs evenly, obtain oil-phase solution；(3) water of 1-10% is slowly pumped into above-mentioned oil-phase solution
In, it stirs at low speed, a kind of gel water-in-oil emulsion composition is prepared.
Preferably, the cation opsonizing agent is guar hydroxypropyltrimonium ammonium chloride, Polyquaternium-10 and polyquaternary amine
One of salt -7 is a variety of.
It is further preferred that the cation opsonizing agent is guar hydroxypropyltrimonium ammonium chloride.
Preferably, the anionic surfactant is lauryl sodium sulfate, ammonium lauryl sulfate, fatty alcohol polyoxy
One of ethylene ether sodium sulfate, alpha-olefin sodium sulfonate, fatty alcohol polyoxyethylene ether ammonium sulfate and lauric acid sodium taurocholate are more
Kind.
It is further preferred that the anionic surfactant is lauryl sodium sulfate, fatty alcohol polyoxyethylene ether sulphur
The weight ratio of the composition of sour sodium, the lauryl sodium sulfate and sodium sulfate of polyethenoxy ether of fatty alcohol is 1:14-16.
Preferably, the inorganic salts thickener is sodium chloride.
Preferably, the cithrol is PEG-6000 distearate.
Preferably, the alkyl glycosides is APG-0810 alkyl glycosides, APG-1220 alkyl glycosides, APG-0814 alkyl sugar
One of glycosides is a variety of.
It is further preferred that the alkyl glycosides is APG-0810 alkyl glycosides.
Preferably, the zwitterionic surfactant is Cocoamidopropyl betaine, dodecyl dimethyl beet
One of alkali and palmitamide propyl betaine are a variety of.
It is further preferred that the zwitterionic surfactant is Cocoamidopropyl betaine.
Preferably, the preservative is one of Kathon CG, sodium benzoate, Phenoxyethanol, paraben esters or a variety of.
It is further preferred that the preservative is Kathon CG.
Preferably, the pigment is one of brilliant blue, lemon yellow or a variety of.
It is further preferred that the pigment is brilliant blue, the composition in lemon yellow, sunset yellow, the brilliant blue and lemon yellow
Weight ratio be 1:1.
The present invention also provides a kind of preparation method of no silicone oil shampoo, the preparation method is comprised the steps of：
(1) cation opsonizing agent and citric acid are added to the water, homogeneous is transparent to solution, is warming up to 70-80 DEG C, is mixed
Close solution A；
(2) under 70-80 DEG C and stirring condition, by disodium ethylene diamine tetraacetate, sodium citrate, cithrol,
Anionic surfactant, coconut oil list isopropanol amide are added in mixed solution A, obtain mixed solution B；
(3) PEG-7 cocounut oil acid glyceride and gel water-in-oil emulsion composition are mixed, obtains mixed solution C；
(4) zwitterionic surfactant, alkyl glycosides and mixed solution C are added in mixed solution B, at 70-80 DEG C
Lower stirring keeps the temperature 30min, obtains mixed solution D；
(5) solution D to be mixed is cooled to 25-45 DEG C, and propylene glycol, essence, citric acid, preservative, pigment, sodium chloride are added
Enter and mixed in mixed solution D, stirred evenly, the no silicone oil shampoo is made.
Compared with prior art, the beneficial effects of the present invention are：
It joined the gel water-in-oil emulsion composition quite similar with scalp sebum structure in inventive formulation, show
Writing to reduce stimulates caused by scalp, improves safety.Gel water-in-oil emulsion composition in formula can substitute hair washing
Widely applied silicone oil in water is attached to hair surface layer and repairs the hair scale piece being damaged, and the trimethylolpropane tris contained is pungent
The superior ventilation property that acid esters has can make scalp clearly breathe freely, solve because silicone oil deposition caused by hair it is flat collapse, hair follicle blocking,
The problems such as alopecia hair loss.The complex role of gel water-in-oil emulsion composition and coconut oil list isopropanol amide, reduces
Stimulation to skin enhances the moistening effect of shampoo.It is of the invention without silicone oil shampoo foaming abundancy, stabilization, can be effective
Scalp reconstruction hair damage is nourished, carrys out efficient moisture-retention to hair carry, moisten the effect repaired, scalp is protected and maintains hair healthy
State meets the demand that current consumer washes head protector hair to health.
Specific embodiment
Embodiment of the present invention is described in detail below in conjunction with specific embodiment, the embodiment provided is only
Reach illustration purpose, can not be interpreted as limitation of the invention.Constituent content in following embodiments, such as without special theory
It is bright, it is mass percent.
Embodiment 1-6
Embodiment 1-3 is the shampoo prepared according to inventive formulation, and contained component includes guar hydroxypropyltrimonium chlorine
Change ammonium, propylene glycol, coconut oil list isopropanol amide (CMIPA), disodium ethylene diamine tetraacetate (EDTA-2Na), citric acid, lemon
Sour sodium, lauryl sodium sulfate (K12), sodium sulfate of polyethenoxy ether of fatty alcohol (AES), the combination of gel water-in-oil emulsion
Object, PEG-7 cocounut oil acid glyceride (HE), Cocoamidopropyl betaine (CAB), essence (menthol), PEG-6000 distearyl
Acid esters, APG-0810 alkyl glycosides, sodium chloride, Kathon CG, lemon yellow, brilliant blue, water.
Embodiment 4-6 is the shampoo prepared according to inventive formulation, and contained component includes guar hydroxypropyltrimonium
Ammonium chloride, Polyquaternium-10, propylene glycol, CMIPA, EDTA-2Na, citric acid, sodium citrate, K12, ammonium lauryl sulfate
(K12A), laureth ammonium sulfate (AESA), alpha-olefin sodium sulfonate, gel water-in-oil emulsion composition, HE, CAB, ten
Dialkyl dimethyl glycine betaine, menthol, PEG-6000 distearate, APG-0810 alkyl glycosides, sodium chloride, Kathon CG, lemon
Lemon Huang, brilliant blue, water.
Comparative example 7-9
Component contained by comparative example 7-9 includes guar hydroxypropyltrimonium ammonium chloride, propylene glycol, cation flocculation guarantor
Wet conditioner (QZ-1001), coconut oil fatty acid monoethanolamide (CMEA), cocounut oil acid methyl single ethanol amide (CMMEA), second
Edetate disodium (EDTA-2Na), citric acid, sodium citrate, lauryl sodium sulfate (K12), fatty alcohol polyoxyethylene ether
Sodium sulphate (AES), gel water-in-oil emulsion composition, PEG-7 cocounut oil acid glyceride (HE), Cocoamidopropyl betaine
(CAB), essence (menthol), PEG-6000 distearate, APG-0810 alkyl glycosides, sodium chloride, Kathon CG, lemon yellow, bright
Blue, water.
Cation flocculation moisture-regulating agent (QZ-1001) is that our company is commercially available by polyquaternium -49, pyrrolidones carboxylic
The compound that sour sodium, sodium lactate, sodium citrate, glutamic acid, water compound.
Comparative example 7, with inventive formulation the difference is that CMIPA is substituted for CMEA.
Comparative example 8, with inventive formulation the difference is that the QZ-1001 of addition 2%, CMIPA is substituted for
CMEA。
Comparative example 9 with inventive formulation the difference is that CMIPA is substituted for CMMEA, and adds 2%
QZ-1001。
A kind of preparation of gel water-in-oil emulsion composition
A kind of gel water-in-oil emulsion composition, constitutive material are as follows：70% trimethylolpropane tris octanoic acid
Ester；5% saualane；5% thorn A Gan tree benevolence oil；10% three isostearate of polyglycereol -2；10% water.
The gel water-in-oil emulsion composition, is prepared by following methods：
(1) weigh 70% trimethylolpropane tris caprylate, 5% saualane, 5% thorn A Gan tree benevolence oil, be put into
In oily phase pot, stirs evenly, obtain mixed liquor A；(2) mixed liquor A institute is added in three isostearate of polyglycereol -2 for weighing 10%
In oily phase pot, stirs evenly, obtain oil-phase solution；(3) 10% water is slowly pumped into above-mentioned oil-phase solution, low speed stirs
It mixes, a kind of gel water-in-oil emulsion composition is prepared.
Component information contained by embodiment 1-3 is as shown in table 1, and component information contained by embodiment 4-6 is as shown in table 2, real
It is as shown in table 3 to apply component information contained by a 7-9.
The component information table of 1 embodiment 1-3 of table
The component information table of 2 embodiment 4-6 of table
The component information table of 3 embodiment 7-9 of table
A kind of preparation of no silicone oil shampoo
In embodiment 1-6 without silicone oil shampoo, be prepared by the following method：
(1) guar hydroxypropyltrimonium ammonium chloride/Polyquaternium-10, a small amount of citric acid are put into water, and homogeneous is formed
Transparency liquid is warming up to 75 DEG C, obtains mixed solution A；
(2) by EDTA-2Na, sodium citrate, PEG-6000 distearate, K12/K12A, AES/AESA/ alpha-olefin sulphur
Sour sodium, is put into mixed solution A CMIPA, and temperature is maintained at 75 DEG C, and stirring forms transparent clear solution, obtains mixed solution
B；
(3) HE and gel water-in-oil emulsion composition are mixed, obtains mixed solution C；
(4) by CAB/ dodecyldimethylammonium hydroxide inner salt, APG-0810 alkyl glycosides/APG-1220 alkyl glycosides and mixing
Solution C is added in mixed solution B, stirs at 75 DEG C, keeps the temperature 30min, obtains mixed solution D；
(5) solution D to be mixed is cooled to 30-45 DEG C hereinafter, propylene glycol is uniformly mixed with essence (menthol), with lemon
Acid, Kathon CG, lemon yellow, brilliant blue put into mixed solution D and mix, and sodium chloride is added, stirs evenly, and a kind of no silicone oil hair washing is made
Water.
The preparation method of embodiment 7-9 shampoo is identical as embodiment 1-6, and CMIPA is only substituted for CMEA or CMMEA,
The cation flocculation moisture-regulating agent added in comparative example 8-9 is added in step (1).
Testing example 1：Stability experiment
The stability test experiment condition of hair washing is respectively：Shampoo is placed at 40 DEG C for 24 hours by heat-resistant stability, extensive
Whether there is or not laminations for observation after multiple room temperature；Shampoo is placed under 5 DEG C of refrigerating chamber for 24 hours, restores room temperature by cold resistance stability
After observe phenomenon.And be placed on shampoo under -10 DEG C of freezing chamber for 24 hours, phenomenon is observed after restoring room temperature, test result is such as
Shown in table 4.
The stability test result of 4 embodiment 1-9 of table
Although cation flocculation moisture-regulating agent in comparative example 8-9, its stablizing effect is not as good as using of the invention
The embodiment 1-6 of formula, opsonic action are unable to give full play, and the synergistic stability effect between component is not as good as embodiment 1-6.Comparison
CMIPA is substituted for CMEA by embodiment 7, but this formula system stability is still poor, can only keep temporary stabilization, be unfavorable for
Long-term preservation in shampoo industrial production and practical application.
Testing example 2：Applied experiments
(A is the siliceous shampoo of certain brand of market sale, certain product that B is market sale to the comparison of this product practical experiment
Board without silicone oil shampoo, C be in inventive formulation described in embodiment 2 without silicone oil shampoo).
Test equipment：Comb force tester.
Test sample：Import topknot (30 ± 1cm of length, 10 ± 1g of weight).
Test method：The dry and wet carding force for first surveying blank topknot, after 2g hair washing water process hair, test hair washing water process
The dry and wet carding force of topknot afterwards, the relatively variation of front and back carding force.Flushing period 30s, resistance unit are newton, and test result is such as
Shown in table 5.
The test result contrast table of shampoo described in 5 commercial product of table and embodiment 2
Embodiment 1 and 3-6 retest embodiment 2 obtain contrast effect even more preferably similar with table 5, wherein
The wet carding force of embodiment 1 and 3-6 reduce 78.11%, 77.42%, 80.09%, 79.84%, 78.88% respectively；Dry comb
Reason power reduces 53.26%, 52.87%, 55.21%, 50.81%, 55.40% respectively.
In conclusion the present invention by a large number of experiments adjust each component ratio, reached raising product overall stability,
Comprehensive hair washing improves, the purpose of hair care effect.Shampoo synergistic stability effect in inventive formulation is stronger, is able to maintain excellent
Good stability.Meanwhile the gel water-in-oil emulsion composition in formula can substitute widely applied silicon in shampoo again
Oil is attached to hair surface layer and repairs the hair scale piece being damaged, scalp is made clearly to breathe freely, and hair is flat caused by solving because of silicone oil deposition
Collapse, hair follicle blocking, alopecia hair loss the problems such as.A kind of no silicone oil shampoo provided by the invention carrys out the effect of efficient moisture-retention to hair carry
Fruit effectively keeps scalp and hair healthy state, meets the demand that current consumer washes head protector hair to health.
Claims (10)
1. a kind of no silicone oil shampoo, which is characterized in that by mass percentage, raw material composition includes：Propylene glycol 0.1-
2%；Cation opsonizing agent 0.05-0.5%；Coconut oil list isopropanol amide 0.5-3%；Disodium ethylene diamine tetraacetate 0.05-
0.2%；Citric acid 0.05-0.5%；Sodium citrate 0.05-2%；；Anionic surfactant 10-21%；Gel Water-In-Oil
Type emulsion compositions 0.1-2%；PEG-7 cocounut oil acid glyceride 2-4%；Zwitterionic surfactant 1-9%；Essence 0.05-
1%；Cithrol 0.1-1%；Inorganic salts thickener 0.1-2%；Alkyl glycosides 1-3%；Preservative 0.0001-
0.1%；Pigment 0.0001-0.01%；Water 53-83%.
2. a kind of no silicone oil shampoo as described in claim 1, which is characterized in that by mass percentage, raw material composition
Including：Propylene glycol 0.1-2%；Guar hydroxypropyltrimonium ammonium chloride 0.05-0.5%；Coconut oil list isopropanol amide 0.5-
3%；Disodium ethylene diamine tetraacetate 0.05-0.2%；Citric acid 0.05-0.5%；Sodium citrate 0.05-2%；；Dodecyl sulphur
Sour sodium 0.5-3%；Sodium sulfate of polyethenoxy ether of fatty alcohol 10-17%；Gel water-in-oil emulsion composition 0.1-2%；
PEG-7 cocounut oil acid glyceride 2-4%；Cocoamidopropyl betaine 1-9%；Menthol 0.05-1%；PEG-6000 distearyl
Acid esters 0.1-1%；Sodium chloride 0.1-2%；APG0810 alkyl glycosides 1-3%；Kathon CG 0.0001-0.1%；Lemon yellow 0.0001-
0.01%；Brilliant blue 0.0001-0.01%；Water 53-83%.
3. a kind of no silicone oil shampoo as claimed in claim 1 or 2, which is characterized in that the gel water-in-oil emulsion
Composition is to prepare gained with the following method：By weight percentage, raw material is taken：The trimethylolpropane tris of 60-80% is pungent
Acid esters, the saualane of 1-10%, 1-10% thorn A Gan tree benevolence oil, -2 three isostearate of 1-10% polyglycereol, 1-10%
Water；
Step 1)：By the trimethylolpropane tris caprylate of 60-80%, the thorn A Gan tree benevolence of the saualane of 1-10%, 1-10%
Oil is added in oily phase pot, stirs evenly, obtains mixed liquor A；
Step 2)：Where mixed liquor A is added in three isostearate of polyglycereol -2 of 1-10% in oily phase pot, stirs evenly, obtain
To oil-phase solution；
Step 3)：The water of 1-10% is slowly pumped into above-mentioned oil-phase solution, stirs at low speed and the gel oil packet is prepared
Water emulsion composition.
4. a kind of no silicone oil shampoo as described in claim 1, which is characterized in that the cation opsonizing agent is guar gum hydroxyl
One of hydroxypropyltrimonium chloride, Polyquaternium-10 and polyquaternium -7 are a variety of.
5. a kind of no silicone oil shampoo as described in claim 1, which is characterized in that the anionic surfactant is 12
Sodium alkyl sulfate, ammonium lauryl sulfate, sodium sulfate of polyethenoxy ether of fatty alcohol, alpha-olefin sodium sulfonate, aliphatic alcohol polyethenoxy
One of ether ammonium sulfate and lauric acid sodium taurocholate are a variety of.
6. a kind of no silicone oil shampoo as described in claim 1, which is characterized in that the zwitterionic surfactant is coconut palm
One of oleamide propyl betaine, dodecyldimethylammonium hydroxide inner salt and palmitamide propyl betaine are a variety of.
7. a kind of no silicone oil shampoo as described in claim 1, which is characterized in that the preservative be Kathon CG, sodium benzoate,
One of Phenoxyethanol, paraben esters are a variety of.
8. a kind of no silicone oil shampoo as described in claim 1, which is characterized in that the pigment is brilliant blue, lemon yellow, sunset
One of Huang is a variety of.
9. a kind of no silicone oil shampoo as described in claim 1, which is characterized in that the alkyl glycosides is APG-0810 alkyl
One of glucosides, APG-1220 alkyl glycosides, APG-0814 alkyl glycosides are a variety of.
10. a kind of prepare the method without silicone oil shampoo using raw material described in claim 1, which is characterized in that the preparation side
In method, ratio used in each raw material is as described in claim 1, comprises the steps of：
(1) cation opsonizing agent and citric acid are added to the water, homogeneous is transparent to solution, is warming up to 70-80 DEG C, obtains mixing molten
Liquid A；
(2) under 70-80 DEG C and stirring condition, by disodium ethylene diamine tetraacetate, sodium citrate, cithrol, yin from
Sub- surfactant, coconut oil list isopropanol amide are added in mixed solution A, obtain mixed solution B；
(3) PEG-7 cocounut oil acid glyceride and gel water-in-oil emulsion composition are mixed, obtains mixed solution C；
(4) zwitterionic surfactant, alkyl glycosides and mixed solution C are added in mixed solution B, are stirred at 70-80 DEG C
It mixes, keeps the temperature 30min, obtain mixed solution D；
(5) solution D to be mixed is cooled to 25-45 DEG C, propylene glycol, essence, citric acid, preservative, pigment, sodium chloride is added mixed
It closes and is mixed in solution D, stir evenly, the no silicone oil shampoo is made.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201811160305.3A CN108904311A (en) | 2018-09-30 | 2018-09-30 | A kind of no silicone oil shampoo |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201811160305.3A CN108904311A (en) | 2018-09-30 | 2018-09-30 | A kind of no silicone oil shampoo |
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| CN201811160305.3A Pending CN108904311A (en) | 2018-09-30 | 2018-09-30 | A kind of no silicone oil shampoo |
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| CN111437229A (en) * | 2020-05-28 | 2020-07-24 | 赵双 | Shampoo product capable of purifying scalp and improving hair and preparation method thereof |
| WO2021101458A1 (en) * | 2019-11-21 | 2021-05-27 | Cetin Aydin | Lotion for hair and hair skin |
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