A kind of activated carbon filter
Technical field
The present invention relates to water purification fields, and in particular to a kind of activated carbon filter.
Background technology
Filter element of water purifier is the device for the water state required for cleaning to production, life for making to be contaminated, the purpose is to
The solid particle in water is removed, bacterium is killed, filters out harmful chemical component, water is made to reach certain cleanliness factor.The prior art
Filter element of water purifier, usually the inside is all KDF and activated carbon, and active carbon filter core product has two major classes:Compression-type active carbon filter core
With bulk type active carbon filter core.
Compression-type active carbon filter core, as filter material, is eaten using the coaly activated carbon and cocoanut active charcoal of gel powder with high adsorptive
The adhesive of grade is sintered compression molding.One layer of nonwoven for having filtration is respectively wrapped in inside and outside extruded activated carbon filter core
Cloth, it is ensured that charcoal core itself does not fall out powdered carbon, and charcoal core both ends make charcoal core be packed into filter cylinder tool equipped with soft nitrile rubber gasket
There is good leakproofness.Required active carbon particle is fitted into special plastic casing by bulk type active carbon filter core, with weldering
The both ends of the surface that end cap is welded on shell by equipment are connect, the both ends of shell are respectively put into the non-woven fabrics filter disc of filtration, it is ensured that
Charcoal core does not fall out powdered carbon and Heisui River when in use.
However this active carbon filter core, there is a problem of that powdered carbon filter effect is poor, during actual use have to set
Large volume of filter element shell is set, to fill more powdered carbon, improves filter effect;In addition, after being used for a long time, due to powdered carbon
Graininess feature will necessarily there are problems that falling powdered carbon and Heisui River.
Therefore, the use limitation of traditional active carbon filter core is larger, how to improve the bactericidal effect of active carbon filter core
Fruit is a technical problem to be solved urgently.
Invention content
For existing deficiency, of the invention there is provided a kind of activated carbon filters, including filter core upper end cover, activated carbon
Filter core and level-one collection water cover, the active carbon filter core include the interior filter cylinder of tubular, the activated carbon fibre being wrapped on interior filter cylinder,
And it is wrapped in the outer filter cloth on the outside of activated carbon fibre;The filter core upper end cover and level-one collection water cover cover conjunction and are sealed in activity respectively
The top and bottom of filtration core, the level-one, which catchments to cover, is provided with primary effluent hole corresponding with interior filter cylinder position;It is described
Activated carbon water-purifying material is made of following parts by weight, 50~80 parts of flyash, 10~20 parts of activated carbon, 3~5 parts of sodium carbonate,
5~8 parts of nano-titanium dioxide, 10~20 parts of graphene oxide, 10~20 parts of silica gel, 1~3 part of antibacterial component, polyethylene glycol 3~
5 parts.
The activated carbon is any one in wood activated charcoal, active fruit shell carbon, coaly activated carbon, petroleum-type activated carbon
Kind is a variety of.
The number-average molecular weight of polyethylene glycol is 4000~1000.
The bottom of the filter core upper end cover is provided with the first lug, nib of annular, and ring is provided at the top of the level-one collection water cover
Second lug, nib of shape, first lug, nib and the second lug, nib are plugged on the top and bottom of interior filter cylinder respectively.
The bottom margin of the filter core upper end cover is provided with the first place-limited edge of annular, the top sides of the level-one collection water cover
Edge is provided with the second place-limited edge of annular, and first place-limited edge and the second place-limited edge are installed on the active carbon filter core respectively
On the outside of top and bottom.
The active carbon filter core further includes being connected to level-one to catchment the hollow fiber ultrafiltration membrane filter in base portion, the hollow fiber ultrafiltration
Membrane filter includes two level filter element shell and the hollow fiber ultrafiltration membrane that is arranged in shell.
The bottom margin of the level-one collection water cover is provided with the third place-limited edge of annular, and the third place-limited edge is installed on institute
State the inside top face of two level filter element shell.
The bottom of the two level filter element shell is connected with two level collection water cover, and the bottom of two level collection water cover is provided with two level
Apopore.
The preparation method of the activated carbon water-purifying material, specifically includes the following steps:
1) it pre-processes:Activated carbon is crushed, until D95≤0.15mm of particle;
2) it is molded:By step 1) obtain particle in proportion with flyash, sodium carbonate, nano-titanium dioxide, graphite oxide
Alkene, silica gel, antibacterial component and polyethylene glycol are sufficiently mixed, and are activated carbon precursor by mixture extrusion molding;
3) it carbonizes:The activated carbon precursor is subjected to air pre-oxidation at a temperature of 150~200 DEG C, then 780~
It is carbonized at 920 DEG C, activated carbon water-purifying material is obtained after cooling.
The formulation weight proportioning of the antibacterial component is as follows:20~30 parts of nano phase ag_2 o, 40~50 parts of Tourmaline powder and
20~30 parts of negative ion powder.
Further, the preparation method of the nano phase ag_2 o is as follows:Silver nitrate is dissolved in deionized water and is prepared
At the solution of a concentration of 0.2mol/L~4.0mol/L, the ratio by weight 1%~10% in the solution is added organic point
Powder, the ammonia that then the ratio dropwise addition weight percent concentration by weight 5%~15% while being vigorously stirred is 25%
Water forms silver ammino ion solution;Hereafter while being vigorously stirred by this solution be added drop-wise to a concentration of 0.5mol/L~
In the aqueous slkali of 3.0mol/L, precipitation is formed;It is precipitated and is washed with deionized for several times by centrifuging to take out again, freezing is dry
It is dry, you can.
The high efficiency active carbon water purification agent of the present invention, by controlling by the preparation of activated carbon, by flyash, activated carbon, carbonic acid
Sodium, nano-titanium dioxide, graphene oxide, silica gel, antibacterial component, polyethylene glycol combine, and activated carbon water purification is prepared
Material;The raw material of the present invention is common to be easy to get, and has wide range of applications, and has extremely strong practical performance.The present invention's is giving full play to
On the basis of the respective good characteristic of raw material, high efficiency active carbon water-purifying material can be made as needed, clean-up effect is extremely strong.
Specific implementation mode
The following is a clear and complete description of the technical scheme in the embodiments of the invention, it is clear that described embodiment
Only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, the common skill in this field
The every other embodiment that art personnel are obtained without making creative work belongs to the model that the present invention protects
It encloses.
【Embodiment 1】
The preparation method of nano phase ag_2 o is as follows:Silver nitrate is dissolved in deionized water and is configured to a concentration of 4.0mol/L
Solution, in the solution by weight 3% ratio be added organic dispersing agent, then while being vigorously stirred by weight
315% ratio is added dropwise the ammonium hydroxide that weight percent concentration is 25% and forms silver ammino ion solution;Hereafter it is being vigorously stirred
This solution is added drop-wise in the aqueous slkali of a concentration of 0.5mol/L simultaneously, forms precipitation;Again precipitation is taken out by centrifuging simultaneously
It is washed with deionized for several times, freeze-drying, you can.
【Embodiment 2】
1) it pre-processes:Cocoanut active charcoal is crushed, until D95≤0.15mm of particle;
2) it is molded:Weigh the raw material of following parts by weight:20 parts of activated carbon, the carbonic acid that 80 parts of flyash, step 1) obtain
5 parts of sodium, 8 parts of nano-titanium dioxide, 10~20 parts of graphene oxide, 20 parts of silica gel, 3 parts of antibacterial component, 5 parts of polyethylene glycol, will
The raw material weighed is sufficiently mixed, and is activated carbon precursor by mixture extrusion molding, wherein the particle and the middle low temperature
The weight ratio of coal tar is in 3.0: 1 ranges;The formulation weight proportioning of the antibacterial component is as follows:30 parts of nano phase ag_2 o, support
30 parts of 40 parts of agate beautiful jade powder and negative ion powder.
3) it carbonizes:The activated carbon precursor is subjected to air pre-oxidation at a temperature of 200 DEG C, then at 920 DEG C into
Row charing, activated carbon water-purifying material is obtained after cooling.
【Embodiment 3】
1) it pre-processes:Cocoanut active charcoal is crushed, until D95≤0.15mm of particle;
2) it is molded:Weigh the raw material of following parts by weight:10 parts of activated carbon, the carbonic acid that 50 parts of flyash, step 1) obtain
3 parts of sodium, 5 parts of nano-titanium dioxide, 20 parts of graphene oxide, 20 parts of silica gel, 3 parts of antibacterial component, 5 parts of polyethylene glycol, will weigh
Raw material be sufficiently mixed, and be activated carbon precursor by mixture extrusion molding, wherein the particle and the middle low temperature coal tar
The weight ratio of oil is in 2.5: 1 ranges;The formulation weight proportioning of the antibacterial component is as follows:20~30 parts of nano phase ag_2 o, support
20~30 parts of 40~50 parts of agate beautiful jade powder and negative ion powder.
3) it carbonizes:The activated carbon precursor is subjected to air pre-oxidation at a temperature of 150~200 DEG C, then 780~
It is carbonized at 920 DEG C, activated carbon water-purifying material is obtained after cooling.
【Embodiment 4】
1) it pre-processes:Cocoanut active charcoal is crushed, until D95≤0.15mm of particle;
2) it is molded:Weigh the raw material of following parts by weight:50~80 parts of flyash, step 1) obtain 15 parts of activated carbon,
45 parts of sodium carbonate, 6 parts of nano-titanium dioxide, 11 parts of graphene oxide, 15 parts of silica gel, 2 parts of antibacterial component, 4 parts of polyethylene glycol, will
The raw material weighed is sufficiently mixed, and is activated carbon precursor by mixture extrusion molding, wherein the particle and the middle low temperature
The weight ratio of coal tar is in 2: 1 ranges;The formulation weight proportioning of the antibacterial component is as follows:20 parts of nano phase ag_2 o, Tuo Ma
30 parts of 50 parts of beautiful jade powder and negative ion powder.
3) it carbonizes:The activated carbon precursor is subjected to air pre-oxidation at a temperature of 200 DEG C, then at 920 DEG C into
Row charing, activated carbon water-purifying material is obtained after cooling.
【Embodiment 5】
The present embodiment provides a kind of activated carbon filter, including filter core upper end cover, active carbon filter core and level-one collection water cover,
The active carbon filter core includes the interior filter cylinder of tubular, the activated carbon fibre being wrapped on interior filter cylinder and is wrapped in active carbon fibre
Tie up the outer filter cloth in outside;The filter core upper end cover and level-one collection water cover cover the top and bottom closed and be sealed in active carbon filter core respectively
Portion, the level-one, which catchments to cover, is provided with primary effluent hole corresponding with interior filter cylinder position;The bottom of the filter core upper end cover
Be provided with the first lug, nib of annular, be provided with the second lug, nib of annular at the top of the level-one collection water cover, first lug, nib and
Second lug, nib is plugged on the top and bottom of interior filter cylinder respectively.The bottom margin of the filter core upper end cover is provided with the first of annular
Place-limited edge, the top edge of the level-one collection water cover are provided with the second place-limited edge of annular, first place-limited edge and the second limit
Position rib is installed on respectively on the outside of the top and bottom of the active carbon filter core.The carbon fiber filter element of water purifier further includes being connected to
Level-one is catchmented the hollow fiber ultrafiltration membrane filter in base portion, and the hollow fiber ultrafiltration membrane filter includes two level filter element shell and is arranged in shell
Internal hollow fiber ultrafiltration membrane.The bottom margin of the level-one collection water cover is provided with the third place-limited edge of annular, the third
Place-limited edge is installed on the inside top face of the two level filter element shell.The bottom of the two level filter element shell is connected with two level and catchments
Lid, and the bottom of two level collection water cover is provided with secondary effluent hole.
The obtained activated carbon water-purifying materials of embodiment 2-4 are respectively used to above-mentioned water purifier to be tested for the property, test knot
Fruit is shown in Table 1.
Table 1
Above description has fully disclosed the specific implementation mode of the present invention.It should be pointed out that being familiar with the field
Technical staff is to any change for being done of specific implementation mode of the present invention all without departing from the range of claims of the present invention.
Correspondingly, the scope of the claims of the invention is also not limited only to previous embodiment.