[go: up one dir, main page]

CN108623205A - A method of improving cement grinding aid homogeneity - Google Patents

A method of improving cement grinding aid homogeneity Download PDF

Info

Publication number
CN108623205A
CN108623205A CN201710162447.2A CN201710162447A CN108623205A CN 108623205 A CN108623205 A CN 108623205A CN 201710162447 A CN201710162447 A CN 201710162447A CN 108623205 A CN108623205 A CN 108623205A
Authority
CN
China
Prior art keywords
grinding aid
water
cement grinding
follows
improving cement
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201710162447.2A
Other languages
Chinese (zh)
Other versions
CN108623205B (en
Inventor
林辉
刘辉
唐官保
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BEIJING FENGLEBAO TECHNOLOGY Co.,Ltd.
Fenglebao chemical materials (Beijing) Co.,Ltd.
Original Assignee
Beijing Feng Le Bao Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Beijing Feng Le Bao Technology Co Ltd filed Critical Beijing Feng Le Bao Technology Co Ltd
Priority to CN201710162447.2A priority Critical patent/CN108623205B/en
Publication of CN108623205A publication Critical patent/CN108623205A/en
Application granted granted Critical
Publication of CN108623205B publication Critical patent/CN108623205B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B40/00Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
    • C04B40/0028Aspects relating to the mixing step of the mortar preparation
    • C04B40/0039Premixtures of ingredients
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B7/00Hydraulic cements
    • C04B7/36Manufacture of hydraulic cements in general
    • C04B7/48Clinker treatment
    • C04B7/52Grinding ; After-treatment of ground cement
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/001Processes for the treatment of water whereby the filtration technique is of importance
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/34Treatment of water, waste water, or sewage with mechanical oscillations
    • C02F1/36Treatment of water, waste water, or sewage with mechanical oscillations ultrasonic vibrations
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/52Grinding aids; Additives added during grinding

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

A method of improving cement grinding aid homogeneity, be related to cement additive field, includes mainly (one) water treatment technology and (two) grinding aid complex process.Wherein, (one) water treatment technology is as follows:1. adding cleanser;2. sonicated;3. filtering;4. the thickening of water is handled.Parameter is as follows described in each step:(1) cleanser:3wt%~10wt%;(2) supersonic frequency:20‑35KHZ;(3) thickener:2wt%~10wt%;(4) sonication times:10~30min.(2) relevant parameter of complex process and each substance is as follows:The obtained water of (one) technique, dissolved salt, sonicated are added in a reservoir.Hydramine and industrial waste are sequentially added, 15min, sound wave dispersion are stirred.The parameter of each substance is as follows:(1) hydramine:10%~20%;(2) Nacl:8%~17%;(3) industrial waste:20%~30%;(4) water:48%~60%;(5) ultrasonic time:10min~30min.Gained grinding aid active ingredient of the invention greatly improves, and grinding aid stable homogeneous has very big application prospect without sedimentation.

Description

A method of improving cement grinding aid homogeneity
Technical field
The present invention relates to a kind of methods improving cement grinding aid homogeneity, are related to cement concrete admixture compounding neck Domain especially belongs to cement grinding aid production field.
Background technology
Currently, China's overwhelming majority cement production enterprise reduces energy consumption in cement production process, improves cement output, A certain amount of grinding aid is added in manufacture of cement to realize the target of energy-saving and emission-reduction.Cement grinding aid can be carried using one side The performance of high cement products, while can also realize the comprehensive utilization of Industrial Solid Waste raw material.Therefore, grinding aid with being cement Major transformation of industry, while being also to walk high-quality, efficient, low consumption, Environmental compatibility sustainable development to what country advocated The response of road.
The hydramine substance such as triethanolamine/triisopropanolamine is generally acknowledged always relatively good raw material.But with grinding aid The kind of the development of industry, grinding aid raw material is more and more, and hydramine substance can be micro with some in water when grinding aid compounds Ion such as Ca2+、Mg2+Complex reaction occurs for plasma, generates flocculent deposit, the active ingredient in grinding aid is made to reduce.Meanwhile After some raw materials of industry are dissolved in water, the surface tension due to water in dilution is smaller, some indissoluble ingredients in the raw material of industry It settles, seriously affects the homogeneity of grinding aid, the performance of cement grinding aid is caused to decline.Therefore, a kind of improvement is had studied The method of cement grinding aid homogeneity, this method can improve the performance of cement grinding aid very well, solve when grinding aid compounds Sedimentation problem greatly improves grinding aid agent producing process.
Invention content
Present invention mainly solves the flocculent deposit problems occurred when grinding aid compounds, therefore disclose a kind of solution cement and help The method of grinding agent homogeneity.
To solve the problems, such as this, the present invention provides a kind for the treatment of process of grinding aid compounding water, pass through the purification to water Processing and thickening handle to improve the settlement issues occurred when cement grinding aid compounding.Specific implementation step and correlation are with such as Under:
One, water treatment technology
1. adding cleanser:Cleanser is added, stirs 30min.
2. sonicated:Sound wave water process is mainly the colloidal ion group destroyed in water, make colloid group in water with it is net Agent settles.
3. filtering:The suspended matter in water removal and part colloid are removed by gravitational settling, the turbidity of water is reduced, then passes through height Activated adoption object is filtered absorption to supernatant liquor, removes residual molecule.
4. the thickening of water is handled:Thickener is added in 3. water that step obtains, stirs 10min, increases the viscosity of water, with Sound wave dispersion is carried out afterwards, realizes the homogenization of water quality, it is required when obtaining grinding aid compounding to use water.
Processing parameter and correlated quality percentage are as follows described in each step:
(1) cleanser:3%~10% (percentage of water quality);
(2) supersonic frequency:20-35KHZ;
(3) thickener:2%~10% (percentage of water quality);
(4) sonication times:10min~30min;
Two, grinding aid complex process
The obtained water of (one) technique is added in a reservoir, Nacl is added, stirring 10min makes salt using supersound process It is completely dissolved.Hydramine substance and common Industry Waste raw material are then sequentially added, 15min is stirred, carries out sound wave dispersion.
Mass percent and the relevant parameter for being related to grinding aid each component are as follows:
(1) hydramine substance:10%~20%;
(2) Nacl:8%~17%;
(3) industrial waste:20%~30%;
(4) water:48%~60%;
(5) sonication times:10min~30min;
The cleanser is one or both of ferrous sulfate, alum, aluminium polychloride.
The sound wave is ultrasonic wave, frequency 20-35KHZ.
The high activity adsorbent is one or both of activated carbon, silicon rubber.
The thickener is one or both of hydroxypropyl methyl cellulose ether, xanthans, sodium alginate.
The Nacl is one or both of sodium chloride, sodium thiosulfate, potassium nitrate.
The alcamines is one or both of triethanolamine, triisopropanolamine, diethanol amine, diisopropanolamine (DIPA).
The industrial waste is one or both of crude glycerine, resinol, glyceride, sugarcane waste residue.
The present invention provides a kind of technique improving grinding aid homogeneity, has the following advantages that:
(1) present invention avoids water-borne glue body and ion component pair by the processing to water in grinding aid compound process The absorption and complexing of grinding aid active ingredient improve the active ingredient of grinding aid, improve grinding aid performance, reduce grinding energy.
(2) technique makes the viscosity of water increase, and is effectively improved the settlement issues of grinding aid, gained grinding aid stable homogeneous.
Specific implementation mode
Further to embody effect caused by the present invention, with reference to concrete application case to of the invention further detailed It describes in detail bright.
In application example every part representative be parts by weight.
Example 1
3 parts, supersonic frequency 20KHZ of cleanser, 2 parts, ultrasonic time 10min of thickener, treated 48 parts of water, alcamines 10 parts of substance, 8 parts of Nacl, 20 parts of industrial waste are made into grinding aid A1 according to above-mentioned steps (1) (2).
Example 2
5 parts, supersonic frequency 25KHZ of cleanser, 4 parts, ultrasonic time 15min of thickener, treated 51 parts of water, alcamines 13 parts of substance, 10 parts of Nacl, 22 parts of industrial waste are made into grinding aid A2 according to above-mentioned steps (1) (2).
Example 3
6 parts, supersonic frequency 28KHZ of cleanser, 6 parts, ultrasonic time 20min of thickener, treated 54 parts of water, alcamines 16 parts of substance, 12 parts of Nacl, 24 parts of industrial waste are made into grinding aid A3 according to above-mentioned steps (1) (2).
Example 4
8 parts, supersonic frequency 30KHZ of cleanser, 8 parts, ultrasonic time 25min of thickener, treated 57 parts of water, alcamines 18 parts of substance, 14 parts of Nacl, 27 parts of industrial waste are made into grinding aid A4 according to above-mentioned steps (1) (2).
Example 5
10 parts, supersonic frequency 35KHZ of cleanser, 10 parts, ultrasonic time 30min of thickener, treated 60 parts of water, hydramine 20 parts of substance, 17 parts of Nacl, 30 parts of industrial waste are made into grinding aid A5 according to above-mentioned steps (1) (2).
This obtained 5 kinds of grinding aids are subjected to grinding to cement proportion shown in table 1.The chemical composition of Portland clinker It is as shown in table 2 with mineral composition;Gypsum is natural dihydrate gypsum, and wherein crystal water content is 16.7%, SO3Content is 41.8%.Portland clinker and gypsum are taken from Beijing Xin Bei Cement Co., Ltds.Performance survey has been carried out to cement sample Examination, wherein fineness is according to GB/T1345-2005《Cement fineness detection method sieve formula》Test;Specific surface area is according to GB/ T8074-2008《Method of determination for specific surface of cement Bo Shi methods》Test;Intensity according to《Strength of cement mortar detection method (ISO Method)》(GB/T17671-1999) cement mortar strength of cement is tested, test result is as shown in table 3.
1 cement proportion of table (%)
Clinker Gypsum
95 5
2 clinker chemical composition of table and mineral composition analysis (%)
Loss SiO2 Al2O3 Fe2O3 CaO MgO
0.42 21.29 5.76 5.24 63.52 2.11
f-CaO SO3 C3S C2S C3A C4AF
0.58 0.35 47.83 25.82 5.74 16.13
Influence of 3 present invention of table to cement performance
It is as shown in table 3 with the influence of the Grinding Aids On Cement Properties of the Process configuration.In example 1,2,3,4,5, grinding aid Under 0.03% volume, cement 3d and 28d intensity improves tool and increases, and compounds to obtain grinding aid compared to traditional handicraft, 1~2.5MPa of strength of cement can be improved under same volume.And after the grinding aid configured with this method stands 6 months, do not have There is flocculent deposit problem.The technique provides beneficial way to the comprehensive utilization of cement industry energy-saving and emission-reduction and industrial waste.

Claims (8)

1. technical scheme of the present invention:A method of improve cement grinding aid homogeneity, including (one) water treatment technology and (2) grinding aid complex process, when relevant parameter is as follows with each material mass percentage for specific implementation step:
(1) water treatment technology step and relevant parameter and each material mass percentage
1. adding cleanser;
2. sonicated;
3. filtering;
4. the thickening of water is handled.
Processing parameter is as follows described in each step:
(1) cleanser:3%~10% (percentage of water quality);
(2) supersonic frequency:20-35KHZ;
(3) thickener:2%~10% (percentage of water quality);
(4) sonication times:10min~30min;
(2) grinding aid complex process and each material mass percentage when relevant parameter
The obtained water of (one) technique is added in a reservoir, Nacl is added, stirring 10min keeps salt complete using sonicated Dissolving.Hydramine substance and common Industry Waste raw material are then sequentially added, 15min is stirred, carries out sound wave dispersion.
Mass percent and the relevant parameter for being related to grinding aid each component are as follows:
(1) hydramine substance:10%~20%;
(2) Nacl:8%~17%;
(3) industrial waste:20%~30%;
(4) water:48%~60%;
(5) sonication times:10min~30min.
2. a kind of method improving cement grinding aid homogeneity according to claim 1, is technically characterized in that, described Cleanser is one or both of ferrous sulfate, alum, aluminium polychloride.
3. a kind of method improving cement grinding aid homogeneity according to claim 1, is technically characterized in that, described Sound wave is ultrasonic wave, frequency 20-35KHZ.
4. a kind of method improving cement grinding aid homogeneity according to claim 1, is technically characterized in that, described High activity adsorbent is one or both of activated carbon, silicon rubber.
5. a kind of method improving cement grinding aid homogeneity according to claim 1, is technically characterized in that, described Thickener is one or both of hydroxypropyl methyl cellulose ether, xanthans, sodium alginate.
6. a kind of method improving cement grinding aid homogeneity according to claim 1, is technically characterized in that, described Nacl is, one or both of sodium chloride, sodium thiosulfate.
7. a kind of method improving cement grinding aid homogeneity according to claim 1, is technically characterized in that, described Alcamines is one or both of triethanolamine, triisopropanolamine, diethanol amine, diisopropanolamine (DIPA).
8. a kind of method improving cement grinding aid homogeneity according to claim 1, is technically characterized in that, described Industrial waste is one or both of crude glycerine, resinol, glyceride, sugarcane waste residue.
CN201710162447.2A 2017-03-18 2017-03-18 Method for improving homogeneity of cement grinding aid Active CN108623205B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710162447.2A CN108623205B (en) 2017-03-18 2017-03-18 Method for improving homogeneity of cement grinding aid

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710162447.2A CN108623205B (en) 2017-03-18 2017-03-18 Method for improving homogeneity of cement grinding aid

Publications (2)

Publication Number Publication Date
CN108623205A true CN108623205A (en) 2018-10-09
CN108623205B CN108623205B (en) 2021-03-16

Family

ID=63686540

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710162447.2A Active CN108623205B (en) 2017-03-18 2017-03-18 Method for improving homogeneity of cement grinding aid

Country Status (1)

Country Link
CN (1) CN108623205B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111453907A (en) * 2020-04-08 2020-07-28 大连百傲化学股份有限公司 Recycling treatment process of waste brine in production of 1, 2-benzisothiazolin-3-one

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2012551C1 (en) * 1992-01-04 1994-05-15 Иван Васильевич Ситников Method of preparing mixture for production of building materials
CN1605573A (en) * 2003-10-07 2005-04-13 瓦特克瓦巴格有限责任公司 Disintegration of anaerobically digested sewage sludge
JP2005288423A (en) * 2004-03-31 2005-10-20 Kazutoshi Igarashi Adsorption base material for acetaldehyde, or the like, and chemical preparation base material
CN103641247A (en) * 2013-12-27 2014-03-19 姚为 Domestic sewage treatment agent and preparation method thereof
CN105439487A (en) * 2015-12-16 2016-03-30 陈晖� Reinforced type cement grinding aid
CN105503003A (en) * 2016-01-04 2016-04-20 山东宏艺科技股份有限公司 Cement grinding aid and preparation method thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2012551C1 (en) * 1992-01-04 1994-05-15 Иван Васильевич Ситников Method of preparing mixture for production of building materials
CN1605573A (en) * 2003-10-07 2005-04-13 瓦特克瓦巴格有限责任公司 Disintegration of anaerobically digested sewage sludge
JP2005288423A (en) * 2004-03-31 2005-10-20 Kazutoshi Igarashi Adsorption base material for acetaldehyde, or the like, and chemical preparation base material
CN103641247A (en) * 2013-12-27 2014-03-19 姚为 Domestic sewage treatment agent and preparation method thereof
CN105439487A (en) * 2015-12-16 2016-03-30 陈晖� Reinforced type cement grinding aid
CN105503003A (en) * 2016-01-04 2016-04-20 山东宏艺科技股份有限公司 Cement grinding aid and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111453907A (en) * 2020-04-08 2020-07-28 大连百傲化学股份有限公司 Recycling treatment process of waste brine in production of 1, 2-benzisothiazolin-3-one
CN111453907B (en) * 2020-04-08 2022-03-08 大连百傲化学股份有限公司 Recycling treatment process of waste brine in production of 1, 2-benzisothiazolin-3-one

Also Published As

Publication number Publication date
CN108623205B (en) 2021-03-16

Similar Documents

Publication Publication Date Title
CN101693605A (en) Composite high-efficient liquid cement grinding aid
CN103833257B (en) A kind of short solidifying enhanced cement grinding aid
CN107244819B (en) Converter hot-stewed steel slag powder activating agent and preparation method and application thereof
CN110436805A (en) The method for innocent treatment of filleting land plaster and preparation method thereof and ardealite
CN104926190B (en) A kind of composite cement grinding aid
CN112299795B (en) Recycled concrete and preparation method thereof
CN110526631A (en) Fly ash-based geopolymer material and preparation method thereof for solidifying chromium slag
CN106380110B (en) A kind of graphene oxide is modified cement grinding aid and preparation method thereof
CN109231904A (en) A kind of early-strength self-compacting concrete and preparation method thereof
CN108503292A (en) The metakaolin base geological polymer and preparation method thereof of slag powder is discarded in a kind of addition
CN105366977A (en) Cement reinforcing agent, preparation method, and application thereof
CN106517991A (en) Self-toughening magnesia cementitious material
CN108623205A (en) A method of improving cement grinding aid homogeneity
CN109503019A (en) A method of subtracting jelly using the preparation of carbohydrate leftover bits and pieces
CN108439927A (en) A kind of drilling mud curing materials prepared by wet grinding
CN111908820A (en) A method for improving concrete strength and toughness by micro-nano material containing sulfonated fibers
CN105442047A (en) Method for extracting fluorine element from industrial gypsum
CN104844062B (en) Nano modified cement mixing pile additive suitable for ocean rock-soil environment and preparation method of additive
CN108147742A (en) It is a kind of for hybrid fiber concrete of 3D printing and preparation method thereof
CN114105516B (en) Sprayed concrete viscosity modifier and preparation method thereof
CN104232100A (en) Chromium-polluted soil modifier
CN106745464A (en) A kind of waste water control medicament rapidly and efficiently and preparation method thereof
CN108147699A (en) A kind of cement grinding aid and its application
CN110819357B (en) A kind of acidic soil remediation agent and its preparation and application
CN107445532A (en) Over cure electrolytic manganese residues concrete and preparation method thereof

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
TA01 Transfer of patent application right
TA01 Transfer of patent application right

Effective date of registration: 20210219

Address after: Room 211, xinqiwang office building, No.5 Huahua Road, Chaoyang District, Beijing 100023

Applicant after: BEIJING FENGLEBAO TECHNOLOGY Co.,Ltd.

Applicant after: Fenglebao chemical materials (Beijing) Co.,Ltd.

Address before: Room 211, xinqiwang office building, No.5 Huahua Road, Chaoyang District, Beijing 100023

Applicant before: BEIJING FENGLEBAO TECHNOLOGY Co.,Ltd.

GR01 Patent grant
GR01 Patent grant