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CN108785898B - Nose mask - Google Patents

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Publication number
CN108785898B
CN108785898B CN201710295261.4A CN201710295261A CN108785898B CN 108785898 B CN108785898 B CN 108785898B CN 201710295261 A CN201710295261 A CN 201710295261A CN 108785898 B CN108785898 B CN 108785898B
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CN
China
Prior art keywords
graphene
silica gel
filter
nose mask
nose
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Application number
CN201710295261.4A
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Chinese (zh)
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CN108785898A (en
Inventor
张金柱
刘顶
王海龙
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Shandong Shengquan New Material Co Ltd
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Shandong Shengquan New Material Co Ltd
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Priority to CN201710295261.4A priority Critical patent/CN108785898B/en
Publication of CN108785898A publication Critical patent/CN108785898A/en
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Publication of CN108785898B publication Critical patent/CN108785898B/en
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    • AHUMAN NECESSITIES
    • A62LIFE-SAVING; FIRE-FIGHTING
    • A62BDEVICES, APPARATUS OR METHODS FOR LIFE-SAVING
    • A62B23/00Filters for breathing-protection purposes
    • A62B23/06Nose filters

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  • Health & Medical Sciences (AREA)
  • Otolaryngology (AREA)
  • General Health & Medical Sciences (AREA)
  • Business, Economics & Management (AREA)
  • Emergency Management (AREA)
  • Respiratory Apparatuses And Protective Means (AREA)

Abstract

The invention relates to the field of articles for daily use, in particular to a nose mask, which comprises a nose mask body, a filtering device and a fixing belt for fixing the nose mask body; the nose cover body is provided with a cavity capable of accommodating a nose, and is provided with a one-way exhaling device; the filter device is provided with an air inlet and an air outlet, the air inlet is communicated with the outside, the air outlet is communicated with the cavity, and the cavity sucks the outside air through the filter device. According to the nose mask provided by the invention, inhaled external air is filtered by the filtering device, and exhaled air is directly exhausted, so that the whole device is simple and is beneficial to wide popularization and application.

Description

Nose mask
Technical Field
The invention relates to the field of articles for daily use, in particular to a nose mask.
Background
Air pollution generally refers to the phenomenon that certain substances are introduced into the atmosphere due to human activities or natural processes, exhibit a sufficient concentration, reach a sufficient time, and thus endanger the comfort, health, and welfare of the human body or the environment. The harm of atmospheric pollutants to human body is various, and is mainly represented by respiratory diseases and physiological dysfunction, and the diseases caused by irritation of the adhesive film tissues such as eyes, noses and the like, so that the nose mask is generated for coping with various damages caused by air pollution, namely the nose air purifier, and the product directly acts on the nose to provide respiratory protection and purify air.
The application number 201610536814.6 discloses an expanding type one-way filtering dust-haze-preventing nose mask, which comprises a head band (1), an air inlet pipe (3), a nose mask main body (8) and a filtering bag (11); a breathing one-way valve (9) is arranged on the nose mask main body (8), and is opened when the breathing one-way valve exhales and is closed when the breathing one-way valve inhales; the nose mask main body is communicated with the air inlet pipe through a nose mask quick connector (7), and the air inlet pipe is communicated with the filter bag through a filter bag quick connector (10); the filter bag is designed into the shapes of common clothes, caps, scarves, backpacks and the like, the outer layer is wrapped by a high-efficiency filter layer (13), and the inside of the filter bag is supported by a light framework (12) and forms an air flow channel. The device is relatively complex and has high manufacturing cost.
In view of this, the present invention has been made.
Disclosure of Invention
The invention aims to provide a nose mask which has excellent far infrared emission performance, promotes human microcirculation, has good air permeability, is comfortable to use and has the function of inhibiting bacterial growth by selecting specific materials; the air in the filtering device passes through the filter device in an S-shaped or spiral route, so that the filtering efficiency is high, and the space is saved; in addition, can hold multiple material in the filter equipment, better satisfy people's demand, whole nose cup simple structure, the cost is low, does benefit to popularization and application on a large scale.
In order to achieve the above object of the present invention, the following technical solutions are specifically adopted:
a nose mask, comprising a nose mask body, a filtering device and a fixing belt for fixing the nose mask body;
the nose cover body is provided with a cavity capable of accommodating a nose, and is provided with a one-way exhalation device;
the filter device is provided with an air inlet and an air outlet, the air inlet is communicated with the outside, the air outlet is communicated with the cavity, and the cavity sucks in the outside air through the filter device.
According to the nose mask provided by the invention, inhaled external air passes through the filtering device, exhaled air is directly exhausted, and the whole device is simple and is beneficial to wide popularization and application.
Further, the one-way exhale device comprises an exhale channel, wherein a breathing one-way valve is arranged in the exhale channel.
Preferably, the exhalation device is disposed on the mask body at a location corresponding to the location of the nostril.
Further, the filtering device includes a filtering tank and a container for containing the filtering tank.
Preferably, the filter tank is detachably connected to the receiving body, preferably in the form of a drawer.
Preferably, the air inlet of the filtering device is provided with holes at one end of the filtering tank far away from the cavity and the corresponding accommodating body, and the air outlet of the filtering device is provided with holes at one end of the filtering tank near to the cavity and the corresponding accommodating body.
Preferably, the filter tank comprises a bottom plate and a side wall, and at least one baffle is arranged in the filter tank to separate the filter tank and keep the baffles communicated.
Preferably, the baffle plate completely breaks the filter tank, and at least one vent hole is arranged on the baffle plate.
Preferably, the outside air passes through the filter device in an S-shaped passage or a spiral passage.
Preferably, the baffles extend from one side wall to the opposite side wall but are not connected with the side wall, the baffles arranged on the opposite side wall are staggered, and S-shaped passages are formed between the adjacent baffles.
Further, the baffles are arranged in parallel.
Preferably, the height of the baffle is flush with the side wall.
Preferably, the number of the baffles is 2-20, more preferably 4-10.
Preferably, the fixing straps are arranged at the left end and the right end of the nose mask body, and the filtering device is arranged between the nose mask body and the fixing straps.
Preferably, the two filtering devices are respectively arranged at two sides of the nose mask body.
Preferably, the nose mask body, the filtering device and the fastening strap are integrally designed.
Further, the filler material within the filter device comprises one or more of a filter material, a fragrance material, and a pharmaceutical composition.
Preferably, the filler material in the filter device comprises a filter material, a fragrance material, and a pharmaceutical ingredient.
Preferably, the filling materials in the filter device are filter materials, fragrance materials and medicine components from outside to inside.
Further, the inner surface of the nose mask body is provided with a fiber material layer.
Preferably, the fiber material layer is a graphene composite fiber layer.
Preferably, the nose mask body is made of graphene composite silica gel or bamboo charcoal silica gel.
Further, the nose mask body is made of graphene composite silica gel, and the graphene composite silica gel contains the following components: the coating comprises the following components in parts by weight: 50 to 70 parts of silica gel, 30 to 50 parts of white carbon black, 0.1 to 5.0 parts of graphene material, 0.5 to 5.0 parts of silicone oil and 0.2 to 2.0 parts of bridging agent.
According to the invention, the graphene material is creatively added into the silica gel product, all the components are cooperatively reinforced, and the prepared graphene composite silica gel has higher far infrared function, increases human microcirculation, has good air permeability, is comfortable to use, and has the function of inhibiting bacterial growth.
Preferably, the composition comprises the following components in parts by weight: 50-65 parts of silica gel, 35-45 parts of white carbon black, 0.5-4.0 parts of graphene material, 1-4 parts of silicone oil and 0.5-1.5 parts of bridging agent;
More preferably, the composition comprises the following components in parts by weight: 55-60 parts of silica gel, 38-42 parts of white carbon black, 1-3 parts of graphene material, 1.5-2.5 parts of silicone oil and 1-1.5 parts of bridging agent;
preferably, the graphene material comprises one or more of graphene, reduced graphene oxide, biomass graphene and derivatives thereof; the graphene material is preferably biomass graphene.
Preferably, the silicone oil comprises one or more than two of methyl silicone oil, ethyl silicone oil, vinyl silicone oil, methyl hydroxyl silicone oil, high hydrogen silicone oil, ethyl hydrogen silicone oil and hydroxyl hydrogen silicone oil;
preferably, the bridging agent comprises one or more than two of benzoyl peroxide, 2, 4-dichloro benzoyl peroxide, di-tert-butyl peroxide, diisopropylamine peroxide and tetraethoxysilane;
preferably, the silica gel is food grade silica gel;
preferably, the white carbon black is prepared by adopting a precipitation method.
Preferably, the graphene material comprises a graphene material with a particle size of less than 1 mu m and a graphene material with a particle size of 1-10 mu m;
the graphene material mainly exists in two forms in graphene composite silica gel, wherein the graphene material with the particle size smaller than 1 mu m is mainly combined with white carbon black in an adsorption mode; the graphene material with the particle size of 1-10 mu m mainly exists in a dispersed form in the graphene composite silica gel.
Preferably, the addition weight ratio of the graphene material with the particle size smaller than 1 μm to the graphene material with the particle size of 1-10 μm is 1:1-10, preferably 1:1-5, more preferably 1:2-3.
Preferably, the graphene composite silica gel is prepared by the following method: mixing the above materials, and vulcanizing.
The preparation method of the graphene composite silica gel provided by the invention is simple and feasible, and is easy to popularize and apply in a large range.
Preferably, the components are mixed specifically as follows:
(a) Adding a graphene material with the particle size smaller than 1 mu m into at least one of silica gel, a bridging agent, white carbon black and silicone oil, and then adding the rest components to mix to obtain a first mixture;
(b) And adding the graphene material with the particle size of 1-10 mu m into the first mixture, and uniformly mixing.
Preferably, step (a) is: firstly mixing white carbon black and a graphene material with the particle size smaller than 1 mu m, then adding silica gel, a bridging agent and silicone oil, and uniformly mixing to obtain the first mixture.
Preferably, in step (a), the graphene material having a particle size of less than 1 μm is mixed with the other components in batches, each time the mixture, the component containing the graphene material is not more than 10 times the mass of the component not containing the graphene material.
Compared with the prior art, the invention has the beneficial effects that:
(1) According to the nose mask provided by the invention, inhaled external air passes through the filtering device and passes through the filtering device in the S-shaped passage or the spiral passage, so that the passing route is prolonged, the filtering efficiency is high, exhaled air is directly discharged, and the whole device is simple and is beneficial to popularization and application in a large range.
(2) According to the filtering device provided by the invention, different substances can be placed in the grids among different baffles, so that different public demands can be better met.
(3) The nose mask provided by the invention has the advantages that the fiber material layer is filled in the cavity, the fiber material layer is particularly limited to the graphene composite fiber layer, the nose mask has the effects of keeping warm, absorbing water vapor and inhibiting bacteria, and the nose mask is more comfortable to wear.
(4) The nose mask is also limited to be made of graphene composite silica gel or bamboo charcoal silica gel, and the graphene composite silica gel and the bamboo charcoal silica gel have certain far infrared emission performance, promote human microcirculation, have good air permeability, are comfortable to use and have the function of inhibiting bacterial growth.
Drawings
In order to more clearly illustrate the embodiments of the present invention or the technical solutions in the prior art, the drawings that are needed in the description of the embodiments or the prior art will be briefly described, and it is obvious that the drawings in the description below are some embodiments of the present invention, and other drawings can be obtained according to the drawings without inventive effort for a person skilled in the art.
FIG. 1 is a perspective view of a nose mask according to an embodiment of the present invention;
FIG. 2 is a partially extracted perspective view of the filter tank of the nasal mask provided in example 2;
FIG. 3 is a top view of the filter tank in example 2;
FIG. 4 is a plan view of a baffle plate according to example 2;
FIG. 5 is a plan view of another baffle of example 2;
FIG. 6 is a top view of the filter tank in example 3;
FIG. 7 is a side perspective view of the nasal mask of example 3;
FIG. 8 is a perspective view of the reverse side of the nose mask of example 3;
reference numerals:
1-a nose mask body; 2-a filtering device; 21-a filter tank; 211-baffle plates; 3-fixing band.
Detailed Description
The following description of the embodiments of the present invention will be made apparent and fully in view of the accompanying drawings, in which some, but not all embodiments of the invention are shown. All other embodiments, which can be made by those skilled in the art based on the embodiments of the invention without making any inventive effort, are intended to be within the scope of the invention.
In the description of the present invention, it should be noted that the directions or positional relationships indicated by the terms "center", "upper", "lower", "left", "right", "vertical", "horizontal", "inner", "outer", etc. are based on the directions or positional relationships shown in the drawings, are merely for convenience of describing the present invention and simplifying the description, and do not indicate or imply that the devices or elements referred to must have a specific orientation, be configured and operated in a specific orientation, and thus should not be construed as limiting the present invention. Furthermore, the terms "first," "second," and "third" are used for descriptive purposes only and are not to be construed as indicating or implying relative importance.
In the description of the present invention, it should be noted that, unless explicitly specified and limited otherwise, the terms "mounted," "connected," and "connected" are to be construed broadly, and may be either fixedly connected, detachably connected, or integrally connected, for example; can be mechanically or electrically connected; can be directly connected or indirectly connected through an intermediate medium, and can be communication between two elements. The specific meaning of the above terms in the present invention will be understood in specific cases by those of ordinary skill in the art.
Fig. 1 is a perspective view of a nose mask according to an embodiment of the present invention. As shown in fig. 1, the nose mask provided by the invention comprises a nose mask body 1, a filtering device 2 and a fixing belt 3 for fixing the nose mask body;
the nose cover body 1 is provided with a cavity capable of accommodating a nose, and the nose cover body 1 is provided with a one-way exhalation device;
the filter device 2 has an air inlet communicating with the outside and an air outlet communicating with the cavity, which sucks in the outside air through the filter device 2.
The shape of the nose mask body 1 may be various, such as a rectangular parallelepiped, a square, an oval, various cartoon shapes, and the like.
The nose mask body 1 has a cavity capable of accommodating a nose, and the cavity is adapted to the structure of a nose of a person.
One end of the filter device 2 is communicated with the outside, and the other end is communicated with the cavity, so that the outside air enters the cavity through the filter device 2 and is further sucked.
The filtering device 2 can be arranged at any position around the nose mask body 1, and the air outlet of the filtering device 2 can be directly communicated with the cavity or communicated with the cavity through a pipe.
The filter device 2 may be provided with one or more, for example 1, 2, 3, 4, etc.
The filter device 2 has various shapes, and may be rectangular, square, cylindrical, spherical, elliptical, or some irregular shape.
The connection between the filtering device 2 and the nose mask body 1 can be in various forms, such as fixed connection and detachable connection.
The fixed connection may be a direct welding together of the filter device 2 and the mask body 1 or a direct integral design.
The detachable connection may be a threaded connection, a snap connection, a hinged connection, an adsorption connection, or the like.
The connection between the filter device 2 and the mask body 1 may be a point connection, a line connection, a surface connection, or the like, and the surface connection may be one surface connection, a plurality of surface connections, or the like. If the shape of the filtering device 2 is consistent with the shape of the periphery of the nose mask body 1, the filtering device 2 is directly sleeved on the periphery of the nose mask body 1, namely, the periphery of the nose mask body 1 is the filtering device 2, and the design is an example of connection of a plurality of surfaces.
In addition, the filter device 2 may be integrally designed, or may be detachably designed.
The material of the fixing band 3 may be various, such as elastic band, cotton tape, fiber band, knitting wool band, etc.
The fixing band 3 may be of various types, such as a one-piece type, a pull type, a lacing type, etc.
Preferably, the fixing straps 3 are disposed at the left and right ends of the nose mask body 1, and the filtering device 2 is disposed between the nose mask body 1 and the fixing straps 3.
Further, the filtering devices 2 are respectively arranged at two sides of the nose mask body 1.
The nose mask body 1 is provided with a one-way exhalation device for exhausting exhaled air. Preferably, the one-way exhalation device includes an exhalation passageway having a breathing one-way valve disposed therein. The device is simple and convenient to set and easy to implement.
Further, in order to facilitate the timely evacuation of exhaled air, exhalation means are provided on the mask body 1 at locations corresponding to the locations where the nostrils are accommodated.
According to the nose mask provided by the embodiment of the invention, the external air is inhaled through the filtering device 2, and the exhaled air is directly exhausted, so that the whole device is simple and is beneficial to popularization and application in a large range.
As shown in fig. 2, further, the filtering apparatus 2 includes a filtering tank 21 and a housing body housing the filtering tank 21. The shape of the filter device 2 may be various, such as a cylinder, a cuboid, a cube, an ellipsoid, a sphere, and other irregular patterns. Accordingly, the filter tank 21 and the receiving body have corresponding shapes.
In order to facilitate the replacement of the material therein, the filter tank 21 is preferably detachably connected to the receiving body. The detachable connection may be a snap connection, a threaded connection, a hinged connection, an adsorption connection, or the like. The adsorption connection may be by opposite pole attraction of the magnetic material, for example, an opposite pole material may be provided between one end of the filter tank 21 and the container.
Preferably, the filter tank 21 is connected to the housing body in a drawer-type manner. The connection is easy to operate and easy to manufacture.
Preferably, the air inlet of the filtering device 2 is provided with holes at one end of the filtering tank 21 far away from the cavity and the corresponding accommodating body, and the air outlet of the filtering device 2 is provided with holes at one end of the filtering tank 21 near to the cavity and the corresponding accommodating body.
Further, the filter tank 21 includes a bottom plate and side walls, and at least one baffle 211 is provided in the filter tank to separate the filter tank 21 and maintain communication between the baffles 211. For example, 1 baffle 211, 2 baffles 211 (as shown in fig. 3), 3 baffles 211, 4 baffles 211, 5 baffles 211, etc. may be provided in the filter tank 21; the communication between the retaining baffles 211 is mainly based on the filtering of the inhaled external air through the whole filtering tank 21; by providing baffles 211 to separate the filter cells 21 so that the filter cells 21 present different areas, different materials can be placed in the different areas and the inhaled air is disposed of through the different materials.
Wherein, the communication between the baffles 211 can be realized by arranging holes on the baffles 211, and preferably, the baffles 211 completely disconnect the filter tank 21, and at least one vent hole is arranged on the baffles 211. For example, one hole (as shown in fig. 4) or a plurality of holes (as shown in fig. 5) can be formed in the baffle 211, and mesh holes are formed in the baffle 211, so that the baffle 211 can be communicated quickly; a vent hole may be provided at one end of the baffle 211, so that air passes through the filtering device 2 in a nonlinear manner, thereby increasing the filtering effect of the air.
In order to increase the efficiency of the filtration and to save the volume of the filter device 2, it is preferred that the outside air passes in an S-shaped or spiral path in the filter device 2.
The outside air passes through the filter device 2 in different ways, and different baffle 211 forms can be correspondingly arranged.
Further, as shown in fig. 6, the baffles 211 extend from one side wall to the opposite side wall but are not connected with the opposite side wall, the baffles 211 arranged on the opposite side wall are staggered, and an S-shaped passage is formed between adjacent baffles 211.
The filter tank 21 is made of hard materials, so that the filter tank 21 and the accommodating body are convenient to seal, the drawing is convenient, and the cost is saved.
Further, the baffles 211 are arranged in parallel.
Preferably, the height of the baffle 211 is flush with the side wall, so that the baffle 211 is conveniently sealed in the accommodating body, and an S-shaped line is better realized when external air enters.
Preferably, the number of the baffles 211 is preferably 2 to 20, more preferably 4 to 10. For example, the number of baffles 211 may be 2, 3, 5, 6, 7, 8, 10, 12, 15, 18, 20, etc.
The number of baffles 211 is set according to the effect achieved by the material placed.
Further, the fixing straps 3 are disposed at the left and right ends of the nose mask body 1, and the filtering device 2 is disposed between the nose mask body 1 and the fixing straps 3.
As shown in fig. 7 and 8, the nose mask body 1, the filtering device 2 and the fixing band 3 are preferably integrally designed. The integrated design is convenient for preparing and ensuring the quality of the product and is more beautiful.
The filtering device 2 can be directly filled with different materials, and different substances can be placed in the space between the different baffles 211 so as to meet different public demands.
Further, the filler material in the filter device 2 includes any one or more of a filter material, a fragrance material, and a pharmaceutical ingredient. The filling material in the filter device 2 may be changed according to the use, for example, in a haze day, the filling material at least comprises the filter material, i.e. only the filter material can be contained; additional materials may be added, such as a number of pleasurable fragrance materials for better sensitivity; in addition, if diseased, some of the pharmaceutical ingredients may be placed; etc.
Preferably, the filler material in the filter device 2 comprises a filter material, a fragrance material, a pharmaceutical composition. The three components are filled simultaneously, when the nose mask is worn, the nose mask breathes cleaner air and simultaneously enjoys fragrance comfort, has the effect of treating diseases, and has better sensitivity.
In order to achieve better effect, more preferably, the filling materials in the filtering device 2 are filtering materials, fragrant materials and medicinal components from outside to inside.
Further, the surface of the cavity is provided with a fiber material layer. The cavity is filled with the fiber material layer, so that the heat preservation and water vapor adsorption effects are realized, and the wearing is more comfortable. The cavities may be specially provided with grooves for filling the layers of fibrous material.
Preferably, the fiber material layer is a graphene composite fiber layer.
The graphene composite fiber has excellent antibacterial performance, far infrared performance, excellent toughness, hot water resistance, antistatic performance and other performances, and the graphene composite fiber layer prepared from the material has excellent comprehensive performance.
Preferably, the nose mask body 1 is made of graphene composite silica gel or bamboo charcoal silica gel. The container of the filter device and the fixing belt 3 can also be graphene composite silica gel or bamboo charcoal silica gel.
The graphene composite silica gel and the bamboo charcoal silica gel have certain far infrared emission performance, promote human microcirculation, have good air permeability, are comfortable to use, and also have the function of inhibiting bacterial growth.
Further, the nose mask body 1 is made of graphene composite silica gel, and the graphene composite silica gel contains the following components: the coating comprises the following components in parts by weight: 50 to 70 parts of silica gel, 30 to 50 parts of white carbon black, 0.1 to 5.0 parts of graphene material, 0.5 to 5.0 parts of silicone oil and 0.2 to 2.0 parts of bridging agent.
According to the invention, the graphene material is creatively added into the silica gel product, all the components are cooperatively reinforced, and the prepared graphene composite silica gel has higher far infrared function, increases human microcirculation, has good air permeability, is comfortable to use, and has the function of inhibiting bacterial growth.
In order to further enhance the synergistic enhancement effect among the components, the prepared graphene composite silica gel has good performance, and preferably comprises the following components in parts by weight: 50-65 parts of silica gel, 35-45 parts of white carbon black, 0.5-4.0 parts of graphene material, 1-4 parts of silicone oil and 0.5-1.5 parts of bridging agent;
more preferably, the composition comprises the following components in parts by weight: 55-60 parts of silica gel, 38-42 parts of white carbon black, 1-3 parts of graphene material, 1.5-2.5 parts of silicone oil and 1-1.5 parts of bridging agent;
Preferably, the graphene material comprises one or more of graphene, reduced graphene oxide, biomass graphene and derivatives thereof; the graphene material is preferably biomass graphene.
Preferably, the silicone oil comprises one or more than two of methyl silicone oil, ethyl silicone oil, vinyl silicone oil, methyl hydroxyl silicone oil, high hydrogen silicone oil, ethyl hydrogen silicone oil and hydroxyl hydrogen silicone oil;
preferably, the bridging agent comprises one or more than two of benzoyl peroxide, 2, 4-dichloro benzoyl peroxide, di-tert-butyl peroxide, diisopropylamine peroxide and tetraethoxysilane;
preferably, the silica gel is food grade silica gel;
preferably, the white carbon black is prepared by adopting a precipitation method.
Preferably, the graphene material comprises a graphene material with a particle size of less than 1 mu m and a graphene material with a particle size of 1-10 mu m;
the graphene material mainly exists in two forms in graphene composite silica gel, wherein the graphene material with the particle size smaller than 1 mu m is mainly combined with white carbon black in an adsorption mode; the graphene material with the particle size of 1-10 mu m mainly exists in a dispersed form in the graphene composite silica gel.
Graphene materials with particle sizes less than 1 μm, i.e. D100, may be 0.1 μm, 0.2 μm, 0.3 μm, 0.5 μm, 0.6 μm, 0.8 μm, 0.9 μm, etc. Graphene materials having particle sizes of 1-10 μm, i.e., minimum particle size of 1 μm, maximum particle size of 2 μm, 3 μm, 5 μm, 6 μm, 7 μm, 8 μm, 9 μm, 10 μm, etc. may be used.
In order to achieve a better dispersion balance system, preferably, the addition weight ratio of the graphene material with the particle size smaller than 1 μm to the graphene material with the particle size of 1-10 μm is 1:1-10, preferably 1:1-5, more preferably 1:2-3.
The inventor finds that graphene is not easy to disperse uniformly in the silica gel system in the research and development process, and the smaller the particle size of the graphene is, the easier the graphene is agglomerated. In view of this, the inventors have found through a large number of experiments that graphene with a smaller particle size can be combined with white carbon black through adsorption, and then graphene with a larger particle size is redispersed, wherein the dispersibility of graphene is good, the obtained dispersion system is stable, and the performance of the obtained graphene composite silica gel is excellent.
Preferably, the graphene composite silica gel is prepared by the following method: mixing the above materials, and vulcanizing.
The preparation method of the graphene composite silica gel provided by the invention is simple and feasible, and is easy to popularize and apply in a large range.
Preferably, the components are mixed specifically as follows:
(a) Adding a graphene material with the particle size smaller than 1 mu m into at least one of silica gel, a bridging agent, white carbon black and silicone oil, and then adding the rest components to mix to obtain a first mixture;
(b) And adding the graphene material with the particle size of 1-10 mu m into the first mixture, and uniformly mixing.
The remaining components in step (a) are those for silica gel, bridging agent, white carbon black and silicone oil, such as: if the graphene material with the particle size smaller than 1 mu m is added into the silica gel, then the rest components are a bridging agent, white carbon black and silicone oil; if the graphene material with the particle size smaller than 1 mu m is added into the silica gel and the bridging agent, then the rest components are white carbon black and silicone oil; and so on.
According to the invention, the graphene material with small particle size is added firstly, and is easy to agglomerate and not easy to disperse, so that the graphene material with small particle size is mixed with any one or more of other components, the graphene material is partially dispersed firstly, then the other components are added, the graphene material is mainly combined with white carbon black in an adsorption mode, the graphene material in adsorption is in a relatively stable state, and a good environment is provided for adding large-particle-size graphene; at this time, large-particle-size graphene is added, and the large-particle-size graphene material mainly exists in a dispersed form in the graphene composite silica gel and is in a stable and balanced state. The graphene composite silica gel prepared finally is uniform and stable in dispersion, the graphene can fully play the functions of the graphene, and other components are matched, so that the prepared graphene composite silica gel is excellent in performance.
Preferably, step (a) is: firstly mixing white carbon black and a graphene material with the particle size smaller than 1 mu m, then adding silica gel, a bridging agent and silicone oil, and uniformly mixing to obtain the first mixture.
In the experimental process, it is unexpectedly found that graphene with small particle size and white carbon black directly have a certain adsorption force, and the graphene with small particle size can be adsorbed on the white carbon black, so that the white carbon black and the graphene with small particle size are firstly mixed and mutually adsorbed, namely, the graphene is pre-dispersed through the white carbon black, then silica gel, a bridging agent and silicone oil are added, and the three components can be added together or independently and not limited in sequence, so that the graphene and the white carbon black are dispersed together in a system to form a relatively uniform system. At the moment, the graphene with larger particle size is added, so that the graphene is easier to disperse, the method is simple and easy to implement, the graphene in the obtained product is uniformly dispersed, and the product performance is excellent.
Since graphene with small particle size is easy to agglomerate and not easy to disperse, preferably, in the step (a), the graphene material with particle size smaller than 1 μm is mixed with other components in batches, and the component containing the graphene material is not more than 10 times of the component without the graphene material in mass when mixed each time. Such as 1-fold, 2-fold, 3-fold, 5-fold, 7-fold, 8-fold, 10-fold, etc.
The structure of the nose mask provided by the present invention is exemplified below.
Example 1
As shown in fig. 1, a nose mask comprises a nose mask body 1, a filtering device 2 and a fixing band 3 for fixing the nose mask body 1;
the nose mask body 1 is provided with a cavity capable of accommodating a nose, and the surface of the cavity is provided with a fiber material layer, preferably a graphene composite fiber layer;
the nose mask body 1 is provided with a one-way exhalation device, the one-way exhalation device comprises an exhalation channel, a breathing one-way valve is arranged in the exhalation channel, and the exhalation device is arranged on the nose mask body 1 at a position corresponding to the nostril accommodating position;
the filtering device 2 is arranged on the nose mask body 1, one end, close to the nose mask body 1, is provided with an air outlet, the air outlet is communicated with the cavity, the filtering device 2 contacting the outside is provided with an air inlet, the air inlet is communicated with the outside, and the cavity sucks the outside air through the filtering device 2;
the filter device 2 is of an integrated design, that is, the filter device 2 is directly filled with a material, and the filled material can be any one or more of a filter material, a fragrance material and a medicine component;
the nose mask body 1 is made of graphene composite silica gel or bamboo charcoal silica gel, and the accommodating body of the filtering device and the fixing belt 3 can also be selected from graphene composite silica gel or bamboo charcoal silica gel; the graphene composite silica gel and the bamboo charcoal silica gel have certain far infrared emission performance, promote human microcirculation, have good air permeability, are comfortable to use, and also have the function of inhibiting bacterial growth.
The shape of the nose mask body 1 can be various, such as cuboid, cube, ellipse, various cartoon shapes and the like;
the filtering device 2 can be arranged at any position around the nose mask body 1, and the air outlet of the filtering device 2 can be directly communicated with the cavity or communicated with the cavity through a pipe;
the filter device 2 may be provided with one or more, such as 1, 2, 3, 4, etc.;
the filter device 2 has various shapes, such as cuboid, cube, cylinder, sphere, elliptic sphere and some irregular shapes;
the connection between the filtering device 2 and the nose mask body 1 can be in various forms, such as fixed connection and detachable connection; the fixed connection can be that the filtering device 2 and the nose mask body 1 are directly welded together or are directly designed in an integral way; the detachable connection can be a threaded connection, a snap connection, a hinge connection, an adsorption connection, etc.; the connection between the filter device 2 and the mask body 1 may be a point connection, a line connection, a surface connection, or the like, and the surface connection may be one surface connection, a plurality of surface connections, or the like.
The material of the fixing band 3 can be various, such as elastic band, cotton tape, fiber band, knitting wool band, etc.; the fixing band 3 may be of various types, such as a one-piece type, a pull type, a lacing type, etc.
Example 2
As shown in fig. 1, a nose mask comprises a nose mask body 1, a filtering device 2 and a fixing band 3 for fixing the nose mask body 1;
the nose mask body 1 is provided with a cavity capable of accommodating a nose, and the surface of the cavity is provided with a fiber material layer, preferably a graphene composite fiber layer;
the nose mask body 1 is provided with a one-way exhalation device, the one-way exhalation device comprises an exhalation channel, a breathing one-way valve is arranged in the exhalation channel, and the exhalation device is arranged on the nose mask body 1 at a position corresponding to the nostril accommodating position;
the filtering device 2 is arranged on the nose mask body 1, one end, close to the nose mask body 1, is provided with an air outlet, the air outlet is communicated with the cavity, the filtering device 2 contacting the outside is provided with an air inlet, the air inlet is communicated with the outside, and the cavity sucks the outside air through the filtering device 2;
as shown in fig. 2, the filter device 2 includes a filter tank 21 and a housing body housing the filter tank, and the filter tank 21 is connected to the housing body in a drawing manner;
as shown in fig. 3, the filter tank 21 comprises a bottom plate and side walls, and 2 baffles 211 are arranged in the filter tank 21 to separate the filter tank, wherein the baffles 211 can be equally distributed or unevenly distributed; the baffle 211 is provided with one or more holes, the positions of the holes are arbitrary, the baffle 211 is provided with one hole as shown in fig. 4, the baffle 211 is provided with a plurality of holes as shown in fig. 5, and the holes are communicated with each other;
The space between the baffles 211 is filled with any one or more of filtering material, fragrant material and medicine component, preferably, three materials are contained, and the space between the two baffles contains one material, and the three materials are in the order of medicine component, fragrant material and filtering material when seen from the cavity outwards;
the air inlet of the filter device 2 is provided with holes on one end of the filter tank 21 far away from the cavity and the corresponding accommodating body, and the air outlet of the filter device 2 is provided with holes on one end of the filter tank 211 near the cavity and the corresponding accommodating body;
the nose mask body 1 is made of graphene composite silica gel or bamboo charcoal silica gel, and the accommodating body of the filtering device 2 and the fixing belt 3 can also be selected from graphene composite silica gel or bamboo charcoal silica gel; the graphene composite silica gel and the bamboo charcoal silica gel have certain far infrared emission performance, promote human microcirculation, have good air permeability, are comfortable to use, and also have the function of inhibiting bacterial growth.
The shape of the nose mask body 1 can be various, such as cuboid, cube, ellipse, various cartoon shapes and the like;
the filtering device 2 can be arranged at any position around the nose mask body 1, and the air outlet of the filtering device 2 can be directly communicated with the cavity or communicated with the cavity through a pipe;
The filter device 2 may be provided with one or more, such as 1, 2, 3, 4, etc.;
the filter device 2 has various shapes, such as cuboid, cube, cylinder, sphere, elliptic sphere and some irregular shapes;
the connection between the filtering device 2 and the nose mask body 1 can be in various forms, such as fixed connection and detachable connection; the fixed connection can be that the filtering device 2 and the nose mask body 1 are directly welded together or are directly designed in an integral way; the detachable connection can be a threaded connection, a snap connection, a hinge connection, an adsorption connection, etc.; the connection between the filter device 2 and the mask body 1 may be a point connection, a line connection, a surface connection, or the like, and the surface connection may be one surface connection, a plurality of surface connections, or the like.
The material of the fixing band 3 can be various, such as elastic band, cotton tape, fiber band, knitting wool band, etc.; the fixing band 3 may be of various types, such as a one-piece type, a pull type, a lacing type, etc.
Example 3
As shown in fig. 7, a nose mask includes a nose mask body 1, a filtering device 2, and a fixing band 3 for fixing the nose mask body 1;
The nose mask body 1 is provided with a cavity capable of accommodating a nose, and the surface of the cavity is provided with a fiber material layer, preferably a graphene composite fiber layer;
the nose mask body 1 is provided with a one-way exhalation device, the one-way exhalation device comprises an exhalation channel, a breathing one-way valve is arranged in the exhalation channel, and the exhalation device is arranged on the nose mask body 1 at a position corresponding to the nostril accommodating position;
the filtering device 2 is arranged on the nose mask body 1, one end, close to the nose mask body 1, is provided with an air outlet, the air outlet is communicated with the cavity, the filtering device 2 contacting the outside is provided with an air inlet, the air inlet is communicated with the outside, and the cavity sucks the outside air through the filtering device 2;
as shown in fig. 2, the filter device 2 comprises a filter tank 21 and a container for containing the filter tank 21, wherein the filter tank 21 is connected with the container in a drawing manner;
as shown in fig. 6, the filter tank 21 comprises a bottom plate and side walls, wherein the baffle plates 211 extend from one side wall to the opposite side wall direction but are not connected with the opposite side wall direction, the baffle plates 211 arranged on the opposite side wall are staggered, S-shaped passages are formed between the adjacent baffle plates 211, the baffle plates 211 are arranged in parallel, and the height of the baffle plates 211 is parallel to the side wall;
the space between the baffles 211 is filled with any one or more of filter material, flavoring material, and medicinal component;
The two filtering devices 2 are respectively arranged at two sides of the nose mask body;
the air inlet of the filtering device 2 is provided with holes on one end of the filtering tank 21 far away from the cavity and the corresponding accommodating body, and the air outlet of the filtering device 2 is provided with holes on one end of the filtering tank 21 near to the cavity and the corresponding accommodating body;
as shown in fig. 7 and 8, the nose mask body 1, the filtering device 2 and the fixing band 3 are integrally designed;
the nose mask body 1 is made of graphene composite silica gel or bamboo charcoal silica gel, and the accommodating body of the filtering device 2 and the fixing belt 3 can also be selected from graphene composite silica gel or bamboo charcoal silica gel; the graphene composite silica gel and the bamboo charcoal silica gel have certain far infrared emission performance, promote human microcirculation, have good air permeability, are comfortable to use, and also have the function of inhibiting bacterial growth.
The shape of the nose mask body 1 can be various, such as cuboid, cube, ellipse, various cartoon shapes and the like;
the filtering device 2 can be arranged at any position around the nose mask body 1, and the air outlet of the filtering device 2 can be directly communicated with the cavity or communicated with the cavity through a pipe;
the filter device 2 has various shapes, such as cuboid, cube, cylinder, sphere, elliptic sphere and some irregular shapes;
The connection between the filtering device 2 and the nose mask body 1 can be in various forms, such as fixed connection and detachable connection; the fixed connection can be that the filtering device 2 and the nose mask body 1 are directly welded together or are directly designed in an integral way; the detachable connection can be a threaded connection, a snap connection, a hinge connection, an adsorption connection, etc.; the connection between the filter device 2 and the mask body 1 may be a point connection, a line connection, a surface connection, or the like, and the surface connection may be one surface connection, a plurality of surface connections, or the like.
The material of the fixing band 3 can be various, such as elastic band, cotton tape, fiber band, knitting wool band, etc.; the fixing band 3 may be of various types, such as a one-piece type, a pull type, a lacing type, etc.
Example 4
Except for the filter tank 21, the nose mask of the present invention is obtained by preparing the nose mask body 1 by vulcanizing the material, designing a mold according to the structure of the nose mask shown in fig. 1-2 and fig. 7-8, preparing the filter tank 21 from plastic according to fig. 6, and then assembling. The preparation of the graphene composite silica gel is illustrated in detail below.
Experimental example 1
The following components are taken: 60 parts of food-grade silica gel, 40 parts of white carbon black prepared by precipitation, 3 parts of biomass graphene (particle size d100=0.5 mu m 0.5 parts, particle size 1-5 mu m 2.5 parts), 2 parts of methyl silicone oil and 1 part of 2, 4-dichloro benzoyl peroxide;
The components were mixed in the following manner:
group 1: directly mixing the components;
group 2: (a) Mixing biomass graphene with the particle size d100=0.5 mu m with silica gel powder, adding a bridging agent, white carbon black and silicone oil, and uniformly mixing to obtain a first mixture;
(b) And adding the biomass graphene with the particle size of 1-5 mu m into the first mixture, and uniformly mixing.
Group 3: (a) Mixing biomass graphene with the particle size d100=0.5 mu m with white carbon black, adding a bridging agent, silica gel and silicone oil, and uniformly mixing to obtain a first mixture;
(b) And adding the biomass graphene with the particle size of 1-5 mu m into the first mixture, and uniformly mixing.
Group 4: (a) Mixing biomass graphene with the particle size d100=0.5 mu m with a bridging agent, adding white carbon black, silica gel and silicone oil, and uniformly mixing to obtain a first mixture;
(b) And adding the biomass graphene with the particle size of 1-5 mu m into the first mixture, and uniformly mixing.
Group 5: (a) Mixing biomass graphene with the particle size d100=0.5 mu m with silicone oil, adding white carbon black, silica gel and a bridging agent, and uniformly mixing to obtain a first mixture;
(b) And adding the biomass graphene with the particle size of 1-5 mu m into the first mixture, and uniformly mixing.
Group 6: (a) Mixing biomass graphene with the particle size d100=0.5 mu m with a bridging agent and white carbon black, adding silica gel and silicone oil, and uniformly mixing to obtain a first mixture;
(b) And adding the biomass graphene with the particle size of 1-5 mu m into the first mixture, and uniformly mixing.
Group 7: (a) Mixing biomass graphene with the particle size d100=0.5 mu m with silicone oil and a bridging agent, adding white carbon black and silica gel, and uniformly mixing to obtain a first mixture;
(b) And adding the biomass graphene with the particle size of 1-5 mu m into the first mixture, and uniformly mixing.
Group 8: (a) Mixing biomass graphene with the particle size d100=0.5 mu m with white carbon black and silicone oil, adding silica gel and a bridging agent, and uniformly mixing to obtain a first mixture;
(b) And adding the biomass graphene with the particle size of 1-5 mu m into the first mixture, and uniformly mixing.
Group 9: (a) Mixing biomass graphene with the particle size d100=0.5 mu m with white carbon black in batches, adding a bridging agent, silica gel and silicone oil in batches, and uniformly mixing a component containing a graphene material with the mass 10 times of that of a component not containing the graphene material when mixing each time to obtain a first mixture;
(b) And adding the biomass graphene with the particle size of 1-5 mu m into the first mixture, and uniformly mixing.
Group 10: (a) Mixing biomass graphene with the particle size d100=0.5 mu m with silicone oil in batches, adding a bridging agent, silica gel and white carbon black in batches, wherein the mass of the graphene-containing material component is 10 times that of the graphene-free material component during each mixing, and uniformly mixing to obtain a first mixture;
(b) And adding the biomass graphene with the particle size of 1-5 mu m into the first mixture, and uniformly mixing.
And adding the mixture obtained after mixing into a mould, and vulcanizing to obtain the nose mask main body.
Observing the uniformity of the dispersion of each component of the prepared nasal mask main body under a microscope, and sequencing the components, wherein the sequence from the good uniformity dispersion to the poor uniformity is as follows: group 9, group 10, group 3, group 6, group 8, group 5, group 7, group 4, group 2, group 1.
In addition, changing the type of graphene material such as using one or more of commercially available graphene, reduced graphene oxide, graphene oxide and derivatives thereof gives substantially the same results as described above;
changing the kind of the silicone oil such as ethyl silicone oil, vinyl silicone oil, methyl hydroxyl silicone oil, high hydrogen silicone oil, ethyl hydrogen silicone oil, hydroxyl hydrogen silicone oil or a mixture of two or more thereof gives substantially the same results as described above;
Changing the kind of the bridging agent such as benzoyl oxide, 2, 4-dichlorobenzoyl peroxide, di-t-butyl peroxide, diisopropylamine peroxide, or a mixture of two or more of ethyl orthosilicate gives substantially the same results as described above.
Experimental example 2
The following components are taken: 50 parts of food-grade silica gel, 30 parts of white carbon black prepared by adopting a precipitation method, 0.1 part of reduced graphene oxide (with the particle size d100=0.8 mu m 0.05 part and the particle size of 1-6 mu m 0.05 part), 0.5 part of vinyl silicone oil and 0.2 part of di-tert-butyl peroxide;
(a) Mixing reduced graphene oxide with the particle size d100=0.8 mu m with white carbon black in batches, adding a bridging agent of di-tert-butyl peroxide, silica gel and vinyl silicone oil in batches, and uniformly mixing the components containing the graphene material with the mass which is 9 times that of the components not containing the graphene material when mixing each time to obtain a first mixture;
(b) Adding the reduced graphene oxide with the particle size of 1-6 mu m into the first mixture, and uniformly mixing;
(c) And putting the obtained mixture into a mould, and vulcanizing to obtain the graphene composite silica gel nose mask main body.
Experimental example 3
A graphene composite silica gel is prepared by the following steps:
the following components are taken: 55 parts of food-grade silica gel, 35 parts of white carbon black prepared by adopting a precipitation method, 0.5 part of graphene oxide (with the particle size d100=0.3 mu m 0.1 part and the particle size of 1-8 mu m 0.4 part), 1 part of ethyl hydrogen silicone oil and 0.5 part of tetraethoxysilane;
(a) Mixing graphene oxide with the particle size d100=0.3 mu m with white carbon black in batches, adding tetraethoxysilane, silica gel and ethyl hydrogen-containing silicone oil in batches, and uniformly mixing the components containing the graphene material with the mass which is 8 times of that of the components not containing the graphene material when mixing each time to obtain a first mixture;
(b) Adding graphene oxide with the particle size of 1-8 mu m into the first mixture, and uniformly mixing;
(c) And putting the obtained mixture into a mould, and vulcanizing to obtain the graphene composite silica gel nose mask main body.
Experimental example 4
A graphene composite silica gel is prepared by the following steps:
the following components are taken: 55 parts of food-grade silica gel, 38 parts of white carbon black prepared by adopting a precipitation method, 1 part of graphene oxide (with the particle size d100=0.5 mu m 0.1 part and the particle size of 1-10 mu m 0.9 part), 1.5 parts of methyl vinyl silicone oil and 1 part of bridge girder erection agent diisopropylamine peroxide;
(a) Mixing graphene oxide with the particle size d100=0.5 mu m with white carbon black in batches, adding a bridging agent of diisopropylamine peroxide, silica gel and methyl vinyl silicone oil in batches, and uniformly mixing the components containing the graphene material with the mass which is 2 times of that of the components not containing the graphene material when mixing each time to obtain a first mixture;
(b) Adding graphene oxide with the particle size of 1-10 mu m into the first mixture, and uniformly mixing;
(c) And putting the obtained mixture into a mould, and vulcanizing to obtain the graphene composite silica gel nose mask main body.
Experimental example 5
A graphene composite silica gel is prepared by the following steps:
the following components are taken: 60 parts of food-grade silica gel, 42 parts of white carbon black prepared by adopting a precipitation method, 3 parts of biomass graphene (with the particle size d100=0.5 mu m 1 part and the particle size of 1-2 mu m 2 parts), 2.5 parts of methyl hydroxyl silicone oil and 1.5 parts of a bridging agent di-tert-butyl peroxide;
(a) Mixing biomass graphene with the particle size d100=0.5 mu m with silicone oil in batches, adding a bridging agent, silica gel and white carbon black in batches, wherein the mass of the graphene-containing material component is 10 times that of the graphene-free material component during each mixing, and uniformly mixing to obtain a first mixture;
(b) Adding biomass graphene with the particle size of 1-2 mu m into the first mixture, and uniformly mixing;
(c) And putting the obtained mixture into a mould, and vulcanizing to obtain the graphene composite silica gel nose mask main body.
Experimental example 6
A graphene composite silica gel is prepared by the following steps:
the following components are taken: 65 parts of food-grade silica gel, 45 parts of white carbon black prepared by adopting a precipitation method, 4 parts of biomass graphene (with the particle size d100=0.2 mu m 1 part and the particle size of 1-2 mu m 3 part), 4 parts of high-hydrogen silicone oil and 1 part of bridge-erecting agent benzoyl peroxide;
(a) Mixing biomass graphene with the particle size d100=0.2 mu m with silicone oil in batches, adding a bridging agent, silica gel and white carbon black in batches, wherein the mass of the graphene-containing material component is 10 times that of the graphene-free material component during each mixing, and uniformly mixing to obtain a first mixture;
(b) Adding biomass graphene with the particle size of 1-2 mu m into the first mixture, and uniformly mixing;
(c) And putting the obtained mixture into a mould, and vulcanizing to obtain the graphene composite silica gel nose mask main body.
Experimental example 7
A graphene composite silica gel is prepared by the following steps:
the following components are taken: according to the weight parts, 70 parts of food-grade silica gel, 50 parts of white carbon black prepared by adopting a precipitation method, 5 parts of biomass graphene (with the particle size d100=0.2 mu m 1 part and the particle size of 1-2 mu m 4 part), 5 parts of ethyl silicone oil and 2 parts of bridging agent 2, 4-dichloro benzoyl peroxide;
(a) Mixing biomass graphene with the particle size d100=0.2 mu m with white carbon black in batches, adding a bridging agent, silica gel and ethyl silicone oil in batches, and uniformly mixing a component containing a graphene material with the mass 10 times of that of a component not containing the graphene material when mixing each time to obtain a first mixture;
(b) Adding biomass graphene with the particle size of 1-2 mu m into the first mixture, and uniformly mixing;
(c) And putting the obtained mixture into a mould, and vulcanizing to obtain the graphene composite silica gel nose mask main body.
Experimental example 8
A graphene composite silica gel is prepared by the following steps:
the following components are taken: 60 parts of food-grade silica gel, 40 parts of white carbon black prepared by adopting a precipitation method, 1.1 parts of biomass graphene (with the particle size d100=0.5 mu m 0.1 part and the particle size of 1-5 mu m 1 part), 2 parts of methyl hydroxyl silicone oil, 0.5 part of 2, 4-dichloro benzoyl peroxide and 0.5 part of di-tert-butyl peroxide;
(a) Mixing biomass graphene with the particle size d100=0.5 mu m with white carbon black in batches, adding a bridging agent, silica gel and silicone oil in batches, and uniformly mixing a component containing a graphene material with the mass 10 times of that of a component not containing the graphene material when mixing each time to obtain a first mixture;
(b) Adding biomass graphene with the particle size of 1-5 mu m into the first mixture, and uniformly mixing;
(c) And putting the obtained mixture into a mould, and vulcanizing to obtain the graphene composite silica gel nose mask main body.
Experimental example 9
A graphene composite silica gel is prepared by the following steps:
the following components are taken: 60 parts of food-grade silica gel, 42 parts of white carbon black prepared by adopting a precipitation method, 4 parts of biomass graphene (with the particle size d100=0.5 mu m 1 part and the particle size of 1-6 mu m 3 part), 0.5 part of alkenyl silicone oil, 0.5 part of methyl vinyl silicone oil, 0.5 part of methyl hydroxyl silicone oil, 0.5 part of high-hydrogen silicone oil, 0.5 part of ethyl hydrogen silicone oil, 0.5 part of di-tert-butyl peroxide, 0.5 part of diisopropylamine peroxide and 0.5 part of ethyl orthosilicate;
(a) Mixing biomass graphene with the particle size d100=0.5 mu m with silicone oil in batches, adding a bridging agent, silica gel and white carbon black in batches, wherein the mass of the graphene-containing material component is 10 times that of the graphene-free material component during each mixing, and uniformly mixing to obtain a first mixture;
(b) Adding biomass graphene with the particle size of 1-6 mu m into the first mixture, and uniformly mixing;
(c) And putting the obtained mixture into a mould, and vulcanizing to obtain the graphene composite silica gel nose mask main body.
Experimental example 10
A graphene composite silica gel is prepared by the following steps:
the following components are taken: 60 parts of food-grade silica gel, 42 parts of white carbon black prepared by adopting a precipitation method, 3 parts of biomass graphene (particle size of 1-5 mu m), 1.5 parts of methyl hydroxyl silicone oil, 1 part of ethyl hydrogen silicone oil, 0.5 part of 2, 4-dichloro benzoyl peroxide, 0.5 part of di-tert-butyl peroxide and 0.5 part of diisopropylamine peroxide;
(a) Adding biomass graphene into a mixed solution of methyl hydroxyl silicone oil and ethyl hydrogen-containing silicone oil, and then respectively adding a bridging agent, silica gel and white carbon black to obtain a mixture;
(b) And putting the obtained mixture into a mould, and vulcanizing to obtain the graphene composite silica gel nose mask main body.
Experimental example 11
The nose mask main body is prepared by taking bamboo charcoal silica gel as a material.
Control group
The main body of the nose mask is made of commercially available silica gel.
And (3) temperature rising performance test:
test example 1 group 9 and test examples 2 to 11 (corresponding groups 1 to 11) and control groups were subjected to temperature rise test, specifically with reference to GB/T30127-2013. The obtained detection results are shown in Table 1.
TABLE 1 results of temperature rise test
As can be seen from Table 1, the temperature rising speed of the nose mask body prepared from the graphene composite silica gel provided by the invention is obviously higher than that of the existing silica gel, and the bamboo charcoal silica gel has a basically consistent effect.
Antibacterial performance test: the nasal mask bodies prepared in the experimental example 1, the experimental example 9, the experimental examples 2 to 11 and the control group were tested for bacteriostasis, and the test was specifically performed with reference to the GB/T20944.2-2007 standard.
The antibacterial rate of the nose mask main body prepared in the experimental example 1, the experimental example 9 and the experimental examples 2-11 on escherichia coli, staphylococcus aureus and candida albicans is more than 95 percent; the control group has no bacteriostasis, which indicates that the nose mask main body prepared from the graphene composite silica gel or the bamboo charcoal silica gel has excellent bacteriostasis performance.
Customer sensitivity evaluation: the nose masks obtained in experimental example 1, group 9, and experimental examples 2 to 11 and the control group were subjected to user experience evaluation by adding a filter tank (containing a filter material). Each group of users is 100, the age of the crowd is 25-60 years old, each group of users respectively uses the nose masks of the embodiment and the control group, and the corresponding embodiments are groups 1-11 respectively. And scoring the comfort and the smoothness of breathing when the user is comprehensively wearing after the experience is finished, and obtaining an average value to obtain a final score. The statistical results are shown in Table 3.
TABLE 3 statistical results
The nose mask prepared by the embodiment of the invention is prepared from graphene composite silica gel or bamboo charcoal silica gel, has excellent far infrared emission performance, promotes human microcirculation, has good air permeability, is comfortable to use, and has the function of inhibiting bacterial growth; the air in the filtering device 2 passes through the S-shaped route, so that the filtering efficiency is high, and the space is saved; in addition, can hold multiple material in the filter equipment 2, better satisfy people's demand, whole nose cup simple structure, the cost is low, does benefit to popularization and application on a large scale.
While particular embodiments of the present invention have been illustrated and described, it will be appreciated that various other changes and modifications can be made without departing from the spirit and scope of the invention. It is therefore intended to cover in the appended claims all such changes and modifications that are within the scope of this invention.

Claims (10)

1. A nose mask, which is characterized by comprising a nose mask body, a filtering device and a fixing belt for fixing the nose mask body;
the nose cover body is provided with a cavity capable of accommodating a nose, and is provided with a one-way exhalation device;
the filter device is provided with an air inlet and an air outlet, the air inlet is communicated with the outside, the air outlet is communicated with the cavity, and the cavity sucks outside air through the filter device;
The one-way exhalant device comprises an exhalant channel, and a breathing one-way valve is arranged in the exhalant channel; the exhaling device is arranged on the nose mask body at a position corresponding to the nostril;
the filter device comprises a filter tank and a containing body for containing the filter tank; the filter tank is detachably connected with the accommodating body;
the air inlet of the filtering device is provided with holes on one end of the filtering groove far away from the cavity and the corresponding accommodating body, and the air outlet of the filtering device is provided with holes on one end of the filtering groove near to the cavity and the corresponding accommodating body;
the filter tank comprises a bottom plate and side walls, and at least one baffle plate is arranged in the filter tank to separate the filter tank and keep the baffle plates communicated with each other;
the baffles extend from one side wall to the opposite side wall direction but are not connected with the side wall, the baffles arranged on the opposite side wall are staggered, and S-shaped passages are formed between the adjacent baffles;
the inner surface of the nose mask body is provided with a fiber material layer, and the fiber material layer is a graphene composite fiber layer; the nose mask body is made of graphene composite silica gel or bamboo charcoal composite silica gel.
2. The mask of claim 1 wherein the filter trough is connected to the containing body in a pull-out manner.
3. The mask of claim 1 wherein the baffles are disposed in parallel relation to each other; the number of the baffles is 2-20.
4. A nasal mask according to claim 3 wherein the height of the baffle is flush with the side wall; the number of the baffles is 4-10.
5. The nasal mask according to claim 1, wherein the fixing bands are provided at both left and right ends of the mask body, and the filtering device is located between the mask body and the fixing bands;
the number of the filtering devices is two.
6. The mask of claim 1, wherein the filtering means are provided on both sides of the mask body, respectively.
7. The nasal mask of claim 1, wherein the mask body, the filtering device and the fastening strap are integrally designed.
8. The nasal mask of claim 1, wherein the filler material within the filter device comprises any one or more of a filter material, a fragrance material, a pharmaceutical composition.
9. The nasal mask of claim 1, wherein the filler material within the filter device comprises a filter material, a flavoring material, a pharmaceutical composition.
10. The nasal mask of claim 1, wherein the filler material in the filter device is in the order of filter material, flavor material, pharmaceutical composition from the outside to the inside.
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CN110101499A (en) * 2019-04-30 2019-08-09 华南理工大学 A kind of intelligent heating nose cup

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2417304A1 (en) * 1978-02-20 1979-09-14 Bourdier Ste Civile Etu Rech Dust filter for nasal breathing - has flexible body inserted into nostril with air passing over dust trapping coated spiral wound fibres
CN103585724A (en) * 2012-08-18 2014-02-19 魏婷婷 Breathing filter for nose
CN104338264A (en) * 2014-11-24 2015-02-11 孝感市奇思妙想文化传媒有限公司 Nose mask filtering device
CN204428650U (en) * 2014-12-24 2015-07-01 徐炎业 A kind of nose cup

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009022004A2 (en) * 2007-08-14 2009-02-19 Plastiflex Belgium A respiratory system
NZ630757A (en) * 2014-08-01 2016-03-31 Resmed Ltd Self-optimising respiratory therapy system

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2417304A1 (en) * 1978-02-20 1979-09-14 Bourdier Ste Civile Etu Rech Dust filter for nasal breathing - has flexible body inserted into nostril with air passing over dust trapping coated spiral wound fibres
CN103585724A (en) * 2012-08-18 2014-02-19 魏婷婷 Breathing filter for nose
CN104338264A (en) * 2014-11-24 2015-02-11 孝感市奇思妙想文化传媒有限公司 Nose mask filtering device
CN204428650U (en) * 2014-12-24 2015-07-01 徐炎业 A kind of nose cup

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