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CN108658249B8 - Biological adsorber for treating heavy metal wastewater - Google Patents

Biological adsorber for treating heavy metal wastewater Download PDF

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Publication number
CN108658249B8
CN108658249B8 CN201810573047.5A CN201810573047A CN108658249B8 CN 108658249 B8 CN108658249 B8 CN 108658249B8 CN 201810573047 A CN201810573047 A CN 201810573047A CN 108658249 B8 CN108658249 B8 CN 108658249B8
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Prior art keywords
adsorption
balls
screen
adsorber
biological
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CN201810573047.5A
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CN108658249A (en
CN108658249B (en
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不公告发明人
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Shandong Torch Zhongyuan Technology Market Management Co ltd
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Tengzhou Daozhisheng Intelligent Technology Co ltd
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Publication of CN108658249B publication Critical patent/CN108658249B/en
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    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12N—MICROORGANISMS OR ENZYMES; COMPOSITIONS THEREOF; PROPAGATING, PRESERVING, OR MAINTAINING MICROORGANISMS; MUTATION OR GENETIC ENGINEERING; CULTURE MEDIA
    • C12N11/00—Carrier-bound or immobilised enzymes; Carrier-bound or immobilised microbial cells; Preparation thereof
    • C12N11/02—Enzymes or microbial cells immobilised on or in an organic carrier
    • C12N11/08—Enzymes or microbial cells immobilised on or in an organic carrier the carrier being a synthetic polymer
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00—Biological treatment of water, waste water, or sewage
    • C02F3/34—Biological treatment of water, waste water, or sewage characterised by the microorganisms used
    • C02F3/347—Use of yeasts or fungi
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/223—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material containing metals, e.g. organo-metallic compounds, coordination complexes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/24—Naturally occurring macromolecular compounds, e.g. humic acids or their derivatives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/26—Synthetic macromolecular compounds
    • B01J20/261—Synthetic macromolecular compounds obtained by reactions only involving carbon to carbon unsaturated bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/26—Synthetic macromolecular compounds
    • B01J20/262—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon to carbon unsaturated bonds, e.g. obtained by polycondensation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/26—Synthetic macromolecular compounds
    • B01J20/264—Synthetic macromolecular compounds derived from different types of monomers, e.g. linear or branched copolymers, block copolymers, graft copolymers
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00—Biological treatment of water, waste water, or sewage
    • C02F3/34—Biological treatment of water, waste water, or sewage characterised by the microorganisms used
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12N—MICROORGANISMS OR ENZYMES; COMPOSITIONS THEREOF; PROPAGATING, PRESERVING, OR MAINTAINING MICROORGANISMS; MUTATION OR GENETIC ENGINEERING; CULTURE MEDIA
    • C12N1/00—Microorganisms, e.g. protozoa; Compositions thereof; Processes of propagating, maintaining or preserving microorganisms or compositions thereof; Processes of preparing or isolating a composition containing a microorganism; Culture media therefor
    • C12N1/14—Fungi; Culture media therefor
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12N—MICROORGANISMS OR ENZYMES; COMPOSITIONS THEREOF; PROPAGATING, PRESERVING, OR MAINTAINING MICROORGANISMS; MUTATION OR GENETIC ENGINEERING; CULTURE MEDIA
    • C12N1/00—Microorganisms, e.g. protozoa; Compositions thereof; Processes of propagating, maintaining or preserving microorganisms or compositions thereof; Processes of preparing or isolating a composition containing a microorganism; Culture media therefor
    • C12N1/14—Fungi; Culture media therefor
    • C12N1/16—Yeasts; Culture media therefor
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12N—MICROORGANISMS OR ENZYMES; COMPOSITIONS THEREOF; PROPAGATING, PRESERVING, OR MAINTAINING MICROORGANISMS; MUTATION OR GENETIC ENGINEERING; CULTURE MEDIA
    • C12N1/00—Microorganisms, e.g. protozoa; Compositions thereof; Processes of propagating, maintaining or preserving microorganisms or compositions thereof; Processes of preparing or isolating a composition containing a microorganism; Culture media therefor
    • C12N1/14—Fungi; Culture media therefor
    • C12N1/16—Yeasts; Culture media therefor
    • C12N1/18—Baker's yeast; Brewer's yeast
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12N—MICROORGANISMS OR ENZYMES; COMPOSITIONS THEREOF; PROPAGATING, PRESERVING, OR MAINTAINING MICROORGANISMS; MUTATION OR GENETIC ENGINEERING; CULTURE MEDIA
    • C12N1/00—Microorganisms, e.g. protozoa; Compositions thereof; Processes of propagating, maintaining or preserving microorganisms or compositions thereof; Processes of preparing or isolating a composition containing a microorganism; Culture media therefor
    • C12N1/20—Bacteria; Culture media therefor
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12N—MICROORGANISMS OR ENZYMES; COMPOSITIONS THEREOF; PROPAGATING, PRESERVING, OR MAINTAINING MICROORGANISMS; MUTATION OR GENETIC ENGINEERING; CULTURE MEDIA
    • C12N11/00—Carrier-bound or immobilised enzymes; Carrier-bound or immobilised microbial cells; Preparation thereof
    • C12N11/02—Enzymes or microbial cells immobilised on or in an organic carrier
    • C12N11/04—Enzymes or microbial cells immobilised on or in an organic carrier entrapped within the carrier, e.g. gel or hollow fibres
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12N—MICROORGANISMS OR ENZYMES; COMPOSITIONS THEREOF; PROPAGATING, PRESERVING, OR MAINTAINING MICROORGANISMS; MUTATION OR GENETIC ENGINEERING; CULTURE MEDIA
    • C12N11/00—Carrier-bound or immobilised enzymes; Carrier-bound or immobilised microbial cells; Preparation thereof
    • C12N11/02—Enzymes or microbial cells immobilised on or in an organic carrier
    • C12N11/10—Enzymes or microbial cells immobilised on or in an organic carrier the carrier being a carbohydrate
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00—Nature of the contaminant
    • C02F2101/10—Inorganic compounds
    • C02F2101/20—Heavy metals or heavy metal compounds
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2203/00—Apparatus and plants for the biological treatment of water, waste water or sewage
    • C02F2203/006—Apparatus and plants for the biological treatment of water, waste water or sewage details of construction, e.g. specially adapted seals, modules, connections

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Zoology (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • Wood Science & Technology (AREA)
  • Genetics & Genomics (AREA)
  • Microbiology (AREA)
  • Biotechnology (AREA)
  • General Health & Medical Sciences (AREA)
  • Mycology (AREA)
  • Biomedical Technology (AREA)
  • Biochemistry (AREA)
  • General Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Virology (AREA)
  • Medicinal Chemistry (AREA)
  • Tropical Medicine & Parasitology (AREA)
  • Botany (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Molecular Biology (AREA)
  • Inorganic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Micro-Organisms Or Cultivation Processes Thereof (AREA)
  • Immobilizing And Processing Of Enzymes And Microorganisms (AREA)
  • Preparation Of Compounds By Using Micro-Organisms (AREA)
  • Purification Treatments By Anaerobic Or Anaerobic And Aerobic Bacteria Or Animals (AREA)
  • Water Treatment By Sorption (AREA)

Abstract

The invention discloses a biological adsorber for treating heavy metal wastewater, which is formed by connecting a plurality of adsorption columns in series, wherein the side wall of the lower part of each adsorption column is provided with a water inlet, the side wall of the upper part of each adsorption column is provided with an overflow outlet, the adsorption columns are internally provided with an upper screen and a lower screen, the upper screen is higher than the water inlet, the lower screen is lower than the overflow outlet, an adsorption space defined by the side wall of each adsorption column and the upper and lower screens is filled with immobilized cell balls and rhizopus oryzae hyphae balls, the volume filling ratio of the immobilized cell balls to the rhizopus oryzae hyphae balls is 60-90:10-40, the total filling ratio of the immobilized cell balls to the rhizopus oryzae hyphae balls in the adsorption space is 50-80%, an annular guide cylinder is also arranged in the adsorption space, and the upper end and the lower end of the annular guide cylinder are not contacted with the upper screen and the lower screen respectively, the bottom of the adsorption column is provided with an aeration device which is positioned below the annular guide cylinder.
CN201810573047.5A 2016-02-29 2016-02-29 Biological adsorber for treating heavy metal wastewater Active CN108658249B8 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810573047.5A CN108658249B8 (en) 2016-02-29 2016-02-29 Biological adsorber for treating heavy metal wastewater

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201610113569.8A CN105753171B (en) 2016-02-29 2016-02-29 A method of processing heavy metal wastewater thereby
CN201810573047.5A CN108658249B8 (en) 2016-02-29 2016-02-29 Biological adsorber for treating heavy metal wastewater

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
CN201610113569.8A Division CN105753171B (en) 2016-02-29 2016-02-29 A method of processing heavy metal wastewater thereby

Publications (3)

Publication Number Publication Date
CN108658249A CN108658249A (en) 2018-10-16
CN108658249B CN108658249B (en) 2021-11-12
CN108658249B8 true CN108658249B8 (en) 2021-12-07

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Family Applications (5)

Application Number Title Priority Date Filing Date
CN201810591279.3A Active CN108483680B (en) 2016-02-29 2016-02-29 Biosorbent for treating heavy metal wastewater and preparation method thereof
CN201810573047.5A Active CN108658249B8 (en) 2016-02-29 2016-02-29 Biological adsorber for treating heavy metal wastewater
CN201810573048.XA Active CN108715843B (en) 2016-02-29 2016-02-29 Preparation method of immobilized cell ball for treating heavy metal wastewater
CN201810573043.7A Active CN108751427B (en) 2016-02-29 2016-02-29 Preparation method of rhizopus oryzae mycelium pellets for treating heavy metal wastewater
CN201610113569.8A Active CN105753171B (en) 2016-02-29 2016-02-29 A method of processing heavy metal wastewater thereby

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Family Applications After (3)

Application Number Title Priority Date Filing Date
CN201810573048.XA Active CN108715843B (en) 2016-02-29 2016-02-29 Preparation method of immobilized cell ball for treating heavy metal wastewater
CN201810573043.7A Active CN108751427B (en) 2016-02-29 2016-02-29 Preparation method of rhizopus oryzae mycelium pellets for treating heavy metal wastewater
CN201610113569.8A Active CN105753171B (en) 2016-02-29 2016-02-29 A method of processing heavy metal wastewater thereby

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CN106045222A (en) * 2016-07-22 2016-10-26 宁国市渠源净水设备有限公司 Apparatus for purifying wastewater and waste gas produced in regenerated zinc industry
CN106115937A (en) * 2016-07-22 2016-11-16 汪枫 Equip for producing the process of the sewage waste gas of the industry of zinc
CN106219863A (en) * 2016-07-22 2016-12-14 汪枫 The purifier of the sewage waste gas that reviver industry produces
CN106045220A (en) * 2016-07-22 2016-10-26 宁国市渠源净水设备有限公司 Equipment for treating industrial wastewater and waste gas generated during lead production
CN106219864A (en) * 2016-07-22 2016-12-14 汪枫 A kind of for administering the device producing copper industry waste water and gas
CN106001078A (en) * 2016-07-29 2016-10-12 宁国市渠源净水设备有限公司 Equipment for remediating cobalt-polluted soil
CN106216390A (en) * 2016-07-29 2016-12-14 李晶晶 The process pond polluted for zinc in soil
CN106216389A (en) * 2016-07-29 2016-12-14 宁国市渠源净水设备有限公司 A kind of device repairing selenium contamination soil
CN106040730A (en) * 2016-07-29 2016-10-26 许邦祥 Soil treatment device for mercury pollution
CN106111696A (en) * 2016-07-29 2016-11-16 许邦祥 The processing means of heavy metal chromium pollution soil
CN106216388A (en) * 2016-07-29 2016-12-14 宁国市渠源净水设备有限公司 The equipment of purifying arsenic contamination soil
CN106216369A (en) * 2016-07-29 2016-12-14 宁国市渠源净水设备有限公司 The process pond of the soil of copper staining
CN106001079A (en) * 2016-07-29 2016-10-12 李晶晶 Treating pond for lead contaminated soil
CN106180178A (en) * 2016-07-29 2016-12-07 宁国市渠源净水设备有限公司 The device of cadmium pollution soil repair
CN106064176A (en) * 2016-07-29 2016-11-02 许邦祥 The controlling device of organotin pollution soil
CN107376856A (en) * 2017-07-03 2017-11-24 安徽天顺环保设备股份有限公司 A kind of heavy metal adsorbent composition
CN109097591B (en) * 2018-08-02 2021-03-23 中南大学 Calcium alginate immobilized microbial adsorbent, preparation method thereof and application thereof in recycling platinum group metal secondary resources
CN112481177B (en) * 2020-11-30 2023-10-13 深圳市职业病防治院 Construction and application of cadmium ion microorganism whole-cell biosensing-adsorber
CN112694213A (en) * 2021-01-12 2021-04-23 陕西科技大学 Method for removing metal ions in wastewater

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Publication number Publication date
CN108751427A (en) 2018-11-06
CN108658249A (en) 2018-10-16
CN105753171A (en) 2016-07-13
CN108715843A (en) 2018-10-30
CN108483680B (en) 2019-09-13
CN105753171B (en) 2018-07-27
CN108483680A (en) 2018-09-04
CN108751427B (en) 2021-01-29
CN108715843B (en) 2019-12-20
CN108658249B (en) 2021-11-12

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Address after: 277599 room 1419, Lunda Jinling International, Beixin street, Tengzhou City, Zaozhuang City, Shandong Province

Patentee after: Tengzhou daozhisheng Intelligent Technology Co.,Ltd.

Address before: 213000 room 18-812, Tongjiang Road, Xinbei District, Changzhou City, Jiangsu Province

Patentee before: CHANGZHOU AISHANGXUE EDUCATION TECHNOLOGY Co.,Ltd.

TR01 Transfer of patent right
CI03 Correction of invention patent

Correction item: Patentee|Address

Correct: Tengzhou daozhisheng Intelligent Technology Co.,Ltd.|Room 1419, Lunda Jinling International, Beixin street, Tengzhou City, Zaozhuang City, Shandong Province, 277599

False: CHANGZHOU AISHANGXUE EDUCATION TECHNOLOGY Co.,Ltd.|213000 room 18-812, Tongjiang Road, Xinbei District, Changzhou, Jiangsu.

Number: 46-02

Page: The title page

Volume: 37

Correction item: Patentee|Address

Correct: Tengzhou daozhisheng Intelligent Technology Co.,Ltd.|Room 1419, Lunda Jinling International, Beixin street, Tengzhou City, Zaozhuang City, Shandong Province, 277599

False: CHANGZHOU AISHANGXUE EDUCATION TECHNOLOGY Co.,Ltd.|213000 room 18-812, Tongjiang Road, Xinbei District, Changzhou, Jiangsu.

Number: 46-02

Volume: 37

CI03 Correction of invention patent
TR01 Transfer of patent right

Effective date of registration: 20221226

Address after: Room 216, Tus Star, No. 2059, Zhonghua West Road, High tech Zone, Heze City, Shandong Province, 274039

Patentee after: Shandong Torch Zhongyuan Technology Market Management Co.,Ltd.

Address before: Room 1419, Lunda Jinling International, Beixin street, Tengzhou City, Zaozhuang City, Shandong Province, 277599

Patentee before: Tengzhou daozhisheng Intelligent Technology Co.,Ltd.

TR01 Transfer of patent right