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CN108790337A - A kind of environment-friendly waterproof combined type warm-keeping and life-saving fabric and its production method - Google Patents

A kind of environment-friendly waterproof combined type warm-keeping and life-saving fabric and its production method Download PDF

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Publication number
CN108790337A
CN108790337A CN201810229787.7A CN201810229787A CN108790337A CN 108790337 A CN108790337 A CN 108790337A CN 201810229787 A CN201810229787 A CN 201810229787A CN 108790337 A CN108790337 A CN 108790337A
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China
Prior art keywords
fabric
water
thermal insulating
keeping
life
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Granted
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CN201810229787.7A
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CN108790337B (en
Inventor
张炜栋
黄旭
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Nantong Textile Vocational Technology College
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Nantong Textile Vocational Technology College
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/12Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B63SHIPS OR OTHER WATERBORNE VESSELS; RELATED EQUIPMENT
    • B63CLAUNCHING, HAULING-OUT, OR DRY-DOCKING OF VESSELS; LIFE-SAVING IN WATER; EQUIPMENT FOR DWELLING OR WORKING UNDER WATER; MEANS FOR SALVAGING OR SEARCHING FOR UNDERWATER OBJECTS
    • B63C9/00Life-saving in water
    • B63C9/02Lifeboats, life-rafts or the like, specially adapted for life-saving
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/40Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads
    • D03D15/47Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads multicomponent, e.g. blended yarns or threads
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06CFINISHING, DRESSING, TENTERING OR STRETCHING TEXTILE FABRICS
    • D06C11/00Teasing, napping or otherwise roughening or raising pile of textile fabrics
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06CFINISHING, DRESSING, TENTERING OR STRETCHING TEXTILE FABRICS
    • D06C27/00Compound processes or apparatus, for finishing or dressing textile fabrics, not otherwise provided for
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06CFINISHING, DRESSING, TENTERING OR STRETCHING TEXTILE FABRICS
    • D06C9/00Singeing
    • D06C9/02Singeing by flame
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/02Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with hydrocarbons
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03Polysaccharides or derivatives thereof
    • D06M15/11Starch or derivatives thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/327Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof
    • D06M15/333Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof of vinyl acetate; Polyvinylalcohol
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/30Properties of the layers or laminate having particular thermal properties
    • B32B2307/304Insulating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/554Wear resistance
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/582Tearability
    • B32B2307/5825Tear resistant
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/724Permeability to gases, adsorption
    • B32B2307/7242Non-permeable
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/73Hydrophobic
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2437/00Clothing
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00Cellulose-based fibres, e.g. vegetable fibres
    • D10B2201/01Natural vegetable fibres
    • D10B2201/02Cotton
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00Cellulose-based fibres, e.g. vegetable fibres
    • D10B2201/20Cellulose-derived artificial fibres
    • D10B2201/22Cellulose-derived artificial fibres made from cellulose solutions
    • D10B2201/24Viscose
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2321/00Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D10B2321/02Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins
    • D10B2321/021Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins polyethylene
    • D10B2321/0211Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins polyethylene high-strength or high-molecular-weight polyethylene, e.g. ultra-high molecular weight polyethylene [UHMWPE]
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/02Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
    • D10B2331/021Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides aromatic polyamides, e.g. aramides
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/04Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/14Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polycondensates of cyclic compounds, e.g. polyimides, polybenzimidazoles

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Mechanical Engineering (AREA)
  • Ocean & Marine Engineering (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Woven Fabrics (AREA)

Abstract

The invention discloses a kind of environment-friendly waterproof combined type warm-keeping and life-saving fabric and its production methods, the environment-friendly waterproof combined type warm-keeping and life-saving fabric includes the thermal insulating and water-proof fabric side bed of material, membrane waterproofing and polymeric layer, the membrane waterproofing is arranged in fabric outer layer, and polymeric layer pastes fabric internal layer.Include the following steps:The techniques such as raw material choice, weaving, dyeing, plucking, arrangement, coating.Present invention process is simple, mass automatic production can be achieved, it has a good application prospect, the Novel lifesaving fabric has light fabric quality, strength height, resistance to mill performance of cutting good, and pro-skin is comfortable, has good air-tightness and waterproof, antifouling, tearing brute force, heat seal strength and water soak resistance energy good.

Description

A kind of environment-friendly waterproof combined type warm-keeping and life-saving fabric and its production method
Technical field
The present invention relates to textile fields, and in particular to a kind of environment-friendly waterproof combined type warm-keeping and life-saving fabric and its producer Method.
Background technology
Life vest is to ensure that drowning people floats on the water surface with safe condition, prevents drowned clothes.Inflatable life jacket with Its excellent air-tightness, wearability, resistance to ag(e)ing, high-strength pulling-resisting and the characteristics such as environmental protection, pollution-free, on the market increasingly To the favor of people.For life vest fabric components, tearing brute force, peel strength are more demanding, at present the 231dtex of industry Lasting yarn nylon fabric is difficult to up to standard.
Invention content
Goal of the invention:In order to solve the deficiencies in the prior art, rescue the present invention provides a kind of environment-friendly waterproof combined type is warming Raw fabric and its production method.The Novel lifesaving fabric has that fabric quality is light, strength is high, resistance to cuts that mill performance is good, and pro-skin is relaxed It is suitable, good with good air-tightness and waterproof, antifouling, tearing brute force, heat seal strength and water soak resistance energy.Present invention process letter It is single, it can mass produce, the market competitiveness has by force good market prospects.
Technical solution:A kind of environment-friendly waterproof combined type warm-keeping and life-saving fabric, the environment-friendly waterproof combined type warm-keeping and life-saving Include the thermal insulating and water-proof fabric side bed of material, membrane waterproofing and polymeric layer with fabric, the membrane waterproofing is arranged in outside fabric Layer, polymeric layer paste fabric internal layer.
As an optimization:The thermal insulating and water-proof fabric side bed of material by ultra-high molecular weight polyethylene/coffee carbon mixed yarn, aramid fiber/ Viscose blended yarn, polyimides/silk/cotton blended yarn or pbo fiber one of which or several, blending ratio 50/50,35/65,30/ 70,10/90 one of which are several, yarn count 60 or more.
A kind of production method of environment-friendly waterproof combined type warm-keeping and life-saving fabric described in basis, includes the following steps:Raw material Apolegamy, sizing, weaving, bristle, arrangement, coating;Wherein:
The thermal insulating and water-proof fabric side bed of material sizing operation:Sizing is carried out using karr Meyer sizing machine, River Bank Stability is former It is then highly concentrated low viscous principle, formula of size is:Maleic anhydride converted starch 50-55kg, PVA2488 slurry 20-25kg, PVA0588 slurries 30-35kg, HX-88 crosslinked starch 20-25kg, HA-soft80 emulsifying wax 3-5kg, EL16 antistatic agent 1- 3kg, slurry bucket solid content 12.4-13.2%, 92-97 DEG C of slurry bucket temperature.
As an optimization:The thermal insulating and water-proof fabric side bed of material sizing operation:Follow first light pressure, rear weight, low-tension, patch hair The principle of plumage, rate of sizing 12%-17%, regain 6-8%, enhancing rate are 55-65%, and it is 25-30%, sizing to subtract the rate of stretching Speed is 35-45m/min, and the Ith platen pressure is 10-15kN, and the IIth platen pressure is 8-13kN;Pressure roller hardness 80HR, drying Mode is layered preliminary drying, merges 102-115 DEG C of drying preliminary drying temperature, main 100-110 DEG C of baking temperature.
As an optimization:The thermal insulating and water-proof fabric side bed of material weaving process:It is weaved using Tianjin river flowing from Guizhou Province through Hunan into Dongting Lake CH11 air-jet looms, Double plain weave, cloth cover is selected to form a kind of fine and close honeycomb trellis, warp-wise tightness is 70-90%, and broadwise tightness is 45%- 55%, weft yarn main burner pressure is 2.5 × 105Pa-3.0×105Pa, auxiliary nozzle exit pressure are 3.4 × 105Pa-3.8×105Pa, Speed 550-600r/min.
As an optimization:The thermal insulating and water-proof fabric side bed of material bristle process:It singes before bristle, singeing:Burner Two forward one-reverses, speed 95-110m/min, 1000-1100 DEG C of flame temperature;Using carbon sanding roller, Buddha's warrior attendant rubber (100-500 Mesh), one or both of grinding material of nylon brush thread twice sanding is carried out to fabric one side, generate short peach face so that fabric has Standby physics waterproof effect, process conditions speed 12-25m/min.
As an optimization:The thermal insulating and water-proof fabric side bed of material arranging process:Dressing liquid is prepared in the following proportions, PE-100 profits The fluffy soft silicone oil 10-20g/L of humectant 0.5-1.5g/L, NT-X620 three-proof finishing agent 50-70g/L, GA-100.Waterproof is protected Warm fabrics fabric is immersed in dressing liquid, an immersing and rolling drying and shaping, pick-up:60-65%, 130 DEG C of drying, and at 150 DEG C It bakes 30 seconds so that thermal insulating and water-proof fabric side bed of material two sides is respectively formed continuous uniform membrane waterproofing.
As an optimization:The thermal insulating and water-proof fabric side bed of material coats process:Made with graphene oxide modified TPU laminated film For upper layer fabric, thermal insulating and water-proof fabric is lower layer's fabric, by thermal insulating and water-proof fabric smooth surface graphene oxide modified TPU The compound importing OP-450GS continous ways fabric Adhesive machine of laminated film, film thickness 0.010-0.012mm, speed 10-15cm/s, Pressure 1.2-1.8MPa, 130-150 DEG C of temperature, finished product.
Advantageous effect:Present invention process is simple, it can be achieved that mass automatic production, has a good application prospect, face Material light weight, strength are high, resistance to mill performance of cutting is good, pro-skin is comfortable, have good air-tightness and waterproof, antifouling, tearing brute force, Heat seal strength and water soak resistance can be good.
In the present invention, thermal insulating and water-proof fabric side bed of material raw material be ultra-high molecular weight polyethylene/coffee carbon mixed yarn, aramid fiber/ Viscose blended yarn, polyimides/silk/cotton blended yarn or pbo fiber one of which or several, wherein ultra-high molecular weight polyethylene, virtue Synthetic fibre, polyimides and pbo fiber provide strength it is high, it is resistance to cut mill performance, coffee carbon, viscose glue, cotton, polyimide fiber provide Pro-skin is comfortable and thermal property.
In the present invention, the thermal insulating and water-proof fabric side bed of material is the tight structure fabric of high-count and high-density, and fabric tissue space is small, makes Fabric can not be soaked by obtaining water, have certain physics water resistance.
In the present invention, the thermal insulating and water-proof fabric side bed of material is double plain weave, and cloth cover forms a kind of fine and close honeycomb trellis, Sanding processing is carried out on the basis of this and forms short peach face fabric, and the suede of the small densification of similar lotus leaf surface is formed on fabric surface layer Hair tissue, has certain physics water resistance, strengthening physical water resistance, due to the raising of physics water resistance, after reduction Road water-proof aagent coating agent is practical, there is certain feature of environmental protection.
In the present invention, the thermal insulating and water-proof fabric side bed of material is weaved for high-count yarn, and since yarn is thinner, filoplume is excessive, this hair It is bright using highly concentrated low viscous sizing formula and technique, so that serous infiltration yarn internal layer, the cohesive force between increased fiber is improved yarn Fracture strength keeps yarn more resistant, bears loom mechanism and friction, reduces weaving end breakage rate, improves weavability and product Quality.
In the present invention, arranging process provides thermal insulating and water-proof fabric side bed of material two sides and is respectively formed continuous uniform membrane waterproofing Further increase water proofing property.
In the present invention, the coating process of the thermal insulating and water-proof fabric side bed of material uses graphene oxide modified TPU laminated film Tearing brute force, heat seal strength and the water soak resistance energy of fabric are improved, and provides water proofing property, air-tightness, and mitigate weight significantly The effect of amount.
Specific implementation mode
The technical scheme in the embodiments of the invention will be clearly and completely described below, so that the technology of this field Personnel can be better understood from advantages and features of the invention, to make apparent boundary to protection scope of the present invention It is fixed.Embodiment described in the invention is only a part of the embodiment of the present invention, instead of all the embodiments, based on the present invention In embodiment, the every other implementation that those of ordinary skill in the art are obtained without making creative work Example, shall fall within the protection scope of the present invention.
Specific embodiment 1
A kind of environment-friendly waterproof combined type warm-keeping and life-saving fabric, the environment-friendly waterproof combined type warm-keeping and life-saving include with fabric The thermal insulating and water-proof fabric side bed of material, membrane waterproofing and polymeric layer, the membrane waterproofing are arranged in fabric outer layer, polymeric layer Paste fabric internal layer.
The thermal insulating and water-proof fabric side bed of material is by ultra-high molecular weight polyethylene/coffee carbon mixed yarn, blending ratio 50/50, Yarn count 60 or more.
A kind of production method of environment-friendly waterproof combined type warm-keeping and life-saving fabric described in basis, includes the following steps:Raw material Apolegamy, sizing, weaving, bristle, arrangement, coating;Wherein:
The thermal insulating and water-proof fabric side bed of material sizing operation:Sizing is carried out using karr Meyer sizing machine, River Bank Stability is former It is then highly concentrated low viscous principle, formula of size is:Maleic anhydride converted starch 50kg, PVA2488 slurry 20kg, PVA0588 slurry Expect 30kg, HX-88 crosslinked starch 20kg, HA-soft80 emulsifying wax 3kg, EL16 antistatic agent 1kg, slurry bucket solid content 12.4%, 92 DEG C of slurry bucket temperature.
The thermal insulating and water-proof fabric side bed of material sizing operation:First light pressure, rear weight, low-tension, the principle for pasting filoplume are followed, The rate of sizing is 12%, regain 6%, and enhancing rate is 55%, and it is 25% to subtract the rate of stretching, and sizing speed is 35m/min, the Ith pressure roller Pressure is 10kN, and the IIth platen pressure is 8kN;Pressure roller hardness 80HR, drying mode are layered preliminary drying, merge drying preliminary drying temperature 102 DEG C, main 100 DEG C of baking temperature.
The thermal insulating and water-proof fabric side bed of material weaving process:It is weaved, is selected double using Tianjin river flowing from Guizhou Province through Hunan into Dongting Lake CH11 air-jet looms Plain weave, cloth cover form a kind of fine and close honeycomb trellis, and warp-wise tightness is 70%, and broadwise tightness is 45%, weft yarn main burner pressure Power is 2.5 × 105Pa, auxiliary nozzle exit pressure are 3.4 × 105Pa, speed 550r/min.
The thermal insulating and water-proof fabric side bed of material bristle process:It singes before bristle, singeing:Two forward one-reverse of burner, Speed 95m/min, 1000 DEG C of flame temperature;Using one in carbon sanding roller, Buddha's warrior attendant rubber (100 mesh), grinding material of nylon brush thread It plants or two kinds carries out twice sanding to fabric one side, generate short peach face so that fabric has physics waterproof effect, process conditions Speed 12m/min,
The thermal insulating and water-proof fabric side bed of material arranging process:Dressing liquid is prepared in the following proportions, PE-100 wetting agents 0.5g/ The fluffy soft silicone oil 10g/L of L, NT-X620 three-proof finishing agent 50g/L, GA-100.Thermal insulating and water-proof fabric is immersed in arrangement In liquid, an immersing and rolling drying and shaping, pick-up:60%, 130 DEG C of drying, and baked 30 seconds at 150 DEG C so that thermal insulating and water-proof is knitted Object plane bed of material two sides is respectively formed continuous uniform membrane waterproofing.
The thermal insulating and water-proof fabric side bed of material coats process:Using graphene oxide modified TPU laminated film as face layer Material, thermal insulating and water-proof fabric is lower layer's fabric, by thermal insulating and water-proof fabric smooth surface graphene oxide modified TPU laminated film Compound importing OP-450GS continous way fabric Adhesive machines, film thickness 0.010mm, speed 10cm/s, pressure 1.2MPa, temperature 130 DEG C, finished product.
Specific embodiment 2
A kind of environment-friendly waterproof combined type warm-keeping and life-saving fabric, the environment-friendly waterproof combined type warm-keeping and life-saving include with fabric The thermal insulating and water-proof fabric side bed of material, membrane waterproofing and polymeric layer, the membrane waterproofing are arranged in fabric outer layer, polymeric layer Paste fabric internal layer.
The thermal insulating and water-proof fabric side bed of material is by aramid fiber/viscose blended yarn, blending ratio 35/65,30/70, one of which, Yarn count 60 or more.
A kind of production method of environment-friendly waterproof combined type warm-keeping and life-saving fabric described in basis, includes the following steps:Raw material Apolegamy, sizing, weaving, bristle, arrangement, coating;Wherein:
The thermal insulating and water-proof fabric side bed of material sizing operation:Sizing is carried out using karr Meyer sizing machine, River Bank Stability is former It is then highly concentrated low viscous principle, formula of size is:Maleic anhydride converted starch 55kg, PVA2488 slurry 25kg, PVA0588 slurry Expect 35kg, HX-88 crosslinked starch 25kg, HA-soft80 emulsifying wax 5kg, EL16 antistatic agent 3kg, slurry bucket solid content 13.2%, 97 DEG C of slurry bucket temperature.
The thermal insulating and water-proof fabric side bed of material sizing operation:First light pressure, rear weight, low-tension, the principle for pasting filoplume are followed, The rate of sizing is 17%, regain 8%, and enhancing rate is 65%, and it is 30% to subtract the rate of stretching, and sizing speed is 45m/min, the Ith pressure roller Pressure is 15kN, and the IIth platen pressure is 13kN;Pressure roller hardness 80HR, drying mode are layered preliminary drying, merge drying preliminary drying temperature 115 DEG C, main 110 DEG C of baking temperature.
The thermal insulating and water-proof fabric side bed of material weaving process:It is weaved, is selected double using Tianjin river flowing from Guizhou Province through Hunan into Dongting Lake CH11 air-jet looms Plain weave, cloth cover form a kind of fine and close honeycomb trellis, and warp-wise tightness is 90%, and broadwise tightness is 55%, weft yarn main burner pressure Power is 3.0 × 105Pa, auxiliary nozzle exit pressure are 3.8 × 105Pa, speed 600r/min.
The thermal insulating and water-proof fabric side bed of material bristle process:It singes before bristle, singeing:Two forward one-reverse of burner, Speed 110m/min, 1100 DEG C of flame temperature;Using one in carbon sanding roller, Buddha's warrior attendant rubber (500 mesh), grinding material of nylon brush thread It plants or two kinds carries out twice sanding to fabric one side, generate short peach face so that fabric has physics waterproof effect, process conditions Speed 25m/min.
The thermal insulating and water-proof fabric side bed of material arranging process:Dressing liquid is prepared in the following proportions, PE-100 wetting agents 1.5g/ The fluffy soft silicone oil 20g/L of L, NT-X620 three-proof finishing agent 70g/L, GA-100.Thermal insulating and water-proof fabric is immersed in arrangement In liquid, an immersing and rolling drying and shaping, pick-up:65%, 130 DEG C of drying, and baked 30 seconds at 150 DEG C so that thermal insulating and water-proof is knitted Object plane bed of material two sides is respectively formed continuous uniform membrane waterproofing.
The thermal insulating and water-proof fabric side bed of material coats process:Using graphene oxide modified TPU laminated film as face layer Material, thermal insulating and water-proof fabric is lower layer's fabric, by thermal insulating and water-proof fabric smooth surface graphene oxide modified TPU laminated film Compound importing OP-450GS continous way fabric Adhesive machines, film thickness 0.012mm, speed 15cm/s, pressure 1.8MPa, temperature 150 DEG C, finished product.
Specific embodiment 3
A kind of environment-friendly waterproof combined type warm-keeping and life-saving fabric, the environment-friendly waterproof combined type warm-keeping and life-saving include with fabric The thermal insulating and water-proof fabric side bed of material, membrane waterproofing and polymeric layer, the membrane waterproofing are arranged in fabric outer layer, polymeric layer Paste fabric internal layer.
The thermal insulating and water-proof fabric side bed of material is by polyimides/silk/cotton blended yarn or pbo fiber, blending ratio 10/90, yarn count 60 or more.
A kind of production method of environment-friendly waterproof combined type warm-keeping and life-saving fabric described in basis, includes the following steps:Raw material Apolegamy, sizing, weaving, bristle, arrangement, coating;Wherein:
The thermal insulating and water-proof fabric side bed of material sizing operation:Sizing is carried out using karr Meyer sizing machine, River Bank Stability is former It is then highly concentrated low viscous principle, formula of size is:Maleic anhydride converted starch 53kg, PVA2488 slurry 24kg, PVA0588 slurry Expect 32kg, HX-88 crosslinked starch 23kg, HA-soft80 emulsifying wax 4kg, EL16 antistatic agent 2kg, slurry bucket solid content 12.8%, 94 DEG C of slurry bucket temperature.
The thermal insulating and water-proof fabric side bed of material sizing operation:First light pressure, rear weight, low-tension, the principle for pasting filoplume are followed, The rate of sizing is 14%, regain 7%, and enhancing rate is 59%, and it is 27% to subtract the rate of stretching, and sizing speed is 39m/min, the Ith pressure roller Pressure is 13kN, and the IIth platen pressure is 10kN;Pressure roller hardness 80HR, drying mode are layered preliminary drying, merge drying preliminary drying temperature 109 DEG C, main 107 DEG C of baking temperature.
The thermal insulating and water-proof fabric side bed of material weaving process:It is weaved, is selected double using Tianjin river flowing from Guizhou Province through Hunan into Dongting Lake CH11 air-jet looms Plain weave, cloth cover form a kind of fine and close honeycomb trellis, and warp-wise tightness is 80%, broadwise tightness 51%, weft yarn main burner pressure It is 2.7 × 105Pa, auxiliary nozzle exit pressure are 3.6 × 105Pa, speed 570r/min.
The thermal insulating and water-proof fabric side bed of material bristle process:It singes before bristle, singeing:Two forward one-reverse of burner, Speed 103m/min, 1060 DEG C of flame temperature;Using one in carbon sanding roller, Buddha's warrior attendant rubber (300 mesh), grinding material of nylon brush thread It plants or two kinds carries out twice sanding to fabric one side, generate short peach face so that fabric has physics waterproof effect, process conditions Speed 19m/min.
The thermal insulating and water-proof fabric side bed of material arranging process:Dressing liquid is prepared in the following proportions, PE-100 wetting agents 0.9g/ The fluffy soft silicone oil 17g/L of L, NT-X620 three-proof finishing agent 60g/L, GA-100.Thermal insulating and water-proof fabric is immersed in arrangement In liquid, an immersing and rolling drying and shaping, pick-up:62%, 130 DEG C of drying, and baked 30 seconds at 150 DEG C so that thermal insulating and water-proof is knitted Object plane bed of material two sides is respectively formed continuous uniform membrane waterproofing.
The thermal insulating and water-proof fabric side bed of material coats process:Using graphene oxide modified TPU laminated film as face layer Material, thermal insulating and water-proof fabric is lower layer's fabric, by thermal insulating and water-proof fabric smooth surface graphene oxide modified TPU laminated film Compound importing OP-450GS continous way fabric Adhesive machines, film thickness 0.011mm, speed 13cm/s, pressure 1.4MPa, temperature 140 DEG C, finished product.
Present invention process is simple, it can be achieved that mass automatic production, has a good application prospect, fabric quality is light, Strength is high, resistance to mill performance of cutting is good, pro-skin is comfortable, have good air-tightness and waterproof, antifouling, tearing brute force, heat seal strength and Water soak resistance can be good.
In the present invention, thermal insulating and water-proof fabric side bed of material raw material be ultra-high molecular weight polyethylene/coffee carbon mixed yarn, aramid fiber/ Viscose blended yarn, polyimides/silk/cotton blended yarn or pbo fiber one of which or several, wherein ultra-high molecular weight polyethylene, virtue Synthetic fibre, polyimides and pbo fiber provide strength it is high, it is resistance to cut mill performance, coffee carbon, viscose glue, cotton, polyimide fiber provide Pro-skin is comfortable and thermal property.
In the present invention, the thermal insulating and water-proof fabric side bed of material is the tight structure fabric of high-count and high-density, and fabric tissue space is small, makes Fabric can not be soaked by obtaining water, have certain physics water resistance.
In the present invention, the thermal insulating and water-proof fabric side bed of material is double plain weave, and cloth cover forms a kind of fine and close honeycomb trellis, Sanding processing is carried out on the basis of this and forms short peach face fabric, and the suede of the small densification of similar lotus leaf surface is formed on fabric surface layer Hair tissue, has certain physics water resistance, strengthening physical water resistance, due to the raising of physics water resistance, after reduction Road water-proof aagent coating agent is practical, there is certain feature of environmental protection.
In the present invention, the thermal insulating and water-proof fabric side bed of material is weaved for high-count yarn, and since yarn is thinner, filoplume is excessive, this hair It is bright using highly concentrated low viscous sizing formula and technique, so that serous infiltration yarn internal layer, the cohesive force between increased fiber is improved yarn Fracture strength keeps yarn more resistant, bears loom mechanism and friction, reduces weaving end breakage rate, improves weavability and product Quality.
In the present invention, arranging process provides thermal insulating and water-proof fabric side bed of material two sides and is respectively formed continuous uniform membrane waterproofing Further increase water proofing property.
In the present invention, the coating process of the thermal insulating and water-proof fabric side bed of material uses graphene oxide modified TPU laminated film Tearing brute force, heat seal strength and the water soak resistance energy of fabric are improved, and provides water proofing property, air-tightness, and mitigate weight significantly The effect of amount.

Claims (8)

1. a kind of environment-friendly waterproof combined type warm-keeping and life-saving fabric, it is characterised in that:The environment-friendly waterproof combined type warm-keeping and life-saving Include the thermal insulating and water-proof fabric side bed of material, membrane waterproofing and polymeric layer with fabric, the membrane waterproofing is arranged in outside fabric Layer, polymeric layer paste fabric internal layer.
2. environment-friendly waterproof combined type warm-keeping and life-saving fabric according to claim 1, it is characterised in that:The thermal insulating and water-proof is knitted The object plane bed of material is by ultra-high molecular weight polyethylene/coffee carbon mixed yarn, aramid fiber/viscose blended yarn, polyimides/silk/cotton blended yarn or Pbo fiber one of which is several, 50/50,35/65,30/70,10/90 one of which or several of blending ratio, yarn count 60 More than.
3. a kind of production method of environment-friendly waterproof combined type warm-keeping and life-saving fabric according to claim 1, it is characterised in that: Include the following steps:Raw material choice, sizing, weaving, bristle, arrangement, coating;Wherein:
The thermal insulating and water-proof fabric side bed of material sizing operation:Sizing is carried out using karr Meyer sizing machine, River Bank Stability principle is Highly concentrated low viscous principle, formula of size are:Maleic anhydride converted starch 50-55kg, PVA2488 slurry 20-25kg, PVA0588 Slurry 30-35kg, HX-88 crosslinked starch 20-25kg, HA-soft80 emulsifying wax 3-5kg, EL16 antistatic agent 1-3kg, slurry bucket Solid content 12.4-13.2%, 92-97 DEG C of slurry bucket temperature.
4. the production method of environment-friendly waterproof combined type warm-keeping and life-saving fabric according to claim 3, it is characterised in that:It is described Thermal insulating and water-proof fabric side bed of material sizing operation:Following first light pressure, rear weight, low-tension, the principle for pasting filoplume, the rate of sizing is 12%-17%, regain 6-8%, enhancing rate are 55-65%, and it is 25-30% to subtract the rate of stretching, and sizing speed is 35-45m/min, Ith platen pressure is 10-15kN, and the IIth platen pressure is 8-13kN;Pressure roller hardness 80HR, drying mode are layered preliminary drying, merge Dry 102-115 DEG C of preliminary drying temperature, main 100-110 DEG C of baking temperature.
5. the production method of environment-friendly waterproof combined type warm-keeping and life-saving fabric according to claim 3, it is characterised in that:It is described Thermal insulating and water-proof fabric side bed of material weaving process:It is weaved using Tianjin river flowing from Guizhou Province through Hunan into Dongting Lake CH11 air-jet looms, selects double plain weave, cloth cover A kind of fine and close honeycomb trellis is formed, warp-wise tightness is 70-90%, and broadwise tightness is 45%-55%, and weft yarn main burner pressure is 2.5×105Pa-3.0×105Pa, auxiliary nozzle exit pressure are 3.4 × 105Pa-3.8×105Pa, speed 550-600r/min.
6. the production method of environment-friendly waterproof combined type warm-keeping and life-saving fabric according to claim 3, it is characterised in that:It is described Thermal insulating and water-proof fabric side bed of material bristle process:It singes before bristle, singeing:Two forward one-reverse of burner, speed 95-110m/ Min, 1000-1100 DEG C of flame temperature;Using one in carbon sanding roller, Buddha's warrior attendant rubber (100-500 mesh), grinding material of nylon brush thread It plants or two kinds carries out twice sanding to fabric one side, generate short peach face so that fabric has physics waterproof effect, process conditions Speed 12-25m/min.
7. the production method of environment-friendly waterproof combined type warm-keeping and life-saving fabric according to claim 3, it is characterised in that:It is described Thermal insulating and water-proof fabric side bed of material arranging process:Dressing liquid is prepared in the following proportions, PE-100 wetting agents 0.5-1.5g/L, NT- The fluffy soft silicone oil 10-20g/L of X620 three-proof finishing agents 50-70g/L, GA-100.Thermal insulating and water-proof fabric is immersed in whole It manages in liquid, an immersing and rolling drying and shaping, pick-up:60-65%, 130 DEG C of drying, and baked 30 seconds at 150 DEG C so that waterproof is protected Warm fabrics precoat two sides is respectively formed continuous uniform membrane waterproofing.
8. the production method of environment-friendly waterproof combined type warm-keeping and life-saving fabric according to claim 3, it is characterised in that:It is described The thermal insulating and water-proof fabric side bed of material coats process:Using graphene oxide modified TPU laminated film as upper layer fabric, thermal insulating and water-proof is knitted Object plane material is lower layer's fabric, by the compound importing OP- of thermal insulating and water-proof fabric smooth surface graphene oxide modified TPU laminated film 450GS continous way fabric Adhesive machines, film thickness 0.010-0.012mm, speed 10-15cm/s, pressure 1.2-1.8MPa, temperature 130-150 DEG C of degree, finished product.
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112431024A (en) * 2020-10-26 2021-03-02 武汉纺织大学 Heat-insulating polyimide fabric and production method thereof
CN113292822A (en) * 2021-05-24 2021-08-24 安徽工程大学 Aramid fiber-epoxy resin based composite material and preparation method and application thereof

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5040193B1 (en) * 1970-12-26 1975-12-22
CN102071578A (en) * 2010-11-26 2011-05-25 安徽中天印染股份有限公司 Dyeing and finishing technology of nano multifunctional fabric
CN105155096A (en) * 2015-10-09 2015-12-16 江苏工程职业技术学院 Production technology of cool high-grade simulated down poplin bedding fabric
CN105199366A (en) * 2015-10-09 2015-12-30 昆山金有利新材料科技有限公司 Antistatic & heat-insulating polyurethane film and preparation method thereof
CN105231501A (en) * 2015-10-30 2016-01-13 丁宏利 A stiff, smooth and comfortable fabric and a production method thereof
CN105442151A (en) * 2016-01-06 2016-03-30 江苏工程职业技术学院 Novel ice sense cotton summer sleeping mat fabric and production method thereof
CN105463856A (en) * 2016-01-06 2016-04-06 江苏工程职业技术学院 Novel ultra-high molecular weight polyethylene woven fire-fighting hose and manufacturing method thereof

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5040193B1 (en) * 1970-12-26 1975-12-22
CN102071578A (en) * 2010-11-26 2011-05-25 安徽中天印染股份有限公司 Dyeing and finishing technology of nano multifunctional fabric
CN105155096A (en) * 2015-10-09 2015-12-16 江苏工程职业技术学院 Production technology of cool high-grade simulated down poplin bedding fabric
CN105199366A (en) * 2015-10-09 2015-12-30 昆山金有利新材料科技有限公司 Antistatic & heat-insulating polyurethane film and preparation method thereof
CN105231501A (en) * 2015-10-30 2016-01-13 丁宏利 A stiff, smooth and comfortable fabric and a production method thereof
CN105442151A (en) * 2016-01-06 2016-03-30 江苏工程职业技术学院 Novel ice sense cotton summer sleeping mat fabric and production method thereof
CN105463856A (en) * 2016-01-06 2016-04-06 江苏工程职业技术学院 Novel ultra-high molecular weight polyethylene woven fire-fighting hose and manufacturing method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112431024A (en) * 2020-10-26 2021-03-02 武汉纺织大学 Heat-insulating polyimide fabric and production method thereof
CN112431024B (en) * 2020-10-26 2022-12-09 武汉纺织大学 Heat-insulating polyimide fabric and production method thereof
CN113292822A (en) * 2021-05-24 2021-08-24 安徽工程大学 Aramid fiber-epoxy resin based composite material and preparation method and application thereof
CN113292822B (en) * 2021-05-24 2022-07-15 安徽工程大学 Aramid fiber-epoxy resin based composite material and preparation method and application thereof

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