[go: up one dir, main page]

CN108754250A - A kind of high strength die-casting aluminum alloy and its manufacturing method - Google Patents

A kind of high strength die-casting aluminum alloy and its manufacturing method Download PDF

Info

Publication number
CN108754250A
CN108754250A CN201810560062.6A CN201810560062A CN108754250A CN 108754250 A CN108754250 A CN 108754250A CN 201810560062 A CN201810560062 A CN 201810560062A CN 108754250 A CN108754250 A CN 108754250A
Authority
CN
China
Prior art keywords
high strength
aluminum alloy
casting aluminum
strength die
permanent magnetic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810560062.6A
Other languages
Chinese (zh)
Inventor
杨涛
张逸智
徐珍果
臧永强
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shenzhen Xinshen New Material Technology Co Ltd
Huawei Technologies Co Ltd
Original Assignee
Shenzhen Xinshen New Material Technology Co Ltd
Huawei Technologies Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shenzhen Xinshen New Material Technology Co Ltd, Huawei Technologies Co Ltd filed Critical Shenzhen Xinshen New Material Technology Co Ltd
Priority to CN201810560062.6A priority Critical patent/CN108754250A/en
Publication of CN108754250A publication Critical patent/CN108754250A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • C22C21/02Alloys based on aluminium with silicon as the next major constituent
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/02Making non-ferrous alloys by melting
    • C22C1/026Alloys based on aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/06Making non-ferrous alloys with the use of special agents for refining or deoxidising

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Continuous Casting (AREA)

Abstract

The invention discloses a kind of high strength die-casting aluminum alloy and its manufacturing methods.Component and its weight percent in the high strength die-casting aluminum alloy are:Si, which accounts for 8.0%~9.0%, Mg and accounts for 1.0%~1.5%, Zn, accounts for 4.0%~5.0%, Fe accounts for 0.6%~0.9%, Mn less than 0.15% but accounts for 2.0%~3.0% without 0%, Cu, Ni less than 0.15% but accounts for 0.08%~0.12% without 0%, Ti, remaining is Al and a small amount of inevitable impurity.Manufacturing method is:Fine aluminium ingot is launched into stove, is heated to 200~230 DEG C, preheat 2 hours or more, to eliminate moisture and the other impurity in raw material;Then it puts into and carries out melting in permanent magnetic stirring smelting apparatus, smelting temperature is 680~750 DEG C;After the completion of melting, molten soup is poured into Aluminium ingot mould, the high strength die-casting aluminum alloy ingot is obtained after cooling.The high strength die-casting aluminum alloy casting character is excellent, intensity is high, has certain plasticity, good economy performance, especially suitable for using die-casting process manufacture communication, electronic product structural member.

Description

A kind of high strength die-casting aluminum alloy and its manufacturing method
Technical field
The present invention relates to field of aluminum alloys more particularly to a kind of high strength die-casting aluminum alloys.
Background technology
Aluminium and its alloy are a kind of important industrial raw materials, in aerospace, machinery, electronics, ship and chemical industry Middle application is huge.Die casting has many advantages, such as that manufacture efficiency height, near-net-shape, surface quality are good, especially suitable for high-volume, fast section The industrialization manufacture played is widely used in the industries such as automobile, communication, electronics, household electrical appliances.
As communication, electronic product develop to miniaturization, light-weighted direction, the wall thickness of structural member is more and more thinner, because This also proposed increasingly higher demands to the intensity of structural material.It adds the alloy that certain element is formed and is keeping fine aluminium matter Gently, can also have higher plasticity, toughness and intensity while the advantages that corrosion-resistant, make ideal structural material.But It is that, due to being limited by material composition and forming property, traditional high strength die-casting aluminum alloy material often has the prices of raw materials The unfavorable factors such as costliness or casting character are bad cause the problems such as cost is high, high rejection rate even is difficult to shape.Mesh Before, as communication, electronic product are higher and higher to the performance requirement of structural material, the good and economic high-strength press of exploitation formability Cast aluminium alloy new material is just particularly important.
Invention content
The object of the present invention is to provide a kind of high strength die-casting aluminum alloy and its manufacturing methods, pass through the alloy to aluminium alloy Element optimizes, and improves its intensity, to adapt to the requirements of the products to structural material such as a new generation's communication, electronics.The high intensity Pack alloy casting character is excellent, and intensity is high, has certain plasticity, good economy performance, especially suitable for manufacture communication, electronics The structural member of equal products.
The purpose of the present invention is achieved through the following technical solutions:
The weight percent of a kind of high strength die-casting aluminum alloy, component and each component is:Si accounts for 8.0%~9.0%, Mg and accounts for 1.0%~1.5%, Zn account for 4.0%~5.0%, Fe and account for 0.6%~0.9%, Mn less than 0.15% but accounted for without 0%, Cu 2.0%~3.0%, Ni less than 0.15% but account for 0.08%~0.12% without 0%, Ti, remaining is inevitable for Al and on a small quantity Impurity.
A method of the above-mentioned high strength die-casting aluminum alloy of manufacture, it is characterised in that:It mainly includes the following steps that:
(1) fine aluminium ingot is launched into smelting apparatus, is heated to 200~230 DEG C, preheat 2 hours or more, to remove furnace body and former material Moisture in material;750~760 DEG C are then heated to, 20min is kept the temperature, fine aluminium ingot is made fully to melt;Again into molten aluminum be added Si, Mn, Zn, Cu, Fe melt successively, then cool the temperature to 700~720 DEG C, and Mg and remaining alloy compositions are added in molten aluminum;
(2) 20min is kept the temperature, is sufficiently stirred using untouchable permanent magnetic stirring technology, molten aluminum is reheated to 730~750 DEG C, Refining agent refining is added, rotates degasification, stands 20min, molten soup temperature is adjusted to 700~720 DEG C;
(3) molten soup is poured into Aluminium ingot mould, obtains above-mentioned high strength die-casting aluminum alloy ingot.
As a preferred embodiment of the above technical solution, the untouchable permanent magnetic stirring technology described in step 2 includes permanent magnetic stirring With the intermittent merging flow of sound source, the permanent magnetic stirring and the intermittent merging flow of sound source include working cycles below:It follows The first step of ring:Permanent magnetic stirring rotates clockwise, angular frequency w, and the mixing time rotated clockwise is t1;The second of cycle Step:Source emission head is put into smelting furnace, sound duration t2 is reduced at this point, permanent magnetic stirring rotates clockwise angular frequency w/2;The third of cycle walks:Source emission head is taken out, permanent magnetic stirring rotates counterclockwise, angular frequency w, mixing time t1, forever Magnetic stirring stops;4th step of cycle:Source emission head is put into smelting furnace, sound duration t2 takes out source emission Head;Then the first step of cycle is entered back into, the sound that the inside of the source emission head is sent out is the recording that the cicada cried, the sound Volume energy density be 500 watts to 1000 watts every cubic metre, the computational methods of the volume energy density of the sound are sound The volume of total metal fluid in the general power divided by smelting furnace of source emitting head.
As a preferred embodiment of the above technical solution, the working cycles are repeated 2 times above, complete stirring;The sound source The horizontal position that emitting head is placed is the symmetrical centre of smelting furnace, is put into 12 centimetres of vertical positions below below metal fluid liquid level It sets;The angular frequency w is that 60-100 circles are per minute;The mixing time is that t1 is 5 to 10 minutes;The sound go Time is that t2 is 5 to 10 minutes.
As a preferred embodiment of the above technical solution, the gas that the rotation degasification described in step 2 uses can be nitrogen or argon Gas.
The beneficial effects of the present invention are:By the composition design to alloy, multicomponent mutually acts synergistically, and significantly carries The high intensity of alloy, and maintain certain plasticity and excellent casting character.Such as:The present invention Si constituent contents be 8.0%~9.0%, belong to hypoeutectic cast aluminium alloy gold, there is preferable mobility and casting character;Mg has strongly in Al Solution strengthening effect, while Mg can with Si formed intermetallic compound Mg2Si has the function of dispersion-strengtherning, hence it is evident that improves The yield strength of material;Mobility can be improved in Zn, improves mechanical property, improves yield strength;Fe elements under certain condition can Coarse Fe-riched phase is formed, the plasticity of material is damaged, but Fe can reduce the sticking to mould tendency of alloy in press casting procedure, so die casting aluminium Alloy all contains a certain amount of Fe mostly, and Fe contents are limited within 0.7%~0.8% by the present invention, slightly below traditional ADC12 pack alloys;Mn can improve corrosion resistance and intensity, and it is fine and closely woven that suitable Mn can make acicular Fe-Al that can be changed into Fe-Mn-Al, reduces adverse effect of the iron to mechanical property, and Mn can also reduce sticking to mould tendency when aluminium alloy compression casting;Cu elements With apparent solution strengthening effect, Cu and Al can form intermetallic compound Al2Cu plays the role of dispersion-strengtherning;Ti exists Heterogeneous forming core base, crystal grain thinning can be used as to play the role of refined crystalline strengthening in aluminium alloy.
The alloy of the present invention has reached good reinforcing effect using multicomponent cooperative reinforcing, also avoids each constituent element and contains It is adversely affected caused by amount is excessive.This alloy has obvious ageing strengthening effect, since die casting cooling velocity is fast, Al matrixes In can be dissolved a large amount of solute atoms, such as Si, Mg, Cu, in the storage and transportational process of structural member, it may occur that when natural Effect, makes the intensity of alloy be improved.Since there is the alloy of the present invention preferable casting character and good solution strengthening to imitate Fruit, therefore the mode of preferably metal mold compression casting carries out the manufacture of structural member, fills type, quickly solidification in conjunction with high-pressure casting high speed The characteristics of, obtain the product structure and more preferably mechanical property of complex precise.
Description of the drawings
Fig. 1 is the stress strain curve of high strength die-casting aluminum alloy die casting tensile sample;
Fig. 2 is the metallograph obtained on high strength die-casting aluminum alloy die casting tensile sample.
Specific implementation mode
Embodiment:
The present embodiment provides a kind of high strength die-casting aluminum alloys, are made of the element of following mass percent:Si is accounted for 8.777%, Mg, which account for 1.179%, Zn and account for 4.91%, Fe and account for 0.787%, Mn and account for 0.136%, Cu and account for 2.405%, Ni, to be accounted for 0.053%, Ti account for 0.119%, remaining is Al and a small amount of inevitable impurity.
Preparation method includes the following steps:
(1) fine aluminium ingot is launched into smelting furnace, is heated to 200~230 DEG C, preheat 2 hours or more, to remove furnace body and raw material In moisture;750~760 DEG C are then heated to, 20min is kept the temperature, fine aluminium ingot is made fully to melt;Again into molten aluminum be added Si, Mn, Zn, Fe melt successively, then cool the temperature to 700~720 DEG C, and Mg and remaining alloy compositions are added in molten aluminum;(2) it keeps the temperature 20min is sufficiently stirred using untouchable permanent magnetic stirring technology.Molten aluminum is reheated to 730~750 DEG C, refining agent is added Refining rotates degasification, stands 20min, molten soup temperature is adjusted to 700~720 DEG C;
(3) molten soup is poured into Aluminium ingot mould, obtains above-mentioned high strength die-casting aluminum alloy ingot.
The high strength die-casting aluminum alloy ingot of the embodiment of the present invention is melted again, is heated to 670 DEG C, with die casting machine by molten soup It is pressed into metal die, the tensile sample of high strength die-casting aluminum alloy is made.Natural aging treatment is carried out to above-mentioned tensile sample, is surveyed Its mechanical property is tried, the results are shown in Table 1.
The mechanical property of the tensile sample of 1 high strength die-casting aluminum alloy of the embodiment of the present invention of table
From the results shown in Table 1, the aluminium alloy of the invention have high intensity and certain plasticity, disclosure satisfy that communication, Demand of the electronic product to structural material.And with the extension of aging time, the yield strength and tensile strength of alloy obtain Apparent raising is arrived.When aging time reaches 30 days, intensity tends towards stability.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with Understanding without departing from the principles and spirit of the present invention can carry out these embodiments a variety of variations, modification, replace And modification, the scope of the present invention is defined by the appended.

Claims (5)

1. a kind of high strength die-casting aluminum alloy, it is characterised in that:Component in the high strength die-casting aluminum alloy and its weight hundred Point ratio is:Si, which accounts for 8.0%~9.0%, Mg and accounts for 1.0%~1.5%, Zn and account for 4.0%~5.0%, Fe and account for 0.6%~0.9%, Mn, to be less than 0.15% but account for 2.0%~3.0%, Ni less than 0.15% but accounting for 0.08%~0.12% without 0%, Ti without 0%, Cu, remaining for Al with A small amount of inevitable impurity.
2. a kind of method of manufacture high strength die-casting aluminum alloy as described in claim 1, it is characterised in that:Include mainly following Step:
(1) fine aluminium ingot is launched into smelting apparatus, is heated to 200~230 DEG C, preheat 2 hours or more, to remove furnace body and original Moisture in material;750~760 DEG C are then heated to, 20 min is kept the temperature, fine aluminium ingot is made fully to melt;It is added again into molten aluminum Si, Mn, Zn, Cu, Fe melt successively, then cool the temperature to 700~720 DEG C, and molten aluminum is added in Mg and remaining alloy compositions In;
(2) 20 min are kept the temperature, is sufficiently stirred using untouchable permanent magnetic stirring technology, molten aluminum is reheated to 730~750 DEG C, refining agent refining is added, rotates degasification, stands 20 min, molten soup temperature is adjusted to 700~720 DEG C;
(3) molten soup is poured into Aluminium ingot mould, obtains above-mentioned high strength die-casting aluminum alloy ingot.
3. the manufacturing method of high strength die-casting aluminum alloy according to claim 2, it is characterised in that:Non- in step 2 connects It includes permanent magnetic stirring and the intermittent merging flow of sound source to touch property permanent magnetic stirring technology, the permanent magnetic stirring and sound source is intermittent sets It includes working cycles below to enter flow:The first step of cycle:Permanent magnetic stirring rotates clockwise, and angular frequency w is rotated clockwise Mixing time be t1;The second step of cycle:Source emission head, sound duration t2, at this point, permanent magnetism are put into smelting furnace Stirring rotates clockwise angular frequency and is reduced to w/2;The third of cycle walks:Source emission head is taken out, permanent magnetic stirring rotates counterclockwise, angle Frequency is w, mixing time t1, permanent magnetic stirring stopping;4th step of cycle:Source emission head, sound are put into smelting furnace Duration is t2, takes out source emission head;Then the first step of cycle is entered back into, the inside of the source emission head is sent out Sound be the recording that the cicada cried, the volume energy density of the sound is 500 watts to 1000 watts every cubic metre, the body of the sound The computational methods of product energy density are the volume of total metal fluid in the general power divided by smelting furnace of source emission head.
4. according to the manufacturing method of the high strength die-casting aluminum alloy described in claim 2, which is characterized in that described is non-contact Property permanent magnetic stirring technology in working cycles be repeated 2 times it is above, complete stirring;The horizontal position that the source emission head is placed For the symmetrical centre of smelting furnace, it is put into 12 centimetres of upright positions below below metal fluid liquid level;The angular frequency w is 60-100 circles are per minute;The mixing time is that t1 is 5 to 10 minutes;The sound duration is that t2 is 5 to 10 points Clock.
5. the production method of high strength die-casting aluminum alloy according to claim 2, it is characterised in that:Described in step 2 Gas can be nitrogen or argon gas used by rotating degasification.
CN201810560062.6A 2018-06-03 2018-06-03 A kind of high strength die-casting aluminum alloy and its manufacturing method Pending CN108754250A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810560062.6A CN108754250A (en) 2018-06-03 2018-06-03 A kind of high strength die-casting aluminum alloy and its manufacturing method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810560062.6A CN108754250A (en) 2018-06-03 2018-06-03 A kind of high strength die-casting aluminum alloy and its manufacturing method

Publications (1)

Publication Number Publication Date
CN108754250A true CN108754250A (en) 2018-11-06

Family

ID=64002014

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201810560062.6A Pending CN108754250A (en) 2018-06-03 2018-06-03 A kind of high strength die-casting aluminum alloy and its manufacturing method

Country Status (1)

Country Link
CN (1) CN108754250A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110144499A (en) * 2019-06-21 2019-08-20 广东省材料与加工研究所 A kind of die-casting aluminum alloy for 5G communication base station housing and its preparation method
CN111155000A (en) * 2020-02-29 2020-05-15 张逸智 Rapid heat treatment strengthening high-strength and high-toughness aluminum alloy material for die-casting thin-walled piece and preparation method and application thereof
WO2022130484A1 (en) * 2020-12-15 2022-06-23 日軽エムシーアルミ株式会社 Aluminum alloy and aluminum alloy casting material

Citations (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS59229458A (en) * 1983-06-09 1984-12-22 N D C Kk Al alloy sliding material and its production
JPS60255996A (en) * 1984-06-01 1985-12-17 Fumio Kono Aluminum alloy product
JPH02149630A (en) * 1988-11-30 1990-06-08 Aisin Seiki Co Ltd Piston material for internal combustion engine
PL290222A1 (en) * 1991-05-10 1992-11-16 Inst Metali Niezelaznych Aluminium casting alloy and method of obtaining such alloy
JP2004225121A (en) * 2003-01-23 2004-08-12 Aisin Seiki Co Ltd Alloy for die casting piston
JP2005264301A (en) * 2004-03-22 2005-09-29 Toyota Central Res & Dev Lab Inc Cast aluminum alloy, aluminum alloy casting and method for producing the same
CN101921933A (en) * 2010-06-03 2010-12-22 怡球金属资源再生(中国)股份有限公司 High-purity stabilized aluminum alloy ingot and production method thereof
CN102108463A (en) * 2010-01-29 2011-06-29 北京有色金属研究总院 Aluminium alloy product suitable for manufacturing structures and preparation method
CN102304651A (en) * 2011-08-15 2012-01-04 镇江汇通金属成型有限公司 Casting aluminum-silicon alloy and strengthening method thereof
CN102312135A (en) * 2010-06-30 2012-01-11 通用汽车环球科技运作有限责任公司 Improved y alloy y
WO2014109624A1 (en) * 2013-01-14 2014-07-17 주식회사 케이에이치바텍 Aluminum alloy for die casting and preparation method therefor
CN103958113A (en) * 2011-12-02 2014-07-30 株式会社Uacj Aluminium alloy-copper alloy bond, and bonding method for same
EP2865773A1 (en) * 2013-10-23 2015-04-29 Befesa Aluminio, S.L. Aluminium casting alloy
CN104911417A (en) * 2015-06-30 2015-09-16 辽宁科技大学 High-purity aluminum magnesium alloy plate ingot for mechanical hard disk, and production method thereof
CN107312955A (en) * 2016-04-27 2017-11-03 现代自动车株式会社 Aluminium diecasting alloy and heat-treating methods are carried out to it

Patent Citations (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS59229458A (en) * 1983-06-09 1984-12-22 N D C Kk Al alloy sliding material and its production
JPS60255996A (en) * 1984-06-01 1985-12-17 Fumio Kono Aluminum alloy product
JPH02149630A (en) * 1988-11-30 1990-06-08 Aisin Seiki Co Ltd Piston material for internal combustion engine
PL290222A1 (en) * 1991-05-10 1992-11-16 Inst Metali Niezelaznych Aluminium casting alloy and method of obtaining such alloy
JP2004225121A (en) * 2003-01-23 2004-08-12 Aisin Seiki Co Ltd Alloy for die casting piston
JP2005264301A (en) * 2004-03-22 2005-09-29 Toyota Central Res & Dev Lab Inc Cast aluminum alloy, aluminum alloy casting and method for producing the same
CN102108463A (en) * 2010-01-29 2011-06-29 北京有色金属研究总院 Aluminium alloy product suitable for manufacturing structures and preparation method
CN101921933A (en) * 2010-06-03 2010-12-22 怡球金属资源再生(中国)股份有限公司 High-purity stabilized aluminum alloy ingot and production method thereof
CN102312135A (en) * 2010-06-30 2012-01-11 通用汽车环球科技运作有限责任公司 Improved y alloy y
CN102304651A (en) * 2011-08-15 2012-01-04 镇江汇通金属成型有限公司 Casting aluminum-silicon alloy and strengthening method thereof
CN103958113A (en) * 2011-12-02 2014-07-30 株式会社Uacj Aluminium alloy-copper alloy bond, and bonding method for same
WO2014109624A1 (en) * 2013-01-14 2014-07-17 주식회사 케이에이치바텍 Aluminum alloy for die casting and preparation method therefor
EP2865773A1 (en) * 2013-10-23 2015-04-29 Befesa Aluminio, S.L. Aluminium casting alloy
CN104911417A (en) * 2015-06-30 2015-09-16 辽宁科技大学 High-purity aluminum magnesium alloy plate ingot for mechanical hard disk, and production method thereof
CN107312955A (en) * 2016-04-27 2017-11-03 现代自动车株式会社 Aluminium diecasting alloy and heat-treating methods are carried out to it

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110144499A (en) * 2019-06-21 2019-08-20 广东省材料与加工研究所 A kind of die-casting aluminum alloy for 5G communication base station housing and its preparation method
CN111155000A (en) * 2020-02-29 2020-05-15 张逸智 Rapid heat treatment strengthening high-strength and high-toughness aluminum alloy material for die-casting thin-walled piece and preparation method and application thereof
WO2022130484A1 (en) * 2020-12-15 2022-06-23 日軽エムシーアルミ株式会社 Aluminum alloy and aluminum alloy casting material
JP7472318B2 (en) 2020-12-15 2024-04-22 日軽エムシーアルミ株式会社 Aluminum alloys and aluminum alloy castings

Similar Documents

Publication Publication Date Title
CN109652685B (en) A high thermal conductivity and high corrosion resistance cast aluminum alloy and its preparation method
CN111155000A (en) Rapid heat treatment strengthening high-strength and high-toughness aluminum alloy material for die-casting thin-walled piece and preparation method and application thereof
CN104726756B (en) High-performance beryllium-aluminum alloy and preparing method thereof
CN103320651A (en) Fine-grained zinc-based alloy for die and preparation process thereof
CN108754250A (en) A kind of high strength die-casting aluminum alloy and its manufacturing method
CN101775530A (en) Hypereutectic al-si alloy piston material
CN112626390B (en) High-elongation die-casting aluminum alloy and preparation method thereof
CN114457263A (en) High-strength high-toughness high-heat-conductivity die-casting aluminum alloy and manufacturing method thereof
CN109518027B (en) A kind of preparation method and application of fine-grained Mg-Al-Ti-C master alloy
CN101693963B (en) Environment-friendly metal decoration material
WO2020088635A1 (en) Aluminum alloy material, aluminum alloy molded part and preparation method therefor, and terminal device
CN107130137A (en) A kind of low-pressure casting process of environmentally friendly silizin tap
CN107794405B (en) Fine-grain copper-tin alloy and preparation method thereof
CN101289721A (en) Magnesium-manganese master alloy with high manganese content and preparation method thereof
CN107904461B (en) Low-cost high-performance magnesium alloy profile and preparation method thereof
CN111304509A (en) A kind of refined magnesium alloy by adding VN particles and preparation method thereof
CN111118356A (en) Aluminum alloy material, aluminum alloy molded part, preparation method of aluminum alloy molded part and terminal equipment
CN102534310B (en) High-strength aluminum alloy doped with Mo2C and MgH2 and preparation method thereof
CN102277521A (en) High-temperature high-tenacity single-phase solid-solution magnesium rare earth base alloy and preparation method thereof
CN107723491B (en) A kind of modifier for special casting aluminum alloy for IC equipment and modification treatment method
CN107177755B (en) High-strength, high-anti-friction zinc-containing alloy, its casting preparation method and dedicated unit
CN113462926B (en) A kind of high-strength wear-resistant high-lead tin bronze material and preparation method thereof
CN104060154A (en) QT500 casting and production method thereof
CN111057902B (en) Die-casting copper alloy, preparation method and application thereof and die-casting copper alloy composite plastic product
CN113234968A (en) High-performance uniform aluminum alloy ingot and production method thereof

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
WD01 Invention patent application deemed withdrawn after publication
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20181106