CN108866808A - A kind of antibiotic ultraviolet-resistant non-woven fabrics - Google Patents
A kind of antibiotic ultraviolet-resistant non-woven fabrics Download PDFInfo
- Publication number
- CN108866808A CN108866808A CN201810768988.4A CN201810768988A CN108866808A CN 108866808 A CN108866808 A CN 108866808A CN 201810768988 A CN201810768988 A CN 201810768988A CN 108866808 A CN108866808 A CN 108866808A
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- Prior art keywords
- woven fabrics
- tio
- polyamide
- resistant non
- ultraviolet
- Prior art date
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Links
- 239000004745 nonwoven fabric Substances 0.000 title claims abstract description 51
- 230000003115 biocidal effect Effects 0.000 title claims abstract description 25
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 80
- 239000004952 Polyamide Substances 0.000 claims abstract description 30
- 229920002647 polyamide Polymers 0.000 claims abstract description 30
- 239000000843 powder Substances 0.000 claims abstract description 26
- 239000002994 raw material Substances 0.000 claims abstract description 16
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 claims abstract description 9
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 42
- JLDSOYXADOWAKB-UHFFFAOYSA-N aluminium nitrate Chemical compound [Al+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O JLDSOYXADOWAKB-UHFFFAOYSA-N 0.000 claims description 22
- 239000000463 material Substances 0.000 claims description 16
- HSJPMRKMPBAUAU-UHFFFAOYSA-N cerium nitrate Inorganic materials [Ce+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O HSJPMRKMPBAUAU-UHFFFAOYSA-N 0.000 claims description 15
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 9
- 229940068918 polyethylene glycol 400 Drugs 0.000 claims description 8
- 239000002759 woven fabric Substances 0.000 claims description 6
- 244000248349 Citrus limon Species 0.000 claims 1
- 235000005979 Citrus limon Nutrition 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- 150000001408 amides Chemical class 0.000 claims 1
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 3
- 230000000694 effects Effects 0.000 abstract description 3
- 241000894006 Bacteria Species 0.000 description 3
- 230000000845 anti-microbial effect Effects 0.000 description 3
- 239000000835 fiber Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 230000035699 permeability Effects 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 230000001954 sterilising effect Effects 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 241000588724 Escherichia coli Species 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 241000191967 Staphylococcus aureus Species 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000029087 digestion Effects 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000005274 electronic transitions Effects 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 230000001408 fungistatic effect Effects 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 150000001455 metallic ions Chemical class 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 239000011858 nanopowder Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000010355 oscillation Effects 0.000 description 1
- 230000001766 physiological effect Effects 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/4326—Condensation or reaction polymers
- D04H1/4334—Polyamides
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
- D01F1/103—Agents inhibiting growth of microorganisms
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
- D01F1/106—Radiation shielding agents, e.g. absorbing, reflecting agents
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
- D01F6/90—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyamides
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/413—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties containing granules other than absorbent substances
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/13—Physical properties anti-allergenic or anti-bacterial
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/22—Physical properties protective against sunlight or UV radiation
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of antibiotic ultraviolet-resistant non-woven fabrics, the antibiotic ultraviolet-resistant non-woven fabrics is TiO2：(Al, Ce)/polyamide non-woven fabrics, raw material include TiO2：(Al, Ce) powder, polyamide, n,N-dimethylacetamide.Non-woven fabrics of the invention has good antibacterial, uvioresistant effect.
Description
Technical field
The present invention relates to field of nonwoven fabric technology, and in particular to a kind of antibiotic ultraviolet-resistant non-woven fabrics.
Background technique
Non-woven fabrics is also known as nonwoven fabric, is to be made of fiber orient or random, is environment-friendly materials of new generation, has anti-
It is damp, ventilative, flexible, light, not combustion-supporting, be easy to decompose, be nontoxic nonirritant, rich in color, cheap, recyclable etc.
Feature.The wide range of applications of non-woven fabrics is mainly used in the fields such as medical protection, clothes, industry and agricultural.But at present
Medical non-woven fabrics antibacterial, in terms of can not meet medical a variety of needs simultaneously, it is functional relatively simple.
Summary of the invention
Technical problems based on background technology, the invention proposes a kind of antibiotic ultraviolet-resistant non-woven fabrics, have very
Antibacterial well, uvioresistant effect.
The invention proposes a kind of antibiotic ultraviolet-resistant non-woven fabrics, the antibiotic ultraviolet-resistant non-woven fabrics is TiO2：(Al,
Ce)/polyamide non-woven fabrics, raw material include TiO2：(Al, Ce) powder, polyamide, n,N-dimethylacetamide.
Preferably, the TiO2：The raw material of (Al, Ce) powder includes Ti (NO3)4、Ce(NO3)3、Al(NO3)3, citric acid,
Polyethylene glycol 400.
Preferably, the Ti (NO3)4、Ce(NO3)3、Al(NO3)3The mass ratio of the material be 1：3-4：90-110.
Preferably, the described (Ti4++Ce3++Al3+) it with the mass ratio of the material of citric acid is 1：1.5-2.0.
Preferably, the TiO2：TiO in (Al, Ce)/polyamide non-woven fabrics2：The mass fraction of (Al, Ce) is 40-50%.
Preferably, the TiO2：The weight ratio of (Al, Ce) powder and polyamide is 4-5：1-1.5.
The present invention is prepared by conventional method in that art.
The present invention is with TiO2：(Al, Ce) powder, polyamide, n,N-dimethylacetamide are raw material, and the spinning of non-woven fabrics is steady
Calmly, dispersion degree is smaller, and fibre diameter is smaller, and metal-powder is uniform and is densely distributed in the surface of Fypro, energy
Enough ultraviolet light penetrances for reducing non-woven fabrics of the present invention, effectively enhancing anti-uv-ray；The TiO that the present invention adds2：(Al,
Ce) powder is by Ti (NO3)4、Ce(NO3)3、Al(NO3)3, citric acid, polyethylene glycol 400 etc. be used as raw material, Al- can be obtained
Ce is co-doped with TiO2Nano-powder, i.e. TiO2：Ce, Al metal ion of (Al, Ce) powder, doping can reduce electronic transition energy,
Enhance sterilization, anti-microbial property, while there are also a small amount of digestion of metallic ion, reacted with the group on protein or destroy microorganism and is thin
The enzyme of born of the same parents' electron transport system, so that bacterial cell and its physiological activity are destroyed, to achieve the effect that sterilization, in addition, receiving
Rice TiO2Also there is very strong anti-ultraviolet function, further enhance anti-ultraviolet property of the invention, effectively reduce radiation pair
Human body damages.
Specific embodiment
In the following, technical solution of the present invention is described in detail by specific embodiment.
Embodiment 1
A kind of antibiotic ultraviolet-resistant non-woven fabrics, the antibiotic ultraviolet-resistant non-woven fabrics are TiO2：(Al, Ce)/polyamide without
Woven fabric, raw material include TiO2：(Al, Ce) powder, polyamide, n,N-dimethylacetamide；
Wherein, the TiO2：The raw material of (Al, Ce) powder includes Ti (NO3)4、Ce(NO3)3、Al(NO3)3, it is citric acid, poly-
Ethylene glycol 400；Ti (the NO3)4、Ce(NO3)3、Al(NO3)3The mass ratio of the material be 1：4：90；(the Ti4++Ce3++Al3+)
The mass ratio of the material with citric acid is 1：2.0；The TiO2：TiO in (Al, Ce)/polyamide non-woven fabrics2：The quality of (Al, Ce)
Score is 40%；The TiO2：The weight ratio of (Al, Ce) powder and polyamide is 5：1.
Embodiment 2
A kind of antibiotic ultraviolet-resistant non-woven fabrics, the antibiotic ultraviolet-resistant non-woven fabrics are TiO2：(Al, Ce)/polyamide without
Woven fabric, raw material include TiO2：(Al, Ce) powder, polyamide, n,N-dimethylacetamide；
Wherein, the TiO2：The raw material of (Al, Ce) powder includes Ti (NO3)4、Ce(NO3)3、Al(NO3)3, it is citric acid, poly-
Ethylene glycol 400；Ti (the NO3)4、Ce(NO3)3、Al(NO3)3The mass ratio of the material be 1：3：110；(the Ti4++Ce3++Al3 +) it with the mass ratio of the material of citric acid is 1：1.5；The TiO2：TiO in (Al, Ce)/polyamide non-woven fabrics2：The matter of (Al, Ce)
Measuring score is 50%；The TiO2：The weight ratio of (Al, Ce) powder and polyamide is 4：1.5.
Embodiment 3
A kind of antibiotic ultraviolet-resistant non-woven fabrics, the antibiotic ultraviolet-resistant non-woven fabrics are TiO2：(Al, Ce)/polyamide without
Woven fabric, raw material include TiO2：(Al, Ce) powder, polyamide, n,N-dimethylacetamide；
Wherein, the TiO2：The raw material of (Al, Ce) powder includes Ti (NO3)4、Ce(NO3)3、Al(NO3)3, it is citric acid, poly-
Ethylene glycol 400；Ti (the NO3)4、Ce(NO3)3、Al(NO3)3The mass ratio of the material be 1：4：105；(the Ti4++Ce3++Al3 +) it with the mass ratio of the material of citric acid is 1：1.6；The TiO2：TiO in (Al, Ce)/polyamide non-woven fabrics2：The matter of (Al, Ce)
Measuring score is 48%；The TiO2：The weight ratio of (Al, Ce) powder and polyamide is 4：1.
Embodiment 4
A kind of antibiotic ultraviolet-resistant non-woven fabrics, the antibiotic ultraviolet-resistant non-woven fabrics are TiO2：(Al, Ce)/polyamide without
Woven fabric, raw material include TiO2：(Al, Ce) powder, polyamide, n,N-dimethylacetamide；
Wherein, the TiO2：The raw material of (Al, Ce) powder includes Ti (NO3)4、Ce(NO3)3、Al(NO3)3, it is citric acid, poly-
Ethylene glycol 400；Ti (the NO3)4、Ce(NO3)3、Al(NO3)3The mass ratio of the material be 1：3：95；(the Ti4++Ce3++Al3+)
The mass ratio of the material with citric acid is 1：1.8；The TiO2：TiO in (Al, Ce)/polyamide non-woven fabrics2：The quality of (Al, Ce)
Score is 42%；The TiO2：The weight ratio of (Al, Ce) powder and polyamide is 5：1.5.
Embodiment 5
A kind of antibiotic ultraviolet-resistant non-woven fabrics, the antibiotic ultraviolet-resistant non-woven fabrics are TiO2：(Al, Ce)/polyamide without
Woven fabric, raw material include TiO2：(Al, Ce) powder, polyamide, n,N-dimethylacetamide；
Wherein, the TiO2：The raw material of (Al, Ce) powder includes Ti (NO3)4、Ce(NO3)3、Al(NO3)3, it is citric acid, poly-
Ethylene glycol 400；Ti (the NO3)4、Ce(NO3)3、Al(NO3)3The mass ratio of the material be 1：3.5：100；(the Ti4++Ce3++
Al3+) it with the mass ratio of the material of citric acid is 1：1.7；The TiO2：TiO in (Al, Ce)/polyamide non-woven fabrics2：(Al, Ce's)
Mass fraction is 45%；The TiO2：The weight ratio of (Al, Ce) powder and polyamide is 4.5：1.
Reference examples 1
A kind of non-woven fabrics, using the nano-TiO undoped with Al, Ce2, other conditions are same as Example 5.
Test example 1
The non-woven fabrics to 3-5 of the embodiment of the present invention and the non-woven fabrics of reference examples 1 carry out anti-microbial property measurement respectively：By nonwoven
Cloth, which is respectively put into the shaker flask containing bacteria suspension, vibrates 10h, and the bacterium solution for then taking out oscillation front and back carries out gradient dilution culture
It counts, test organisms uses staphylococcus aureus and Escherichia coli, calculates test organisms bacteriostasis rate, the results are shown in Table 1.
Table 1
| Project | Embodiment 3 | Embodiment 4 | Embodiment 5 | Reference examples 1 |
| Bacteriostasis rate (%) | 98.68 | 98.76 | 98.78 | 50.18 |
As can be seen from Table 1, after non-woven fabrics of the invention vibrates 10h in having bacteria suspension, fungistatic effect is obvious, therefore,
Non-woven fabrics of the invention has excellent anti-microbial property.
Test example 2
The non-woven fabrics to 3-5 of the embodiment of the present invention and the non-woven fabrics of reference examples 1 carry out anti-ultraviolet property measurement respectively：Root
According to GB/T 18830-2009, non-woven fabrics is tested respectively using UV1000F type ultraviolet permeability analyzer, is obtained ultraviolet
Ultraviolet permeability data under line protecting factor UPF value and different wave length are simultaneously mapped, wherein UVA is the purple of wavelength 315-400nm
Outside line, UVB are the ultraviolet light of wavelength 290-315nm, record UVA transmitance, UVB transmitance, the results are shown in Table 2.
Table 2
| Project | Embodiment 3 | Embodiment 4 | Embodiment 5 | Reference examples 1 |
| UPF value | 50+ | 50+ | 50+ | 50+ |
| UVA transmitance (%) | 0.05 | 0.04 | 0.05 | 0.45 |
| UVB transmitance (%) | 0.06 | 0.06 | 0.05 | 0.52 |
As can be seen from Table 2, non-woven fabrics of the invention can effectively reduce the transmitance of ultraviolet light, have excellent uvioresistant
Linear energy.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto,
Anyone skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its
Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.
Claims (6)
1. a kind of antibiotic ultraviolet-resistant non-woven fabrics, which is characterized in that the antibiotic ultraviolet-resistant non-woven fabrics is TiO2：(Al, Ce)/
Polyamide non-woven fabrics, raw material include TiO2：(Al, Ce) powder, polyamide, n,N-dimethylacetamide.
2. antibiotic ultraviolet-resistant non-woven fabrics according to claim 1, which is characterized in that the TiO2：The original of (Al, Ce) powder
Material includes Ti (NO3)4、Ce(NO3)3、Al(NO3)3, citric acid, polyethylene glycol 400.
3. antibiotic ultraviolet-resistant non-woven fabrics according to claim 2, which is characterized in that the Ti (NO3)4、Ce(NO3)3、Al
(NO3)3The mass ratio of the material be 1：3-4：90-110.
4. antibiotic ultraviolet-resistant non-woven fabrics according to claim 2, which is characterized in that (the Ti4++Ce3++Al3+) and lemon
The mass ratio of the material of acid is 1：1.5-2.0.
5. antibiotic ultraviolet-resistant non-woven fabrics according to claim 1, which is characterized in that the TiO2：(Al, Ce)/polyamide without
TiO in woven fabric2：The mass fraction of (Al, Ce) is 40-50%.
6. antibiotic ultraviolet-resistant non-woven fabrics according to claim 1, which is characterized in that the TiO2：(Al, Ce) powder and poly-
The weight ratio of amide is 4-5：1-1.5.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810768988.4A CN108866808A (en) | 2018-07-13 | 2018-07-13 | A kind of antibiotic ultraviolet-resistant non-woven fabrics |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810768988.4A CN108866808A (en) | 2018-07-13 | 2018-07-13 | A kind of antibiotic ultraviolet-resistant non-woven fabrics |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108866808A true CN108866808A (en) | 2018-11-23 |
Family
ID=64301630
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810768988.4A Pending CN108866808A (en) | 2018-07-13 | 2018-07-13 | A kind of antibiotic ultraviolet-resistant non-woven fabrics |
Country Status (1)
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Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1467314A (en) * | 2003-06-12 | 2004-01-14 | 东南大学 | Antibacterial nanofiber material and preparation method thereof |
| CN101029433A (en) * | 2007-03-06 | 2007-09-05 | 天津工业大学 | Production and producer for functional modified microgranular melt-jetting non-woven cloth |
| CN101876091A (en) * | 2010-05-25 | 2010-11-03 | 合肥利阳环保科技有限公司 | Ultraviolet-resistant environmental-protection ecological cloth and preparation method thereof |
| CN101990586A (en) * | 2008-04-03 | 2011-03-23 | Usg内部股份有限公司 | Non-woven material and method of making such material |
| CN102511499A (en) * | 2011-10-27 | 2012-06-27 | 浙江金海环境技术股份有限公司 | Green ecological habitat antibacterial self-cleaning material |
| CN103485074A (en) * | 2013-08-09 | 2014-01-01 | 天津工业大学 | Device and method of preparing electrostatic spinning polymer/inorganic particle nano-composite film |
| CN105658423A (en) * | 2013-10-21 | 2016-06-08 | 纳幕尔杜邦公司 | Composites and ballistic resistant armor articles containing composites |
| CN107675361A (en) * | 2017-10-12 | 2018-02-09 | 上海工程技术大学 | A kind of Static Spinning nano-composite fiber felt and its preparation method and application |
-
2018
- 2018-07-13 CN CN201810768988.4A patent/CN108866808A/en active Pending
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1467314A (en) * | 2003-06-12 | 2004-01-14 | 东南大学 | Antibacterial nanofiber material and preparation method thereof |
| CN101029433A (en) * | 2007-03-06 | 2007-09-05 | 天津工业大学 | Production and producer for functional modified microgranular melt-jetting non-woven cloth |
| CN101990586A (en) * | 2008-04-03 | 2011-03-23 | Usg内部股份有限公司 | Non-woven material and method of making such material |
| CN101876091A (en) * | 2010-05-25 | 2010-11-03 | 合肥利阳环保科技有限公司 | Ultraviolet-resistant environmental-protection ecological cloth and preparation method thereof |
| CN102511499A (en) * | 2011-10-27 | 2012-06-27 | 浙江金海环境技术股份有限公司 | Green ecological habitat antibacterial self-cleaning material |
| CN103485074A (en) * | 2013-08-09 | 2014-01-01 | 天津工业大学 | Device and method of preparing electrostatic spinning polymer/inorganic particle nano-composite film |
| CN105658423A (en) * | 2013-10-21 | 2016-06-08 | 纳幕尔杜邦公司 | Composites and ballistic resistant armor articles containing composites |
| CN107675361A (en) * | 2017-10-12 | 2018-02-09 | 上海工程技术大学 | A kind of Static Spinning nano-composite fiber felt and its preparation method and application |
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Application publication date: 20181123 |