CN108887286A - A kind of agricultural chemical composition and application thereof - Google Patents
A kind of agricultural chemical composition and application thereof Download PDFInfo
- Publication number
- CN108887286A CN108887286A CN201810837703.8A CN201810837703A CN108887286A CN 108887286 A CN108887286 A CN 108887286A CN 201810837703 A CN201810837703 A CN 201810837703A CN 108887286 A CN108887286 A CN 108887286A
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- CN
- China
- Prior art keywords
- salt
- aerosol
- pest
- sodium pyrosulfite
- fungicide
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims abstract description 41
- 239000003905 agrochemical Substances 0.000 title claims abstract description 15
- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 claims abstract description 65
- 235000010262 sodium metabisulphite Nutrition 0.000 claims abstract description 59
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical class [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 claims abstract description 45
- 241000607479 Yersinia pestis Species 0.000 claims abstract description 38
- 230000000855 fungicidal effect Effects 0.000 claims abstract description 24
- 239000000417 fungicide Substances 0.000 claims abstract description 24
- 230000002363 herbicidal effect Effects 0.000 claims abstract description 24
- 239000004009 herbicide Substances 0.000 claims abstract description 22
- 239000000470 constituent Substances 0.000 claims abstract description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 23
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 20
- -1 granula subtilis Substances 0.000 claims description 15
- 239000003921 oil Substances 0.000 claims description 15
- 150000001875 compounds Chemical class 0.000 claims description 13
- 239000000843 powder Substances 0.000 claims description 13
- 241000578422 Graphosoma lineatum Species 0.000 claims description 10
- 241001414989 Thysanoptera Species 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 10
- 239000000375 suspending agent Substances 0.000 claims description 10
- 239000004563 wettable powder Substances 0.000 claims description 10
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- 239000002552 dosage form Substances 0.000 claims description 4
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- PMZURENOXWZQFD-UHFFFAOYSA-L sodium sulphate Substances [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 3
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- RZHBMYQXKIDANM-UHFFFAOYSA-N dioctyl butanedioate;sodium Chemical compound [Na].CCCCCCCCOC(=O)CCC(=O)OCCCCCCCC RZHBMYQXKIDANM-UHFFFAOYSA-N 0.000 claims description 2
- 239000012530 fluid Substances 0.000 claims description 2
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- XDDAORKBJWWYJS-UHFFFAOYSA-N glyphosate Chemical group OC(=O)CNCP(O)(O)=O XDDAORKBJWWYJS-UHFFFAOYSA-N 0.000 claims description 2
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- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 2
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- ZEKANFGSDXODPD-UHFFFAOYSA-N glyphosate-isopropylammonium Chemical compound CC(C)N.OC(=O)CNCP(O)(O)=O ZEKANFGSDXODPD-UHFFFAOYSA-N 0.000 description 5
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- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 2
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- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 239000004552 water soluble powder Substances 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 238000009333 weeding Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/02—Sulfur; Selenium; Tellurium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
- A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
- A01N41/04—Sulfonic acids; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/34—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the groups, e.g. biuret; Thio analogues thereof; Urea-aldehyde condensation products
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
- A01N57/20—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing acyclic or cycloaliphatic radicals
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of agricultural chemical compositions and application thereof, belong to agricultural chemicals technical field, composition contains active constituent sodium pyrosulfite and aerosol-OT salt, and wherein the weight ratio of sodium pyrosulfite and aerosol-OT salt is 1:100 to 100:1, the synergist for pre- pest control or control pest and as fungicide or herbicide uses.The present invention but can effectively kill the pest with sucking mouth parts without farm chemical ingredients, without any side effects to plant, can substitute pesticide to a certain degree and carry out the prevention of pest or the control of pest, to alleviate environmental pollution.The present invention is used cooperatively with fungicide, can not only promote the bactericidal effect of fungicide, moreover it is possible to the usage amount of fungicide is reduced, so that pollution of the fungicide to environment be greatly decreased.The present invention is used cooperatively with herbicide, can not only promote the herbicidal effect of herbicide, moreover it is possible to the usage amount of herbicide is reduced, so that pollution of the herbicide to environment be greatly decreased.
Description
Technical field
The invention belongs to agricultural chemicals technical fields, and in particular to a kind of agricultural chemical composition and application thereof.
Background technique
Chemical prevention is agriculturally to prevent and control an important means for pest.However, currently used medicament is to certain
The effect of a little pests is still not satisfied enough；Also, since long-time uses insecticide, many pests have been produced to common insecticide
Resistance.For certain pests, especially to the stinkbug class (Stinkbug) of sucking mouth parts, wood louse class (Cryptophagus
Decoratus, plant lousen), aleyrodid class (Whitefly), Phytophthira (Aphid), shell insects (Icerya
Purchasi), for thrips class (Thrips), mite class (acaridn), planthopper (Rice planthopper), routine is utilized
Medicament carries out prevention and control and just becomes increasingly difficult.Therefore, there is an urgent need to develop go out for controlling these pests and providing fungicide
With the new method and drug of herbicide effects.In addition, also continuous currently for requirement of the insecticide on environment and economic aspect
It improves, such as effect wide spectrum, toxicity, selectivity, pesticide residue and advantageous preparation ability etc..In addition, also as may be right
Resistance is led to the problem of in known activity compound, developing new at least has in some or some aspects relative to existing drug
The novel new product for killing sucking pest of advantage is just at a permanent task.
Sodium pyrosulfite：
Chinese nickname：Sodium Metabisulfite；Pyrosulfurous acid sodium；Weight sulphur oxygen；Coke-ness alpha sulfate；Sodium metasulfite；
Sodium pyrosulfite；Edible sodium pyrosulfite.Chemicals English name：sodium metabisulfite.Product specification：Titanium dioxide
Sulphur >=65%；Iron≤0.005%；Water-insoluble≤0.05%；PH value：4.0-4.6.Classification：Antioxidant；Molecular formula：
Na2S2O5；Molecular weight 190.10.
Appearance and character：For the crystallization of colourless prism-shaped or white powder；There is sulfur dioxide taste, acid, salty；Storage with the passing of time color is gradually
Turn yellow.Fusing point (DEG C)：>300 (decomposition)；Relative density (water=1)：1.48；Dissolubility：It is dissolved in water, aqueous solution is in (20 DEG C acid
When be 54g/100ml water；It is 81.7g/100ml water at 100 DEG C).It is dissolved in glycerol, is slightly soluble in ethyl alcohol.Relative density 1.4.It is dissolved in
Water, aqueous solution contact with strong acid in acidity, release SO2 and generate corresponding salt, be long placed in air, be then oxidized to
Na2S2O6, therefore the product cannot be deposited long.Higher than 150 degrees Celsius, that is, decomposite SO2.It is dissolved in glycerol, is slightly soluble in ethyl alcohol.Dampness is easy
It decomposes, dew empties oxidizable at sodium sulphate in gas.It is contacted with strong acid and releases sulfur dioxide and generate corresponding salt.It is heated to
150 DEG C of decomposition.
Stability and reactivity；Prohibit and matches object：Strong acid, strong oxidizer；The condition avoided contact with：Humid air.
Aerosol-OT salt：
Chinese name：Fast penetrant T；【Chemical component】Fatty alcohol polyoxyethylene ether；
Chemical name：Diisooctyl maleate sulfonate (aerosol-OT salt)
Belong to aerosol-OT salt.Make fabric quickly penetrating agent in printing and dyeing industry, it is not only quickly but also uniform.Also it uses
Make emulsifier, detergent, surfactant etc..Appearance：Colourless to yellowish liquid (25 DEG C of range estimations)；PH value：5.0~7.0
(1% aqueous solution) moisture：≤ 0.5%；Penetration：≤ 45s (0.1% aqueous solution).
Performance and purposes：Fast penetrant T is a kind of anionic surfactant, has and permeates quick, uniform, wetting
The features such as property, emulsibility, good foaming characteristic.Intolerant to strong acid, highly basic, heavy metallic salt and reducing agent etc..Fast penetrant T dissolves in
The hydrophilic solvents such as water, lower alcohol；Also benzene, carbon tetrachloride, kerosene, petroleum solvent series etc. are dissolved in.Aqueous solution is creamy white,
The pH value of 1% aqueous solution is 6.5 ± 0.5.This product permeates Quick uniform.Temperature is at 40 DEG C hereinafter, pH value uses between 5-10
Effect is best.Silk fabrics etc. can not influence its permeance property because temperature, soda acid etc. change after penetrant treating is complete.It is main
It is used for fabric pentration, printing and dyeing, pesticidal emulsifiable synergy etc..
Currently, also not about the report of sodium pyrosulfite and aerosol-OT salt combined application.
Summary of the invention
Object of the present invention is to solve the problems, such as at least one aspect of above-mentioned at least one or its, especially for effective control evil
Worm and the effect for improving fungicide and herbicide, through a large amount of field trial and screening, inventors have surprisingly discovered that
Sodium pyrosulfite and aerosol-OT salt (especially aerosol-OT salt) can be combined for preventing
Or control pest and the synergist as fungicide and herbicide.The effect of this combination is especially good.
The technical scheme adopted by the invention is as follows：
A kind of agricultural chemical composition, containing active constituent sodium pyrosulfite and aerosol-OT salt,
The weight ratio of middle sodium pyrosulfite and aerosol-OT salt is 1:100 to 100:1.
Preferably, the weight ratio of the sodium pyrosulfite and aerosol-OT salt is 1:40 to 40:1.
Preferably, the weight ratio of the sodium pyrosulfite and aerosol-OT salt is 1:9 to 9:1.
Further, the weight ratio of the sodium pyrosulfite and aerosol-OT salt is 1:4 to 4:1.
Further, the weight ratio of the sodium pyrosulfite and aerosol-OT salt is 2:3 to 3:2.
Preferably, the weight ratio of the sodium pyrosulfite and aerosol-OT salt is 1:1.
Preferably, the sodium pyrosulfite and aerosol-OT salt account for the composition by weight in total
5% to 95%.
Further, the sodium pyrosulfite and aerosol-OT salt account for the composition by weight in total
20% to 85%.
Further, the composition also includes additive, solvent, carrier, organic silicon defoamer or extender.
Preferably, the dosage form of the composition be aerosol, suspending agent, microcapsulated granule, granula subtilis, flowable concentrate,
Ready to use solution agent, pulvis, missible oil, aqueous emulsion, oil emu, big granula, fine granule, oil loose powder, the miscible mobility concentration of oil
It is object, oily miscible fluid, foaming agent, paste, suspending concentrate, suspending agent, solubility concentrate, soluble powder, granule, water-soluble
Property particle, tablet, water solube powder, wettable powder, through reactive compound dipping natural or synthetic material, polymer material
In microcapsules and/or water-dispersible granule.Particularly, most with missible oil, suspending agent, solution and soluble concentrate drug effect
It is excellent.
Further, the composition also includes one or more kinds of other active components.
The invention also discloses above-mentioned agricultural chemical compositions for pre- pest control or control pest and as sterilization
The purposes of the synergist of agent or herbicide.
Preferably, the pest is in stinkbug class, wood louse class, aleyrodid class, Phytophthira, shell insects, thrips class, mite class
It is at least one.
Preferably, the fungicide is bacterial germicide and fungoid fungicide.
Further, the herbicide is glyphosate, N-alpha-chloroacetyl-N-isopropyl-o ethylaniline and phosphine oxamate.
The invention also discloses using the pre- pest control of above-mentioned agricultural chemical composition or control pest and Synergistic sterilizing
The method of agent or herbicide, including separate, sequentially or simultaneously apply sodium pyrosulfite and aerosol-OT salt.
The invention also discloses a kind of for pre- pest control or controls the reagent of pest and synergy fungicide or herbicide
Box, wherein including sodium pyrosulfite and aerosol-OT salt, wherein sodium pyrosulfite and sulfosuccinate dioctyl phthalate
The weight ratio of sodium salt is 1:100 to 100:1, preferred weight ratio is 1:40 to 40:1,1:9 to 9:1,1:4 to 4:1,2:3 to 3:
2 or 1:1.
Beneficial effects of the present invention are：
The present invention but can effectively be killed with sucking mouth parts without farm chemical ingredients, without any side effects to plant
Pest can substitute pesticide and carry out the prevention of pest or the control of pest, to a certain degree to alleviate environmental pollution.
The present invention is used cooperatively with fungicide, can not only promote the bactericidal effect of fungicide, moreover it is possible to reduce fungicide
Usage amount, so that pollution of the fungicide to environment be greatly decreased.
The present invention is used cooperatively with herbicide, can not only promote the herbicidal effect of herbicide, moreover it is possible to reduce herbicide
Usage amount, so that pollution of the herbicide to environment be greatly decreased.
Specific embodiment
Further explaination is done to the present invention combined with specific embodiments below.
The present inventor has found between accidental through a large amount of field trial and screening：By sodium pyrosulfite and sulfosuccinate two
The combination of monooctyl ester sodium salt can not only prevent or control causing harm for pest sucking pest, but also importantly, make us frightened
The synergy of happiness realized to fungicide and herbicide.
In one embodiment, the present invention provides a kind of sodium pyrosulfites and aerosol-OT salt conduct
The agrochemical composition of active constituent, wherein the weight ratio of sodium pyrosulfite and aerosol-OT salt is 1:100
To 100:1, preferably 1:80 to 80:1, such as 1:60 to 60:1 or 1:40 to 40:1.
In some more particular embodiments, the weight ratio of above two compound for use in the present invention is independent of one another
Ground is 90:1 to 1:90,80:1 to 1:80,70:1 to 1:70,60:1 to 1:60,50:1 to 1:50,40:1 to 1:40,30:1 arrives
1:30,20:1 to 1:20,10:1 to 1:10,9:1 to 1:9,8:1 to 1:8,7:1 to 1:7,6:1 to 1:6,5:1 to 1:5,4:1 arrives
1:4,3:1 to 1:3,2:1 to 1:2 or 1:1.
The total amount of active compound component can be selected according to material elements in the present composition, the phase to realize
The effect of prestige, described factor such as dosage form, object to be administered, method of administration etc..In one embodiment, sodium pyrosulfite and
Aerosol-OT salt accounts for 5% to 95% of the composition by weight in total, and preferably 20% to 85%.
Composition of the invention optionally including agronomically acceptable additive, solvent, carrier, surfactant or
Extender.
According to the present invention, term " carrier " refer to can with active compound or combine so that it is easier to be administered to object
The natural or synthetic organic or inorganic compound of (such as plant, crop or careless class).Therefore, the carrier is preferably inertia
, it at least should be agronomically acceptable.The carrier can be solid or liquid.
Suitable carrier can for it is following those：Such as sulfate and natural rock powder, such as kaolinite, clay, talcum,
Chalk, quartz, attapulgite, montmorillonite or diatomite, for example finely divided silica of synroc powder, aluminium oxide and silicon
Hydrochlorate, oily wax, organic solvent, mineral and vegetable oil and its derivative；Suitably it is for the solid carrier of particle：For example, powder
Broken and classification natural rock such as calcite, marble, float stone, sepiolite, dolomite and inorganic and organic dust synthesis
Particle.
Suitable liquid-carrier is：For example, water, polarity and nonpolar organic chemistry liquid, such as aromatic hydrocarbons and non-aromatics
Class (such as paraffin, alkylbenzene), pure and mild polyalcohol, esters (including rouge and oil).
If liquid-carrier used is water, it is auxiliary agent that such as organic solvent, which also can be used,.Mineral and vegetable oil and
Water.
Composition of the invention also may include annexing ingredient.Particularly, the composition also may include organic silicon defoaming
Agent.
Colorant, such as inorganic pigment can be used, such as iron oxide, titanium oxide and Prussian blue and organic pigment, such as
Alizarin dyes, azo dyes and metallized phthalocyanine dye；And microelement, such as molysite, manganese salt and boron salt.
Optionally, also may include other annexing ingredients, for example, protecting colloid, adhesive, thickener, bleeding agent, stabilizer,
Screening agent.More commonly, reactive compound of the invention can be combined with any solid or liquid additive, this meets general configuration
Agent.
Composition of the invention, the pharmacology of desinsection are that can release sulfur dioxide, belong to a kind of novel sulphur preparation
Desinsection.
Combination or composition of the invention can be used directly, and make using dosage form or as use form prepared therefrom
With for example, aerosol, suspending agent, microcapsulated granule, granula subtilis, flowable concentrate, ready to use solution agent, pulvis, missible oil, water and milk
Agent, oil emu, big granula, fine granule, oil loose powder, the miscible mobility concentrate of oil, oily miscible liquids, foaming agent, paste,
Suspending concentrate, suspending agent, solubility concentrate, soluble powder, granule, water-soluble granular and/or tablet, water soluble powder
Agent, wettable powder, the natural or synthetic material through reactive compound dipping, microcapsules and water dispersible in polymer material
Particle.In preferred embodiments, a kind of to contain sodium pyrosulfite and aerosol-OT salt chemical composition, agent
Type is missible oil, suspending agent, solution, soluble concentrate.
The reactive compound can be mixed preparation with conventional additives by known way by the preparation of the invention.
For example conventional extender of the conventional additives and solvent or diluent, emulsifier, dispersing agent, wetting agent, if it is desired, also
It may include drier and colorant, stabilizer, pigment, defoaming agent, thickener, water and other processing aids.
The preparation suitable for application can be made in composition of the invention in the form of the composition of its active compound component,
It can also be with the combined form application of the commercial preparation of its suitable dosage.Can also be administered in combination with its activating agent, it is described its
His agents such as insecticide, attractant, bactericide, acaricide, nematicide, fungicide, growth regulator, weeding
Agent, safener, fertilizer or semiochemical etc..
On the other hand, the present invention provides a kind of for preventing or controlling pest, fungicide and the increasing of herbicide
The method for imitating agent, including sodium pyrosulfite and aerosol-OT salt is administered in combination.
In some preferred embodiments, the pest is selected from stinkbug class (Stinkbug), the wood louse class of sucking mouth parts
(Cryptophagus decoratus, plant lousen), aleyrodid class (Whitefly), Phytophthira (Aphid), shell insects
(Icerya purchasi), thrips class (Thrips), mite class (acaridn), planthopper (Rice planthopper) etc..
Term " pest " used herein means any organism that can cause to damage to the normal condition of plant, including
Such as insect, fungi, bacterium, nematode, acarid, thrips, microorganism, aphid, aleyrodid, coccid, planthopper, wood louse, stinkbug etc..
With method processing plant of the invention or crop perhaps careless class or described in compositions-treated of the invention it is right
As, it can directly be carried out by usual processing method or be carried out by acting on environment, habitat or storage areas, it is described logical
Normal processing method the methods of such as passes through pouring, dropper, is sprayed, evaporates, is atomized, broadcasts sowing；Also institute can be applied by ultra-low volume method
It states compound or the compound or composition itself injects in soil.
Method of the invention additionally provide by separate, sequentially or simultaneously in a manner of the reactive compound is administered in combination.One
In a embodiment, sodium pyrosulfite and aerosol-OT salt is administered simultaneously.In another embodiment, successively
Apply sodium pyrosulfite and aerosol-OT salt.In yet another embodiment, separate administration sodium pyrosulfite and
Aerosol-OT salt.
Composition of the invention or activating agent combination are common and advantageous when usually being applied with following dosage：
For leaf portion processing：0.1-10000g/ha, preferably 10-1000g/ha, more preferable 30-5000g/ha；For dipping
Or for application of instiling, the dosage even can also be reduced.
For soil treatment：0.1-10000g/ha, preferably 10-5000g/ha.
Above-mentioned dosage is only general exemplary dose, and those skilled in the art can be according to the actual situation when reality is applied
And needs, rate of application is adjusted especially in accordance with the property and insect pest situation of plant to be processed or crop.
Activating agent of the invention have good plant compatibility, be suitable for control pest, especially insect, fungi, bacterium,
Nematode, acarid, thrips, microorganism, aphid, aleyrodid, coccid, planthopper, wood louse, stinkbug etc., are preferably applied at leaf
The composition of reason, soil treatment.
The combination of the present composition and activating agent is generally for sensitive and resistant species and all or individually
Stage of development is all effective.The pest includes for example：Stinkbug class (Stinkbug), the wood louse class of sucking mouth parts
(Cryptophagus decoratus, plant lousen), aleyrodid class (Whitefly), Phytophthira (Aphid), shell insects
(Icerya purchasi), thrips class (Thrips), mite class (acaridn), planthopper (Rice planthopper) etc..
In another embodiment, the present invention also provides one kind for preventing or controlling pest, fungicide and remove
The kit of the synergist of careless agent, wherein including sodium pyrosulfite and aerosol-OT salt.
It should be pointed out that in the sense of the present invention, term " sodium pyrosulfite and the combination of aerosol-OT salt "
Including separating, sequentially or simultaneously using sodium pyrosulfite and aerosol-OT salt.Preferably, the sodium pyrosulfite
The shape of the composition comprising sodium pyrosulfite and aerosol-OT salt is combined into aerosol-OT salt group
Formula.
It should be pointed out that any technical characteristic of any embodiment or embodiment of the invention can freely independently
It is combined with each other with any other embodiment of the invention.That is, one or more skills of any embodiment of the present invention
Art feature can all be reconfigured with any other technical characteristic.Thus the technical characteristic that technical characteristic is reconfigured and formed discloses
Herein, if it is especially recorded herein equally.
It is enumerated by implementation below and illustrates the present invention, it being understood, however, that, the present invention is not limited to given implementations
Example.
Embodiment 1:+ 40% aerosol-OT salt suspending agent of 1% sodium pyrosulfite
The each components such as active constituent, dispersing agent, bentonite and water are uniformly mixed according to the ratio of formula, it is ground and/
Or 41% sodium pyrosulfite+aerosol-OT salt suspending agent is obtained after high speed shear.
Embodiment 2:+ 20% aerosol-OT salt wettable powder of 20% sodium pyrosulfite
| Sodium pyrosulfite | 20% |
| Aerosol-OT salt | 20% |
| Neopelex | 2% |
| Sodium lignin sulfonate | 5% |
| White carbon black | 10% |
| Kaolin | Complement to 100% |
Active component, various auxiliary agents and filler etc. are mixed by the proportional components of formula, after ultra-fine pulverizer disintegrating, i.e.,
Obtain 40% sodium pyrosulfite+aerosol-OT salt wettable powder.
Embodiment 3:+ 49.5% aerosol-OT salt aqueous emulsion of 0.5% sodium pyrosulfite
Raw medicine, solvent, emulsifier are added together, make to be dissolved into homogeneous phase；Water-soluble component and water are mixed to prepare water
Phase；It is mixed under high velocity agitation, 50% sodium pyrosulfite+aerosol-OT salt is made.
Embodiment 4:+ 45% aerosol-OT brine dispersion granula of 5% sodium pyrosulfite
| Sodium pyrosulfite | 5% |
| Aerosol-OT salt | 45% |
| Sodium lignin sulfonate | 4% |
| Neopelex | 2% |
| Urea | 2% |
| Kaolin | Complement to 100% |
Active constituent, dispersing agent, wetting agent, disintegrating agent and condiment are mixed according to the formula uniformly, by air-flow powder
It is broken into wettable powder, adds a certain amount of water mixing extrusion granulation.50% sodium pyrosulfite+sulphur is obtained after dry screening
Change dioctyl succinate sodium salt water dispersible granules.
Embodiment 5:+ 30% aerosol-OT salt aqueous emulsion of 20% sodium pyrosulfite
By in methyl oleate sodium pyrosulfite and aerosol-OT salt, mixed according to the component in formula equal
It is even, it then carries out high speed shear and obtains 50% sodium pyrosulfite+aerosol-OT salt aqueous emulsion.
Embodiment 6:+ 40% aerosol-OT salt aqueous emulsion of 10% sodium pyrosulfite
| Sodium pyrosulfite | 10% |
| Aerosol-OT salt | 40% |
| Methyl naphthalene sulfonate formaldehyde condensate | 10% |
| Xanthan gum | 1% |
| Glycerine | 5% |
| Water | Complement to 100% |
The each components such as active constituent point, dispersing agent and water are uniformly mixed according to the ratio of formula, according to the group in formula
Divide and be uniformly mixed, then carries out high speed shear and obtain 50% sodium pyrosulfite+aerosol-OT salt aqueous emulsion.
Test example 1：Citrus red mite test
On citrus crop, the dilution of the application concentration needed for embodiment 1-6 is handled by sprinkling, and blade still
The adult of red spider under wetness conditions.After the required time, the killing rate indicated in the form of % is determined.100% refers to killing
All adult；0% refers to and does not kill adult.
As seen from the above table, synergistic effect is obvious after sodium pyrosulfite and aerosol-OT salt compound, to citrus
The preventive effect of red spider is significantly better than single dose.And the dosage of effective component significantly reduces, and without farm chemical ingredients can kill it is red
Spider, meets the actual demand of the year two thousand twenty pesticide zero growth rate, to alleviate environmental pollution.
Test example 2：The test of lemon red spider
On citrus crop, the dilution of the application concentration needed for embodiment 1-6 is handled by sprinkling, and blade still
The adult of red spider under wetness conditions.After the required time, the killing rate indicated in the form of % is determined.100% refers to killing
All adult；0% refers to and does not kill adult.
As seen from the above table, synergistic effect is obvious after sodium pyrosulfite and aerosol-OT salt compound, to lemon
The preventive effect of red spider is significantly better than single dose.And the dosage of effective component significantly reduces, and without farm chemical ingredients can kill it is red
Spider, meets the actual demand of the year two thousand twenty pesticide zero growth rate, to alleviate environmental pollution.
Test example 3：The test of eggplant red spider
On eggplant crop, the dilution of the application concentration needed for embodiment 1-6 is handled by sprinkling, and blade still
The adult of red spider under wetness conditions.After the required time, the killing rate indicated in the form of % is determined.100% refers to killing
All adult；0% refers to and does not kill adult.
As seen from the above table, synergistic effect is obvious after sodium pyrosulfite and aerosol-OT salt compound, to eggplant
Red spider preventive effect on crop is significantly better than single dose.And the dosage of effective component significantly reduces, and can be with without farm chemical ingredients
Red spider is killed, the actual demand of the year two thousand twenty pesticide zero growth rate is met, to alleviate environmental pollution.
Test example 4：The test of tomato red spider
On tomato crop, the dilution of the application concentration needed for embodiment 1-6 is handled by sprinkling, and blade still
The adult of red spider under wetness conditions.After the required time, the killing rate indicated in the form of % is determined.100% refers to killing
All adult；0% refers to and does not kill adult.
As seen from the above table, synergistic effect is obvious after sodium pyrosulfite and aerosol-OT salt compound, to tomato
The preventive effect of red spider is significantly better than single dose.And the dosage of effective component significantly reduces, and without farm chemical ingredients can kill it is red
Spider, meets the actual demand of the year two thousand twenty pesticide zero growth rate, to alleviate environmental pollution.
Test example 5：With the prevention and treatment bitter rot or anthracnose of grape test of 70% thiophanate-methyl wettable powder interworking
It is dense by required application with+70% thiophanate-methyl wettable powder of embodiment 1-6 formulation product on grape crop
The dilution of degree is handled by sprinkling, after seven days Germicidal efficacies, determines the average preventive effect indicated in the form of %.100%
Refer to and 100% is reached to anthracnose preventive effect；0% refers to there is not any preventive effect to anthracnose.
As seen from the above table ,+70% thiophanate-methyl is wettable after sodium pyrosulfite and aerosol-OT salt compound
Property pulvis synergistic effect it is obvious, single dose is significantly better than to the preventive effect of bitter rot or anthracnose of grape, also above 70% methyl sulfur bacterium is used alone
Clever wettable powder.The 70% thiophanate-methyl wettable powder that one third can be reduced in situation similar in preventive effect, from
And alleviate pesticide environmental pollution.
Test example 6：It is tested with 41% glyphosate isopropyl amine salt interworking annual grassy weeds
On annual grassy weeds (such as barnyard grass, herba setariae viridis, amur foxtail, herba eleusines indicae, grasswort, herba digitariae, Chenopodiaceae, herba stellariae mediae, clearvers),
It is handled, is passed through by sprinkling by the dilution of required application concentration with+41% glyphosate isopropyl amine salt of embodiment 1-6 formulation product
After seven days Germicidal efficacies, the weeds death rate indicated in the form of % is determined.100% refers to that the weeds death rate reaches 100%；
0% refers to weeds without death.
As seen from the above table ,+41% glyphosate isopropyl amine salt after sodium pyrosulfite and aerosol-OT salt compound
Synergistic effect is obvious, to annual grassy weeds (such as barnyard grass, herba setariae viridis, amur foxtail, herba eleusines indicae, grasswort, herba digitariae, Chenopodiaceae, herba stellariae mediae, clearvers
Deng) it is significantly better than single dose, also above 41% glyphosate isopropyl amine salt is used alone.Three can be reduced in situation similar in preventive effect
/ mono- 41% glyphosate isopropyl amine salt, to alleviate pesticide environmental pollution.
The present invention is not limited to above-mentioned optional embodiment, anyone can show that other are each under the inspiration of the present invention
The product of kind form.Above-mentioned specific embodiment should not be understood the limitation of pairs of protection scope of the present invention, protection of the invention
Range should be subject to be defined in claims, and specification can be used for interpreting the claims.
Claims (10)
1. a kind of agricultural chemical composition, it is characterised in that contain active constituent sodium pyrosulfite and sulfosuccinate dioctyl phthalate
Sodium salt, wherein the weight ratio of sodium pyrosulfite and aerosol-OT salt is 1:100 to 100:1.
2. a kind of agricultural chemical composition according to claim 1, it is characterised in that：The sodium pyrosulfite and sulfonation
The weight ratio of dioctyl succinate sodium salt is 1:40 to 40:1.
3. a kind of agricultural chemical composition according to claim 1 or 2, it is characterised in that：The sodium pyrosulfite and
Aerosol-OT salt accounts for 20% to 85% of the composition by weight in total.
4. a kind of agricultural chemical composition according to claim 3, it is characterised in that：The composition also includes addition
Agent, solvent, carrier, organic silicon defoamer or extender.
5. a kind of agricultural chemical composition according to claim 1, it is characterised in that：The dosage form of the composition is gas
Mist agent, suspending agent, microcapsulated granule, granula subtilis, flowable concentrate, ready to use solution agent, pulvis, missible oil, aqueous emulsion, oil emu,
Big granula, fine granule, oil loose powder, the miscible mobility concentrate of oil, oily miscible fluid, foaming agent, paste, suspending concentrate,
Suspending agent, solubility concentrate, soluble powder, granule, water-soluble granular, tablet, water solube powder, wettable powder,
Microcapsules and/or water-dispersible granule in natural or synthetic material, polymer material through reactive compound dipping.
6. a kind of agricultural chemical composition described in claim 1 is for pre- pest control or control pest and as fungicide
Or the purposes of the synergist of herbicide.
7. purposes according to claim 6, wherein the pest is selected from stinkbug class, wood louse class, aleyrodid class, Phytophthira, shell
At least one of insects, thrips class, mite class.
8. purposes according to claim 6, wherein the fungicide is bacterial germicide and fungoid fungicide；It is described
Herbicide is glyphosate, N-alpha-chloroacetyl-N-isopropyl-o ethylaniline and phosphine oxamate.
9. using the pre- pest control of composition described in claim 1 or control pest and the method for synergy fungicide or herbicide,
Including separating, sequentially or simultaneously applying sodium pyrosulfite and aerosol-OT salt.
10. it is a kind of for pre- pest control or control pest and the kit of synergy fungicide or herbicide, wherein comprising burnt sub-
Sodium sulphate and aerosol-OT salt, wherein the weight ratio of sodium pyrosulfite and aerosol-OT salt is 1:
100 to 100:1.
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| CN201810837703.8A CN108887286A (en) | 2018-07-26 | 2018-07-26 | A kind of agricultural chemical composition and application thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2582997A (en) * | 2019-02-08 | 2020-10-14 | Scam S P A | Improvements in or relating to sulfur based pesticides |
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| CN1640253A (en) * | 2004-12-23 | 2005-07-20 | 湖南大方农化有限公司 | Use of rapid penetrant T for pesticide preparation |
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| CN1640253A (en) * | 2004-12-23 | 2005-07-20 | 湖南大方农化有限公司 | Use of rapid penetrant T for pesticide preparation |
| CN104839198A (en) * | 2015-03-20 | 2015-08-19 | 山西省农业科学院植物保护研究所 | Thermosensitive pesticide slow release agent for preventing and treating carposina niponensis walshingham |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2582997A (en) * | 2019-02-08 | 2020-10-14 | Scam S P A | Improvements in or relating to sulfur based pesticides |
| GB2582997B (en) * | 2019-02-08 | 2023-11-01 | Scam S P A | Improvements in or relating to sulfur based pesticides |
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Application publication date: 20181127 |