CN108892970A - A kind of extracting method and its application method of vegetalitas batik pigment - Google Patents
A kind of extracting method and its application method of vegetalitas batik pigment Download PDFInfo
- Publication number
- CN108892970A CN108892970A CN201810428381.1A CN201810428381A CN108892970A CN 108892970 A CN108892970 A CN 108892970A CN 201810428381 A CN201810428381 A CN 201810428381A CN 108892970 A CN108892970 A CN 108892970A
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- China
- Prior art keywords
- pigment
- batik
- vegetalitas
- fabric
- application method
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- 239000000049 pigment Substances 0.000 title claims abstract description 39
- 238000000034 method Methods 0.000 title claims abstract description 28
- 239000004744 fabric Substances 0.000 claims abstract description 16
- 238000000605 extraction Methods 0.000 claims abstract description 12
- 241001517312 Calanthe Species 0.000 claims abstract description 9
- 241000123870 Geum aleppicum Species 0.000 claims abstract description 9
- 235000014266 Geum aleppicum Nutrition 0.000 claims abstract description 9
- 241001062009 Indigofera Species 0.000 claims abstract description 8
- 229940037003 alum Drugs 0.000 claims abstract description 8
- 239000000843 powder Substances 0.000 claims abstract description 8
- 238000002360 preparation method Methods 0.000 claims abstract description 6
- 238000000194 supercritical-fluid extraction Methods 0.000 claims abstract description 4
- 239000000975 dye Substances 0.000 claims description 20
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 12
- 239000000284 extract Substances 0.000 claims description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- 235000019441 ethanol Nutrition 0.000 claims description 6
- 235000013312 flour Nutrition 0.000 claims description 5
- 239000002994 raw material Substances 0.000 claims description 5
- 239000012153 distilled water Substances 0.000 claims description 3
- 239000012530 fluid Substances 0.000 claims description 3
- 239000012467 final product Substances 0.000 claims description 2
- 244000292697 Polygonum aviculare Species 0.000 claims 1
- 239000007788 liquid Substances 0.000 claims 1
- 238000004043 dyeing Methods 0.000 abstract description 9
- 238000005516 engineering process Methods 0.000 abstract description 2
- 230000003647 oxidation Effects 0.000 abstract description 2
- 238000007254 oxidation reaction Methods 0.000 abstract description 2
- 238000007639 printing Methods 0.000 abstract description 2
- 238000010298 pulverizing process Methods 0.000 abstract 1
- 241000196324 Embryophyta Species 0.000 description 12
- 230000000694 effects Effects 0.000 description 3
- WITLAWYGGVAFLU-UHFFFAOYSA-N 3-(6-methoxy-1,3-benzodioxol-5-yl)-8,8-dimethylpyrano[2,3-f]chromen-4-one Chemical compound C1=CC(C)(C)OC2=CC=C(C(C(C3=CC=4OCOC=4C=C3OC)=CO3)=O)C3=C21 WITLAWYGGVAFLU-UHFFFAOYSA-N 0.000 description 2
- 229930182559 Natural dye Natural products 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 239000000978 natural dye Substances 0.000 description 2
- 108010082495 Dietary Plant Proteins Proteins 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 230000000536 complexating effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910001410 inorganic ion Inorganic materials 0.000 description 1
- 238000009940 knitting Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 238000000859 sublimation Methods 0.000 description 1
- 230000008022 sublimation Effects 0.000 description 1
- 230000002459 sustained effect Effects 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 238000012549 training Methods 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
- 239000001052 yellow pigment Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B61/00—Dyes of natural origin prepared from natural sources, e.g. vegetable sources
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0096—Purification; Precipitation; Filtration
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/34—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using natural dyestuffs
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/54—Improvements relating to the production of bulk chemicals using solvents, e.g. supercritical solvents or ionic liquids
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Coloring (AREA)
Abstract
The invention discloses the extracting methods and its application method of a kind of vegetalitas batik pigment, are related to wax printing technology field.The extracting method is first by indigo plant, yellow avens, calanthe Ordinary pulverization, then pulverizes, and the vegetalitas batik pigment then is made in Ultramicro-powder means of supercritical extraction；Application method of the invention is：First fabric is added in alum solution, is impregnated, is placed into boil in dye solution and dry, the method for the present invention extraction efficiency is high, the pigment solubility of preparation is good, and rapidly, dyeing efficiency is high for oxidation, and pigment storage of the present invention is conveniently, using simplicity, has excellent economic value.
Description
Technical field
The present invention relates to wax printing technology field, in particular to the extracting method of a kind of vegetalitas batik pigment and its user
Method.
Background technique
Natural plant dye is nontoxic, ecology, and color is soft, certainly however characteristic, and it has good environment compatible
Property and medicinal health-care performance, there is vast potential for future development.It is most of logical from the point of view of the dyeing of current natural plant dye
Water or solvent are crossed by heating extraction dyestuff, and the dyeing that dye liquor is directly used in textile (is gone into business, Gong builds training frequently seen plants
The pigment of dyestuff yellow class extracts and dyeing, dyeing and finishing technique [J], and volume 2006,28 (3)：24-27；Chinese invention patent discloses
Number：CN 1204667, a kind of natural plant pure yellow pigment for blanket kind and its preparation and application).The method has a disadvantage that,
1. dye moiety is thermally decomposed, the sublimation characteristics of stability difference 2. natural plant dye are destroyed 3. perishable, should not be stored
4. reproducibility is difficult to grasp (current situation and development of Yu Jing, Jia Li rosy clouds natural dye application, new to weave [J], 2005 (4)：
26-28).For by Cortex Phellodendri, natural plants Cortex Phellodendri by conditions such as geographical environment, weather, seasons because being influenced, institute in bark
Content containing jamaicin will be different, thus its pigment content is also different.The number of vegetable colour pigment content by it is above-mentioned because
Element influences very big, this makes even if same strain plant because that can be not quite similar amount of pigment contained by plucking time difference plant,
For dyeing and weaving object reproducibility as one can imagine.Furthermore due to there is partial pigment unstable in natural plant dye, in different realities
It carries out being also possible to obvious color difference occur when repeated experiment under the conditions of testing, substantially be wanted every time in practical application
Again it extracts, filter, and cause each pigment content not energetic, be also just even more that reproducibility is difficult to realize.
Currently, the natural plant dye of the method and quality stabilization, function admirable that lack mature extraction natural plant dye produces
Product consume high craftwork batik, regulation and standardization, the high-efficiency reform of conventional natural dye especially as a kind of dyestuff
It is more urgent.
Summary of the invention
For the defect for overcoming the above-mentioned prior art, the present invention provides a kind of extracting method of vegetalitas batik pigment and its makes
With method, to promote the high-efficiency reform of batik pigment, and the dyeing effect of pigment is improved.
It is achieved particular by following technical scheme：.
A kind of extracting method of vegetalitas batik pigment, includes the following steps：
（1）Raw material preparation：Indigo plant, yellow avens, calanthe are mixed, Room-temperature low-pressure is dry to be lower than 8% to water content, then by indigo plant,
Yellow avens, calanthe are put into conventional electric crusher and crush, and it is spare to obtain common flour；
（2）It extracts：Common flour is added in vibration type ultramicro disintegrator, 30min is crushed at 25-35 DEG C and obtains Ultramicro-powder, it will
Ultramicro-powder is fitted into means of supercritical extraction tank, is to extract fluid with CO2, and using ethyl alcohol as entrainer, the dosage of ethyl alcohol is 0.5-
0.7mL/g, extracting pressure 50-80Mpa, 45-50 DEG C of extraction temperature, extraction time 2-2.5h carry out supercritical extract to obtain the final product
The vegetalitas batik pigment；
Further, step（1）In, the indigo plant, yellow avens, calanthe mass ratio be 10:8:1.
Further, step（1）In, the Room-temperature low-pressure is 25-30 DEG C, 0.1-0.3 standard atmospheric pressure of temperature.
The application method of vegetalitas batik pigment of the invention, including：
（1）Vegetalitas batik pigment and distilled water are made into the solution of mass concentration 3-5% to get dye solution；
（2）First fabric is added in alum solution, 40-60min is impregnated, then directly takes out fabric, be put into dye solution and boil
2-3h is boiled, taking-up fabric is spread out under ventilated environment to be hung 2-3 weeks.
Further, the mass ratio of the fabric and alum solution is 1:40；The alum solution concentration is 5%, and temperature is
85℃。
Further, the mass ratio of the fabric and dyestuff is 1:35.
Beneficial effects of the present invention：
（1）The present invention passes through scientific matching between raw material, reasonable disposition color colour system, so that knitting after pigment batik of the present invention
Damp tenderness is looked for, it is sustained, and raw material drying is first crushed and is pulverized again later by the present invention, is then carried out again overcritical
Extraction, extraction conditions are mild, and supercritical extract is high-efficient, and pigment loss is small in manufacturing process, also retain the sugar in plant
Point, the ingredients such as vegetable protein, promote the attachment and solidification of pigment on the fabric, the present invention sufficiently combines natural pigment in use
Pigment effect is shown to greatest extent by coordinating dyeing condition, improves pattern by the complexing between inorganic ions
Quality effect.
（2）The pigment solubility of the method for the present invention preparation is good, and rapidly, dyeing efficiency is high for oxidation, and pigment of the present invention stores
It is convenient, using simplicity, there is excellent economic value.
Specific embodiment
Embodiment 1
A kind of extracting method of vegetalitas batik pigment, includes the following steps：
（1）Raw material preparation：In mass ratio 10:8:1 mixes indigo plant, yellow avens, calanthe, big in 25 DEG C, 0.1 standard of temperature
It is dried under air pressure to water content and is lower than 8%, then indigo plant, yellow avens, calanthe are put into conventional electric crusher and crushed, obtained commonly
Powder is spare；
（2）It extracts：Common flour is added in vibration type ultramicro disintegrator, 30min is crushed at 25 DEG C and obtains Ultramicro-powder, by ultra micro
Powder is fitted into means of supercritical extraction tank, with CO2To extract fluid, using ethyl alcohol as entrainer, the dosage of ethyl alcohol is 0.5mL/g, extraction
Pressure power 50Mpa, 45 DEG C of extraction temperature, extraction time 2h carry out supercritical extract up to the vegetalitas batik pigment；
The application method of vegetalitas batik pigment of the invention, including：
（1）Vegetalitas batik pigment and distilled water are made into the solution of mass concentration 3% to get dye solution；
（2）In mass ratio 1:40 mix fabric with the alum solution that concentration is 5%, in 85 DEG C of immersion 40min, then directly take
Fabric out is put into dye solution and boils 2h, and taking-up fabric is spread out under ventilated environment to be hung 2 weeks；Wherein fabric and dye
The mass ratio of material is 1:35.
Claims (6)
1. a kind of extracting method of vegetalitas batik pigment, which is characterized in that include the following steps：
（1）Raw material preparation：Indigo plant, yellow avens, calanthe are mixed, Room-temperature low-pressure is dry to be lower than 8% to water content, then by indigo plant,
Yellow avens, calanthe are put into conventional electric crusher and crush, and it is spare to obtain common flour；
（2）It extracts：Common flour is added in vibration type ultramicro disintegrator, 30min is crushed at 25-35 DEG C and obtains Ultramicro-powder, it will
Ultramicro-powder is fitted into means of supercritical extraction tank, with CO2To extract fluid, using ethyl alcohol as entrainer, the dosage of ethyl alcohol is 0.5-
0.7mL/g, extracting pressure 50-80Mpa, 45-50 DEG C of extraction temperature, extraction time 2-2.5h carry out supercritical extract to obtain the final product
The vegetalitas batik pigment.
2. the extracting method of vegetalitas batik pigment described in accordance with the claim 1, which is characterized in that step（1）In, the knotweed
Indigo plant, yellow avens, calanthe mass ratio be 10:8:1.
3. the extracting method of vegetalitas batik pigment described in accordance with the claim 1, which is characterized in that step（1）In, it is described normal
Warm low pressure is 25-30 DEG C, 0.1-0.3 standard atmospheric pressure of temperature.
4. the application method of the described in any item vegetalitas batik pigment of claim 1-3, which is characterized in that including：
（1）Vegetalitas batik pigment and distilled water are made into the solution of mass concentration 3-5% to get dye solution；
（2）First fabric is added in alum solution, 40-60min is impregnated, then directly takes out fabric, be put into dye solution and boil
2-3h is boiled, taking-up fabric is spread out under ventilated environment to be hung 2-3 weeks.
5. the application method of vegetalitas batik pigment according to claim 4, which is characterized in that the fabric and alum are molten
The mass ratio of liquid is 1:40；The alum solution concentration is 5%, and temperature is 85 DEG C.
6. the application method of vegetalitas batik pigment according to claim 4, which is characterized in that the fabric and dyestuff
Mass ratio is 1:35.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810428381.1A CN108892970B (en) | 2018-05-07 | 2018-05-07 | Extraction method and application method of vegetable wax printing pigment |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810428381.1A CN108892970B (en) | 2018-05-07 | 2018-05-07 | Extraction method and application method of vegetable wax printing pigment |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN108892970A true CN108892970A (en) | 2018-11-27 |
| CN108892970B CN108892970B (en) | 2020-07-31 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810428381.1A Active CN108892970B (en) | 2018-05-07 | 2018-05-07 | Extraction method and application method of vegetable wax printing pigment |
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| Country | Link |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112221192A (en) * | 2020-10-15 | 2021-01-15 | 南京林业大学 | A kind of supercritical extraction method of bamboo green cortex wax |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104341793A (en) * | 2014-10-29 | 2015-02-11 | 合肥新桥制衣有限公司 | Cotton cloth vegetable blue dye |
| CN105992583A (en) * | 2013-12-06 | 2016-10-05 | 莱雅公司 | Process for dyeing keratin materials using powder from indigo-producing plants and alkaline agent(s) |
-
2018
- 2018-05-07 CN CN201810428381.1A patent/CN108892970B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105992583A (en) * | 2013-12-06 | 2016-10-05 | 莱雅公司 | Process for dyeing keratin materials using powder from indigo-producing plants and alkaline agent(s) |
| CN104341793A (en) * | 2014-10-29 | 2015-02-11 | 合肥新桥制衣有限公司 | Cotton cloth vegetable blue dye |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112221192A (en) * | 2020-10-15 | 2021-01-15 | 南京林业大学 | A kind of supercritical extraction method of bamboo green cortex wax |
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| Publication number | Publication date |
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| CN108892970B (en) | 2020-07-31 |
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