CN108793653B - A system and method for comprehensive utilization of all components of sludge - Google Patents
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F11/00—Treatment of sludge; Devices therefor
- C02F11/12—Treatment of sludge; Devices therefor by de-watering, drying or thickening
- C02F11/121—Treatment of sludge; Devices therefor by de-watering, drying or thickening by mechanical de-watering
- C02F11/122—Treatment of sludge; Devices therefor by de-watering, drying or thickening by mechanical de-watering using filter presses
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F11/00—Treatment of sludge; Devices therefor
- C02F11/02—Biological treatment
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F11/00—Treatment of sludge; Devices therefor
- C02F11/10—Treatment of sludge; Devices therefor by pyrolysis
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F11/00—Treatment of sludge; Devices therefor
- C02F11/12—Treatment of sludge; Devices therefor by de-watering, drying or thickening
- C02F11/121—Treatment of sludge; Devices therefor by de-watering, drying or thickening by mechanical de-watering
- C02F11/127—Treatment of sludge; Devices therefor by de-watering, drying or thickening by mechanical de-watering by centrifugation
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F7/00—Fertilisers from waste water, sewage sludge, sea slime, ooze or similar masses
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/20—Heavy metals or heavy metal compounds
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
- Y02A40/10—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
- Y02A40/20—Fertilizers of biological origin, e.g. guano or fertilizers made from animal corpses
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Abstract
本发明公开了一种综合利用污泥系统及方法,所述系统包括:污泥仓(1)、水力旋流器(2)、生物反应器(3)、压滤机(4)、热水解反应器(5)、炭化装置(6)、浓缩池(7)、吸附剂产品仓(8)、肥料产品仓(9)、菌种罐(10)、菌肥产品仓(11)、金属泥处理仓(12)和调理池(13)。本发明优点在于:水力旋流器无运动部件,构造简单,单位容积的生产能力大;利用不同工艺处理不同粒径有机质:复合菌群分解粒径较大中颗粒中有机质,热水解分解小粒径轻颗粒中有机质,提高了有机质分解效率的同时降低能耗;既回收了重金属,又充分利用其中的N、P、K等有机物质与无机物质。
The invention discloses a system and method for comprehensively utilizing sludge, the system comprising: a sludge bin (1), a hydrocyclone (2), a biological reactor (3), a filter press (4), a hot water Decomposition reactor (5), carbonization device (6), concentration tank (7), adsorbent product bin (8), fertilizer product bin (9), bacterial seed tank (10), bacterial fertilizer product bin (11), metal A mud treatment bin (12) and a conditioning tank (13). The advantages of the invention are: the hydrocyclone has no moving parts, the structure is simple, and the production capacity per unit volume is large; the organic matter with different particle sizes is processed by different processes: the complex bacteria group decomposes the organic matter in the particles with larger particle size, and the thermal hydrolysis decomposition is small. The organic matter in the particles with light particle size improves the decomposition efficiency of organic matter and reduces energy consumption; it not only recovers heavy metals, but also makes full use of organic and inorganic substances such as N, P, and K.
Description
技术领域technical field
本发明属于环保领域,具体地,本发明涉及将污泥全组分综合利用的系统和方法。The invention belongs to the field of environmental protection, and in particular, the invention relates to a system and method for comprehensively utilizing all components of sludge.
背景技术Background technique
污泥中含水量高,易腐烂,成分复杂,不仅含有N、P、K等营养元素,而且含有大量的病原菌、细菌、寄生虫卵及重金属等有毒有害物质及致癌物质,并伴有强烈恶臭。中国专利CN106949475A(一种污泥焚烧系统及其焚烧方法)采用焚烧的常规方法处理污泥,但常规方法无法利用污泥中有机物质,并且污泥中的贵金属及有毒物质不能得到有效处理,污染环境。中国专利CN106747779A(一种污泥堆肥改良方法),在污泥中加入发酵菌等进行堆肥发酵,可以综合利用污泥中的有机物质,但是不能有效的处理工业污泥中含量较高的重金属,会对环境造成污染。The sludge has high water content, perishable and complex composition. It not only contains N, P, K and other nutrients, but also contains a large number of pathogenic bacteria, bacteria, parasite eggs and heavy metals and other toxic and harmful substances and carcinogens, and is accompanied by a strong odor. . Chinese patent CN106949475A (a kind of sludge incineration system and its incineration method) adopts the conventional method of incineration to process the sludge, but the conventional method cannot utilize the organic substances in the sludge, and the precious metals and toxic substances in the sludge cannot be effectively treated, polluting surroundings. Chinese patent CN106747779A (a kind of sludge composting improvement method), adding fermentation bacteria etc. to sludge to carry out composting fermentation, can comprehensively utilize the organic matter in sludge, but cannot effectively deal with heavy metals with higher content in industrial sludge, will pollute the environment.
发明内容SUMMARY OF THE INVENTION
本发明目的在于,提供一种污泥全组分综合利用系统及方法,该方法解决常规工艺污泥处理后不能彻底除去重金属等有毒物质、有机物质不能综合利用、能耗高的问题。The purpose of the present invention is to provide a system and method for comprehensive utilization of all components of sludge, which solves the problems that toxic substances such as heavy metals cannot be completely removed, organic substances cannot be comprehensively utilized, and energy consumption is high after conventional sludge treatment.
为达到上述目的,本发明采用如下的技术方案:To achieve the above object, the present invention adopts the following technical scheme:
一种污泥全组分综合利用系统,所述系统包括:污泥仓1、水力旋流器2、生物反应器3、压滤机4、热水解反应器5、炭化装置6、浓缩池7、吸附剂产品仓8、肥料产品仓9、菌种罐10、菌肥产品仓11、金属泥处理仓12和调理池13;A sludge full-component comprehensive utilization system, the system includes: a sludge bin 1, a hydrocyclone 2, a biological reactor 3, a filter press 4, a
所述水力旋流器2包括一段水力旋流器2-1和二段水力旋流器2-2;The hydrocyclone 2 includes a first-stage hydrocyclone 2-1 and a second-stage hydrocyclone 2-2;
所述压滤机4包括第一压滤机4-1和第二压滤机4-2;The filter press 4 includes a first filter press 4-1 and a second filter press 4-2;
所述污泥仓1的出料口与一段水力旋流器2-1的进料口连接,一段水力旋流器2-1的底流出口与第一压滤机4-1的进料口连接;第一压滤机4-1的溢流出口与浓缩池7的进料口连接,第一压滤机4-1的滤饼出口与炭化装置6的进料口连接,炭化装置6的出料口与吸附剂产品仓8的进料口连接;The discharge port of the sludge bin 1 is connected with the feed port of the first stage of the hydrocyclone 2-1, and the underflow outlet of the first stage of the hydrocyclone 2-1 is connected with the feed port of the first filter press 4-1 ; The overflow outlet of the first filter press 4-1 is connected with the feed port of the
所述一段水力旋流器2-1的溢流出口与二段水力旋流器2-2的进料口连接,二段水力旋流器2-2的溢流出口与热解反应器5的进料口连接,二段水力旋流器2-2的底流出口与生物反应池3的进料口连接,生物反应池3的出料口和热解反应器5的出料口均与第二压滤机4-2的进料口连接;第二压滤机4-2的滤液出口与浓缩池7的进料口连接,浓缩池7的出料口与调理池13的进料口连接,调理池13的液体出口与水力旋流器2相连,使液体返回水力旋流器2循环利用,调理池13的固体出口与金属泥处理仓12的进料口连接;The overflow outlet of the first-stage hydrocyclone 2-1 is connected with the feed port of the second-stage hydrocyclone 2-2, and the overflow outlet of the second-stage hydrocyclone 2-2 is connected to the outlet of the
所述第二压滤机4-2的滤饼出口与肥料产品仓9,肥料产品仓9的菌种进料口与菌种罐10的出料口连接,肥料产品仓9的出料口与菌肥产品仓11的进料口连接。The filter cake outlet of the second filter press 4-2 is connected to the
优选地,一段水力旋流器和二段水力旋流器串联使用;一段水力旋流器的直径200-300mm,放置锥角20-30°;二段水力旋流器的直径50-150mm,放置锥角10-15°。Preferably, the first-stage hydrocyclone and the second-stage hydrocyclone are used in series; the diameter of the first-stage hydrocyclone is 200-300mm, and the placement cone angle is 20-30°; the diameter of the second-stage hydrocyclone is 50-150mm, which is placed Cone angle 10-15°.
本发明还提供了一种基于上述系统的污泥全组分综合利用方法,所述方法包括如下步骤:The present invention also provides a method for comprehensive utilization of all sludge components based on the above system, the method comprising the following steps:
1)污泥从污泥仓1泵入到一段水力旋流器2-1,经一段水力旋流器2-1分离后,重颗粒物质底流泵入到第一压滤机4-1,第一压滤机4-1的滤液通入浓缩池7,滤饼进入炭化装置6,炭化处理后作为吸附剂进入吸附剂产品仓8;1) The sludge is pumped from the sludge silo 1 to the first stage of the hydrocyclone 2-1. After being separated by the first stage of the hydrocyclone 2-1, the underflow of heavy particulate matter is pumped into the first filter press 4-1. The filtrate of a filter press 4-1 is passed into the
2)一段水力旋流器2-1溢流自流到二段水力旋流器2-2进行再处理,二段水力旋流器2-2分离的轻颗粒物质溢流进入热水解反应器5,加入添加剂进行热水解,热水解所得物质进入第二压滤机4-2过滤,滤液进入浓缩池7,浓缩后进入调理池13进行生物化学调理,液体返回旋流器2循环利用,固体物质进入金属泥处理仓12回收利用金属泥;第二压滤机4-2过滤的滤饼进入肥料产品仓9,加入菌种罐10的菌,得到的菌肥进入到菌肥产品仓11;2) The overflow of the first-stage hydrocyclone 2-1 flows to the second-stage hydrocyclone 2-2 for reprocessing, and the light particulate matter separated by the second-stage hydrocyclone 2-2 overflows into the
3)二段水力旋流器2-2分离的中颗粒物质底流进入生物反应池3并加入复合菌群进行反应处理,反应产物进入第二压滤机4-2过滤;滤液进入浓缩池7,浓缩后进入调理池13进行生物化学调理,液体返回旋流器2循环利用,固体物质进入金属泥处理仓12回收利用金属泥;第二压滤机4-2过滤的滤饼进入肥料产品仓9,加入菌种罐10的菌,得到的菌肥进入到菌肥产品仓11。3) The underflow of medium particulate matter separated by the second-stage hydrocyclone 2-2 enters the biological reaction tank 3 and adds compound bacteria to carry out reaction treatment, and the reaction product enters the second filter press 4-2 for filtration; the filtrate enters the
优选地,所述步骤1)中,炭化装置6中炭化温度为180℃-300℃,炭化时间为2h-4h。Preferably, in the step 1), the carbonization temperature in the
优选地,所述步骤2)中,热水解反应器5的热水解温度为150℃-250℃,时间为2h-4h。Preferably, in the step 2), the thermal hydrolysis temperature of the
优选地,所述步骤2)中,添加剂为铵盐,进一步优选地,所述铵盐为氯化铵。Preferably, in the step 2), the additive is ammonium salt, and further preferably, the ammonium salt is ammonium chloride.
优选地,所述步骤3)中,加入的复合菌群为嗜酸性氧化硫硫杆菌和嗜酸性氧化亚铁硫杆菌,嗜酸性氧化硫硫杆菌和嗜酸性氧化亚铁硫杆菌的比例为4:1-2:1。Preferably, in the described step 3), the compound flora that is added is Thiobacillus acidophilus thiooxidans and Thiobacillus acidophilus ferrooxidans, and the ratio of Thiobacillus acidophilus thiooxidans and Thiobacillus acidophilus ferrooxidans is 4: 1-2:1.
优选地,步骤2)和3)中,根据不同污泥重金属种类的差异,通过调节温度、pH、电化学环境,或添加微生物加速其还原等不同方法使重金属形成金属化合物(络合物)或金属单质,形成金属泥进行回收。Preferably, in steps 2) and 3), according to the difference in the types of heavy metals in different sludges, by adjusting the temperature, pH, electrochemical environment, or adding microorganisms to accelerate their reduction and other methods, the heavy metals are formed into metal compounds (complexes) or Elemental metal to form metal mud for recycling.
本发明属于环保-资源综合处理领域,涉及将一种污泥进行全组分综合处理的方法和设备,首先污泥通入水力旋流器,分离得到重颗粒、中颗粒、轻颗粒物质;以二氧化硅等无机物为主的重颗粒在180℃-300℃的温度条件下进行炭化焙烧,以中粒级有机物为主的中颗粒进行混菌酸性处理,以小粒级有机物为主的轻颗粒加入铵盐等添加剂,在200℃条件下热水解处理。过程中过滤产生的滤液通入浓缩池进行生物化学调理,形成重金属化合物(络合物)和金属单质,混合金属泥回收利用,上清液返回到旋流器,进入下一循环。重颗粒处理后用作吸附剂,中、轻颗粒处理后形成的肥料,加入菌制成菌肥。本发明根据污泥所含物质密度和粒度的不同,使用水力旋流器将污泥分为可无机物质、不同粒度大小的有机物质,再进一步加工成吸附剂、肥料、菌肥和金属泥,将污染全元素回收利用。优点在于:利用不同的工艺处理不同粒径的有机物质,大大提高了分解有机质的效率,既回收了重金属,又充分利用其中的N、P、K等有机物质和无机物质。The invention belongs to the field of environmental protection-resource comprehensive treatment, and relates to a method and equipment for comprehensively treating a sludge with all components. First, the sludge is passed into a hydrocyclone to separate heavy particles, medium particles and light particles; The heavy particles mainly composed of inorganic substances such as silica are subjected to carbonization and roasting at a temperature of 180℃-300℃, the medium particles mainly composed of medium-sized organic substances are subjected to mixed bacteria acid treatment, and the light particles mainly composed of small-sized organic substances Add additives such as ammonium salt, and perform thermal hydrolysis treatment at 200°C. The filtrate produced by filtration in the process is passed into the concentration tank for biochemical conditioning to form heavy metal compounds (complexes) and metal elements, mixed with metal mud for recycling, and the supernatant liquid is returned to the cyclone to enter the next cycle. The heavy particles are treated as adsorbents, and the fertilizers formed by the treatment of medium and light particles are added with bacteria to make bacterial fertilizers. According to the difference in density and particle size of the substances contained in the sludge, the invention uses a hydrocyclone to divide the sludge into inorganic substances and organic substances with different particle sizes, and further processes them into adsorbents, fertilizers, bacterial fertilizers and metal mud. Recycle all elements of pollution. The advantages are: using different processes to treat organic substances with different particle sizes greatly improves the efficiency of decomposing organic substances, not only recovering heavy metals, but also making full use of organic and inorganic substances such as N, P, and K.
本发明使用的水力旋流器无运动部件,构造简单,造价低,单位容积的生产能力大;利用不同工艺处理不同粒径有机质:复合菌群分解粒径较大中颗粒中有机质,热水解分解小粒径轻颗粒中有机质,提高了有机质分解效率的同时降低能耗,分离后的产物利用复合菌群处理及热处理的方法可以分解有机质并加以回收;根据污泥自身的物理性质,使用水力旋流器将污泥分离,既可以回收污泥中的贵金属等有害物质,又可以充分利用其中的N、P、K等有机物质与无机物质。The hydrocyclone used in the present invention has no moving parts, simple structure, low cost, and large production capacity per unit volume; different processes are used to process organic matter of different particle sizes: the compound bacteria decompose the organic matter in the particles with larger particle size, and thermal hydrolysis Decompose organic matter in small particle size light particles, improve the decomposition efficiency of organic matter and reduce energy consumption. The separated product can be decomposed and recovered by the method of compound flora treatment and heat treatment; according to the physical properties of the sludge itself, hydraulic The cyclone separates the sludge, which can not only recover harmful substances such as precious metals in the sludge, but also make full use of organic and inorganic substances such as N, P, and K.
附图说明Description of drawings
图1为本发明的污泥全组分综合利用方法技术路线图;Fig. 1 is the technical roadmap of the comprehensive utilization method of sludge full components of the present invention;
图2为本发明的污泥全组分综合利用系统的结构示意图;Fig. 2 is the structural schematic diagram of the sludge full-component comprehensive utilization system of the present invention;
附图标记:Reference number:
1、污泥仓;2、水力旋流器;2-1、一段水力旋流器;2-2、二段水力旋流器;3、生物反应器;4、压滤机;4-1、第一压滤机;4-2、第二压滤机;5、热水解反应器;6、炭化装置;7、浓缩池;8、吸附剂产品仓;9、肥料产品仓;10、菌种罐;11、菌肥产品仓;12、金属泥处理仓;13、调理池。1. Sludge bin; 2. Hydrocyclone; 2-1, One-stage hydrocyclone; 2-2, Two-stage hydrocyclone; 3. Bioreactor; 4. Filter press; 4-1, The first filter press; 4-2, the second filter press; 5, the thermal hydrolysis reactor; 6, the carbonization device; 7, the concentration tank; 8, the adsorbent product warehouse; 9, the fertilizer product warehouse; 10, the bacteria Seed tank; 11. Bacterial fertilizer product warehouse; 12. Metal mud treatment warehouse; 13. Conditioning tank.
具体实施方式Detailed ways
本说明书中公开得任一特征,除非特别叙述,均可被其他等效或具有类似目的的替代特征加以替换。除非特别叙述,每个特征只是一系列等效或者类似特征中的一个例子而已。所述仅仅是为了帮助理解本发明,不应该视为对本发明的具体限制。Any feature disclosed in this specification, unless expressly stated otherwise, may be replaced by other equivalent or alternative features serving a similar purpose. Unless stated otherwise, each feature is only one example of a series of equivalent or similar features. The description is only for helping understanding of the present invention and should not be regarded as a specific limitation of the present invention.
下面以附图和具体实施方式对本发明作进一步详细的说明。The present invention will be described in further detail below with the accompanying drawings and specific embodiments.
实施例1Example 1
如图2所示,一种污泥全组分综合利用系统,所述系统包括:污泥仓1、水力旋流器2、生物反应器3、压滤机4、热水解反应器5、炭化装置6、浓缩池7、吸附剂产品仓8、肥料产品仓9、菌种罐10、菌肥产品仓11、金属泥处理仓12和调理池13;As shown in Figure 2, a system for comprehensive utilization of all sludge components, the system includes: a sludge bin 1, a hydrocyclone 2, a bioreactor 3, a filter press 4, a
所述水力旋流器2包括一段水力旋流器2-1和二段水力旋流器2-2;The hydrocyclone 2 includes a first-stage hydrocyclone 2-1 and a second-stage hydrocyclone 2-2;
所述压滤机4包括第一压滤机4-1和第二压滤机4-2;The filter press 4 includes a first filter press 4-1 and a second filter press 4-2;
所述污泥仓1的出料口与一段水力旋流器2-1的进料口连接,一段水力旋流器2-1的底流出口与第一压滤机4-1的进料口连接;第一压滤机4-1的溢流出口与浓缩池7的进料口连接,第一压滤机4-1的滤饼出口与炭化装置6的进料口连接,炭化装置6的出料口与吸附剂产品仓8的进料口连接;The discharge port of the sludge bin 1 is connected with the feed port of the first stage of the hydrocyclone 2-1, and the underflow outlet of the first stage of the hydrocyclone 2-1 is connected with the feed port of the first filter press 4-1 ; The overflow outlet of the first filter press 4-1 is connected with the feed port of the
所述一段水力旋流器2-1的溢流出口与二段水力旋流器2-2的进料口连接,二段水力旋流器2-2的溢流出口与热解反应器5的进料口连接,二段水力旋流器2-2的底流出口与生物反应池3的进料口连接,生物反应池3的出料口和热解反应器5的出料口均与第二压滤机4-2的进料口连接;第二压滤机4-2的滤液出口与浓缩池7的进料口连接,浓缩池7的出料口与调理池13的进料口连接,调理池13的液体出口与水力旋流器2相连,使液体返回水力旋流器2循环利用,调理池13的固体出口与金属泥处理仓12的进料口连接;The overflow outlet of the first-stage hydrocyclone 2-1 is connected with the feed port of the second-stage hydrocyclone 2-2, and the overflow outlet of the second-stage hydrocyclone 2-2 is connected to the outlet of the
所述第二压滤机4-2的滤饼出口与肥料产品仓9,肥料产品仓9的菌种进料口与菌种罐10的出料口连接,肥料产品仓9的出料口与菌肥产品仓11的进料口连接。The filter cake outlet of the second filter press 4-2 is connected to the
一段水力旋流器和二段水力旋流器串联使用;一段水力旋流器的直径200-300mm,放置锥角20-30°;二段水力旋流器的直径50-150mm,放置锥角10-15°。The first-stage hydrocyclone and the second-stage hydrocyclone are used in series; the diameter of the first-stage hydrocyclone is 200-300mm, and the cone angle is 20-30°; the diameter of the second-stage hydrocyclone is 50-150mm, and the cone angle is 10° -15°.
实施例2Example 2
如图1所示,一种基于实施例1所述系统的污泥全组分综合利用方法,所述方法包括如下步骤:As shown in Figure 1, a method for comprehensive utilization of all components of sludge based on the system described in Example 1, the method includes the following steps:
1)污泥从污泥仓1泵入到一段水力旋流器2-1,经一段水力旋流器2-1分离后,重颗粒物质底流泵入到第一压滤机4-1,第一压滤机4-1的滤液通入浓缩池7,滤饼进入炭化装置6,炭化处理后作为吸附剂进入吸附剂产品仓8;1) The sludge is pumped from the sludge silo 1 to the first stage of the hydrocyclone 2-1. After being separated by the first stage of the hydrocyclone 2-1, the underflow of heavy particulate matter is pumped into the first filter press 4-1. The filtrate of a filter press 4-1 is passed into the
2)一段水力旋流器2-1溢流自流到二段水力旋流器2-2进行再处理,二段水力旋流器2-2分离的轻颗粒物质溢流进入热水解反应器5,加入添加剂进行热水解,热水解所得物质进入第二压滤机4-2过滤,滤液进入浓缩池7,浓缩后进入调理池13进行生物化学调理,液体返回旋流器2循环利用,固体物质进入金属泥处理仓12回收利用金属泥;第二压滤机4-2过滤的滤饼进入肥料产品仓9,加入菌种罐10的菌,得到的菌肥进入到菌肥产品仓11;2) The overflow of the first-stage hydrocyclone 2-1 flows to the second-stage hydrocyclone 2-2 for reprocessing, and the light particulate matter separated by the second-stage hydrocyclone 2-2 overflows into the
3)二段水力旋流器2-2分离的中颗粒物质底流进入生物反应池3并加入复合菌群进行反应处理,反应产物进入第二压滤机4-2过滤;滤液进入浓缩池7,浓缩后进入调理池13进行生物化学调理,液体返回旋流器2循环利用,固体物质进入金属泥处理仓12回收利用金属泥;第二压滤机4-2过滤的滤饼进入肥料产品仓9,加入菌种罐10的菌,得到的菌肥进入到菌肥产品仓11。3) The underflow of medium particulate matter separated by the second-stage hydrocyclone 2-2 enters the biological reaction tank 3 and adds compound bacteria to carry out reaction treatment, and the reaction product enters the second filter press 4-2 for filtration; the filtrate enters the
所述步骤1)中,炭化装置6中炭化温度为180℃-300℃,炭化时间为2h-4h。In the step 1), the carbonization temperature in the
所述步骤2)中,热水解反应器5的热水解温度为150℃-250℃,时间为2h-4h。In the step 2), the thermal hydrolysis temperature of the
所述步骤2)中,添加剂为铵盐。In the step 2), the additive is an ammonium salt.
所述步骤3)中,加入的复合菌群为嗜酸性氧化硫硫杆菌和嗜酸性氧化亚铁硫杆菌,复合菌群接种率为10%-20%。In the step 3), the added complex flora is Thiobacillus acidophilus thiooxidans and Thiobacillus acidophilus ferrooxidans, and the inoculation rate of the complex flora is 10%-20%.
步骤2)和3)中,根据不同污泥重金属种类的差异,通过调节温度、pH、电化学环境,或添加微生物加速其还原等不同方法使重金属形成金属化合物(络合物)或金属单质,形成金属泥进行回收。In steps 2) and 3), according to the difference of different types of heavy metals in different sludges, by adjusting temperature, pH, electrochemical environment, or adding microorganisms to accelerate their reduction, etc., the heavy metals are formed into metal compounds (complexes) or metal elements, Metal sludge is formed for recycling.
实施例3Example 3
取自北京某地区市政污泥,化学多元素分析如下:取自北京某地区市政污泥,化学多元素分析如下表:Taken from municipal sludge in a certain area of Beijing, chemical multi-element analysis is as follows: Taken from municipal sludge in a certain area of Beijing, chemical multi-element analysis is as follows:
所选市政污泥含水量高,pH为6.59,含水率90%,含有丰富的N、P、K及Cd、Cr、Cu、Pb和Zn等重金属。The selected municipal sludge has high water content, pH is 6.59, water content is 90%, and it is rich in heavy metals such as N, P, K and Cd, Cr, Cu, Pb and Zn.
基于实施例1的系统和实施例2的方法,称取一定质量污泥浆化,用泵打入水力旋流器中,分级得到35%重颗粒物质、35%中颗粒物质、30%轻颗粒物质。重颗粒物质过滤后180℃下炭化4h,炭化后固体加工为吸附剂,滤液通入浓缩池;将嗜酸性氧化硫硫杆菌和嗜酸性氧化亚铁硫杆菌以3:1的比例加入到中颗粒中进行复合菌群处理,过滤后滤液通入浓缩池,滤渣加入菌后续加工为菌肥;氯化铵作为添加剂加入到轻颗粒物质中,150℃热水解,过滤滤液通入浓缩池,滤渣加入菌制作菌肥;滤液在浓缩池浓缩后进行生物化学调理,通过调PH,微生物直接还原,得到Zn、Cu、Mg等金属化合物(络合物)和金属单质等沉淀。Based on the system of Example 1 and the method of Example 2, a certain mass of sludge was weighed and slurried, pumped into a hydrocyclone, and classified to obtain 35% heavy particulate matter, 35% medium particulate matter, and 30% light particulate matter. substance. After the heavy particulate matter was filtered, it was carbonized at 180 °C for 4 hours. After carbonization, the solid was processed into an adsorbent, and the filtrate was passed into the concentration tank; Thiobacillus acidophilus thiooxidans and Thiobacillus acidophilus ferrooxidans were added to the medium particles in a ratio of 3:1. After filtering, the filtrate is passed into the concentration tank, and the filter residue is added to the bacteria for subsequent processing into bacterial fertilizer; ammonium chloride is added as an additive to the light particulate matter, thermally hydrolyzed at 150 °C, the filtrate is passed into the concentration tank, and the filter residue Bacteria are added to make bacterial fertilizer; the filtrate is concentrated in the concentration tank and then subjected to biochemical conditioning, and by adjusting the pH, the microorganisms are directly reduced to obtain metal compounds (complexes) such as Zn, Cu, Mg, and metal elements and other precipitations.
实验中测得滤液中COD较低,有机质充分分解,最终得到的菌肥中有机质含量为30%,水分为20%,Cr含量为131mg/Kg,Cd含量为8.6mg/kg,符合生产复合菌肥的生产标准;测得脱除重金属的水中Zn含量为3.2mg/l,Cu含量为2.1mg/l,Pb含量为0.9mg/l,Cr含量为1.1mg/l,水中重金属含量低于国家标准,并且得到的重金属可以回收利用。In the experiment, the COD in the filtrate was low, and the organic matter was fully decomposed. The organic matter content in the final bacterial fertilizer was 30%, the moisture was 20%, the Cr content was 131 mg/Kg, and the Cd content was 8.6 mg/kg, which was in line with the production of compound bacteria. Fertilizer production standards; it is measured that the Zn content in the water removed from heavy metals is 3.2 mg/l, the Cu content is 2.1 mg/l, the Pb content is 0.9 mg/l, and the Cr content is 1.1 mg/l, and the heavy metal content in the water is lower than the national standard, and the resulting heavy metals can be recycled.
实施例4Example 4
取自某地区冶金钢铁混合污泥,化学多元素分析如下表:Taken from the metallurgical steel mixed sludge in a certain area, the chemical multi-element analysis is as follows:
所选工业污泥为冶金钢铁污泥,pH=6.32,含水率78%,Cu、Zn、Pb等重金属含量较高,不同于其他污泥,钢铁冶金混合污泥中Fe含量较高。The selected industrial sludge is metallurgical iron and steel sludge, with pH=6.32, moisture content of 78%, and high content of heavy metals such as Cu, Zn, and Pb. Different from other sludges, iron and steel metallurgical mixed sludge has high Fe content.
基于实施例1的系统和实施例2的方法,称取一定量的污泥,加入一定比例的水浆化处理后,用泵打入水力旋流器中,分级得到25%重颗粒物质、35%中颗粒物质、40%轻颗粒物质。重颗粒物质过滤后200℃下炭化3.5h,炭化后固体加工为吸附剂,滤液通入浓缩池;将嗜酸性氧化硫硫杆菌和嗜酸性氧化亚铁硫杆菌以4:1的比例加到中颗粒产物中进行复合菌群处理,过滤后滤液通入浓缩池,滤渣加入菌剂后续加工为菌肥;氯化铵作为添加剂加入到轻颗粒物质产物中,200℃热水解,过滤后滤液通入浓缩池,滤渣加入菌剂制作菌肥;滤液在浓缩池浓缩后进行生物化学调理,通过调PH、生物化学调理的方法,得到Zn、Cu、PB等金属化合物(络合物)和金属单质等沉淀。Based on the system of Example 1 and the method of Example 2, a certain amount of sludge was weighed, and after adding a certain proportion of water for slurry treatment, it was pumped into a hydrocyclone, and graded to obtain 25% heavy particulate matter, 35% % Medium Particulate Matter, 40% Light Particulate Matter. After the heavy particulate matter was filtered, it was carbonized at 200 °C for 3.5 hours. After carbonization, the solid was processed into an adsorbent, and the filtrate was passed into the concentration tank; The granular product is treated with compound bacteria. After filtration, the filtrate is passed into the concentration tank, and the filter residue is added to the bacterial agent for subsequent processing into bacterial fertilizer; ammonium chloride is added as an additive to the light particulate matter product, thermally hydrolyzed at 200 °C, and the filtrate is filtered after passing through. Into the concentration tank, the filter residue is added with bacterial agent to make bacterial fertilizer; after the filtrate is concentrated in the concentration tank, biochemical conditioning is carried out, and metal compounds (complexes) and metal elements such as Zn, Cu, PB, etc. are obtained by adjusting pH and biochemical conditioning. Wait for precipitation.
实验中所得菌肥有机质含量为27%,水分21%,cfu为0.52亿/g,P80mg/kg,符合复合菌肥国家标准;吸附剂经过吸附性能试验复合行业标准;金属泥中铁的回收率为75%,Zn含量为2.9mg/l,Cu含量为1.9mg/l,Pb含量为0.75mg/l,As含量为0.4%,废水可充分利用或排放,金属回收利用。In the experiment, the organic matter content of the obtained bacterial fertilizer was 27%, the moisture content was 21%, the cfu was 0.52 billion/g, and P80 mg/kg, which was in line with the national standard for compound bacterial fertilizer; the adsorbent was tested for adsorption performance and compounded the industry standard; the recovery rate of iron in the metal mud was 75%, Zn content is 2.9mg/l, Cu content is 1.9mg/l, Pb content is 0.75mg/l, As content is 0.4%, wastewater can be fully utilized or discharged, and metals are recycled.
实施例5Example 5
取自某地区电镀污泥,化学多元素分析如下表:Taken from electroplating sludge in a certain area, the chemical multi-element analysis is as follows:
所选工业污泥为电镀污泥,pH=7.99,含水率80%,Cd和Pb含量较低,Zn、Cu、Cr含量远超国家标准值,N、P、K、S等营养元素含量较低。The selected industrial sludge is electroplating sludge, pH=7.99, moisture content 80%, low Cd and Pb content, Zn, Cu, Cr content far exceeding the national standard value, N, P, K, S and other nutrient elements content are relatively low. Low.
基于实施例1的系统和实施例2的方法,称取一定量的污泥,加入一定比例的水浆化处理后,用泵打入水力旋流器中,分级得到15%重颗粒物质、45%中颗粒物质、40%轻颗粒物质。重颗粒物质过滤后250℃下炭化3h,炭化后固体加工为吸附剂,滤液通入浓缩池;将嗜酸性氧化硫硫杆菌和嗜酸性氧化亚铁硫杆菌以4:1的比例加到中颗粒产物中进行复合菌群处理,过滤后滤液通入浓缩池,滤渣加入菌剂后续加工为菌肥;氯化铵作为添加剂加入到轻颗粒物质产物中,250℃热水解,过滤后滤液通入浓缩池,滤渣加入菌剂制作菌肥;滤液在浓缩池浓缩后进行生物化学调理,通过调PH、生物化学调理,得到Zn、Cu、Cr、Sn等金属化合物(络合物)和金属单质等沉淀。Based on the system of Example 1 and the method of Example 2, a certain amount of sludge was weighed, and after adding a certain proportion of water for slurry treatment, it was pumped into a hydrocyclone, and classified to obtain 15% heavy particulate matter, 45% % Medium Particulate Matter, 40% Light Particulate Matter. After the heavy particulate matter was filtered, it was carbonized at 250 °C for 3 hours. After carbonization, the solid was processed into an adsorbent, and the filtrate was passed into the concentration tank; Thiobacillus acidophilus thiooxidans and Thiobacillus acidophilus ferrooxidans were added to the medium particles in a ratio of 4:1. The product is treated with complex flora, and the filtrate is passed into the concentration tank after filtration, and the filter residue is added to the bacterial agent for subsequent processing into bacterial fertilizer; ammonium chloride is added as an additive to the light particulate matter product, thermally hydrolyzed at 250 °C, and filtered and passed into the filtrate. In the concentration tank, the filter residue is added with bacterial agent to make bacterial fertilizer; after the filtrate is concentrated in the concentration tank, biochemical conditioning is carried out. Through pH adjustment and biochemical conditioning, metal compounds (complexes) such as Zn, Cu, Cr, Sn, and other metal elements are obtained. precipitation.
电镀污泥中有机质含量较低,经过复合菌群处理后,滤液中COD小,所得菌肥有机质含量为25.2%,水分20.5%,cfu为0.48亿/g,Cr含量为120mg/kg;所得金属泥Al的回收率为75%,分离后可加工利用,回收再利用;污泥中含量较高的Cu经处理后含量为2.6%,CR含量为1.3%,符合国家标准。The content of organic matter in the electroplating sludge is relatively low. After the treatment of compound bacteria, the COD in the filtrate is small. The organic matter content of the obtained bacterial fertilizer is 25.2%, the moisture content is 20.5%, the cfu is 0.48 billion/g, and the Cr content is 120 mg/kg; the obtained metal The recovery rate of Al in the sludge is 75%, which can be processed and reused after separation; the Cu content with higher content in the sludge is 2.6% after treatment, and the content of CR is 1.3%, which is in line with the national standard.
实施例6Example 6
取自某地区化工污泥,化工废水处理后污泥含水率同样较高,在70%~98%不等甚至更高,在未脱水前通常呈流体状或胶状,其颗粒较细,比重接近1。污泥成分复杂,化工污泥中含有病原微生物、细菌、合成有机物和重金属离子等大量毒害物质。通常其固体成分主要为有机残片、微生物菌体、无机颗粒和胶体等。Taken from chemical sludge in a certain area, the water content of sludge after chemical wastewater treatment is also high, ranging from 70% to 98% or even higher. Before dehydration, it is usually fluid or gelatinous, with fine particles and specific gravity close to 1. The sludge composition is complex, and chemical sludge contains a large number of toxic substances such as pathogenic microorganisms, bacteria, synthetic organic matter and heavy metal ions. Usually its solid components are mainly organic debris, microbial cells, inorganic particles and colloids.
基于实施例1的系统和实施例2的方法,称取一定量的污泥,加入一定比例的水浆化处理后,用泵打入水力旋流器中,分级得到25%重颗粒物质、50%中颗粒物质、25%轻颗粒物质。重颗粒物质过滤后300℃下炭化2h,炭化后固体加工为吸附剂,滤液通入浓缩池;将嗜酸性氧化硫硫杆菌和嗜酸性氧化亚铁硫杆菌以2:1的比例加到中颗粒产物中进行复合菌群处理,过滤后滤液通入浓缩池,滤渣加入菌剂后续加工为菌肥;氯化铵作为添加剂加入到轻颗粒物质产物中,200℃热水解,过滤后滤液通入浓缩池,滤渣加入菌剂制作菌肥;滤液在浓缩池浓缩后进行生物化学调理,通过调PH、生物化学调理的方法,得到重金属化合物(络合物)和金属单质等沉淀。Based on the system of Example 1 and the method of Example 2, a certain amount of sludge was weighed, and after adding a certain proportion of water for slurry treatment, it was pumped into a hydrocyclone, and graded to obtain 25% heavy particulate matter, 50 % Medium Particulate Matter, 25% Light Particulate Matter. After the heavy particulate matter was filtered, it was carbonized at 300 °C for 2 hours. After carbonization, the solid was processed into an adsorbent, and the filtrate was passed into the concentration tank; Thiobacillus acidophilus thiooxidans and Thiobacillus acidophilus ferrooxidans were added to the medium particles in a ratio of 2:1. The product is treated with compound bacteria, the filtrate is passed into the concentration tank after filtration, and the filter residue is added to the bacterial agent for subsequent processing into bacterial fertilizer; ammonium chloride is added as an additive to the light particulate matter product, thermally hydrolyzed at 200 °C, and filtered and passed into the filtrate. In the concentration tank, the filter residue is added with bacterial agent to make bacterial fertilizer; after the filtrate is concentrated in the concentration tank, biochemical conditioning is carried out.
实验中复合菌群处理中颗粒后,污泥中有机合成物含量降低,被分解为可利用的有机小分子,菌肥有机质含量为26.7%,水分21.3%,cfu为0.52亿/g;化工污泥的重金属离子得到富集回收。In the experiment, the content of organic compounds in the sludge was reduced after the compound bacterial flora treated the particles, and was decomposed into small organic molecules that could be used. The heavy metal ions in the mud are enriched and recovered.
最后所应说明的是,以上实施例仅用以说明本发明的技术方案而非限制。尽管参照实施例对本发明进行了详细说明,本领域的普通技术人员应该理解,对本发明的技术方案进行修改或者等同替换,都不脱离本发明技术方案的精神和范围,其均应涵盖在本发明的权利要求范围当中。Finally, it should be noted that the above embodiments are only used to illustrate the technical solutions of the present invention and not to limit them. Although the present invention has been described in detail with reference to the embodiments, those of ordinary skill in the art should understand that any modification or equivalent replacement of the technical solutions of the present invention will not depart from the spirit and scope of the technical solutions of the present invention, and should be included in the present invention. within the scope of the claims.
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Citations (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA2420064A1 (en) * | 2000-08-22 | 2002-02-28 | Green Farm Energy A/S | Concept for slurry separation and biogas production |
US7179379B2 (en) * | 2003-03-28 | 2007-02-20 | Ab-Cwt, Llc | Apparatus for separating particulates from a suspension, and uses thereof |
WO2012158013A1 (en) * | 2011-05-13 | 2012-11-22 | Ronser Bio-Tech Sdn Bhd | Anaerobic treatment of organic wastewater |
CN103304112A (en) * | 2012-03-13 | 2013-09-18 | 侯向明 | Treatment technology and complete set of equipment for clean production of oil sludge |
CN103396815A (en) * | 2013-08-05 | 2013-11-20 | 中国科学院城市环境研究所 | Method for preparing carbon materials by use of sludge |
CN104271535A (en) * | 2012-02-03 | 2015-01-07 | 优尼缇化肥有限责任公司 | System and method for conversion and treatment of organic sludge for production of multi-nutrient single-adsorption granular high-efficiency fertilizer |
CN105000783A (en) * | 2015-07-31 | 2015-10-28 | 三川德青科技有限公司 | Pipe duct sludge reduction and innocent treatment technology and device |
CN105645702A (en) * | 2014-11-12 | 2016-06-08 | 北京精诚博桑科技有限公司 | Low water consumption sludge treatment system and method |
CN105792856A (en) * | 2013-11-04 | 2016-07-20 | Sgc顾问有限责任公司 | Thermal treatment system and method for efficient processing of organic material |
CN106467352A (en) * | 2015-08-14 | 2017-03-01 | 北京中科国通环保工程技术有限公司 | A kind of for the foul smell resource reutilization of sludge organism drying technique with the method for deodorization |
CN106746477A (en) * | 2016-12-13 | 2017-05-31 | 北京城市排水集团有限责任公司 | A kind of urban wastewater treatment firm Treatment of Sludge and resource utilization method |
CN107265800A (en) * | 2017-07-03 | 2017-10-20 | 江门市三清环境技术工程有限公司 | A kind of river and lake silt innocuity disposal system and method |
-
2018
- 2018-05-17 CN CN201810471901.7A patent/CN108793653B/en not_active Expired - Fee Related
Patent Citations (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA2420064A1 (en) * | 2000-08-22 | 2002-02-28 | Green Farm Energy A/S | Concept for slurry separation and biogas production |
US7179379B2 (en) * | 2003-03-28 | 2007-02-20 | Ab-Cwt, Llc | Apparatus for separating particulates from a suspension, and uses thereof |
WO2012158013A1 (en) * | 2011-05-13 | 2012-11-22 | Ronser Bio-Tech Sdn Bhd | Anaerobic treatment of organic wastewater |
CN104271535A (en) * | 2012-02-03 | 2015-01-07 | 优尼缇化肥有限责任公司 | System and method for conversion and treatment of organic sludge for production of multi-nutrient single-adsorption granular high-efficiency fertilizer |
CN103304112A (en) * | 2012-03-13 | 2013-09-18 | 侯向明 | Treatment technology and complete set of equipment for clean production of oil sludge |
CN103396815A (en) * | 2013-08-05 | 2013-11-20 | 中国科学院城市环境研究所 | Method for preparing carbon materials by use of sludge |
CN105792856A (en) * | 2013-11-04 | 2016-07-20 | Sgc顾问有限责任公司 | Thermal treatment system and method for efficient processing of organic material |
CN105645702A (en) * | 2014-11-12 | 2016-06-08 | 北京精诚博桑科技有限公司 | Low water consumption sludge treatment system and method |
CN105000783A (en) * | 2015-07-31 | 2015-10-28 | 三川德青科技有限公司 | Pipe duct sludge reduction and innocent treatment technology and device |
CN106467352A (en) * | 2015-08-14 | 2017-03-01 | 北京中科国通环保工程技术有限公司 | A kind of for the foul smell resource reutilization of sludge organism drying technique with the method for deodorization |
CN106746477A (en) * | 2016-12-13 | 2017-05-31 | 北京城市排水集团有限责任公司 | A kind of urban wastewater treatment firm Treatment of Sludge and resource utilization method |
CN107265800A (en) * | 2017-07-03 | 2017-10-20 | 江门市三清环境技术工程有限公司 | A kind of river and lake silt innocuity disposal system and method |
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