CN108755132A - A kind of antibacterial plant fibrous material - Google Patents
A kind of antibacterial plant fibrous material Download PDFInfo
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- CN108755132A CN108755132A CN201810632342.3A CN201810632342A CN108755132A CN 108755132 A CN108755132 A CN 108755132A CN 201810632342 A CN201810632342 A CN 201810632342A CN 108755132 A CN108755132 A CN 108755132A
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- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 31
- 239000002657 fibrous material Substances 0.000 title claims abstract description 24
- 239000000835 fiber Substances 0.000 claims abstract description 38
- 230000002421 anti-septic effect Effects 0.000 claims abstract description 15
- 230000004913 activation Effects 0.000 claims abstract description 12
- 239000012190 activator Substances 0.000 claims abstract description 11
- 238000002360 preparation method Methods 0.000 claims abstract description 11
- 239000004744 fabric Substances 0.000 claims abstract description 9
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 claims abstract description 6
- 238000010438 heat treatment Methods 0.000 claims abstract description 6
- 230000010355 oscillation Effects 0.000 claims abstract description 6
- 235000010413 sodium alginate Nutrition 0.000 claims abstract description 6
- 229940005550 sodium alginate Drugs 0.000 claims abstract description 6
- 239000000661 sodium alginate Substances 0.000 claims abstract description 6
- 238000010792 warming Methods 0.000 claims abstract description 6
- 241000196324 Embryophyta Species 0.000 claims description 52
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 18
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 12
- PGMYKACGEOXYJE-UHFFFAOYSA-N pentyl acetate Chemical compound CCCCCOC(C)=O PGMYKACGEOXYJE-UHFFFAOYSA-N 0.000 claims description 12
- 239000003814 drug Substances 0.000 claims description 11
- 239000000706 filtrate Substances 0.000 claims description 10
- 239000000843 powder Substances 0.000 claims description 10
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 6
- 240000001851 Artemisia dracunculus Species 0.000 claims description 6
- 241000143476 Bidens Species 0.000 claims description 6
- 235000010662 Bidens pilosa Nutrition 0.000 claims description 6
- 241000218170 Coriaria Species 0.000 claims description 6
- 241000790646 Cotinis Species 0.000 claims description 6
- 241000218671 Ephedra Species 0.000 claims description 6
- 235000009140 Gnetum buchholzianum Nutrition 0.000 claims description 6
- 244000130592 Hibiscus syriacus Species 0.000 claims description 6
- 235000018081 Hibiscus syriacus Nutrition 0.000 claims description 6
- 244000219416 Hypericum japonicum Species 0.000 claims description 6
- 240000002262 Litsea cubeba Species 0.000 claims description 6
- 235000012854 Litsea cubeba Nutrition 0.000 claims description 6
- 244000302909 Piper aduncum Species 0.000 claims description 6
- 235000016761 Piper aduncum Nutrition 0.000 claims description 6
- 240000003731 Piper cubeba Species 0.000 claims description 6
- 235000002711 Piper cubeba Nutrition 0.000 claims description 6
- 241000610442 Schima superba Species 0.000 claims description 6
- 235000011341 Sideroxylon dulcificum Nutrition 0.000 claims description 6
- 244000179853 Sideroxylon dulcificum Species 0.000 claims description 6
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 6
- 241001072888 Teucrium Species 0.000 claims description 6
- 241000700647 Variola virus Species 0.000 claims description 6
- 235000013399 edible fruits Nutrition 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 6
- 235000005221 swamp mahogany Nutrition 0.000 claims description 6
- 244000239645 swamp mahogany Species 0.000 claims description 6
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 5
- 230000001476 alcoholic effect Effects 0.000 claims description 5
- 239000012153 distilled water Substances 0.000 claims description 5
- 238000001914 filtration Methods 0.000 claims description 5
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 5
- 239000002994 raw material Substances 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- JGFBQFKZKSSODQ-UHFFFAOYSA-N Isothiocyanatocyclopropane Chemical compound S=C=NC1CC1 JGFBQFKZKSSODQ-UHFFFAOYSA-N 0.000 claims description 4
- PWLNAUNEAKQYLH-UHFFFAOYSA-N butyric acid octyl ester Natural products CCCCCCCCOC(=O)CCC PWLNAUNEAKQYLH-UHFFFAOYSA-N 0.000 claims description 4
- UUIQMZJEGPQKFD-UHFFFAOYSA-N n-butyric acid methyl ester Natural products CCCC(=O)OC UUIQMZJEGPQKFD-UHFFFAOYSA-N 0.000 claims description 4
- 235000009051 Ambrosia paniculata var. peruviana Nutrition 0.000 claims description 3
- 235000003097 Artemisia absinthium Nutrition 0.000 claims description 3
- 235000017731 Artemisia dracunculus ssp. dracunculus Nutrition 0.000 claims description 3
- 235000003261 Artemisia vulgaris Nutrition 0.000 claims description 3
- 239000001138 artemisia absinthium Substances 0.000 claims description 3
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims description 3
- NGEWQZIDQIYUNV-UHFFFAOYSA-N 2-hydroxy-3-methylbutyric acid Chemical compound CC(C)C(O)C(O)=O NGEWQZIDQIYUNV-UHFFFAOYSA-N 0.000 claims 2
- 240000002800 Sanicula europaea Species 0.000 claims 2
- 230000003213 activating effect Effects 0.000 claims 2
- 239000003795 chemical substances by application Substances 0.000 claims 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims 1
- 150000008107 benzenesulfonic acids Chemical class 0.000 claims 1
- 239000003599 detergent Substances 0.000 claims 1
- 150000004702 methyl esters Chemical class 0.000 claims 1
- 238000010025 steaming Methods 0.000 claims 1
- 238000002474 experimental method Methods 0.000 abstract description 3
- 238000001994 activation Methods 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 9
- 238000000034 method Methods 0.000 description 5
- WBIQQQGBSDOWNP-UHFFFAOYSA-N 2-dodecylbenzenesulfonic acid Chemical compound CCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O WBIQQQGBSDOWNP-UHFFFAOYSA-N 0.000 description 4
- 241000736038 Sanicula Species 0.000 description 4
- 229940060296 dodecylbenzenesulfonic acid Drugs 0.000 description 4
- 241000894006 Bacteria Species 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 235000013311 vegetables Nutrition 0.000 description 2
- QQGISFDJEJMKIL-JAIQZWGSSA-N (5z)-5-[[3-(hydroxymethyl)thiophen-2-yl]methylidene]-10-methoxy-2,2,4-trimethyl-1h-chromeno[3,4-f]quinolin-9-ol Chemical group C1=CC=2NC(C)(C)C=C(C)C=2C2=C1C=1C(OC)=C(O)C=CC=1O\C2=C/C=1SC=CC=1CO QQGISFDJEJMKIL-JAIQZWGSSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 241000592344 Spermatophyta Species 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 229930013930 alkaloid Natural products 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 210000004027 cell Anatomy 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 230000003370 grooming effect Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- -1 polyethylene Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 210000001938 protoplast Anatomy 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
- D06M15/13—Alginic acid or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/144—Alcohols; Metal alcoholates
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/144—Alcohols; Metal alcoholates
- D06M13/148—Polyalcohols, e.g. glycerol or glucose
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
- D06M13/256—Sulfonated compounds esters thereof, e.g. sultones
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/327—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof
- D06M15/333—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof of vinyl acetate; Polyvinylalcohol
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- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
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- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
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- General Chemical & Material Sciences (AREA)
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of antibacterial plant fibrous material, preparation method specifically includes following steps：(1) plant fiber is immersed in activator solution 50-60 minutes under the conditions of 50-55 DEG C of temperature, pressure 0.33-0.38Mpa, obtains activation plant fiber；(2) the activation plant fiber is immersed in antiseptic solution again under the conditions of 68-72 DEG C of temperature, pressure 0.41-0.45Mpa, and uses supersonic oscillations 5-8 minutes, dried after taking-up and impregnated again, is repeated 5-8 times, obtain modified plant fibers；(3) by the modified plant fibers woven into fabric, it is then immersed in sodium alginate soln 30-45 minutes, it takes out, the constant temperature steam that temperature is 122-126 DEG C is placed in handle 5-8 minutes, with the heating rate of 1.8-2.1 DEG C/min be warming up to 144-148 DEG C continue constant temperature steam handle 1-3 minutes to get.By experiment, a kind of broad-spectrum antibacterial rate of antibacterial plant fibrous material provided by the invention is up to 99.3% or more, and common plant fibrous material in the prior art does not have broad-spectrum antibacterial effect.
Description
Technical field
The present invention relates to fibrous material technical field, specifically a kind of antibacterial plant fibrous material.
Background technology
Plant fiber is a kind of sclerenchyma being widely distributed in seed plant.Its cell is elongated, and both ends are sharp, tool
There is thicker secondary wall, often there is simple pit on wall, the protoplast of typically no work when ripe.Plant fiber is main in plant
Play mechanical supporting function.Plant fiber is processed into towel-like cloth, then has high-hydroscopicity, this towel of washed Hair grooming
Moisture content can be sopped up quickly, make hair quick-drying, Reusability and extremely durable.
Vegetable fibre fabric selects pure natural plant fiber as base stock, will be planted by special technique and production technology
Sugar and fat part in fibres are rejected, and sophistication eradicates the electrostatic reaction of substance, produces knitwear.Whole process
In there is no any ingredient chemically, be all 100% green product as cotton.
In the prior art, the easy mould growth of vegetable fibre fabric antibacterial effect difference, seriously affects its use quality, Er Qieyi
Do harm to huamn body.
Invention content
In order to solve the problems mentioned above in the background art, the present invention provides a kind of antibacterial plant fibrous materials.
A kind of antibacterial plant fibrous material, preparation method specifically include following steps：
(1) plant fiber is immersed to 50- in activator solution under the conditions of 50-55 DEG C of temperature, pressure 0.33-0.38Mpa
60 minutes, obtain activation plant fiber；
(2) that the activation plant fiber is immersed antibacterial again under the conditions of 68-72 DEG C of temperature, pressure 0.41-0.45Mpa is molten
It in liquid, and uses supersonic oscillations 5-8 minutes, dries after taking-up and impregnated again, is repeated 5-8 times, obtain improved plant fibre
Dimension；
(3) it by the modified plant fibers woven into fabric, is then immersed in sodium alginate soln 30-45 minutes, takes out,
It is placed in the constant temperature steam that temperature is 122-126 DEG C to handle 5-8 minutes, 144- is warming up to the heating rate of 1.8-2.1 DEG C/min
148 DEG C continue constant temperature steams handle 1-3 minutes to get.
Further, step (1) activator solution is made by following component according to the mass fraction：Acrylic acid 12-
15 parts, 8-12 parts of n-butanol, 6-10 parts of silane coupling agent, 14-18 parts of dodecyl benzene sulfonic acid, 5-8 parts of ethylene glycol, pentyl acetate
3-6 parts, 1-5 parts of polyvinyl alcohol, 3-8 parts of 2- hydroxy-3-methyl methyl butyrates.
Further, step (2) antiseptic solution is made by following component according to the mass fraction：5-8 parts of Chinese coriaria leaf,
1-3 parts of Buddhist's Xiao smallpox, 2-4 parts of radix ranunculi ternati, 8-12 parts of Swamp Mahogany Leaf, 1-5 parts of azedarach, 6-9 parts of shrub althea flower, 1-4 parts of FOLIUM ET RAMULUS COTINI,
8-12 parts of hypericum japonicum, 8-15 parts of subdigitate wormwood herb, 3-9 parts of beggar-ticks, 1-3 parts of mountain spicy tree root and rhizome, 0.5-2 parts of sweetberry jointfir, 1-3 parts of sanicle,
6-8 parts of Chinese wild pepper, 4-7 parts of the fruit of a cubeb litsea tree, silver-colored 7-13 parts of Schima superba, 2-5 parts of viscid germander herb.
Further, step (2) antiseptic solution, preparation method specifically include following steps：
(2) all raw materials are cleaned, crushes, sieves with 100 mesh sieve, obtain traditional Chinese medicine powder, 20-25 times of the traditional Chinese medicine powder weight is added and measures
Distilled water, small fire decoct 30-40 minutes, filter to obtain extracting solution and filter residue；
(2) volume fraction that 10 times of amounts of its weight are added into the filter residue is the alcoholic solution of 75%-82%, in 50-
55 DEG C, 33-38kHz be ultrasonically treated 15-20 minutes, the filtrate of filtering；
(3) all extracting solutions and the filtrate are merged, be concentrated in vacuo in 40-42 DEG C the 1/5 of original volume to get.
Further, step (2) ultrasonic wave, frequency 35-45kHz.
Compared with prior art, the beneficial effects of the invention are as follows：
Plant fiber is placed in activation process in activator solution, wherein plant fiber can be improved in a variety of alkaloids contained
Surface and microporous activated increases the absorption to treatment fluid active ingredient, then immerses in antiseptic solution and impregnated again, improves and plants
The bacteriostasis property of fibres, while the antiseptic solution pure Chinese medicine is extracted, and is prepared simply, it is cheap, scale can be carried out
Production, it is safe and non-toxic, it is environmentally protective.By experiment, a kind of antibacterial plant fibrous material provided by the invention has outstanding anti-
Bacterium performance, broad-spectrum antibacterial rate is up to 99.3% or more, and common plant fibrous material in the prior art does not have broad-spectrum antibacterial
Effect.
Specific implementation mode
Embodiment 1
A kind of antibacterial plant fibrous material, preparation method specifically include following steps：
(1) plant fiber is immersed under the conditions of 50-55 DEG C of temperature, pressure 0.33-0.38Mpa in activator solution to 50 points
Clock obtains activation plant fiber；
(2) that the activation plant fiber is immersed antibacterial again under the conditions of 68-72 DEG C of temperature, pressure 0.41-0.45Mpa is molten
It in liquid, and uses supersonic oscillations 5 minutes, dries after taking-up and impregnated again, be repeated 5 times, obtain modified plant fibers；
(3) it by the modified plant fibers woven into fabric, is then immersed in sodium alginate soln 30 minutes, takes out, set
Enter the constant temperature steam that temperature is 122-126 DEG C to handle 5 minutes, 144-148 DEG C is warming up to the heating rate of 1.8-2.1 DEG C/min
Continue constant temperature steam handle 1 minute to get.
Further, step (1) activator solution is made by following component according to the mass fraction：Acrylic acid 12
Part, 8 parts of n-butanol, 6 parts of silane coupling agent, 14 parts of dodecyl benzene sulfonic acid, 5 parts of ethylene glycol, 3 parts of pentyl acetate, polyvinyl alcohol 1
Part, 3 parts of 2- hydroxy-3-methyls methyl butyrate.
Further, step (2) antiseptic solution is made by following component according to the mass fraction：5 parts of Chinese coriaria leaf, Xiao
1 part of smallpox of ancient India, 2 parts of radix ranunculi ternati, 8 parts of Swamp Mahogany Leaf, 1 part of azedarach, 6 parts of shrub althea flower, 1 part of FOLIUM ET RAMULUS COTINI, 8 parts of hypericum japonicum, oxtail
8 parts of wormwood artemisia, 3 parts of beggar-ticks, 1 part of mountain spicy tree root and rhizome, 0.5 part of sweetberry jointfir, 1 part of sanicle, 6 parts of Chinese wild pepper, 4 parts of the fruit of a cubeb litsea tree, silver-colored Schima superba 7
Part, 2 parts of viscid germander herb.
Further, step (2) antiseptic solution, preparation method specifically include following steps：
(3) all raw materials are cleaned, crushes, sieves with 100 mesh sieve, obtain traditional Chinese medicine powder, 20 times of amounts of the traditional Chinese medicine powder weight are added
Distilled water, small fire decoct 30 minutes, filter to obtain extracting solution and filter residue；
(2) volume fraction that 10 times of amounts of its weight are added into the filter residue is the alcoholic solution of 75%-82%, in 50-
55 DEG C, 33-38kHz be ultrasonically treated 15 minutes, the filtrate of filtering；
(3) all extracting solutions and the filtrate are merged, be concentrated in vacuo in 40-42 DEG C the 1/5 of original volume to get.
Further, step (2) ultrasonic wave, frequency 35-45kHz.
Embodiment 2
A kind of antibacterial plant fibrous material, preparation method specifically include following steps：
(1) plant fiber is immersed under the conditions of 50-55 DEG C of temperature, pressure 0.33-0.38Mpa in activator solution to 60 points
Clock obtains activation plant fiber；
(2) that the activation plant fiber is immersed antibacterial again under the conditions of 68-72 DEG C of temperature, pressure 0.41-0.45Mpa is molten
It in liquid, and uses supersonic oscillations 8 minutes, dries after taking-up and impregnated again, be repeated 8 times, obtain modified plant fibers；
(3) it by the modified plant fibers woven into fabric, is then immersed in sodium alginate soln 45 minutes, takes out, set
Enter the constant temperature steam that temperature is 122-126 DEG C to handle 8 minutes, 144-148 DEG C is warming up to the heating rate of 1.8-2.1 DEG C/min
Continue constant temperature steam handle 3 minutes to get.
Further, step (1) activator solution is made by following component according to the mass fraction：Acrylic acid 15
Part, 12 parts of n-butanol, 10 parts of silane coupling agent, 18 parts of dodecyl benzene sulfonic acid, 8 parts of ethylene glycol, 6 parts of pentyl acetate, polyethylene
5 parts of alcohol, 8 parts of 2- hydroxy-3-methyls methyl butyrate.
Further, step (2) antiseptic solution is made by following component according to the mass fraction：8 parts of Chinese coriaria leaf, Xiao
3 parts of smallpox of ancient India, 4 parts of radix ranunculi ternati, 12 parts of Swamp Mahogany Leaf, 5 parts of azedarach, 9 parts of shrub althea flower, 4 parts of FOLIUM ET RAMULUS COTINI, 12 parts of hypericum japonicum, ox
15 parts of tail wormwood artemisia, 9 parts of beggar-ticks, 3 parts of mountain spicy tree root and rhizome, 2 parts of sweetberry jointfir, 3 parts of sanicle, 8 parts of Chinese wild pepper, 7 parts of the fruit of a cubeb litsea tree, silver-colored Schima superba 13
Part, 5 parts of viscid germander herb.
Further, step (2) antiseptic solution, preparation method specifically include following steps：
(4) all raw materials are cleaned, crushes, sieves with 100 mesh sieve, obtain traditional Chinese medicine powder, 25 times of amounts of the traditional Chinese medicine powder weight are added
Distilled water, small fire decoct 40 minutes, filter to obtain extracting solution and filter residue；
(2) volume fraction that 10 times of amounts of its weight are added into the filter residue is the alcoholic solution of 75%-82%, in 50-
55 DEG C, 33-38kHz be ultrasonically treated 20 minutes, the filtrate of filtering；
(3) all extracting solutions and the filtrate are merged, be concentrated in vacuo in 40-42 DEG C the 1/5 of original volume to get.
Further, step (2) ultrasonic wave, frequency 35-45kHz.
Embodiment 3
A kind of antibacterial plant fibrous material, preparation method specifically include following steps：
(1) plant fiber is immersed under the conditions of 50-55 DEG C of temperature, pressure 0.33-0.38Mpa in activator solution to 55 points
Clock obtains activation plant fiber；
(2) that the activation plant fiber is immersed antibacterial again under the conditions of 68-72 DEG C of temperature, pressure 0.41-0.45Mpa is molten
It in liquid, and uses supersonic oscillations 6 minutes, dries after taking-up and impregnated again, be repeated 6 times, obtain modified plant fibers；
(3) it by the modified plant fibers woven into fabric, is then immersed in sodium alginate soln 40 minutes, takes out, set
Enter the constant temperature steam that temperature is 122-126 DEG C to handle 6 minutes, 144-148 DEG C is warming up to the heating rate of 1.8-2.1 DEG C/min
Continue constant temperature steam handle 2 minutes to get.
Further, step (1) activator solution is made by following component according to the mass fraction：Acrylic acid 13
Part, 10 parts of n-butanol, 8 parts of silane coupling agent, 16 parts of dodecyl benzene sulfonic acid, 6 parts of ethylene glycol, 4 parts of pentyl acetate, polyvinyl alcohol
4 parts, 5 parts of 2- hydroxy-3-methyls methyl butyrate.
Further, step (2) antiseptic solution is made by following component according to the mass fraction：6 parts of Chinese coriaria leaf, Xiao
2 parts of smallpox of ancient India, 3 parts of radix ranunculi ternati, 10 parts of Swamp Mahogany Leaf, 4 parts of azedarach, 7 parts of shrub althea flower, 3 parts of FOLIUM ET RAMULUS COTINI, 10 parts of hypericum japonicum, ox
12 parts of tail wormwood artemisia, 6 parts of beggar-ticks, 2 parts of mountain spicy tree root and rhizome, 1.5 parts of sweetberry jointfir, 2 parts of sanicle, 7 parts of Chinese wild pepper, 5 parts of the fruit of a cubeb litsea tree, silver-colored Schima superba
10 parts, 3 parts of viscid germander herb.
Further, step (2) antiseptic solution, preparation method specifically include following steps：
(5) all raw materials are cleaned, crushes, sieves with 100 mesh sieve, obtain traditional Chinese medicine powder, 22 times of amounts of the traditional Chinese medicine powder weight are added
Distilled water, small fire decoct 35 minutes, filter to obtain extracting solution and filter residue；
(2) volume fraction that 10 times of amounts of its weight are added into the filter residue is the alcoholic solution of 75%-82%, in 50-
55 DEG C, 33-38kHz be ultrasonically treated 18 minutes, the filtrate of filtering；
(3) all extracting solutions and the filtrate are merged, be concentrated in vacuo in 40-42 DEG C the 1/5 of original volume to get.
Further, step (2) ultrasonic wave, frequency 35-45kHz.
Comparative example 1
Compared with Example 1, without step (1) operation, method and step in addition to this is homogeneous for this comparative example 1
Together.
Comparative example 2
This comparative example 2 compared with Example 2, without step (2) operation, method and step in addition to this is equal
It is identical.
Comparative example 3
This comparative example 3 compared with Example 3, without step (3) operation, method and step in addition to this is equal
It is identical.
Control group
Existing common plant fibrous material.
Broad-spectrum antibacterial rate experiment is carried out using above-mentioned 7 kinds of sponges respectively, as a result such as following table：
| Broad-spectrum antibacterial rate % | |
| Embodiment 1 | 99.3 |
| Embodiment 2 | 99.5 |
| Embodiment 3 | 99.8 |
| Comparative example 1 | 81.2 |
| Comparative example 2 | 83.5 |
| Comparative example 3 | 71.7 |
| Control group | - |
As seen from the above table, a kind of antibacterial plant fibrous material provided by the invention has outstanding anti-microbial property, wide spectrum suppression
Bacterium rate is up to 99.3% or more, and common plant fibrous material in the prior art does not have broad-spectrum antibacterial effect.
Claims (7)
1. a kind of antibacterial plant fibrous material, which is characterized in that preparation method specifically includes following steps：
(1) plant fiber is immersed in activator solution 50-60 points under the conditions of 50-55 DEG C of temperature, pressure 0.33-0.38Mpa
Clock obtains activation plant fiber；
(2) the activation plant fiber is immersed into antiseptic solution again under the conditions of 68-72 DEG C of temperature, pressure 0.41-0.45Mpa
In, and use supersonic oscillations 5-8 minutes, it dries after taking-up and is impregnated again, is repeated 5-8 times, obtain modified plant fibers；
(3) it by the modified plant fibers woven into fabric, is then immersed in sodium alginate soln 30-45 minutes, takes out, merging
The constant temperature steam that temperature is 122-126 DEG C is handled 5-8 minutes, and 144-148 DEG C is warming up to the heating rate of 1.8-2.1 DEG C/min
Continue constant temperature steam handle 1-3 minutes to get.
2. a kind of antibacterial plant fibrous material according to claim 1, which is characterized in that step (1) described activating agent is molten
Liquid is made by following component according to the mass fraction：12-15 parts of acrylic acid, 8-12 parts of n-butanol, 6-10 parts of silane coupling agent, ten
14-18 parts of dialkyl benzene sulfonic acids, 5-8 parts of ethylene glycol, 3-6 parts of pentyl acetate, 1-5 parts of polyvinyl alcohol, 2- hydroxy-3-methyl butyric acid
3-8 parts of methyl esters.
3. a kind of antibacterial plant fibrous material according to claim 1, which is characterized in that step (1) described activating agent is molten
Liquid is made by following component according to the mass fraction：13 parts of acrylic acid, 10 parts of n-butanol, 8 parts of silane coupling agent, detergent alkylate
16 parts of sulfonic acid, 6 parts of ethylene glycol, 4 parts of pentyl acetate, 4 parts of polyvinyl alcohol, 5 parts of 2- hydroxy-3-methyls methyl butyrate.
4. a kind of antibacterial plant fibrous material according to claim 1, which is characterized in that step (2) described antiseptic solution,
According to the mass fraction, it is made by following component：5-8 parts of Chinese coriaria leaf, 1-3 parts of Buddhist's Xiao smallpox, 2-4 parts of radix ranunculi ternati, Swamp Mahogany Leaf 8-
12 parts, 1-5 parts of azedarach, 6-9 parts of shrub althea flower, 1-4 parts of FOLIUM ET RAMULUS COTINI, 8-12 parts of hypericum japonicum, 8-15 parts of subdigitate wormwood herb, beggar-ticks 3-9
Part, 1-3 parts of mountain spicy tree root and rhizome, 0.5-2 parts of sweetberry jointfir, 1-3 parts of sanicle, 6-8 parts of Chinese wild pepper, 4-7 parts of the fruit of a cubeb litsea tree, silver-colored Schima superba 7-13
Part, 2-5 parts of viscid germander herb.
5. a kind of antibacterial plant fibrous material according to claim 1, which is characterized in that step (2) described antiseptic solution,
According to the mass fraction, it is made by following component：6 parts of Chinese coriaria leaf, 2 parts of Buddhist's Xiao smallpox, 3 parts of radix ranunculi ternati, 10 parts of Swamp Mahogany Leaf, China tree
4 parts of skin, 7 parts of shrub althea flower, 3 parts of FOLIUM ET RAMULUS COTINI, 10 parts of hypericum japonicum, 12 parts of subdigitate wormwood herb, 6 parts of beggar-ticks, 2 parts of mountain spicy tree root and rhizome, sweetberry jointfir 1.5
Part, 2 parts of sanicle, 7 parts of Chinese wild pepper, 5 parts of the fruit of a cubeb litsea tree, silver-colored 10 parts of Schima superba, 3 parts of viscid germander herb.
6. a kind of antibacterial plant fibrous material according to claim 1, which is characterized in that step (2) described antiseptic solution,
Preparation method specifically includes following steps：
(1) all raw materials are cleaned, crushes, sieves with 100 mesh sieve, obtain traditional Chinese medicine powder, the steaming that 20-25 times of the traditional Chinese medicine powder weight is measured is added
Distilled water, small fire decoct 30-40 minutes, filter to obtain extracting solution and filter residue；
(2) volume fractions that 10 times of its weight amount is added into the filter residue are the alcoholic solution of 75%-82%, in 50-55 DEG C,
33-38kHz is ultrasonically treated 15-20 minutes, the filtrate of filtering；
(3) all extracting solutions and the filtrate are merged, be concentrated in vacuo in 40-42 DEG C the 1/5 of original volume to get.
7. a kind of antibacterial plant fibrous material according to claim 1, it is characterised in that：Step (2) described ultrasonic wave, frequency
Rate is 35-45kHz.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109315856A (en) * | 2018-11-07 | 2019-02-12 | 安徽升医疗设备有限公司 | A kind of natural antibacterial medical mask |
| CN110230112A (en) * | 2019-06-05 | 2019-09-13 | 罗莱生活科技股份有限公司 | A kind of antibiosis anti-acarien smelly eliminating viscose fiber and preparation method thereof |
| CN113840552A (en) * | 2020-03-24 | 2021-12-24 | 株式会社滋贺干洗与地球 | Method for manufacturing antiviral fiber product and antiviral mask manufactured by using same |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106192553A (en) * | 2016-07-22 | 2016-12-07 | 阜南县金威工艺品有限公司 | A kind of paper antibacterial mildew inhibitor |
| CN106758216A (en) * | 2016-12-02 | 2017-05-31 | 辽东学院 | A kind of processing method of antibacterial, uvioresistant bafta |
| CN107401066A (en) * | 2017-07-28 | 2017-11-28 | 界首市双鑫纺织有限公司 | A kind of colouring method of antimildew and antibacterial superfine fibre towel |
| CN107700203A (en) * | 2017-09-25 | 2018-02-16 | 安徽华祺汽车装饰有限公司 | A kind of processing method of modified soybean fiber |
| CN107938164A (en) * | 2017-12-25 | 2018-04-20 | 合肥洁诺无纺布制品有限公司 | A kind of preparation method of the antibacterial plant fiber non-woven fabric of fragrance |
| CN107974829A (en) * | 2017-12-22 | 2018-05-01 | 阜阳皖春家俬有限公司 | A kind of production method of mattress ramee |
-
2018
- 2018-06-19 CN CN201810632342.3A patent/CN108755132A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106192553A (en) * | 2016-07-22 | 2016-12-07 | 阜南县金威工艺品有限公司 | A kind of paper antibacterial mildew inhibitor |
| CN106758216A (en) * | 2016-12-02 | 2017-05-31 | 辽东学院 | A kind of processing method of antibacterial, uvioresistant bafta |
| CN107401066A (en) * | 2017-07-28 | 2017-11-28 | 界首市双鑫纺织有限公司 | A kind of colouring method of antimildew and antibacterial superfine fibre towel |
| CN107700203A (en) * | 2017-09-25 | 2018-02-16 | 安徽华祺汽车装饰有限公司 | A kind of processing method of modified soybean fiber |
| CN107974829A (en) * | 2017-12-22 | 2018-05-01 | 阜阳皖春家俬有限公司 | A kind of production method of mattress ramee |
| CN107938164A (en) * | 2017-12-25 | 2018-04-20 | 合肥洁诺无纺布制品有限公司 | A kind of preparation method of the antibacterial plant fiber non-woven fabric of fragrance |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109315856A (en) * | 2018-11-07 | 2019-02-12 | 安徽升医疗设备有限公司 | A kind of natural antibacterial medical mask |
| CN110230112A (en) * | 2019-06-05 | 2019-09-13 | 罗莱生活科技股份有限公司 | A kind of antibiosis anti-acarien smelly eliminating viscose fiber and preparation method thereof |
| CN113840552A (en) * | 2020-03-24 | 2021-12-24 | 株式会社滋贺干洗与地球 | Method for manufacturing antiviral fiber product and antiviral mask manufactured by using same |
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