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CN108793061B - A kind of preparation method of all-electrode relief structure CMUT device - Google Patents

A kind of preparation method of all-electrode relief structure CMUT device Download PDF

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CN108793061B
CN108793061B CN201810515043.1A CN201810515043A CN108793061B CN 108793061 B CN108793061 B CN 108793061B CN 201810515043 A CN201810515043 A CN 201810515043A CN 108793061 B CN108793061 B CN 108793061B
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余远昱
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Abstract

本发明涉及电子科学与技术的技术领域,更具体地,涉及一种全电极凸纹结构CMUT器件的制备方法,将高浓度掺杂的硅晶圆作为基底,使用表面微加工技术和电镀工艺,依次在基底上制备绝缘层、空腔、振动薄膜、凸纹结构的圆环,全覆盖于振动薄膜的顶电极、底电极极板及导线,完成全电极凸纹结构CMUT器件的制备。本发明制备的全电极凸纹结构CMUT器件,在塌陷工作模式下能有效提升输出声压从而达到增加超声波发射功率的效果;该制备方法技术成熟,适合大批量制造。该发明可用于生物医学检测、工业无损探伤等使用超声检测领域中超声换能器的加工制造,并将推进基于CMUT器件的超声探头技术的发展与应用,具备广阔的市场应用前景。

Figure 201810515043

The present invention relates to the technical field of electronic science and technology, and more particularly, to a method for preparing a CMUT device with an all-electrode relief structure. An insulating layer, a cavity, a vibrating film, and a ring of relief structure are sequentially prepared on the substrate, and the top electrode, bottom electrode plate and wires of the vibrating film are fully covered to complete the preparation of a CMUT device with an all-electrode relief structure. The all-electrode embossed structure CMUT device prepared by the invention can effectively increase the output sound pressure in the collapse working mode to achieve the effect of increasing the ultrasonic transmission power; the preparation method has mature technology and is suitable for mass production. The invention can be used for the processing and manufacture of ultrasonic transducers in the fields of ultrasonic testing such as biomedical testing and industrial non-destructive testing, and will promote the development and application of ultrasonic probe technology based on CMUT devices, and has broad market application prospects.

Figure 201810515043

Description

一种全电极凸纹结构CMUT器件的制备方法A kind of preparation method of all-electrode relief structure CMUT device

技术领域technical field

本发明涉及电子科学与技术的技术领域,更具体地,涉及一种全电极凸纹结构CMUT器件的制备方法。The present invention relates to the technical field of electronic science and technology, and more particularly, to a preparation method of a CMUT device with an all-electrode relief structure.

背景技术Background technique

在生物医学成像中,既需要有较高的图像分辨率,也对成像的实时性有较高要求。此外,还要求设备辐射小,以减少对生物组织的损害。超声波是一种机械振动波,可以在空气、液体、固体以及生物组织内传播,与X光、CT、核磁检测技术相比,没有电离辐射性,更适合用于生物组织的成像。超声波检测技术是基于回波原理实现的,成像速度快且图像分辨率可达几十微米的数量级,足以满足生物医学检测的需求。所以,超声波检测技术已经成为生物医学成像领域内的主流技术。超声波检测技术除在生物医学成像中广泛使用之外,在工业无损检测行业中也普遍应用。In biomedical imaging, both high image resolution and real-time imaging are required. In addition, the equipment is also required to have low radiation to reduce damage to biological tissues. Ultrasound is a mechanical vibration wave that can propagate in air, liquid, solid and biological tissue. Compared with X-ray, CT and nuclear magnetic detection technology, it has no ionizing radiation and is more suitable for imaging of biological tissue. Ultrasonic detection technology is based on the echo principle, and the imaging speed is fast and the image resolution can reach the order of tens of microns, which is enough to meet the needs of biomedical detection. Therefore, ultrasonic detection technology has become the mainstream technology in the field of biomedical imaging. In addition to being widely used in biomedical imaging, ultrasonic testing technology is also widely used in the industrial non-destructive testing industry.

超声换能器是超声检测技术的关键部件,实现了电能量和超声能量之间相互的转化。在目前所使用的超声换能器中,压电式超声换能器被广泛使用,常见的压电材料为压电陶瓷。传统的压电式超声换能器声阻抗高,导致制造超声探头工艺复杂,而且带宽较小。此外,压电材料也无法和电路集成,不适合制造高集成度的超声探头。使用微机电系统(MEMS)工艺加工制造的电容式微机械超声换能器(CMUT),其声阻抗较低且可以调节,因此制造超声探头的时候不需要添加阻抗匹配层,不仅减少了探头制造的难度,也提升了带宽。CMUT器件制造工艺与CMOS集成电路的工艺相兼容,且使用光刻蚀技术,因此CMUT适合于制造高集成度、大规模阵列的超声探头,可以满足临床医学领域中对信息获取日益增长的需求。鉴于以上优点,CMUT已被视为下一代超声换能器。Ultrasonic transducer is the key component of ultrasonic testing technology, which realizes the mutual conversion between electric energy and ultrasonic energy. Among the ultrasonic transducers currently used, piezoelectric ultrasonic transducers are widely used, and a common piezoelectric material is piezoelectric ceramics. The traditional piezoelectric ultrasonic transducer has high acoustic impedance, which leads to complicated manufacturing process of ultrasonic probe and small bandwidth. In addition, piezoelectric materials cannot be integrated with circuits, and are not suitable for manufacturing high-integration ultrasound probes. Capacitive micromachined ultrasonic transducers (CMUTs) manufactured by microelectromechanical systems (MEMS) technology have low acoustic impedance and can be adjusted, so there is no need to add an impedance matching layer when manufacturing ultrasonic probes, which not only reduces the cost of probe manufacturing. The difficulty also increases the bandwidth. The CMUT device manufacturing process is compatible with the process of CMOS integrated circuits and uses photolithography technology. Therefore, CMUT is suitable for manufacturing high-integration, large-scale array ultrasound probes, which can meet the growing demand for information acquisition in the field of clinical medicine. In view of the above advantages, CMUT has been regarded as the next-generation ultrasonic transducer.

但是相比压电陶瓷超声换能器,现有CMUT的输出声压仍比较小。超声波在人体组织内传输的衰减系数较大,经过长距离的传输,信号的幅度会明显减弱。超声检测技术是基于超声探头所接收的反射回波实现目标的定位。较小的输出声压,使得微弱的回波信号容易受到外界噪声的干扰,降低了回波信号的信噪比,从而影响成像的品质。所以,提升CMTU的输出声压,是目前CMUT技术发展亟待解决的问题之一。However, compared with the piezoelectric ceramic ultrasonic transducer, the output sound pressure of the existing CMUT is still relatively small. The attenuation coefficient of ultrasonic transmission in human tissue is large, and the amplitude of the signal will be significantly weakened after long-distance transmission. Ultrasonic detection technology is based on the reflected echo received by the ultrasonic probe to achieve target positioning. The small output sound pressure makes the weak echo signal easily interfered by external noise, which reduces the signal-to-noise ratio of the echo signal, thereby affecting the imaging quality. Therefore, improving the output sound pressure of the CMTU is one of the problems to be solved urgently in the current development of the CMUT technology.

目前提升CMUT输出声压的途径可以分为两类,一类为修改CMUT的工作模式,使其工作在塌陷模式下;另一类为修改CMUT的振动薄膜的结构。发明人提出了一种综合以上两类途径的具有全电极凸纹结构的CUMT器件的制备方法。At present, there are two ways to improve the output sound pressure of a CMUT. One is to modify the working mode of the CMUT to make it work in the collapsed mode; the other is to modify the structure of the vibrating membrane of the CMUT. The inventor proposes a preparation method of a CUMT device with an all-electrode relief structure that integrates the above two approaches.

发明内容SUMMARY OF THE INVENTION

本发明为克服上述现有技术所述的至少一种缺陷,提供一种全电极凸纹结构CMUT器件的制备方法,实现了CMUT可与电路集成,易于制造大规模阵列,适合大批量生产的优点。In order to overcome at least one of the above-mentioned defects in the prior art, the present invention provides a method for preparing a CMUT device with an all-electrode relief structure, which realizes the advantages that the CMUT can be integrated with circuits, is easy to manufacture large-scale arrays, and is suitable for mass production. .

为解决上述技术问题,本发明的技术方案如下:For solving the above-mentioned technical problems, the technical scheme of the present invention is as follows:

一种全电极凸纹结构CMUT器件的制备方法,所述的制备方法包括以下步骤:A preparation method of an all-electrode relief structure CMUT device, the preparation method comprises the following steps:

步骤1:使用高浓度掺杂的硅晶圆作为基底制备基底层;Step 1: Use a highly doped silicon wafer as a substrate to prepare a base layer;

步骤2:在步骤1中基底上沉积制备绝缘层;Step 2: depositing an insulating layer on the substrate in step 1;

步骤3:在步骤2中的绝缘层上沉积多晶硅薄膜制备牺牲层,并去除多余的多晶硅薄膜层;Step 3: deposit a polysilicon film on the insulating layer in step 2 to prepare a sacrificial layer, and remove the redundant polysilicon film layer;

步骤4:在步骤3制备的CMUT单元上沉积振动薄膜;Step 4: deposit a vibrating film on the CMUT unit prepared in step 3;

步骤5:进一步去除步骤3中保留的多晶硅薄膜层形成封闭的空腔;Step 5: further removing the polysilicon film layer retained in step 3 to form a closed cavity;

步骤6:沉积用于制备CMUT单元顶电极和底电极极板的导电层;Step 6: depositing conductive layers for preparing the top and bottom electrode plates of the CMUT unit;

步骤7:在振动薄膜顶部的导电层上制备凸纹圆环;Step 7: Prepare a relief ring on the conductive layer on top of the vibrating membrane;

步骤8:使用光刻蚀工艺定义导电层制备全覆盖于振动薄膜的顶电极、底电极极板及导线,并去除多余导电层;完成全电极凸纹结构CMUT器件的制备。Step 8: Use the photolithography process to define the conductive layer to prepare the top electrode, the bottom electrode plate and the wires that fully cover the vibrating film, and remove the redundant conductive layer; complete the preparation of the all-electrode relief structure CMUT device.

优选地,所述步骤7具体包括以下步骤:Preferably, the step 7 specifically includes the following steps:

步骤71:在振动薄膜顶部的导电层上使用正光阻并结合光刻蚀工艺定义所述凸纹圆环的尺寸;Step 71: define the size of the relief ring by using a positive photoresist on the conductive layer on top of the vibrating film and combining with a photolithography process;

步骤72:在步骤71定义凸纹圆环的尺寸区域使用电镀工艺制备凸纹圆环。Step 72: Define the size area of the relief ring at step 71 to prepare the relief ring using an electroplating process.

所述步骤71中凸纹圆环的高度及宽度由所述正光阻经显影后的高度和宽度决定,所述凸纹圆环的高度为0.5~6μm,宽度为0.5~3μm;所述步骤72中凸纹圆环为金属镍或其他高密度的金属。In the step 71, the height and width of the relief ring are determined by the height and width of the positive photoresist after development, and the height of the relief ring is 0.5-6 μm and the width is 0.5-3 μm; the step 72 The ribbed ring is nickel metal or other high-density metal.

优选地,所述步骤4中振动薄膜为低残余应力氮化硅薄膜,厚度为0.3~2μm;步骤4还包括与所述振动薄膜一体沉积的支撑层。Preferably, in the step 4, the vibrating film is a low residual stress silicon nitride film with a thickness of 0.3-2 μm; and the step 4 further includes a support layer integrally deposited with the vibrating film.

优选地,所述的步骤5具体包括以下步骤:Preferably, the step 5 specifically includes the following steps:

步骤51:使用干法刻蚀工艺在保留的多晶硅薄膜层上方的刻蚀通道上刻蚀腐蚀孔,再使用湿法刻蚀工艺通过腐蚀孔去除保留的多晶硅薄膜层,形成空腔;Step 51 : using a dry etching process to etch an etching hole on the etching channel above the remaining polysilicon film layer, and then using a wet etching process to remove the remaining polysilicon film layer through the etching hole to form a cavity;

步骤52:使用等离子体增强化学气相沉积法(PECVD)沉积氮化硅层,填充步骤51中的腐蚀孔;Step 52: use plasma enhanced chemical vapor deposition (PECVD) to deposit a silicon nitride layer to fill the etched holes in step 51;

步骤53:使用干法蚀刻工艺,蚀刻步骤52中填充腐蚀孔后的氮化硅层,将振动薄膜厚度减至所述步骤4的薄膜厚度。Step 53 : use a dry etching process to etch the silicon nitride layer filled with the etched holes in step 52 , and reduce the thickness of the vibrating film to the film thickness of step 4 .

优选地,所述步骤51中湿法刻蚀工艺的刻蚀剂为氢氧化钾溶液。Preferably, the etchant used in the wet etching process in step 51 is potassium hydroxide solution.

优选地,所述步骤2中的绝缘层为使用低压力化学气相沉积(LPCVD)工艺沉积的单层氮化硅一种材料或者使用干式氧化工艺及低压力化学气相沉积(LPCVD)工艺沉积的二氧化硅与氮化硅两种材料的复合层构成。Preferably, the insulating layer in the step 2 is a single-layer silicon nitride material deposited by a low pressure chemical vapor deposition (LPCVD) process or a material deposited by a dry oxidation process and a low pressure chemical vapor deposition (LPCVD) process. It is composed of a composite layer of silicon dioxide and silicon nitride.

优选地,所述步骤6具体包括以下步骤:Preferably, the step 6 specifically includes the following steps:

步骤61:使用干法蚀刻工艺,去掉基底一端的覆盖层,暴露出基底;Step 61: use a dry etching process to remove the cover layer at one end of the substrate to expose the substrate;

步骤62:使用电子束蒸镀(E-beam evaporation)工艺在步骤61的单元上沉积导电层。Step 62: Deposit a conductive layer on the cell of Step 61 using an E-beam evaporation process.

优选地,所述步骤62中的导电层为铬、金复合结构。Preferably, the conductive layer in the step 62 is a composite structure of chromium and gold.

所述的全电极凸纹结构CMUT器件工作在塌陷模式时,所述振动薄膜的中心部分在静电力作用下发生塌陷,贴合在基底上的绝缘层表面,形成塌陷薄膜部分;未塌陷部分的薄膜为CMUT器件工作时的振动薄膜部分。凸纹结构位于振动薄膜部分上方。When the all-electrode relief structure CMUT device works in the collapsed mode, the central part of the vibrating membrane collapses under the action of electrostatic force, and is attached to the surface of the insulating layer on the substrate to form a collapsed membrane part; The thin film is the part of the vibrating thin film when the CMUT device works. The relief structure is located above the vibrating membrane portion.

与现有技术相比,有益效果是:Compared with the prior art, the beneficial effects are:

(1)本发明使用表面微加工技术,和现有的CMUT制备工艺相兼容,实现了CMUT可与电路集成,易于制造大规模阵列,适合大批量生产的优点;(1) The present invention uses surface micromachining technology, which is compatible with the existing CMUT preparation process, and realizes the advantages that CMUT can be integrated with circuits, is easy to manufacture large-scale arrays, and is suitable for mass production;

(2)本发明使用表面微加工技术实现了凸纹结构CMUT器件的制备。使用了镍或者其他高密度的金属作为凸纹圆环的材料;较大密度材料的凸纹圆环,可以有效减少圆环尺寸对振动薄膜的影响;(2) The present invention realizes the preparation of the relief structure CMUT device by using the surface micromachining technology. Nickel or other high-density metal is used as the material of the relief ring; the relief ring of larger density material can effectively reduce the influence of the ring size on the vibrating membrane;

(3)使用了正光阻及光刻蚀技术,可以精确控制凸纹圆环的尺寸;结合电镀工艺制备凸纹圆环,电镀工艺适合制备高度较大的圆环;而使用传统电子束蒸镀(E-beamevaporation)、热蒸镀(Thermal evaporation)、磁控溅射(Sputtering)等金属薄膜沉积工艺沉积高度超过1μm的金属层,不仅耗时久,而且费用也很昂贵;(3) The use of positive photoresist and photolithography technology can accurately control the size of the relief ring; the relief ring is prepared by combining with the electroplating process, and the electroplating process is suitable for the preparation of rings with a large height; while using traditional electron beam evaporation (E-beamevaporation), thermal evaporation (thermal evaporation), magnetron sputtering (Sputtering) and other metal film deposition processes to deposit metal layers with a height of more than 1μm, not only time-consuming, but also very expensive;

(4)制备全覆盖于振动薄膜的顶电极结构,全覆盖顶电极保证凸纹结构下方结构(薄膜和顶电极)的密度均匀性,提高了将振动薄膜部分的振动中心调节至凸纹结构位置的准确性;(4) Prepare a top electrode structure that fully covers the vibrating membrane. The full coverage of the top electrode ensures the density uniformity of the structure (membrane and top electrode) below the relief structure, and improves the adjustment of the vibration center of the vibrating membrane to the position of the relief structure. accuracy;

(5)相比现有CMUT器件,工作在塌陷模式下的具有全电极凸纹结构CMUT,可以明显提升有效输出声压;该发明解决了现有CMUT输出声压较低的问题,将推进基于CMUT的超声探头技术的发展与应用。(5) Compared with the existing CMUT devices, the CMUT with all-electrode relief structure working in the collapsed mode can significantly improve the effective output sound pressure; this invention solves the problem of low output sound pressure of the existing CMUT, and will promote the The development and application of ultrasonic probe technology of CMUT.

附图说明Description of drawings

图1是本发明塌陷工作状态结构示意图。FIG. 1 is a schematic structural diagram of the present invention in a collapsed working state.

图2 (a)~(m)是本发明制备工艺流程图。Fig. 2 (a)~(m) is the preparation process flow chart of the present invention.

具体实施方式Detailed ways

附图仅用于示例性说明,不能理解为对本专利的限制;为了更好说明本实施例,附图某些部件会有省略、放大或缩小,并不代表实际产品的尺寸;对于本领域技术人员来说,附图中某些公知结构及其说明可能省略是可以理解的。附图中描述位置关系仅用于示例性说明,不能理解为对本专利的限制。The accompanying drawings are for illustrative purposes only, and should not be construed as limitations on this patent; in order to better illustrate the present embodiment, some parts of the accompanying drawings may be omitted, enlarged or reduced, and do not represent the size of the actual product; for those skilled in the art It is understandable to the artisan that certain well-known structures and descriptions thereof may be omitted from the drawings. The positional relationships described in the drawings are only for exemplary illustration, and should not be construed as a limitation on the present patent.

如图2 (m)所示,本发明提供的制备方法制备一种全电极凸纹结构CMUT器件包括依次设置的凸纹结构、顶电极61、振动薄膜1、空腔2、绝缘层4和基底5,还包括支撑空腔2的支撑层3;在基底5的顶面一端设置有底电极极板62;所述的支撑层3内设置有空腔2,空腔2设置在振动薄膜1与绝缘层4之间;在所述振动薄膜1的顶部设置有全覆盖振动薄膜1的顶电极61;顶电极61的顶面还设置有凸纹结构;所述的凸纹结构为凸纹圆环7,其中心与所述的振动薄膜1以及空腔2的中心位于同一竖直线上,所述凸纹圆环7的底端连接于顶电极61的顶面。如图1所示,为所述全电极凸纹结构CMUT器件工作在塌陷模式的结构示意图,当工作在塌陷模式时,所述振动薄膜1的中心部分在静电力作用下产生塌陷,贴合在基底上的绝缘层4表面,成为塌陷薄膜部分11;未塌陷部分的振动薄膜1是CMUT器件工作时的振动薄膜部分12。通过调节工作中直流偏置电压,将振动薄膜部分12的振动中心移动到凸纹圆环7的位置,从而达到增大输出声压的效果。As shown in FIG. 2 (m), the preparation method provided by the present invention to prepare an all-electrode relief structure CMUT device includes a relief structure, a top electrode 61, a vibrating film 1, a cavity 2, an insulating layer 4 and a substrate arranged in sequence. 5, also includes a support layer 3 supporting the cavity 2; a bottom electrode plate 62 is provided at one end of the top surface of the base 5; the support layer 3 is provided with a cavity 2, and the cavity 2 is arranged between the vibrating membrane 1 and the Between the insulating layers 4; a top electrode 61 fully covering the vibrating film 1 is arranged on the top of the vibrating film 1; the top surface of the top electrode 61 is also provided with a relief structure; the relief structure is a relief ring 7. Its center is located on the same vertical line as the center of the vibrating membrane 1 and the cavity 2, and the bottom end of the relief ring 7 is connected to the top surface of the top electrode 61. As shown in FIG. 1, it is a schematic structural diagram of the all-electrode relief structure CMUT device working in the collapsed mode. When working in the collapsed mode, the central part of the vibrating membrane 1 collapses under the action of electrostatic force, and is attached to the The surface of the insulating layer 4 on the substrate becomes the collapsed membrane part 11 ; the vibration membrane 1 of the non-collapsed part is the vibration membrane part 12 when the CMUT device operates. By adjusting the DC bias voltage during operation, the vibration center of the vibrating membrane portion 12 is moved to the position of the relief ring 7, thereby achieving the effect of increasing the output sound pressure.

一种全电极凸纹结构CMUT器件的制备方法,具体包括以下步骤:A preparation method of an all-electrode relief structure CMUT device, specifically comprising the following steps:

步骤1:使用高浓度掺杂的硅晶圆作为基底5制备基底层;使用高浓度掺杂的硅晶圆(导电率:0.1-1 ohm-cm,厚度525 μm)作为基底5,上述基底5还可以作为CMUT单元的公共底电极;Step 1: Use a highly doped silicon wafer as the substrate 5 to prepare the base layer; use a highly doped silicon wafer (conductivity: 0.1-1 ohm-cm, thickness 525 μm) as the substrate 5, the above-mentioned substrate 5 It can also be used as the common bottom electrode of the CMUT unit;

步骤2:在步骤1中基底5上沉积制备绝缘层4;所述步骤2中的绝缘层4为使用低压力化学气相沉积(LPCVD)工艺沉积的单层氮化硅一种材料或者使用干式氧化工艺及低压力化学气相沉积(LPCVD)工艺沉积的二氧化硅与氮化硅两种材料的复合层构成;本实施例为二氧化硅与氮化硅两种材料的复合绝缘层;Step 2: In step 1, an insulating layer 4 is deposited on the substrate 5; the insulating layer 4 in step 2 is a single-layer silicon nitride material deposited by a low pressure chemical vapor deposition (LPCVD) process or a dry type It is composed of a composite layer of silicon dioxide and silicon nitride deposited by an oxidation process and a low pressure chemical vapor deposition (LPCVD) process; this embodiment is a composite insulating layer of silicon dioxide and silicon nitride;

步骤3:使用低压力化学气相沉积(LPCVD)工艺在步骤2中制备的绝缘层4上沉积多晶硅薄膜层作为牺牲层81,并去除多余的多晶硅薄膜层;多晶硅薄膜层的厚度决定了CMUT器件空腔2的厚度;Step 3: Use a low pressure chemical vapor deposition (LPCVD) process to deposit a polysilicon thin film layer as a sacrificial layer 81 on the insulating layer 4 prepared in step 2, and remove the excess polysilicon thin film layer; the thickness of the polysilicon thin film layer determines the CMUT device hollow the thickness of cavity 2;

步骤4:在步骤3的CMUT单元上沉积振动薄膜1;使用低压力化学气相沉积(LPCVD)工艺在所述步骤3的单元上沉积低残余应力的氮化硅薄膜层,所述步骤4中振动薄膜1厚度为0.3~2μm;步骤4还包括与所述振动薄膜1一体沉积的支撑层3;Step 4: Deposit vibrating film 1 on the CMUT unit of step 3; use a low pressure chemical vapor deposition (LPCVD) process to deposit a low residual stress silicon nitride film layer on the unit of step 3, vibrate in step 4 The thickness of the film 1 is 0.3-2 μm; step 4 further includes a support layer 3 integrally deposited with the vibration film 1 ;

步骤5:进一步去除步骤3中保留的多晶硅薄膜层8形成封闭的空腔2;Step 5: further remove the polysilicon thin film layer 8 retained in step 3 to form a closed cavity 2;

步骤6:沉积用于制备CMUT单元顶电极61和底电极极板62的导电层6;Step 6: depositing the conductive layer 6 for preparing the top electrode 61 and bottom electrode plate 62 of the CMUT unit;

步骤7:在振动薄膜1顶部的导电层6上制备凸纹圆环7;Step 7: prepare a relief ring 7 on the conductive layer 6 on top of the vibrating membrane 1;

步骤8:使用光刻蚀工艺定义导电层6制备全覆盖于振动薄膜1的顶电极61、底电极极板62及导线,并去除多余导电层;完成全电极凸纹结构CMUT器件的制备。所述的底电极可以由高浓度掺杂的基底5实现,也可以在绝缘层4靠近基底层5的一端使用金属层实现,本实施中底电极极板62为覆盖于基底5一端的金和铬的复合金属的导电层6。Step 8: Use the photolithography process to define the conductive layer 6 to prepare the top electrode 61, the bottom electrode plate 62 and the wires fully covering the vibration film 1, and remove the redundant conductive layer; complete the preparation of the all-electrode relief structure CMUT device. The bottom electrode can be realized by a high-concentration doped substrate 5, or a metal layer can be used at one end of the insulating layer 4 close to the substrate layer 5. In this embodiment, the bottom electrode plate 62 is a gold and metal layer covering one end of the substrate 5. Conductive layer 6 of chromium composite metal.

更近一步地,所述的步骤5具体包括以下步骤:Further, the described step 5 specifically includes the following steps:

步骤51:使用干法刻蚀工艺在保留的多晶硅薄膜层8上方的刻蚀通道上刻蚀腐蚀孔9,再使用湿法刻蚀工艺,氢氧化钾溶液通过腐蚀孔9去除保留的多晶硅薄膜层8,形成空腔2;Step 51: Use a dry etching process to etch the etching hole 9 on the etching channel above the remaining polysilicon film layer 8, and then use a wet etching process to remove the remaining polysilicon film layer through the etching hole 9 with a potassium hydroxide solution 8. Form cavity 2;

步骤52:使用等离子体增强化学气相沉积法(PECVD)沉积氮化硅层,填充步骤51中的腐蚀孔9;Step 52 : depositing a silicon nitride layer using plasma enhanced chemical vapor deposition (PECVD) to fill the etched hole 9 in step 51 ;

步骤53:使用干法蚀刻工艺,蚀刻步骤52中填充腐蚀孔9后的氮化硅层,将振动薄膜厚度减至所述步骤4的薄膜厚度。Step 53 : use a dry etching process to etch the silicon nitride layer after filling the etching hole 9 in step 52 , and reduce the thickness of the vibration film to the film thickness of step 4 .

更近一步地,所述步骤6具体包括以下步骤:Further, the step 6 specifically includes the following steps:

步骤61:使用干法蚀刻工艺,去掉基底5一端的覆盖层,暴露出基底5;Step 61: Using a dry etching process, remove the cover layer at one end of the substrate 5 to expose the substrate 5;

步骤62:使用电子束蒸镀(E-beam evaporation)工艺在步骤61的单元上沉积铬、金复合结构的导电层6。Step 62 : deposit the conductive layer 6 of the chromium, gold composite structure on the unit of step 61 using an E-beam evaporation process.

更近一步地,所述步骤7具体包括以下步骤:Further, the step 7 specifically includes the following steps:

步骤71:在振动薄膜1顶部的导电层6上使用正光阻并结合光刻蚀工艺定义所述凸纹圆环7的尺寸;所述凸纹圆环7的高度及宽度由所述正光阻经显影后的高度和宽度决定,所述凸纹圆环7的高度为0.5~6μm,宽度为0.5~3μm;Step 71: Use a positive photoresist on the conductive layer 6 on the top of the vibrating film 1 and combine the photolithography process to define the size of the relief ring 7; the height and width of the relief ring 7 are determined by the positive photoresist. The height and width after development are determined, and the height of the relief ring 7 is 0.5-6 μm and the width is 0.5-3 μm;

步骤72:在步骤71定义凸纹圆环7的尺寸区域使用电镀工艺制备凸纹圆环7,所述凸纹圆环7为金属镍或其他高密度的金属,本实施例为金属镍。Step 72 : Define the size area of the relief ring 7 in step 71 and use an electroplating process to prepare the relief ring 7 , the relief ring 7 is metal nickel or other high-density metal, and this embodiment is metal nickel.

本实施例中,如图2(a)~(m)所示,具体的实施步骤如下:In this embodiment, as shown in Figure 2 (a) ~ (m), the specific implementation steps are as follows:

步骤1:如图2 (a),使用高浓度掺杂的硅晶圆(导电率:0.1-1 ohm-cm,厚度525 μm)作为基底5;Step 1: As shown in Figure 2 (a), use a highly doped silicon wafer (conductivity: 0.1-1 ohm-cm, thickness 525 μm) as the substrate 5;

步骤2:对步骤1中硅晶圆基底5清洗后,将其放入氧化炉管中,使用干式氧化工艺在硅晶圆基底上沉积厚度为150 nm的二氧化硅41;之后,使用低压力化学气相沉积(LPCVD)工艺在上述的二氧化硅41上沉积150 nm的氮化硅42,如图2 (b),至此,制备了由二氧化硅41和氮化硅42复合而成的绝缘层4;Step 2: After cleaning the silicon wafer substrate 5 in step 1, put it into an oxidation furnace tube, and use a dry oxidation process to deposit silicon dioxide 41 with a thickness of 150 nm on the silicon wafer substrate; The pressure chemical vapor deposition (LPCVD) process deposits 150 nm silicon nitride 42 on the above-mentioned silicon dioxide 41, as shown in Figure 2 (b). So far, a composite of silicon dioxide 41 and silicon nitride 42 has been prepared. insulating layer 4;

步骤3:先使用低压力化学气相沉积(LPCVD)工艺在步骤2中制备的绝缘层4上沉积300 nm多晶硅薄膜层作为牺牲层81,多晶硅薄膜层的厚度决定了CMUT器件空腔2的厚度,如图2 (c)所示;然后使用光刻蚀工艺定义各CMUT单元的形状,包括腔体2和刻蚀通道等。本实施例中CMUT单元为圆形,半径为20 μm,刻蚀通道的宽度为2 μm,长度为12 μm。再使用干法刻蚀技术,将CMUT单元之外的多晶硅薄膜层蚀刻掉,保留下的区域即为CMUT单元轮廓,如图2 (d)所示,保留的多晶硅薄膜层8即为后续步骤的空腔2,在该步骤之后,需要将残余光阻去除;Step 3: First use a low pressure chemical vapor deposition (LPCVD) process to deposit a 300 nm polysilicon thin film layer as a sacrificial layer 81 on the insulating layer 4 prepared in step 2. The thickness of the polysilicon thin film layer determines the thickness of the cavity 2 of the CMUT device. As shown in Fig. 2 (c); the shape of each CMUT unit, including cavity 2 and etching channels, etc., is then defined using a photolithography process. In this embodiment, the CMUT unit is circular, the radius is 20 μm, the width of the etching channel is 2 μm, and the length is 12 μm. Then use dry etching technology to etch away the polysilicon film layer outside the CMUT unit, and the remaining area is the outline of the CMUT unit. Cavity 2, after this step, the residual photoresist needs to be removed;

步骤4:使用低压力化学气相沉积(LPCVD)工艺在所述步骤3的CMUT单元上沉积低残余应力的氮化硅薄膜层。其中沉积的氮化硅薄膜层位于保留的多晶硅薄膜层8顶面的部分作为CMUT单元的振动薄膜1,位于保留的多晶硅薄膜层8两侧的部分作为器件的支撑层3,用于支撑所述的空腔2;所述的支撑层3与所述的振动薄膜1是一体沉积,如图2 (e)所示。所述的振动薄膜1的厚度为0.3~2μm,本实施例中振动薄膜1的厚度为700 nm;Step 4: Use a low pressure chemical vapor deposition (LPCVD) process to deposit a low residual stress silicon nitride thin film layer on the CMUT unit of step 3. The part of the deposited silicon nitride film layer on the top surface of the remaining polysilicon film layer 8 is used as the vibration film 1 of the CMUT unit, and the parts on both sides of the remaining polysilicon film layer 8 are used as the supporting layer 3 of the device for supporting the The cavity 2; the support layer 3 and the vibration film 1 are integrally deposited, as shown in Figure 2 (e). The thickness of the vibration film 1 is 0.3-2 μm, and the thickness of the vibration film 1 in this embodiment is 700 nm;

步骤5:具体包括以下步骤:Step 5: Specifically include the following steps:

步骤51:首先使用光刻蚀技术,在CMUT单元步骤4中的氮化硅覆盖的刻蚀通道上定义腐蚀孔区域,腐蚀孔9的直径为2 μm;之后使用干法刻蚀技术,将腐蚀孔9区域内的氮化硅层蚀刻掉,使得腐蚀孔9直通到保留的多晶硅薄膜层8,如图2 (f)所示。此工艺完成后需要去除残余的光阻;Step 51: First, use the photolithography technology to define the etching hole area on the etching channel covered by the silicon nitride in step 4 of the CMUT unit, and the diameter of the etching hole 9 is 2 μm; The silicon nitride layer in the area of the hole 9 is etched away, so that the etched hole 9 leads directly to the remaining polysilicon thin film layer 8, as shown in FIG. 2(f). After this process is completed, the residual photoresist needs to be removed;

步骤52:将上述刻蚀腐蚀孔后的整片硅晶圆浸入氢氧化钾溶液中,在常温下进行湿法蚀刻保留的多晶硅薄膜层8,多晶硅经过腐蚀通道从腐蚀孔9中被彻底去除掉,从而在氮化硅的振动薄膜1之下形成了空腔2,空腔2的高度由保留的多晶硅薄膜层8的高度决定,在本实施例中是300 nm,如图2 (g)所示;使用等离子体增强化学的气相沉积法(PECVD)沉积厚度为1.2 μm的氮化硅,将腐蚀孔填充,从而形成了封闭的空腔2,如图2(h)所示;因为等离子体增强化学的气相沉积法(PECVD)炉管内气压很低,可认为空腔2是真空封闭的;Step 52: Immerse the whole silicon wafer after the above-mentioned etching and etching holes in the potassium hydroxide solution, perform wet etching at room temperature to retain the polysilicon thin film layer 8, and the polysilicon is completely removed from the etching holes 9 through the etching channel , so that a cavity 2 is formed under the vibration film 1 of silicon nitride, and the height of the cavity 2 is determined by the height of the polysilicon film layer 8 remaining, which is 300 nm in this embodiment, as shown in Fig. 2(g) The etched holes were filled with silicon nitride with a thickness of 1.2 μm deposited by plasma-enhanced chemical vapor deposition (PECVD), thereby forming a closed cavity 2, as shown in Fig. 2(h); because the plasma The gas pressure in the enhanced chemical vapor deposition (PECVD) furnace tube is very low, and it can be considered that the cavity 2 is vacuum closed;

步骤53:步骤52中填充腐蚀孔9之后使得CMUT器件的氮化硅振动薄膜加厚,故需要将薄膜的厚度减薄至700 nm。使用干法刻蚀工艺将步骤52中沉积在薄膜上的1.2 μm 的氮化硅层去除掉,减薄后的CMUT单元如图2(i)所示。完成该步骤工艺后,需要去除残留光阻;Step 53: After filling the etching hole 9 in step 52, the silicon nitride vibration film of the CMUT device is thickened, so the thickness of the film needs to be reduced to 700 nm. The 1.2 μm silicon nitride layer deposited on the thin film in step 52 is removed by a dry etching process, and the thinned CMUT unit is shown in FIG. 2(i). After completing this step process, the residual photoresist needs to be removed;

步骤6:具体包括以下步骤:Step 6: Specifically include the following steps:

步骤61:使用光刻蚀技术定义了CMUT器件底电极极板62的区域后,再使用干法蚀刻工艺将CMUT器件阵元旁的底电极极板区域的上方的绝缘层4及氮化硅层去除,暴露出基底5,即将绝缘层4的氮化硅41,二氧化硅42,以及步骤4所沉积氮化硅全部蚀刻掉,暴露出掺杂硅的基底5。经过此工艺后,实现了底电极极板区域的高浓度掺杂硅基底的暴露,如图2(j)所示。在该步骤后,需要清除残余光阻;Step 61: After the area of the bottom electrode plate 62 of the CMUT device is defined by photolithography, the insulating layer 4 and the silicon nitride layer above the area of the bottom electrode plate next to the array element of the CMUT device are then separated by a dry etching process. Removing, exposing the substrate 5, that is, the silicon nitride 41, silicon dioxide 42 of the insulating layer 4, and the silicon nitride deposited in step 4 are all etched away, exposing the substrate 5 doped with silicon. After this process, the exposure of the highly doped silicon substrate in the bottom electrode pad region is achieved, as shown in Figure 2(j). After this step, the residual photoresist needs to be removed;

步骤62:使用电子束蒸镀(E-beam evaporation)工艺,在步骤61后包括CMUT单元在内的硅晶圆上沉积20 nm铬和180 nm金形成复合金属层,作为导电层6,如图2(k)所示。铬作为金与氮化硅,硅基底的粘附层,金作为导电层6。此导电层6用于制备CMUT单元的顶电极61和底电极极板62;Step 62: Using an E-beam evaporation process, deposit 20 nm of chromium and 180 nm of gold on the silicon wafer including the CMUT unit after step 61 to form a composite metal layer as a conductive layer 6, as shown in the figure 2(k). Chromium serves as the adhesion layer between gold and silicon nitride, the silicon substrate, and gold serves as the conductive layer 6 . This conductive layer 6 is used to prepare the top electrode 61 and the bottom electrode plate 62 of the CMUT unit;

步骤7:具体包括以下步骤:Step 7: Specifically include the following steps:

步骤71:使用正光阻并结合光刻蚀工艺在步骤62中的导电层6上定义凸纹圆环7。首先使用光蚀刻技术,使用正光阻在导电层6上定义凸纹圆环7的区域,每个CMUT单元上都有一同心的凸纹圆环7;经过曝光、显影步骤后,凸纹圆环7区域的导电层6暴露出来,其余区域则被光阻覆盖,圆环的宽度为2 μm,内径为12 μm,外径为14 μm,光阻的厚度为2 μm。凸纹圆环7的宽度由经显影后的正光阻区域宽度决定,凸纹圆环7的最大高度则由光阻的厚度决定,即本实施例中的凸纹圆环7的宽度为2 μm,内径为12 μm,外径为14 μm;Step 71 : Define relief rings 7 on the conductive layer 6 in Step 62 using positive photoresist and a photolithography process. First, the photo-etching technology is used to define the area of the relief ring 7 on the conductive layer 6 by using a positive photoresist. Each CMUT unit has a concentric relief ring 7; after the exposure and development steps, the relief ring 7 The conductive layer 6 of the area is exposed, and the remaining areas are covered by photoresist. The width of the ring is 2 μm, the inner diameter is 12 μm, the outer diameter is 14 μm, and the thickness of the photoresist is 2 μm. The width of the relief ring 7 is determined by the width of the positive photoresist area after development, and the maximum height of the relief ring 7 is determined by the thickness of the photoresist, that is, the width of the relief ring 7 in this embodiment is 2 μm , the inner diameter is 12 μm, and the outer diameter is 14 μm;

步骤72:使用瓦特镍(硫酸镍、氯化镍和硼酸)方法进行电镀。电镀阳极为纯镍板,阴极为待镀镍环的CMUT单元。选择合适的电镀条件(浓度、电流、温度和时间等),可以实现镍圆环高度的准确控制。本实施例中使用瓦特镍电镀配方(硫酸镍、氯化镍和硼酸,参考比例为NiSO4 .6-7H2O: NiCl2 .6H2O: H3BO3 : H2O=676: 114: 96: 2400 (g)),溶液温度设定在50℃,DC电流为80 mA,电镀时间为50s。电镀镍厚度为2 μm,故镍圆环的高度就是2 μm,如图2(l)所示。完成电镀后,使用丙酮清除硅晶圆上的光阻,即完成凸纹圆环7的加工流程。步骤62中的复合金属的导电层6作为电镀镍的基底面,提高凸纹圆环7的电镀结合力;Step 72: Electroplating using the Watts Nickel (Nickel Sulfate, Nickel Chloride, and Boric Acid) method. The electroplating anode is a pure nickel plate, and the cathode is the CMUT unit to be plated with nickel rings. By choosing the appropriate plating conditions (concentration, current, temperature and time, etc.), accurate control of the height of the nickel ring can be achieved. In this example, Watt's nickel electroplating formula (nickel sulfate, nickel chloride and boric acid is used, and the reference ratio is NiSO 4 .6-7H 2 O: NiCl 2 .6H 2 O: H 3 BO 3 : H 2 O=676: 114 : 96: 2400 (g)), the solution temperature was set at 50 °C, the DC current was 80 mA, and the plating time was 50 s. The thickness of the electroplated nickel is 2 μm, so the height of the nickel ring is 2 μm, as shown in Figure 2(l). After the electroplating is completed, the photoresist on the silicon wafer is removed with acetone, that is, the processing flow of the relief ring 7 is completed. The conductive layer 6 of the composite metal in step 62 is used as the base surface of electroplating nickel to improve the electroplating bonding force of the relief ring 7;

步骤8:使用光蚀刻工艺,定义CMUT器件的电极(全覆盖顶电极、底电极极板)和CMUT单元间导线,上述的顶电极61区域为全覆盖于振动薄膜1的全电极结构,底电极极板62设置在基底5的一端;将包含CMUT单元的硅晶圆浸入金蚀刻剂内,将非电极和导线区域的金去除;再将硅晶圆浸入铬蚀刻剂内,将非电极和导线区域的铬去除,如图2(m)所示,此步骤完成后,需要去除残余光阻。复合金属的顶电极61覆盖了振动薄膜1的全部区域,形成全电极结构。使用步骤62中的电子束蒸镀(E-beam evaporation)工艺可制备密度均匀导电层6,得到位于振动薄膜1上的密度分布均匀的顶电极61,密度均匀的顶电极61提升了振动薄膜的振动稳定性,也易于通过调节直流偏置电压将振动薄膜部分的振动中心移动至凸纹圆环处;Step 8: Use the photo-etching process to define the electrodes of the CMUT device (fully covering the top electrode, the bottom electrode plate) and the wires between the CMUT cells. The above-mentioned top electrode 61 area is a full-electrode structure that fully covers the vibrating film 1. The bottom electrode The polar plate 62 is arranged at one end of the substrate 5; the silicon wafer containing the CMUT unit is immersed in the gold etchant, and the gold in the non-electrode and wire areas is removed; then the silicon wafer is immersed in the chromium etchant, and the non-electrode and wire are immersed in the chrome etchant. The chrome removal of the area, as shown in Figure 2(m), after this step is completed, the residual photoresist needs to be removed. The top electrode 61 of the composite metal covers the entire area of the vibrating membrane 1 to form an all-electrode structure. Using the E-beam evaporation process in step 62, the conductive layer 6 with uniform density can be prepared to obtain a top electrode 61 with uniform density distribution on the vibrating membrane 1, and the top electrode 61 with uniform density can improve the vibrating membrane. Vibration stability, it is also easy to move the vibration center of the vibrating membrane part to the relief ring by adjusting the DC bias voltage;

对上述1-8步骤完成的全电极凸纹结构CMUT器件,使用晶圆切割机,对硅晶圆上的CMUT阵列进行分割划片。然后使用环氧树脂将切割后的CMUT阵列固定在印刷电路板(PCB)之上。通过打线机用铝线将与顶电极61相连的公共顶电极,底电极极板62和PCB板上对应的电极相连。完成所有电极的导线连接之后,再使用环氧树脂保护连接的铝线。For the all-electrode relief structure CMUT device completed in the above steps 1-8, a wafer dicing machine is used to divide and scribe the CMUT array on the silicon wafer. The cut CMUT array is then mounted on a printed circuit board (PCB) using epoxy. The common top electrode connected to the top electrode 61 and the bottom electrode plate 62 are connected to the corresponding electrodes on the PCB board through a wire bonding machine with aluminum wires. After completing the wire connections for all electrodes, epoxy the connected aluminum wires to protect them.

当CMUT器件工作在塌陷模式下,薄膜中心部分贴合到基底绝缘层之上。在特定的电压范围内,凸纹结构位于未塌陷的圆环形薄膜振动中心附近,从而能够增大输出声压。有限元仿真表明,该凸纹结构能将工作在塌陷模式下的CMUT最大输出声压提升约88.1%[1]([1] Yu, Y., Pun, S. H., Mak, P. U., Cheng, C. H., Wang, J., Mak, P. I., andVai, M. I, Design of a Collapse-Mode CMUT with an Embossed Membrane forImproving Output Pressure, IEEE Transactions on Ultrasonics, Ferroelectrics,and Frequency Control, 2016, 63(6):854-863)。When the CMUT device operates in collapse mode, the central portion of the film is attached to the base insulating layer. In a specific voltage range, the relief structure is located near the vibration center of the non-collapsed annular membrane, which can increase the output sound pressure. The finite element simulation shows that the ridge structure can increase the maximum output sound pressure of the CMUT in collapse mode by about 88.1% [1] ([1] Yu, Y., Pun, SH, Mak, PU, Cheng, CH, Wang, J., Mak, PI, andVai, M. I, Design of a Collapse-Mode CMUT with an Embossed Membrane forImproving Output Pressure, IEEE Transactions on Ultrasonics, Ferroelectrics,and Frequency Control, 2016, 63(6):854- 863).

显然,本发明的上述实施例仅仅是为清楚地说明本发明所作的举例,而并非是对本发明的实施方式的限定。对于所属领域的普通技术人员来说,在上述说明的基础上还可以做出其它不同形式的变化或变动。这里无需也无法对所有的实施方式予以穷举。凡在本发明的精神和原则之内所作的任何修改、等同替换和改进等,均应包含在本发明权利要求的保护范围之内。Obviously, the above-mentioned embodiments of the present invention are only examples for clearly illustrating the present invention, and are not intended to limit the embodiments of the present invention. For those of ordinary skill in the art, changes or modifications in other different forms can also be made on the basis of the above description. There is no need and cannot be exhaustive of all implementations here. Any modifications, equivalent replacements and improvements made within the spirit and principle of the present invention shall be included within the protection scope of the claims of the present invention.

Claims (9)

1.一种全电极凸纹结构CMUT器件的制备方法,其特征在于,所述的制备方法包括以下步骤:1. a preparation method of all-electrode relief structure CMUT device, is characterized in that, described preparation method comprises the following steps: 步骤1:使用高浓度掺杂的硅晶圆作为基底(5)制备基底层;Step 1: using a highly doped silicon wafer as a substrate (5) to prepare a base layer; 步骤2:在步骤1中基底(5)上沉积制备绝缘层(4);Step 2: depositing an insulating layer (4) on the substrate (5) in step 1; 步骤3:在步骤2中的绝缘层(4)上沉积多晶硅薄膜制备牺牲层(81),并去除多余的多晶硅薄膜层,定义CMUT单元;Step 3: depositing a polysilicon film on the insulating layer (4) in step 2 to prepare a sacrificial layer (81), and removing the redundant polysilicon film layer to define a CMUT unit; 步骤4:在步骤3制备的CMUT单元上沉积振动薄膜(1);Step 4: depositing a vibrating film (1) on the CMUT unit prepared in step 3; 步骤5:去除步骤3中保留的多晶硅薄膜层(8)形成封闭的空腔(2);Step 5: removing the polysilicon thin film layer (8) retained in step 3 to form a closed cavity (2); 步骤6:沉积用于制备CMUT单元顶电极(61)和底电极极板(62)的导电层(6);Step 6: depositing a conductive layer (6) for preparing the top electrode (61) and bottom electrode plate (62) of the CMUT unit; 步骤7:在振动薄膜(1)顶部的导电层(6)上制备凸纹圆环(7);Step 7: preparing a relief ring (7) on the conductive layer (6) on top of the vibrating membrane (1); 步骤8:使用光刻蚀工艺定义导电层(6),制备全覆盖于振动薄膜(1)的顶电极(61)、底电极极板(62)及导线,并去除多余导电层(6);完成全电极凸纹结构CMUT器件的制备;所述的步骤5具体包括以下步骤:Step 8: using a photolithography process to define the conductive layer (6), preparing the top electrode (61), the bottom electrode plate (62) and the wires fully covering the vibrating membrane (1), and removing the redundant conductive layer (6); The preparation of the all-electrode relief structure CMUT device is completed; the step 5 specifically includes the following steps: 步骤51:使用干法刻蚀工艺在保留的多晶硅薄膜层(8)顶部的刻蚀通道上刻蚀腐蚀孔(9),再使用湿法刻蚀工艺通过腐蚀孔(9)去除保留的多晶硅薄膜层(8),形成封闭的空腔(2);Step 51: Use a dry etching process to etch an etching hole (9) on the etching channel on the top of the remaining polysilicon film layer (8), and then use a wet etching process to remove the remaining polysilicon film through the etching hole (9). layer (8), forming a closed cavity (2); 步骤52:使用等离子体增强化学气相沉积法(PECVD)沉积氮化硅层,填充步骤51中的腐蚀孔(9);Step 52: use plasma enhanced chemical vapor deposition (PECVD) to deposit a silicon nitride layer to fill the etched hole (9) in step 51; 步骤53:使用干法蚀刻工艺,蚀刻步骤52中填充腐蚀孔(9)后的氮化硅层,将振动薄膜厚度减所述步骤4的厚度。Step 53: Using a dry etching process, the silicon nitride layer after filling the etching hole (9) in step 52 is etched, and the thickness of the vibrating film is reduced by the thickness of the step 4. 2.根据权利要求1所述的一种全电极凸纹结构CMUT器件的制备方法,其特征在于,所述步骤7具体包括以下步骤:2. the preparation method of a kind of all-electrode relief structure CMUT device according to claim 1, is characterized in that, described step 7 specifically comprises the following steps: 步骤71:在振动薄膜(1)顶部的导电层(6)上使用正光阻并结合光刻蚀工艺定义所述凸纹圆环(7)的尺寸;Step 71: use positive photoresist on the conductive layer (6) on top of the vibrating film (1) and combine the photolithography process to define the size of the relief ring (7); 步骤72:在步骤71定义凸纹圆环(7)的尺寸区域使用电镀工艺制备凸纹圆环(7)。Step 72: Define the size area of the relief ring (7) at step 71 to prepare the relief ring (7) using an electroplating process. 3.根据权利要求2所述的一种全电极凸纹结构CMUT器件的制备方法,其特征在于,所述步骤71中凸纹圆环(7)的高度及宽度由所述正光阻经显影后的高度和宽度决定,所述凸纹圆环(7)的高度为0.5~6μm,宽度为0.5~3μm;所述步骤72中凸纹圆环(7)为金属镍。3 . The method for preparing a CMUT device with an all-electrode relief structure according to claim 2 , wherein the height and width of the relief ring ( 7 ) in the step 71 are determined by the positive photoresist after developing. 4 . The height and width of the relief ring (7) are determined by the height and width of 0.5-6 μm, and the width is 0.5-3 μm; in the step 72, the relief ring (7) is metal nickel. 4.根据权利要求1所述的一种全电极凸纹结构CMUT器件的制备方法,其特征在于,所述步骤4中振动薄膜(1)为低残余应力氮化硅薄膜,厚度为0.3~2μm;步骤4包括有与所述振动薄膜(1)一体沉积的支撑层(3)。4 . The method for preparing a CMUT device with an all-electrode relief structure according to claim 1 , wherein in the step 4, the vibrating film (1) is a low residual stress silicon nitride film with a thickness of 0.3-2 μm. 5 . ; Step 4 includes a supporting layer (3) deposited integrally with the vibrating membrane (1). 5.根据权利要求4所述的一种全电极凸纹结构CMUT器件的制备方法,其特征在于,所述步骤51中湿法刻蚀工艺的刻蚀剂为氢氧化钾溶液。5 . The method for preparing a CMUT device with an all-electrode relief structure according to claim 4 , wherein the etchant in the wet etching process in the step 51 is potassium hydroxide solution. 6 . 6.根据权利要求1所述的一种全电极凸纹结构CMUT器件的制备方法,其特征在于,所述步骤2中的绝缘层(4)为使用低压力化学气相沉积(LPCVD)工艺沉积的单层氮化硅一种材料或者使用干式氧化工艺及低压力化学气相沉积(LPCVD)工艺沉积的二氧化硅与氮化硅两种材料的复合层构成。6. The method for preparing an all-electrode relief structure CMUT device according to claim 1, wherein the insulating layer (4) in the step 2 is deposited by a low pressure chemical vapor deposition (LPCVD) process. A single-layer silicon nitride material or a composite layer of silicon dioxide and silicon nitride deposited by dry oxidation and low pressure chemical vapor deposition (LPCVD) processes. 7.根据权利要求1所述的一种全电极凸纹结构CMUT器件的制备方法,其特征在于,所述步骤6具体包括以下步骤:7. the preparation method of a kind of all-electrode relief structure CMUT device according to claim 1, is characterized in that, described step 6 specifically comprises the following steps: 步骤61:使用干法蚀刻工艺,去掉基底(5)一端的覆盖层,暴露出基底(5);Step 61: use a dry etching process to remove the cover layer at one end of the substrate (5) to expose the substrate (5); 步骤62:使用电子束蒸镀(E-beam evaporation)工艺在步骤61制备的CMUT单元上沉积导电层(6)。Step 62: Deposit a conductive layer (6) on the CMUT cell prepared in Step 61 using an E-beam evaporation process. 8.根据权利要求7所述的一种全电极凸纹结构CMUT器件的制备方法,其特征在于,所述步骤62中的导电层(6)为铬、金复合结构。8 . The method for preparing a CMUT device with an all-electrode relief structure according to claim 7 , wherein the conductive layer ( 6 ) in the step 62 is a composite structure of chromium and gold. 9 . 9.根据权利要求1所述的一种全电极凸纹结构CMUT器件的制备方法,其特征在于,所述的全电极凸纹结构CMUT器件工作在塌陷模式时,所述振动薄膜(1)的中心部分在静电力作用下发生塌陷,贴合在基底(5)上的绝缘层(4)表面,形成塌陷薄膜部分(11);未塌陷部分的薄膜为CMUT器件工作时的振动薄膜部分(12),所述的凸纹圆环(7)位于振动薄膜部分(12)。9 . The method for preparing an all-electrode relief structure CMUT device according to claim 1 , wherein when the all-electrode relief structure CMUT device operates in a collapsed mode, the vibration film (1) has a The central part collapses under the action of electrostatic force, and is attached to the surface of the insulating layer (4) on the substrate (5) to form a collapsed membrane part (11); the membrane of the uncollapsed part is the vibrating membrane part (12) when the CMUT device works ), the relief ring (7) is located in the vibrating membrane part (12).
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