CN108794221A - A kind of high concentration resistive connection crystalline substance humic acid Water-soluble liquid fertilizer - Google Patents
A kind of high concentration resistive connection crystalline substance humic acid Water-soluble liquid fertilizer Download PDFInfo
- Publication number
- CN108794221A CN108794221A CN201811065115.3A CN201811065115A CN108794221A CN 108794221 A CN108794221 A CN 108794221A CN 201811065115 A CN201811065115 A CN 201811065115A CN 108794221 A CN108794221 A CN 108794221A
- Authority
- CN
- China
- Prior art keywords
- potassium
- water
- high concentration
- crystalline substance
- humic acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003337 fertilizer Substances 0.000 title claims abstract description 28
- 239000007788 liquid Substances 0.000 title claims abstract description 15
- QJZYHAIUNVAGQP-UHFFFAOYSA-N 3-nitrobicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid Chemical compound C1C2C=CC1C(C(=O)O)C2(C(O)=O)[N+]([O-])=O QJZYHAIUNVAGQP-UHFFFAOYSA-N 0.000 title claims abstract description 14
- 239000004021 humic acid Substances 0.000 title claims abstract description 14
- 239000000126 substance Substances 0.000 title claims abstract description 14
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims abstract description 36
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 34
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 claims abstract description 19
- 229930195725 Mannitol Natural products 0.000 claims abstract description 17
- 235000011187 glycerol Nutrition 0.000 claims abstract description 17
- 235000010355 mannitol Nutrition 0.000 claims abstract description 17
- 239000000594 mannitol Substances 0.000 claims abstract description 17
- 229910000402 monopotassium phosphate Inorganic materials 0.000 claims abstract description 14
- 235000019796 monopotassium phosphate Nutrition 0.000 claims abstract description 14
- PJNZPQUBCPKICU-UHFFFAOYSA-N phosphoric acid;potassium Chemical compound [K].OP(O)(O)=O PJNZPQUBCPKICU-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000002994 raw material Substances 0.000 claims abstract description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims abstract description 11
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000004202 carbamide Substances 0.000 claims abstract description 11
- 229910052700 potassium Inorganic materials 0.000 claims abstract description 11
- 239000011591 potassium Substances 0.000 claims abstract description 11
- 239000004480 active ingredient Substances 0.000 claims abstract description 3
- 235000013399 edible fruits Nutrition 0.000 abstract description 5
- 230000004720 fertilization Effects 0.000 abstract description 2
- 235000013311 vegetables Nutrition 0.000 abstract description 2
- 238000006243 chemical reaction Methods 0.000 description 5
- 239000012535 impurity Substances 0.000 description 5
- 235000013619 trace mineral Nutrition 0.000 description 5
- 239000011573 trace mineral Substances 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000005189 flocculation Methods 0.000 description 3
- 230000016615 flocculation Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 235000015097 nutrients Nutrition 0.000 description 3
- 238000001556 precipitation Methods 0.000 description 3
- 239000002689 soil Substances 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000013522 chelant Substances 0.000 description 2
- 239000008139 complexing agent Substances 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 229940072033 potash Drugs 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 235000015320 potassium carbonate Nutrition 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical compound ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 230000000536 complexating effect Effects 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- ZPWVASYFFYYZEW-UHFFFAOYSA-L dipotassium hydrogen phosphate Chemical compound [K+].[K+].OP([O-])([O-])=O ZPWVASYFFYYZEW-UHFFFAOYSA-L 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 230000002262 irrigation Effects 0.000 description 1
- 238000003973 irrigation Methods 0.000 description 1
- 230000035800 maturation Effects 0.000 description 1
- 230000004060 metabolic process Effects 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000003204 osmotic effect Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 230000008635 plant growth Effects 0.000 description 1
- 230000037039 plant physiology Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000003303 reheating Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 230000001502 supplementing effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B7/00—Fertilisers based essentially on alkali or ammonium orthophosphates
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/80—Soil conditioners
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/20—Liquid fertilisers
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Pest Control & Pesticides (AREA)
- Soil Sciences (AREA)
- Fertilizers (AREA)
Abstract
The present invention relates to agricultural fertilizer field, i.e., a kind of high concentration resistive connection crystalline substance humic acid Water-soluble liquid fertilizer.It is suitble to vegetables and fruits class crop fertilization.Its active ingredient is made of the raw material of following weight percent：Glycerine 8-12%, mannitol 12-18%, urea 12-18%, potassium dihydrogen phosphate 20-30%, potassium hydroxide 9-15%, potassium humate 6-10%, water 12-18%.Solve the problems, such as that liquid Water soluble fertilizer residue is high, content is low, fertilizer efficiency is insufficient, utilization rate is low.
Description
Technical field
The present invention relates to agricultural fertilizer field, i.e., a kind of high concentration resistive connection crystalline substance humic acid Water-soluble liquid fertilizer.It is suitble to vegetables and fruits class
Crop fertilization.
Background technology
In the prior art, humic acid water soluble fertilizer present in market is there are shortcomings, interreaction between raw material
Generate insoluble substance causes production cost big, simple inorganic salts since inorganic salts dissolution of raw material degree restricted concentration is low
It is low as nutrient crop absorption ratio, while in modern agriculture water-fertilizer integral, sprinkling irrigation and dropper facility are used, if water-soluble
Property fertilizer residue rate it is excessively high, it will phenomena such as leading to plugging, and since the uncontrollable reaction of storeroom causes fertilizer efficiency to reduce, profit
It is accordingly reduced with rate.
Invention content
The purpose of the present invention is provide a kind of high concentration resistive connection crystalline substance humic acid Water-soluble liquid fertilizer against the above deficiency.
Solve the problems, such as that liquid Water soluble fertilizer residue is high, content is low, fertilizer efficiency is insufficient, utilization rate is low.
Technical solution of the invention is：A kind of high concentration resistive connection crystalline substance humic acid Water-soluble liquid fertilizer, feature exist
It is made of the raw material of following weight percent in its active ingredient：Glycerine 8-12%, mannitol 12-18%, urea 12-
18%, potassium dihydrogen phosphate 20-30%, potassium hydroxide 9-15%, potassium humate 6-10%, water 12-18%.
Fang Xie：
Glycerine：Adjust crop osmotic pressure, and mannitol collective effect, by complexing of metal ion in soil.
Mannitol：Resistance of the crop to active oxygen is improved, the organoleptic quality and sugar content of the products such as fruit are improved.Addition third
Triol, mannitol are as the complexing agent for being also easy to produce impurity trace element and other metallic elements, it is therefore prevented that the generation of impurity.Due to
The addition of glycerine and mannitol can promote the surface tension of product whole system, expand dissolving power of the solvent to solute, simultaneously
PH value is adjusted close to neutrality, enhances glycerine and mannitol to the ability of dicyandiamide solution surface tension adjustment, is finally reached promotion
Concentration and non crystallized purpose
Urea：It can promote plant growth, especially cauline leaf effect is protruded.
Potassium dihydrogen phosphate：Crop can be promoted to fully absorb nitrogen and P elements, for lacking the crop energy of phosphorus, nitrogen stress
Play the role of quickly supplementing.It is more many soon than previous common phosphorus potash fertilizer, enhance the resistance of crop, drought resisting, cold tolerance,
Crop and fruit can be significantly expanded, increases mouthfeel etc., while maturation can also be accelerated
Potassium hydroxide：It is main to adjust product pH value, it can simultaneously serve as potash fertilizer and absorbed for crop.
Potassium humate：Stimulate plant physiology metabolism, chelating Trace Elements in Soil to be absorbed for crop, improve soil texture,
Enhance crop anti-adversity.
Specific preparation method is as follows：Water is first injected in reacting tank body, glycerine and mannitol is sequentially added, is sufficiently mixed
After uniformly, potassium dihydrogen phosphate and potassium hydroxide are alternately added, and are uniformly mixed fully reaction, material is allowed fully to be chelated,
Urea is added after reaction, be all added and potassium humate is added after dissolving, until stirring evenly.
It is an advantage of the invention that：1, it can not be stable in the presence of with over-saturation state for extended periods for inorganic salts a great number of elements
In solution system, now use alcohol chelating technology, be made highly effective chelating fertilizer, can use glycerine, mannitol, effect better than citric acid,
The chelate fertilizers such as amino acid, at the same using alcohol chelating after product can again with it is trace element chelated, solve conventional products add
Flocculation, precipitation are led to the problem of after entering trace element（Conventional products since micro- anion is combined with acid group cationoid,
As insoluble or indissoluble metallic salt, deposition flocculation in the product uses chelating technology in this product, by micro- sun from
Son and chelant ties avoid generating flocculation, precipitation to solve the problems, such as that micro- cation is combined with acid ion）.
2, can nutrient be transported to the crops demand such as fruit position rapidly after applying fertilizer.Concentration can be not only promoted, while solving height
Concentration crystallisation problems（Due to the addition of glycerine and mannitol, the surface tension of product whole system can be promoted, expands solvent pair
The dissolving power of solute, while pH value is adjusted close to neutrality, enhance glycerine and mannitol to dicyandiamide solution surface tension adjustment
Ability is finally reached and promotes concentration and non crystallized purpose）.3, in addition to Chelating state element, the reasonable autoreaction of storeroom is also used
Mode remove from production and need the energy consumption heated, while using itself chemical reaction by acid-base value adjustment lifting body
It is stability, and concentration is further promoted.Potassium dihydrogen phosphate itself in product can be used as weak diacid, in system itself
Dissociate hydrogen ion, and it is in acidity to make solution integrally, while potassium dihydrogen phosphate own solubility is limited, can not promote content, now will
The potassium hydroxide of proper ratio is added, and combination reaction is carried out with potassium dihydrogen phosphate, anyway system temperature can be made by generating heat in the process
Degree increases the production cost for saving reheating, while generating dipotassium hydrogen phosphate, can not only be used for chelating agent aid, while lifting body
It is temperature, nutrient can also be greatly promoted and contained.4, this product can both solve due to product design it is low caused by freight it is high,
The big two large problems of usage amount, while this product can solve crystallization, precipitation, impurity plugging that product occurs in the market etc. now
As.（Usually there is problem in conventional products, this product is in raw material selection in order to reduce cost in raw material selection and auxiliary material addition
Using the raw material of high-purity, while glycerine, mannitol are added as being also easy to produce impurity trace element and other metallic elements
Complexing agent, it is therefore prevented that the generation of impurity.）
Embodiments of the present invention are described in further detail below in conjunction with embodiment.
Specific implementation mode
Embodiment 1
A kind of high concentration resistive connection crystalline substance humic acid Water-soluble liquid fertilizer, is made of the raw material of following weight percent：Glycerine 8%,
Mannitol 18%, urea 12%, potassium dihydrogen phosphate 30%, potassium hydroxide 10%, potassium humate 10%, water 12%.
Embodiment 2
A kind of high concentration resistive connection crystalline substance humic acid Water-soluble liquid fertilizer, it is characterised in that by the raw material system of following weight percent
At：Glycerine 12%, mannitol 12%, urea 18%, potassium dihydrogen phosphate 20%, potassium hydroxide 15%, potassium humate 8%, water 15%.
Embodiment 3
A kind of high concentration resistive connection crystalline substance humic acid Water-soluble liquid fertilizer, is made of the raw material of following weight percent：Glycerine
10%, mannitol 15%, urea 15%, potassium dihydrogen phosphate 25%, potassium hydroxide 12%, potassium humate 8%, water 15%.
It is described above, only specific implementation mode of the invention, various illustrations are not to the substantive content structure of the present invention
At limitation.
Claims (4)
1. a kind of high concentration resistive connection crystalline substance humic acid Water-soluble liquid fertilizer, it is characterised in that its active ingredient is by following weight percent
The raw material of ratio is made：Glycerine 8-12%, mannitol 12-18%, urea 12-18%, potassium dihydrogen phosphate 20-30%, hydroxide
Potassium 9-15%, potassium humate 6-10%, water 12-18%.
2. high concentration resistive connection crystalline substance humic acid Water-soluble liquid fertilizer described in accordance with the claim 1, it is characterised in that by following heavy
The raw material of amount percentage is made：Glycerine 10%, mannitol 15%, urea 15%, potassium dihydrogen phosphate 25%, potassium hydroxide 12%, humic
Sour potassium 8%, water 15%.
3. according to high concentration resistive connection crystalline substance humic acid Water-soluble liquid fertilizer as claimed in claim 1 or 2, it is characterised in that by following
The raw material of weight percent is made：Glycerine 8%, mannitol 18%, urea 12%, potassium dihydrogen phosphate 30%, potassium hydroxide 10%, corruption
Grow sour potassium 10%, water 12%.
4. high concentration resistive connection crystalline substance humic acid Water-soluble liquid fertilizer described in accordance with the claim 3, it is characterised in that by following heavy
The raw material of amount percentage is made：Glycerine 12%, mannitol 12%, urea 18%, potassium dihydrogen phosphate 20%, potassium hydroxide 15%, humic
Sour potassium 8%, water 15%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811065115.3A CN108794221A (en) | 2018-09-13 | 2018-09-13 | A kind of high concentration resistive connection crystalline substance humic acid Water-soluble liquid fertilizer |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811065115.3A CN108794221A (en) | 2018-09-13 | 2018-09-13 | A kind of high concentration resistive connection crystalline substance humic acid Water-soluble liquid fertilizer |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108794221A true CN108794221A (en) | 2018-11-13 |
Family
ID=64082351
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811065115.3A Pending CN108794221A (en) | 2018-09-13 | 2018-09-13 | A kind of high concentration resistive connection crystalline substance humic acid Water-soluble liquid fertilizer |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108794221A (en) |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6165245A (en) * | 1998-09-09 | 2000-12-26 | Yamashita; Thomas T. | Foliar fertilizer and method for using the same |
| CN104909901A (en) * | 2015-06-08 | 2015-09-16 | 京博农化科技股份有限公司 | Sugar alcohol chelator-amino acid calcium fertilizer and preparation method thereof |
| CN105669297A (en) * | 2015-12-30 | 2016-06-15 | 湖南泰谷生物科技股份有限公司 | Humic acid-containing complete-element water soluble fertilizer, and preparation method and application thereof |
| CN105948955A (en) * | 2016-07-13 | 2016-09-21 | 赵广林 | Production method of fertilizer containing sugar alcohol chelated micro elements |
| CN106146177A (en) * | 2016-08-09 | 2016-11-23 | 青岛大学 | A kind of compound plant fertilizer |
| CN106380279A (en) * | 2016-08-29 | 2017-02-08 | 张文博 | Composite sugar alcohol organic liquid and preparation method thereof |
| CN106892747A (en) * | 2017-02-20 | 2017-06-27 | 深圳市芭田生态工程股份有限公司 | Organic chelated fertilizer synergist and preparation method thereof |
-
2018
- 2018-09-13 CN CN201811065115.3A patent/CN108794221A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6165245A (en) * | 1998-09-09 | 2000-12-26 | Yamashita; Thomas T. | Foliar fertilizer and method for using the same |
| CN104909901A (en) * | 2015-06-08 | 2015-09-16 | 京博农化科技股份有限公司 | Sugar alcohol chelator-amino acid calcium fertilizer and preparation method thereof |
| CN105669297A (en) * | 2015-12-30 | 2016-06-15 | 湖南泰谷生物科技股份有限公司 | Humic acid-containing complete-element water soluble fertilizer, and preparation method and application thereof |
| CN105948955A (en) * | 2016-07-13 | 2016-09-21 | 赵广林 | Production method of fertilizer containing sugar alcohol chelated micro elements |
| CN106146177A (en) * | 2016-08-09 | 2016-11-23 | 青岛大学 | A kind of compound plant fertilizer |
| CN106380279A (en) * | 2016-08-29 | 2017-02-08 | 张文博 | Composite sugar alcohol organic liquid and preparation method thereof |
| CN106892747A (en) * | 2017-02-20 | 2017-06-27 | 深圳市芭田生态工程股份有限公司 | Organic chelated fertilizer synergist and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 曾益坤 等: "《油脂化工》", 28 February 1996, 中国商业出版社 * |
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| PB01 | Publication | ||
| PB01 | Publication | ||
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Application publication date: 20181113 |